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Author Janssens, K.; Nobels, J.; van Espen, P. pdf  doi
openurl 
  Title PC-MCA : a software package for the acquisition and processing of spectral data Type A1 Journal article
  Year 1988 Publication Chemometrics and intelligent laboratory systems Abbreviated Journal  
  Volume 3 Issue 4 Pages 335-341  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1988P260100012 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0169-7439 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:149776 Serial 5768  
Permanent link to this record
 

 
Author Janssens, K.; van Espen, P. pdf  doi
openurl 
  Title A general-purpose interface between fortran and the low-level functions of the ibm-pc Type A1 Journal article
  Year 1988 Publication Trends in analytical chemistry Abbreviated Journal  
  Volume 7 Issue 4 Pages 128-130  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1988M999800003 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0165-9936 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:149778 Serial 5450  
Permanent link to this record
 

 
Author van Espen, P.; Janssens, K.; Nobels, J. pdf  doi
openurl 
  Title AXIL-PC, software for the analysis of complex-x-ray spectra Type A1 Journal article
  Year 1986 Publication Chemometrics and intelligent laboratory systems Abbreviated Journal  
  Volume 1 Issue 1 Pages 109-114  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1986K579000015 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0169-7439 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:149781 Serial 5487  
Permanent link to this record
 

 
Author Van Dyck, P.M.; Török, S.B.; Van Grieken, R.E. doi  openurl
  Title Enhancement effect in X-ray fluorescence analysis of environmental samples of medium thickness Type A1 Journal article
  Year 1986 Publication Analytical chemistry Abbreviated Journal  
  Volume 58 Issue 8 Pages 1761-1766  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1986C955500040 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116522 Serial 7915  
Permanent link to this record
 

 
Author Bosch, B.; Leleu, M.; Oustrière, P.; Sarcia, C.; Sureau, J.F.; Blommaert, W.; Gijbels, R.; Sadurski, A.; Vandelannoote, R.; Van Grieken, R.; Van 'T Dack, L.; pdf  doi
openurl 
  Title Hydrogeochemistry in the zinclead mining district of Les Malines (Gard, France) Type A1 Journal article
  Year 1986 Publication Chemical geology Abbreviated Journal Chem Geol  
  Volume 55 Issue 1/2 Pages 31-44  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Sensitive multi-element analysis techniques together with major-element and isotopic analyses were applied to spring, mine and surface waters in the vicinity of an important known zinclead deposit in a carbonate environment, in the Les Malines area (Gard, France). Both the dissolved and suspended phases were investigated, and concretions and sediments were also considered in some cases. This methodological test shows that the ore body leaves various clear fingerprints, such as the Zn, As, Sb, Pb and U levels in the dissolved phase, the sulfate increment and the δ 34S. Some of the elements in solution are controlled by slightly soluble compounds, e.g. Zn by smithsonite and hydrozincite, Ba by barite, and Pb by hydrocerussite. Mapping the saturation indices for these elements appears useful for displaying the hydrogeochemical anomaly.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos (down) A1986C743300003 Publication Date 2003-08-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0009-2541; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.524 Times cited 3 Open Access  
  Notes Approved CRYSTALLOGRAPHY 19/26 Q3 # PHYSICS, CONDENSED MATTER 53/67 Q4 #  
  Call Number UA @ lucian @ c:irua:111481 Serial 1537  
Permanent link to this record
 

 
Author Markowicz, A.A.; Storms, H.M.; Van Grieken, R.E. doi  openurl
  Title Absorption correction in electron probe x-ray microanalysis of thin samples Type A1 Journal article
  Year 1986 Publication Analytical chemistry Abbreviated Journal  
  Volume 58 Issue 7 Pages 1282-1285  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1986C594100007 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116524 Serial 7409  
Permanent link to this record
 

