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Author Moro, G.; Foumthuim, C.J.D.; Spinaci, M.; Martini, E.; Cimino, D.; Balliana, E.; Lieberzeit, P.; Romano, F.; Giacometti, A.; Campos, R.; De Wael, K.; Moretto, L.M.
Title How perfluoroalkyl substances modify fluorinated self-assembled monolayer architectures : an electrochemical and computational study Type A1 Journal article
Year 2022 Publication (down) Analytica chimica acta Abbreviated Journal
Volume 1204 Issue Pages 339740-12
Keywords A1 Journal article; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab)
Abstract There is an urgent need for sensing strategies to screen perfluoroalkyl substances (PFAS) in aqueous matrices. These strategies must be applicable in large-scale monitoring plans to face the ubiquitous use of PFAS, their wide global spread, and their fast evolution towards short-chain, branched molecules. To this aim, the changes in fluorinated self-assembled monolayers (SAM) with different architectures (pinholes/defects-free and with randomized pinholes/defects) were studied upon exposure to both long and short-chain PFAS. The applicability of fluorinated SAM in PFAS sensing was evaluated. Changes in the SAM structures were characterised combining electrochemical impedance spectroscopy and voltam-metric techniques. The experimental data interpretation was supported by molecular dynamics simu-lations to gain a more in-depth understanding of the interaction mechanisms involved. Pinhole/defect-free fluorinated SAM were found to be applicable to long-chain PFAS screening within switch-on sensing strategy, while a switch-off sensing strategy was reported for screening of both short/long-chain PFAS. These strategies confirmed the possibility to play on fluorophilic interactions when designing PFAS screening methods.(c) 2022 Elsevier B.V. All rights reserved.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000789493000010 Publication Date 2022-03-17
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access Not_Open_Access
Notes Approved no
Call Number UA @ admin @ c:irua:188658 Serial 8880
Permanent link to this record
 

 
Author Thiruvottriyur Shanmugam, S.; Trashin, S.; De Wael, K.
Title Gold-sputtered microelectrodes with built-in gold reference and counter electrodes for electrochemical DNA detection Type A1 Journal article
Year 2020 Publication (down) Analyst Abbreviated Journal Analyst
Volume Issue Pages
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Gold-sputtered microelectrodes with built-in gold reference and counter electrodes represent a promising platform for the development of disposable DNA sensors. Pretreating gold electrode surfaces and immobilization of DNA thereon is commonly employed in biosensing applications. However, with no scientific or practical guidelines to prepare a DNA sensor using these miniature gold-sputtered microelectrodes, cleaning and immobilization steps need to be systematically optimized and updated. In this work, we present efficient cleaning and modification of miniaturized gold-sputtered microelectrodes with thiolated DNA probes for DNA detection. Additional discussions on subtleties and nuances involved at each stage of pretreating and modifying gold-sputtered microelectrodes are included to present a robust, well-founded protocol. It was evident that the insights on cleaning polycrystalline gold disk electrodes with a benchmark electrode surface for DNA sensors, cannot be transferred to clean these miniature gold-sputtered microelectrodes. Therefore, a comparison between five different cleaning protocols was made to find the optimal one for gold-sputtered microelectrodes. Additionally, two principally different immobilization techniques for gold-sputtered microelectrode modification with thiolated ssDNA were compared i.e., immobilization through passive chemisorption and potential perturbation were compared in terms of thiol-specific attachment and thiol-unspecific adsorption through nitrogenous bases. The hybridization performance of these prepared electrodes was characterized by their sensitive complementary DNA capturing ability, detected by a standard alkaline phosphatase assay. Immobilization through passive chemisorption proved to be efficient in capturing the complementary target DNA with a detection limit of 0.14 nM and sensitivity of 9.38 A M−1 cm2. In general, this work presents a comprehensive understanding of cleaning, modification and performance of gold-sputtered microelectrodes with built-in gold reference and counter electrodes for both fundamental investigations and practical DNA sensing applications.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000592315100017 Publication Date 2020-09-17
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2654 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.2 Times cited Open Access
Notes Approved Most recent IF: 4.2; 2020 IF: 3.885
Call Number UA @ admin @ c:irua:172447 Serial 6527
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Author Daems, E.; Moro, G.; Berghmans, H.; Moretto, L.M.; Dewilde, S.; Angelini, A.; Sobott, F.; De Wael, K.
Title Native mass spectrometry for the design and selection of protein bioreceptors for perfluorinated compounds Type A1 Journal article
Year 2021 Publication (down) Analyst Abbreviated Journal Analyst
Volume 146 Issue 6 Pages 2065-2073
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Biosensing platforms are answering the increasing demand for analytical tools for environmental monitoring of small molecules, such as per- and polyfluoroalkyl substances (PFAS). By transferring toxicological findings in bioreceptor design we can develop innovative pathways for biosensor design. Indeed, toxicological studies provide fundamental information about PFAS-biomolecule complexes that can help evaluate the applicability of the latter as bioreceptors. The toolbox of native mass spectrometry (MS) can support this evaluation, as shown by the two case studies reported in this work. The analysis of model proteins’ (i.e. albumin, haemoglobin, cytochrome c and neuroglobin) interactions with well-known PFAS, such as perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), demonstrated the potential of this native MS screening approach. In the first case study, untreated albumin and delipidated albumin were compared in the presence and absence of PFOA confirming that the delipidation step increases albumin affinity for PFOA without affecting protein stability. In the second case study, the applicability of our methodology to identify potential bioreceptors for PFOS/PFOA was extended to other proteins. Structurally related haemoglobin and neuroglobin revealed a 1 : 1 complex, whereas no binding was observed for cytochrome c. These studies have value as a proof-of-concept for a general application of native MS to identify bioreceptors for toxic compounds.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000631575100031 Publication Date 2021-01-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2654; 1364-5528 ISBN Additional Links UA library record; WoS full record
Impact Factor 3.885 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 3.885
Call Number UA @ admin @ c:irua:177074 Serial 8294
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Author Jambers, W.; Van Grieken, R.
Title A message in the dust Type A3 Journal article
Year 1996 Publication (down) Analysis Europe Abbreviated Journal
Volume Issue Pages 25-29
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:14638 Serial 8216
Permanent link to this record
 

