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Author Brognara, A.; Kashiwar, A.; Jung, C.; Zhang, X.; Ahmadian, A.; Gauquelin, N.; Verbeeck, J.; Djemia, P.; Faurie, D.; Dehm, G.; Idrissi, H.; Best, J.P.; Ghidelli, M.
Title Tailoring mechanical properties and shear band propagation in ZrCu metallic glass nanolaminates through chemical heterogeneities and interface density Type A1 Journal article
Year 2024 Publication Small Structures Abbreviated Journal
Volume (up) Issue Pages 2400011-11
Keywords A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT)
Abstract The design of high‐performance structural thin films consistently seeks to achieve a delicate equilibrium by balancing outstanding mechanical properties like yield strength, ductility, and substrate adhesion, which are often mutually exclusive. Metallic glasses (MGs) with their amorphous structure have superior strength, but usually poor ductility with catastrophic failure induced by shear bands (SBs) formation. Herein, we introduce an innovative approach by synthesizing MGs characterized by large and tunable mechanical properties, pioneering a nanoengineering design based on the control of nanoscale chemical/structural heterogeneities. This is realized through a simplified model Zr 24 Cu 76 /Zr 61 Cu 39 , fully amorphous nanocomposite with controlled nanoscale periodicity ( Λ , from 400 down to 5 nm), local chemistry, and glass–glass interfaces, while focusing in‐depth on the SB nucleation/propagation processes. The nanolaminates enable a fine control of the mechanical properties, and an onset of crack formation/percolation (>1.9 and 3.3%, respectively) far above the monolithic counterparts. Moreover, we show that SB propagation induces large chemical intermixing, enabling a brittle‐to‐ductile transition when Λ  ≤ 50 nm, reaching remarkably large plastic deformation of 16% in compression and yield strength ≈2 GPa. Overall, the nanoengineered control of local heterogeneities leads to ultimate and tunable mechanical properties opening up a new approach for strong and ductile materials.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001226546100001 Publication Date 2024-05-20
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2688-4062 ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:205798 Serial 9176
Permanent link to this record
 

 
Author Chai, Z.-N.; Wang, X.-C.; Yusupov, M.; Zhang, Y.-T.
Title Unveiling the interaction mechanisms of cold atmospheric plasma and amino acids by machine learning Type A1 Journal article
Year 2024 Publication Plasma processes and polymers Abbreviated Journal
Volume (up) Issue Pages 1-26
Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT)
Abstract Plasma medicine has attracted tremendous interest in a variety of medical conditions, ranging from wound healing to antimicrobial applications, even in cancer treatment, through the interactions of cold atmospheric plasma (CAP) and various biological tissues directly or indirectly. The underlying mechanisms of CAP treatment are still poorly understood although the oxidative effects of CAP with amino acids, peptides, and proteins have been explored experimentally. In this study, machine learning (ML) technology is introduced to efficiently unveil the interaction mechanisms of amino acids and reactive oxygen species (ROS) in seconds based on the data obtained from the reactive molecular dynamics (MD) simulations, which are performed to probe the interaction of five types of amino acids with various ROS on the timescale of hundreds of picoseconds but with the huge computational load of several days. The oxidative reactions typically start with H-abstraction, and the details of the breaking and formation of chemical bonds are revealed; the modification types, such as nitrosylation, hydroxylation, and carbonylation, can be observed. The dose effects of ROS are also investigated by varying the number of ROS in the simulation box, indicating agreement with the experimental observation. To overcome the limits of timescales and the size of molecular systems in reactive MD simulations, a deep neural network (DNN) with five hidden layers is constructed according to the reaction data and employed to predict the type of oxidative modification and the probability of occurrence only in seconds as the dose of ROS varies. The well-trained DNN can effectively and accurately predict the oxidative processes and productions, which greatly improves the computational efficiency by almost ten orders of magnitude compared with the reactive MD simulation. This study shows the great potential of ML technology to efficiently unveil the underpinning mechanisms in plasma medicine based on the data from reactive MD simulations or experimental measurements. In this study, since reactive molecular dynamics simulation can currently only describe interactions between a few hundred atoms in a few hundred picoseconds, deep neural networks (DNN) are introduced to enhance the simulation results by predicting more data efficiently. image
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001202061200001 Publication Date 2024-04-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1612-8850 ISBN Additional Links UA library record; WoS full record
Impact Factor 3.5 Times cited Open Access
Notes Approved Most recent IF: 3.5; 2024 IF: 2.846
Call Number UA @ admin @ c:irua:205512 Serial 9181
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Author O'Modhrain, C.; Trenchev, G.; Gorbanev, Y.; Bogaerts, A.
Title Upscaling plasma-based CO₂ conversion : case study of a multi-reactor gliding arc plasmatron Type A1 Journal article
Year 2024 Publication ACS Engineering Au Abbreviated Journal
Volume (up) Issue Pages
Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT)
Abstract Atmospheric pressure plasmas have shifted in recent years from being a burgeoning research field in the academic setting to an actively investigated technology in the chemical, oil, and environmental industries. This is largely driven by the climate change mitigation efforts, as well as the evident pathways of value creation by converting greenhouse gases (such as CO2) into useful chemical feedstock. Currently, most high technology readiness level (TRL) plasma-based technologies are based on volumetric and power-based scaling of thermal plasma systems, which results in large capital investment and regular maintenance costs. This work investigates bringing a quasi-thermal (so-called “warm”) plasma setup, namely, a gliding arc plasmatron, from a lab-scale to a pilot-scale capacity with an increase in throughput capacity by a factor of 10. The method of scaling is the parallelization of plasmatron reactors within a single housing, with the aim of maintaining a warm plasma regime while simultaneously improving build cost and efficiency (compared to separate reactors operating in parallel). Special attention is also given to the safety and control features implemented in the setup, a key component required for integration into industrial systems. The performance of the multi-reactor gliding arc plasmatron (MRGAP) reactor is investigated, focusing on the influence of flow rate and the number of active reactors. The location of active reactors was deemed to have a negligible effect on the monitored metrics of conversion, energy efficiency, and energy cost. The optimum operating conditions were found to be with the most active reactors (five) at the highest investigated flow rate (80 L/min). Analysis of results suggests that an optimum conversion (9%) and plug power-based energy efficiency (19%) can be maintained at a specific energy input (SEI) around 5.3 kJ/L (or 1 eV/molecule). The concept of parallelization of plasmatron reactors within a singular housing was demonstrated to be a viable method for scaling up from a lab-scale to a prototype-scale device, with performance analysis suggesting that increasing the power (through adding more reactor channels) and total flow rate, while maintaining an SEI around 5.3 or 4.2 kJ/L, i.e., 1.3 or 1 eV/molecule (based on plug power and plasma-deposited power, respectively), can result in increased conversion rate without sacrificing absolute conversion or energy efficiency.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001166625200001 Publication Date 2024-02-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:204749 Serial 9182
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Author Fabri, C.; Tsagris, M.; Moretti, M.; Van Passel, S.
Title Adaptation to climate change : the irrigation technology mix of Italian farmers Type A1 Journal article
Year 2023 Publication Applied economic perspectives and policy Abbreviated Journal
Volume (up) Issue Pages 1-22
Keywords A1 Journal article; Economics; Engineering Management (ENM)
Abstract Farmers should increasingly adopt more water‐efficient irrigation technologies—such as drip irrigation—as a result of climate warming and aggravating water scarcity. We analyze how Italian farmers adapt to climate change by changing their irrigation technology mix. We apply a two‐stage econometric model to data from 5876 Italian farms. We find that farmers' initial reaction to increasing temperatures is reducing their surface‐irrigated fractions. When temperatures increase further, farmers switch toward more sprinkler irrigation. Our results show that farmers are not autonomously moving to drip irrigation in response to climate change, suggesting that government incentives are needed to encourage this transition.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001125360800001 Publication Date 2023-12-16
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2040-5790 ISBN Additional Links UA library record; WoS full record
Impact Factor 5.8 Times cited Open Access
Notes Approved Most recent IF: 5.8; 2023 IF: 1.361
Call Number UA @ admin @ c:irua:201688 Serial 9184
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Author Teleshkan, E.; Van Schoubroeck, S.; Spiller, M.; Van Passel, S.
Title Assessing policy impacts on nutrient circularity : a comprehensive review Type A1 Journal article
Year 2024 Publication Nutrient cycling in agroecosystems Abbreviated Journal
Volume (up) Issue Pages 1-15
Keywords A1 Journal article; Economics; Engineering sciences. Technology; Engineering Management (ENM)
Abstract Nutrient circularity is an emerging concept that seeks to address the environmental problems and nutrient losses caused by agriculture and food consumption. The implementation of circular nutrient technologies and practices (CNTPs), that recover, reuse, and recycle nutrients from agricultural and urban waste is an important policy objective. Yet, which policies govern the adoption of CNTPs is not well defined. This study presents the first systematic review of impact evaluations of policy measures that aim to improve nutrient circularity regulating components of the biological cycle of the circular economy, particularly focusing on bioaccessible nutrients. The key CNTPs that were subject to existing impact evaluations were identified. CNTPs were categorized into nutrient circularity themes, with manure management emerging as a prominent focus. The reviewed studies implemented several methods to assess the impacts of policies on various dependent variables, associated with nutrient circularity. Economic simulation models and linear programming were the most prevalent methods for impact evaluation. Policy measures were labeled as either enabling or not-enabling nutrient circularity based on whether they sufficiently promoted nutrient circularity through facilitating the adoption of CNTPs, and controlling for soil, water and air health, preventing its contamination. It is concluded that incentive policies, harmonizing market support, tax incentives, and technological advancements, as well as coherence of local, national and cross-country legislation prove indispensable in steering the economic feasibility and sustainability of CNTPs, offering a promising avenue for progress and a transformative shift towards nutrient circularity.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001175764500001 Publication Date 2024-02-29
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1385-1314; 1573-0867 ISBN Additional Links UA library record; WoS full record
Impact Factor 3.1 Times cited Open Access
Notes Approved Most recent IF: 3.1; 2024 IF: 1.843
Call Number UA @ admin @ c:irua:204250 Serial 9185
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Author Verbruggen, S.; Van Acker, M.; Furlan, C.; Mercelis, S.; Durt, A.
Title ATLANTES : the mATeriaL spAtial dimeNsion of wasTE flowS: visualising waste streams in the Province of Antwerp Type Minutes and reports
Year 2023 Publication Abbreviated Journal
Volume (up) Issue Pages
Keywords Minutes and reports; Economics; Engineering sciences. Technology; Internet Data Lab (IDLab); Research Group for Urban Development; Henry van de Velde
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:199837 Serial 9187
Permanent link to this record
 