 
Author Niessner, R.; Klockow, D.; Bruynseels, F.; Van Grieken, R. doi  openurl
  Title Investigation of heterogeneous reactions of PAH's on particle surfaces using laser microprobe mass analysis Type A1 Journal article
  Year 1985 Publication International journal of environmental analytical chemistry Abbreviated Journal  
  Volume 22 Issue 3/4 Pages 281-295  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Artificially generated NaCl particles were coated with PAH's by using a condensation technique. These particles were exposed to reactive gases like ozone, bromine and nitrogen dioxide. The original as well as the exposed particles were investigated by fluorimetric analysis and by LAMMA (Laser Microprobe Mass Analysis) in the desorption mode, which allows the evaporation and characterization of surfaces of single particles. The results are interpreted in terms of possible heterogeneous atmospheric reactions. The reactivity of the considered PAH's towards nitrogen dioxide was found to be negligible. The structure of the reaction products formed with ozone was partially elucidated.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1985AZE2300009 Publication Date 2007-07-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116576 Serial 8124  
Permanent link to this record
 

 
Author Bruynseels, F.; Storms, H.; Tavares, T.; Van Grieken, R. doi  openurl
  Title Characterization of individual particle types in coastal air by laser microprobe mass analysis Type A1 Journal article
  Year 1985 Publication International journal of environmental analytical chemistry Abbreviated Journal  
  Volume 23 Issue 1 Pages 1-14  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Laser Microprobe Mass Analysis (LAMMA) was used in a preliminary study to characterize aerosol particles from a beach and inland sites and from a heavily industrialized area. As many as six types of both positive and negative mass spectra with different inorganic and organic signals could be distinguished in the different particle size ranges. Information about the elemental composition and the speciation of S and N was obtained. With increasing distance from sea, progressive uptake of nitrate in seasalt particles was found. Complex particles, containing soot and organic ammonium sulfate, were also detected.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1985AZE1800001 Publication Date 2007-07-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116575 Serial 7626  
Permanent link to this record
 

 
Author Markowicz, A.A.; Storms, H.M.; Van Grieken, R.E. doi  openurl
  Title Bremsstrahlung background in electron-probe X-ray-microanalysis of thin films Type A1 Journal article
  Year 1985 Publication Analytical chemistry Abbreviated Journal  
  Volume 57 Issue 14 Pages 2885-2889  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1985AVD0100033 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113616 Serial 7567  
Permanent link to this record
 

 
Author Subramanian, V.; Van 't dack, L.; Van Grieken, R. pdf  doi
openurl 
  Title Chemical composition of river sediments from the Indian sub-continent Type A1 Journal article
  Year 1985 Publication Chemical geology Abbreviated Journal  
  Volume 48 Issue Pages 271-280  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract River sediments from all of the major drainage basins (except the Indus) in the Indian sub-continent were collected and analysed by thin-film X-ray fluorescence technique (XRF) to determine their chemical composition. On the basis of analysis of more than 120 samples, average chemical compositions of river-borne sediments from the Indian sub-continent have been calculated. Also, average concentration values for sediments from each of the river basins, and the sub-continent average and the inter-basin differences are discussed in relation to weathering processes in the drainage basins. Comparisons have been made with the chemistry of sediments from the Bay of Bengal (which receives the bulk of sediments delivered by Indian rivers). Our observations are discussed in the light of average chemical composition of world-river sediments and the world surface rock exposed for continental weathering.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1985AFW3500022 Publication Date 2003-08-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0009-2541 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:111480 Serial 7654  
Permanent link to this record
 

 
Author Roekens, E.J.; Van Grieken, R.E. pdf  doi
openurl 
  Title Kinetics of iron(II) oxidation in seawater of various pH : reply Type A1 Journal article
  Year 1984 Publication Marine chemistry Abbreviated Journal  
  Volume 15 Issue 3 Pages 281-284  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1984TZ60600009 Publication Date 2003-08-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0304-4203; 1872-7581 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116711 Serial 8141  
Permanent link to this record
 