 
Author Kontozova-Deutsch, V.; Deutsch, F.; Krata, A.; Van Grieken, R.
Title Charakterystyka i wpływ zanieczyszczeń powietrza na eksponaty w muzeach Type A3 Journal article
Year 2008 Publication (down) Análityka Abbreviated Journal
Volume Issue 1 Pages 64-68
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:67549 Serial 7637
Permanent link to this record
 

 
Author Kontozova, V.; Godoi, R.; Krata, A.; Van Grieken, R.
Title Oszklenie ochronne i jego wpływ na średniowieczne okna witrazowe: z perspektywy chemii atmosfery: studium przypadku kaplica Sainte Chapelle w Paryzu Type A3 Journal article
Year 2007 Publication (down) Analityka Abbreviated Journal
Volume Issue 3 Pages 20-25
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:65079 Serial 8349
Permanent link to this record
 

 
Author Mabesoone, J.M.; Farias, C.C.; Van Grieken, R.; Duarte, P.J.; Delgado, A.; Freira, E.M.P.
Title Parnaiba Basin shales (Northeast Brazil) Type A1 Journal article
Year 1985 Publication (down) Anais da Academia Brasileira de Ciências Abbreviated Journal
Volume 57 Issue Pages 481-495
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0001-3765; 1678-2690 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116716 Serial 8357
Permanent link to this record
 

 
Author Godoi, R.H.M.; Godoi, A.F.L.; de Quadros, L.C.; Polezer, G.; Silva, T.O.B.; Yamamoto, C.I.; Van Grieken, R.; Potgieter-Vermaak, S.
Title Risk assessment and spatial chemical variability of PM collected at selected bus stations Type A1 Journal article
Year 2013 Publication (down) Air quality, atmosphere & health Abbreviated Journal
Volume Issue Pages 1-11
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The chemical characterization of particulate matter inside and outside of confined bus shelters has been discerned for the first time. Transit patrons are at risk due to the close vicinity of densely trafficked areas resulting in elevated pollution footprints. Incomplete combustion processes, as well as exhaust and wear and tear emissions from public and personal transportation vehicles, are key contributors to degraded urban air quality and are often implicated as causal to various diseases in humans. Urban planning, therefore, includes efficient public transport systems to mitigate the effect. The bus rapid transit system was inaugurated in Curitiba to ensure dedicated traffic lanes, major bus interchanges and semi-confined bus stops called tube stations. To assess the chemical risk that the passengers are exposed to, an investigation of the aerosol inside and outside five of these tube stations was launched. Electron probe X-ray micro-analysis and X-ray fluorescence were used to determine the elemental composition of individual and of bulk particle samples. An aethalometer quantified the black carbon. Elemental concentrations inside the shelters were in general higher than outside, especially for traffic-related elements. The lead concentration exceeded the NAAS standard at times, although the average was below the guideline. The biogenic, organic and soot clusters showed the highest abundance for the city centre sites. The overall carcinogenic risk could be classed as moderate, and the risk was significant at two sites during one of the sampling campaigns. The non-carcinogenic risk is well below the significant value.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000328332500006 Publication Date 2013-11-01
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1873-9318 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:111086 Serial 8484
Permanent link to this record
 

