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Author | van der Snickt, G.; Schalm, O.; Caen, J.; Janssens, K.; Schreiner, M. | ||||
Title | Blue enamel on sixteenth- and seventeenth-century window glass : deterioration, microstructure, composition and preparation | Type | A1 Journal article | ||
Year | 2006 | Publication | Studies in conservation | Abbreviated Journal | Stud Conserv |
Volume | 51 | Issue | Pages | 212-222 | |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000241941100006 | Publication Date | 2014-01-09 | |
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Series Volume | Series Issue | Edition | |||
ISSN | 0039-3630; 2047-0584 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 0.578 | Times cited | 8 | Open Access | |
Notes | Approved | Most recent IF: 0.578; 2006 IF: 0.609 | |||
Call Number | UA @ admin @ c:irua:60712 | Serial ![]() |
5492 | ||
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Author | van der Linden, V.; Schalm, O.; Houbraken, J.; Thomas, M.; Meesdom, E.; Devos, A.; van Dooren, R.; Nieuwdorp, H.; Janssen, E.; Janssens, K. | ||||
Title | Chemical analysis of 16th to 19th century Limoges School painted enamel objects in three museums of the Low Countries | Type | A1 Journal article | ||
Year | 2010 | Publication | X-ray spectrometry | Abbreviated Journal | X-Ray Spectrom |
Volume | 39 | Issue | 2 | Pages | 112-121 |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
Abstract | In this study, the results of analysing of a series of 16th-19th century painted enamel objects of the Limoges School currently in collections in three Dutch and Flemish museums by means of portable and micro x-ray fluorescence analysis (PXRF and µ-XRF) and electron probe micro analysis (EPMA) are presented. The aim of the investigation was the authentication of specific pieces. Therefore, the glass compositions as well as the (glass) colouring agents used by the Limoges' artists were studied as a function of the age of the objects. Due to the evolution of these properties, it is possible to approximately date these objects based on their chemical composition. The complete émail peint collection of the Museum Boijmans-Van Beuningen (Rotterdam, The Netherlands), consisting of 20 émail peint plaques, was analysed with µ-XRF. Quantitative information was obtained by EPMA analysis of 15 enamel fragments of objects from museum and private collections in the Low Countries. PXRF analyses were performed on the painted enamel collection of the Antwerp Vleeshuis Museum (13 objects) and the Mayer van den Bergh Museum (4 objects) and on a set of 18 plaques that were donated to the Boijmans-Van Beuningen Museum by a private collector. The results obtained by means of EPMA, µ-XRF and PXRF proved to be useful in the discrimination of 16th century painted enamel objects from those of the19th century. From a total of 70 objects examined, 2 objects (OM964A and OM993) featured a chemical signature that deviated from the published literature composition and pigment use consistent with its presumed period of manufacture. | ||||
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Language | Wos | 000275959400007 | Publication Date | 2009-08-11 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0049-8246 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 1.298 | Times cited | 8 | Open Access | |
Notes | ; ; | Approved | Most recent IF: 1.298; 2010 IF: 1.661 | ||
Call Number | UA @ admin @ c:irua:82325 | Serial ![]() |
5509 | ||
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Author | Elia, A.; De Wael, K.; Dowsett, M.; Adriaens, A. | ||||
Title | Electrochemical deposition of a copper carboxylate layer on copper as potential corrosion inhibitor | Type | A1 Journal article | ||
Year | 2011 | Publication | Journal of solid state electrochemistry | Abbreviated Journal | J Solid State Electr |
Volume | 16 | Issue | 1 | Pages | 143-148 |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
Abstract | Carboxylic acids and sodium carboxylates are used to protect metals against aqueous and atmospheric corrosion. In this paper, we describe the application of a layer of copper carboxylate on the surface of a copper electrode by means of cyclic voltammetry technique and tests which measure the corresponding resistance to aqueous corrosion. Unlike the soaking process, which also forms a film on the surface, the use of cyclic voltammetry allows one to follow the deposition process of the copper carboxylates onto the electrode. The modified electrodes have been characterised with infrared spectroscopy. In addition, the corrosion resistance of the film has been investigated using polarisation resistance and Tafel plot measurements. | ||||
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Language | Wos | 000298651700018 | Publication Date | 2011-01-25 | |
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Series Volume | Series Issue | Edition | |||
ISSN | 1432-8488 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 2.316 | Times cited | 8 | Open Access | |
Notes | ; Authors would like to acknowledge the Research Foundation-Flanders (FWO) for funding assistance (A. Elia is a FWO aspirant) and V. Vermeersch and S. Van Vlierberghe (Ghent University, Polymer Chemistry and Biomaterials Research Group) for the FTIR-ATR measurements. ; | Approved | Most recent IF: 2.316; 2011 IF: 2.131 | ||
Call Number | UA @ admin @ c:irua:89618 | Serial ![]() |
5588 | ||
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Author | De Jong, M.; Florea, A.; de Vries, A.-M.; van Nuijs, A.L.N.; Covaci, A.; Van Durme, F.; Martins, J.C.; Samyn, N.; De Wael, K. | ||||
Title | Levamisole : a common adulterant in cocaine street samples hindering electrochemical detection of cocaine | Type | A1 Journal article | ||
Year | 2018 | Publication | Analytical chemistry | Abbreviated Journal | Anal Chem |
Volume | 90 | Issue | 8 | Pages | 5290-5297 |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Toxicological Centre | ||||
Abstract | The present work investigates the electrochemical determination of cocaine in the presence of levamisole, one of the most common adulterants found in cocaine street samples. Levamisole misleads cocaine color tests, giving a blue color (positive test) even in the absence of cocaine. Moreover, the electrochemical detection of cocaine is also affected by the presence of levamisole, with a suppression of the oxidation signal of cocaine. When levamisole is present in the sample in ratios higher than 1:1, the cocaine signal is no longer detected, thus leading to false negative results. Mass spectrometry and nuclear magnetic resonance were used to investigate if the signal suppression is due to the formation of a complex between cocaine and levamisole in bulk solution. Strategies to eliminate this suppressing effect are further suggested in this manuscript. In a first approach, the increase of the pH of the sample solution from pH 7 to pH 12 allowed the voltammetric determination of cocaine in the presence of levamisole in a concentration range from 10 to 5000 μM at nonmodified graphite disposable electrodes with a detection limit of 5 μM. In a second approach, the graphite electrode was cathodically pretreated, resulting in the presence of oxidation peaks of both cocaine and levamisole, with a detection limit for cocaine of 3 μM over the linear range of concentrations from 10 to 2500 μM. Both these strategies have been successfully applied for the simultaneous detection of cocaine and levamisole in three street samples on unmodified graphite disposable electrodes. | ||||
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Language | Wos | 000430512200049 | Publication Date | 2018-02-23 | |
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Series Volume | Series Issue | Edition | |||
ISSN | 0003-2700; 5206-882x | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 6.32 | Times cited | 8 | Open Access | |
Notes | ; This project has received funding from the European Union's Horizon 2020 Research and Innovation Programme under the Marie Sklodowska-Curie Grant Agreement No. 753223 Narcoreader. This work was also supported by BR/314/PI/ APTADRU Project and IOF-SBO (UAntwerp). Alexander van Nuijs acknowledges the Research Foundation-Flanders (FWO) for his postdoctoral fellowship. ; | Approved | Most recent IF: 6.32 | ||
Call Number | UA @ admin @ c:irua:149528 | Serial ![]() |
5693 | ||
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Author | Nuyts, G.; Cagno, S.; Bugani, S.; Janssens, K. | ||||
Title | Micro-XANES study on Mn browning: use of quantitative valence state maps | Type | A1 Journal article | ||
Year | 2015 | Publication | Journal of analytical atomic spectrometry | Abbreviated Journal | J Anal Atom Spectrom |
Volume | 30 | Issue | 3 | Pages | 642-650 |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
