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Author |
Van Grieken, R.; Speecke, A.; Hoste, J. |
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Title |
Simultaneous determination of silicon and phosphorus in cast iron by 14 MeV neutron activation analysis |
Type |
A3 Journal article |
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Year |
1970 |
Publication |
Journal of radioanalytical chemistry |
Abbreviated Journal |
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Volume |
6 |
Issue |
2 |
Pages |
385-398 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
A fast (10 min), non-destructive simultaneous determination of silicon and phosphorus in cast iron and steel by 14 MeV neutron activation was developed. The 1.78 MeV28Al activity (T=2.24 min) induced by the reaction28Si(n, p)28Al is counted on a NaI(Tl) detector. Two measurements are made to correct for the 1.81 MeV56Mn activity (T=2.58 hr) from the iron matrix. However,28Al is also produced via31P(n, α)28Al. By (n, 2n) reaction, phosphorus yields also30P (T=2.6 min), the 0.511 MeV annihilation radiation of which is counted by two opposite NaI(Tl) detectors in coincidence. Again, two successive coincidence measurements are carried out in order to take into account the53Fe activity (β+; T=8.9 min) from54Fe(n, 2n)53Fe. The28Al measurement is appropriately corrected via the computed phosphorus content. An oxygen flux monitor was used to normalize to the same flux. Nuclear interferences have been examined. Special attention has been paid to the presence of copper. The standard deviation for phosphorus being as high as ca. 0.09% P for a single determination, this technique can only be practical as an independent phosphorus analysis for high phosphorus cast irons. The precision on the28Al measurement is 5% relative for 0.2% Si and 2.5% above 1% Si. |
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2006-10-11 |
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ISSN |
0134-0719; 2064-2857 |
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Call Number |
UA @ admin @ c:irua:116450 |
Serial  |
8528 |
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Author |
Ro, C.-U.; Oh, K.-Y.; Kim, H.; Kim, Y.P.; Lee, C.B.; Kim, K.-H.; Kang, C.H.; Osán, J.; de Hoog, J.; Worobiec, A.; Van Grieken, R. |
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Title |
Single-particle analysis of aerosols at Cheju Island, Korea, using low-Z electron probe X-ray microanalysis: a direct proof of nitrate formation from sea salts |
Type |
A1 Journal article |
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Year |
2001 |
Publication |
Environmental science and technology |
Abbreviated Journal |
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Volume |
35 |
Issue |
22 |
Pages |
4487-4494 |
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Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
000172177700014 |
Publication Date |
2002-07-26 |
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ISSN |
0013-936x; 1520-5851 |
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Call Number |
UA @ admin @ c:irua:36092 |
Serial |
8529 |
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Author |
van Malderen, H.; Van Grieken, R.; Khodzher, T.V.; Grachev, M.; Bufetov, N.S.; Koutsenogii, K.P. |
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Title |
Single particle analysis of aerosols from Siberia |
Type |
P3 Proceeding |
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Year |
1994 |
Publication |
Proceedings of the Russian-Ukrainian-Austrian-German Analytical Symposium |
Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:9527 |
Serial |
8530 |
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Author |
de Bock, L.A.; Joos, P.E.; Noone, K.J.; Pockalny, R.A.; Van Grieken, R.E. |
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Title |
Single particle analysis of aerosols, observed in the marine boundary layer during the Monterey Area Ship Tracks Experiment (MAST), with respect to cloud droplet formation |
Type |
A1 Journal article |
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Year |
2000 |
Publication |
Journal of atmospheric chemistry |
Abbreviated Journal |
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Volume |
37 |
Issue |
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Pages |
299-329 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
000089349400005 |
Publication Date |
2002-12-22 |
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Edition |
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ISSN |
0167-7764 |
ISBN |
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UA library record; WoS full record; WoS citing articles |
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Call Number |
UA @ admin @ c:irua:31674 |
Serial |
8531 |
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Author |
Török, S.; Sandor, S.; Xhoffer, C.; Van Grieken, R.; Meszaros, E.; Molnar, A. |
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Title |
Single particle analysis of Hungarian background aerosol |
Type |
A3 Journal article |
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Year |
1992 |
Publication |
Idojaras: quarterly journal of the Hungarian Meteorological Service |
Abbreviated Journal |
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Volume |
96 |
Issue |
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Pages |
223-233 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:2847 |
Serial |
8532 |
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Author |
Dekov, V.M.; van Put, A.; Eisma, D.; Van Grieken, R. |
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Title |
