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Author Worobiec, A.; Potgieter-Vermaak, S.S.; Berghmans, P.; Winkler, H.; Burger, R.; Van Grieken, R. doi  openurl
  Title Air particulate emissions in developing countries : a case study in South Africa Type A1 Journal article
  Year (up) 2011 Publication Analytical letters Abbreviated Journal  
  Volume 44 Issue 11 Pages 1907-1924  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract Atmospheric aerosols were collected during the winter in Bethlehem, South Africa. The particulate mass concentrations, ambient carbon mass concentrations, and chemical composition of various particulate fractions showed that the area is highly polluted. The fine particle mass concentrations peaked at 1000 µg/m3 for PM2.5. Ambient carbon mass concentrations ranged from 20 to 40 µg/m3. Single particle analysis confirmed that the fine particle fraction was dominated by organic particles. The topographical conditions, causing a low inversion, together with the high amounts of emissions from biomass burning, result in unacceptable levels of air pollution and pose a considerable health threat to the population.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000294602300006 Publication Date 2011-08-12  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2719 ISBN Additional Links UA library record; WoS full record; WoS citing articles; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:91079 Serial 7429  
Permanent link to this record
 

 
Author Darchuk, L.; Gatto Rotondo, G.; Swaenen, M.; Worobiec, A.; Tsybrii, Z.; Makarovska, Y.; Van Grieken, R. pdf  doi
openurl 
  Title Composition of prehistoric rock-painting pigments from Egypt (Gilf Kébir area) Type A1 Journal article
  Year (up) 2011 Publication Spectrochimica acta: part A: molecular and biomolecular spectroscopy Abbreviated Journal  
  Volume 83 Issue 1 Pages 34-38  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract The composition of rock-painting pigments from Egypt (Gilf Kebia area) has been analyzed by means of molecular spectroscopy such as Fourier transform infrared and micro-Raman spectroscopy and scanning electron microscopy coupled to an energy dispersive X-ray spectrometer and X-ray fluorescence analysis. Red and yellow pigments were recognized as red and yellow ochre with additional rutile.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000296827600005 Publication Date 2011-07-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1386-1425 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:92015 Serial 7713  
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Author Worobiec, A.; Darchuk, L.; Brooker, A.; Potgieter, H.; Van Grieken, R. doi  openurl
  Title Damage and molecular changes under a laser beam in SEM-EDX/MRS interface : a case study on iron-rich particles Type A1 Journal article
  Year (up) 2011 Publication Journal of Raman spectroscopy Abbreviated Journal  
  Volume 42 Issue 4 Pages 808-814  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract The control of damage to individual environmental particles by a laser beam during Raman spectroscopy carried out in ambient air is generally well understood. The nature and control of damage under vacuum conditions (e.g. in the scanning electron microscopy with energy X-ray detection combined with micro-Raman spectroscopyinterfaced SEM-EDX/MRS) are more complex and less well comprehended. The physical and chemical processes that affect the damage caused to small particles by lasers still remain somewhat unclear, but certainly the atmosphere (vacuum/air) and the beam intensity have very significant influences. Furthermore, it has been determined that some particles (e.g. haematite), although stable under an electron beam, are damaged by the laser beam, hampering their analysis. Additionally, when simultaneous analyses by SEM/EDX and MRS are considered, the correct choice of the collection surface plays a crucial role. As a result, the following collection substrates were tested to determine their influence on the laser beam damage process to the particle: silver and aluminium foils and silicon wafers. A test study was performed using artificial examples of haematite (Fe2O3) particles. Exposure of Fe2O3 particles in vacuum to 514- and 785-nm laser radiation often leads to their melting, transformation and evaporation. The dependence of the damage caused by the laser beam on the particle structure is reported here. Molecular and crystallographic changes have also been revealed. Formation of magnetite (as an effect of re-crystallisation) and Raman inactive structures was detected.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000290484700033 Publication Date 2010-09-27  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0377-0486 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:89518 Serial 7751  
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Author Van Grieken, R.; Darchuk, L.; Kontozova, V.; Potgieter-Vermaak, S.; van Meel, K.; Stefaniak, E.; Worobiec, A. isbn  openurl
  Title Integration of analysis techniques of different scales using X ray induced and electron induced X ray spectrometry for applications in preventive conservation and environmental monitoring Type H2 Book chapter
