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Author Moro, G.; Foumthuim, C.J.D.; Spinaci, M.; Martini, E.; Cimino, D.; Balliana, E.; Lieberzeit, P.; Romano, F.; Giacometti, A.; Campos, R.; De Wael, K.; Moretto, L.M. pdf  doi
openurl 
  Title How perfluoroalkyl substances modify fluorinated self-assembled monolayer architectures : an electrochemical and computational study Type A1 Journal article
  Year 2022 Publication Analytica chimica acta Abbreviated Journal  
  Volume 1204 Issue Pages (down) 339740-12  
  Keywords A1 Journal article; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab)  
  Abstract There is an urgent need for sensing strategies to screen perfluoroalkyl substances (PFAS) in aqueous matrices. These strategies must be applicable in large-scale monitoring plans to face the ubiquitous use of PFAS, their wide global spread, and their fast evolution towards short-chain, branched molecules. To this aim, the changes in fluorinated self-assembled monolayers (SAM) with different architectures (pinholes/defects-free and with randomized pinholes/defects) were studied upon exposure to both long and short-chain PFAS. The applicability of fluorinated SAM in PFAS sensing was evaluated. Changes in the SAM structures were characterised combining electrochemical impedance spectroscopy and voltam-metric techniques. The experimental data interpretation was supported by molecular dynamics simu-lations to gain a more in-depth understanding of the interaction mechanisms involved. Pinhole/defect-free fluorinated SAM were found to be applicable to long-chain PFAS screening within switch-on sensing strategy, while a switch-off sensing strategy was reported for screening of both short/long-chain PFAS. These strategies confirmed the possibility to play on fluorophilic interactions when designing PFAS screening methods.(c) 2022 Elsevier B.V. All rights reserved.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000789493000010 Publication Date 2022-03-17  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access Not_Open_Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:188658 Serial 8880  
Permanent link to this record
 

 
Author Neven, L.; Barich, H.; Sleegers, N.; Cánovas, R.; Debruyne, G.; De Wael, K. pdf  url
doi  openurl
  Title Development of a combi-electrosensor for the detection of phenol by combining photoelectrochemistry and square wave voltammetry Type A1 Journal article
  Year 2022 Publication Analytica chimica acta Abbreviated Journal  
  Volume 1206 Issue Pages (down) 339732  
  Keywords A1 Journal article; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab)  
  Abstract The high toxicity, endocrine-disrupting effects and low (bio)degradability commonly attributed to phenolic compounds have promoted their recognition as priority toxic pollutants. For this reason, the monitoring of these compounds in industrial, domestic and agricultural streams is crucial to prevent and decrease their toxicity in our daily life. To confront this relevant environmental issue, we propose the use of a combi-electrosensor which combines singlet oxygen (1O2)-based photoelectrochemistry (PEC) with square wave voltammetry (SWV). The high sensitivity of the PEC sensor (being a faster alternative for traditional COD measurements) ensures the detection of nmol L−1 levels of phenolic compounds while the SWV measurements (being faster than the color test kits) allow the differentiation between phenolic compounds. Herein, we report on the development of such a combi-electrosensor for the sensitive and selective detection of phenol (PHOH) in the presence of related phenolic compounds such as hydroquinone (HQ), bisphenol A (BPA), resorcinol (RC) and catechol (CC). The PEC sensor was able to determine the concentration of PHOH in spiked river samples containing only PHOH with a recovery between 96% and 111%. The SWV measurements elucidated the presence of PHOH, HQ and CC in the spiked samples containing multiple phenol compounds. Finally, the practicality of the combi-electrosensor set-up with a dual SPE containing two working electrodes and shared reference and counter electrodes was demonstrated. As a result, the combination of the two techniques is a powerful and valuable tool in the analysis of phenolic samples, since each technique improves the general performance by overcoming the inherent drawbacks that they display independently.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000793070200016 Publication Date 2022-03-16  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access OpenAccess  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:187499 Serial 8848  
Permanent link to this record
 