Abstract | Historical glass, especially non-durable medieval glass, can undergo corrosion. This sometimes results in the formation of dark-coloured manganese-rich inclusions that reduce the transparency of the glass. While unaltered bulk glass contains manganese mainly present in the +II valence state, inside the inclusions Mn is present in higher valence states (+III to +IV). Two different strategies may be considered by conservators when aiming to improve the transparency. One is based on the reduction of highly oxidised black/brown compounds using mildly reducing solutions, while the other focuses more on the extraction of manganese from the inclusions by the application of chelating agents. In this paper, a method for quantitative mapping of the Mn speciation inside partially corroded historical windowpanes based on X-Ray Absorption Near-Edge Structure (XANES) spectroscopy is discussed. The calibration of such Mn valence state maps based on the combo method, a fairly reliable way to determine the oxidation state, is described in more detail. This method is used to evaluate the effect of reducing treatments on historical glass, dated to the 14th century and originating from Sidney Sussex College (Cambridge, UK), suffering from Mn browning. Glasses were examined by means of Synchrotron Radiation (SR) based microscopic X-Ray Absorption Near-Edge Structure (mXANES) spectroscopy and microscopic X-Ray Fluorescence (mXRF). X-Ray elemental distribution maps of glass cross-sections are recorded at different energies, while Mn K-edge spectra are used to convert these into Mn valence state (VS) maps. Such valence state maps will allow evaluation of a reducing treatment. | ||||
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Language | Wos | 000350650800009 | Publication Date | 2015-02-23 | |
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ISSN | 0267-9477 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 3.379 | Times cited | 8 | Open Access | |
Notes | ; This research was supported by the Interuniversity Attraction Poles Programme Belgian Science Policy (IUAP VI/16) and partially by the Research Council of Norway through its Centres of Excellence funding scheme, project number 223268/ F50. The text also presents results of Center of Excellence AGRECHEM (Research Fund University of Antwerp, Belgium) and from the Fund for Scientific Research (FWO, Brussels, Belgium) projects no. G.0C12.13 and G.01769.09. We gratefully acknowledge ESRF for granting beamtime (experiment EC768) and the beamline scientists of ID21 for their support. The authors also want to thank Leonie Seliger of Canterbury Cathedral, UK, the Sidney Sussex College Council and Bursar Charles Larkum for providing the archaeological samples of the Franciscan Friary which are kept in store for Sidney Sussex College in Cambridge (UK). ; | Approved | Most recent IF: 3.379; 2015 IF: 3.466 | ||
Call Number | UA @ admin @ c:irua:125476 | Serial ![]() |
5719 | ||
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Author | Rindby, A.; Janssens, K.; Osán, J. | ||||
Title | Reconstruction of the three-dimensional distribution of elements in fly-ash particles by micro-XRF spectroscopy | Type | A1 Journal article | ||
Year | 2003 | Publication | X-ray spectrometry | Abbreviated Journal | X-Ray Spectrom |
Volume | 32 | Issue | 3 | Pages | 248-257 |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000183630400011 | Publication Date | 2003-06-12 | |
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Series Volume | Series Issue | Edition | |||
ISSN | 0049-8246 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 1.298 | Times cited | 8 | Open Access | |
Notes | Approved | Most recent IF: 1.298; 2003 IF: 1.227 | |||
Call Number | UA @ admin @ c:irua:41805 | Serial ![]() |
5807 | ||
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Author | Alfeld, M.; Wahabzada, M.; Bauckhage, C.; Kersting, K.; van der Snickt, G.; Noble, P.; Janssens, K.; Wellenreuther, G.; Falkenberg, G. | ||||
Title | Simplex Volume Maximization (SiVM): a matrix factorization algorithm with non-negative constrains and low computing demands for the interpretation of full spectral X-ray fluorescence imaging data | Type | A1 Journal article | ||
Year | 2017 | Publication | Microchemical journal | Abbreviated Journal | Microchem J |
Volume | 132 | Issue | Pages | 179-184 | |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
Abstract | Technological progress allows for an ever-faster acquisition of hyperspectral data, challenging the users to keep up with interpreting the recorded data. Matrix factorization, the representation of data sets by bases (or loads) and coefficient (or score) images is long used to support the interpretation of complex data sets. We propose in this publication Simplex Volume Maximization (SiVM) for the analysis of X-ray fluorescence (XRF) imaging data sets. SiVM selects archetypical data points that represents the data set and thus provides easily understandable bases, preserves the non-negative character of XRF data sets and has low demands concerning computing resources. We apply SiVM on an XRF data set of Hans Memling's Portrait of a man from the Lespinette family from the collection of the Mauritshuis (The Hague, NL) and discuss capabilities and shortcomings of SiVM. (C) 2017 Elsevier B.V. All rights reserved. | ||||
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Language | Wos | 000399845700026 | Publication Date | 2017-02-04 | |
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Series Volume | Series Issue | Edition | |||
ISSN | 0026-265x; 0026-265x | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 3.034 | Times cited | 8 | Open Access | |
Notes | ; The German Federal Ministry of Education and Research (BMBF) is acknowledged for the financial support (Verbundprojekt 05K2012 POISSON: Fortschrittliche Faktorenanalyse ffir Poisson-verteilte Daten). ; | Approved | Most recent IF: 3.034 | ||
Call Number | UA @ admin @ c:irua:152647 | Serial ![]() |
5830 | ||
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Author | Alfeld, M.; Janssens, K.; Sasov, A.; Liu, X.; Kostenko, A.; Rickers-Appel, K.; Falkenberg, G. | ||||
Title | The use of full-field XRF for simultaneous elemental mapping | Type | P1 Proceeding | ||
Year | 2010 | Publication | Abbreviated Journal | ||
Volume | Issue | Pages | 111-118 | ||
Keywords | P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
Abstract | The characteristics of a Full-Field X-ray Fluorescence (FF-XRF) set-up for element-specific imaging, installed at the HASYLAB synchrotron radiation source, were determined. A lateral resolution of 10 μm and limits of detection in the percentage range were found. Further potential developments in CCDs available for FF-XRF are discussed and the use of polycapillary lenses as image transfer optics is illustrated in some explorative experiments. | ||||
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Language | Wos | 000278534600020 | Publication Date | 2010-04-16 | |
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ISSN | 978-0-7354-0764-0 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | Times cited | 8 | Open Access | ||
Notes | ; This research was supported by the Interuniversity Attraction Poles Programme – Belgian Science Policy (IUAP VI/16) and by GOA XANES meets EELS (Research Fund University of Antwerp, Belgium). M. Alfeld is supported by the Research Foundation – Flanders (FWO). The research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/ 2007-2013) under grant agreement no 226716. ; | Approved | Most recent IF: NA | ||
Call Number | UA @ admin @ c:irua:82179 | Serial ![]() |
5891 | ||
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Author | De Keersmaecker, M.; De Wael, K.; Adriaens, A. | ||||
Title | The use of lead dodecanoate as an environmentally friendly coating to inhibit the corrosion of lead objects : comparison of three different deposition methods | Type | A1 Journal article | ||
Year | 2012 | Publication | Progress in organic coatings | Abbreviated Journal | Prog Org Coat |
Volume | 74 | Issue | 1 | Pages | 1-7 |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
Abstract | An aqueous sodium dodecanoate solution has been used for the formation of a protective coating for lead. Three deposition methods have been compared: immobilization using cyclic voltammetry, immersion and amperometry. Apart from this, we tested a reduction pretreatment of the lead surface (−1.5 V during 600 s) in order to obtain a more reproducible coating, resulting in a better corrosion protection behavior. The corrosion inhibition properties were examined using potentiodynamic polarization curves and electrochemical impedance measurements in a standard corrosive environment. | ||||
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Language | Wos | 000302585300001 | Publication Date | 2012-02-16 | |