Single particle analysis of suspended matter in the Makasar Strait and Flores Sea with particular reference to tin-bearing particles |
Type |
A1 Journal article |
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Year |
1999 |
Publication |
Journal of sea research |
Abbreviated Journal |
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Volume |
41 |
Issue |
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Pages |
35-53 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
000079367500004 |
Publication Date |
2002-07-25 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1385-1101 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
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Call Number |
UA @ admin @ c:irua:23183 |
Serial |
8533 |
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Author |
de Bock, L.A.; Van Grieken, R.E. |
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Title |
Single particle analysis techniques |
Type |
H3 Book chapter |
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Year |
1999 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
243-275
T2 - Analytical chemistry of aerosols / Sp |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:27599 |
Serial |
8534 |
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Author |
Jambers, W.; Dekov, V.; Van Grieken, R. |
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Title |
Single particle and inorganic characterization of rainwater collected above the North Sea |
Type |
A1 Journal article |
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Year |
2000 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
256 |
Issue |
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Pages |
133-150 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
000088065200006 |
Publication Date |
2002-07-25 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:31673 |
Serial |
8535 |
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Author |
Jambers, W.; Dekov, V.; Van Grieken, R. |
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Title |
Single particle characterisation of inorganic and organic North Sea suspension |
Type |
A1 Journal article |
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Year |
1999 |
Publication |
Marine chemistry |
Abbreviated Journal |
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Volume |
67 |
Issue |
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Pages |
17-32 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
000082709500002 |
Publication Date |
2002-07-25 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0304-4203; 1872-7581 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Open Access |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:27581 |
Serial |
8536 |
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Author |
Jambers, W.; Van Grieken, R. |
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Title |
Single particle characterisation of inorganic North Sea suspensions |
Type |
P3 Proceeding |
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Year |
1996 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:14670 |
Serial |
8537 |
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Author |
Jambers, W.; Van Grieken, R. |
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Title |
Single particle characterisation of inorganic suspension in Lake Baikal |
Type |
A1 Journal article |
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Year |
1997 |
Publication |
Environmental science and technology |
Abbreviated Journal |
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Volume |
31 |
Issue |
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Pages |
1525-1533 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Edition |
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ISSN |
0013-936x; 1520-5851 |
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UA library record |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:18776 |
Serial |
8538 |
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Author |
Hoornaert, S.; Godoi, R.H.M.; Van Grieken, R. |
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Title |
Single particle characterisation of the aerosol in the marine boundary layer and free troposphere over Tenerife, NE Atlantic, during ACE-2 |
Type |
A1 Journal article |
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Year |
2003 |
Publication |
Journal of atmospheric chemistry |
Abbreviated Journal |
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Volume |
46 |
Issue |
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Pages |
271-293 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
000186253500003 |
Publication Date |
2003-11-04 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0167-7764 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:43521 |
Serial |
8539 |
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Author |
Ro, C.-U.; Hwang, H.; Kim, H.K.; Chun, Y.; Van Grieken, R. |
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Title |
Single-particle characterization of four “Asian Dust” samples collected in Korea, using low-Z particle electron probe X-ray microanalysis |
Type |
A1 Journal article |
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Year |
2005 |
Publication |
Environmental science and technology |
Abbreviated Journal |
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Volume |
39 |
Issue |
6 |
Pages |
1409-1419 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Wos |
000227636300012 |
Publication Date |
2005-03-11 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0013-936x; 1520-5851 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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| |
Call Number |
UA @ admin @ c:irua:51591 |