 
Author Vanderborght, B.; Van Grieken, R. pdf  doi
openurl 
  Title Reduction of trace metal levels in analytical-grade activated carbon Type A1 Journal article
  Year 1977 Publication Analytica chimica acta Abbreviated Journal  
  Volume 89 Issue 2 Pages (down) 399-402  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1977DB52500022 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116368 Serial 8466  
Permanent link to this record
 

 
Author van Grieken, R.; Gijbels, R.; Speecke, A.; Hoste, J. pdf  doi
openurl 
  Title Internal standard activation analysis of silicon in steel Type A1 Journal article
  Year 1968 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta  
  Volume 43 Issue Pages (down) 381-395  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Non-destructive 14-MeV neutron activation analysis for silicon in steel has been applied with 56Mn as internal standard.56Mn is formed from the iron matrix via the 56Fe(n,p)56Mn reaction. Several methods of internal standardisation via56Mn are discussed. The 0.84-MeV photopeak of 56Mn is recommended if steel samples of about the same composition are to be analysed. Chemically analysed steel samples are used as silicon standards. A precision of 0.7% was obtained for an analysis plus standardisation time of 13 min. Special attention was paid to interferences produced by concentration changes of impurity elements. Several possible sources of errors were investigated.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos A1968C185100003 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.513 Times cited 14 Open Access  
  Notes Approved no  
  Call Number UA @ lucian @ c:irua:116358 Serial 1701  
Permanent link to this record
 

 
Author Gijbels, R.; Dams, R. pdf  doi
openurl 
  Title Determination of silicon in natural and pollution aerosols by 14-MeV neutron activation analysis Type A1 Journal article
  Year 1973 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta  
  Volume 63 Issue 2 Pages (down) 369-381  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT)  
  Abstract The determination of silicon via the 28Si(n,p)28 Al reaction by means of 14-MeV neutrons is applied to the analysis of pollution and natural aerosols. A Whatman 41 filter (40 cm2) on which airborne particulate material has been collected is compressed into a 3 × 12.7 mm pellet. Standards are prepared in the same way from clean filters spiked with a silicate solution. After a 50-s irradiation and a 75-s decay time, the sample is counted for 2 min with 5 × 5 NaI(Tl) well detector. The 1.779-MeV photopeak of 28Al is measured with a single channel sealer chain or with a multichannel analyser. The reproducibility, sensitivity and liability to interference from other elements were investigated for both counting systems. The homogeneity of the pellets and the filters was checked. The overall precision of one single-channel determination was estimated to be 3.5% after a 24-h high-volume sampling time. Samples collected in urban, industrial and remote areas with concentrations ranging from 0.05 to 15 μg Si m-3 air were analysed and the results are discussed.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos A1973O944700013 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.513 Times cited 16 Open Access  
  Notes Approved no  
  Call Number UA @ lucian @ c:irua:116365 Serial 672  
Permanent link to this record
 

 
Author Lins Galdino, S.M.; Costa Dantas, C.; Van Grieken, R. pdf  doi
openurl 
  Title Radio-isotope neutron activation analysis for vanadium, manganese and tungsten in alloy steels Type A1 Journal article
  Year 1987 Publication Analytica chimica acta Abbreviated Journal  
  Volume 196 Issue Pages (down) 337-343  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract An instrumental neutron activation method for V, Mn and W in alloy steels with a 241 Am/Be isotopic neutron source is described. The samples were irradiated to induce the nuclear reactions 51V(n, γ) 52V, 55Mn(n, γ)56Mn, and 186W(n, γ)187W. The activities were measured with a NaI(TI) detector. Interferences on the measured photopeaks were shown to be negligible by measuring the half-lives of 62V, 56Mn and 187W.These thre elementes were determined in the range 1.512.9% in special steels; manganese in the range 0.51.6% was measured in cast irons. Calibration was done by comparison with results from wet chemistry and x-ray fluorescence spectrometry. The processing times for the vanadium, manganese and tungsten determinations were 11 min, 3 h and 26.3 h, respectively, but these were reduced greatly by intoruding a scheme wherein six samples were simultaneously irradiated and the 56Mn and 187W nuclides were measured sequentially for a series of 66 samples. The average processing time was reduced to 45 min for tungsten with a precision of 4.0% and accuracy of 3.4% and 22.8 min for manganese with a precision of 3.8% and accuracy of 3.1%.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1987K058900044 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116445 Serial 8449  
Permanent link to this record
 

