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Records |
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Author |
Injuk, J.; Van Grieken, R. |
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Title |
Reference matarials for microanalytical nuclear techniques |
Type |
P3 Proceeding |
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Year |
1995 |
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Abbreviated Journal |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:55574 |
Serial |
8467 |
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Author |
Tytgat, T. |
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Title |
Research and development of self-supporting TiO2 foams for removal of VOCs from ambient air |
Type |
Doctoral thesis |
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Year |
2012 |
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Pages |
164 p. |
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Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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ISBN |
978-90-5728-395-6 |
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Call Number |
UA @ admin @ c:irua:104607 |
Serial |
8472 |
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Author |
Kontozova, V.; Krupińska, B.; Van Grieken, R.; Janssen, E.; Moris, H.; Aerts, D.; Watteeuw, L.; van Bos, M.; Peckstadt, A. |
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Title |
Research for preventive conservation and optimal presentation of world heritage in Museum Plantin-Moretus, Antwerp |
Type |
P3 Proceeding |
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Year |
2011 |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISBN |
978-989-97522-0-7 |
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Call Number |
UA @ admin @ c:irua:92095 |
Serial |
8473 |
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Author |
Swerling, G.; Travaglini, B.; Van Grieken, R.; Spolnik, Z.; Bencs, L.; [et al.]; European Project Freindly-Heating |
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Title |
Il riscaldamento nelle chiese e la conservazione dei beni culturali = Church heating and the preservation of the cultural heritage |
Type |
ME2 Book as editor or co-editor |
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Year |
2006 |
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Volume |
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Pages |
240 p. |
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Keywords |
ME2 Book as editor or co-editor; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISBN |
88-370-5034-8 |
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no |
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Call Number |
UA @ admin @ c:irua:61684 |
Serial |
8480 |
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Author |
Vandekerckhove, T.G.L.; Courtens, E.N.P.; Prat, D.; Boon, N.; Vlaeminck, S.E. |
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Title |
The rise of thermophilic biotechnology for nitrogen removal |
Type |
P3 Proceeding |
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Year |
2016 |
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Pages |
17 p.
T2 - WEF/IWA Nutrient Removal and Recovery C |
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Keywords |
P3 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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no |
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Call Number |
UA @ admin @ c:irua:151125 |
Serial |
8481 |
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Author |
Potgieter-Vermaak, S.; Van Grieken, R.; Potgieter, H. |
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Title |
Die risikoprofiel van Pb en Cr in stedelike padstof |
Type |
A2 Journal article |
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Year |
2012 |
Publication |
Litnet akademies : 'n joernaal vir die geesteswetenskappe |
Abbreviated Journal |
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Volume |
9 |
Issue |
3 |
Pages |
1-22 |
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Keywords |
A2 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The risk profile of Cr and Pb in urban road deposited sediment Exponential urbanisation and industrial growth occur on a global scale and result in an ecological burden, of which one important part is pollution. It is well known that the extent of air pollution has escalated over the past two decades in several parts of the world, despite mitigating measures and legislation. Current research points to the fact that air pollution in urban and industrial areas is substantially different from that found in rural areas. Road dust (RD) contributes up to 35% of airborne particulate matter due to resuspension thereof, and poses a health concern due to carcinogenic and toxic components potentially present in the micron-sized fractions. Although literature does report on the concentrations of trace, toxic metals and metalloids present in RD (Hooker and Nathanail 2006), the molecular make-up of particulates generated due to the resuspension of the RD is not well documented. In vitro and animal toxicological studies have confirmed that the chemical composition of inhaled particles plays a major role in its toxic, genotoxic