Serial |
8540 |
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| Permanent link to this record |
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Author |
Ro, C.-U.; Kim, H.; Oh, K.-Y.; Yea, S.K.; Lee, C.B.; Jang, M.; Van Grieken, R. |
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Title |
Single-particle characterization of urban aerosol particles collected in three Korean cities using low-Z electron probe x-ray microanalysis |
Type |
A1 Journal article |
| |
Year |
2002 |
Publication |
Environmental science and technology |
Abbreviated Journal |
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| |
Volume |
36 |
Issue |
22 |
Pages |
4770-4776 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Wos |
000179348500010 |
Publication Date |
2002-11-13 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0013-936x; 1520-5851 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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| |
Call Number |
UA @ admin @ c:irua:40617 |
Serial |
8541 |
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| Permanent link to this record |
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Author |
Krata, A.; Kontozova-Deutsch, V.; Bencs, L.; Deutsch, F.; Van Grieken, R. |
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Title |
Single-run ion chromatographic separation of inorganic and low-molecular-mass organic anions under isocratic elution: application to environmental samples |
Type |
A1 Journal article |
| |
Year |
2009 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
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| |
Volume |
79 |
Issue |
1 |
Pages |
16-21 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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| |
Abstract |
For the isocratic ion chromatography (IC) separation of low-molecular-mass organic acids and inorganic anions three different anion-exchange columns were studied: IonPac AS14 (9 ìm particle size), Allsep A-2 (7 ìm particle size), and IC SI-50 4E (5 ìm particle size). A complete baseline separation for all analyzed anions (i.e., F−, acetate, formate, Cl−, NO2−, Br−, NO3−, HPO42− and SO42−) in one analytical cycle of shorter than 17 min was achieved on the IC SI-50 4E column, using an eluent mixture of 3.2 mM Na2CO3 and 1.0 mM NaHCO3 with a flow rate of 1.0 mL min−1. On the IonPac AS14 column, it was possible to separate acetate from inorganic anions in one run (i.e., less than 9 min), but not formate, under the following conditions: 3.5 mM Na2CO3 plus 1.0 mM NaHCO3 with a flow rate of 1.2 mL min−1. Therefore, it was necessary to adapt a second run with a 2.0 mM Na2B4O7 solution as an eluent under a flow rate of 0.8 mL min−1 for the separation of organic ions, which considerably enlarged the analysis time. For the Allsep A-2 column, using an eluent mixture of 1.2 mM Na2CO3 plus 1.5 mM NaHCO3 with a flow rate of 1.6 mL min−1, it was possible to separate almost all anions in one run within 25 min, except the fluoride-acetate critical pair. A Certified Multianion Standard Solution PRIMUS for IC was used for the validation of the analytical methods. The lowest RSDs (less than 1%) and the best LODs (0.02, 0.2, 0.16, 0.11, 0.06, 0.05, 0.04, 0.14 and 0.09 mg L−1 for F−, Ac−, For−, Cl−, NO2−, Br−, NO3−, HPO42− and SO42−, respectively) were achieved using the IC SI-50 4E column. This column was applied for the separation of concerned ions in environmental precipitation samples such as snow, hail and rainwater. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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| |
Language |
|
Wos |
000266187600004 |
Publication Date |
2009-03-06 |
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| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0039-9140; 1873-3573 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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| |
Impact Factor |
|
Times cited |
|
Open Access |
|
|
| |
Notes |
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Approved |
no |
|
| |
Call Number |
UA @ admin @ c:irua:75475 |
Serial |
8542 |
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| Permanent link to this record |
| |
|
| |
|
Author |
Eltayeb, M.A.H.; van Espen, P.J.; Cafmeyer, J.; Van Grieken, R.E.; Maenhaut, W. |
|
| |
Title |
Size-differentiated composition of aerosols in Khartoum, Sudan |
Type |
A1 Journal article |
| |
Year |
1992 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
|
| |
Volume |
120 |
Issue |
|
Pages |
281-299 |
|
| |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
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| |
Abstract |
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| |
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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| |
Language |
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Wos |
A1992JA65200008 |
Publication Date |
2003-09-12 |
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| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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| |
Impact Factor |
|
Times cited |
|
Open Access |
|
|
| |
Notes |
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Approved |
no |
|
| |
Call Number |
UA @ admin @ c:irua:2834 |
Serial |
8543 |
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| Permanent link to this record |
| |
|
| |
|
Author |
Oprya, M.; Kiro, S.; Worobiec, A.; Horemans, B.; Darchuk, L.; Novakovic, V.; Ennan, A.; Van Grieken, R. |
|
| |
Title |
Size distribution and chemical properties of welding fumes of inhalable particles |
Type |
A1 Journal article |
| |
Year |
2012 |
Publication |
Journal of aerosol science |
Abbreviated Journal |
|