 
Author Cidu, R.; Fanfani, L.; Shaud, P.; Edmunds, W.M.; Van 't dack, L.; Gijbels, R. doi  openurl
  Title Determination of gold at the ultratrace level in natural waters Type A1 Journal article
  Year 1994 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta  
  Volume 296 Issue Pages (down) 295-304  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos A1994PM14000010 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.513 Times cited 20 Open Access  
  Notes Approved no  
  Call Number UA @ lucian @ c:irua:10252 Serial 668  
Permanent link to this record
 

 
Author Spolnik, Z.M.; Claes, M.; Van Grieken, R. doi  openurl
  Title Determination of trace elements in organic matrices by grazing-emission X-ray fluorescence spectrometry Type A1 Journal article
  Year 1999 Publication Analytica chimica acta Abbreviated Journal  
  Volume 401 Issue Pages (down) 293-298  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000083981600037 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:27586 Serial 7792  
Permanent link to this record
 

 
Author Robberecht, H.; Van Grieken, R.; Shani, J.; Barak, S. pdf  doi
openurl 
  Title Evaluation of multi-element analysis of blood serum by energy-dispersive x-ray spectrometry Type A1 Journal article
  Year 1982 Publication Analytica chimica acta Abbreviated Journal  
  Volume 136 Issue Pages (down) 285-292  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Conventional energy-dispersive x-ray fluorescence is applied in the analysis of blood serum to give the concentrations of 710 elements simultaneously with minimal manipulation of the samples. Simple spotting onto a Mylar carrier of 250 μl of serum, doped with two internal standards, was chosen as the sample preparation step. Some 200 serum samples, analyzed in replicate (n = 26), were used to evaluate this procedure. The detection limits are 4 μg ml-1 for K and Ca, 0.50.2 μg ml-1 for Fe, Cu, Pb and Zn, and less than 0.1 μg ml-1 for Se, Rb and Sr. Well above these limits, the standard deviation is around 10%. Comparison with the results of other measurements on the same samples indicates an accuracy of that order. The simplicity and high throughput, and the possibility of automating the x.r.f. measurements, make the proposed procedure suitable for screening large numbers of sera.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1982NL48600032 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116440 Serial 7940  
Permanent link to this record
 

 
Author Van Grieken, R.; Speecke, A.; Hoste, J. pdf  doi
openurl 
  Title On the precision of oxygen determinations in steel by 14-MeVv neutron activation Type A1 Journal article
  Year 1970 Publication Analytica chimica acta Abbreviated Journal  
  Volume 52 Issue 2 Pages (down) 275-280  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The precision of the 14-MeV neutron activation determination of oxygen in steel has been examined as a function of the oxygen content for a large number of steel and cast iron samples. The experimental and the statistically expected standard deviations have been compared. In the conditions used, 2.5 counts from 16N were registered for each p.p.m. of oxygen in the samples. The neutron flux was monitored by a simultaneously irradiated oxygen standard.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116362 Serial 8332  
Permanent link to this record
 

 
Author Vos, L.; Komy, G.; Reggers, G.; Roekens, E.; Van Grieken, R. pdf  doi
openurl 
  Title Determination of trace metals in rain water by differential-pulse stripping voltammetry Type A1 Journal article
  Year 1986 Publication Analytica chimica acta Abbreviated Journal  
  Volume 184 Issue Pages (down) 271-280  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Differential-pulse stripping voltammetry is applied to measure zinc, cadmium, lead and copper by anodic stripping and selenium(IV) by cathodic stripping in rain water at pH 2; subsequently, at pH 9,1, manganese is measured by anodic stripping on the same portion, and cobalt and nickel are measured in the adsorptive mode after formation of their dimethylglyoximates. The instrumental parameters are optimized. The linear ranges, mutual interferences and detection limits are studied. Excellent accuracy is demonstrated; the standard deviation is around 15% at 2.550 μg l−1 levels. The method is shown to be applicable for rain water.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986D964700026 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116444 Serial 7793  
Permanent link to this record
 