and carcinogenic mechanisms, but the component-specific toxic effects are still not understood. Transition metals binding to air particle matter can result in reactive oxygen species in the human body (particularly in the lungs), and this is a significant risk, especially for vulnerable population groups like elderly people, children and terminally ill patients. The characterisation of the molecular composition of the fine fraction is evidently of importance for public health. During an earlier study, road dust from an inner-city environment in the UK was collected and partially characterised (Barrett e.a. 2010). These same-size fractions were analysed for their elemental concentrations, using X-ray Fluorescence Spectrometry (XRFS) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). In addition, single-particle analysis was performed on the different fractions by means of Computer Controlled Electron Probe X-ray Micro Analysis (CC-EPXMA) and their molecular structure probed by studying elemental associations. These findings were correlated with Micro Raman Spectroscopy (MRS) results. It was found that the fine fraction (<38 μm) had the highest Pb (238 ppm) and Cr (171 ppm) concentrations. The CC-EPXMA data showed >50% association of Cr-rich particles with Pb and the MRS data showed that the Cr was mostly present as lead chromate and therefore in the Cr(VI) oxidation state. Concentrations of both Pb and Cr decreased substantially (279 (<38 mm) 13 ppm (<1mm); 171 (<38 mm) 91 ppm (<1mm) respectively) in the larger fractions. Apart from rather alarmingly high concentrations of oxidative stressors (Cu, Fe, Mn), the carcinogenic and toxic potential of the inhalable fraction is evident. Preliminary bioaccessibility data indicated that both Cr and Pb are readily |
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ISSN |
1995-5928 |
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no |
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Call Number |
UA @ admin @ c:irua:102566 |
Serial |
8482 |
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Author |
Moropoulou, A.; Bisbikou, K.; Torfs, K.; Van Grieken, R. |
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Title |
Risk analysis for the protection of cultural heritage from industrial pollution |
Type |
H3 Book chapter |
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Year |
1999 |
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Pages |
475-484
T2 - Structural studies, repairs and maint |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Call Number |
UA @ admin @ c:irua:27598 |
Serial |
8483 |
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Author |
Chou, L.; Harlay, J.; Roevros, N.; Lannuzel, D.; Rebreanu, L.; van der Zee, C.; Lapernat, P.-E.; Daro, M.-H.; Aerts, K.; Godoi, R.; Van Grieken, R. |
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Title |
Role of oceanic production and dissolution of calcium carbonate in climate change (CCCC): final report |
Type |
Minutes and reports |
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Year |
2009 |
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Keywords |
Minutes and reports; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:80696 |
Serial |
8486 |
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Author |
Delalieux, F.; Van Grieken, R.; Moropoulou, A. |
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Title |
Salt weathering research: present state and future directions |
Type |
P3 Proceeding |
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Year |
2003 |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Call Number |
UA @ admin @ c:irua:42732 |
Serial |
8490 |
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Author |
Schmeling, M.; Van Grieken, R.E. |
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Title |
Sample preparation for X-ray fluorescence |
Type |
H3 Book chapter |
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Year |
2002 |
Publication |
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Abbreviated Journal |
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Volume |
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Pages |
933-976
T2 - Handbook of X-ray spectrometry / Grie |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:36388 |
Serial |
8494 |
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Author |
Injuk, J.; Van Grieken, R. |
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Title |
Sample preparation for X-ray fluorescence analysis |
Type |
H3 Book chapter |
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Year |
2000 |
Publication |
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Abbreviated Journal |
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Volume |
15 |
Issue |
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Pages |
13338-13347
T2 - Encyclopedia of analytical chemis |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Call Number |
UA @ admin @ c:irua:31656 |
Serial |
8495 |
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Author |
Injuk, J.; Van Grieken, R.E. |
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Title |
Sample preparation for XRF |
Type |
H3 Book chapter |
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Year |
1992 |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
