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Author Sauter, L.; Van der Ben, D.; Van Grieken, R.
Title Trace analysis of estuarine brown algae by energy-dispersive X-ray fluorescence Type A1 Journal article
Year (up) 1979 Publication X-ray spectrometry Abbreviated Journal
Volume 8 Issue 4 Pages 159-163
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Brown algae, which are good indicators for estuarine metal pollution, can advantageously be analysed by energy-dispersive X-ray fluorescence. The use of thin film samples and samples of intermediate thickness has several advantages over the conventional thick pellet procedure. A quite homogeneous thin target is prepared by suspending 15 mg of dried and ground seaweed powder in bi-distilled water and evaporating the slurry on a 10 cm2 Mylar foil held in a Teflon ring. The effective sample weight in the beam is calculated by a procedure based on the scatter peaks in the spectrum. Sensitivities are typically in the 215 ppm range. The coefficient of variation per analysis averaged over ten elements amounts to 10%. The natural concentration variation in seaweed specimens at one location is 13%. Samples from locations in the more polluted western Scheldt estuary yield significantly higher values for several elements, relative to the eastern Scheldt sites. Possible trace element variations between the top and base of plants, and between different seaweed specimens and sampling seasons, are discussed.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1979JC63700003 Publication Date 2005-05-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116481 Serial 8687
Permanent link to this record
 
 
Author Blommaert, W.; Vandelannoote, R.; Van 't dack, L.; Gijbels, R.; van Grieken, R.
Title Relative evaluation of neutron activation, X-ray fluorescence and spark source mass spectrometry for multi-element analysis of geothermal waters Type A3 Journal article
Year (up) 1980 Publication Journal of radioanalytical chemistry Abbreviated Journal
Volume 57 Issue Pages 382-400
Keywords A3 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 0000-00-00
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0134-0719 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved
Call Number UA @ lucian @ c:irua:111432 Serial 2859
Permanent link to this record
 
 
Author Gijbels, R.; van Grieken, R.; Vandelannoote, R.; Blommaert, W.; Van 't dack, L.
Title Trace element geochemistry in thermal waters from Amélie-les-Bains (Eastern Pyrenees, France) Type P3 Proceeding
Year (up) 1980 Publication Abbreviated Journal
Volume Issue Pages 123-126
Keywords P3 Proceeding; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication S.l. Editor
Language Wos Publication Date 0000-00-00
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ lucian @ c:irua:111509 Serial 3690
Permanent link to this record
 
 
Author Gijbels, R.; van Grieken, R.; Blommaert, W.; Vandelannoote, R.; Van 't dack, L.
Title Trace element geochemistry in thermal waters from Plombières and Bains (Vosges) Type P3 Proceeding
Year (up) 1980 Publication Abbreviated Journal
Volume Issue Pages 396-409
Keywords P3 Proceeding; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Reidel Place of Publication Dordrecht Editor
Language Wos Publication Date 0000-00-00
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ lucian @ c:irua:111508 Serial 3691
Permanent link to this record
 
 
Author Van Dyck, P.M.; Van Grieken, R.E.
Title Absorption correction via scattered radiation in energy-dispersive X-ray fluorescence analysis for samples of variable composition and thickness Type A1 Journal article
Year (up) 1980 Publication Analytical chemistry Abbreviated Journal
Volume 52 Issue 12 Pages 1859-1864
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980KJ65700021 Publication Date 2005-03-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116516 Serial 7410
Permanent link to this record
 