 
Author Ysebaert, T.; Samson, R.; Denys, S.
Title Revisiting dry deposition modelling of particulate matter on vegetation at the microscale Type A1 Journal article
Year 2023 Publication (down) Air quality, atmosphere & health Abbreviated Journal
Volume Issue Pages
Keywords A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Dry deposition is an important process determining pollutant concentrations, especially when studying the influence of urban green infrastructure on particulate matter (PM) levels in cities. Computational fluid dynamics (CFD) models of PM capture by vegetation are useful tools to increase their applicability. The meso-scale models of Zhang et al. (Atmos Environ 35:549-560, 2001) and Petroff and Zhang (Geosci Model Dev 3(2):753-769, 2010) have often been adopted in CFD models, however a comparison of these models with measurements including all PM particle sizes detrimental to health has been rarely reported and certainly not for green wall species. This study presents dry deposition experiments on real grown Hedera helix in a wind tunnel setup with wind speeds from 1 to 4 m s(-1) and PM consisting of a mixture of soot (0.02 – 0.2 mu mu m) and dust particles (0.3 – 10 mu mu m). Significant factors determining the collection efficiency (%) were particle diameter and wind speed, but relative air humidity and the type of PM (soot or dust) did not have a significant influence. Zhang's model outperformed Petroff's model for particles < 0.3 mu mu m, however the inclusion of turbulent impaction in Petroff's model resulted in better agreement with the measurements for particles > 2 – 3 mu mu m. The optimised model had an overall root-mean-square-error of similar to 4% for collection efficiency (CE) and 0.4 cm s-1 for deposition velocity (nu d), which was shown to be highly competitive against previously described models. It can thus be used to model PM deposition on other plant species, provided the correct parameterisation of the drag by this species. A detailed description of the spatial distribution of the vegetation could solve the underestimation for particle sizes of 0.3 – 2 mu mu m.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001125841300001 Publication Date 2023-12-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1873-9318; 1873-9326 ISBN Additional Links UA library record; WoS full record
Impact Factor 5.1 Times cited Open Access
Notes Approved Most recent IF: 5.1; 2023 IF: 3.184
Call Number UA @ admin @ c:irua:201986 Serial 9086
Permanent link to this record
 

 
Author Alvarez-Martin, A.; Wilcop, M.; Anderson, R.; Wendt, D.; Barden, R.; Kavich, G.M.
Title Investigation of volatile organic compounds in museum storage areas Type A1 Journal article
Year 2021 Publication (down) Air Quality Atmosphere And Health Abbreviated Journal Air Qual Atmos Hlth
Volume 14 Issue 11 Pages 1797-1809
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp X-ray Imaging and Spectroscopy (AXIS)
Abstract This study investigates the complex mixture of volatile organic compounds (VOCs) released by and accumulated within a collection of historic medicinal, pharmaceutical, and cosmetic artifacts housed at the National Museum of American History (Smithsonian Institution). In recent years, staff have become concerned, both for the safety of the objects and for personnel working in the collection, about strong unremediated odors accumulating within several storage cabinets. Museum staff also wondered if non-odorous off-gassing might need remediation. Solid-phase microextraction combined with gas chromatography–mass spectrometry analysis (SPME–GC–MS) was used to identify VOCs present in the storage room housing the collection. Over 160 compounds were detected and identified overall. Among these, 49 appeared to be directly related to ingredients used in the manufacture of many collection items. The results of the study suggest that SPME–GC–MS can be a strong tool for the rapid screening of multicomponent museum collections exhibiting off-gassing problems, before the pursuit of other more tedious analytical approaches. Additionally, the study reveals valuable insight into the characteristic volatile emission of historic medicinal, pharmaceutical, and cosmetic artifacts, increasing understanding of, and decision-making for, similar collections of objects. Eventually, it is hoped that this information can be used to inform mitigation strategies for the capture and reduction of VOCs in collections storage areas.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000659058300001 Publication Date 2021-06-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1873-9318 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.184 Times cited Open Access Not_Open_Access
Notes Approved Most recent IF: 3.184
Call Number UA @ admin @ c:irua:181923 Serial 8129
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Author Worobiec, A.; Potgieter-Vermaak, S.; Darchuk, L.; Vishnyakov, V.; Potgieter, H.; Van Grieken, R.
Title Behavior of semi-volatile particles under a laser and electron beam: influence on the quality of analytical results Type A1 Journal article
Year 2010 Publication (down) AIP conference proceedings Abbreviated Journal
Volume 1267 Issue Pages 523-524
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000281210900279 Publication Date 2010-08-05
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0094-243x ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:84573 Serial 7553
Permanent link to this record
 

 
Author Darchuk, L.; Worobiec, A.; Khan, V.; Krasnov, V.; Van Grieken, R.
Title Composition of aerosols from the shelter of the Chernobyl power plant Type A1 Journal article
Year 2010 Publication (down) AIP conference proceedings Abbreviated Journal
Volume 1267 Issue Pages 512-513
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000281210900273 Publication Date 2010-08-05
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0094-243x ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:84572 Serial 7705
Permanent link to this record
 