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Series Volume | Series Issue | Edition | |||
ISSN | 0300-9440; 0033-0655 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 2.858 | Times cited | 8 | Open Access | |
Notes | ; The Research Foundation – Flanders (FWO) and Ghent University are acknowledged for funding this work. The authors would like to thank Pieter Van Hoe for the production of the embedded lead electrodes. They also acknowledge Pieter Arickx and Jonas Van Damme for their contribution. ; | Approved | Most recent IF: 2.858; 2012 IF: 1.848 | ||
Call Number | UA @ admin @ c:irua:96354 | Serial ![]() |
5894 | ||
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Author | Singh, B.R.; Timsina, Y.N.; Lind, O.C.; Cagno, S.; Janssens, K. | ||||
Title | Zinc and iron concentration as affected by nitrogen fertilization and their localization in wheat grain | Type | A1 Journal article | ||
Year | 2018 | Publication | Frontiers in plant science | Abbreviated Journal | Front Plant Sci |
Volume | 9 | Issue | 9 | Pages | |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) | ||||
Abstract | Nearly half of the world cereal production comes from soils low or marginal in plant available zinc, leading to unsustainable and poor quality grain production. Therefore, the effects of nitrogen (N) rate and application time on zinc (Zn) and iron (Fe) concentration in wheat grain were investigated. Wheat (Triticum aestivum var. Krabat) was grown in a growth chamber with 8 and 16 h of day and night periods, respectively. The N rates were 29, 43, and 57 mg N kg(-1) soil, equivalent to 80, 120, and 160 kg N ha(-1). Zinc and Fe were applied at 10 mg kg(-1) growth media. In one of the N treatments, additional Zn and Fe through foliar spray (6 mg of Zn or Fe in 10 ml water / pot) was applied. Micro-analytical localization of Zn and Fe within grain was performed using scanning macro-X-ray fluorescence (MA-XRF) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The following data were obtained: grain and straw yield pot 1, 1000 grains weight, number of grains pot 1, whole grain protein content, concentration of Zn and Fe in the grains. Grain yield increased from 80 to 120 kg N ha(-1) rates only and decreased at 160 kg N ha(-1) g. Relatively higher protein content and Zn and Fe concentration in the grain were recorded with the split N application of 160 kg N ha(-1). Soil and foliar supply of Zn and Fe (Zn + Fes+f), with a single application of 120 kg N ha(-1) N at sowing, increased the concentration of Zn by 46% and of Fe by 35%, as compared to their growth media application only. Line scans of freshly cut areas of sliced grains showed co-localization of Zn and Fe within germ, crease and aleurone. We thus conclude that split application of N at 160 kg ha(-1) at sowing and stem elongation, in combination with soil and foliar application of Zn and Fe, can be a good agricultural practice to enhance protein content and the Zn and Fe concentration in grain. | ||||
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Language | Wos | 000427034400002 | Publication Date | 2018-03-09 | |
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Series Volume | Series Issue | Edition | |||
ISSN | 1664-462x | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 4.298 | Times cited | 8 | Open Access | |
Notes | ; The research part of this master study was financed by the project “Mineral Improved Food and Feed Crops for Human and Animal Health” (Project No. 332160UA) and by a grant from the Norwegian Ministry of Foreign Affairs under the Program for Higher Education, Research and Development (HERD) in Western Balkan. The financial assistance for conducting this study is gratefully acknowledged. We also acknowledge the assistance by CERAD: this study has been funded by the Norwegian Research Council through its Centre of Excellence (CoE) funding scheme (Project No. 223268/F50). This research was supported by the Hercules Foundation (Brussels, Belgium) under grant AUHA09004 and FWO (Brussels, Belgium) Project Nos. G.0C12.13 and G.01769.09. ; | Approved | Most recent IF: 4.298 | ||
Call Number | UA @ admin @ c:irua:149859 | Serial ![]() |
5924 | ||
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Author | Meire, M.; Verbruggen, S.W.; Lenaerts, S.; Lommens, P.; Van Der Voort, P.; Van Driessche, I. | ||||
Title | Microwave-assisted synthesis of mesoporous titania with increased crystallinity, specific surface area, and photocatalytic activity | Type | A1 Journal article | ||
Year | 2016 | Publication | Journal of materials science | Abbreviated Journal | J Mater Sci |
Volume | 51 | Issue | 21 | Pages | 9822-9829 |
Keywords | A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) | ||||
Abstract | Mesoporous titanium dioxide is a material finding its use in a wide range of applications. For many of these, it is important to achieve a high degree of crystallinity in the material. It is generally accepted that the use of the soft templating approach to synthesize mesoporous titania, results in a compromise between crystallinity and specific surface area due to thermal instability of the used templates. In this paper, we explore how the use of microwave irradiation can influence the crystallinity, specific surface area, and the electronic properties of mesoporous titania. Therefore, we combined microwave radiation with an evaporation-induced self-assembly (EISA) synthesis. We show that additional microwave treatment at carefully chosen synthesis steps can enhance the crystallinity with 20 % without causing significant loss of surface area (>360 m2/g). Surface photovoltage measurements were used to investigate the electronic properties. The photocatalytic activity of the samples was evaluated in aqueous media by following the degradation of an industrial dye, methylene blue, and the herbicide isoproturon under UV irradiation and in gaseous media looking at the degradation of acetaldehyde, a common indoor pollutant under UVA irradiation. In all cases, the microwave treatment results in more active materials. | ||||
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Language | Wos | 000381182200023 | Publication Date | 2016-07-18 | |
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ISSN | 0022-2461 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 2.599 | Times cited | 8 | Open Access | |
Notes | ; M. Meire and S. W. Verbruggen acknowledge the FWO-Flanders (Fund for Scientific Research-Flanders) for financial support. We want to thank T. Planckaert for the N<INF>2</INF> sorption measurements, J. Watte for the XRD measurements, and professor K. De Buysser for the quantitative Rietveld refinements. ; | Approved | Most recent IF: 2.599 | ||
Call Number | UA @ admin @ c:irua:140098 | Serial ![]() |
5970 | ||
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Author | Verbruggen, S.W.; Dirckx, J.J.J.; Martens, J.A.; Lenaerts, S. | ||||
Title | Surface photovoltage measurements : a quick assessment of the photocatalytic activity? | Type | A1 Journal article | ||
Year | 2013 | Publication | Catalysis today | Abbreviated Journal | Catal Today |
Volume | 209 | Issue | Pages | 215-220 | |
Keywords | A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) | ||||
Abstract | Surface photovoltage (SPV) measurements can contribute to a better understanding of electronic properties of photocatalysts under illumination. Direct linking of SPV data to the actual photocatalytic activity remains troublesome. This work aims to discuss SPV measurements from a photocatalytic point of view. By means of several application-based scenarios we illustrate that the trend between SPV and photocatalysis strongly depends on parameters such as the crystal structure, surface modifications, morphology and humidity. This makes the interpretation far from straightforward. | ||||
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Language | Wos | 000319498800035 | Publication Date | 2013-01-16 | |
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ISSN | 0920-5861 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 4.636 | Times cited | 8 | Open Access | |
Notes | ; ; | Approved | Most recent IF: 4.636; 2013 IF: 3.309 | ||
Call Number | UA @ admin @ c:irua:106520 | Serial ![]() |
5995 | ||
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Author | Hauchecorne, B.; Lenaerts, S. | ||||
Title | Unravelling the mysteries of gas phase photocatalytic reaction pathways by studying the catalyst surface : a literature review of different Fourier transform infrared spectroscopic reaction cells used in the field | Type | A1 Journal article | ||
Year | 2013 | Publication | Journal of photochemistry and photobiology: C: photochemistry reviews | Abbreviated Journal | J Photoch Photobio C |
Volume | 14 | Issue | Pages | 72-85 | |
Keywords | A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) | ||||