  Year (up) 2011 Publication Abbreviated Journal  
  Volume Issue Pages 53-56 T2 - Integration of nuclear spectrometry met  
  Keywords H2 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract In the past years, and also within the framework of this CRP, we have used a combination of several nuclear and non-nuclear techniques in fundamental research and especially in various applications. Most work has been done with energy-dispersive X ray fluorescence in combination with electron probe X ray microanalysis, but several other more common analysis techniques have been used as well. The applications have included mostly preventive conservation (e.g. characterisation of damaging atmospheric particles in many museums) and environmental monitoring (e.g. for atmospheric particles in relation to their health effects in outdoor and especially indoor environments). Fundamental aspects have been in the optimising of interfaced electron microprobe and Raman microprobe analysis and the evaluation of the potential of such an instrument for atmospheric aerosols; quite a few unexpected and unpredicted problems have appeared in the latter study.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-92-0-121310-5 Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:97169 Serial 8110  
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Author Potgieter-Vermaak, S.; Worobiec, A.; Darchuk, L.; Van Grieken, R. isbn  openurl
  Title Micro-Raman spectroscopy for the analysis of environmental particles Type H1 Book chapter
  Year (up) 2011 Publication Abbreviated Journal  
  Volume Issue Pages 193-208 T2 - Fundamentals and applications in aero  
  Keywords H1 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-1-4200-8571-6 Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:86614 Serial 8233  
Permanent link to this record
 

 
Author Darchuk, L.A.; Zaverbna, L.V.; Worobiec, A.; Van Grieken, R. doi  openurl
  Title Structural features of human tooth tissues affected by high dose of external ionizing radiation after nuclear catastrophe of Chernobyl plant Type A1 Journal article
  Year (up) 2011 Publication Microchemical journal Abbreviated Journal  
  Volume 97 Issue 2 Pages 282-285  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract The application of micro-Raman spectroscopy is discussed for the analysis of structural features of human tooth tissues affected by high doses of external ionizing radiation (0.51.7 Gy) after the nuclear plant catastrophe in Chernobyl in 1986. The results have shown significant changes in the mineral matrix of dental enamel that lead to the decrease of tooth enamel hardness. Destruction of the collagen chain of the organic matrix has been observed for dentin and cementum.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000286558200029 Publication Date 2010-10-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0026-265x; 0026-265x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:86818 Serial 8585  
Permanent link to this record
 

 
Author Van Grieken, R.; Worobiec, A. url  doi
openurl 
  Title X-ray spectrometry for preventive conservation of cultural heritage Type A1 Journal article
  Year (up) 2011 Publication Pramåna: a journal of physics Abbreviated Journal  
  Volume 72 Issue 2 Pages 191-200  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract Analytical chemistry does play a key role in the chemical characterization of the environment and it appears that X-ray spectrometry, in its many forms, is one of the most relevant analytical techniques in preventive conservation, as it is in cultural heritage research in general. X-ray spectrometry has indeed been the method of choice for the characterization of the inorganic composition of atmospheric aerosols, for a long time. We have, over the last decade, intensively used various forms of X-ray spectrometry, viz., mostly energy-dispersive X-ray fluorescence, e.g. with polarized high-energy beam excitation, and automated electron probe X-ray microanalysis, together with other techniques, to identify particle types and their sources in indoor environments, including museums, while gaseous indoor pollutants were assessed using passive diffusion samplers. In each case, both bulk aerosols and individual aerosol particles were studied. For microanalysis of single particles, we have investigated a dozen techniques, but for wide, real-life applications, automated electron probe X-ray microanalysis is the most rewarding. We have first studied atmospheric aerosols in and around the Correr Museum in Venice, many other museums in Austria, Japan and England, and in the caves with prehistoric rock paintings in Altamira, Spain. Very recently, measurements were done in the Metropolitan Museum of Art in New York and theWawel Castle in Cracow, in Italian and Polish mountain churches, in a number of museums in Belgium and the Netherlands, and in cathedrals with medieval stained glass windows. In the Correr museum, it appeared that the particles most threatening for the Bellini paintings were released by the deteriorating plaster renderings, and this could be avoided by simply improving the rendering on the museum walls. In the Wawel Castle, outdoor pollution particles, like fine soot from diesel traffic, entering via leaks in the windows and doors, and also street-deicing salts and coal burning pollution particles, brought in by visitors, mostly in winter, were found to be most worrisome. Urgent questions that are not solved at this moment pertain to the deposition processes from the atmosphere to the cultural heritage items, the critical surface interactions that take place on these items, and the establishment of suitable particle concentration standards.