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Author van Malderen, H.; Hoornaert, S.; Injuk, J.; Przybylowicz, W.J.; Pineda, C.A.; Prozesky, V.M.; Van Grieken, R. doi  openurl
  Title Individual particle characterization of Siberian aerosols by micro-PIXE and backscattering spectrometry Type A1 Journal article
  Year 2001 Publication X-ray spectrometry Abbreviated Journal  
  Volume 30 Issue Pages 320-329  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000171234700008 Publication Date 2002-08-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:36084 Serial 8080  
Permanent link to this record
 

 
Author Van Dyck, P.; Markowicz, A.; Van Grieken, R. doi  openurl
  Title Influence of sample thickness, excitation energy and geometry on particle size effects in XRF Type A1 Journal article
  Year 1985 Publication X-ray spectrometry Abbreviated Journal  
  Volume 14 Issue 4 Pages 183-187  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Expressions are presented for calculating the matrix effect and the pure particle size effect in the XRF analysis of particulate samples with a discrete particle size. The equations are based on the absorption-weighted radiometric diameter concept. Two excitationdetection geometries are considered, with the angles between the sample plane and both the incident and emerging radiation being either 90° (π geometry) or 45° (π/2 geometry). Calculations were made for different sample loadings and exciting radiation energies. The influence of these parameters on the matrix and pure particle size effects is shown. From the results, it is possible to predict the performances of alternative experimental correction procedures for the particle size effect, involving dual measurements at different excitation energies or in different excitationdetection geometries.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1985ATB6100007 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116486 Serial 8097  
Permanent link to this record
 

 
Author Van Grieken, R. doi  openurl
  Title Introducing four new members of the editorial board of X-ray spectrometry Type Editorial
  Year 2015 Publication X-ray spectrometry Abbreviated Journal  
  Volume 44 Issue 1 Pages 1-2  
  Keywords Editorial; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000346727300001 Publication Date 2014-12-22  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:123608 Serial 8119  
Permanent link to this record
 

 
Author Van Grieken, R. doi  openurl
  Title Introducing John Campbell, the new regional editor for North America of X-Ray Spectrometry Type Editorial
  Year 2014 Publication X-ray spectrometry Abbreviated Journal  
  Volume 43 Issue 2 Pages 67  
  Keywords Editorial; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000331386000001 Publication Date 2014-02-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:114470 Serial 8120  
Permanent link to this record
 

 
Author Ozen, S.A.; Ozkalayci, F.; Cevik, U.; Van Grieken, R. pdf  doi
openurl 
  Title Investigation of heavy metal distributions along 15m soil profiles using EDXRF, XRD, SEM-EDX, and ICP-MS techniques Type A1 Journal article
  Year 2018 Publication X-ray spectrometry Abbreviated Journal  
  Volume 47 Issue 3 Pages 231-241  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The research of soil contamination by heavy metal is an important field due to its environmental and health implications. The goal was to study the elemental mobility as a function of depth. For this reason, the distribution of heavy metals (V, Cr, Co, Ni, Cu, Zn, As, Sn, and Pb) was investigated along soil profiles up to a depth of 15m at 9 sampling sites in the Nilufer industrial district (Bursa, Turkey). Elemental analyses were done with the Epsilon 5 energy dispersive X-ray fluorescence and inductively coupled plasma mass spectrometry equipment. Particle analysis was performed with a JEOL scanning electron microscope equipped with a Si(Li) X-ray detector. The crystallographic compositions of oxide compounds in soil samples were identified by a Rigaku X-ray diffraction instrument. Different parameters such as the soil's chemical (mineralogical structure, pH, and electrical conductivity) and physical properties (the number of blows, the stiffness index, the liquidity index, the plasticity index, and the water content) were analyzed. To assess the mobility of the heavy metals, diffusion (D) and convection coefficients (?) were calculated with the finite difference method. Convection was determined to dominate the studied region. In addition, the mobility coefficient was determined for each metal. High mobilities were determined for Zn and V, moderate mobilities for Cr, Ni, Cu, and As, and low mobilities were determined for Co and Pb. The results revealed that elements had reached depths of up to 15m, causing irreversible soil contamination that may lead to environmental health issues.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000430188700005 Publication Date 2018-03-09  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:150722 Serial 8123  
Permanent link to this record
 