 
Author Van Hoecke, L.
Title CFD-Assisted design of fluidized reactors for H2 release from LOHC Type Doctoral thesis
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages XXXIII, 181 p.
Keywords Doctoral thesis; Engineering sciences. Technology
Abstract Hydrogen (H2) is expected to become a key molecule in the transition towards a society running on renewable energy. It can be used to store excess renewable energy at peak production moments and release this energy at a later stage when renewable energy production is less. However, storing H2 is challenging due to the low density of this gas. As a solution, Liquid Organic Hydrogen Carriers or LOHC molecules have been proposed in the passed to increase volumetric energy density of H2. LOHC are a class of molecules that have storage sites available, to which the H2 gas can be chemically bounded. The LOHC molecule under investigation was dibenzyltoluene (DBT), which is an oil like liquid, that is easy to transport and poses little fire or explosion risks. To release the H2 from the DBT carrier, via a so-called dehydrogenation reaction, efficient mass and heat transfer is required during the process, since a large volume increase is expected from H2 release and the reaction is endothermic, i.e., a self – cooling process that takes place at temperatures around 300 C. The heat has to be supplied specifically to the active sites of catalyst particles that are present inside the reactor and which enable the dehydrogenation to proceed. For heat transfer limited processes fluidized bed reactors are often used, which is a type of reactor where the particle phase is being agitated by the fluid flow. The research proposed in this work, was to explore via computational fluid dynamics (CFD) simulations the possibilities and challenges of using fluidized bed reactors for the dehydrogenation of LOHC. The model selection required for CFD simulations of a three-phase system was investigated in this work, with a main emphasis on the drag model selection. The CFD modelling study was focused on the use of swirling fluidized bed reactors, since it was hypothesised that the swirling effect could also aid in increased removal of the gas phase from the reaction medium to increase the efficiency of the process. Ultimately, it was shown that the main challenges in the design of fluidized bed reactors will be to create uniform particle distribution inside the reactor. A new design for a dehydrogenation reactor is proposed based on the insights gained in this thesis.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2024-06-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:205645 Serial 9192
Permanent link to this record
 

 
Author Lembrechts, J.; Clavel, J.; Lenoir, J.; Haider, S.; McDougall, K.; Nunez, M.; Alexander, J.; Barros, A.; Milbau, A.; Seipel, T.; Verbruggen, E.; Nijs, I.
Title Dataset: Roadside disturbance promotes plant communities with arbuscular mycorrhizal associations in mountain regions worldwide Type Dataset
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages
Keywords Dataset; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Aim: We aimed to assess the impact of road disturbances on the dominant mycorrhizal types in ecosystems at the global level and how this mechanism can potentially lead to lasting plant community changes. Location: Globally distributed mountain regions Time Period: 2007-2018 Taxa studied: Plants (linked to their associated mycorrhizal fungi) Methods: We used a database of coordinated plant community surveys following mountain roads from 894 plots in 11 mountain regions across the globe in combination with an existing database of mycorrhizal-plant associations in order to approximate the relative abundance of mycorrhizal types in natural and disturbed environments. Results: Our findings show that roadside disturbance promotes the cover of plants associated with arbuscular mycorrhizal (AM) fungi. This effect is especially strong in colder mountain environments and in mountain regions where plant communities are dominated by ectomycorrhizal (EcM) or ericoid-mycorrhizal (ErM) associations. Furthermore, non-native plant species, which we confirmed to be mostly AM plants, are more successful in environments dominated by AM associations. Main Conclusions: These biogeographical patterns suggest that changes in mycorrhizal types could be a crucial factor in the worldwide impact of anthropogenic disturbances on mountain ecosystems. Indeed, roadsides foster AM-dominated systems, where AM-fungi might aid AM-associated plant species while potentially reducing the biotic resistance against invasive non-native species, often also associated with AM networks. Restoration efforts in mountain ecosystems will have to contend with changes in the fundamental make-up of EcM- and ErM plant communities induced by roadside disturbance.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:206132 Serial 9198
Permanent link to this record
 