 
Author Leysen, L.; Roekens, E.; Komy, Z.; Van Grieken, R. pdf  doi
openurl 
  Title A study of the weathering of an historic building Type A1 Journal article
  Year 1987 Publication Analytica chimica acta Abbreviated Journal  
  Volume 195 Issue Pages (down) 247-255  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Various bulk and surface analytical techniques were used to study the chemical deterioration of the 13th-to-15th century limestone cathedral in Mechelen, Belgium. The weathering crust on the walls was found to be rich in sulfate, regardless of the geographic orientation. Nitrate and chloride were only detected in minor amounts in the crust and run-off samples. Attack by gaseous sulfur compounds seems to play a dominant role in the stone deterioration mechanism. Electron microprobe analysis showed predominantly bar-shaped gypsum crystals in the crust, and laser microprobe mass spectrometry showed that carbon seems to be responsible for the blackness of most crust samples. Automated electron microprobe analysis also indicated significant differences in the analytical composition of suspensions in run-off water and in rain-water.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1987K019500022 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116446 Serial 8608  
Permanent link to this record
 

 
Author Vanderborght, B.; Van Grieken, R. pdf  doi
openurl 
  Title Automated evaluation of photographically recorded spark-source mass spectra Type A1 Journal article
  Year 1978 Publication Analytica chimica acta Abbreviated Journal  
  Volume 103 Issue 3 Pages (down) 223-235  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A computer routine was developed for qualitative and quantitative analysis of photographically recorded spark-source mass spectra. Particular attention is given to the case of a graphite matrix. The program starts from the line intensities (expressed as Seidel values) and isotope masses calculated from the densitometer readings by a commercially available routine. From the intensities in the different exposures (typically 15 stages), it computes the parameters for the linear parts of the density curves for each ion. Taking into account mutual interferences of multivalent ions, isotope or C-clusters, oxide, carbide and dicarbide ions, the program automatically identifies and then quantifies the elements present. The precision of the results is around 5%. Reading and complete processing of one photoplate is achieved within 23 h.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1978GD90900003 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113631 Serial 7538  
Permanent link to this record
 

 
Author Smits, J.; Nelissen, J.; Van Grieken, R. pdf  doi
openurl 
  Title Comparison of preconcentration procedures for trace metals in natural waters Type A1 Journal article
  Year 1979 Publication Analytica chimica acta Abbreviated Journal  
  Volume 111 Issue Pages (down) 215-226  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The relative merits of eight procedures for preconcentrations of trace metal ions from natural water samples and synthetic solutions are evaluated. Spikes (100 μg l−1 ) of Mn, Co, Zn, Eu, Cs and Ba and the corresponding radioactive tracers were added to batches of drinking water, estuarine water, sea water, ground water, twice-distilled water and ahumic material solution. After equilibration for 25 months, the following techniques were applied: passage through columns of Dowex Al chelating resin and ofsilylated silica gel, filtration through laminate membrane filters and chelating diethylenetriamine cellulose filters, precipitation with sodium diethyldithiocarbamate and l-(2-pyridylazo)-2-naphthol, extraction with ammonium pyrrolidinedithiocarbamate, and chelation by 8-quinolinol (oxine) followed by adsorption on activated carbon. The quantitative characteristics of these techniques and the influence of the water matrix effects are discussed, as well as the applicability for x-ray fluorescence analysis.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1979HX09300018 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116369 Serial 7695  
Permanent link to this record
 

 
Author Osán, J.; de Hoog, J.; Worobiec, A.; Ro, C.-U.; Oh, K.-Y.; Szalóki, I.; Van Grieken, R. openurl 
  Title Application of chemometric methods for classification of atmospheric particles based on thin-window electron probe microanalysis data Type A1 Journal article
  Year 2001 Publication Analytica chimica acta Abbreviated Journal  
  Volume 446 Issue Pages (down) 211-222  
  Keywords A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000172309400020 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:36385 Serial 7468  
Permanent link to this record
 