 
Author Injuk, J.; Van Grieken, R. doi  openurl
  Title Literature trends in x-ray emission spectrometry in the period 1990-2000: a review Type A1 Journal article
  Year 2003 Publication X-ray spectrometry Abbreviated Journal  
  Volume 32 Issue Pages 35-39  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000180811200006 Publication Date 2005-01-19  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:40614 Serial 8175  
Permanent link to this record
 

 
Author Van Dyck, P.; Török, S.; Van Grieken, R. doi  openurl
  Title Monte Carlo simulation of backscattered peaks in secondary target energy-dispersive X-ray spectra Type A1 Journal article
  Year 1986 Publication X-ray spectrometry Abbreviated Journal  
  Volume 15 Issue 4 Pages 231-238  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A Monte Carlo simulation has been developed to describe the incoherent and coherent scatter processes for the complex geometry of a secondary target energy-dispersive x-ray fluorescence system. Photons are followed from the x-ray tube anode until the detection of scattered secondary target photons in the active Si layer of the detector. The program quantitatively shows the broadening of the incoherent scatter peak with increasing atomic number, and it models the incoherent peak shape adequately. The incoherent-to-coherent scatter intensity ratios obtained differ by 1030% from the theoretical values, while their dependence on the sample atomic number corresponds to that expected from theory.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986E535600001 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113612 Serial 8280  
Permanent link to this record
 

 
Author Van Grieken, R. openurl 
  Title New Chinese members of the Advisory Board of X-Ray Spectrometry Type A1 Journal article
  Year 2006 Publication X-ray spectrometry Abbreviated Journal  
  Volume 35 Issue 4 Pages 205-206  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:58861 Serial 8297  
Permanent link to this record
 

 
Author Romero-Pastor, J.; Garcia-Porras, A.; Van Grieken, R.; Potgieter-Vermaak, S.; Coll-Conesa, J.; Cardell, C. pdf  doi
openurl 
  Title New insights in technology characterization of medieval Valencia glazes Type A1 Journal article
  Year 2015 Publication X-ray spectrometry Abbreviated Journal  
  Volume 44 Issue 6 Pages 426-435  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract This study shows the first Raman microscopy (RM) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX) characterization of two 14th and 15th century lead-glazed and luster ceramics from the Manises and Paterna workshops (Valencia, Spain) produced after the Aragon Christian conquest of the Iberian Peninsula (14th century). According to experts, these coetaneous ceramics were most probably involved in a process of technological transfer from the Islamic area of Southeast Spain to the Christian area of Valencia (East Spain) at the beginning of the 14th century; later on, the celebrated Manises and Paterna workshops were formed. Although these ceramics have been studied widely in terms of production technology (ceramic body, glazes and luster) using an array of diverse analytical techniques, until now, an RM study has not been carried out. This paper presents results regarding the complex chemical composition of the glaze and luster coloring agents, and the quality of color manufacturing processes, elucidating firing conditions via spectral components analysis (i.e., Q(n) for stretching/bending components) and polymerization index (Ip), emphasizing chronology and pigment technology changes between both Valencian workshops. Coloring agents identified in glazes and lusters were cobalt present in blue glazes, copper in greenish glazes, copper and cobalt in the turquoise glaze, and pyrolusite in black glazes. Tin oxyde was used as an opacifier in white glazes. Two luster manufacture recipes were recognized mainly based on copper and silver compounds. Calculated firing temperatures were up to 1000 degrees C for white glazes and up to 600 degrees C for luster and color glazes. Copyright (c) 2015 John Wiley & Sons, Ltd.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000363279600002 Publication Date 2015-03-12  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:129445 Serial 8300  
Permanent link to this record
 

 
Author Van Grieken, R. pdf  doi
openurl 
  Title New members of the editorial board of X-ray Spectrometry Type A1 Journal article
  Year 2013 Publication X-ray spectrometry Abbreviated Journal  
  Volume 42 Issue 1 Pages 1-2  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000314971600001 Publication Date 2012-12-22  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:104627 Serial 8301  
Permanent link to this record
 