 
Author Van Dyck, P.; Markowicz, A.; Van Grieken, R.
Title Automatic absorption correction in x-ray fluorescence analysis of intermediate thickness samples using a dual external reference signal Type A1 Journal article
Year (up) 1980 Publication X-ray spectrometry Abbreviated Journal
Volume 9 Issue 2 Pages 70-76
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract A method has been investigated which allows calculations from the X-ray fluorescence spectra of the absorption coefficients at any energy for any sample, without any additional measurement. Use is made of the ratio of the characteristic X-ray signals from a Zr wire positioned in front of the sample and from a Pd foil placed behind the sample, both in a fixed geometry. From the experimentally measured absorption coefficient at the Pd L energy (2.9 keV), the coefficients for higher energies are calculated. By the use of an iterative computer routine in which corrections for the enhancement of the Pd foil by the sample are also included, an accuracy of 2% or better on the absorption coefficient determination can be reached for homogenous samples in one measurement. Grain-size and heterogeneity effects induce inaccuracies on the absorption coefficient determinations which might well reach 20% for particulate samples like intermediate thickness deposits of geological materials. This approach thus has the same limitations as the classical transmission method for such heterogeneous samples.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980JN16500007 Publication Date 2005-05-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116483 Serial 7541
Permanent link to this record
 
 
Author Smits, J.A.; Van Grieken, R.E.
Title Characterization of a 2,2'-diaminodiethylamine-cellulose filter toward metal cation extraction Type A1 Journal article
Year (up) 1980 Publication Analytical chemistry Abbreviated Journal
Volume 52 Issue 9 Pages 1479-1489
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980KB79500027 Publication Date 2005-03-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116515 Serial 7610
Permanent link to this record
 
 
Author Robberecht, H.; Van Grieken, R.; Van der Sloot, H.A.
Title OPtimized selenite determination in environmental waters by X-ray fluorescence Type H3 Book chapter
Year (up) 1980 Publication Abbreviated Journal
Volume Issue Pages 463-468 T2 - Analytical techniques in environmenta
Keywords H3 Book chapter; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:117482 Serial 8343
Permanent link to this record
 
 
Author Markowicz, A.; Van Dyck, P.; Van Grieken, R.
Title Radiometric diameter concept and exact intensities for spherical particles in x-ray fluorescence analysis Type A1 Journal article
Year (up) 1980 Publication X-ray spectrometry Abbreviated Journal
Volume 9 Issue 2 Pages 52-56
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract In X-ray fluorescence analysis the concept of radiometric diameter, d, is often introduced in considerations of the fluorescent intensity from a particulate sample. It represents the mean geometric path of the X-rays through one particle and is usually simply taken to be equal to the volume-to-area ratio of the particle. The effective radiometric path is, however, itself dependent on geometry and absorption effects. Rigorous calculations of the fluorescent intensity from a particle in the π and π/2 geometries were carried out to evaluate the errors involved. It appears that, for π geometry, the discrepancy between these exact results and the intensity calculated via the use of d does not exceed 5.2%. For the π/2 geometry, the errors are much larger and can amount to 50% in realistic cases of X-ray fluorescence analysis. These conclusions are also applicable to monolayers. The effective radiometric diameter approaches d only when absorption effects become negligible, but is smaller in other cases.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980JN16500003 Publication Date 2005-05-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116482 Serial 8451
Permanent link to this record
 
 
Author Van Grieken, R.; Van de Velde, R.; Robberecht, H.
Title Sample contamination from a commercial grinding unit Type A1 Journal article
Year (up) 1980 Publication Analytica chimica acta Abbreviated Journal
Volume 118 Issue 1 Pages 137-143
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The contamination of ground samples by a commercially available Lovibond McCrone Micronizing Mill is discussed. Tracer and weighing experiments showed that abrasion of corundum grinding elements was important, introducing 620 mg of abrasion products per minute of wet grinding. Agate grinding elements were abraded at ⩽6 mg min-1. The abrasion products and grinding elements were analyzed by x-ray fluorescence, spark-source mass spectrometry and neutron activation analysis. Contamination in trace element analysis of geological materials is likely to be negligible for agate grinding elements and, except for a few transition metals, also for corundum grinding elements. Contamination of typical biological samples is significant for a few elements even when agate elements are used, and is absolutely prohibitive for trace analysis when corundum elements are used.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980JZ95100016 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116436 Serial 8492
Permanent link to this record
 