 
Author Baez, J.F.; Compton, M.; Chahrati, S.; Cánovas, R.; Blondeau, P.; Andrade, F.J. doi  openurl
  Title Controlling the mixed potential of polyelectrolyte-coated platinum electrodes for the potentiometric detection of hydrogen peroxide Type A1 Journal article
  Year 2020 Publication Analytica Chimica Acta Abbreviated Journal Anal Chim Acta  
  Volume 1097 Issue Pages (down) 204-213  
  Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The use of a Pt electrode coated with a layer of Nafion has been described in previous works as an attractive way to perform the potentiometric detection of hydrogen peroxide. Despite of the attractive features of this approach, the nature of the non-Nernstian response of this system was not properly addressed. In this work, using a mixed potential model, the open circuit potential of the Pt electrode is shown to be under kinetic control of the oxygen reduction reaction (ORR). It is proposed that hydrogen peroxide acts as an oxygenated species that blocks free sites on the Pt surface, interfering with the ORR. Therefore, the effect of the polyelectrolyte coating can be understood in terms of the modulation of the factors that affects the kinetics of the ORR, such as an increase of the H+ concentration, minimization of the effect of the spectator species, etc. Because of the complexity and the lack of models that accurately describe systems with practical applications, this work is not intended to provide a mechanistic but rather a phenomenological view on problem. A general framework to understand the factors that affect the potentiometric response is provided. Experimental evidence showing that the use of polyelectrolyte coatings are a powerful way to control the mixed potential open new ways for the development of robust and simple potentiometric sensors.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2019-11-13  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record  
  Impact Factor 6.2 Times cited Open Access  
  Notes Approved Most recent IF: 6.2; 2020 IF: 4.95  
  Call Number UA @ admin @ c:irua:184381 Serial 7731  
Permanent link to this record
 

 
Author Padilla, R.; Schalm, O.; Janssens, K.; Arrazcaeta, R.; van Espen, P. doi  openurl
  Title Microanalytical characterization of surface decoration in Majolica pottery Type A1 Journal article
  Year 2005 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta  
  Volume 535 Issue 1-2 Pages (down) 201-211  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000228194200025 Publication Date 2005-01-15  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.95 Times cited 20 Open Access  
  Notes Approved Most recent IF: 4.95; 2005 IF: 2.760  
  Call Number UA @ admin @ c:irua:52143 Serial 5722  
Permanent link to this record
 

 
Author van Grieken, R.; Gijbels, R.; Speecke, A.; Hoste, J. pdf  doi
openurl 
  Title The determination of silicon in steel by 14-mev neutron activation analysis Type A1 Journal article
  Year 1968 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta  
  Volume 43 Issue Pages (down) 199-209  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A fast (25 min) non-destructive determination of silicon in steel by 14-MeV neutron activation is described. The 1.78-MeV 28Al activity, induced by the reaction 28Si(n,p)28Al, is counted on a NaI(Tl) detector. An oxygen flux monitor is used to normalise to the same neutron flux. Two methods are described to correct for the 56Mn activity (2.58 h), induced into the iron matrix via 56Fe(n,p)56Mn. Nuclear interferences of phosphorus and aluminium have been examined. Special attention has been paid to stainless steels. A sensitivity of 0.02 to 0.05% of silicon is obtained. The precision is 2 to 3% for steels containing above 1% silicon, and 7% for 0.1% of silicon.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos A1968C007600004 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.513 Times cited 19 Open Access  
  Notes Approved no  
  Call Number UA @ lucian @ c:irua:116357 Serial 673  
Permanent link to this record
 

 
Author Vandecasteele, C.; van Grieken, R.; Gijbels, R.; Speecke, A. pdf  doi
openurl 
  Title Systematic errors in 14-MeV neutron activation analysis for oxygen : part 1 : neutron and γ-ray attenuation effects Type A1 Journal article
  Year 1973 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta  
  Volume 64 Issue 2 Pages (down) 187-196  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A detailed account is given of neutron and γ-ray attenuation effects in 14-MeV neutron activation analysis of oxygen. Appropriate neutron cross-section values have been determined in two different ways and compared with literature values. It appears that the attenuation process is best described in terms of nonelastic scattering cross-sections. It is also shown that the narrow beam total γ-ray attenuation coefficients at 6 MeV, given in the literature are suitable for correction purposes if 16N γ-rays are counted with a window of 4.56.5 MeV. Attention was paid to the contribution of β-rays when the 16N activity is counted in this energy interval with a NaI(Tl) detector.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos A1973P353000003 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.513 Times cited 11 Open Access  
  Notes Approved CHEMISTRY, PHYSICAL 54/144 Q2 # PHYSICS, ATOMIC, MOLECULAR & CHEMICAL 9/35 Q2 #  
  Call Number UA @ lucian @ c:irua:116363 Serial 3464  
Permanent link to this record
 