 
Author Szalóki, I.; Osán, J.; Worobiec, A.; de Hoog, J.; Van Grieken, R. doi  openurl
  Title Optimization of experimental conditions of thin-window EPMA for ligh-element analysis of individual environmental particles Type A1 Journal article
  Year 2001 Publication X-ray spectrometry Abbreviated Journal  
  Volume 30 Issue Pages 143-155  
  Keywords A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000169194800003 Publication Date 2005-01-24  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:34102 Serial 8338  
Permanent link to this record
 

 
Author Arana, A.; Loureiro, A.L.; Barbosa, H.M.J.; Van Grieken, R.; Artaxo, P. pdf  doi
openurl 
  Title Optimized energy dispersive X-ray fluorescence analysis of atmospheric aerosols collected at pristine and perturbed Amazon Basin sites Type A1 Journal article
  Year 2014 Publication X-ray spectrometry Abbreviated Journal  
  Volume 43 Issue 4 Pages 228-237  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Elemental composition of aerosols is important to source apportionment studies and to understand atmospheric processes that influence aerosol composition. Energy dispersive X-ray fluorescence spectroscopy was applied for measuring the elemental composition of Amazonian atmospheric aerosols. The instrument used was a spectrometer Epsilon 5, PANalytical B. V., with tridimensional geometry that reduces the background signal with a polarized X-ray detection. The measurement conditions were optimized for low-Z elements, e. g. Mg, Al, Si, that are present at very low concentrations in the Amazon. From Na to K, our detection limits are about 50% to 75% lower than previously published results for similar instrument. Calibration was performed using Micromatter standards, except for P whose standard was produced by nebulization of an aqueous solution of KH2PO4 at our laboratory. The multi-element reference material National Institute of Standards and Technology-2783 (air particulate filter) was used for evaluating the accuracy of the calibration procedure of the 22 elements in our standard analysis routine, and the uncertainty associated with calibration procedures was evaluated. The overall performance of the instrument and validation of our measurements were assessed by comparison with results obtained from parallel analysis using particle-induced X-ray emission and another Epsilon 5 spectrometer. The elemental composition in 660 samples collected at a pristine site in the Amazon Basin and of 1416 samples collected at a site perturbed by land use change was determined. Our measurements show trace elements associated with biogenic aerosols, soil dust, biomass burning, and sea-salt, even for the very low concentrations as observed in Amazonia. Copyright (C) 2014 John Wiley & Sons, Ltd.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000337724600006 Publication Date 2014-06-09  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:118419 Serial 8342  
Permanent link to this record
 

 
Author Samek, L.; Injuk, J.; van Espen, P.; Van Grieken, R. doi  openurl
  Title Performance of a new compact EDXRF spectrometer for aerosol analysis Type A1 Journal article
  Year 2002 Publication X-ray spectrometry Abbreviated Journal  
  Volume 31 Issue Pages 84-86  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000173653400015 Publication Date 2002-10-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:36383 Serial 8371  
Permanent link to this record
 

 
Author Claes, M.; de Bokx, P.; Van Grieken, R. doi  openurl
  Title Progress in laboratory grazing emission X-ray fluorescence spectrometry Type A1 Journal article
  Year 1999 Publication X-ray spectrometry Abbreviated Journal  
  Volume 28 Issue Pages 224-229  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000081693400004 Publication Date 2005-12-05  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:24715 Serial 8423  
Permanent link to this record
 

 
Author Markowicz, A.; Van Dyck, P.; Van Grieken, R. doi  openurl
  Title Radiometric diameter concept and exact intensities for spherical particles in x-ray fluorescence analysis Type A1 Journal article
  Year 1980 Publication X-ray spectrometry Abbreviated Journal  
  Volume 9 Issue 2 Pages 52-56  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract In X-ray fluorescence analysis the concept of radiometric diameter, d, is often introduced in considerations of the fluorescent intensity from a particulate sample. It represents the mean geometric path of the X-rays through one particle and is usually simply taken to be equal to the volume-to-area ratio of the particle. The effective radiometric path is, however, itself dependent on geometry and absorption effects. Rigorous calculations of the fluorescent intensity from a particle in the π and π/2 geometries were carried out to evaluate the errors involved. It appears that, for π geometry, the discrepancy between these exact results and the intensity calculated via the use of d does not exceed 5.2%. For the π/2 geometry, the errors are much larger and can amount to 50% in realistic cases of X-ray fluorescence analysis. These conclusions are also applicable to monolayers. The effective radiometric diameter approaches d only when absorption effects become negligible, but is smaller in other cases.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1980JN16500003 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116482 Serial 8451  
Permanent link to this record
 

