Records |
Author |
van Malderen, H.; Van Grieken, R.; Bufetov, N.V.; Koutzenogii, K.P. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterization of individual aerosol particles in Central Siberia |
Type |
A1 Journal article |
Year |
1996 |
Publication |
Environmental science and technology |
Abbreviated Journal |
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Volume |
30 |
Issue |
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Pages |
312-321 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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A1996TN49700065 |
Publication Date |
2002-07-26 |
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Edition |
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ISSN |
0013-936x; 1520-5851 |
ISBN |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:14636 |
Serial |
7648 |
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Author |
Bruynseels, F.; Storms, H.; Van Grieken, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterization of individual aerosol particles from remote and polluted marine air |
Type |
P3 Proceeding |
Year |
1985 |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117497 |
Serial |
7647 |
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Author |
Bruynseels, F.; Storms, H.; Van Grieken, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterization of airborne particulate matter above the North Sea |
Type |
P3 Proceeding |
Year |
1985 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117500 |
Serial |
7646 |
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Author |
Spolnik, Z.; Worobiec, A.; Injuk, J.; Neilen, D.; Schellen, H.; Van Grieken, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterization of airborne particles in St. Martinus Cathedral in Weert, The Netherlands |
Type |
A1 Journal article |
Year |
2004 |
Publication |
Microchimica acta |
Abbreviated Journal |
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Volume |
145 |
Issue |
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Pages |
223-227 |
Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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000221453500037 |
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2004-04-21 |
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no |
Call Number |
UA @ admin @ c:irua:44334 |
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7645 |
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Author |
Ravindra, K.; Stranger, M.; Van Grieken, R.; Sokhi, R.S. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterization and source apportionment of fine aerosols |
Type |
H3 Book chapter |
Year |
2009 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISBN |
978-1-905313-64-8 |
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no |
Call Number |
UA @ admin @ c:irua:97558 |
Serial |
7644 |
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Author |
Ravindra, K.; Stranger, M.; Van Grieken, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterization and multivariate analysis of atmospheric PM2.5 particles |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Journal of atmospheric chemistry |
Abbreviated Journal |
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Volume |
59 |
Issue |
3 |
Pages |
199-218 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The new European Council Directive (PE-CONS 3696/07) frames the inhalable (PM10) and fine particles (PM2.5) on priority to chemically characterize these fractions in order to understand their possible relation with health effects. Considering this, PM2.5 was collected during four different seasons to evaluate the relative abundance of bulk elements (Cl, S, Si, Al, Br, Cu, Fe, Ti, Ca, K, Pb, Zn, Ni, Mn, Cr and V) and water soluble ions (F−, Cl−, NO2 −, NO3 −, SO4 2−, Na+, NH4 +, Ca2+ and Mg2+) over Menen, a Belgian city near the French border. The air quality over Menen is influenced by industrialized regions on both sides of the border. The most abundant ionic species were NO3 −, SO4 2− and NH4 +, and they showed distinct seasonal variation. The elevated levels of NO3 − during spring and summer were found to be related to the larger availability of the NOx precursor. The various elemental species analyzed were distinguished into crustal and anthropogenic source categories. The dominating elements were S and Cl in the PM2.5 particles. The anthropogenic fraction (e.g. Zn, Pb, and Cu) shows a more scattered abundance. Furthermore, the ions and elemental data were also processed using principal component analysis and cluster analysis to identify their sources and chemistry. These approach identifies anthropogenic (traffic and industrial) emissions as a major source for fine particles. The variations in the natural/anthropogenic fractions of PM2.5 were also found to be a function of meteorological conditions as well as of long-range transport of air masses from the industrialized regions of the continent. |
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000258087700004 |
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2008-07-08 |
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Edition |
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ISSN |
0167-7764 |
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no |
Call Number |
UA @ admin @ c:irua:70640 |
Serial |
7643 |
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Author |