Abstract | Unlike the profound knowledge of the reaction mechanisms occurring in water phase photocatalysis, still fairly little is known on the reaction mechanisms occurring on the catalyst surface when dealing with gaseous pollutants. Unfortunately, there are some differences between both reactions. For one, there are no abundant hydroxyl radicals present in the gas phase, so that possibly other species prove to be important in abating the pollutant. In order to unravel the mysteries of gas phase photocatalytic reaction pathways, in situ techniques must be used to allow the detection and identification of reaction intermediates on a working catalyst. Several techniques were already used in the past, of which Fourier transform infrared spectroscopy seems to be the most versatile. This review will therefore give a selective overview of different spectroscopic reaction cells constructed for the in situ study of photocatalytic gas phase reactions. | ||||
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Language | Wos | 000314669600005 | Publication Date | 2012-09-28 | |
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ISSN | 1389-5567 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 12.317 | Times cited | 8 | Open Access | |
Notes | ; The University of Antwerp is greatly acknowledged for the fellowship granted to Birger Hauchecorne. The authors would also like to thank Sammy W. Verbruggen for his help in providing several papers of interest. ; | Approved | Most recent IF: 12.317; 2013 IF: 11.625 | ||
Call Number | UA @ admin @ c:irua:106518 | Serial ![]() |
6001 | ||
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Author | Vanschoenwinkel, J.; Mendelsohn, R.; Van Passel, S. | ||||
Title | Do Western and Eastern Europe have the same agricultural climate response? Taking adaptive capacity into account | Type | A1 Journal article | ||
Year | 2016 | Publication | Global Environmental Change-Human And Policy Dimensions | Abbreviated Journal | Global Environ Chang |
Volume | 41 | Issue | Pages | 74-87 | |
Keywords | A1 Journal article; Economics; Engineering Management (ENM) | ||||
Abstract | Current cross-sectional methodologies measuring climate change impacts assume that regions at the same latitude face a similar climate response and therefore have the same adaptive capacity. This paper proves that assumption to be erroneous in the European Union. It does so by ameliorating the Ricardian methodology by restricting which farmers (and therefore which adaptation options) are allowed in the dataset. In doing so, a comparative Ricardian methodology is suggested that makes it possible to examine, for the first time, how the climate responsiveness of a region changes if adaptive capacity changes. The paper combines climate, soil, geographic, socio-economic, and farm-level data in a linear mixed-effect model and examines whether Eastern and Western Europe have the same climate responses and how these responses change if regional adaptive capacity increases. The paper concludes that both regions currently have a significantly different climate response, but that if Eastern Europe were to implement the same adaptation options as Western Europe, it could avoid a large decrease in land value and even benefit from climate change depending on the climate scenario. | ||||
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Corporate Author | Thesis | ||||
Publisher | Place of Publication | Editor | |||
Language | Wos | 000389732700007 | Publication Date | 2016-09-25 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0959-3780; 1872-9495 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles; WoS full record; WoS citing articles | |
Impact Factor | 6.327 | Times cited | 8 | Open Access | |
Notes | ; Steven Van Passel would kindly want to express his gratitude towards DG AGRI for access to the Farm Accountancy Data Network (FADN). The authors also thank the reviewers of this journal for their improvements to the final manuscript and they are grateful for the comments and suggestions they received at the conferences where this paper has been presented (IAMO forum 2015, EAAE PhD workshop 2015, Belgian PhD symposium 2015, EAERE conference 2016). Janka Vanschoenwinkel also wants to thank FWO and the Doctoral Schools of Hasselt University for giving a mobility grant to go to the EAAE PhD workshop in Rome. ; | Approved | Most recent IF: 6.327 | ||
Call Number | UA @ admin @ c:irua:139026 | Serial ![]() |
6185 | ||
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Author | Kuppens, T.; Van Dael, M.; Vanreppelen, K.; Carleer, R.; Yperman, J.; Schreurs, S.; Van Passel, S. | ||||
Title | Techno-economic assessment of pyrolysis char production and application : a review | Type | P1 Proceeding | ||
Year | 2014 | Publication | Abbreviated Journal | ||
Volume | Issue | Pages | 67-72 | ||
Keywords | P1 Proceeding; Engineering sciences. Technology | ||||
Abstract | Many organic residue streams such as pig manure are not or inefficiently used, although they can be converted into valuable materials, as well as energy, using pyrolysis. The yield of the pyrolysis products (i.e. oil, gas and char) is dependent on the process conditions and the feedstock used. Char as a soil amendment or activated carbon are interesting options for valorization of biomass residues. Here, a review is presented of the techno-economic potential of both valorization options based on literature and own experiments with wood from phytoremediation, particle board and waste from beer production. The term “biochar” is specifically used to designate pyrolysis char that is intentionally applied to soil in order to enhance its structure and fertility. Biochar applications are often also motivated by the objective of climate change mitigation. Two main disadvantages for the economic feasibility of biochar applications have been discerned. Firstly, carbon sequestration in agricultural crops and soils is not yet eligible under the Clean Development Mechanism. Secondly, the impact of biochar on crop productivity is unclear. Activated carbon (AC) seems to have interesting adsorption characteristics resulting in potentially high sales prices. A preliminary techno-economic assessment showed that AC production is preferred above oil production for wood from phytoremediation as long as the market price of 2 kEUR.t(-1) for commercially available ACs can be attained. Whenever a feedstock with high nitrogen content is available (e.g. particle board with melamine urea formaldehyde resin), even higher market prices might be attained. This study shows that valorization of the pyrolysis char might be an answer to the slow adoption of pyrolysis in commercial applications. Focus in research and development, for instance in future research with regard to pig manure valorization, should therefore be on sustainable products with high economic value and direct utilization potential. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000346540000012 | Publication Date | ||
Series Editor | Series Title | Abbreviated Series Title | International Conference on BioMass (iconBM 2014), 4-7 May 2014, Florence, Italy / Ranzi, Eliseo [edit.]; et al. | ||
Series Volume | 37 | Series Issue | Edition | ||
ISSN | 978-88-95608-28-0 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | Times cited | 8 | Open Access | ||
Notes | ; ; | Approved | Most recent IF: NA | ||
Call Number | UA @ admin @ c:irua:127547 | Serial ![]() |
6265 | ||
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Author | Thomassen, G.; Van Dael, M.; Van Passel, S. | ||||
Title | The potential of microalgae biorefineries in Belgium and India : an environmental techno-economic assessment | Type | A1 Journal article | ||
Year | 2018 | Publication | Bioresource Technology | Abbreviated Journal | Bioresource Technol |
Volume | 267 | Issue | 267 | Pages | 271-280 |
Keywords | A1 Journal article; Engineering sciences. Technology; Engineering Management (ENM) | ||||
Abstract | This study performs an environmental techno-economic assessment (ETEA) for multiple microalgae biorefinery concepts at different locations, those being Belgium and India. The ETEA methodology, which integrates aspects of the TEA and LCA methodologies and provides a clear framework for an integrated assessment model, has been proposed and discussed. The scenario in India has a higher profitability with a NPV of (sic)40 million over a period of 10 years, while the environmental impact in Belgium is lower. The inclusion of a medium recycling step provides the best scenario from both perspectives. The crucial parameters for feasibility are the beta-caroteneprice and content, the upstream environmental impact of electricity and the maximum biomass concentration during cultivation. The identification of these parameters by the ETEA guides future technology developments and shortens the time-to-market for microalgal-based biorefineries. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000441876100034 | Publication Date | 2018-07-10 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0960-8524 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles; WoS full record; WoS citing articles | |