 
Author Robberecht, H.; Van Grieken, R.
Title Selenium content and speciation in environmental waters determied by X-ray fluorescence spectroscopy Type H3 Book chapter
Year (up) 1980 Publication Abbreviated Journal
Volume Issue Pages 362-366 T2 - Trace substances in environmental hea
Keywords H3 Book chapter; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:117481 Serial 8505
Permanent link to this record
 
 
Author Robberecht, H.J.; Van Grieken, R.E.
Title Sub-part-per-billion determination of total dissolved selenium and selenite in environmental waters by X-ray fluorescence spectrometry Type A1 Journal article
Year (up) 1980 Publication Analytical chemistry Abbreviated Journal
Volume 52 Issue 3 Pages 449-453
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980JG67900021 Publication Date 2005-03-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116514 Serial 8613
Permanent link to this record
 
 
Author Maenhaut, W.; Selen, A.; van Espen, P.; Van Grieken, R.; Winchester, J.W.
Title Sulfur and heavy metals over the Atlantic Ocean : comparison with other marine data Type P3 Proceeding
Year (up) 1980 Publication Abbreviated Journal
Volume Issue Pages
Keywords P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:117480 Serial 8618
Permanent link to this record
 
 
Author Costa Dantas, C.; Moura de Amorim, W.; Van 't dack, L.; Van Grieken, R.
Title Trace elements in the atmospheric aerosols and soils in and around Recife, N.E. Brasil Type A3 Journal article
Year (up) 1980 Publication Ciencia e cultura Abbreviated Journal
Volume 32 Issue Pages 1525-1532
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0009-6725 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:111434 Serial 8690
Permanent link to this record
 
 
Author Vanderborght, B.M.; Van Grieken, R.E.
Title Water analysis by spark-source mass-spectrometry after preconcentration on activated carbon Type A1 Journal article
Year (up) 1980 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal
Volume 27 Issue 5 Pages 417-422
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract For trace analyses of environmental waters, spark-source mass-spectrometry has been combined with a preconcentration procedure involving chelation of the dissolved trace elements with oxine and subsequent adsorption of the oxinates and naturally occurring organic and colloidal metal species onto activated carbon. The activated carbon is filtered off and ashed at low temperature. The residue is dissolved, an internal standard and pure graphite are added and, after drying, the electrodes are prepared. The photographically recorded mass spectrum is evaluated by a suitable computer routine. The error of the procedure is around 30%. While this preconcentration and analysis procedure is capable of measuring about 40 elements quantitatively, in practice 1025 trace elements are determined simultaneously above the 0.1-μg/l. detection limit, as is illustrated by analyses of drinking water, surface and ground water samples. Although a sophisticated technique, SSMS can be considered for regular panoramic survey analyses.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980JR07800006 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116557 Serial 8746
Permanent link to this record
 
 
Author Vandelannoote, R.; Blommaert, W.; Gijbels, R.; van Grieken, R.
Title Analysis of geothermal waters by spark source mass spectrometry Type A3 Journal article
Year (up) 1981 Publication Fresenius' Zeitschrift für analytische Chemie Abbreviated Journal
Volume 309 Issue 4 Pages 291-294
Keywords A3 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Although the analysis of thermal water by spark-source mass spectrometry (SSMS) is rather timeconsuming, it allows the detection of about 20 elements of geochemical interest down to the ppb-level. A physical preconcentration is proposed in order to collect elements having quite different chemical properties, e.g. alkalis, transition elements, and elements occurring in anionic form. The relative sensitivity factors appear to be rather independent of the salt content of the graphite electrodes. Contrary to neutron activation analysis, SSMS has a quite uniform elemental sensitivity, and allows to determine elements for which neutron activation is not suitable, e.g. Sn and Pb. The precision of SSMS is however by a factor of about 2 worse than that obtained for neutron activation.
Address
Corporate Author Thesis
Publisher Place of Publication München Editor
Language Wos Publication Date 2004-11-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0016-1152;1618-2650; ISBN Additional Links UA library record
Impact Factor Times cited 8 Open Access
Notes Approved no
Call Number UA @ lucian @ c:irua:116638 Serial 100
Permanent link to this record
 