 
Author Worobiec, A.; Kaplinski, A.; Van Grieken, R. doi  openurl
  Title Ruthenium staining as an alternative preparation method for automated EPMA of individual biogenic and organic particles Type A1 Journal article
  Year 2005 Publication X-ray spectrometry Abbreviated Journal  
  Volume 34 Issue 3 Pages 245-252  
  Keywords A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000229093000014 Publication Date 2005-01-31  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:52229 Serial 8488  
Permanent link to this record
 

 
Author Markowicz, A.; Storms, H.; Van Grieken, R. doi  openurl
  Title A simple absorption correction for electron probe X-ray microanalysis of bulk samples Type A1 Journal article
  Year 1986 Publication X-ray spectrometry Abbreviated Journal  
  Volume 15 Issue 2 Pages 115-119  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A simple procedure is proposed for the calculation of the absorption correction factor in electron-probe x-ray microanalysis. It is based on the concept of an effective depth of x-ray production, assuming a rectangular depth distribution function for x-ray generation. This effective x-ray production depth is expressed as a fraction of the x-ray excitation depth given by Whelan's expression. Adequate values for this fraction are presented. Two versions are considered. In the first the effective x-ray production is a function of both the characteristic x-ray energy and the atomic numbers of the matrix elements, whereas in the second one, which is indicated for routine use, the energy dependence is neglected. Calculations pointed to satisfactory results, even for low x-ray energies and high overvoltages.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986C017300007 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113872 Serial 8524  
Permanent link to this record
 

 
Author Samek, L.; Ostachowicz, B.; Worobiec, A.; Spolnik, Z.; Van Grieken, R. doi  openurl
  Title Speciation of selected metals in aerosol samples by TXRF after sequential leaching Type A1 Journal article
  Year 2006 Publication X-ray spectrometry Abbreviated Journal  
  Volume 35 Issue 4 Pages 226-231  
  Keywords A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000239321500004 Publication Date 2006-06-29  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:58901 Serial 8572  
Permanent link to this record
 

 
Author Trincavelli, J.; Montoro, S.; van Espen, P.; Van Grieken, R. doi  openurl
  Title M\alpha/L\alpha intensity ratios for Ta, W, Pt, Au, Pb and Bi for electron energies in the 11-40 keV range Type A1 Journal article
  Year 1993 Publication X-ray spectrometry Abbreviated Journal  
  Volume 22 Issue Pages 372-376  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract Both energy- and wavelength-dispersive systems were used to obtain Malpha/Lalpha intensity ratios for Ta, W, Pt, Au, Pb and Bi at various overvoltages. A table of these ratios corrected for matrix absorption and detector efficiency is presented, in addition to an interpolatory function of Malpha/Lalpha generated ratios vs. overvoltage, for each element. In addition, three different ZAF correction models were used to predict both detected and generated ratios. Finally, experimental Mbeta/Malpha ratios measured at different overvoltages are presented for the six elements considered.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1993MB01200008 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:6221 Serial 8649  
Permanent link to this record
 

 
Author Muia, L.M.; Van Grieken, R. doi  openurl
  Title Theoretical evaluation of the effective alpha and De Jongh approaches in X-ray fluorescence analysis of geological materials in borax glass beads Type A1 Journal article
  Year 1989 Publication X-ray spectrometry Abbreviated Journal  
  Volume 18 Issue 6 Pages 259-262  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract An evaluation of the accuracy and suitability of the LachanceTraill algorithm using effective α-coefficients, and the De Jongh α approach for x-ray fluorescence analysis of borax glass beads prepared from geological material was performed. By using theoretical α-coefficients obtained from the same standard and calculated elemental intensities, the two algorithms were compared under identical conditions. When only the monitor standard is used, the LachanceTrail1 approach is found to be inferior to the De Jongh basic α method. If multi-standard calibration is performed for both approaches, the accuracies are almost identical and no significant difference is found in the results. The LachanceTraill algorithm has the advantage of being easier to implement on a minicomputer and, when used without standards, it is found to give results within a few percent of the true values, which is a useful indicator in the choice of appropriate standards for more accurate analytical work.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1989CE70800002 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116490 Serial 8660  
Permanent link to this record
 