Impact Factor | 5.651 | Times cited | 8 | Open Access | |
Notes | ; ; | Approved | Most recent IF: 5.651 | ||
Call Number | UA @ admin @ c:irua:153599 | Serial ![]() |
6270 | ||
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Author | Jin, B.; Liang, F.; Hu, Z.-Y.; Wei, P.; Liu, K.; Hu, X.; Van Tendeloo, G.; Lin, Z.; Li, H.; Zhou, X.; Xiong, Q.; Zhai, T. | ||||
Title | Nonlayered CdSe flakes homojunctions | Type | A1 Journal article | ||
Year | 2020 | Publication | Advanced Functional Materials | Abbreviated Journal | Adv Funct Mater |
Volume | 30 | Issue | 30 | Pages | 1908902 |
Keywords | A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) | ||||
Abstract | 2D homojunctions have stimulated extensive attention because of their perfect thermal and lattice matches, as well as their tunable band structures in 2D morphology, which provide fascinating opportunities for novel electronics and optoelectronics. Recently, 2D nonlayered materials have attracted the attention of researchers owing to their superior functional applications and diverse portfolio of the 2D family. Therefore, 2D nonlayered homojunctions would open the door to a rich spectrum of exotic 2D materials. However, they are not investigated due to their extremely difficult synthesis methods. Herein, nonlayered CdSe flakes homojunctions are obtained via self-limited growth with InCl3 as a passivation agent. Interestingly, two pieces of vertical wurtzite-zinc blende (WZ-ZB) homojunctions epitaxially integrate into WZ/ZB lateral junctions. These homojunctions show a divergent second-harmonic generation intensity, strongly correlated to the multiple twinned ZB phase, as identified by aberration-corrected scanning transmission electron microscopy and theoretical calculations. Impressively, the photodetector based on this WZ/ZB CdSe homojunction shows excellent performances, integrating a high photoswitching ratio (3.4 x 10(5)) and photoresponsivity (3.7 x 10(3) A W-1), suggesting promising potential for applications in electronics and optoelectronics. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000508624800001 | Publication Date | 2020-01-23 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 1616-301x | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 19 | Times cited | 8 | Open Access | Not_Open_Access |
Notes | ; This work was supported by the National Natural Science Foundation of China (Grant Nos. 21825103, 51727809, and 51802103), the Hubei Provincial Natural Science Foundation of China (2019CFA002), and the Fundamental Research Funds for the Central Universities (HUST: 2019kfyXMBZ018; WUT: 2019III012GX). Here the authors also thank the support from Analytical and Testing Center in HUST and the State Key Laboratory of Silicate Materials for Architectures in WUT. ; | Approved | Most recent IF: 19; 2020 IF: 12.124 | ||
Call Number | UA @ admin @ c:irua:165654 | Serial ![]() |
6314 | ||
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Author | Marchetti, A.; Saniz, R.; Krishnan, D.; Rabbachin, L.; Nuyts, G.; De Meyer, S.; Verbeeck, J.; Janssens, K.; Pelosi, C.; Lamoen, D.; Partoens, B.; De Wael, K. | ||||
Title | Unraveling the Role of Lattice Substitutions on the Stabilization of the Intrinsically Unstable Pb2Sb2O7Pyrochlore: Explaining the Lightfastness of Lead Pyroantimonate Artists’ Pigments | Type | A1 Journal article | ||
Year | 2020 | Publication | Chemistry Of Materials | Abbreviated Journal | Chem Mater |
Volume | 32 | Issue | 7 | Pages | 2863-2873 |
Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Electron microscopy for materials research (EMAT); Condensed Matter Theory (CMT) | ||||
Abstract | The pyroantimonate pigments Naples yellow and lead tin antimonate yellow are recognized as some of the most stable synthetic yellow pigments in the history of art. However, this exceptional lightfastness is in contrast with experimental evidence suggesting that this class of mixed oxides is of semiconducting nature. In this study the electronic structure and light-induced behavior of the lead pyroantimonate pigments were determined by means of a combined multifaceted analytical and computational approach (photoelectrochemical measurements, UV-vis diffuse reflectance spectroscopy, STEM-EDS, STEM-HAADF, and density functional theory calculations). The results demonstrate both the semiconducting nature and the lightfastness of these pigments. Poor optical absorption and minority carrier mobility are the main properties responsible for the observed stability. In addition, novel fundamental insights into the role played by Na atoms in the stabilization of the otherwise intrinsically unstable Pb2Sb2O7 pyrochlore were obtained. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000526394000016 | Publication Date | 2020-04-14 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0897-4756 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 8.6 | Times cited | 8 | Open Access | OpenAccess |
Notes | Universiteit Antwerpen; Belgian Federal Science Policy Office; | Approved | Most recent IF: 8.6; 2020 IF: 9.466 | ||
Call Number | EMAT @ emat @c:irua:168819 | Serial ![]() |
6363 | ||
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Author | Wang, J.; Gauquelin, N.; Huijben, M.; Verbeeck, J.; Rijnders, G.; Koster, G. | ||||
Title | Metal-insulator transition of SrVO 3 ultrathin films embedded in SrVO 3 / SrTiO 3 superlattices | Type | A1 Journal article | ||
Year | 2020 | Publication | Applied Physics Letters | Abbreviated Journal | Appl Phys Lett |
Volume | 117 | Issue | 13 | Pages | 133105 |
Keywords | A1 Journal article; Electron microscopy for materials research (EMAT) | ||||
Abstract | The metal-insulator transition (MIT) in strongly correlated oxides is a topic of great interest for its potential applications, such as Mott field effect transistors and sensors. We report that the MIT in high quality epitaxial SrVO3 (SVO) thin films is present as the film thickness is reduced, lowering the dimensionality of the system, and electron-electron correlations start to become the dominant interactions. The critical thickness of 3 u.c is achieved by avoiding effects due to off-stoichiometry using optimal growth conditions and excluding any surface effects by a STO capping layer. Compared to the single SVO thin films, conductivity enhancement in SVO/STO superlattices is observed. This can be explained by the interlayer coupling effect between SVO sublayers in the superlattices. Magnetoresistance and Hall measurements indicate that the dominant driving force of MIT is the electron–electron interaction. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000577126100001 | Publication Date | 2020-09-28 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0003-6951 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 4 | Times cited | 8 | Open Access | OpenAccess |
Notes | Nederlandse Organisatie voor Wetenschappelijk Onderzoek, 13HTSM01 ; | Approved | Most recent IF: 4; 2020 IF: 3.411 | ||
Call Number | EMAT @ emat @c:irua:172461 | Serial ![]() |
6415 | ||
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Author | Vanherck, J.; Bacaksiz, C.; Sorée, B.; Milošević, M.V.; Magnus, W. | ||||
Title | 2D ferromagnetism at finite temperatures under quantum scrutiny | Type | A1 Journal article | ||
Year | 2020 | Publication | Applied Physics Letters | Abbreviated Journal | Appl Phys Lett |
Volume | 117 | Issue | 5 | Pages | 052401 |
Keywords | A1 Journal article; Condensed Matter Theory (CMT) | ||||
Abstract | Recent years have seen a tremendous rise of two-dimensional (2D) magnetic materials, several of which were verified experimentally. However, most of the theoretical predictions to date rely on ab initio methods, at zero temperature and fluctuation-free, while one certainly expects detrimental quantum fluctuations at finite temperatures. Here, we present the solution of the quantum Heisenberg model for honeycomb/hexagonal lattices with anisotropic exchange interaction up to third nearest neighbors and in an applied field in arbitrary direction, which answers the question whether long-range magnetization can indeed survive in the ultrathin limit of materials, up to which temperature, and what the characteristic excitation (magnon) frequencies are, all essential to envisaged applications of magnetic 2D materials. We find that long-range magnetic order persists at finite temperature for materials with overall easy-axis anisotropy. We validate the calculations on the examples of monolayers CrI3, CrBr3, and MnSe2. Moreover, we provide an easy-to-use tool to calculate Curie temperatures of new 2D computational materials. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000559330100001 | Publication Date | 2020-08-03 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0003-6951; 1077-3118 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 4 | Times cited | 8 | Open Access | |