 
Author Van Grieken, R.; Jaenicke, R.; Koutsenogii, K.P.; Khodzher, T.V.; Kulipanov, G.N.
Title Atmospheric aerosols in the Asian part of the former Soviet Union Type P1 Proceeding
Year 2000 Publication (down) AIP conference proceedings T2 – 15th International Conference on Nucleation and Atmospheric Aerosols, (ICNAA), August 06-11, 2000, Univ. Missouri Rolla, Rolla, MO Abbreviated Journal
Volume 534 Issue Pages 740-743
Keywords P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The paper presents the results of the study of atmospheric aerosols in the Siberian region. This research was focused on studying the chemical and biological characteristics of both natural and pollution aerosols in this vast territory of the Asian part of the former Soviet Union (FSU). The data received within the frame of this project formed the basis for the evaluation of the impact of these aerosols on the Arctic region and the global climate. The Asian part of FSU is of scientific interest in the context of environmental chemistry, air pollution and study of atmospheric aerosols, The specific relevance of aerosol research in Siberia is as follows. There are areas that are very remote from industrial or densely populated centres, In these circumstances, aerosol characterization contributes to the definition of global continental “background”) or “baseline” aerosol, i.e, the aerosol which should occur in natural circumstances and on which all pollution is superimposed. Recently, in the context of global and long-term climatic changes, baseline aerosols and long-range transport of particulate air pollutants have become a topic of much debate, This is because it has been thought that aerosols might compensate for the well-known greenhouse effect to a significant. In this context, more and more attention is being paid to long-range effects of continental aerosols on the polar regions. Research in Norway and Alaska showed that Western or Central Siberia may be a very important source of pollutants affecting the air composition in the Arctic region. Cities and regions in south Siberia are enormously polluted by heavy metals, the level of pollution being many times higher than in the Western world, thus the health of local population is seriously affected. In most cases, gigantic point sources are in the area, which is simple from the viewpoint of environmental chemistry and unambiguous results should be obtained easily. Atmospheric deposition is a possible cause of the existence of heavy metals in the southern part of Lake Baikal. in the northern part of the lake, the environment is unpolluted. However in the southern part of the lake is considerably threatened by pollution from Baikalsk wood-pulp mill and industrial enterprises of Irkutsk, Angarsk,
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000089526000168 Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1-56396-958-0 ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:95766 Serial 7516
Permanent link to this record
 

 
Author Doevenspeck, J.; Zografos, O.; Gurunarayanan, S.; Lauwereins, R.; Raghavan, P.; Sorée, B.
Title Design and simulation of plasmonic interference-based majority gate Type A1 Journal article
Year 2017 Publication (down) AIP advances Abbreviated Journal
Volume 7 Issue 6 Pages 065116
Keywords A1 Journal article; Engineering sciences. Technology; Condensed Matter Theory (CMT)
Abstract Major obstacles in current CMOS technology, such as the interconnect bottleneck and thermal heat management, can be overcome by employing subwavelength-scaled light in plasmonic waveguides and devices. In this work, a plasmonic structure that implements the majority (MAJ) gate function is designed and thoroughly studied through simulations. The structure consists of three merging waveguides, serving as the MAJ gate inputs. The information of the logic signals is encoded in the phase of transmitted surface plasmon polaritons (SPP). SPPs are excited at all three inputs and the phase of the output SPP is determined by theMAJof the input phases. The operating dimensions are identified and the functionality is verified for all input combinations. This is the first reported simulation of a plasmonic MAJ gate and thus contributes to the field of optical computing at the nanoscale. (C) 2017 Author(s).
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000404621200036 Publication Date 2017-06-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2158-3226 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:152632 Serial 7764
Permanent link to this record
 

 
Author Espinosa, I.M.P.; Karaaslan, Y.; Sevik, C.; Martini, A.
Title Atomistic model of the anisotropic response of ortho-Mo₂C to indentation Type A1 Journal article
Year 2023 Publication (down) AIP advances Abbreviated Journal
Volume 13 Issue 6 Pages 065125-65127
Keywords A1 Journal article; Engineering sciences. Technology; Condensed Matter Theory (CMT)
Abstract Molybdenum carbide has various applications for which studying the material using classical molecular dynamics simulations would be valuable. Here, we develop an empirical potential within the Tersoff formalism using particle swarm optimization for the orthorhombic phase of Mo2C. The developed potential is shown to predict lattice constants, elastic properties, and equation of state results that are consistent with current and previously reported results from experiments and first principles calculations. We demonstrate the potential with simulations of indentation using multiple indenter sizes that load and unload in three different directions relative to the crystallographic lattice of orthorhombic Mo2C. Direction-dependent force-displacement trends are analyzed and explained in terms of the spatial distributions of stress and strain within the material during indentation. This study reveals the anisotropic elasticity of orthorhombic Mo2C and, more generally, provides researchers with a new empirical potential that can be used to explore the properties and behavior of the material going forward.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001016472500005 Publication Date 2023-06-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2158-3226 ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access OpenAccess
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:198333 Serial 8834
Permanent link to this record
 

 
Author Vermeulen, B.B.; Raymenants, E.; Pham, V.T.; Pizzini, S.; Sorée, B.; Wostyn, K.; Couet, S.; Nguyen, V.D.; Temst, K.
Title Towards fully electrically controlled domain-wall logic Type A1 Journal article
Year 2024 Publication (down) AIP advances Abbreviated Journal
Volume 14 Issue 2 Pages 025030-25035
Keywords A1 Journal article; Engineering sciences. Technology; Condensed Matter Theory (CMT)
Abstract Utilizing magnetic tunnel junctions (MTJs) for write/read and fast spin-orbit-torque (SOT)-driven domain-wall (DW) motion for propagation, enables non-volatile logic and majority operations, representing a breakthrough in the implementation of nanoscale DW logic devices. Recently, current-driven DW logic gates have been demonstrated via magnetic imaging, where the Dzyaloshinskii-Moriya interaction (DMI) induces chiral coupling between perpendicular magnetic anisotropy (PMA) regions via an in-plane (IP) oriented region. However, full electrical operation of nanoscale DW logic requires electrical write/read operations and a method to pattern PMA and IP regions compatible with the fabrication of PMA MTJs. Here, we study the use of a Hybrid Free Layer (HFL) concept to combine an MTJ stack with DW motion materials, and He+ ion irradiation to convert the stack from PMA to IP. First, we investigate the free layer thickness dependence of 100-nm diameter HFL-MTJ devices and find an optimal CoFeB thickness, from 7 to 10 angstrom, providing high tunneling magnetoresistance (TMR) readout and efficient spin-transfer torque (STT) writing. We then show that high DMI materials, like Pt/Co, can be integrated into an MTJ stack via interlayer exchange coupling with the CoFeB free layer. In this design, DMI values suitable for SOT-driven DW motion are measured by asymmetric bubble expansion. Finally, we demonstrate that He+ irradiation reliably converts the coupled free layers from PMA to IP. These findings offer a path toward the integration of fully electrically controlled DW logic circuits.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001163573400005 Publication Date 2024-02-16
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2158-3226 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access Not_Open_Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:203823 Serial 9109
Permanent link to this record
 