 
Author Markowicz, A.A.; Van Grieken, R.E. doi  openurl
  Title Atomic number correction in electron probe X-ray microanalysis of curved samples and particles Type A1 Journal article
  Year 1984 Publication Analytical chemistry Abbreviated Journal  
  Volume 56 Issue 14 Pages 2798-2801  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1984TU34600040 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116519 Serial 7535  
Permanent link to this record
 

 
Author Markowicz, A.A.; Van Grieken, R.E. doi  openurl
  Title Composition dependence of Bremsstrahlung background in electron-probe x-ray microanalysis Type A1 Journal article
  Year 1984 Publication Analytical chemistry Abbreviated Journal  
  Volume 56 Issue 12 Pages 2049-2051  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1984TL48800021 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116518 Serial 7704  
Permanent link to this record
 

 
Author Verbueken, A.H.; Van Grieken, R.E.; Paulus, G.J.; De Bruijn, W.C. doi  openurl
  Title Embedded ion exchange beads as standards for laser microprobe mass analysis of biological specimens Type A1 Journal article
  Year 1984 Publication Analytical chemistry Abbreviated Journal  
  Volume 56 Issue 8 Pages 1362-1370  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1984SX51800045 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116520 Serial 7898  
Permanent link to this record
 

 
Author Verbueken, A.H.; van de Vijver, F.L.; Van Grieken, R.E.; Paulus, G.J.; Visser, W.J.; d'Haese, P.; de Broe, M.E. pdf  openurl
  Title Ultrastructural localization of aluminum in patients with dialysis-associated osteomalacia Type A1 Journal article
  Year 1984 Publication Clinical chemistry : international journal of laboratory medicine and molecular diagnostics Abbreviated Journal  
  Volume 30 Issue 5 Pages 763-768  
  Keywords A1 Journal article; Pharmacology. Therapy; Pathophysiology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract Using laser microprobe mass analysis, we studied the ultrastructural localization of aluminum in liver and bone tissue of chronic-hemodialysis patients with proven aluminum-induced osteomalacia. In the liver, aluminum was observed to be almost exclusively associated with iron. Detectable aluminum and large amounts of iron were found in lysosomes of both hepatocytes and Kupffer cells. In bone, aluminum was localized at the osteoid/calcified-bone interface and also was associated with iron in some cases.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1984SR66500043 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0009-9147; 1530-8561 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116713 Serial 8703  
Permanent link to this record
 

 
Author Bruynseels, F.J.; Van Grieken, R.E. doi  openurl
  Title Laser microprobe mass spectrometric identification of sulfur species in single micrometer-size particles Type A1 Journal article
  Year 1984 Publication Analytical chemistry Abbreviated Journal  
  Volume 56 Issue 6 Pages 871-873  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1984SP09600012 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116521 Serial 8163  
Permanent link to this record
 

 
Author Vandelannoote, R.; Blommaert, W.; Sadurski, A.; Van 'T Dack, L.; Gijbels, R.; Van Grieken, R.; Bosch, B.; Leleu, M.; Rochon, J.; Sarcia, C.; Sureau, J.F.; pdf  doi
openurl 
  Title Trace-elemental anomalies in surface water near a small lead-zinc mineralization at Menez-Albot (Brittany, France) Type A1 Journal article
  Year 1984 Publication Journal of geochemical exploration Abbreviated Journal J Geochem Explor  
  Volume 20 Issue 1 Pages 33-46  
  Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Sensitive multi-element analysis techniques were applied to water samples collected in the vicinity of a small Zn-Pb-Cu sulfide mineralization in the region of Menez-Albot (Finistère, France). The variation of the trace-element content along a local stream shows the presence of the mineralization, mainly through a simultaneous positive anomaly in solution for a group of about 10 elements (e.g. Ni, Cu, Zn, As, Sb) which are connected with this type of mineralization. The anomaly decreases steeply due to the influx of swamp water rich in Fe, Mn and organic matter. The precipitation barrier is reflected in the stream sediment composition. Contamination from fertilizers was observed in some samples.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos (down) A1984SF42900004 Publication Date 2003-08-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0375-6742; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.747 Times cited 4 Open Access  
  Notes Approved no  
  Call Number UA @ lucian @ c:irua:111449 Serial 3695  
Permanent link to this record
 