 
Author Chekol Zewdie, M.; Moretti, M.; Tenessa, D.B.; Van Passel, S.
Title Farmers' preferences and willingness to pay for improved irrigation water supply program : a discrete choice experiment Type A1 Journal article
Year 2023 Publication Environment, development and sustainability Abbreviated Journal
Volume (up) Issue Pages 1-24
Keywords A1 Journal article; Engineering sciences. Technology; Engineering Management (ENM)
Abstract This study examines smallholder farmers' preferences and willingness to pay for an improved irrigation water supply program in northwest Ethiopia. We employed a discrete choice experiment with five attributes and three levels. Data were collected from randomly selected sample households of both irrigation users and non-users. A total of 379 respondents participated, and a mixed logit model was used to analyze the household-level survey data. The result indicates that to deviate from the business-as-usual scenario, smallholder farmers are willing to pay between 3,228 and 8,327 Ethiopian Birr per hectare of irrigated land. Furthermore, the results showed a strong public preference for access to produce cash crops, followed by irrigation water availability in the dry season, and adequate access to improved farm inputs. The results also provide useful information for policymakers and suggested possibilities for generating finance from farmers to cover the operation and maintenance costs of irrigation schemes. Also, this study result reveals that irrigation development and expansion must be integrated into a comprehensive support package that combines irrigation water with access to improved farm inputs and access to produce cash crops on farmers' farm plots.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001048896000004 Publication Date 2023-08-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1387-585x; 1573-2975 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.9 Times cited Open Access
Notes Approved Most recent IF: 4.9; 2023 IF: NA
Call Number UA @ admin @ c:irua:198283 Serial 9204
Permanent link to this record
 

 
Author Van Oijstaeijen, W.
Title Green infrastructure and local implementation : (green) bridging the gap between research and practice Type Administrative Services
Year 2023 Publication Abbreviated Journal
Volume (up) Issue Pages xvii, 194 p.
Keywords Administrative Services; Doctoral thesis; Engineering sciences. Technology; Engineering Management (ENM)
Abstract Climate change is an ever-increasing threat to our planet, with the urbanisation of previously open spaces exacerbating the issue. The loss of open space leads to a decrease in ecosystem services, which negatively impacts the liveability in urbanised environments, and beyond. The incorporation of green infrastructure (GI) into the built environment is acknowledged as an effective and multi-functional measure to make our living environment resilient and future-proof. Notwithstanding that the local level is essential for effective GI implementation, research into local decision making is very limited. This thesis therefore aims to address two significant gaps in the implementation of GI. The first objective is to bridge the science-policy gap by integrating scientific knowledge on ES and GI into local decision-making processes. In this context, the policy dimension within this thesis involves the process of translating overarching policy objectives into practical actions within local decision-making practices, abstracting from the intricacies of higher-level policymaking itself. The second objective focuses on the people-policy gap, which involves understanding stakeholders' perspectives and priorities regarding GI and its associated ecosystem services. Through stated preference valuation techniques (discrete choice experiments and a best-worst scaling experiment), multi-stakeholder GI perceptions are gathered. Finally, a novel tool to GI valuation is developed, acknowledging the different stakeholder views and building on the insights of collaborative tool development and design. By gaining insights into the demand, prioritisation, and provision of GI from the two most important stakeholder groups at the local level (residents and local decision-makers), this research aims to foster effective communication and alignment between public preferences and policy implementation. Ultimately, addressing these gaps will contribute to more informed planning and decision-making practices related to green infrastructure. The overall goal of this thesis is to enhance the uptake of GI knowledge in the local decision-making context, proposing pathways to facilitate and optimise investments in public GI.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 978-90-5728-814-2 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:199925 Serial 9206
Permanent link to this record
 

 
Author De Keyzer, M.; Soens, T.; Verbruggen, C.
Title Mens en natuur : een geschiedenis Type MA2 Book as author
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages 313 p.
Keywords MA2 Book as author; History; Centre for Urban History
Abstract Onze relatie met de natuur om ons heen is, op zijn zachtst gezegd, ingewikkeld. Mensen gingen niet plots een bedreiging vormen voor het leven op aarde nadat ze er eeuwenlang mee in harmonie hadden geleefd. Verschillende ideeën over de omgang met de natuurlijke omgeving – sommige duurzaam, andere ronduit desastreus – hebben altijd naast elkaar bestaan. We waren er ons al verrassend vroeg van bewust dat ons handelen een nefaste impact kon hebben op de natuur. Maar die bezwaren werden geregeld aan de kant geschoven. Deze inleiding tot de milieugeschiedenis helpt de lezer te begrijpen hoe onze hedendaagse problematische omgang met de natuur en ons milieu tot stand is gekomen. Het is een introductie tot het recente onderzoek naar de relatie tussen mens en natuur doorheen de eeuwen, in de Lage Landen en ver daarbuiten.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 978-94-014-0395-5 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:205213 Serial 9212
Permanent link to this record
 

 
Author Clavel, J.
Title Plant-mycorrhizal interactions and their role in plant invasions in mountains Type Doctoral thesis
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages 182 p.
Keywords Doctoral thesis; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Non-native species invasions are one of the most impactful drivers of biodiversity and ecosystem services loss worldwide. One aspect of plant species invasion, which is only recently starting to be recognized as a determinant of invasion success, is the symbiosis between plant and mycorrhizal fungi. Here, I focus on anthropogenic disturbance in mountain ecosystems and its impact on plant communities and mycorrhizal fungi to answer how these communities are impacted by disturbance and whether non-native plants can benefit to establish and spread. To this end I used a combination of different approaches: 1) repeated surveys of plants and arbuscular mycorrhizal fungi along disturbed roadsides in the mountains of Norway, 2) combining a global dataset of native and non-native plants along mountain roads with a database associating plants with their mycorrhizal types, and 3) an in-situ experiment measuring non-native plant success and changes in fungal community following different types of disturbances. Through these methods, I could assess the effects of anthropogenic disturbance on mycorrhizal symbiosis and non-native plant species at multiple scales and resolutions. We found that road disturbance has a globally consistent effect on mycorrhizal types in mountain systems, as plants associated with arbuscular mycorrhizal (AM) fungi were more abundant following disturbance. Conversely, vegetation associated with either ectomycorrhizal (EcM) or ericoid mycorrhizal (ErM) fungi was less abundant in disturbed sites. In the regional study, AM fungi were most abundant and diverse in the roots of plant communities affected by road disturbance. Non-native plants were also restricted to these disturbed sites. The experimental results showed that physical disturbance and nutrient addition have negative effects on EcM fungi and positive effects on fungal pathogens, and facilitate non-native plant success. Our results show that anthropogenic disturbance does have an effect on mycorrhizal fungi that in turn impacts the distribution of plant species in disturbed mountain systems. The resulting shift in mycorrhizal fungi benefiting AM fungi and AM plant species could have implications for non-native plant invasions. Indeed, we know that non-native plants predominantly form associations with AM fungi. Therefore, anthropogenic disturbance can facilitate non-native plant success through disruption of the native fungal communities, and especially so in high elevation and cold climate regions which are naturally less dominated by AM plants. I believe this highlights the importance of mycorrhizal symbiosis in understanding plant invasions and emphasizes the importance of monitoring sources of anthropogenic disturbance in mountains to prevent future establishment of non-native plants.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:204154 Serial 9219
Permanent link to this record
 