 
Author Biely, K.; Von Muenchhausen, S.; Van Passel, S.
Title Vertical integration as a strategy to increase value absorption by primary producers : the Belgian sugar beet and the German rapeseed case Type A1 Journal article
Year 2022 Publication (down) AIMS Agriculture and Food Abbreviated Journal
Volume 7 Issue 3 Pages 659-682
Keywords A1 Journal article; Pharmacology. Therapy; Engineering Management (ENM)
Abstract Vertical integration is a means of increasing market power. For some agricultural products, it is easier for farmers to exert control over their product beyond the farm gate, but for others it is more difficult. Cases in the latter category have two main characteristics. First, the farmer cannot sell the respective product to final consumers without processing. Second, processing is capital-intensive. Consequently, farmers have limited sales channels, and vertical integration of the supply chain is complex and challenging. It implies cooperation among farmers to process the raw material at a profitable scale and to finance the installation of processing facilities. Thus, for these product categories, farmers are prone to market power issues, since they depend on private businesses that have the financial means to install processing facilities and the logistical capacities to organize the collection of large amounts of raw material. This paper aims to identify and analyze the role of supply chain integration for farmers who are already cooperating horizontally. Two case studies serve as the basis for the analysis: sugar beet in Flanders, Belgium, and oilseed rape in Hessen, Germany. The analysis is based on a qualitative research approach combining interviews, focus groups, and workshops with farmers and processors. While for sugar beet, the effects of market power are emerging only now with the termination of the quota system, farmers growing oilseed rape have been experiencing these problems since the 1990s. Our analysis concludes that most strategies to maintain or improve farm income have been exhausted. Even various forms of vertical integration supported by European policies do not necessarily work as a successful strategy.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000860666800001 Publication Date 2022-08-17
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2471-2086 ISBN Additional Links UA library record; WoS full record
Impact Factor 1.8 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 1.8
Call Number UA @ admin @ c:irua:191514 Serial 7374
Permanent link to this record
 