 
Author Roekens, E.J.; Van Grieken, R.E. pdf  doi
openurl 
  Title Kinetics of iron(II) oxidation in seawater of various pH Type A1 Journal article
  Year 1983 Publication Marine chemistry Abbreviated Journal  
  Volume 13 Issue 3 Pages 195-202  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The rate of iron(II) oxidation in North Sea water of pH 5.510 in the range 1025°C has been studied. The oxygenation rate depends linearly on the iron(II) and dissolved oxygen concentrations. The second-order dependence on [OH−], found by several investigators for synthetic solutions, was confirmed in seawater, but only for pOH > 6.9. For pOH < 5.9 the rate appeared to be independent of the pOH. In the intermediate range, pOH 5.96.9, corresponding to the natural pH of seawater, a first-order dependence on the pOH is obeyed. The important discrepancy in the literature between the second-order rate constant for NaCHO3 solutions and for seawater can be attributed predominantly to the incorrect assumption of a second-order pOH dependence in natural seawater. The results can be useful, for example, in predicting the effect of dumping acidic iron waste from the titanium-dioxide industry into the ocean.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1983RD52600003 Publication Date 2003-08-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0304-4203; 1872-7581 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116695 Serial 8140  
Permanent link to this record
 

 
Author Robberecht, H.J.; Van Grieken, R.E.; Van den Bosch, P.A.; Deelstra, H.; vanden Berghe, D. pdf  doi
openurl 
  Title Losses of metabolically incorporated selenium in common digestion procedures for biological material Type A1 Journal article
  Year 1982 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal  
  Volume 29 Issue 11 Pages 1025-1028  
  Keywords A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Two common procedures for wet destruction of biological materials for subsequent determination of selenium have been investigated. Rat organs and biological fluids were endogenously labelled with 75Se to monitor losses during the procedures. Addition of nitric and perchloric acids with gradual heating up to 210° seemed to be the best method: at this temperature the labelled selenium was still recovered quantitatively, and the destruction was fast and efficient.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1982PP35500009 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116568 Serial 8186  
Permanent link to this record
 

 
Author Robberecht, H.; Van Grieken, R. pdf  doi
openurl 
  Title Selenium in environmental waters : determination, speciation and concentration levels Type A1 Journal article
  Year 1982 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal  
  Volume 29 Issue 10 Pages 823-844  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract This article reviews the different methods used for the determination of selenium species in all types of environmental waters. Basic difficulties are discussed and the efficiency of the methods is explained in view of the sub-μg/1. concentration levels. Special attention is paid to preconcentration steps. Published data on speciation and concentration levels in various water samples are critically reviewed.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1982PK22900004 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113627 Serial 8509  
Permanent link to this record
 

 
Author Chakravorty, R.; Van Grieken, R. doi  openurl
  Title Co-precipitation with iron hydroxide and X-ray fluorescence analysis of trace metals in water Type A1 Journal article
  Year 1982 Publication International journal of environmental analytical chemistry Abbreviated Journal  
  Volume 11 Issue 1 Pages 67-80  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Preconcentration of transition trace ions by coprecipitation on iron-hydroxide has been combined with energy-dispersive X-ray fluorescence for environmental water analysis. The optimized preconcentration procedure implies adding 2 mg of iron to a 200 ml water sample, adding dilute NaOH up to pH 9, filtering off on a Nuclepore membrane after a 1 h equilibration time, and analyzing. Quantitative recoveries could then be obtained for Ni, Cu, Zn and Pb, e.g. at the 10 μg/l level in waters of varying salinity while Mn was partially collected. (In fact, for a given problem the iron carrier amount can be adjusted to obtain a satisfactory compromise between high recovery and low detection limit). The precision is 7-8% at the 10 μg/l level, and the detection limits are in the 0.5-1 μg/l range. Various environmental water samples are analysed by way of illustration.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1982NG99200007 Publication Date 2007-07-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116573 Serial 7676  
Permanent link to this record
 