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000288861000002 Publication Date 2011-05-20  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0304-4289; 0973-7111 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:87025 Serial 8785  
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Author Krupińska, B.; Worobiec, A.; Rotondo, G.G.; Novaković, V.; Kontozova, V.; Ro, C.-U.; Van Grieken, R.; De Wael, K. pdf  doi
openurl 
  Title Assessment of the air quality (NO2, SO2, O3 and particulate matter) in the Plantin-Moretus Museum/Print Room in Antwerp, Belgium, in different seasons of the year Type A1 Journal article
  Year (up) 2012 Publication Microchemical journal Abbreviated Journal Microchem J  
  Volume 102 Issue 1 Pages 49-53  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract The Plantin-Moretus Museum/Print Room in Antwerp, Belgium, gathers one of the most precious collections of typographical material and old printed books in the world. Rich decorations of this former printing-house and the history of the building itself underline its uniqueness. The cultural heritage (CH) objects collected in the museum, in particular books and manuscripts are vulnerable to the atmospheric pollution and can be irreversibly damaged. To assess the air quality inside the museum, four consecutive sampling campaigns were performed in each season of the year. The gas monitoring of nitrogen dioxide (NO2), sulphur dioxide (SO2) and ozone (O3) was carried out outside the building, in galleries and in showcases by means of using diffusive samplers. The particulate matter (PM) was collected in bulk form and as single particles and then analysed with use of energy dispersive X-ray fluorescence (EDXRF) and electron probe micro-analyser (EPMA), respectively. The museum complex turned out to show good protection against gaseous pollutants, especially SO2 and O3. The concentrations of these pollutants were significantly reduced inside the building in comparison to the outdoor ones. Similar protective character of the museum complex was established in case of the coarse fraction of PM; however with some limitations. Single particle analysis showed that the relative abundance of carbon-rich particles inside the museum was greater than outside. Moreover, these particles contributed more to the fine fraction of PM than to the coarse fraction. Therefore, for better preservation of cultural heritage, special attention should be paid to the small particles and their distribution within the museum.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000301559100007 Publication Date 2011-11-22  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0026-265x; 0026-265x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.034 Times cited 25 Open Access  
  Notes ; The presented work was realised in the frame of the project Preventive conservation/preservation in the museum Plantin-Moretus/Prentenkabinet, Antwerp, financed by the Flemish Government. Special thanks are due to Mrs Hanne Moris and Mrs Elke van Herck and all the staff of the Museum Plantin-Moretus/Print Room in Antwerp for their sincere interest in this work and their eager assistance during all the sampling campaigns. Barbara Krupinska is supported as PhD student by the Flemish Fund for Scientific Research (FWO, Belgium). ; Approved Most recent IF: 3.034; 2012 IF: 2.879  
  Call Number UA @ admin @ c:irua:94466 Serial 5483  
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Author Darchuk, L.A.; Zaverbna, L.V.; Worobiec, A.; Van Grieken, R. isbn  openurl
  Title Molecular spectroscopy study of human tooth tissues affected by high dose of external ionizing radiation (caused by the nuclear catastrophe of the Chernobyl plant) Type H1 Book chapter
  Year (up) 2012 Publication Abbreviated Journal  
  Volume Issue Pages 349-362 T2 - Current topics in ionizing radiation  
  Keywords H1 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-953-51-0196-3 Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:104626 Serial 8274  
Permanent link to this record
 

 
Author Oprya, M.; Kiro, S.; Worobiec, A.; Horemans, B.; Darchuk, L.; Novakovic, V.; Ennan, A.; Van Grieken, R. pdf  doi
openurl 
  Title Size distribution and chemical properties of welding fumes of inhalable particles Type A1 Journal article
  Year (up) 2012 Publication Journal of aerosol science Abbreviated Journal  