 
Author Komy, Z.; Roekens, E.; Van Grieken, R. pdf  doi
openurl 
  Title Analysis of rain water by differential-pulse stripping voltammetry in nitric acid medium Type A1 Journal article
  Year 1988 Publication Analytica chimica acta Abbreviated Journal  
  Volume 204 Issue Pages (down) 179-187  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Differential-pulse anodic stripping voltammetry is applied to determine cadmium, lead and copper in rain water acidified with nitric acid to pH 1.5, and zinc after partial neutralization to pH 4.5. Subsequently, cobalt and nickel are measured in the adsorptive mode after formation of their dimethylglyoximates. The effects of pH on the stripping peaks for Zn, Cd, Pb and Cu and of chloride on the stripping peak of copper are reported. Good agreement is found with d.p.s.v. determinations in hydrochloric acid medium and with a.a.s. measurements in most cases. Excellent accuracy is demonstrated; the average relative standard deviation per measurement appears to be between 12 and 22% for the overall analytical procedure for concentrations of 0.1550 μgl−1 of the various metals in the samples.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1988M945900016 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116449 Serial 7450  
Permanent link to this record
 

 
Author Eltayeb, M.A.H.; Van Grieken, R.E. doi  openurl
  Title Coprecipitation with aluminium hydroxide and x-ray fluorescence determination of trace metals in water Type A1 Journal article
  Year 1992 Publication Analytica chimica acta Abbreviated Journal  
  Volume 268 Issue Pages (down) 177-183  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1992JQ23300020 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:2840 Serial 7733  
Permanent link to this record
 

 
Author Muia, L.M.; Van Grieken, R. openurl 
  Title Determination of rare earth elements in geological materials by total reflection X-ray fluorescence Type A1 Journal article
  Year 1991 Publication Analytica chimica acta Abbreviated Journal  
  Volume 251 Issue Pages (down) 177-181  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:663 Serial 7786  
Permanent link to this record
 

 
Author Janssens, K.; van Espen, P. pdf  doi
openurl 
  Title Evaluation of energy-dispersive x-ray-spectra with the aid of expert systems Type A1 Journal article
  Year 1986 Publication Analytica chimica acta Abbreviated Journal  
  Volume 191 Issue Pages (down) 169-180  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986H681700015 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:149780 Serial 5612  
Permanent link to this record
 

 
Author Vos, L.; Robberecht, H.; Van Dyck, P.; Van Grieken, R. pdf  doi
openurl 
  Title Multi-element analysis of urine by energy-dispersive x-ray fluorescence spectrometry Type A1 Journal article
  Year 1981 Publication Analytica chimica acta Abbreviated Journal  
  Volume 130 Issue 1 Pages (down) 167-175  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract For multi-element analysis of human urine, 25-ml samples doped with yttrium as internal standard are evaporated gently and then ashed up to 460°C overnight. The residue is pelletized and analysed by energy-dispersive x-ray fluorescence. Acid addition to facilitate the digestion is not mandatory. Recoveries are nearly quantitative for traces of Fe, Ni, Cu, Zn and Sr, to a lesser extent for lead, but not for arsenic or selenium. The standard deviation per measurement is typically around 6%. The detection limits are such that some 10 elements can be determined simultaneously in normal urine, and possibly more in cases of importance to toxicology or industrial hygiene.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1981ME98900017 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116439 Serial 8285  
Permanent link to this record
 