 
Author Smits, J.; Van Grieken, R. doi  openurl
  Title Chelating 2,2′-diaminodiethylamine cellulose filters and X-ray fluorescence for preconcentration and trace analysis of natural waters Type A1 Journal article
  Year 1981 Publication International journal of environmental analytical chemistry Abbreviated Journal  
  Volume 9 Issue 2 Pages 81-92  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The 2,2′-diaminodiethylamine (DEN) functional group can be expected to have ideal properties for the chelation of transition metals and their collection from aqueous solutions, independent of the alkali and alkaline earth ions concentration. Introducing DEN into cellulose filters allows straightforward preconcentration of trace cations by a simple filtration step, and the DEN-filter constitutes a suitable target for X-ray fluorescence (XRF) analysis. The linearity between the XRF-response on the loaded DEN-filter and the trace cation concentration in the solution appears excellent, up to a total filter capacity of ca. 3 μeq.cm−2. The detection limits are around 0.5 μg. l−1 in most practical cases. Accuracy and precision are around 10%. The applicability of the proposed procedure is illustrated on a comparative basis by XRF-analysis of drinking water and surface water, after preconcentration by DEN-filtration and by alternative procedures.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1981LF48000001 Publication Date 2007-07-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116571 Serial 7638  
Permanent link to this record
 

 
Author Van Dyck, P.M.; Van Grieken, R.E. doi  openurl
  Title Absorption correction via scattered radiation in energy-dispersive X-ray fluorescence analysis for samples of variable composition and thickness Type A1 Journal article
  Year 1980 Publication Analytical chemistry Abbreviated Journal  
  Volume 52 Issue 12 Pages 1859-1864  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1980KJ65700021 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116516 Serial 7410  
Permanent link to this record
 

 
Author Smits, J.A.; Van Grieken, R.E. doi  openurl
  Title Characterization of a 2,2'-diaminodiethylamine-cellulose filter toward metal cation extraction Type A1 Journal article
  Year 1980 Publication Analytical chemistry Abbreviated Journal  
  Volume 52 Issue 9 Pages 1479-1489  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1980KB79500027 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116515 Serial 7610  
Permanent link to this record
 

 
Author Vanderborght, B.M.; Van Grieken, R.E. pdf  doi
openurl 
  Title Water analysis by spark-source mass-spectrometry after preconcentration on activated carbon Type A1 Journal article
  Year 1980 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal  
  Volume 27 Issue 5 Pages 417-422  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract For trace analyses of environmental waters, spark-source mass-spectrometry has been combined with a preconcentration procedure involving chelation of the dissolved trace elements with oxine and subsequent adsorption of the oxinates and naturally occurring organic and colloidal metal species onto activated carbon. The activated carbon is filtered off and ashed at low temperature. The residue is dissolved, an internal standard and pure graphite are added and, after drying, the electrodes are prepared. The photographically recorded mass spectrum is evaluated by a suitable computer routine. The error of the procedure is around 30%. While this preconcentration and analysis procedure is capable of measuring about 40 elements quantitatively, in practice 1025 trace elements are determined simultaneously above the 0.1-μg/l. detection limit, as is illustrated by analyses of drinking water, surface and ground water samples. Although a sophisticated technique, SSMS can be considered for regular panoramic survey analyses.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1980JR07800006 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116557 Serial 8746  
Permanent link to this record
 

 
Author Robberecht, H.J.; Van Grieken, R.E. doi  openurl
  Title Sub-part-per-billion determination of total dissolved selenium and selenite in environmental waters by X-ray fluorescence spectrometry Type A1 Journal article
  Year 1980 Publication Analytical chemistry Abbreviated Journal  
  Volume 52 Issue 3 Pages 449-453  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1980JG67900021 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116514 Serial 8613  
Permanent link to this record
 