 
Author Clavel, J.; Lembrechts, J.; Lenoir, J.; Haider, S.; McDougall, K.; Nunez, M.A.; Alexander, J.; Barros, A.; Milbau, A.; Seipel, T.; Pauchard, A.; Fuentes-Lillo, E.; Backes, A.R.; Dar, P.; Reshi, Z.A.; Aleksanyan, A.; Zong, S.; Sierra, J.R.A.; Aschero, V.; Verbruggen, E.; Nijs, I.
Title Roadside disturbance promotes plant communities with arbuscular mycorrhizal associations in mountain regions worldwide Type A1 Journal article
Year 2024 Publication Ecography Abbreviated Journal
Volume (up) Issue Pages e07051-14
Keywords A1 Journal article; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract We assessed the impact of road disturbances on the dominant mycorrhizal types in ecosystems at the global level and how this mechanism can potentially lead to lasting plant community changes. We used a database of coordinated plant community surveys following mountain roads from 894 plots in 11 mountain regions across the globe in combination with an existing database of mycorrhizal-plant associations in order to approximate the relative abundance of mycorrhizal types in natural and disturbed environments. Our findings show that roadside disturbance promotes the cover of plants associated with arbuscular mycorrhizal (AM) fungi. This effect is especially strong in colder mountain environments and in mountain regions where plant communities are dominated by ectomycorrhizal (EcM) or ericoid-mycorrhizal (ErM) associations. Furthermore, non-native plant species, which we confirmed to be mostly AM plants, are more successful in environments dominated by AM associations. These biogeographical patterns suggest that changes in mycorrhizal types could be a crucial factor in the worldwide impact of anthropogenic disturbances on mountain ecosystems. Indeed, roadsides foster AM-dominated systems, where AM-fungi might aid AM-associated plant species while potentially reducing the biotic resistance against invasive non-native species, often also associated with AM networks. Restoration efforts in mountain ecosystems will have to contend with changes in the fundamental make-up of EcM- and ErM plant communities induced by roadside disturbance.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001198654900001 Publication Date 2024-04-09
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0906-7590 ISBN Additional Links UA library record; WoS full record
Impact Factor 5.9 Times cited Open Access
Notes Approved Most recent IF: 5.9; 2024 IF: 4.902
Call Number UA @ admin @ c:irua:205605 Serial 9224
Permanent link to this record
 

 
Author Vervoort, P.; Grymonprez, H.; Bouckaert, N.; Derijcke, D.; De Wael, W.
Title Ruimte en gezondheidsongelijkheid aanpakken : een kwestie van sociale rechtvaardigheid Type H2 Book chapter
Year 2023 Publication Abbreviated Journal
Volume (up) Issue Pages
Keywords H2 Book chapter; Sociology; Law; Centre for Research on Environmental and Social Change
Abstract De bijdrage gaat dieper in op de relatie tussen ruimte en gezondheidsongelijkheid, bespreekt gezondheidsongelijkheid vanuit een rechtenperspectief en illustreert een aantal praktijken waarin de aandacht voor ruimte en gezondheidsongelijkheid samenkomen.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 978-2-509-04324-5 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:200534 Serial 9225
Permanent link to this record
 

 
Author Labey, E.; Fonteyn, F.; Wilmot, A.; El Amouri, S.; Gjurova, A.; De Cock, W.; De Wael, F.
Title Shaping utopia through law: how the law does (not) provide an answer to societal challenges Type ME2 Book as editor or co-editor
Year 2023 Publication Abbreviated Journal
Volume (up) Issue Pages 210 p.
Keywords ME2 Book as editor or co-editor; Law; Government and Law
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 978-94-000-1654-5 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:198938 Serial 9227
Permanent link to this record
 

 
Author Le Noir de Carlan, C.; Kaarlejarvi, E.; De Tender, C.; Heinecke, T.; Eskelinen, A.; Verbruggen, E.
Title Shifts in mycorrhizal types of fungi and plants in response to fertilisation, warming and herbivory in a tundra grassland Type A1 Journal article
Year 2024 Publication New phytologist Abbreviated Journal
Volume (up) Issue Pages
Keywords A1 Journal article; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Climate warming is severely affecting high-latitude regions. In the Arctic tundra, it may lead to enhanced soil nutrient availability and interact with simultaneous changes in grazing pressure. It is presently unknown how these concurrently occurring global change drivers affect the root-associated fungal communities, particularly mycorrhizal fungi, and whether changes coincide with shifts in plant mycorrhizal types. We investigated changes in root-associated fungal communities and mycorrhizal types of the plant community in a 10-yr factorial experiment with warming, fertilisation and grazing exclusion in a Finnish tundra grassland. The strongest determinant of the root-associated fungal community was fertilisation, which consistently increased potential plant pathogen abundance and had contrasting effects on the different mycorrhizal fungal types, contingent on other treatments. Plant mycorrhizal types went through pronounced shifts, with warming favouring ecto- and ericoid mycorrhiza but not under fertilisation and grazing exclusion. Combination of all treatments resulted in dominance by arbuscular mycorrhizal plants. However, shifts in plant mycorrhizal types vs fungi were mostly but not always aligned in their magnitude and direction. Our results show that our ability to predict shifts in symbiotic and antagonistic fungal communities depend on simultaneous consideration of multiple global change factors that jointly alter plant and fungal communities.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001220955000001 Publication Date 2024-05-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0028-646x ISBN Additional Links UA library record; WoS full record
Impact Factor 9.4 Times cited Open Access
Notes Approved Most recent IF: 9.4; 2024 IF: 7.33
Call Number UA @ admin @ c:irua:206016 Serial 9228
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Author Kummamuru, N.B.; Ciocarlan, R.-G.; Houlleberghs, M.; Martens, J.; Breynaert, E.; Verbruggen, S.W.; Cool, P.; Perreault, P.
Title Surface modification of mesostructured cellular foam to enhance hydrogen storage in binary THF/H₂ clathrate hydrate Type A1 Journal article
Year 2024 Publication Sustainable energy & fuels Abbreviated Journal
Volume (up) Issue Pages 1-15
Keywords A1 Journal article; Engineering sciences. Technology; Laboratory of adsorption and catalysis (LADCA)
Abstract This study introduces solid-state tuning of a mesostructured cellular foam (MCF) to enhance hydrogen (H-2) storage in clathrate hydrates. Grafting of promoter-like molecules (e.g., tetrahydrofuran) at the internal surface of the MCF resulted in a substantial improvement in the kinetics of formation of binary H-2-THF clathrate hydrate. Identification of the confined hydrate as sII clathrate hydrate and enclathration of H-2 in its small cages was performed using XRD and high-pressure H-1 NMR spectroscopy respectively. Experimental findings show that modified MCF materials exhibit a similar to 1.3 times higher H-2 storage capacity as compared to non-modified MCF under the same conditions (7 MPa, 265 K, 100% pore volume saturation with a 5.56 mol% THF solution). The enhancement in H-2 storage is attributed to the hydrophobicity originating from grafting organic molecules onto pristine MCF, thereby influencing water interactions and fostering an environment conducive to H-2 enclathration. Gas uptake curves indicate an optimal tuning point for higher H-2 storage, favoring a lower density of carbon per nm(2). Furthermore, a direct correlation emerges between higher driving forces and increased H-2 storage capacity, culminating at 0.52 wt% (46.77 mmoles of H-2 per mole of H2O and 39.78% water-to-hydrate conversions) at 262 K for the modified MCF material with fewer carbons per nm(2). Notably, the substantial H-2 storage capacity achieved without energy-intensive processes underscores solid-state tuning's potential for H-2 storage in the synthesized hydrates. This study evaluated two distinct kinetic models to describe hydrate growth in MCF. The multistage kinetic model showed better predictive capabilities for experimental data and maintained a low average absolute deviation. This research provides valuable insights into augmenting H-2 storage capabilities and holds promising implications for future advancements.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001208396000001 Publication Date 2024-04-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:205764 Serial 9232
Permanent link to this record
 