van Malderen, H.; de Bock, L.; Hoornaert, S.; Injuk, J.; Van Grieken, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterisation, source identification and quantification of the input of atmospheric particulate matter into the North Sea |
Type |
H3 Book chapter |
Year |
1996 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
103-112
T2 - Dialogue between scientists and users |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:14671 |
Serial |
7642 |
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Author |
Roekens, E.; Leysen, L.; Van Grieken, R.; Komy, Z. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical characterisation of weathering crust and run-off water for a deteriorated limestone cathedral |
Type |
P3 Proceeding |
Year |
1986 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:117506 |
Serial |
7641 |
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Author |
Aerts, A.; Janssens, K.; Adams, F. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical analysis of the powder deposit on Chinese jade objects |
Type |
H3 Book chapter |
Year |
1995 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
12-13 |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:10986 |
Serial |
5510 |
Permanent link to this record |
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Author |
Gijbels, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical analysis in metal processing: overview and future needs in refined and ultrapure metals |
Type |
A3 Journal article |
Year |
1991 |
Publication |
Acta technica Belgica: metallurgie |
Abbreviated Journal |
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Volume |
30 |
Issue |
4 |
Pages |
91-98 |
Keywords |
A3 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
Abstract |
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Place of Publication |
Brussel |
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Publication Date |
0000-00-00 |
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Abbreviated Series Title |
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Series Issue |
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Edition |
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ISSN |
0365-7302 |
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no |
Call Number |
UA @ lucian @ c:irua:711 |
Serial |
342 |
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Author |
Monico, L.; Hendriks, E.; Geldof, M.; Miliani, C.; Janssens, K.; Brunetti, B.G.; Cotte, M.; Vanmeert, F.; Chieli, A.; Van der Snickt, G.; Romani, A.; Melo, M.J. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chemical alteration and colour changes in the Amsterdam sunflowers |
Type |
H1 Book chapter |
Year |
2019 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
125-158
T2 - Van Gogh’s Sunflowers illuminated – a |
Keywords |
H1 Book chapter; Art; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES) |
Abstract |
This chapter provides a description of colour changes in the Amsterdam Sunflowers due to chemical alteration of pigments, with a focus on geranium lakes and chrome yellows. The brilliant and forceful colours of these and other late nineteenth-century synthetic materials offered artists such as Vincent van Gogh new means of artistic expression that exploited a range of contrasting hues and tints. However, geranium lakes have a strong tendency to fade and chrome yellows to darken under the influence of light. Van Gogh, like other artists of his day, was aware of this drawback, yet he continued to favour the use of both pigments up until his death in July 1890 due to the unparalleled effects they gave. In April 1888, Vincent wrote to his brother Theo: Van Gogh's use of unstable colours opens a series of questions regarding the extent to which colour change affects the way his paintings look today, as discussed here in relation to the Amsterdam Sunflowers. Furthermore, given the frequency with which geranium lakes and chrome yellows occur in Van Gogh's paintings of the period 1888–90 and the predominance of chrome yellows in Sunflowers, it becomes important to understand the factors that can drive these processes of deterioration in order to develop appropriate strategies for conserving the artist's works. |
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Publication Date |
2020-11-25 |
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Edition |
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ISSN |
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ISBN |
978-94-6372-532-3 |
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no |
Call Number |
UA @ admin @ c:irua:190779 |
Serial |
7640 |
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Author |
Van Grieken, R.E.; Bresseleers, C.M.; Vanderborght, B.M. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chelex-100 ion-exchange filter membranes for preconcentration in x-ray-fluorescence analysis of water |
Type |
A1 Journal article |
Year |
1977 |
Publication |
Analytical chemistry |
Abbreviated Journal |
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Volume |
49 |
Issue |
9 |
Pages |
1326-1331 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
A1977DP25600011 |
Publication Date |
2005-03-08 |
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Abbreviated Series Title |
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Edition |
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ISSN |
0003-2700; 5206-882x |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:113632 |