 
Author Tavernier, S.M.F.; Nies, E.; Gijbels, R.
Title Hard-spere model for hydrodynamic chromatography systems Type A1 Journal article
Year (up) 1981 Publication Analytical proceedings Abbreviated Journal
Volume 18 Issue Pages 31-34
Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication London Editor
Language Wos Publication Date 2004-03-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0144-557X; ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ lucian @ c:irua:110347 Serial 1409
Permanent link to this record
 
 
Author Costa Dantas, C.; Da Silveira Dantas, H.; Van 't dack, L.; Van Grieken, R.
Title Analise de solos por meio de fluorescencia de raios-X nao-dispersiva Type A1 Journal article
Year (up) 1981 Publication Química nova Abbreviated Journal
Volume 4 Issue Pages 110-116
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0100-4042; 1678-7064 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:111435 Serial 7438
Permanent link to this record
 
 
Author Smits, J.; Van Grieken, R.
Title Chelating 2,2′-diaminodiethylamine cellulose filters and X-ray fluorescence for preconcentration and trace analysis of natural waters Type A1 Journal article
Year (up) 1981 Publication International journal of environmental analytical chemistry Abbreviated Journal
Volume 9 Issue 2 Pages 81-92
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The 2,2′-diaminodiethylamine (DEN) functional group can be expected to have ideal properties for the chelation of transition metals and their collection from aqueous solutions, independent of the alkali and alkaline earth ions concentration. Introducing DEN into cellulose filters allows straightforward preconcentration of trace cations by a simple filtration step, and the DEN-filter constitutes a suitable target for X-ray fluorescence (XRF) analysis. The linearity between the XRF-response on the loaded DEN-filter and the trace cation concentration in the solution appears excellent, up to a total filter capacity of ca. 3 μeq.cm−2. The detection limits are around 0.5 μg. l−1 in most practical cases. Accuracy and precision are around 10%. The applicability of the proposed procedure is illustrated on a comparative basis by XRF-analysis of drinking water and surface water, after preconcentration by DEN-filtration and by alternative procedures.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1981LF48000001 Publication Date 2007-07-07
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116571 Serial 7638
Permanent link to this record
 
 
Author Smits, J.; Van Grieken, R.
Title Enrichment of trace anions from water with 2,2'-diaminodiethylamine cellulose filters Type A1 Journal article
Year (up) 1981 Publication Analytica chimica acta Abbreviated Journal
Volume 123 Issue Pages 9-17
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Cellulose filters with immobilized 2,2'-diaminodiethylamine (DEN) functional groups are studied for trace anion preconcentration from aqueous solution, with subsequent x-ray fluorescence measurements. For most oxoanions with a central metal atom, nearly quantitative collection can be achieved by 10-cm2 DEN filters under the following optimized conditions: pH 36, filtration rate up to 0.5 ml cm-2 min-1, and sample volume up to 100 ml cm-2. The collection yield is independent of the trace oxoanion concentration up to at least 1.5 μmol cm-2. Although the DEN filter exhibits some selectivity towards oxoanions with a central metal atom, ionic strength affects the results; the collection efficiency is strongly depressed with salt (e.g. NaCl) concentrations above 0.01 M. The applicability of the DEN filter in anion collection is therefore limited to dilute solutions.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1981LA22400002 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116437 Serial 7922
Permanent link to this record
 
 
Author Verbueken, A.; Van Grieken, R.
Title Influence on photoplate evaluation parameters in spark source mass spectrometric analysis Type A1 Journal article
Year (up) 1981 Publication Bulletin des sociétés chimiques belges Abbreviated Journal
Volume 90 Issue Pages 331-341
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0037-9646 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116626 Serial 8099
Permanent link to this record
 