 
Author Ramirez-Rojas, I.
Title Underground connections : the interplay between tropical rainforest trees and soil microbial communities Type Doctoral thesis
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages 205 p.
Keywords Doctoral thesis; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Tropical rainforests host an exceptional biodiversity and play a fundamental role in the regulation of global climatic cycles. Soil fungi and bacteria are key players in the transformation and processing of nutrients in terrestrial ecosystems while having an essential role as tree mutualists or antagonists. Still, there are gaps in our understanding of the main variables driving soil microbes on these forests and it is unclear how future climate change scenarios may impact soil microbes and further affect the ecosystem. In this thesis, we first explored the drivers of the microbial community composition in two pristine forests in French Guiana by using amplicon DNA sequencing. The neighboring tree species were found to be a crucial factor influencing the fungal and bacterial community composition at our sites regardless of the season. Additionally, within the environmental factors explored, soil moisture, phosphorus (P) and nitrogen (N) availability were consistently the main soil properties controlling the composition of soil microbial communities. Secondly, as increased nutrient deposition due to anthropogenic activities are expected to affect tropical forests ecosystems N and P availability, a factorial N and P nutrient addition experiment in the same sites was used to assess the effects of changes in the soil nutrient stoichiometry on the soil microbial communities. These results showed that after 3 years of nutrient additions, the bacterial and fungal community composition was affected by both the N and P additions. Besides, the fungal community composition had a stronger response to the nutrient addition, especially when P was added. Moreover, when the nutrient addition effect was assessed in bacteria and fungi with different life strategies, we found different nutrient optima between them. Furthermore, to study the effect of the connection to an existing mycorrhizal mycelium on tree seedlings, I established a mycelium exclusion experiment. Interestingly, we could not detect an effect of the mycorrhizal mycelium exclusion on the seedling N uptake, performance, or fungal community composition in roots after one year. All together this work provides a deeper understanding of the factors influencing the soil microbial communities on these lowland tropical forests, demonstrating that the tree community composition exerts a higher influence on the soil microbial community composition than previously expected. Moreover, our results show that the fungal and bacterial community composition and its relationship with trees in the vicinity is highly dependent on the ecosystem nutrient availability.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:204907 Serial 9237
Permanent link to this record
 

 
Author Gebremariam, Y.A.; Dessein, J.; Wondimagegnhu, B.A.; Breusers, M.; Lenaerts, L.; Adgo, E.; Van Passel, S.; Minale, A.S.; Nyssen, J.
Title Undoing the development army : a paradigm shift from transfer of technology to agricultural innovation system in Ethiopian extension Type A1 Journal article
Year 2023 Publication Environment, development and sustainability Abbreviated Journal
Volume (up) Issue Pages 1-27
Keywords A1 Journal article; Engineering sciences. Technology; Engineering Management (ENM)
Abstract Appropriate use of agricultural technologies and diversifying the farming activities is critical to addressing food security problems in Africa, including Ethiopia. The country is experimenting with the new Agricultural Innovation System (AIS) approach alongside the well-established Transfer of Technology (ToT) approach. This paper analyzes the gaps between policy discourses (as reflected in policy documents and strategic orientation documents) and extension practices (as reflected in the daily exchanges between farmers and the frontline staff of the Ethiopian extension system). It provides insights into the challenges faced and emphasizes the need for better coordination between policy formulation and implementation to enhance extension services. Policymakers, practitioners, and researchers can benefit from the valuable perspectives the findings offer. The study contributes to understanding the relationship between policy discourses and extension practices, and its implications can inform policy design and implementation in similar contexts. A qualitative research approach was deployed to analyze policy discourse and practice. Data were collected in Fogera, a district in Northwest Ethiopia, between August 2018 and February 2019. The data for the paper were obtained from 23 Focus Group Discussions conducted with men and women. 13 Informant Interviews (KIIs) were also carried out with personnel at different levels of government agricultural services and departments. Transcripts of recordings of the Focus Group Discussions (FGDs) and Key Informant Interviews (KIIs) were analyzed using a deductive approach. The study focuses on rice crops in the Fogera district, which are crucial for food security and reducing poverty. Although the geographic area is limited, the results can be used to improve the extension system in other areas facing similar challenges. Specifically, the study suggests switching from the traditional transfer of technology approach to the agricultural innovation system approach. Furthermore, the study's techniques, such as qualitative interviews, may have limitations and not fully capture the intricacies of policy and extension practices. The findings demonstrate that, although the policy documents strongly adhere to agricultural innovation system principles, top-down transfer of technology approaches continues to dominate in practice. Moreover, we have found potential discrepancies between the training content delivered and the specific needs of smallholder farmers. Practically, prescriptive systems are still used because agricultural innovation system approaches are not well understood by the Extension Agents. To realize a genuine agricultural innovation system, Ethiopia's extension apparatus should move forward with building committed and robust relationships between farmers, extension agents, researchers, private sectors, and non-governmental organizations. To this end, more research, enhanced training, and improved institutions are needed on what genuine agricultural innovation system could look like at the grass-roots level. This also includes understanding the roles that different actors within Ethiopia's development army should assume how a multi-actor policy dialogue can be organized.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001126500500006 Publication Date 2023-12-19
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1387-585x; 1573-2975 ISBN Additional Links UA library record; WoS full record
Impact Factor 4.9 Times cited Open Access
Notes Approved Most recent IF: 4.9; 2023 IF: NA
Call Number UA @ admin @ c:irua:202804 Serial 9238
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Author Gios, E.; Verbruggen, E.; Audet, J.; Burns, R.; Butterbach-Bahl, K.; Espenberg, M.; Fritz, C.; Glatzel, S.; Jurasinski, G.; Larmola, T.; Mander, U.; Nielsen, C.; Rodriguez, A.F.; Scheer, C.; Zak, D.; Silvennoinen, H.M.
Title Unraveling microbial processes involved in carbon and nitrogen cycling and greenhouse gas emissions in rewetted peatlands by molecular biology Type A1 Journal article
Year 2024 Publication Biogeochemistry Abbreviated Journal
Volume (up) Issue Pages
Keywords A1 Journal article; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Restoration of drained peatlands through rewetting has recently emerged as a prevailing strategy to mitigate excessive greenhouse gas emissions and re-establish the vital carbon sequestration capacity of peatlands. Rewetting can help to restore vegetation communities and biodiversity, while still allowing for extensive agricultural management such as paludiculture. Belowground processes governing carbon fluxes and greenhouse gas dynamics are mediated by a complex network of microbial communities and processes. Our understanding of this complexity and its multi-factorial controls in rewetted peatlands is limited. Here, we summarize the research regarding the role of soil microbial communities and functions in driving carbon and nutrient cycling in rewetted peatlands including the use of molecular biology techniques in understanding biogeochemical processes linked to greenhouse gas fluxes. We emphasize that rapidly advancing molecular biology approaches, such as high-throughput sequencing, are powerful tools helping to elucidate the dynamics of key biogeochemical processes when combined with isotope tracing and greenhouse gas measuring techniques. Insights gained from the gathered studies can help inform efficient monitoring practices for rewetted peatlands and the development of climate-smart restoration and management strategies.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001185747700001 Publication Date 2024-03-16
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0168-2563; 1573-515x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4 Times cited Open Access
Notes Approved Most recent IF: 4; 2024 IF: 3.428
Call Number UA @ admin @ c:irua:204875 Serial 9239
Permanent link to this record
 