Serial |
7639 |
Permanent link to this record |
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Author |
Smits, J.; Van Grieken, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Chelating 2,2′-diaminodiethylamine cellulose filters and X-ray fluorescence for preconcentration and trace analysis of natural waters |
Type |
A1 Journal article |
Year |
1981 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
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Volume |
9 |
Issue |
2 |
Pages |
81-92 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The 2,2′-diaminodiethylamine (DEN) functional group can be expected to have ideal properties for the chelation of transition metals and their collection from aqueous solutions, independent of the alkali and alkaline earth ions concentration. Introducing DEN into cellulose filters allows straightforward preconcentration of trace cations by a simple filtration step, and the DEN-filter constitutes a suitable target for X-ray fluorescence (XRF) analysis. The linearity between the XRF-response on the loaded DEN-filter and the trace cation concentration in the solution appears excellent, up to a total filter capacity of ca. 3 μeq.cm−2. The detection limits are around 0.5 μg. l−1 in most practical cases. Accuracy and precision are around 10%. The applicability of the proposed procedure is illustrated on a comparative basis by XRF-analysis of drinking water and surface water, after preconcentration by DEN-filtration and by alternative procedures. |
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A1981LF48000001 |
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2007-07-07 |
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Edition |
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ISSN |
0306-7319 |
ISBN |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116571 |
Serial |
7638 |
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Author |
Shi, J.M.; Koenraad, P.M.; van de Stadt, A.F.W.; Peeters, F.M.; Devreese, J.T.; Wolter, J.H. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Charged-impurity correlations in Si ?-doped GaAs |
Type |
P3 Proceeding |
Year |
1996 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
2351-2354 |
Keywords |
P3 Proceeding; Condensed Matter Theory (CMT); Theory of quantum systems and complex systems |
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Place of Publication |
Singapore |
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Publication Date |
0000-00-00 |
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MATERIALS SCIENCE, MULTIDISCIPLINARY 135/271 Q2 # PHYSICS, APPLIED 70/145 Q2 # PHYSICS, CONDENSED MATTER 40/67 Q3 # |
Call Number |
UA @ lucian @ c:irua:20368 |
Serial |
341 |
Permanent link to this record |
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Author |
Koenraad, P.M.; Shi, J.M.; van de Stadt, A.F.W.; Smets, A.; Perenboom, J.A.A.J.; Peeters, F.M.; Devreese, J.T.; Wolter, J.H. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Charged-impurity correlations in a δ-doped quantum barrier |
Type |
P3 Proceeding |
Year |
1996 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
2351-2354 |
Keywords |
P3 Proceeding; Condensed Matter Theory (CMT); Theory of quantum systems and complex systems |
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Publisher |
World Scientific |
Place of Publication |
Singapore |
Editor |
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Publication Date |
0000-00-00 |
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no |
Call Number |
UA @ lucian @ c:irua:15806 |
Serial |
340 |
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Author |
Sabzalipour, A. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Charge transport in magnetic topological insulators |
Type |
Doctoral thesis |
Year |
2021 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
xiv, 185 p. |
Keywords |
Doctoral thesis; Condensed Matter Theory (CMT) |
Abstract |
Novel quantum phases of matter and developing practical control over their characteristics is one of the primary aims of current condensed matter physics. It offers the potential for a new generation of energy, electronic and photonic technologies. Among all the newly found phases of matter, topological insulators are novel phases of quantum matter with fascinating bulk band topology and surface states protected by specific symmetries. For example, at the boundary of a strong topological insulator and a trivial insulator, metallic surface states appear that are protected by time-reversal symmetry. As a result, the bulk continues to be insulating, while the surface can support exotic high-mobility spin-polarized electronic states. Since there is no such thing as a clean system, impurities and other disorders are always present in materials. Even while impurities appear to be unfavorable to a system at first look, doping the host system with impurities allows us to engineer different electronic properties of systems, such as the Fermi level or electron density. Because of the symmetry protected metallic states in topological insulators, charge transport responds distinctively to magnetic and non-magnetic impurities. This doctoral dissertation explores how the longitudinal charge transport in magnetic topological thin films and the anomalous Hall effect on the surface of 3D magnetic topological insulators is influenced by point-like and randomly distributed