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Author Broos, W.; Wittner, N.; Dries, J.; Vlaeminck, S.E.; Gunde-Cimerman, N.; Cornet, I.
Title Rhodotorula kratochvilovae outperforms Cutaneotrichosporon oleaginosum in the valorisation of lignocellulosic wastewater to microbial oil Type A1 Journal article
Year 2024 Publication Process biochemistry (1991) Abbreviated Journal
Volume 137 Issue Pages 229-238
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL); Biochemical Wastewater Valorization & Engineering (BioWaVE)
Abstract Rhodotorula kratochvilovae has shown to be a promising species for microbial oil production from lignin-derived compounds. Yet, information on R. kratochvilovae’s detoxification and microbial oil production is scarce. This study investigated the growth and microbial oil production on the phenolic-containing effluent from poplar steam explosion and its detoxification with five R. kratochvilovae strains (EXF11626, EXF9590, EXF7516, EXF3697, EXF3471) and compared them with Cutaneotrichosporon oleaginosum. The R. kratochvilovae strains reached a maximum growth rate up to four times higher than C. oleaginosum. Furthermore, all R. kratochvilovae strains generally degraded phenolics more rapidly and to a larger extent than C. oleaginosum. However, the diluted substrate limited the lipid production by all strains as the maximum lipid content and titre were 10.5% CDW and 0.40 g/L, respectively. Therefore, future work should focus on increasing lipid production by using advanced fermentation strategies and stimulating the enzyme excretion by the yeasts for complex substrate breakdown.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos (down) Publication Date 2024-01-13
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1359-5113 ISBN Additional Links UA library record
Impact Factor 4.4 Times cited Open Access Not_Open_Access
Notes Approved Most recent IF: 4.4; 2024 IF: 2.497
Call Number UA @ admin @ c:irua:202365 Serial 9087
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Author De Meyer, R.; Gorbanev, Y.; Ciocarlan, R.-G.; Cool, P.; Bals, S.; Bogaerts, A.
Title Importance of plasma discharge characteristics in plasma catalysis: Dry reforming of methane vs. ammonia synthesis Type A1 Journal Article
Year 2024 Publication Chemical Engineering Journal Abbreviated Journal Chemical Engineering Journal
Volume 488 Issue Pages 150838
Keywords A1 Journal Article; Gas conversion Dry reforming of methane Ammonia Microdischarges Dielectric barrier discharge; Plasma, laser ablation and surface modeling Antwerp (PLASMANT) ;
Abstract Plasma catalysis is a rapidly growing field, often employing a packed-bed dielectric barrier discharge plasma reactor. Such dielectric barrier discharges are complex, especially when a packing material (e.g., a catalyst) is introduced in the discharge volume. Catalysts are known to affect the plasma discharge, though the underlying mechanisms influencing the plasma physics are not fully understood. Moreover, the effect of the catalysts on the plasma discharge and its subsequent effect on the overall performance is often overlooked. In this work, we deliberately design and synthesize catalysts to affect the plasma discharge in different ways. These Ni or Co alumina-based catalysts are used in plasma-catalytic dry reforming of methane and ammonia synthesis. Our work shows that introducing a metal to the dielectric packing can affect the plasma discharge, and that the distribution of the metal is crucial in this regard. Further, the altered discharge can greatly influence the overall performance. In an atmospheric pressure dielectric barrier discharge reactor, this apparently more uniform plasma yields a significantly better performance for ammonia synthesis compared to the more conventional filamentary discharge, while it underperforms in dry reforming of methane. This study stresses the importance of analyzing the plasma discharge in plasma catalysis experiments. We hope this work encourages a more critical view on the plasma discharge characteristics when studying various catalysts in a plasma reactor.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos (down) Publication Date 2024-03-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1385-8947 ISBN Additional Links UA library record
Impact Factor 15.1 Times cited Open Access
Notes This research was supported through long-term structural funding (Methusalem FFB15001C) and by the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme with grant agreement No 810182 (SCOPE ERC Synergy project) and with grant agreement No 815128 (REALNANO). We acknowledge the practical contribution of Senne Van Doorslaer. Approved Most recent IF: 15.1; 2024 IF: 6.216
Call Number PLASMANT @ plasmant @c:irua:205154 Serial 9115
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Author Pankratov, D.; Hidalgo Martinez, S.; Karman, C.; Gerzhik, A.; Gomila, G.; Trashin, S.; Boschker, H.T.S.; Geelhoed, J.S.; Mayer, D.; De Wael, K.; Meysman, F.J.R.