 
Author Vanderborght, B.; Van Grieken, R. pdf  doi
openurl 
  Title Spark-source mass-spectrometric sensitivity factors for elements in a graphite matrix Type A1 Journal article
  Year 1979 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal  
  Volume 26 Issue 6 Pages 461-465  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Relative sensitivity factors for determination of 41 elements by spark-source mass-spectrometry have been measured. The samples were pressed into graphite electrodes and ionized with a radiofrequency spark. The mass spectra were recorded on a photoplate and the resulting data processed by a computer. Indium was used as standard and the relative sensitivity factors for both singly- and doubly-charged ions were determined with reference to the singly-charged indium ion, with an overall error of 30%. The mean analysis precision was 16%.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1979GX58000005 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113630 Serial 8563  
Permanent link to this record
 

 
Author van Espen, P.; Van 't dack, L.; Adams, F.; Van Grieken, R. doi  openurl
  Title Effective sample weight from scatter peaks in energy-dispersive x-ray fluorescence Type A1 Journal article
  Year 1979 Publication Analytical chemistry Abbreviated Journal  
  Volume 51 Issue 7 Pages 961-967  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1979GW66100047 Publication Date 2005-03-16  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:111404 Serial 7841  
Permanent link to this record
 

 
Author Vanderstappen, M.G.; Van Grieken, R.E. pdf  doi
openurl 
  Title Co-crystallization with 1-(2-pyridylazo)-2-naphthol, and X-ray fluorescence, for trace metal analysis of water Type A1 Journal article
  Year 1978 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal  
  Volume 25 Issue 11/12 Pages 653-658  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Adding 20mg of 1-(2-pyridylazo)-2-naphthol (PAN) to a water sample at 70°, and filtering off the precipitate after cooling, gives efficient preconcentration prior to X-ray fluorescence analysis of water. Up to the capacity of about 100 μeq of PAN used, the trace metal recoveries are around 90% or higher for Cr3+, Mn2+, Ni2+, Cu2+, Zn2+, Hg2+ and Eu3+, and above 70% for many other ions. The recovery yields usually do not vary critically with pH in the neutral pH-range, and are practically independent of the sample salinity, sample volume and trace-metal concentration. Enrichment factors as high as 2 × 105 can be achieved. Counting statistics would then allow detection limits of 0.03 ppM. The blank levels in commercial PAN, however, lead to typical detection limits of about 1 ppm. The coefficient of variation is typically in the 510% range at the 10-ppM level. The accuracy and applicability of the procedure are illustrated by comparative analyses on samples of synthetic solutions, river and drinking water.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1978GG18200005 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116556 Serial 7675  
Permanent link to this record
 

 
Author Vanderborght, B.M.; Van Grieken, R.E. doi  openurl
  Title Trace metal analysis of water containing humic substances by X-ray fluorescence Type A1 Journal article
  Year 1978 Publication International journal of environmental analytical chemistry Abbreviated Journal  
  Volume 5 Issue 3 Pages 221-237  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Chelation by oxine followed by adsorption on activated carbon results in the efficient collection of many trace metal ions, independent of the trace metal concentration and of high alkali and alkaline earth ion abundances. Preconcentration factors around 10000 are often achieved. When this preconcentration procedure is combined with energy-dispersive X-ray fluorescence, accurate and precise analysis can be carried out, as was proven in several experiments. The technique can also be applied for the determination of divalent ions in natural waters containing up to 10 ppm of humic substances. Trivalent ions can quantitatively be collected from natural water provided suKicient activated carbon is added. Omitting the oxine chelation prior to the activated carbon adsorption step still results in collection of a sometimes important fraction of the trace metal ions from natural waters. This is related to organically bound or colloidal forms of the trace metals.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos (down) A1978FR88000005 Publication Date 2007-07-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116570 Serial 8692  
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