 
Author Li, L.
Title Untangling microbial community assembly in rainforest and grassland soils under increasing precipitation persistence Type Doctoral thesis
Year 2023 Publication Abbreviated Journal
Volume (up) Issue Pages 179 p.
Keywords Doctoral thesis; Integrated Molecular Plant Physiology Research (IMPRES); Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Climate change is causing alterations in precipitation patterns, leading to adverse ecological consequences in many ecosystems. Recently, an increasingly persistent weather pattern has emerged, characterized by lengthening the duration of alternating dry and wet periods, which is more complex than exclusively drought or increasing precipitation. It is currently unclear how soil microbial communities respond to these new regimes in relation to their interactions with plants, especially in precipitation-sensitive ecosystems, such as tropical rainforests and grasslands. In this thesis, we explored responses of soil bacterial and fungal communities to increasing weather persistence in rainforests and grasslands, using high throughput sequencing technology. We firstly investigated the resistance and resilience of microbial communities to prolonged drought in a mature seasonal tropical rainforest which experiences unusually intensive dry seasons in the current century. Through excluding rainfall during and after the dry season, a simulated prolongation of the dry season by five months was compared to the control. Our results indicate that as rain exclusion progressed, the microbial communities increasingly diverged from the control, indicating a moderate resistance to prolonged drought. However, when the drought ceased, the composition and co-occurrence patterns of soil microbial communities immediately recovered to that in the control, implying a high resilience. To further investigate the ecological roles of soil microbial communities in response to increasing weather persistence, we set up grassland mesocosm experiments. In these experiments, precipitation frequency was adjusted along a series, ranging from 1 to 60 consecutive days alternating of dry and wet periods, while keeping the total precipitation constant. Our results show that microbial community assembly tended to be more stochastic processes at intermediate persistence of dry and wet alternations while more deterministic processes dominated at low and high persistence within 120 days regime exposure. Moreover, more persistent precipitation reduced the fungal diversity and network connectivity but barely impacted that of bacterial communities. The prior experiences of persistent weather events for one year caused legacy effects. The soil microbial legacy induced by soil microbial communities subjected to prior persistent weather events was more enduring in subsequent fungal communities than bacterial communities, likely due to slower growth of fungi compared to bacteria. However, a minor effect of soil microbial legacy  was observed on plant performance. In addition, we kept the grassland mesocosm experiment for two growing seasons. The effects of precipitation persistence on soil microbial communities increased in the second year. The dissimilarities of microbial communities between the first and second year were less with more persistent precipitation, potentially resulting in more vulnerable microbial communities, due to some taxa disappearing and a reduction in functional redundancy under more persistent weather. To conclude, our findings provide a comprehensive theoretical understanding of soil microbial communities in response to the current and future climate change, drawing from both natural and experimental systems. It helps in predicting and managing the impacts of future climate change on ecosystems mediated by microbial communities. Additionally, the findings of microbe-mediated legacy effects on grassland ecosystems can provide practical guidance for their application in agriculture, specifically for using an inoculum to mitigate the impacts of climate change.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:198498 Serial 9240
Permanent link to this record
 

 
Author Montiel, F.N.
Title Voltage against illicit drug trafficking : capabilities of electrochemical fingerprinting to detect illicit drugs Type Doctoral thesis
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages 256 p.
Keywords Doctoral thesis; Pharmacology. Therapy; Engineering sciences. Technology; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:204707 Serial 9243
Permanent link to this record
 

 
Author Steijlen, A.; Docter, M.; Bastemeijer, J.; Topyla, M.; Moraczewska, M.; Hoekstra, T.; Parrilla, M.; De Wael, K.
Title A practical guide to build a Raspberry Pi Pico based potentiostat for educational electrochemistry and electronic instrumentation Type A1 Journal article
Year 2024 Publication Journal of chemical education Abbreviated Journal
Volume (up) Issue Pages
Keywords A1 Journal article; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab); Antwerp engineering, PhotoElectroChemistry & Sensing (A-PECS)
Abstract This manuscript presents the first practical guide to build a Raspberry Pi Pico based potentiostat for electrical and electrochemical instrumentation education. The circuit enables us to perform different types of voltammetry such as cyclic and square wave voltammetry. Voltammograms of paracetamol tablets in a neutral buffer solution were successfully recorded and compared to lab equipment. Thereafter, the effect of different scan rates and different concentrations was studied as a proof of concept. Furthermore, the experiments were expanded with measurements of other pharmaceutical tablets such as vitamin C. Over 80 nanobiology bachelor students successfully built their own potentiostat in an electronic instrumentation course. They validated their systems successfully with electrochemical experiments using paracetamol as a conventional pharmaceutical that can be performed in a classroom. The students acquired a valuable understanding of the electronic building blocks and system architecture within electrochemical instrumentation, equipping them with the requisite knowledge to effectively optimize instrumentation parameters in their future research work.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=brocade2&SrcAuth=WosAPI&KeyUT=WOS:001291 Publication Date 2024-08-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0021-9584; 1938-1328 ISBN Additional Links UA library record; WoS full record
Impact Factor 3 Times cited Open Access
Notes Approved Most recent IF: 3; 2024 IF: 1.419
Call Number UA @ admin @ c:irua:207478 Serial 9276
Permanent link to this record
 