|
| |
Volume |
45 |
Issue |
1 |
Pages |
50-57 |
|
| |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
|
| |
Abstract |
The goal of the present study was to analyze the relationship between the fume formation rate, welding conditions, chemical composition of welding fume particles and their size. In the range from 0.25 to 16 μm aerodynamic diameter, three distinct types of welding fume particles were identified in the welder's breathing zone. The elemental composition of each type depended completely on the used welding materials, and reflects their mechanism of formation. Their relative abundance in the welding fume appeared to be dependent on the electrode coating, as well as the heat input during welding. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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| |
Language |
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Wos |
000300140000005 |
Publication Date |
2011-10-26 |
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| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0021-8502; 1879-1964 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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| |
Impact Factor |
|
Times cited |
|
Open Access |
|
|
| |
Notes |
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Approved |
no |
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| |
Call Number |
UA @ admin @ c:irua:93184 |
Serial |
8544 |
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| Permanent link to this record |
| |
|
| |
|
Author |
Smekens, A.; Berghmans, P.; Van Grieken, R. |
|
| |
Title |
The size distribution and surface area of soot emitted by different sources |
Type |
A1 Journal article |
| |
Year |
2000 |
Publication |
Journal of aerosol science |
Abbreviated Journal |
|
|
| |
Volume |
31 |
Issue |
S1 |
Pages |
706-707 |
|
| |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
| |
Abstract |
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Address |
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| |
Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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| |
Language |
|
Wos |
|
Publication Date |
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| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0021-8502; 1879-1964 |
ISBN |
|
Additional Links |
UA library record |
|
| |
Impact Factor |
|
Times cited |
|
Open Access |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
UA @ admin @ c:irua:31643 |
Serial |
8545 |
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| Permanent link to this record |
| |
|
| |
|
Author |
Shani, J.; Barak, S.; Levi, D.; Ram, M.; Schachner, E.R.; Schlesinger, T.; Robberecht, H.; Van Grieken, R.; Avrach, W.W. |
|
| |
Title |
Skin penetration of minerals in psoriatics and guinea-pigs bathing in hypertonic salt solutions |
Type |
A3 Journal article |
| |
Year |
1985 |
Publication |
Pharmacological research communications |
Abbreviated Journal |
|
|
| |
Volume |
17 |
Issue |
6 |
Pages |
501-512 |
|
| |
Keywords |
A3 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
| |
Abstract |
Penetration of electrolytes through the human skin was measured in healthy volunteers and in psoriatic patients after bathing in the Dead-Sea or in simulated bath-salt solutions. Significant increases in the levels of serum Br, Rb, Ca and Zn were noticed only in the psoriatic patients after daily bathing in the Dead-Sea for a 4-week regimen. Guinea-pigs bathed in simulated Dead-Sea bath-salt solutions containing radionuclides of Ca, Mg, K and Br. Traces of each radionuclide were detected in the blood and in some internal organs after 60 minutes of bathing. The radionuclides showed a physiological pattern in their organ distribution. Even though the whole investigation was carried out in hypertonic solutions, there is a definite penetration of salts through healthy (human and guinea-pigs) and damaged (psoriatic) epidermis. This finding suggests that improvement of the psoriatic condition after bathing in the Dead-Sea, may be partly attributed (in addition to ultraviolet irradiation) to the minerals' effect on the psoriatic skin. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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| |
Language |
|
Wos |
|
Publication Date |
2006-07-20 |
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0031-6989 |
ISBN |
|
Additional Links |
UA library record |
|
| |
Impact Factor |
|
Times cited |
|
Open Access |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
UA @ admin @ c:irua:116755 |
Serial |
8547 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Van Grieken, R.; Van 't dack, L.; Costa Dantas, C.; Da Silveira Dantas, H. |
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| |
Title |
Soil analysis by thin-film energy-dispersive X-ray fluorescence |
Type |
A1 Journal article |
| |
Year |
1979 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
|
| |
Volume |
108 |
Issue |
|
Pages |
93-101 |
|
| |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
| |
Abstract |
Energy-dispersive x-ray fluorescence is advantageous for trace analysis of soils present as thin films. A target thickness of about 2 mg cm-2 provides a compromise between optimal sensitivity and minimal absorption effect or optimal accuracy. Sample preparation involves only suspending the finely ground soil in water and drying this suspension on a thin mylar foil glued on a ring that fits into the x.r.f. spectrometer. The effective sample weight present in the exciting beam area is computed from the scatter peaks, a method that cancels out target heterogeneity problems. High accuracy is demonstrated for many elements in reference soil and rock materials; a precision around 5% and a detection limit around 10 ppm can be achieved. As an illustration, results for 16 trace elements and preliminary interpretation are given for a series of pedologically important soil samples from Brasil. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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| |