 
Author Sauter, L.; Van der Ben, D.; Van Grieken, R. doi  openurl
  Title Trace analysis of estuarine brown algae by energy-dispersive X-ray fluorescence Type A1 Journal article
  Year 1979 Publication X-ray spectrometry Abbreviated Journal  
  Volume 8 Issue 4 Pages 159-163  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Brown algae, which are good indicators for estuarine metal pollution, can advantageously be analysed by energy-dispersive X-ray fluorescence. The use of thin film samples and samples of intermediate thickness has several advantages over the conventional thick pellet procedure. A quite homogeneous thin target is prepared by suspending 15 mg of dried and ground seaweed powder in bi-distilled water and evaporating the slurry on a 10 cm2 Mylar foil held in a Teflon ring. The effective sample weight in the beam is calculated by a procedure based on the scatter peaks in the spectrum. Sensitivities are typically in the 215 ppm range. The coefficient of variation per analysis averaged over ten elements amounts to 10%. The natural concentration variation in seaweed specimens at one location is 13%. Samples from locations in the more polluted western Scheldt estuary yield significantly higher values for several elements, relative to the eastern Scheldt sites. Possible trace element variations between the top and base of plants, and between different seaweed specimens and sampling seasons, are discussed.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1979JC63700003 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116481 Serial 8687  
Permanent link to this record
 

 
Author Muia, L.M.; Van Grieken, R. doi  openurl
  Title Use of theoretical accurate binary influence coefficients with Tertian's equation in X-ray fluorescence analysis of silicate rocks in borax glass beads Type A1 Journal article
  Year 1990 Publication X-ray spectrometry Abbreviated Journal  
  Volume 19 Issue 3 Pages 141-144  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A study of the suitability of the Tertian algorithm using new accurate binary influence coefficients and a comparison standard for x-ray fluorescence analysis of geological materials prepared as borax glass beads was performed. The algorithm was found to give satisfactory results for the analysis of four major components in geological materials. Even in the worst case, when there is a factor of 20 difference in the concentration in the specimen and a comparison standard, the algorithm gives results which differ from the true results by a factor of about 2. This makes the algorithm attractive as a diagnostic tool in analyses of unknown specimens and in the identification of appropriate standards. The binary coefficients are easily calculated so that the algorithm can be implemented on a minicomputer.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1990DJ47800009 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116492 Serial 8725  
Permanent link to this record
 