657-692
T2 - Handbook of X-ray spectroscopy / Grie |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Call Number |
UA @ admin @ c:irua:2857 |
Serial |
8496 |
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Author |
Robberecht, H.; Van Grieken, R. |
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Title |
Selenium content and speciation in environmental waters determied by X-ray fluorescence spectroscopy |
Type |
H3 Book chapter |
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Year |
1980 |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
362-366
T2 - Trace substances in environmental hea |
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Keywords |
H3 Book chapter; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:117481 |
Serial |
8505 |
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Author |
vanden Berghe, D.; Deelstra, H.; Robberecht, H.; Van Grieken, R. |
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Title |
Selenium content of soils and rye grass (Lolium multiflorum) in Belgium |
Type |
H3 Book chapter |
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Year |
1981 |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
85-105
T2 - Mineral elements '80 : part 1 |
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Keywords |
H3 Book chapter; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:117483 |
Serial |
8506 |
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| Permanent link to this record |
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Author |
Robberecht, H.; Deelstra, H.; vanden Berghe, D.; Van Grieken, R. |
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Title |
Selenium gehalten van levensmiddelen geconsumeerd in België |
Type |
A3 Journal article |
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Year |
1983 |
Publication |
Revue des fermentations et des industries alimentaires |
Abbreviated Journal |
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Volume |
37 |
Issue |
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Pages |
188-201 |
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Keywords |
A3 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISSN |
0035-2071 |
ISBN |
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no |
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Call Number |
UA @ admin @ c:irua:116701 |
Serial |
8507 |
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Author |
Menezes, R.M.; Sardella, E.; Cabral, L.R.E.; de Souza Silva, C.C. |
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Title |
Self-assembled vortex crystals induced by inhomogeneous magnetic textures |
Type |
A1 Journal article |
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Year |
2019 |
Publication |
Journal of physics : condensed matter |
Abbreviated Journal |
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Volume |
31 |
Issue |
17 |
Pages |
175402 |
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Keywords |
A1 Journal article; Condensed Matter Theory (CMT) |
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Abstract |
We investigate the self-assembly of vortices in a type-II superconducting disk subjected to highly nonuniform confining potentials produced by inhomogeneous magnetic textures. Using a series of numerical experiments performed within the Ginzburg–Landau theory, we show that vortices can arrange spontaneously in highly nonuniform, defect-free crystals, reminiscent of conformal lattices, even though the strict conditions for the conformal crystal are not fulfilled. These results contradict continuum-limit theory, which predicts that the order of a nonuniform crystal is unavoidably frustrated by the presence of topological defects. By testing different cooling routes of the superconductor, we observed several different self-assembled configurations, each of which corresponding to one in a set of allowed conformal transformations, which depends on the magnetic and thermal histories of the system. |
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2019-01-30 |
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0953-8984 |
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no |
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Call Number |
UA @ admin @ c:irua:191094 |
Serial |
8511 |
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Author |
Daems, E. |
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Title |
Shaping up oligonucleotides : aptamer-target recognition investigated by native mass spectrometry |
Type |
Doctoral thesis |
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Year |
2021 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
235 p. |
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Keywords |
Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Aptamers are short, synthetic DNA or RNA molecules that are characterized by a specific 3D conformation which enables specific target recognition. Aptamers are promising tools in many application fields from sensing to therapeutics. One of the major challenges in the aptamer field is understanding the relationship between the sequence and what determines the higher-order structure and specific interactions with targets. Therefore, this PhD thesis focuses on the use of different mass spectrometry (MS) based approaches to characterize aptamers and their interactions. Several of these approaches are already widely applied to study other biomolecules, such as proteins, but are still largely unexplored for aptamers and oligonucleotides in general. A first focus was put on obtaining information on the higher-order structure and conformational stability of aptamers using a combination of MS and with ion mobility (IM) spectrometry by performing collision-induced unfolding (CIU) experiments. CIU was shown to hold great promise to analyze the conformational dynamics and gas-phase stabilities of aptamers. Next, the capabilities and limitations of native IM-MS for the analysis of noncovalent interactions of aptamers were demonstrated. The conformational behavior and interactions of cocaine-binding aptamers were studied and it was found that relative binding affinities of aptamers that only differ slightly in sequence and structure can be determined using native MS. Moreover, native IM-MS allowed the detection of small conformational changes upon binding of a target, which were found to be dependent on the binding mode of the aptamer. An adaptive binding mechanism was suggested for flexible aptamers that require more reorganization upon binding. In the final part of this thesis, the importance of thoroughly characterizing and validating aptamer-target interactions before using them in an application was emphasized. Moreover, the gathered insights were applied in our own development of a proof-of-concept aptamer-based sensor. This was shown by investigating the interactions of ampicillin aptamers which were found to not bind the target they were selected for in the first place. A multi-analytical approach combining complementary techniques was used for this purpose since no single technique is generally applicable to characterize all aptamers and their interactions and to obtain a comprehensive picture of the aptamer-target interactions. Furthermore, such multi-analytical approach was used to characterize a testosterone-binding aptamer while developing an aptamer-based electrochemiluminescent sensing strategy for this target. This shows the importance of native MS, in combination with other techniques, to thoroughly understand the aptamer-target interactions in the development of a designed application. |
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Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:178116 |
Serial |
8517 |
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Author |
De Cocker, P.; Bessiere, Y.; Hernandez-Raquet, G.; Dubos, S.; Mercade, M.; Sun, X.Y.; Mozo, I.; Barillon, B.; Gaval, G.; Caligaris, M.; Martin Ruel, S.; Vlaeminck, S.E.; Sperandio, M. |
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Title |
Short and long term effect of decreasing temperature on anammox activity and enrichment in mainstream granular sludge process |
Type |
P1 Proceeding |
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Year |
2017 |
Publication |
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Abbreviated Journal |
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Volume |
4 |
Issue |
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Pages |
50-54
T2 - Frontiers International Conference on W |
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Keywords |
P1 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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Abstract |
This study investigates the impact of lower temperature on short term and long term (down to 10 degrees C) on a completely anoxic anammox granular sludge process. This is the first time granular sludge Anammox is operated in pure anoxic condition in SBR and at low temperature. Conversion performance, kinetic parameters, sludge characteristics and microbial community were analyzed. |
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2017-05-04 |
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no |
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Call Number |
UA @ admin @ c:irua:151120 |
Serial |
8519 |
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Author |
Koutsenogii, P.K.; van Malderen, H.; Hoornaert, S.; Van Grieken, R.; Koutsenogii, K.P.; Boufetov, N.; Makarov, V.I.; Smoljakov, B.S.; Nemirovski, A.M.; Osipova, L.P.; Krjukov, J.A.; Ivakin, E.A.; Posukh, O.L.; Bronstein, E.L. |
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Title |
Siberian Haze: complex study of aerosols in Siberia |
Type |
A3 Journal article |
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Year |
1996 |
Publication |
Optics of the atmosphere and ocean |
Abbreviated Journal |
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Volume |
9 |
Issue |
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Pages |
712-719 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:14652 |
Serial |
8521 |
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Author |
Zhang, Q.; De Clippeleir, H.; Al-Omari, A.; Wett, B.; Vlaeminck, S.E.; Murthy, S. |
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Title |
Sidestream deammonification on thermal hydrolysis process digestate : strategies to overcome nitritation inhibition |
Type |
P3 Proceeding |
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Year |
2015 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
11 p.