Language |
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Wos |
A1979HL44100012 |
Publication Date |
2002-07-25 |
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| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
| |
Impact Factor |
|
Times cited |
|
Open Access |
|
|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
UA @ admin @ c:irua:111402 |
Serial |
8549 |
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| Permanent link to this record |
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| |
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Author |
Schalm, O.; Nuyts, G.; Janssens, K. |
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| |
Title |
Some critical observations about the degradation of glass : the formation of lamellae explained |
Type |
A1 Journal article |
| |
Year |
2021 |
Publication |
Journal Of Non-Crystalline Solids |
Abbreviated Journal |
J Non-Cryst Solids |
|
| |
Volume |
569 |
Issue |
|
Pages |
120984 |
|
| |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
| |
Abstract |
This study demonstrates that the mechanism responsible for the transformation of glass into a degradation layer is pH-dependent. In acid conditions, the transformed glass is homogeneous and brittle. In mild alkaline conditions, transformed glass is heterogeneous due to the presence of lamellae composed of silica nanoparticles and the occurrence of Ca-rich inclusions. The fundamental difference between acid and alkaline conditions cannot be explained by the currently accepted degradation mechanism based on ion exchange. To explain this critical observation, we propose a refined degradation mechanism based on existing knowledge that involves several inwardly moving reaction fronts. The fronts responsible for the transformation of the silicate network into amorphous silica are also responsible for the morphology of the transformed glass. We have identified the feedback mechanism that explains the formation of lamellae in alkaline conditions. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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| |
Language |
|
Wos |
000674487200009 |
Publication Date |
2021-06-20 |
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0022-3093 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
| |
Impact Factor |
2.124 |
Times cited |
|
Open Access |
OpenAccess |
|
| |
Notes |
|
Approved |
Most recent IF: 2.124 |
|
| |
Call Number |
UA @ admin @ c:irua:179835 |
Serial |
8551 |
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| Permanent link to this record |
| |
|
| |
|
Author |
Kuczumow, A.; Vekemans, B.; Schalm, O.; Vincze, L.; Dorriné, W.; Gysels, K.; Van Grieken, R. |
|
| |
Title |
Some new applications of auxiliary signals in X-ray fluorescence and electron microprobe analysis |
Type |
P1 Proceeding |
| |
Year |
1999 |
Publication |
|
Abbreviated Journal |
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| |
Volume |
|
Issue |
|
Pages |
197-201
T2 - Proceedings of the European Conferenc |
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| |
Keywords |
P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000081658400032 |
Publication Date |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
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Series Issue |
|
Edition |
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| |
ISSN |
|
ISBN |
|
Additional Links |
UA library record; WoS full record |
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| |
Impact Factor |
|
Times cited |
|
Open Access |
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|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
UA @ admin @ c:irua:24716 |
Serial |
8553 |
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| Permanent link to this record |
| |
|
| |
|
Author |
Van Grieken, R.; Kontozova, V.; Godoi, R.H.M.; Spolnik, Z.; Worobiec, A.; Deutsch, F.; Bencs, L. |
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| |
Title |
Some studies of the effect of indoor and outdoor pollutants on cultural heritage items |
Type |
P3 Proceeding |
| |
Year |
2005 |
Publication |
|
Abbreviated Journal |
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| |
Volume |
|
Issue |
|
Pages |
|
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| |
Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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| |
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
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Publication Date |
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| |
Series Editor |
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Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
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Series Issue |
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Edition |
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| |
ISSN |
|
ISBN |
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Additional Links |
UA library record |
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| |
Impact Factor |
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Times cited |
|
Open Access |
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| |
Notes |
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Approved |
no |
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| |
Call Number |
UA @ admin @ c:irua:57632 |
Serial |