Notes | ; This work was supported by the Research Foundation-Flanders (FWO) and the special research funds of the University of Antwerp (BOF-UA). ; | Approved | Most recent IF: 4; 2020 IF: 3.411 | ||
Call Number | UA @ admin @ c:irua:171176 | Serial ![]() |
6445 | ||
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Author | Sun, C.; Liao, X.; Xia, F.; Zhao, Y.; Zhang, L.; Mu, S.; Shi, S.; Li, Y.; Peng, H.; Van Tendeloo, G.; Zhao, K.; Wu, J. | ||||
Title | High-voltage cycling induced thermal vulnerability in LiCoO₂ cathode : cation loss and oxygen release driven by oxygen vacancy migration | Type | A1 Journal article | ||
Year | 2020 | Publication | Acs Nano | Abbreviated Journal | Acs Nano |
Volume | 14 | Issue | 5 | Pages | 6181-6190 |
Keywords | A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) | ||||
Abstract | The release of the lattice oxygen due to the thermal degradation of layered lithium transition metal oxides is one of the major safety concerns in Li-ion batteries. The oxygen release is generally attributed to the phase transitions from the layered structure to spinel and rocksalt structures that contain less lattice oxygen. Here, a different degradation pathway in LiCoO2 is found, through oxygen vacancy facilitated cation migration and reduction. This process leaves undercoordinated oxygen that gives rise to oxygen release while the structure integrity of the defect-free region is mostly preserved. This oxygen release mechanism can be called surface degradation due to the kinetic control of the cation migration but has a slow surface to bulk propagation with continuous loss of the surface cation ions. It is also strongly correlated with the high-voltage cycling defects that end up with a significant local oxygen release at low temperatures. This work unveils the thermal vulnerability of high-voltage Li-ion batteries and the critical role of the surface fraction as a general mitigating approach. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000537682300101 | Publication Date | 2020-04-17 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 1936-0851 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 17.1 | Times cited | 8 | Open Access | Not_Open_Access |
Notes | ; C.S., X.L., and F.X. contributed equally to this work. This work was supported by the National Natural Science Foundation of China (21905169). The S/TEM work was performed at the Nanostructure Research Center (NRC), which is supported by the Fundamental Research Funds for the Central Universities (WUT: 2019III012GX), the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, and the State Key Laboratory of Silicate Materials for Architectures (all of the laboratories are at Wuhan University of Technology). ; | Approved | Most recent IF: 17.1; 2020 IF: 13.942 | ||
Call Number | UA @ admin @ c:irua:170246 | Serial ![]() |
6537 | ||
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Author | Zhao, X.N.; Xu, W.; Xiao, Y.M.; Liu, J.; Van Duppen, B.; Peeters, F.M. | ||||
Title | Terahertz optical Hall effect in monolayer MoS₂ in the presence of proximity-induced interactions | Type | A1 Journal article | ||
Year | 2020 | Publication | Physical Review B | Abbreviated Journal | Phys Rev B |
Volume | 101 | Issue | 24 | Pages | 245412-12 |
Keywords | A1 Journal article; Condensed Matter Theory (CMT) | ||||
Abstract | The effect of proximity-induced interactions such as Rashba spin-orbit coupling (SOC) and exchange interaction on the electronic and optical properties of n-type monolayer (ML) MoS2 is investigated. We predict and demonstrate that the Rashba SOC can induce an in-plane spin splitting with terahertz (THz) energy, while the exchange interaction lifts the energy degeneracy in different valleys. Thus, spin polarization can be achieved in an n-type ML MoS2 and valley Hall or optical Hall effect can be observed using linearly polarized THz radiation. In such a case, the transverse optical conductivity sigma(xy) (omega) results from spin-flip transition within spin-split conduction bands and from the fact that contributions from electrons with different spin orientations in different valleys can no longer be canceled out. Interestingly, we find that for fixed effective Zeeman field (or exchange interaction) the lowest spin-split conduction band in ML MoS2 can be tuned from one in the K valley to another one in the K' valley by varying the Rashba parameter lambda(R). Therefore, by changing lambda(R) we can turn the sign of the spin polarization and Im sigma(xy) (omega) from positive to negative. Moreover, we find that the dominant contribution of the selection rules to sigma(xx)(omega) is from electrons in the K valley and to sigma(xy) (omega) is from electrons in the K' valley. These important and interesting theoretical findings can be helpful to experimental observation of the optical Hall effect in valleytronic systems using linearly polarized THz radiation fields. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000538715500011 | Publication Date | 2020-06-09 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 2469-9969; 2469-9950 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 3.7 | Times cited | 8 | Open Access | |
Notes | ; This work was supported by the National Natural Science Foundation of China (Grants No. U1930116, No. U1832153, and No. 11574319) and the Center of Science and Technology of Hefei Academy of Science (Grant No. 2016FXZY002). ; | Approved | Most recent IF: 3.7; 2020 IF: 3.836 | ||
Call Number | UA @ admin @ c:irua:170206 | Serial ![]() |
6622 | ||
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Author | Van der Donck, M.; Conti, S.; Perali, A.; Hamilton, A.R.; Partoens, B.; Peeters, F.M.; Neilson, D. | ||||
Title | Three-dimensional electron-hole superfluidity in a superlattice close to room temperature | Type | A1 Journal article | ||
Year | 2020 | Publication | Physical Review B | Abbreviated Journal | Phys Rev B |
Volume | 102 | Issue | 6 | Pages | 060503 |
Keywords | A1 Journal article; Condensed Matter Theory (CMT) | ||||
Abstract | Although there is strong theoretical and experimental evidence for electron-hole superfluidity in separated sheets of electrons and holes at low T, extending superfluidity to high T is limited by strong two-dimensional fluctuations and Kosterlitz-Thouless effects. We show this limitation can be overcome using a superlattice of alternating electron- and hole-doped semiconductor monolayers. The superfluid transition in a three-dimensional superlattice is not topological, and for strong electron-hole pair coupling, the transition temperature T-c can be at room temperature. As a quantitative illustration, we show T-c can reach 270 K for a superfluid in a realistic superlattice of transition metal dichalcogenide monolayers. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000562320700001 | Publication Date | 2020-08-25 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 2469-9969; 2469-9950 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 3.7 | Times cited | 8 | Open Access | |
Notes | ; This work was supported by the Research Foundation of Flanders (FWO-Vl) through an aspirant research grant for M.V.d.D., by the FLAG-ERA project TRANS-2D-TMD, and by the Australian Government through the Australian Research Council Centre of Excellence in Future Low-Energy Electronics (Project No. CE170100039). We thank Milorad V. Milossevi ' c, Pierbiagio Pieri, and Jacques Tempere for helpful discussions. ; | Approved | Most recent IF: 3.7; 2020 IF: 3.836 | ||
Call Number | UA @ admin @ c:irua:172064 | Serial ![]() |
6628 | ||
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Author | Bafekry, A.; Shojaei, F.; Obeid, M.M.; Ghergherehchi, M.; Nguyen, C.; Oskouian, M. | ||||
Title | Two-dimensional silicon bismotide (SiBi) monolayer with a honeycomb-like lattice: first-principles study of tuning the electronic properties | Type | A1 Journal article | ||
Year | 2020 | Publication | Rsc Advances | Abbreviated Journal | Rsc Adv |
Volume | 10 | Issue | 53 | Pages | 31894-31900 |
Keywords | A1 Journal article; Condensed Matter Theory (CMT) | ||||