T2 - IWA Nutrient Removal and Recovery 2015: |
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Keywords |
P3 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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no |
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Call Number |
UA @ admin @ c:irua:151147 |
Serial |
8522 |
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Author |
Piñera Hernández, I. |
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Title |
Simulation of atom displacements induced by photons and electrons in solids |
Type |
Doctoral thesis |
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Year |
2014 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
137 p. |
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Keywords |
Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:116687 |
Serial |
8526 |
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Author |
Van Grieken, R.; Speecke, A.; Hoste, J. |
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Title |
Simultaneous determination of silicon and phosphorus in cast iron by 14 MeV neutron activation analysis |
Type |
A3 Journal article |
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Year |
1970 |
Publication |
Journal of radioanalytical chemistry |
Abbreviated Journal |
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Volume |
6 |
Issue |
2 |
Pages |
385-398 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
A fast (10 min), non-destructive simultaneous determination of silicon and phosphorus in cast iron and steel by 14 MeV neutron activation was developed. The 1.78 MeV28Al activity (T=2.24 min) induced by the reaction28Si(n, p)28Al is counted on a NaI(Tl) detector. Two measurements are made to correct for the 1.81 MeV56Mn activity (T=2.58 hr) from the iron matrix. However,28Al is also produced via31P(n, α)28Al. By (n, 2n) reaction, phosphorus yields also30P (T=2.6 min), the 0.511 MeV annihilation radiation of which is counted by two opposite NaI(Tl) detectors in coincidence. Again, two successive coincidence measurements are carried out in order to take into account the53Fe activity (β+; T=8.9 min) from54Fe(n, 2n)53Fe. The28Al measurement is appropriately corrected via the computed phosphorus content. An oxygen flux monitor was used to normalize to the same flux. Nuclear interferences have been examined. Special attention has been paid to the presence of copper. The standard deviation for phosphorus being as high as ca. 0.09% P for a single determination, this technique can only be practical as an independent phosphorus analysis for high phosphorus cast irons. The precision on the28Al measurement is 5% relative for 0.2% Si and 2.5% above 1% Si. |
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2006-10-11 |
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ISSN |
0134-0719; 2064-2857 |
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no |
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Call Number |
UA @ admin @ c:irua:116450 |
Serial |
8528 |
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Author |
van Malderen, H.; Van Grieken, R.; Khodzher, T.V.; Grachev, M.; Bufetov, N.S.; Koutsenogii, K.P. |
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Title |
Single particle analysis of aerosols from Siberia |
Type |
P3 Proceeding |
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Year |
1994 |
Publication |
Proceedings of the Russian-Ukrainian-Austrian-German Analytical Symposium |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Call Number |
UA @ admin @ c:irua:9527 |
Serial |
8530 |
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Author |
Török, S.; Sandor, S.; Xhoffer, C.; Van Grieken, R.; Meszaros, E.; Molnar, A. |
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Title |
Single particle analysis of Hungarian background aerosol |
Type |
A3 Journal article |
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Year |
1992 |
Publication |
Idojaras: quarterly journal of the Hungarian Meteorological Service |
Abbreviated Journal |
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Volume |
96 |
Issue |
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Pages |
223-233 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:2847 |
Serial |
8532 |
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Author |
de Bock, L.A.; Van Grieken, R.E. |
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Title |
Single particle analysis techniques |
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H3 Book chapter |
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Year |
1999 |
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Pages |
243-275
T2 - Analytical chemistry of aerosols / Sp |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:27599 |
Serial |
8534 |
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Author |
Jambers, W.; Van Grieken, R. |
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Title |
Single particle characterisation of inorganic North Sea suspensions |
Type |
P3 Proceeding |
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Year |
1996 |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:14670 |
Serial |
8537 |
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Author |
Jambers, W.; Van Grieken, R. |
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Title |
Single particle characterisation of inorganic suspension in Lake Baikal |
Type |
A1 Journal article |
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Year |
1997 |
Publication |
Environmental science and technology |
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31 |
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Pages |
1525-1533 |
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A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISSN |
0013-936x; 1520-5851 |
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no |
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Call Number |
UA @ admin @ c:irua:18776 |
Serial |
8538 |
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Author |
Smekens, A.; Berghmans, P.; Van Grieken, R. |
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Title |
The size distribution and surface area of soot emitted by different sources |
Type |
A1 Journal article |
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Year |
2000 |
Publication |
Journal of aerosol science |
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31 |
Issue |
S1 |
Pages |
706-707 |
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A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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0021-8502; 1879-1964 |