8556 |
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| Permanent link to this record |
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| |
|
Author |
Al-Emam, E.; Motawea, A.G.; Caen, J.; Janssens, K. |
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| |
Title |
Soot removal from ancient Egyptian complex painted surfaces using a double network gel : empirical tests on the ceiling of the sanctuary of Osiris in the temple of Seti I-Abydos |
Type |
A1 Journal article |
| |
Year |
2021 |
Publication |
Heritage science |
Abbreviated Journal |
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| |
Volume |
9 |
Issue |
1 |
Pages |
1-10 |
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| |
Keywords |
A1 Journal article; Art; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES) |
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| |
Abstract |
In this study, we evaluated the ease of removal of soot layers from ancient wall paintings by employing double network gels as a controllable and safe cleaning method. The ceiling of the temple of Seti I (Abydos, Egypt) is covered with thick layers of soot; this is especially the case in the sanctuary of Osiris. These layers may have been accumulated during the occupation of the temple by Christians, fleeing the Romans in the first centuries A.D. Soot particulates are one of the most common deposits to be removed during conservation-restoration activities of ancient Egyptian wall paintings. They usually mask the painted reliefs and reduce the permeability of the painted surface. A Polyvinyl alcohol-borax/agarose (PVA-B/AG) double network gel was selected for this task since its properties were expected to be compatible with the cleaning treatment requirements. The gel is characterized by its flexibility, permitting to take the shape of the reliefs, while also having self-healing properties, featuring shape stability and an appropriate capacity to retain liquid. The gel was loaded with several cleaning reagents that proved to be effective for soot removal. Soot removal tests were conducted with these gel composites. The cleaned surfaces were evaluated with the naked eye, a digital microscope, and color measurements in order to select the best gel composite. The gel composite, loaded with a solution of 5% ammonia, 0.3% ammonium carbonate, and 0.3% EDTA yielded the most satisfactory results and allowed to safely remove a crust of thick soot layers from the surface. Thus, during the final phase of the study, it was used successfully to clean a larger area of the ceiling. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000604977300001 |
Publication Date |
2021-01-04 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
2050-7445 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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| |
Impact Factor |
|
Times cited |
|
Open Access |
OpenAccess |
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| |
Notes |
|
Approved |
Most recent IF: NA |
|
| |
Call Number |
UA @ admin @ c:irua:174948 |
Serial |
8557 |
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| Permanent link to this record |
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| |
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Author |
Cristale, J.; Álvarez-Martín, A.; Rodriguez-Cruz, S.; Sanchez-Martin, M.J.; Lacorte, S. |
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| |
Title |
Sorption and desorption of organophosphate esters with different hydrophobicity by soils |
Type |
A1 Journal article |
| |
Year |
2017 |
Publication |
Environmental Science and Pollution Research |
Abbreviated Journal |
|
|
| |
Volume |
24 |
Issue |
36 |
Pages |
27870-27878 |
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| |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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| |
Abstract |
Organophosphate esters (OPEs) are ubiquitous contaminants with potentially hazardous effects on both the environment and human health. Knowledge about the soil sorption-desorption process of organic chemicals is important in order to understand their fate, mobility, and bioavailability, enabling an estimation to be made of possible risks to the environment and biota. The aim of this study was to use the batch equilibrium technique to evaluate the sorption-desorption behavior of seven OPEs (TCEP, TCPP, TBEP, TDCP, TBP, TPhP, and EHDP) in soils with distinctive characteristics (two unamended soils and a soil amended with sewage sludge). The equilibrium concentrations of the OPEs were determined by high performance liquid chromatography coupled to a triple quadrupole mass spectrometer (HPLC-MS/MS). All the compounds were sorbed by the soils, and soil organic carbon (OC) played an important role in this process. The sorption of the most soluble OPEs (TCEP, TCPP, and TBEP) depended on soil OC content, although desorption was 58.1%. The less water-soluble OPEs (TDCP, TBP, TPhP, and EHDP) recorded total sorption (100% for TPhP and EHDP) or very high sorption (34.9%) by all the soils and were not desorbed, which could be explained by their highly hydrophobic nature, as indicated by the logarithmic octanol/water partition coefficient (K-ow) values higher than 3.8, resulting in a high affinity for soil OC. The results of the sorption-desorption of the OPEs by soils with different characteristics highlighted the influence of these compounds' physicochemical properties and the content and nature of soil OC in this process. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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| |
Language |
|
Wos |
000417874400025 |
Publication Date |
2017-10-07 |
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| |