 
Author Wang, L.; Griffin, D.K.; Romanov, M.N.; Gielis, J.
Title Comparison of two polar equations in describing the geometries of domestic pigeon (Columba livia domestica) eggs Type A1 Journal article
Year 2024 Publication Poultry science Abbreviated Journal
Volume (up) Issue Pages 104196-104199
Keywords A1 Journal article; Antwerp engineering, PhotoElectroChemistry & Sensing (A-PECS)
Abstract Two-dimensional (2D)egg-shape equa-tions are potent mathematical tools, facilitating the description of avian egg geometries in their applied mathematical modelling and poultry science implementations. In the present study, 2 distinct polar equations,namely the Carter-Morley-Jones equation (CMJE) and simplified Gielis equation(SGE), were used to fit the profile geometries of 415 domestic pigeon (Columba livia domestica) eggs based on nonlinear least squares regression methods.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2024-09-21
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0032-5791; 1525-3171 ISBN Additional Links UA library record
Impact Factor 4.4 Times cited Open Access
Notes Approved Most recent IF: 4.4; 2024 IF: 1.908
Call Number UA @ admin @ c:irua:208221 Serial 9279
Permanent link to this record
 

 
Author Schryvers, N.
Title De hoogspanningselektronenmicroscoop JEM 1250 Type H3 Book chapter
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages 54-55 T2 - Verhalenvertellers : academisch erfgoed
Keywords H3 Book chapter; Documentation and information; Engineering sciences. Technology; History; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:208055 Serial 9282
Permanent link to this record
 

 
Author Vanhooydonck, A.; Vleugels, J.; Parrilla Pons, M.; Clerx, P.; Watts, R.
Title Digital Repository : Optimizing high accuracy 8K LCD 3D-printed Hollow Microneedles: Methodology and ISO-7864:2016 Guided Evaluation for Enhanced Skin Penetration Type Dataset
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages
Keywords Dataset; Engineering sciences. Technology; Product development; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab); Antwerp engineering, PhotoElectroChemistry & Sensing (A-PECS)
Abstract This dataset contains 30 STL files of different geometries of microneedles (face angle, inner diameter, outer diameter, wall thickness) which are 3D printable using mSLA printers.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos https://github.com/AndresVHD/Optimizing_high_accuracy_8K-LCD_3D-printed_Hollow_Microneedles-Digital_ Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; https://github.com/AndresVHD/Optimizing_high_accuracy_8K-LCD_3D-printed_Hollow_Microneedles-Digital_Supplement/tree/main/CAD_Files/MN_Configurations
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:208524 Serial 9283
Permanent link to this record
 

 
Author Gao, C.
Title Exploring electron ptychography for low dose imaging Type Doctoral thesis
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages xii, 146 p.
Keywords Doctoral thesis; Electron microscopy for materials research (EMAT)
Abstract Transmission electron microscopy is an important technique in the exploration of materials’ structures. This is especially true since the development of electron optical aberration correctors greatly facilitated atomic resolution imaging. We are currently experiencing an ongoing revolution in electron microscopy with the widespread adoption of direct electron detectors. Scientists have reported a lot of key scientific findings facilitated by direct electron detectors. One particular research domain is electron ptychography, which holds promise for unraveling the intricate structures of highly beam-sensitive materials like bio samples and achieving super-resolution without the limitation of aperture in the condenser lens system. Nevertheless, challenges persist both in experimental setups and algorithmic processes. Issues such as the comparatively sluggish scanning speed of cameras and contrast reversals of the reconstructed phase for relatively thick specimens, disrupting phase or weak phase approximations, remain noteworthy limitations. This thesis addresses these challenges by the event-driven Timepix3 detector, presenting a viable solution to the speed bottleneck. Moreover, innovative approaches for applying electron ptychography to relatively thick samples, employing a middle focusing strategy, are proposed. This research aims to push the boundaries of electron microscopy, offering solutions to existing limitations and advancing the field towards more efficient and accurate imaging techniques.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2024-07-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:206777 Serial 9289
Permanent link to this record
 