 
Author Cagno, S.; van der Snickt, G.; Legrand, S.; Caen, J.; Patin, M.; Meulebroeck, W.; Dirkx, Y.; Hillen, M.; Steenackers, G.; Rousaki, A.; Vandenabeele, P.; Janssens, K. url  doi
openurl 
  Title Comparison of four mobile, non‐invasive diagnostic techniques for differentiating glass types in historical leaded windows : MA‐XRF , UV–Vis–NIR, Raman spectroscopy and IRT Type A1 Journal article
  Year 2020 Publication X-Ray Spectrometry Abbreviated Journal X-Ray Spectrom  
  Volume Issue Pages xrs.3185-17  
  Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)  
  Abstract This paper critically compares the performance of four non-invasive techniques that match the accuracy, flexibility, time-efficiency, and transportability required for in situ characterization of leaded glass windows: macroscopic X-ray fluorescence imaging (MA-XRF), UV-Vis-NIR, Raman spectroscopy, and infrared thermography (IRT). In order to compare the techniques on equal grounds, all techniques were tested independently of each other by separate research groups on the same historical leaded window tentatively dated to the 17th century, without prior knowledge. The aim was to assess the ability of these techniques to document the conservation history of the window by classifying and grouping the colorless glass panes, based on differences in composition. IRT, MA-XRF and UV-Vis-NIR spectroscopy positively distinguished at least two glass groups, with MA-XRF providing the most detailed chemical information. In particular, based on the ratio between the network modifier (K) and network stabilizer (Ca) and on the level of colorants and decolorizers (Fe, Mn, As), the number of plausible glass families could be strongly reduced. In addition, UV-Vis-NIR detected cobalt at ppm level and gave more specific information on the chromophore Fe2+/Fe(3+)ratio. Raman spectroscopy was hampered by fluorescence caused by the metal ions of the decolorizer in most of the panes, but nevertheless identified one group as HLLA.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000561869600001 Publication Date 2020-08-24  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) 1.2 Times cited Open Access  
  Notes ; Belgian Federal Science Policy Office, Grant/Award Number: BR/175/A3/FENESTRA; Fonds Wetenschappelijk Onderzoek, Grant/Award Number: 12X1919N; Baillet-Latour Fund ; Approved Most recent IF: 1.2; 2020 IF: 1.298  
  Call Number UA @ admin @ c:irua:170972 Serial 6473  
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Author Asfora, V.K.; Bueno, C.C.; de Barros, V.M.; Khoury, H.; Van Grieken, R. pdf  doi
openurl 
  Title X-ray spectrometry applied for characterization of bricks of Brazilian historical sites Type A1 Journal article
  Year 2020 Publication X-Ray Spectrometry Abbreviated Journal X-Ray Spectrom  
  Volume Issue Pages 1-8  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract This paper presents the results of X-ray fluorescence (XRF) analysis of bricks sampled from historical places in Pernambuco, a state in the northeastern region of Brazil. In this study, twenty bricks found in historical sites were analyzed. Two bricks made in the 17th century, presumably used as ballast in ships coming from Holland, five locally manufactured bricks: one from 18th century, three from 19th century, and one from 20th century, and thirteen bricks collected from a recent Archeological investigation of Alto da Se, in the town of Olinda. Qualitative determination of the chemical elements present in the samples was undertaken using a self-assembled portable XRF system based on a compact X-ray tube and a thermoelectrically cooled Si-PIN photodiode system, both commercially available. X-ray diffraction analysis was also carried out to assess the crystalline mineral phases present in the bricks. The results showed that quartz (SiO2) is the major mineral content in all bricks. Although less expressive in the XRD patterns, mineral phases of illite, kaolinite, anorthite, and rutile are also identified. The trace element distribution patterns of the bricks, determined by the XRF technique, is dominated by Fe and, in decreasing order, by K, Ti, Ca, Mn, Zr, Rb, Sr, Cr, and Y with slight differences among them. Analyses of the chemical compositional features of the bricks, evaluated by principal component analysis of the XRF datasets, allowed the samples to be grouped into five clusters with similar chemical composition. These cluster groups were able to identify both age and manufacturing sites. Dutch bricks prepared with different geological clays compositions were defined.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000568830300001 Publication Date 2020-09-17  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record  
  Impact Factor (up) 1.2 Times cited Open Access  
  Notes ; The authors are grateful to CNPQ (Process: 305903/2011-0 and 407458/2013-1) for providing funds to carry out the present work and for supporting a visitor professor to UFPE through the program science without frontier. The authors also thank Mr. Roberto Araujo from the Center of Advanced Studies on Integrated Environmental Protection-CECI that made available the bricks to be analyzed. ; Approved Most recent IF: 1.2; 2020 IF: 1.298  
  Call Number UA @ admin @ c:irua:171960 Serial 6654  
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Author Janssens, K. pdf  doi
openurl 
  Title EXRS2022 : the 2022 edition of the European X-ray Spectrometry conference, held in Bruges, Belgium Type Editorial
  Year 2023 Publication X-ray spectrometry Abbreviated Journal  
  Volume 52 Issue 6 Pages 276-278  
  Keywords Editorial; Antwerp X-ray Imaging and Spectroscopy (AXIS)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 001043528400001 Publication Date 2023-08-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record  
  Impact Factor (up) 1.2 Times cited Open Access Not_Open_Access  
  Notes Approved Most recent IF: 1.2; 2023 IF: 1.298  
  Call Number UA @ admin @ c:irua:198217 Serial 8865  
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Author Fredrickx, P.; de Ryck, I.; Janssens, K.; Schryvers, D.; Petit, J.-P.; Döcking, H. pdf  doi
openurl 
  Title EPMA and µ-SRXRF analysis and TEM-based microstructure characterization of a set of Roman glass fragments Type A1 Journal article
  Year 2004 Publication X-ray spectrometry Abbreviated Journal X-Ray Spectrom  
  Volume 33 Issue 5 Pages 326-333  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000223880800002 Publication Date 2004-04-01  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246;1097-4539; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) 1.298 Times cited 13 Open Access  
  Notes Approved Most recent IF: 1.298; 2004 IF: 1.391  
  Call Number UA @ lucian @ c:irua:48786 Serial 1076  
Permanent link to this record
 