dilute magnetic impurities. We are interested in how charge transport in these systems responds to the orientation of the magnetization orientation and how this response evolves based on the system's main characteristics, such as the magnitude of the Fermi level or gate voltage. Because topological insulators have a strong spin-orbit coupling, the interaction between conducting electrons and local magnetic impurities is very anisotropic. We will show that this anisotropy even enhances when magnetic topological thin films are exposed to a substrate or gate voltage. Therefore, to properly capture this anisotropy in charge transport calculations, we rely on a generalized Boltzmann formalism together with a modified relaxation time scheme. We show that magnetic impurities affect the charge transport in topological insulators by inducing a transition selection rule that governs scatterings of electrons between various electronic states. We see that this selection rule is highly sensitive to the spin direction of the magnetic impurities as well as the position of the Fermi level. According to this selection rule and depending on the position of the Fermi level, two different transport regimes are realized in magnetic topological thin films. In one of these regimes, our findings show that a dissipation less charge current can be generated. In other words, even if there are many magnetic impurities in the system, electrons do not notice them and, remarkably, conduct charge without dissipation. Outside this regime, the charge transport is always dissipative and its sensitivity to the spatial orientation of the magnetic impurities can be effectively modulated by a substrate or gate voltage. In this doctoral thesis, we also explore the anomalous Hall effect (AHE) on the surface of 3D magnetic topological insulators. The AHE is generated by three mechanisms: the intrinsic effect (owing to a nonzero Berry curvature), the side jump effect, and the skew scattering effect. They compete to dominate the AHE in distinct regimes. Analytically, we calculate the contributions of all three mechanisms to the scattering of massive Dirac fermions by magnetic impurities. Our results reveal three transport regimes based on the relative importance of the engaged mechanisms. The identification of these three distinctive transport regimes can assist experimentalists in achieving a regime in which each contribution is dominant over the others, allowing them to measure them separately. Typically, this is not feasible empirically since the total value of the experimentally observed AHE conceals the specific information of each of the three contributions. Based on our analytical calculations, we prove that the AHE can change sign by varying the orientation of the surface magnetization, the concentration of impurities, and the location of the Fermi level, which is consistent with previous experimental findings. In addition, we show that by suitably adjusting the given parameters, any contribution to the AHE, or even the entire AHE, can be turned off. For example, in a system with in-plane magnetization, one can turn off the AHE by pushing the system into the completely metallic regime. Furthermore, we demonstrate that any contribution to the AHE, or even the whole AHE, can be turned off by appropriately changing the provided parameters. For example, in a system with in-plane magnetization, the AHE can be turned off by pushing the system into the fully metallic regime. |
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Call Number |
UA @ admin @ c:irua:182192 |
Serial |
6973 |
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Author |
Hervieu, M.; Martin, C.; Van Tendeloo, G.; Mercey, B.; Maignan, A.; Jirak, Z.; Raveau, B. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Charge ordering and phase transitions in perovskite manganites: correlation with CMR properties |
Type |
H3 Book chapter |
Year |
2000 |
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Volume |
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Issue |
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Pages |
179-182 |
Keywords |
H3 Book chapter; Electron microscopy for materials research (EMAT) |
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s.l. |
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0000-00-00 |
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Most recent IF: NA |
Call Number |
UA @ lucian @ c:irua:54728 |
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336 |
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Kontozova-Deutsch, V.; Deutsch, F.; Krata, A.; Van Grieken, R. |
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Charakterystyka i wpływ zanieczyszczeń powietrza na eksponaty w muzeach |
Type |
A3 Journal article |
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2008 |
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Análityka |
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1 |
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64-68 |
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A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Call Number |
UA @ admin @ c:irua:67549 |
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7637 |
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Lind, O.C.; Claussen-Kjerre, L.; de Nolf, W.; Falkenberg, G.; Jaroszewicz, J.; Janssens, K.; Salbu, B. |