 
Author Chinnabathini, V.C.
Title Gas phase bimetallic nanoclusters-modified TiO2 supports as efficient photo(electro)catalysts for self-cleaning surfaces and water splitting Type Doctoral thesis
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages xviii, 149 p.
Keywords Doctoral thesis; Antwerp engineering, PhotoElectroChemistry & Sensing (A-PECS)
Abstract In the context of global challenges such as climate change and environmental pollution, photocatalysis evolved as one of the promising strategies for sustainable energy conversion and pollutant degradation. In this thesis, photocatalysis using gas phase deposited bimetallic nanoclusters (BNCs) on TiO2 supports is studied in the context of self-cleaning surfaces and photoelectrochemical (PEC) water splitting applications. Thanks to their plasmonic properties, BNCs made of coinage metals can serve as efficient cocatalysts for the degradation of organic pollutants and surface contaminants under light irradiation. They also hold great promise for PEC water splitting, a promising pathway for renewable hydrogen production, which can be used in hydrogen fuel cells or for the environmentally friendly production of fuels in, for example, CO2 hydrogenation processes. The small size and high surface-to-volume ratio of plasmonic BNCs play pivotal roles in influencing the efficiency and selectivity of photocatalytic processes. BNCs have unique optical, physical, chemical, and structural properties distinctly different from their bulk and monometallic counterparts. These properties can be fine-tuned at the single particle level by their size, composition, and atomic arrangement, but also by interaction with other particles through the coverage and through interaction with the support. To design better photocatalysts it is crucial to carefully understand the BNCs’ characteristic properties, especially at the atomic level where synergies between different elements are sought. To achieve this objective, BNCs with well-defined sizes and compositions are deposited on TiO2 supports and we studied their structural properties and their influence on the photocatalytic activity. The general procedure followed in this thesis is the production and deposition of BNCs on TiO2 by the cluster beam deposition (CBD) technique, followed by structural and optical characterization to understand their tailored properties, and photocatalytic testing either for photodecomposition of organic molecules or PEC water splitting. In a first study, AuxAg1-x (x = 1, 0.9, 0.7, 0.5, 0.3, and 0) alloy BNCs with different compositions are synthesized in the gas phase and deposited from a molecular beam on TiO2 P25 supports. The photocatalytic self-cleaning activity of as-prepared samples is tested under UV and visible light towards stearic acid (SA) degradation. SA is a widely accepted model contaminant, which represents the group of organic fouling compounds that typically contaminates glass surfaces. A composition-dependent activity is observed with the Au0.3Ag0.7 nanocluster modified TiO2 exhibiting the highest photoactivity. Scanning transmission electron microscopy (STEM) measurements reveal that, for a mass loading corresponding to an equivalent of 4 atomic monolayers (MLs), the BNCs are uniformly distributed over the surface. The clusters have an average size of 3.5 ± 0.5 nm and are crystalline in nature. The atomic structure is characterized by X-ray absorption fine structure (XAFS) spectroscopy and their electronic structure by X-ray photoelectron spectroscopy (XPS). These measurements demonstrate a charge redistribution between the Ag and Au atoms when alloyed at the nanoscale. The effect of this charge redistribution is likely the stabilization of Ag against oxidation and directly affects the catalytic properties of the clusters. It is suggested that the highest photoactivity of 4 ML loaded Au0.3Ag0.7 under solar light results from a combination of four main possible contributing factors: (i) injection in TiO2 of excited carriers that are generated by the localized surface plasmon resonance (LSPR) effect of the BNCs in the visible light wavelength range which overlaps with the sun’s irradiance spectrum. (ii) a strong near-field enhancement that increases the photoabsorption by the TiO2 for photons that have enough energy to overcome the high bandgap, (iii) the optimized total metal loading of 4 ML leaves enough of the TiO2 surface accessible for light absorption, and finally (iv) an effective charge distribution between Au and Ag. This study demonstrates that CBD is an efficient approach for fabricating well-defined, tunable AuAg plasmon-based photocatalysts for self-cleaning applications, outperforming their monometallic counterparts as well as bimetallic alternatives obtained through colloidal methods. In a second study, titania nanotubes (TNTs) are modified with a series of AuxCu1-x (x = 1, 0.75, 0.5, 0.25, and 0) BNCs using the CBD technique. Based on the results of the first study, we opted again for a loading of 4 ML. TNTs are known for their high surface area, fast charge transfer, and corrosion resistance, while keeping the inherent strengths of traditional TiO2 materials. They prove to be promising photoanodes, enhancing photocurrent in PEC applications for water oxidation. In this work the TNTs are grown via anodic oxidation of a titanium metal foil. The crystalline anatase phase of the grown TNTs is confirmed by the X-ray diffraction technique (XRD), while transmission electron microscopy (TEM) provides information about the size and composition of the deposited BNCs. XAFS provides further structural information, while XPS measurements reveal charge redistribution between Au and Cu, which can aid in the enhancement of the PEC activity. Oxidation of as-prepared electrodes over the time results in structural changes with CuxO at the outer shell functioning as a protective layer, while the majority of the core is an alloy. The optical properties, studied through UV-Vis spectroscopy confirm the extended absorption range of the cluster-modified TNTs towards the visible region. The charge carrier recombination rate is derived from photoluminescence (PL) measurements. The as-prepared electrodes are tested photoelectrochemically for the generation of an anodic photocurrent using simulated sunlight. It is found that the AuxCu1-x (x = 1, 0.75, 0.5, 0.25 and 0) BNC modified TNTs show a remarkable enhancement in the anodic photocurrent relative to pristine TNTs, with Au0.25Cu0.75 exhibiting the highest photocurrent. This is due to the combination of many possible factors. Firstly, the charge redistribution between Au and Cu and increase stability of the Au0.25Cu0.75 electrode as observed in XAFS, indicates that the electronic effect in the cluster is also one of the governing factors for PEC activity. Secondly, formation of a surface CuOx layer, protects against further corrosion of the metallic AuCu BNCs cores. Third, reduced recombination of charge carriers is indicated by lower photoluminescent (PL) intensity compared to pristine TNTs and all other electrodes except pure gold, as observed in PL spectra. This implies that the generated charge carriers are efficiently separated by Au0.25Cu0.75 NCs acting as electron sinks and easily available for redox reactions. Fourth, the highest interfacial charge transfer efficiency is evidenced by the electrochemical impedance spectroscopy (EIS), leading to more efficacious charge migration and separation, facilitating the water oxidation surface reaction. A final beneficial factor is the uniform deposition of well-defined, size- and composition-controlled, ligand-free BNCs. Such BNCs provide more effective surface sites to the reaction medium, in contrast to electrodes synthesized by e.g. sol-gel methods, where (in)organic residues on metal surfaces may decrease the efficiency.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2024-07-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:206758 Serial 9293
Permanent link to this record
 

 
Author Chen, X.; Dong, X.; Zhang, C.; Zhu, M.; Ahmed, E.; Krishnamurthy, G.; Rouzbahani, R.; Pobedinskas, P.; Gauquelin, N.; Jannis, D.; Kaur, K.; Hafez, A.M.E.; Thiel, F.; Bornemann, R.; Engelhard, C.; Schoenherr, H.; Verbeeck, J.; Haenen, K.; Jiang, X.; Yang, N.
Title Interlayer affected diamond electrochemistry Type A1 Journal article
Year 2024 Publication Small methods Abbreviated Journal
Volume (up) Issue Pages 2301774
Keywords A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT)
Abstract Diamond electrochemistry is primarily influenced by quantities of sp3-carbon, surface terminations, and crystalline structure. In this work, a new dimension is introduced by investigating the effect of using substrate-interlayers for diamond growth. Boron and nitrogen co-doped nanocrystalline diamond (BNDD) films are grown on Si substrate without and with Ti and Ta as interlayers, named BNDD/Si, BNDD/Ti/Si, and BNDD/Ta/Ti/Si, respectively. After detailed characterization using microscopies, spectroscopies, electrochemical techniques, and density functional theory simulations, the relationship of composition, interfacial structure, charge transport, and electrochemical properties of the interface between diamond and metal is investigated. The BNDD/Ta/Ti/Si electrodes exhibit faster electron transfer processes than the other two diamond electrodes. The interlayer thus determines the intrinsic activity and reaction kinetics. The reduction in their barrier widths can be attributed to the formation of TaC, which facilitates carrier tunneling, and simultaneously increases the concentration of electrically active defects. As a case study, the BNDD/Ta/Ti/Si electrode is further employed to assemble a redox-electrolyte-based supercapacitor device with enhanced performance. In summary, the study not only sheds light on the intricate relationship between interlayer composition, charge transfer, and electrochemical performance but also demonstrates the potential of tailored interlayer design to unlock new capabilities in diamond-based electrochemical devices. Diamond electrochemistry is revealed to be affected by the interlayers between boron/nitrogen co-doped nanocrystalline diamond (BNDD) film and a Si substrate. A BNDD/Ta/Ti/Si electrode exhibits faster electron transfer processes and smaller electron transfer resistance of redox probes for [Fe(CN)6]3-/4- and [Ru(NH3)6]3+/2+ than the other electrodes, because the interlayer thus determines the intrinsic activity and reaction kinetics of diamond films. image
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001247280600001 Publication Date 2024-06-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2366-9608 ISBN Additional Links UA library record; WoS full record
Impact Factor 12.4 Times cited Open Access
Notes Approved Most recent IF: 12.4; 2024 IF: NA
Call Number UA @ admin @ c:irua:206567 Serial 9298
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Author Janssens, K.; Van der Snickt, G.
Title De macroscopische X-straal fluorescentiescanner voor schilderijen Type H3 Book chapter
Year 2024 Publication Abbreviated Journal
Volume (up) Issue Pages 36-37 T2 - Verhalenvertellers : academisch erfgoed
Keywords H3 Book chapter; Documentation and information; Engineering sciences. Technology; Art; History; Antwerp Cultural Heritage Sciences (ARCHES); Antwerp X-ray Imaging and Spectroscopy (AXIS)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:208047 Serial 9303
Permanent link to this record