Series Editor |
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Series Title |
|
Abbreviated Series Title |
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| |
Series Volume |
|
Series Issue |
|
Edition |
|
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| |
ISSN |
0944-1344; 1614-7499 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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| |
Impact Factor |
|
Times cited |
|
Open Access |
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|
| |
Notes |
|
Approved |
no |
|
| |
Call Number |
UA @ admin @ c:irua:160642 |
Serial |
8558 |
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| Permanent link to this record |
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|
| |
|
Author |
Török, S.; Szandor, S.; Xhoffer, C.; Van Grieken, R. |
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| |
Title |
Source apportionment of individual aerosol particles at Hungarian background stations |
Type |
H3 Book chapter |
| |
Year |
1993 |
Publication |
|
Abbreviated Journal |
|
|
| |
Volume |
|
Issue |
|
Pages |
32-331
T2 - Photo-oxidants: precursors and product |
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| |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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| |
Series Volume |
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Series Issue |
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Edition |
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| |
ISSN |
|
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:6265 |
Serial |
8559 |
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| Permanent link to this record |
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Author |
Vallius, M.; Janssen, N.A.H.; Heinrich, J.; Hoek, G.; Ruuskanen, J.; Cyrys, J.; Van Grieken, R.; de Hartog, J.J.; Kreyling, W.G.; Pekkanen, J. |
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Title |
Sources and elemental composition of ambient PM2.5 in three European cities |
Type |
A1 Journal article |
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Year |
2005 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
337 |
Issue |
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Pages |
147-162 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000226661700013 |
Publication Date |
2004-08-27 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:49804 |
Serial |
8560 |
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| Permanent link to this record |
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Author |
Evangelista, H.; Maldonado, J.; Godoi, R.H.M.; Pereira, E.B.; Koch, D.; Tanizaki-Fonseca, K.; Van Grieken, R.; Sampaio, M.; Setzer, A.; Alencar, A.; Gonçalves, S.C. |
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Title |
Sources and transport of urban and biomass burning aerosol black carbon at the South-West Atlantic coast |
Type |
A1 Journal article |
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Year |
2007 |
Publication |
Journal of atmospheric chemistry |
Abbreviated Journal |
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Volume |
56 |
Issue |
3 |
Pages |
225-238 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000245105900002 |
Publication Date |
2007-01-02 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0167-7764 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:63841 |
Serial |
8561 |
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| Permanent link to this record |
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Author |
Vanderborght, B.; Van Grieken, R. |
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Title |
Spark-source mass-spectrometric sensitivity factors for elements in a graphite matrix |
Type |
A1 Journal article |
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Year |
1979 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
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Volume |
26 |
Issue |
6 |
Pages |
461-465 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Relative sensitivity factors for determination of 41 elements by spark-source mass-spectrometry have been measured. The samples were pressed into graphite electrodes and ionized with a radiofrequency spark. The mass spectra were recorded on a photoplate and the resulting data processed by a computer. Indium was used as standard and the relative sensitivity factors for both singly- and doubly-charged ions were determined with reference to the singly-charged indium ion, with an overall error of 30%. The mean analysis precision was 16%. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Language |
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Wos |
A1979GX58000005 |
Publication Date |
2002-07-25 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0039-9140; 1873-3573 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:113630 |
Serial |
8563 |
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| Permanent link to this record |
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Author |
Vos, L.; Van Grieken, R. |
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Title |
Spark source mass spectrometry for trace analysis of diverse biological matrices |
Type |
H3 Book chapter |
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Year |
1983 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
303-306
T2 - Mass spectrometry advances 1982 / Sch |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
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ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:117486 |
Serial |
8564 |
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| Permanent link to this record |