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Characterization of Yenisey River U-particles using a combination of μ-XRF, μ-XRD and U-LIII μ-XANES |
Type |
H3 Book chapter |
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2008 |
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Pages |
1279-1280 |
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H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Most recent IF: NA |
Call Number |
UA @ admin @ c:irua:74471 |
Serial |
5508 |
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Author |
Leysen, L.A.; Roekens, E.J.; Van Grieken, R.E.; De Geyter, G. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Characterization of the weathering crust of various historical buildings in Belgium |
Type |
A1 Journal article |
Year |
1990 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
90 |
Issue |
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Pages |
117-147 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
A variety of samples, collected from different historical buildings and monuments throughout Belgium, were thoroughly studied, using several trace- and micro-analysis techniques. Thin sections of stones and mortar joints were characterized by means of electron probe X-ray microanalysis (EPXMA). The morphological appearance of the surface weathering crust and the possible presence of non-innate particles in the crust were elucidated using petrographical and electron microscopy. Quantitative characterization of the total chemical composition of the crust surface layer and underlying layer was performed by energy-dispersive X-ray fluorescence, and by ion chromatography and atomic absorption spectrometry for the leachable components. Special attention was also paid to the chemical composition of rain and air at the particular sampling sites. The element distribution in the transition zone between the weathering crust and the original stone material was found to vary greatly amongst the different samples analyzed. Detailed EPXMA measurements on pieces of the weathering crust showed remarkable differences in morphology and composition between the surface and the underlying layer, and provided information about the presence of fly-ash and soil dust particles in the crust. Except for crusts from the city of Brussels, which were all very high in sulphate, the samples appeared to contain very variable sulphate contents; very local micro-climate and environmental conditions at a particular site are more important in determining the weathering condition of the building stones than the local air pollution situation. Bulk analytical characterization further showed, in all the crust samples studied, a very small contribution of nitrogen- and chlorine-containing weathering products, in contrast to sulphur-containing weathering salts. |
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A1990CJ43500010 |
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2003-09-12 |
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0048-9697; 1879-1026 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116650 |
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7636 |
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Vandeputte, D.F.; Van Grieken, R.E.; Foets, B.J.J.; Misotten, L. |
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Characterization of the spheroliths present in primary atypical bandkeratopathy using laser microprobe mass analysis |
Type |
A1 Journal article |
Year |
1989 |
Publication |
Biomedical and environmental mass spectrometry |
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Volume |
18 |
Issue |
9 |
Pages |
753-756 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Laser microprobe mass analysis was applied to study the chemical composition of spheroliths in the Bowman's membrane of patients suffering from primary atypical bandkeratopathy. The inclusions appear to consist mainly of calcium phosphate. |
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2005-05-29 |
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0887-6134 |
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UA @ admin @ c:irua:116824 |
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7635 |
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Schalm, O.; Janssens, K.; Caen, J. |
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Characterization of the main causes of deterioration of grisaille paint layers in 19th C. stained-glass windows by J.-B. Capronnier |
Type |
A1 Journal article |
Year |
2003 |
Publication |
Spectrochimica acta: part B : atomic spectroscopy |
Abbreviated Journal |
Spectrochim Acta B |
Volume |
58 |
Issue |
4 |
Pages |
589-607 |
Keywords |
A1 Journal article; Art; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Twenty-seven glass fragments containing dark coloured grisaille paint layers of different qualities were collected from ten windows of the cathedral St. Michael & St. Gudule in Brussels (Belgium). The windows were made by J.-B. Capronnier (18141891) and cover the period between 1843 and 1878. The samples were cross-sectioned and examined in an electron microscope. Grisaille paint layers are not homogeneous and therefore, it is not meaningful to characterize them in terms of their average composition. Instead, parameters such as granularity, the number of residual gas bubbles per running millimetre of paint, the type of pigments, and the thickness of the paint layer were used to characterize them. The microscopic morphology allows a classification of the grisaille paint layers in four groups, every group associated with a quality level. Moreover, the main causes of the accelerated degradation of some of these paint layers could be explained. The classification made it possible to distinguish two periods in the work of Capronnier: (1) the early period (18431848) is characterized by the presence of either single granular paint layers or of double-layered systems consisting of a granular paint layer on top of a well-melted paint layer. The granular grisaille paint layers tend to pulverize; (2) the later period (18481878) is characterized by the presence of only well-vitrified paint layers. No sign of deterioration was found on the well-vitrified paint layers. |