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no |
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Call Number |
UA @ admin @ c:irua:31643 |
Serial |
8545 |
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| Permanent link to this record |
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Author |
Shani, J.; Barak, S.; Levi, D.; Ram, M.; Schachner, E.R.; Schlesinger, T.; Robberecht, H.; Van Grieken, R.; Avrach, W.W. |
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Title |
Skin penetration of minerals in psoriatics and guinea-pigs bathing in hypertonic salt solutions |
Type |
A3 Journal article |
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Year |
1985 |
Publication |
Pharmacological research communications |
Abbreviated Journal |
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Volume |
17 |
Issue |
6 |
Pages |
501-512 |
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Keywords |
A3 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Penetration of electrolytes through the human skin was measured in healthy volunteers and in psoriatic patients after bathing in the Dead-Sea or in simulated bath-salt solutions. Significant increases in the levels of serum Br, Rb, Ca and Zn were noticed only in the psoriatic patients after daily bathing in the Dead-Sea for a 4-week regimen. Guinea-pigs bathed in simulated Dead-Sea bath-salt solutions containing radionuclides of Ca, Mg, K and Br. Traces of each radionuclide were detected in the blood and in some internal organs after 60 minutes of bathing. The radionuclides showed a physiological pattern in their organ distribution. Even though the whole investigation was carried out in hypertonic solutions, there is a definite penetration of salts through healthy (human and guinea-pigs) and damaged (psoriatic) epidermis. This finding suggests that improvement of the psoriatic condition after bathing in the Dead-Sea, may be partly attributed (in addition to ultraviolet irradiation) to the minerals' effect on the psoriatic skin. |
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2006-07-20 |
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0031-6989 |
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UA @ admin @ c:irua:116755 |
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8547 |
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Author |
Muys, M.; Derese, S.; Verliefde, A.; Vlaeminck, S.E. |
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Title |
Solubilization of struvite as a sustainable nutrient source for single cell protein production |
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A2 Journal article |
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Year |
2016 |
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Communications in agricultural and applied biological sciences |
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81 |
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1 |
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179-184 |
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A2 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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Abstract |
By 2050, the world population will have considerably expanded and the life standard of many will increase, yielding a 50% higher demand in protein (FAO, 2011), and even increases of 82 and 102% for diary and meat products, respectively (Boland et al., 2013). To provide in this increasing demand we are highly dependent on our classical fertilizer to food chain which has a high environmental impact and lacks efficiency. Nutrient losses cause eutrophication and biodiversity loss and the input of resources is already beyond the boundaries of environmental sustainability (Steffen et al., 2015). Phosphate fertilizers are made from phosphate rock (apatite), of which the reserves are predicted to be depleted within 50 100 years if we continue business as usual (Cordell et al., 2009). Next to problems related to the unbalanced geopolitical distribution with dominance in China and Morocco, the decreasing quality of the remaining apatite will result in an increasing environmental impact of fertilizer production. Finally, our traditional food production model requires 30% of all ice-free land, 70% of all available freshwater and produces up to one third of the global greenhouse gas emission, of which 80 to 86% is linked to agricultural production (Vermeulen et al., 2012). To ensure food security, nutrient recovery from waste streams can provide an important strategy. In this context, struvite ( ) crystallisation may be applied to recover phosphorus, along with some nitrogen. Reusing these nutrients as agricultural fertilizer on the field will lead to considerable losses to the environment. In contrast, their use to cultivate micro-organisms, e.g. for single cell protein (SCP), offers to potential of a near perfect conversion efficiency (Moed et al., 2015). At this moment, microalgae represent the most developed type of SCP, and are a promising protein source due to their growth rate, high nutritional quality and extremely high nutrient usage efficiency (Becker, 2007). Reliable solubilisation data are essential to design a technological strategy for struvite dosage in bioreactors for SCP production. The effect on solubility and solubilisation rate of relevant physicochemical parameters was studied experimentally in aqueous solutions. Because pH and temperature greatly affect solubilisation kinetics they were set at a constant value of 7 and 20°C respectively. The effect of some parameters on struvite solubility was already studied (Bhuiyan et al., 2007; Ariyanto et al., 2014; Roncal-Herrero and Oelkers, 2011), but solubilisation rates were not yet considered and pH was not controlled at a constant value. The chemical parameters considered in this study include the concentration of different common ions ( and ), foreign ions ( and the chelating agent ethylenediaminetetraacetic acid, EDTA) present in micro-algal cultivation media as well as ionic strength (as set by NaCl). The main physical parameter included was contact surface, through variation in initial particle size and as well as in struvite dosage concentration. |
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1379-1176 |
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UA @ admin @ c:irua:151150 |
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8550 |
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