Title The organo-metal-like nature of long-range conduction in cable bacteria Type A1 Journal article
Year 2024 Publication Bioelectrochemistry: an international journal devoted to electrochemical aspects of biology and biological aspects of electrochemistry Abbreviated Journal
Volume 157 Issue Pages 108675-10
Keywords A1 Journal article
Abstract Cable bacteria are filamentous, multicellular microorganisms that display an exceptional form of biological electron transport across centimeter-scale distances. Currents are guided through a network of nickel-containing protein fibers within the cell envelope. Still, the mechanism of long-range conduction remains unresolved. Here, we characterize the conductance of the fiber network under dry and wet, physiologically relevant, conditions. Our data reveal that the fiber conductivity is high (median value: 27 S cm−1; range: 2 to 564 S cm−1), does not show any redox signature, has a low thermal activation energy (Ea = 69 ± 23 meV), and is not affected by humidity or the presence of ions. These features set the nickel-based conduction mechanism in cable bacteria apart from other known forms of biological electron transport. As such, conduction resembles that of an organic semi-metal with a high charge carrier density. Our observation that biochemistry can synthesize an organo-metal-like structure opens the way for novel bio-based electronic technologies.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos (down) Publication Date 2024-02-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1567-5394 ISBN Additional Links UA library record
Impact Factor 5 Times cited Open Access
Notes Approved Most recent IF: 5; 2024 IF: 3.346
Call Number UA @ admin @ c:irua:205117 Serial 9215
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Author Raes, A.; Minja, A.C.; Ag, K.R.; Verbruggen, S.W.
Title Recent advances in metal-doped defective TiO₂ for photocatalytic CO₂ conversion Type A1 Journal article
Year 2024 Publication Current Opinion in Chemical Engineering Abbreviated Journal
Volume 44 Issue Pages 101013-11
Keywords A1 Journal article; Engineering sciences. Technology
Abstract Introducing defects in TiO2-based photocatalytic materials is a promising strategy for improving light-driven CO2 reduction. However, defects such as oxygen vacancies are generally unstable. As a solution and to further enhance the photocatalytic activity, metal doping has been applied. This mini review aims to summarize recent progress in this particular field. Herein, we have classified metal-doped architectures into three different categories: single metal doping, alloy- and co-doping, and doping of morphologically nanoengineered TiO2−x substrates. The direct relationship between specific metals and product selectivity remains complex, as selectivity can vary significantly among seemingly similar materials. However, numerous methods do show promise in fine-tuning selectivity towards either CO or CH4. In terms of photocatalytic turnover, remarkable yields have been reported in isolated reports, but insufficient experimental data and divergent reaction conditions hamper a true comparison. This puts an emphasis on the need for standardized activity testing.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos (down) Publication Date 2024-03-16
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2211-3398 ISBN Additional Links UA library record
Impact Factor 6.6 Times cited Open Access
Notes Approved Most recent IF: 6.6; 2024 IF: 3.403
Call Number UA @ admin @ c:irua:204462 Serial 9221
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Author Thiruvottriyur Shanmugam, S.; Campos, R.; Trashin, S.; Daems, E.; Carneiro, D.; Fraga, A.; Ribeiro, R.; De Wael, K.
Title Singlet oxygen-based photoelectrochemical detection of miRNAs in prostate cancer patients’ plasma : a novel diagnostic tool for liquid biopsy Type A1 Journal article
Year 2024 Publication Bioelectrochemistry: an international journal devoted to electrochemical aspects of biology and biological aspects of electrochemistry Abbreviated Journal
Volume 158 Issue Pages 108698-108699
Keywords A1 Journal article; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab)
Abstract Dysregulation of miRNA expression occurs in many cancers, making miRNAs useful in cancer diagnosis and therapeutic guidance. In a clinical context using methods such as polymerase chain reaction (PCR), the limited amount of miRNAs in circulation often limits their quantification. Here, we present a PCR-free and sensitive singlet oxygen (1O2)-based strategy for the detection and quantification of miRNAs in untreated human plasma from patients diagnosed with prostate cancer. A target miRNA is specifically captured by functionalised magnetic beads and a detection oligonucleotide probe in a sandwich-like format. The formed complex is concentrated at the sensor surface via magnetic beads, providing an interface for the photoinduced redox signal amplification. The detection oligonucleotide probe bears a molecular photosensitiser, which produces 1O2 upon illumination, oxidising a redox reporter and creating a redox cycling loop, allowing quantification of pM level miRNA in diluted human plasma within minutes after hybridisation and without target amplification.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos (down) Publication Date 2024-04-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1567-5394 ISBN Additional Links UA library record
Impact Factor 5 Times cited Open Access
Notes Approved Most recent IF: 5; 2024 IF: 3.346
Call Number UA @ admin @ c:irua:205281 Serial 9229
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