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000182744200002 |
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2003-04-23 |
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ISSN |
0584-8547; 0038-6987 |
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UA library record; WoS full record; WoS citing articles |
Impact Factor |
3.241 |
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Most recent IF: 3.241; 2003 IF: 2.361 |
Call Number |
UA @ admin @ c:irua:41208 |
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5505 |
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Author |
Godoi, R.H.M.; Lima Bittencourt, A.V.; Hirata, P.Y.; Jafelicci Junior, M.; dos Reis Neto, J.M.; Van Grieken, R. |
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Characterization of the ionic and particulate systems in the reservoir |
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H2 Book chapter |
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2014 |
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Pages |
143-159
T2 - Reservoir eutrophication : preventive |
Keywords |
H2 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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9781780406473 |
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Call Number |
UA @ admin @ c:irua:119046 |
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7634 |
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Maenhaut, W.; Raemdonck, H.; Selen, A.; Van Grieken, R.; Winchester, J.W. |
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Characterization of the atmospheric aerosol over the eastern equatorial Pacific |
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A1 Journal article |
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1983 |
Publication |
Journal of geophysical research |
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88 |
Issue |
C:9 |
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5353-5364 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
By using a polyester sailboat as sampling platform, a series of duplicate aerosol samples was collected by cascade impactors on a trip from Panama to Tahiti in 1979. Elemental analysis mainly by particle-induced X ray emission (PIXE) indicated, in the samples collected between Panama and the Galapagos Islands, the presence of a substantial crustal component (∼0.4 μg/m3), fine Cu (∼0.4 ng/m3) and Zn (∼0.6 ng/m3), and excess fine S and K (∼100 and ∼2.4 ng/m3, respectively) in addition to the major sea salt elements. The crustal component and fine Cu and Zn are suggested to result from natural continental sources (i.e., eolian dust transport from the American continents and perhaps geothermal emissions). Samples collected west of the Galapagos Islands in the southern trades showed significantly lower concentrations for the nonseawater components. The average Si and Fe levels were as low as 4.8 and 3.3 ng/m3, corresponding to a maximum of 0.066 μg/m3 for an assumed mineral dust component, whereas heavy metal concentrations were all below the detection limits (typically ranging from 0.05 to 0.15 ng/m3 for V, Cr, Mn, Ni, Cu, Zn, and Se). Excess fine S decreased to a mean of 46 ng/m3, a level similar to those reported for other remote marine and continental locations. This all indicates that the marine atmosphere west of the Galapagos was little influenced by natural continental source processes or by anthropogenic emissions. Under these truly marine conditions, several concentration ratios of the major seawater elements were significantly different from those in bulk seawater. Ca, Sr, and S in >1 μm diameter particles were enriched relative to K and Na, with the enrichment being substantially more pronounced (up to 50% or higher) for l4-μm diameter particles than for particles >4 μm. Comparison of these data with a similar data set from samples collected over the Atlantic indicates that the departures from seawater composition are significantly larger for the Pacific. Differences in sea-to-air fractionation processes, probably involving binding of divalent cations to organic matter in the oceanic surface microlayer, are suggested as being responsible for these observations. |
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A1983QU67600025 |
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2008-02-06 |
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ISSN |
0148-0227; 2156-2202; 0022-1406; 0196-6928; 0196-6936; 0885-3401; 8755-8556; 0196-2256; 0747-7309; 1 |
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UA library record; WoS full record; WoS citing articles |
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Call Number |