 
Author Ro, C.-U.; Hoornaert, S.; Van Grieken, R. doi  openurl
  Title Assessment of homogeneity of candidate reference material at the nanogram level and investigation on representativeness of single particle analysis using electron probe X-ray microanalysis Type A1 Journal article
  Year 1999 Publication Analytica chimica acta Abbreviated Journal  
  Volume 389 Issue Pages (down) 151-160  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000080527900016 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:27587 Serial 7506  
Permanent link to this record
 

 
Author Van Grieken, R.; Speecke, A.; Hoste, J. pdf  doi
openurl 
  Title The determination of copper in iron and steel by 14-Mev neutron activation analysis Type A1 Journal article
  Year 1970 Publication Analytica chimica acta Abbreviated Journal  
  Volume 51 Issue 2 Pages (down) 151-162  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A fast (10 min) non-destructive determination of copper in. steel and cast iron by 14-MeV neutron activation analysis is described. The 0.511-MeV annihilation radiation of62Cu (T1/2=9.8 min), induced by the reaction63Cu(n,2n)62Cu, is counted by two opposing NaI(Tl) detectors operating in coincidence. An oxygen flux monitor is used to normalise the irradiations. For high phosphorus contents, two measurements are made and the 9-min activity contribution is calculated. As the iron content of the samples is known, the use of pure iron samples allows correction for53Fe activity from the reaction54Fe(n,2n)53Fe(T1/2= 8.9 min). When the phosphorus and silicon activities are low, the procedure of counting and computing can be greatly simplified. Nuclear interferences of most common alloying and impurity elements were investigated.The precision is 23% for steels containing above 1% Cu, andCa. 10% for 0.1%Cu.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1970H034700002 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116360 Serial 7778  
Permanent link to this record
 

 
Author Struyf, H.; van Roy, W.; van Vaeck, L.; van Grieken, R.; Gijbels, R.; Caravatti, P. doi  openurl
  Title Laser microprobe Fourier transform mass spectrometer with external ion source for organic and inorganic microanalysis Type A1 Journal article
  Year 1993 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta  
  Volume 283 Issue Pages (down) 139-151  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos A1993MK02800013 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.513 Times cited 17 Open Access  
  Notes Approved no  
  Call Number UA @ lucian @ c:irua:6141 Serial 1793  
Permanent link to this record
 

 
Author Van Grieken, R.; Van de Velde, R.; Robberecht, H. pdf  doi
openurl 
  Title Sample contamination from a commercial grinding unit Type A1 Journal article
  Year 1980 Publication Analytica chimica acta Abbreviated Journal  
  Volume 118 Issue 1 Pages (down) 137-143  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The contamination of ground samples by a commercially available Lovibond McCrone Micronizing Mill is discussed. Tracer and weighing experiments showed that abrasion of corundum grinding elements was important, introducing 620 mg of abrasion products per minute of wet grinding. Agate grinding elements were abraded at ⩽6 mg min-1. The abrasion products and grinding elements were analyzed by x-ray fluorescence, spark-source mass spectrometry and neutron activation analysis. Contamination in trace element analysis of geological materials is likely to be negligible for agate grinding elements and, except for a few transition metals, also for corundum grinding elements. Contamination of typical biological samples is significant for a few elements even when agate elements are used, and is absolutely prohibitive for trace analysis when corundum elements are used.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1980JZ95100016 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116436 Serial 8492  
Permanent link to this record
 

 
Author Treiger, B.; van Malderen, H.; Bondarenko, I.; van Espen, P.; Van Grieken, R. doi  openurl
  Title Studying aerosol samples by non-linear mapping of electron probe microanalysis data Type A1 Journal article
  Year 1993 Publication Analytica chimica acta Abbreviated Journal  
  Volume 284 Issue Pages (down) 119-124  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1993MR27600014 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:6224 Serial 8610  
Permanent link to this record
 

 
Author Janssens, K.; van Espen, P. pdf  doi
openurl 
  Title Implementation of an expert system for the qualitative interpretation of x-ray-fluorescence spectra Type A1 Journal article
  Year 1986 Publication Analytica chimica acta Abbreviated Journal  
  Volume 184 Issue Pages (down) 117-132  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986D964700010 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:149782 Serial 5655  
Permanent link to this record
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