 
Author Vos, L.; Robberecht, H.; Van Dyck, P.; Van Grieken, R.
Title Multi-element analysis of urine by energy-dispersive x-ray fluorescence spectrometry Type A1 Journal article
Year (up) 1981 Publication Analytica chimica acta Abbreviated Journal
Volume 130 Issue 1 Pages 167-175
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract For multi-element analysis of human urine, 25-ml samples doped with yttrium as internal standard are evaporated gently and then ashed up to 460°C overnight. The residue is pelletized and analysed by energy-dispersive x-ray fluorescence. Acid addition to facilitate the digestion is not mandatory. Recoveries are nearly quantitative for traces of Fe, Ni, Cu, Zn and Sr, to a lesser extent for lead, but not for arsenic or selenium. The standard deviation per measurement is typically around 6%. The detection limits are such that some 10 elements can be determined simultaneously in normal urine, and possibly more in cases of importance to toxicology or industrial hygiene.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1981ME98900017 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116439 Serial 8285
Permanent link to this record
 
 
Author Maenhaut, W.; Selen, A.; van Espen, P.; Van Grieken, R.; Winchester, W.J.
Title Pixe analysis of aerosol samples collected over the atlantic-ocean from a sailboat Type A1 Journal article
Year (up) 1981 Publication Nuclear instruments and methods Abbreviated Journal
Volume 181 Issue 1-3 Pages 399-405
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)
Abstract Size-fractionated aerosol samples, collected over the Atlantic Ocean, were analyzed for up to 20 elements by PIXE. Using a sailboat as sampling platform, duplicate samples were taken for two-day periods by means of battery operated 6-stage cascade impactors, positioned about 8 m above the sea surface. In the PIXE analysis of the fine particle stages (stages 3 to 5) a 5 times smaller beam size was used than for stages 1 and 2. This led to significant improvement in the detection limits for the former stages. The results from the duplicate impactor samples were normally in good agreement, indicating that the combined uncertainty of sampling and PIXE analysis was of the order of 20%. The precision of the PIXE analysis alone was investigated by rebombarding some samples six months after the first analysis. The trends with time of the fine particle sulfur and the coarse particle iron concentrations are discussed in some detail.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1981LH81100073 Publication Date 2002-11-11
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0029-554x; 1878-3759 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:113628 Serial 8386
Permanent link to this record
 
 
Author vanden Berghe, D.; Deelstra, H.; Robberecht, H.; Van Grieken, R.
Title Selenium content of soils and rye grass (Lolium multiflorum) in Belgium Type H3 Book chapter
Year (up) 1981 Publication Abbreviated Journal
Volume Issue Pages 85-105 T2 - Mineral elements '80 : part 1
Keywords H3 Book chapter; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:117483 Serial 8506
Permanent link to this record
 
 
Author Verbueken, A.; Michiels, E.; Van Grieken, R.
Title Total analysis of plant material and biological tissue by spark source mass spectrometry Type A3 Journal article
Year (up) 1981 Publication Fresenius' Zeitschrift für analytische Chemie Abbreviated Journal
Volume 309 Issue 4 Pages 300-304
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Analysis of biological material by spark source mass spectrometry is reported. Preliminary studies mainly based upon the analysis of the NBS standard reference material SRM-1571 (Orchard Leaves) are described. Attention is drawn to the importance of a suitable sample preparation method. The advantages of a wet digestion technique in a Teflon bomb are discussed and its use is justified by the satisfactory overall analysis precision of about 20%.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2004-11-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0016-1152 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116639 Serial 8675
Permanent link to this record
 
 
Author Van Dyck, P.; Van Grieken, R.
Title Automated energy-dispersive X-ray fluorescence analysis for diverse environmental samples Type H3 Book chapter
Year (up) 1982 Publication Abbreviated Journal
Volume Issue Pages 315-324 T2 - Analytical techniques in environmenta
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:117484 Serial 7536
Permanent link to this record
 