UA @ admin @ c:irua:113625 |
Serial |
7633 |
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Author |
Leroux, F. |
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Characterization of soft-hard matter composite materials by advanced transmission electron microscopy |
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Doctoral thesis |
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2012 |
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Doctoral thesis; Electron microscopy for materials research (EMAT) |
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Universiteit Antwerpen, EMAT |
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Antwerpen |
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0000-00-00 |
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Most recent IF: NA |
Call Number |
UA @ lucian @ c:irua:99023 |
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333 |
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Petrovic, M. |
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Characterization of scanning gate technique and transport in nanostructured graphene |
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Doctoral thesis |
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2017 |
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Doctoral thesis; Condensed Matter Theory (CMT) |
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Antwerpen |
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Call Number |
UA @ lucian @ c:irua:144015 |
Serial |
4590 |
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Bruynseels, F.; Storms, H.; Van Grieken, R.; Van der Auwera, L. |
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Characterization of North-Sea aerosols by individual particle analyses |
Type |
A1 Journal article |
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1988 |
Publication |
Atmospheric environment : an international journal |
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22 |
Issue |
11 |
Pages |
2593-2602 |
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A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
On aerosol and rain water samples, collected in the Southern Bight of the North Sea, single particle analyses were performed using both laser microprobe mass analysis and electron-probe X-ray microanalysis in combination with an automated image analysis system. In the aerosols collected from an air mass that had travelled from the Atlantic Ocean along the coast of North France, pure seasalt constituted the most abundant particle type, while aluminosilicates (mostly spherical fly-ash particles) amounted to about 20% and mixed seasalt/aluminosilicate, carbonaceous particles, CaSO4 and spherical iron oxides contributed each 510 %. In air masses that had a longer residence time over the continent, spherical iron oxides, carbonaceous particles and ammonium sulfates together made up 70 % of the total particle load. Seasalt particles were nearly all enriched in sulfate or nitrate, but they were seen to be washed out efficiently after a rain shower. In rain water, some 40 % of the particles appeared to be spherical or irregularly shaped aluminosilicates, from fly-ash and dust dispersal, but more than 50 % consisted of SiO2. The high relative abundance of these particles in rain water may be the result of Al leaching from fly-ash, or of more efficient scavenging by rain droplets. |
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A1988R523900028 |
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2003-08-06 |
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1352-2310 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:113610 |
Serial |
7632 |
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Author |
Wiktor, C. |
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Characterization of metal-organic frameworks and other porous materials via advanced transmission electron microscopy |
Type |
Doctoral thesis |
Year |
2014 |
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Doctoral thesis; Electron microscopy for materials research (EMAT) |
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Antwerpen |
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0000-00-00 |
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Most recent IF: NA |
Call Number |
UA @ lucian @ c:irua:123905 |
Serial |
325 |
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Author |
Yang, T. |
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Characterization of Laves phase structural evolution and regulation of its precipitation behavior in Al-Zn-Mg based alloys |
Type |
Doctoral thesis |
Year |
2023 |
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Volume |
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Issue |
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Pages |
ii, 106 p. |
Keywords |
Doctoral thesis; Electron microscopy for materials research (EMAT) |
Abstract |