Abstract | Using density functional theory, we investigate a novel two-dimensional silicon bismotide (SiBi) that has a layered GaSe-like crystal structure.Ab initiomolecular dynamic simulations and phonon dispersion calculations suggest its good thermal and dynamical stability. The SiBi monolayer is a semiconductor with a narrow indirect bandgap of 0.4 eV. Our results show that the indirect bandgap decreases as the number of layers increases, and when the number of layers is more than six layers, direct-to-indirect bandgap switching occurs. The SiBi bilayer is found to be very sensitive to an E-field. The bandgap monotonically decreases in response to uniaxial and biaxial compressive strain, and reaches 0.2 eV at 5%, while at 6%, the semiconductor becomes a metal. For both uniaxial and biaxial tensile strains, the material remains a semiconductor and indirect-to-direct bandgap transition occurs at a strain of 3%. Compared to a SiBi monolayer with a layer thickness of 4.89 angstrom, the bandgap decreases with either increasing or decreasing layer thickness, and at a thicknesses of 4.59 to 5.01 angstrom, the semiconductor-to-metal transition happens. In addition, under pressure, the semiconducting character of the SiBi bilayer with a 0.25 eV direct bandgap is preserved. Our results demonstrate that the SiBi nanosheet is a promising candidate for designing high-speed low-dissipation devices. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000565206400027 | Publication Date | 2020-09-02 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 2046-2069 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 3.9 | Times cited | 8 | Open Access | |
Notes | ; This work was supported by the National Research Foundation of Korea (NRF) grant, funded by the Korea government (MSIT) (NRF-2017R1A2B2011989). ; | Approved | Most recent IF: 3.9; 2020 IF: 3.108 | ||
Call Number | UA @ admin @ c:irua:172045 | Serial ![]() |
6644 | ||
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Author | Mychinko, M.; Skorikov, A.; Albrecht, W.; Sánchez‐Iglesias, A.; Zhuo, X.; Kumar, V.; Liz‐Marzán, L.M.; Bals, S. | ||||
Title | The Influence of Size, Shape, and Twin Boundaries on Heat‐Induced Alloying in Individual Au@Ag Core–Shell Nanoparticles | Type | A1 Journal article | ||
Year | 2021 | Publication | Small | Abbreviated Journal | Small |
Volume | Issue | Pages | 2102348 | ||
Keywords | A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) | ||||
Abstract | Environmental conditions during real-world application of bimetallic core–shell nanoparticles (NPs) often include the use of elevated temperatures, which are known to cause elemental redistribution, in turn significantly altering the properties of these nanomaterials. Therefore, a thorough understanding of such processes is of great importance. The recently developed combination of fast electron tomography with in situ heating holders is a powerful approach to investigate heat-induced processes at the single NP level, with high spatial resolution in 3D. In combination with 3D finite-difference diffusion simulations, this method can be used to disclose the influence of various NP parameters on the diffusion dynamics in Au@Ag core–shell systems. A detailed study of the influence of heating on atomic diffusion and alloying for Au@Ag NPs with varying core morphology and crystallographic details is carried out. Whereas the core shape and aspect ratio of the NPs play a minor role, twin boundaries are found to have a strong influence on the elemental diffusion. | ||||
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000673326600001 | Publication Date | 2021-07-14 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 1613-6810 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 8.643 | Times cited | 8 | Open Access | OpenAccess |
Notes | The funding for this project was provided by European Research Council (ERC Consolidator Grant 815128, REALNANO) and European Commission (grant 731019, EUSMI and grant 26019, ESTEEM). This work was performed under the Maria de Maeztu Units of Excellence Programme-Grant No. MDM-2017-0720, Ministry of Science and Innovation.; sygmaSB | Approved | Most recent IF: 8.643 | ||
Call Number | EMAT @ emat @c:irua:179856 | Serial ![]() |
6804 | ||
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Author | Albrecht, W.; Arslan Irmak, E.; Altantzis, T.; Pedrazo‐Tardajos, A.; Skorikov, A.; Deng, T.‐S.; van der Hoeven, J.E.S.; van Blaaderen, A.; Van Aert, S.; Bals, S. | ||||
Title | 3D Atomic‐Scale Dynamics of Laser‐Light‐Induced Restructuring of Nanoparticles Unraveled by Electron Tomography | Type | A1 Journal article | ||
Year | 2021 | Publication | Advanced Materials | Abbreviated Journal | Adv Mater |
Volume | Issue | Pages | 2100972 | ||
Keywords | A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT); Applied Electrochemistry & Catalysis (ELCAT) | ||||
Abstract | Understanding light–matter interactions in nanomaterials is crucial for optoelectronic, photonic, and plasmonic applications. Specifically, metal nanoparticles (NPs) strongly interact with light and can undergo shape transformations, fragmentation and ablation upon (pulsed) laser excitation. Despite being vital for technological applications, experimental insight into the underlying atomistic processes is still lacking due to the complexity of such measurements. Herein, atomic resolution electron tomography is performed on the same mesoporous-silica-coated gold nanorod, before and after femtosecond laser irradiation, to assess the missing information. Combined with molecular dynamics (MD) simulations based on the experimentally determined 3D atomic-scale morphology, the complex atomistic rearrangements, causing shape deformations and defect generation, are unraveled. These rearrangements are simultaneously driven by surface diffusion, facet restructuring, and strain formation, and are influenced by subtleties in the atomic distribution at the surface. |
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Publisher | Place of Publication | Editor | |||
Language | Wos | 000671662000001 | Publication Date | 2021-07-11 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0935-9648 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 19.791 | Times cited | 8 | Open Access | OpenAccess |
Notes | W.A. and E.A.I. contributed equally to this work. The authors acknowledge funding from the European Research Council under the European Union’s Horizon 2020 research and innovation program (ERC Consolidator Grants No. 815128 – REALNANO and No. 770887 – PICOMETRICS), the European Union’s Seventh Framework Programme (ERC Advanced Grant No. 291667 – HierarSACol), and the European Commission (EUSMI). W.A. acknowledges an Individual Fellowship funded by the Marie Sklodowska-Curie Actions (MSCA) in the Horizon2020 program (Grant 797153, SOPMEN). T.-S.D. acknowledges financial support from the National Science Foundation of China (NSFC, Grant No. 61905056). The authors also acknowledge financial support by the Research Foundation Flanders (FWO Grant G.0267.18N).; sygmaSB | Approved | Most recent IF: 19.791 | ||
Call Number | EMAT @ emat @c:irua:179781 | Serial ![]() |
6805 | ||
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Author | Windels, S.; Diefenhardt, T.; Jain, N.; Marquez, C.; Bals, S.; Schlummer, M.; De Vos, D.E. | ||||
Title | Catalytic upcycling of PVC waste-derived phthalate esters into safe, hydrogenated plasticizers | Type | A1 Journal article | ||
Year | 2022 | Publication | Green chemistry : cutting-edge research for a greener sustainable future | Abbreviated Journal | Green Chem |
Volume | 24 | Issue | 2 | Pages | 754-766 |
Keywords | A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) | ||||
Abstract | Recycling of end-of-life polyvinyl chloride (PVC) calls for solutions to deal with the vast amounts of harmful phthalate plasticizers that have historically been incorporated in PVC. Here, we report on the upcycling of such waste-extracted phthalate esters into analogues of the much safer diisononyl 1,2-cyclohexanedicarboxylate plasticizer (DINCH), via a catalytic one-pot (trans)esterification-hydrogenation process. For most of the virgin phthalates, Ru/Al2O3 is a highly effective hydrogenation catalyst, yielding >99% ring-hydrogenated products under mild reaction conditions (0.1 mol% Ru, 80 degrees C, 50 bar H-2). However, applying this reaction to PVC-extracted phthalates proved problematic, (1) as benzyl phthalates are hydrogenolyzed to benzoic acids that inhibit the Ru-catalyst, and (2) because impurities in the plasticizer extract (PVC, sulfur) further retard the hydrogenation. These complications were solved by coupling the hydrogenation to an in situ (trans)esterification with a higher alcohol, and by pretreating the extract with an activated carbon adsorbent. In this way, a real phthalate extract obtained from post-consumer PVC waste was eventually completely (>99%) hydrogenated to phthalate-free, cycloaliphatic plasticizers. | ||||
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Corporate Author | Thesis | ||||
Publisher | Place of Publication | Editor | |||
Language | Wos | 000726865200001 | Publication Date | 2021-11-30 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 1463-9262; 1463-9270 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 9.8 | Times cited | 8 | Open Access | Not_Open_Access |