 
Author Vekemans, B.; Janssens, K.; Vincze, L.; Aerts, A.; Adams, F.; Hertogen, J. openurl 
  Title Automated segmentation of μ-XRF image sets Type A1 Journal article
  Year 1997 Publication X-ray spectrometry Abbreviated Journal X-Ray Spectrom  
  Volume 26 Issue Pages 333-346  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1997YG79300005 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) 1.298 Times cited Open Access  
  Notes Approved Most recent IF: 1.298; 1997 IF: 1.307  
  Call Number UA @ admin @ c:irua:18319 Serial 5486  
Permanent link to this record
 

 
Author Proost, K.; Vincze, L.; Janssens, K.; Gao, N.; Bulska, E.; Schreiner, M.; Falkenberg, G. doi  openurl
  Title Characterization of a polycapillary lens for use in micro-XANES experiments Type A1 Journal article
  Year 2003 Publication X-ray spectrometry Abbreviated Journal X-Ray Spectrom  
  Volume 32 Issue 3 Pages 215-222  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000183630400007 Publication Date 2003-06-12  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) 1.298 Times cited 50 Open Access  
  Notes Approved Most recent IF: 1.298; 2003 IF: 1.227  
  Call Number UA @ admin @ c:irua:41804 Serial 5502  
Permanent link to this record
 

 
Author van der Linden, V.; Schalm, O.; Houbraken, J.; Thomas, M.; Meesdom, E.; Devos, A.; van Dooren, R.; Nieuwdorp, H.; Janssen, E.; Janssens, K. doi  openurl
  Title Chemical analysis of 16th to 19th century Limoges School painted enamel objects in three museums of the Low Countries Type A1 Journal article
  Year 2010 Publication X-ray spectrometry Abbreviated Journal X-Ray Spectrom  
  Volume 39 Issue 2 Pages 112-121  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract In this study, the results of analysing of a series of 16th-19th century painted enamel objects of the Limoges School currently in collections in three Dutch and Flemish museums by means of portable and micro x-ray fluorescence analysis (PXRF and µ-XRF) and electron probe micro analysis (EPMA) are presented. The aim of the investigation was the authentication of specific pieces. Therefore, the glass compositions as well as the (glass) colouring agents used by the Limoges' artists were studied as a function of the age of the objects. Due to the evolution of these properties, it is possible to approximately date these objects based on their chemical composition. The complete émail peint collection of the Museum Boijmans-Van Beuningen (Rotterdam, The Netherlands), consisting of 20 émail peint plaques, was analysed with µ-XRF. Quantitative information was obtained by EPMA analysis of 15 enamel fragments of objects from museum and private collections in the Low Countries. PXRF analyses were performed on the painted enamel collection of the Antwerp Vleeshuis Museum (13 objects) and the Mayer van den Bergh Museum (4 objects) and on a set of 18 plaques that were donated to the Boijmans-Van Beuningen Museum by a private collector. The results obtained by means of EPMA, µ-XRF and PXRF proved to be useful in the discrimination of 16th century painted enamel objects from those of the19th century. From a total of 70 objects examined, 2 objects (OM964A and OM993) featured a chemical signature that deviated from the published literature composition and pigment use consistent with its presumed period of manufacture.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000275959400007 Publication Date 2009-08-11  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) 1.298 Times cited 8 Open Access  
  Notes ; ; Approved Most recent IF: 1.298; 2010 IF: 1.661  
  Call Number UA @ admin @ c:irua:82325 Serial 5509  
Permanent link to this record
 

 
Author Bichlmeier, S.; Janssens, K.; Heckel, J.; Hoffmann, P.; Ortner, H.M. doi  openurl
  Title Comparative material characterization of historical and industrial samples by using a compact micro-XRF spectrometer Type A1 Journal article
  Year 2002 Publication X-ray spectrometry Abbreviated Journal X-Ray Spectrom  
  Volume 31 Issue 1 Pages 87-91  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000173653400016 Publication Date 2002-10-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor (up) 1.298 Times cited 12 Open Access  
  Notes Approved Most recent IF: 1.298; 2002 IF: 1.574  
  Call Number UA @ admin @ c:irua:36670 Serial 5529  
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