Al-Zn-Mg-based high strength alloys are widely used in aerospace applications due to their low density and excellent mechanical properties. A systematic study of the structural evolution of the nano-precipitation phase and its growth mechanism is an important guide for the design of new high-strength alloys. In this work, the Laves structure precipitates in Al-Zn-Mg(-Cu/Y) alloy was systematically characterized. Based on the structure evolution, the structure of submicron Laves particles and quasicrystalline particles in the alloy at microscale, as well as the regulation of the precipitation behavior after adding Y at nanoscale were further investigated. The main innovative results are summarized as follows: (1) Investigation on coexistence of defect structures in Laves structural nanoprecipitates. Three types of Laves structures can coexist within the η-MgZn2 precipitates: C14, C15 and C36, and the Laves structure transition sequence of C14→C36→C15 in this system was determined. Meanwhile, it was found that there are diverse defect structures in the MgZn2 phase, including stacking faults, planar defects and five-fold domain structures, which have significant effects on relieving the internal stress/strain of the precipitates. (2) Investigation on multiple phase transition of Laves structural nanoprecipitates from C14 to C36 and from C14 to quasicrystal clusters. It is found that C14 precipitates can be completely transformed into the C36 precipitates. And it is also found that the C14 Laves phase structure can also transform into quasicrystalline clusters. These investigations on various phase transition mechanisms among Laves phases provide theoretical support for the microstructural characterization of materials containing multi-scale Laves phases. (3) Characterization of Laves and quasicrystal structural particles in submicron scale. Submicron-scale quasicrystal particles were obtained in conventional casting Al-Zn-Mg-Cu alloys for the first time. Industrial impurity elements Fe and Ni can induce the formation of quasicrystalline particles. When there is no Fe/Ni enriched in particles, the structure is characterized as C15-Laves phase. When Fe/Ni is as quasicrystalline core, a stable core-shell quasicrystalline structure with Al-Fe-Ni nucleus and Mg-Cu-Zn shell can be formed. (4) Investigation on the regulation of nanoscale Laves precipitates’ growth. To regulate the defect structure of the precipitates, rare earth element Y was added in Al-Zn-Mg alloys and its influence on the precipitation behavior was investigated. The addition of Y element can dynamically combine with different alloying elements during aging process, which can refine the size of precipitate and further improve the nucleation rate and precipitation rate of the precipitates. |
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UA @ admin @ c:irua:196404 |
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7631 |
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Author |
Kontozova-Deutsch, V.; Cardell, carolina; Urosevic, M.; Ruiz-Agudo, E.; Deutsch, F.; Van Grieken, R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Characterization of indoor and outdoor atmospheric pollutants impacting architectural monuments : the case of San Jerónimo Monastery (Granada, Spain) |
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A1 Journal article |
Year |
2011 |
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Environmental earth sciences |
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63 |
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7/8 |
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1433-1445 |
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A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Indoor and outdoor concentrations of atmospheric gaseous pollutants as well as composition, size, and morphology of particulate matter have been investigated at the monastery of San Jerónimo in Granada (Southern Spain). Complementary micro- and nano-analytical techniques were applied; elemental and mineralogical composition and morphological characteristics of particulate matter were investigated combining electron probe microanalysis at the single particle level, and bulk aerosol samples were analyzed using energy-dispersive X-ray fluorescence, X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray analyzer and transmission electron microscopy (TEM). Microclimatic conditions at the monastery were monitored, and gas concentrations were assessed by means of diffusion tubes subsequently analyzed with ion chromatography. Results revealed high abundances of soil dust particles (aluminosilicates, calcite, dolomite, quartz), salt aerosols (chlorides, sulfates and ammonium-rich salts), and NO2 and SO2 both outdoors and indoors. Amorphous black carbon particles had surprisingly high abundances for Granada, a non-industrialized city. The composition of indoor particles corresponds to severe weathering affecting the construction materials and artworks inside the church; moreover their composition promotes a feedback process that intensifies the deterioration. Chemical reactions between chloride-rich salts and pigments from paintings were confirmed by TEM analyses. Indoors, blackening of surface decorative materials is fostered by particle re-suspension due to cleaning habits in the monastery (i.e. dusting). This is the first air quality study performed in a monument in the city of Granada with the aim of developing a strategy for preventive conservation. |
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000292744300003 |
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2010-07-19 |
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1866-6280 |
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UA @ admin @ c:irua:90766 |
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7630 |
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