Notes | This project has received funding from the European Union’s Horizon 2020 Research and Innovation Programme under grant agreement no. 821366 (programma acronym: Circular Flooring). D. E. D. V. thanks FWO for project funding (SBO project S001819N Triple Cycle); N. J. and S. B. acknowledge the financial support from FWO and FNRS (EOS 30489208). Finally, the authors also thank S. Smolders for assistance with the TGA-MS experiments and D. Paredaens for his experimental contribution | Approved | Most recent IF: 9.8 | ||
Call Number | UA @ admin @ c:irua:184746 | Serial ![]() |
6958 | ||
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Author | Petrov, M.; Bekaert, J.; Milošević, M.V. | ||||
Title | Superconductivity in gallenene | Type | A1 Journal article | ||
Year | 2021 | Publication | 2d Materials | Abbreviated Journal | 2D Mater |
Volume | 8 | Issue | 3 | Pages | 035056 |
Keywords | A1 Journal article; Condensed Matter Theory (CMT) | ||||
Abstract | Among the large variety of two-dimensional (2D) materials discovered to date, elemental monolayers that host superconductivity are very rare. Using ab initio calculations we show that recently synthesized gallium monolayers, coined gallenene, are intrinsically superconducting through electron-phonon coupling. We reveal that Ga-100 gallenene, a planar monolayer isostructural with graphene, is the structurally simplest 2D superconductor to date, furthermore hosting topological edge states due to its honeycomb structure. Our anisotropic Eliashberg calculations show distinctly three-gap superconductivity in Ga-100, in contrast to the alternative buckled Ga-010 gallenene which presents a single anisotropic superconducting gap. Strikingly, the critical temperature (T ( c )) of gallenene is in the range of 7-10 K, exceeding the T ( c ) of bulk gallium from which it is exfoliated. Finally we explore chemical functionalization of gallenene with hydrogen, and report induced multigap superconductivity with an enhanced T ( c ) in the resulting gallenane compound. | ||||
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Corporate Author | Thesis | ||||
Publisher | Place of Publication | Editor | |||
Language | Wos | 000667458500001 | Publication Date | 2021-06-01 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 2053-1583 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 6.937 | Times cited | 8 | Open Access | OpenAccess |
Notes | Approved | Most recent IF: 6.937 | |||
Call Number | UA @ admin @ c:irua:179623 | Serial ![]() |
7025 | ||
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Author | Pedrazo-Tardajos, A.; Arslan Irmak, E.; Kumar, V.; Sánchez-Iglesias, A.; Chen, Q.; Wirix, M.; Freitag, B.; Albrecht, W.; Van Aert, S.; Liz-Marzán, L.M.; Bals, S. | ||||
Title | Thermal Activation of Gold Atom Diffusion in Au@Pt Nanorods | Type | A1 Journal article | ||
Year | 2022 | Publication | ACS nano | Abbreviated Journal | Acs Nano |
Volume | Issue | Pages | |||
Keywords | A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) | ||||
Abstract | Understanding the thermal stability of bimetallic nanoparticles is of vital importance to preserve their functionalities during their use in a variety of applications. In contrast to well-studied bimetallic systems such as Au@Ag, heat-induced morphological and compositional changes in Au@Pt nanoparticles are insufficiently understood, even though Au@Pt is an important material for catalysis. To investigate the thermal instability of Au@Pt nanorods at temperatures below their bulk melting point, we combined in situ heating with two- and three-dimensional electron microscopy techniques, including three-dimensional energy-dispersive X-ray spectroscopy. The experimental results were used as input for molecular dynamics simulations, to unravel the mechanisms behind the morphological transformation of Au@Pt core–shell nanorods. We conclude that thermal stability is influenced not only by the degree of coverage of Pt on Au but also by structural details of the Pt shell. | ||||
Address | |||||
Corporate Author | Thesis | ||||
Publisher | Place of Publication | Editor | |||
Language | Wos | 000819246800001 | Publication Date | 2022-06-10 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 1936-0851 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 17.1 | Times cited | 8 | Open Access | OpenAccess |
Notes | S.B., S.V.A., L.M.L.-M. and A.P.-T. acknowledge financial support from the European Commission under the Horizon 2020 Programme by grant nos. 731019 (EUSMI) and 823717 (ESTEEM3) and ERC Consolidator grant nos. 815128 (REALNANO) and 770887 (PICOMETRICS). L.M.L.-M. acknowledges funding from MCIN/AEI/10.13039/501100011033 through grants no. PID2020-117779RB-I00 and Maria de Maeztu Unit of Excellence no. MDM-2017-0720. The authors acknowledge the resources and services used for the simulations in this work were provided by the VSC (Flemish Supercomputer Center), funded by the Research Foundation – Flanders (FWO) and the Flemish Government.; esteem3reported; esteem3JRA | Approved | Most recent IF: 17.1 | ||
Call Number | EMAT @ emat @c:irua:188540 | Serial ![]() |
7072 | ||
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Author | Yao, Y.; Ugras, T.J.; Meyer, T.; Dykes, M.; Wang, D.; Arbe, A.; Bals, S.; Kahr, B.; Robinson, R.D. | ||||
Title | Extracting pure circular dichroism from hierarchically structured CdS magic cluster films | Type | A1 Journal article | ||
Year | 2022 | Publication | ACS nano | Abbreviated Journal | Acs Nano |
Volume | 16 | Issue | 12 | Pages | 20457-20469 |
Keywords | A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) | ||||
Abstract | Chiroptically active, hierarchically structured materials are difficult to accurately characterize due to linear anisotropic contributions (i.e., linear dichroism (LD) and linear birefringence (LB)) and parasitic ellipticities that produce artifactual circular dichroism (CD) signals, in addition to chiral analyte contributions ranging from molecular-scale clusters to micron-sized assemblies. Recently, we have shown that CdS magic-sized clusters (MSC) can self-assemble into ordered films that have a hierarchical structure spanning seven orders of length-scale. These films have a strong CD response, but the chiral origins are obfuscated by the hierarchical architecture and LDLB contributions. Here, we derive and demonstrate a method for extracting the “pure” CD signal (CD generated by structural dissymmetry) from hierarchical MSC films and identified the chiral origin. The theory behind the method is derived using Mueller matrix and Stokes vector conventions and verified experimentally before being applied to hierarchical MSC and nanoparticle films with varying macroscopic orderings. Each film's extracted “true CD” shares a bisignate profile aligned with the exciton peak, indicating the assemblies adopt a chiral arrangement and form an exciton coupled system. Interestingly, the linearly aligned MSC film possesses one of the highest g-factors (0.05) among semiconducting nanostructures reported. Additionally, we find that films with similar electronic transition dipole alignment can possess greatly different g-factors, indicating chirality change rather than anisotropy is the cause of the difference in the CD signal. The difference in g-factor is controllable via film evaporation geometry. This study provides a simple means to measure “true” CD and presents an example of experimentally understanding chiroptic interactions in hierarchical nanostructures. | ||||
Address | |||||
Corporate Author | Thesis | ||||
Publisher | Place of Publication | Editor | |||
Language | Wos | 000888219600001 | Publication Date | 2022-11-17 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 1936-0851 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 17.1 | Times cited | 8 | Open Access | Not_Open_Access |
Notes | This work was supported in part by the National Science Foundation (NSF) under Award Nos. DMR-2003431 and CHE-2003586. This work made use of the Cornell Center for Materials Research Shared Facilities, which are supported through the NSF MRSEC program (DMR-1719875). This work is partly supported by Grant PID2021-123438NB-I00 (MCIN/AEI/10.13039/501100011033 and “ERDF vA way of making Europe”) and Grant IT1566-22 (Eusko Jaurlaritza). D.W. acknowledges an Individual Fellowship funded by the Marie Sklodowska-Curie Actions (MSCA) in the Horizon 2020 program (Grant 894254 SuprAtom). S.B. acknowledges financial support from ERC Consolidator Grant No. 815128 REALNANO. B.K. acknowledges NSF award DMR-2003968. We would like to thank Dr. Mark August Pfeifer for help with circular dichroism measurements. Additionally, we would like to thank Professor Luis M. Liz-Marzan for invaluable discussions on chirality. | Approved | Most recent IF: 17.1 | ||
Call Number | UA @ admin @ c:irua:192070 | Serial ![]() |
7305 | ||
Permanent link to this record |