 
Author Gebremariam, Y.A.; Dessein, J.; Wondimagegnhu, B.A.; Breusers, M.; Lenaerts, L.; Adgo, E.; Van Passel, S.; Minale, A.S.; Frankl, A.
Title Listen to the radio and go on field trips : a study on farmers' attributes to opt for extension methods in Northwest Ethiopia Type A1 Journal article
Year 2024 Publication (down) AIMS Agriculture and Food Abbreviated Journal
Volume 9 Issue 1 Pages 3-29
Keywords A1 Journal article; Pharmacology. Therapy; Engineering Management (ENM)
Abstract Extension professionals are expected to help disseminate agricultural technologies, information, knowledge and skills to farmers. In order to develop valuable and long-lasting extension services, it is essential to understand the methods of extension that farmers find most beneficial. This understanding helps adopt improved practices, overcome barriers, provide targeted interventions and continuously improve agricultural extension programs. Thus, assessing factors affecting farmers' choice of agricultural extension methods is essential for developing extension methods that comply with farmers' needs and socio-economic conditions. Therefore, we analyzed the factors affecting farmers' preferences in extension methods, using cross-sectional data collected from 300 households in two sample districts and 16 Kebelles in Ethiopia between September 2019 and March 2020. Four extension methods, including training, demonstration, office visits and phone calls were considered as outcome variables. We fitted a multivariate probit model to estimate the factors that influence farmers' choice of extension methods. The results of the study showed that the number of dependents in the household head, formal education and membership of Idir (an informal insurance program a community or group runs to meet emergencies) were negatively associated with farmers' choices to participate in different extension methods compared to no extension. On the other hand, the sex of the household head, farm experience, participation in non-farm activities, monetary loan access, owning a mobile phone, radio access and membership of cooperatives were found to have a statistically significant positive impact on farmers' choices of extension methods. Based on these findings, the government and the concerned stakeholders should take farmers' socio-economic and institutional traits into account when selecting and commissioning agricultural extension methods. This could help to develop contextually relevant extension strategies that are more likely to be chosen and appreciated by farmers. Furthermore, such strategies can aid policymakers in designing extension programs that cater to farmers' needs and concerns. In conclusion, farmers' socio-economic and institutional affiliation should be taken into consideration when selecting agricultural extension methods.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001124466300001 Publication Date 2023-12-13
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2471-2086 ISBN Additional Links UA library record; WoS full record
Impact Factor 1.8 Times cited Open Access
Notes Approved Most recent IF: 1.8; 2024 IF: NA
Call Number UA @ admin @ c:irua:202154 Serial 9209
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Author Kulkarni, S.; Gonzalez-Quiroga, A.; Nuñez, M.; Schuerewegen, C.; Perreault, P.; Goel, C.; Heynderickx, G.J.; Van Geem, K.M.; Marin, G.B.
Title An experimental and numerical study of the suppression of jets, counterflow, and backflow in vortex units Type A1 Journal article
Year 2019 Publication (down) AIChE journal Abbreviated Journal
Volume 65 Issue 8 Pages e16614-13
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Vortex units are commonly considered for various single and multiphase applications due to their process intensification capabilities. The transition from gas‐only flow to gas–solid flow remains largely unexplored nonetheless. During this transition, primary flow phenomenon, jets, and secondary flow phenomena, counterflow and backflow, are substantially reduced, before a rotating solids bed is established. This transitional flow regime is referred to as the vortex suppression regime. In the present work, this flow transition is identified and validated through experimental and computational studies in two vortex units with a scale differing by a factor of 2, using spherical aluminum and alumina particles. This experimental data supports the proposed theoretical particle monolayer solids loading that allows estimation of vortex suppression regime solids capacity for any vortex unit. It is shown that the vortex suppression regime is established at a solids loading theoretically corresponding to a monolayer being formed in the unit for 1g‐Geldart D‐ and 1g‐Geldart B‐type particles. The model closely agrees with experimental vortex suppression range for both aluminum and alumina particles. The model, as well as the experimental data, shows that the flow suppression regime depends on unit dimensions, particle diameter, and particle density but is independent of gas flow rate. This combined study, based on experimental and computational data and on a theoretical model, reveals the vortex suppression to be one of the basic operational parameters to study flow in a vortex unit and that a simple monolayer model allows to estimate the needed solids loading for any vortex device to induce this flow transition.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000474620800026 Publication Date 2019-04-19
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0001-1541 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:162121 Serial 7945
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Author Mazhar, R.; Azadi, H.; Van Passel, S.; Varnik, R.; Pietrzykowski, M.; Skominas, R.; Wei, Z.; Xuehao, B.
Title Does contract length matter? The impact of various contract-farming regimes on land-improvement investment and the efficiency of contract farmers in Pakistan Type A1 Journal article
Year 2023 Publication (down) Agriculture (Basel) Abbreviated Journal
Volume 13 Issue 9 Pages 1651-16
Keywords A1 Journal article; Engineering Management (ENM)
Abstract Land-tenure security is integral to local communities' socioeconomic development. It has been a center of debate in academia and for legislators and advocates to implement reforms to enhance efficient and sustainable development in land management. Yet, knowledge gaps remain in how various contract-farming regimes contribute to land-improvement investment and technical efficiency. This study used a data set of 650 farm households collected through a two-stage stratified sampling to investigate the influence of three contract-farming regimes: long-term, medium-term, and short-term contracts, on the land-improvement investment, productivity, and technical efficiency of contract farmers in Punjab, Pakistan. The study used multivariate probit and ordinary least square regression models to examine the posit relationships. The findings highlight that farmers with long-term land contracts have higher per hectare yield, income and profit than those with medium-term and short-term contracts. The results confirm that farmers with medium- and long-term contracts tend to invest more in land-improvement measures, i.e., organic and green manure. Further, the study findings demonstrate that long-term land tenures are more effective when farmers make decisions regarding the on-farm infrastructure, like tube-well installation, tractor ownership, and holding farm logistics. Last, the study results confirm that long-term contracts are more robust regarding technical efficiency. Moreover, the findings support the Marshallian inefficiency hypothesis and extend the literature on contract farming, land-improvement investment, and land use policy, and offer coherent policy actions for stakeholders to improve farmers' productivity, technical efficiency, and income.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001071045300001 Publication Date 2023-08-22