  Volume 45 Issue 1 Pages 50-57  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract The goal of the present study was to analyze the relationship between the fume formation rate, welding conditions, chemical composition of welding fume particles and their size. In the range from 0.25 to 16 μm aerodynamic diameter, three distinct types of welding fume particles were identified in the welder's breathing zone. The elemental composition of each type depended completely on the used welding materials, and reflects their mechanism of formation. Their relative abundance in the welding fume appeared to be dependent on the electrode coating, as well as the heat input during welding.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000300140000005 Publication Date 2011-10-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0021-8502; 1879-1964 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:93184 Serial 8544  
Permanent link to this record
 

 
Author Akbulut, S.; Krupinska, B.; Worobiec, A.; Čevik, U.; Taskin, H.; Van Grieken, R.; Samek, L.; Wiłkojć, E. pdf  doi
openurl 
  Title Gross alpha and beta activities of airborne particulate samples from Wawel Royal Castle Museum in Cracow, Poland Type A1 Journal article
  Year (up) 2013 Publication Journal of radioanalytical and nuclear chemistry Abbreviated Journal  
  Volume 295 Issue 2 Pages 1567-1573  
  Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract Soils are complex mixtures of organic, inorganic materials, and metal compounds from anthropogenic sources. In order to identify the pollution sources, their magnitude and development, several X-ray analytical methods were applied in this study. The concentrations of 16 elements were determined in all the soil samples using energy dispersive X-ray fluorescence spectrometry. Soils of unknown origin were observed by scanning electron microscopy equipped with a Si(Li) X-ray detector using Monte Carlo simulation approach. The mineralogical analyses were carried out using X-ray diffraction spectrometry. Due to the correlations between heavy metals and oxide compounds, the samples were analyzed also by electron probe microanalyzer (EPMA) in order to have information about their oxide contents. On the other hand, soil pH and salinity levels were identified owing to their influence between heavy metal and soil-surface chemistry. Moreover, the geoaccumulation index (I geo) enables the assessment of contamination by comparing current and pre-industrial concentrations.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000313713300105 Publication Date 2012-07-24  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0236-5731; 1588-2780 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:106763 Serial 8012  
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Author Bencs, L.; Spolnik, Z.; Worobiec, A.; Samek, L.; Jutte, B.A.H.G.; Van Grieken, R. pdf  doi
openurl 
  Title Effects of IR heating on distribution and transport of gaseous air pollutants in urban and mountain churches in Poland Type A1 Journal article
  Year (up) 2019 Publication Journal of cultural heritage Abbreviated Journal  
  Volume 36 Issue Pages 200-209  
  Keywords A1 Journal article; Art; History; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract The spatial distribution and temporal concentration variation of a set of gaseous air components (e.g., CO2, CO, H2CO, H2O) have been monitored with a multi-channel photoacoustic gas-analyzer in an urban church ( Saint Catherine's, Cracow) and a mountain church ( Saint Michaels Archangel, Szalowa) of Poland, in order to assess the likely effects of air pollution indoors under the influence of provisory electrical infrared (IR) heaters and without heating. Likewise, the ventilation characteristic and the leakage of these buildings with different constructions (i.e., plastered stone and wooden structures) with the assistance of decay curves of SF6 tracer gas was evaluated and compared. The wooden building in Szalowa, due to its more open structure, developed about one order higher ventilation rates (e.g., 0.9-1.3 h(-1)) than the stone church in Cracow (e.g., 0.1 h(-1)). The IR-heating affected only modestly the ventilation rate of the wooden church (e.g., 1.2-1.6 h(-1)), but it increased significantly that of the plastered stone church (e.g., 0.27 h(-1)). The ventilation rates were also assessed with the use of the CO2 curve decay method, and satisfactory agreement was found with those observed by the use of SF6 tracer. The spatial distribution of the studied gaseous pollutants (CO2, H2O) was found to be in some occasions nonhomogeneous in both buildings, due to the active usage of the IR-heating, especially, during a couple of consecutive liturgical services. Besides the pollution events due to ingress of gaseous air pollutants, present at enhanced levels outdoors, increased CO, CO2 and H2CO peaks were observed indoors too, which, in most cases, could be associated with incense burning. (C) 2018 Elsevier Masson SAS. All rights reserved.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000460311800021 Publication Date 2018-10-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1296-2074 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:158579 Serial 7847  
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