 
Author Chakravorty, R.; Van Grieken, R.
Title Co-precipitation with iron hydroxide and X-ray fluorescence analysis of trace metals in water Type A1 Journal article
Year (up) 1982 Publication International journal of environmental analytical chemistry Abbreviated Journal
Volume 11 Issue 1 Pages 67-80
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Preconcentration of transition trace ions by coprecipitation on iron-hydroxide has been combined with energy-dispersive X-ray fluorescence for environmental water analysis. The optimized preconcentration procedure implies adding 2 mg of iron to a 200 ml water sample, adding dilute NaOH up to pH 9, filtering off on a Nuclepore membrane after a 1 h equilibration time, and analyzing. Quantitative recoveries could then be obtained for Ni, Cu, Zn and Pb, e.g. at the 10 μg/l level in waters of varying salinity while Mn was partially collected. (In fact, for a given problem the iron carrier amount can be adjusted to obtain a satisfactory compromise between high recovery and low detection limit). The precision is 7-8% at the 10 μg/l level, and the detection limits are in the 0.5-1 μg/l range. Various environmental water samples are analysed by way of illustration.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1982NG99200007 Publication Date 2007-07-07
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116573 Serial 7676
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Author Van Grieken, R.; Van 't dack, L.; Costa Dantas, C.; Moura de Amorim, W.; Maenhaut, W.
Title Elemental constituents of atmospheric aerosols in Recife, North-East Brazil Type A3 Journal article
Year (up) 1982 Publication Environmental pollution: series B : chemical and physical Abbreviated Journal
Volume 4 Issue 2 Pages 143-163
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Few data are available on the inorganic atmospheric pollution in the rapidly expanding cities of South America, like Recife, on the Atlantic Coast of North-east Brazil. Therefore, the elemental composition of atmospheric aerosols was investigated for nine sites in the Recife conurbation and a fairly remote site in the area. Total aerosol samples were collected on cellulose filters for analysis by energy dispersive X-ray fluorescence and cascade impactors were used to collect the aerosols as a function of particle size for subsequent analysis by proton-induced X-ray emission. Local soil aliquots were also analysed. About eighteen elements were quantified in all cases. The average total atmospheric concentrations appeared to be well above natural levels but usually lower than, or comparable with, those of North American and European cities. Dispersal of sea spray and of local soil (often contaminated with, for example, Cu, Zn and Pb from industrial sources) contributes predominantly to the total atmospheric load in Recife. However, the particle size fraction results also indicated strong excesses in the small particle mode for S, K, V, Mn, Ni, Cu, Zn, Br and Pb, mainly in the downtown area. Again, the corresponding enrichment factors were only moderate in comparison with other published urban data.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2003-09-11
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0143-148x; 1878-0695 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:111437 Serial 7894
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Author Van Grieken, R.; Robberecht, H.; Shani, J.; Van Dyck, P.; Vos, L.
Title Energy-dispersive X-ray fluorescence for direct trace analysis of biomedical and environmental samples Type H3 Book chapter
Year (up) 1982 Publication Abbreviated Journal
Volume Issue Pages 159-178 T2 - X-ray fluorescence (XRF and PIXE) in
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:117485 Serial 7904
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Author Robberecht, H.; Van Grieken, R.; Shani, J.; Barak, S.
Title Evaluation of multi-element analysis of blood serum by energy-dispersive x-ray spectrometry Type A1 Journal article
Year (up) 1982 Publication Analytica chimica acta Abbreviated Journal
Volume 136 Issue Pages 285-292
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Conventional energy-dispersive x-ray fluorescence is applied in the analysis of blood serum to give the concentrations of 710 elements simultaneously with minimal manipulation of the samples. Simple spotting onto a Mylar carrier of 250 μl of serum, doped with two internal standards, was chosen as the sample preparation step. Some 200 serum samples, analyzed in replicate (n = 26), were used to evaluate this procedure. The detection limits are 4 μg ml-1 for K and Ca, 0.50.2 μg ml-1 for Fe, Cu, Pb and Zn, and less than 0.1 μg ml-1 for Se, Rb and Sr. Well above these limits, the standard deviation is around 10%. Comparison with the results of other measurements on the same samples indicates an accuracy of that order. The simplicity and high throughput, and the possibility of automating the x.r.f. measurements, make the proposed procedure suitable for screening large numbers of sera.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1982NL48600032 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116440 Serial 7940
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