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2077-0472 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:200373 Serial 9201
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Author Annys, S.; Van Passel, S.; Dessein, J.; Adgo, E.; Nyssen, J.
Title From fast-track implementation to livelihood deterioration: The dam-based Ribb Irrigation and Drainage Project in Northwest Ethiopia Type A1 Journal article
Year 2020 Publication (down) Agricultural Systems Abbreviated Journal Agr Syst
Volume 184 Issue Pages 102909-102913
Keywords A1 Journal article; Engineering Management (ENM)
Abstract The 21st century revival of large-scale water resources development projects makes it important to keep assessing their impacts – preferably from an interdisciplinary perspective – in order to not repeat past mistakes and explore whether they could improve livelihood conditions for rural communities. In this study, costs and benefits of the World Bank-funded Ribb Irrigation and Drainage Project (RIDP) were investigated using a unique systems approach. The impact for farmers with different initial farming systems (rainfed – residual moisture – irrigated) was studied using field observations, document analyses, remote sensing, agronomic data and semi-structured interviews (n = 165). Data on project-induced changes to land and water availability, cropping patterns, farming systems and farm-level economics were collected. The results show that dam and dyke construction has reduced flooding, which has resulted in declining rice productivity ( – 42%) and concomitant shifts to lower value cropping systems. Results also reveal that the land redistribution has caused widespread livelihood deterioration as households had to give up 25% of their farmland and the communal grazing land was fully converted into farmland. Due to top-down implementation, nontransparent communication, delayed construction and lagging financial compensation, social resistance has appeared in the command area, impeding the construction works. In addition to these problems, if no rapid change to higher value crops can be realized, 20.5% of the farmers (those who already irrigate) will experience a loss of livelihood, 64.1% of the farmers (those with rainfed and residual moisture cultivation) will be on the verge of livelihood deterioration and only 13.5% of the farmers (those with solely rainfed cultivation) will enjoy RIDP-induced improved livelihoods. The fate of this project stresses the importance of investigating initial farming systems, exploring worthy project alternatives, improving participation, communication and benefit-sharing and strengthening the institutional capacity of implementing authorities.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000564756600013 Publication Date 2020-08-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0308-521x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.6 Times cited Open Access
Notes Approved Most recent IF: 6.6; 2020 IF: 2.571
Call Number UA @ admin @ c:irua:172030 Serial 6927
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Author Reynaert, S.; Vienne, A.; de Boeck, H.J.; D'Hose, T.; Janssens, I.; Nijs, I.; Portillo-Estrada, M.; Verbruggen, E.; Vicca, S.
Title Basalt addition improves the performance of young grassland monocultures under more persistent weather featuring longer dry and wet spells Type A1 Journal article
Year 2023 Publication (down) Agricultural and forest meteorology Abbreviated Journal
Volume 340 Issue 1 Pages 109610
Keywords A1 Journal article; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Global warming is altering the intra-annual variability of precipitation patterns in the mid-latitudes, including a shift towards longer dry and wet spells compared to historic averages. Such fluctuations will likely alter soil water and nutrient dynamics of managed ecosystems which could negatively influence their functioning (e.g., productivity and fodder quality). Here, we investigated whether basalt addition could attenuate effects of increasingly persistent precipitation regimes (PR) on two agricultural grassland monocultures differing in drought resistance (low: Lolium perenne (LP) vs high: Festulolium (FL)) and digestibility (high: LP, low: FL), while improving soil C sequestration. In total, 32 experimental mesocosms were subjected to either a low (1-day wet/ dry alternation) or a highly (30-day wet/dry alternation) persistent PR over 120 days, keeping total precipitation equal. In half of these mesocosms, we mixed basalt with the top 20 cm soil layer at a rate of 50 t ha-1. Overall, 30-day PR increased average water availability resulting in improved aboveground biomass and shoot digestibility for both species, in spite of elevated physiological stress. These PR also increased shoot Si, K, N and C but reduced Ca accumulation. Basalt addition generally increased soil Al, Ni, Mg, Ca, P, K and Si availability without altering root biomass or total soil carbon. Moreover, differences in root N content and C:N ratio between species were reduced. Interestingly, basalt modified the PR effects on productivity. Within 30-day PR, basalt stimulated aboveground biomass (& PLUSMN;14%) and root Si and K contents without altering plant digestibility, palatability, crude protein content or Ni/Al content. These results indicate that basalt can stimulate grassland productivity and soil nutrient availability under more persistent PR without negatively affecting fodder quality. Hence, basalt application may improve the performance of young temperate grassland monocultures under climate change, though dry soil conditions may limit effects on soil C sequestration during summer.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001051084500001 Publication Date 2023-07-21
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0168-1923 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.2 Times cited Open Access
Notes Approved Most recent IF: 6.2; 2023 IF: 3.887
Call Number UA @ admin @ c:irua:199204 Serial 9189
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Author Janssens, K.H.; Adams, F.C.; van Langevelde, F.; Vis, R.D.; Jones, K.W.; Rivers, M.; Sutton, S.
Title Comparison of synchrotron X-ray microanalysis with electron and proton microscopy for individual particle analysis Type A3 Journal article
Year 1992 Publication (down) Advances in X-ray analysis Abbreviated Journal
Volume 35 Issue Pages 1265-1273
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0376-0308 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:2811 Serial 5530
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Author Claes, M.; van Ham, R.; Janssens, K.; Van Grieken, R.; Klockenkämper, R.; von Bohlen, A.
Title Micro-analysis of artists' pigments by grazing-emission X-ray fluorescence spectrometry Type A3 Journal article
Year 1999 Publication (down) Advances in X-ray analysis Abbreviated Journal
Volume 41 Issue Pages 262-277
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0376-0308 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:24653 Serial 5709
Permanent link to this record
 

 
Author Vincze, L.; Janssens, K.; Adams, F.
Title Optics for X-ray microfluorescence to be used at the European synchrotron radiation facility Type A1 Journal article
Year 1994 Publication (down) Advances in X-ray analysis Abbreviated Journal
Volume 37 Issue Pages 553-563
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1994BB55S00067 Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0376-0308 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:8930 Serial 5757
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Author Vincze, L.; Janssens, K.; Adams, F.; Rindby, A.; Engström, P.; Riekel, C.
Title Optimization of tapered capillary optics for use at the microfocus beamline (ID 13) at the European Synchroton Radiation Facility Type A3 Journal article
Year 1999 Publication (down) Advances in X-ray analysis Abbreviated Journal
Volume 41 Issue Pages 252-261
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0376-0308 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:28216 Serial 5760
Permanent link to this record
 

 
Author Vincze, L.; Janssens, K.; Adams, F.; Rindby, A.; Engström, P.
Title Optimization of tapered capillary optics for use at the microfocus beamline (ID 13) at the European Synchroton Radiation Facility Type A3 Journal article
Year 1998 Publication (down) Advances in X-ray analysis Abbreviated Journal
Volume 41 Issue Pages 252-261
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0376-0308 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:24654 Serial 5761
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Author Gielis, J.; Ricci, P.E.; Tavkhelidze, I.
Title The Möbius phenomenon in Generalized Möbius-Listing surfaces and bodies, and Arnold's Cat phenomenon Type A1 Journal article
Year 2021 Publication (down) Advanced Studies : Euro-Tbilisi Mathematical Journal Abbreviated Journal
Volume 14 Issue 4 Pages 17-35
Keywords A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Möbius bands have been studied extensively, mainly in topology. Generalized Möbius-Listing surfaces and bodies providing a full geometrical generalization, is a quite new field, motivated originally by solutions of boundary value problems. Analogous to cutting of the original Möbius band, for this class of surfaces and bodies, results have been obtained when cutting such bodies or surfaces. In general, cutting leads to interlinked and intertwined different surfaces or bodies, resulting in very complex systems. However, under certain conditions, the result of cutting can be a single surface or body, which reduces complexity considerably. Our research is motivated by this reduction of complexity. In the study of cutting Generalized Möbius-Listing bodies with polygons as cross section, the conditions under which a single body results, displaying the Möbius phenomenon of a one-sided body, have been determined for even and odd polygons. These conditions are based on congruence and rotational symmetry of the resulting cross sections after cutting, and on the knife cutting the origin. The Möbius phenomenon is important, since the process of cutting (or separation of zones in a GML body in general) then results in a single body, not in different, intertwined domains. In all previous works it was assumed that the cross section of the GML bodies is constant, but the main result of this paper is that it is sufficient that only one cross section on the whole GML structure meets the conditions for the Möbius phenomenon to occur. Several examples are given to illustrate this.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000774655100002 Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access OpenAccess
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:183081 Serial 8258
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Author Ying, J.; Lenaerts, S.; Symes, M.D.; Yang, X.-Y.
Title Hierarchical design in nanoporous metals Type A1 Journal article
Year 2022 Publication (down) Advanced Science Abbreviated Journal Adv Sci
Volume 9 Issue 27 Pages 2106117-2106120
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Hierarchically porous metals possess intriguing high accessibility of matter molecules and unique continuous metallic frameworks, as well as a high level of exposed active atoms. High rates of diffusion and fast energy transfer have been important and challenging goals of hierarchical design and porosity control with nanostructured metals. This review aims to summarize recent important progress toward the development of hierarchically porous metals, with special emphasis on synthetic strategies, hierarchical design in structure-function and corresponding applications. The current challenges and future prospects in this field are also discussed.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000831201000001 Publication Date 2022-07-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2198-3844 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 15.1 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 15.1
Call Number UA @ admin @ c:irua:189646 Serial 7170
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Author Vishwakarma, M.; Kumar, M.; Hendrickx, M.; Hadermann, J.; Singh, A.P.; Batra, Y.; Mehta, B.R.
Title Enhancing the hydrogen evolution properties of kesterite absorber by Si-doping in the surface of CZTS thin film Type A1 Journal article
Year 2021 Publication (down) Advanced Materials Interfaces Abbreviated Journal Adv Mater Interfaces
Volume Issue Pages 2002124
Keywords A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract In this work, the effects of Si-doping in Cu2ZnSnS4 are examined computationally and experimentally. The density functional theory calculations show that an increasing concentration of Si (from x = 0 to x = 1) yields a band gap rise due to shifting of the conduction band minimum towards higher energy states in the Cu2Zn(Sn1-xSix)S-4. CZTSiS thin film prepared by co-sputtering process shows Cu2Zn(Sn1-xSix)S-4 (Si-rich) and Cu2ZnSnS4 (S-rich) kesterite phases on the surface and in the bulk of the sample, respectively. A significant change in surface electronic properties is observed in CZTSiS thin film. Si-doping in CZTS inverts the band bending at grain-boundaries from downward to upward and the Fermi level of CZTSiS shifts upward. Further, the coating of the CdS and ZnO layer improves the photocurrent to approximate to 5.57 mA cm(-2) at -0.41 V-RHE in the CZTSiS/CdS/ZnO sample, which is 2.39 times higher than that of pure CZTS. The flat band potential increases from CZTS approximate to 0.43 V-RHE to CZTSiS/CdS/ZnO approximate to 1.31 V-RHE indicating the faster carrier separation process at the electrode-electrolyte interface in the latter sample. CdS/ZnO layers over CZTSiS significantly reduce the charge transfer resistance at the semiconductor-electrolyte interface.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000635804900001 Publication Date 2021-04-02
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2196-7350 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.279 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 4.279
Call Number UA @ admin @ c:irua:177688 Serial 6780
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