NANOlab Center of Excellence literature database -- Query Results

<< 1 2 3 4 >>

Details

Records
Author	Van Tendeloo, G.; De Meulenaere, P.; Letouzé, F.; Martin, C.; Hervieu, M.; Raveau, B.
Title	Cation ordering in [(Tl, M)O] layers of “1202”-based cuprates : similarity to ordering in fcc-based alloys			Type	A1 Journal article
Year	1997	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	132	Issue		Pages	113-122
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	''1201'' Tl-based substituted cuprates of the type (Tl1-xMx) Sr2CuO5 have been synthesized for M = Nb, Ta, or W. These materials do not superconduct due to a statistical distribution of some of the M for Cu. The remarkable feature of these materials is the ordering observed between Tl and M in the (Tl1-xMx-epsilon)O plane. The type of ordering depends on the composition and shows remarkable similarities with the ordering in Ni-Mo or other so-called 1 1/2 0 type fcc-based alloys or with the ordering in rocksalt oxides TiOx. The short-range order, for M = W, can be readily interpreted in terms of a mixing of nano-clusters with two different compositions. These observations of two-dimensional ordering confirm recent ideas about ordering in three-dimensional fcc-based alloys.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1997XY68900015	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	2	Open Access
Notes				Approved	Most recent IF: 2.299; 1997 IF: 1.486
Call Number	UA @ lucian @ c:irua:21448			Serial	299
Permanent link to this record



Author	Khasanova, N.R.; Van Tendeloo, G.; Lebedev, O.I.; Amelinckx, S.; Grippa, A.Y.; Abakumov, A.M.; Istomin, S.Y.; D'yachenko, O.G.; Antipov, E.V.
Title	A new structure type of the ternary sulfide Eu_1.3Nb_1.9S₅			Type	A1 Journal article
Year	2002	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	164	Issue	2	Pages	345-353
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000174848000020	Publication Date	2002-10-06
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	2	Open Access
Notes				Approved	Most recent IF: 2.299; 2002 IF: 1.671
Call Number	UA @ lucian @ c:irua:54714			Serial	2334
Permanent link to this record



Author	Frangis, N.; Van Tendeloo, G.; Manolikas, C.; Amelinckx, S.
Title	Structural and microstructural aspects of Six(Ta, Nb)Te2			Type	A1 Journal article
Year	1998	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	139	Issue		Pages	105-123
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000075511800013	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	2	Open Access
Notes				Approved	Most recent IF: 2.299; 1998 IF: 1.432
Call Number	UA @ lucian @ c:irua:25664			Serial	3199
Permanent link to this record



Author	Huvé, M.; Van Tendeloo, G.; Amelinckx, S.; Hervieu, M.; Raveau, B.
Title	Structural aspects of modulated superconducting oxides: application to Hg_1-xTl_xSr_4-yBa_yCu₂CO₃O_7-\delta			Type	A1 Journal article
Year	1995	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	120	Issue		Pages	332-342
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1995TN20700018	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.133	Times cited	2	Open Access
Notes				Approved
Call Number	UA @ lucian @ c:irua:13327			Serial	3209
Permanent link to this record



Author	Pshirkov, J.S.; Kazakov, S.M.; Abakumov, A.M.; Putilin, S.N.; Antipov, E.V.; Bougerol-Chaillout, C.; Lebedev, O.I.; Van Tendeloo, G.
Title	Synthesis and characterization of new phases: Sr_3.75K_1.75Bi₃O₁₂ and Sr_3.1Na_2.9Bi₃O₁₂			Type	A1 Journal article
Year	2000	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	152	Issue	2	Pages	492-502
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000088056400025	Publication Date	2002-09-18
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	2	Open Access
Notes				Approved	Most recent IF: 2.299; 2000 IF: 1.527
Call Number	UA @ lucian @ c:irua:54706			Serial	3414
Permanent link to this record



Author	Chin, C.-M.; Battle, P.D.; Hunter, E.C.; Avdeev, M.; Hendrickx, M.; Hadermann, J.
Title	Stabilisation of magnetic ordering in La₃Ni_2-xCu_xB'O₉(B'=Sb,Ta,Nb) by the introduction of Cu²⁺			Type	A1 Journal article
Year	2019	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	276	Issue	276	Pages	164-172
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	La3Ni2-xCuxB'O-9 (x = 0.25; B' = Sb, Ta, Nb: x = 0.5; B' = Nb) have been synthesized and characterised by transmission electron microscopy, neutron diffraction and magnetometry. Each adopts a perovskite-like structure (space group P2(1)/n) with two crystallographically-distinct six-coordinate sites, one occupied by a disordered arrangement of Ni2+ and Cu2+ and the other by a disordered similar to 1:2 distribution of Ni2+ and B'(5+), although some Cu2+ is found on the latter site when x = 0.5. Each composition undergoes a magnetic transition in the range 90 <= T/K <= 130 and shows a spontaneous magnetisation at 5 K; the transition temperature always exceeds that of the x = 0 composition by >= 30 K. A long-range ordered G-type ferrimagnetic structure is present in each composition, but small relaxor domains are also present. This contrasts with the pure relaxor and spin-glass behaviour of x = 0, B' = Ta, Nb, respectively.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000473372400023	Publication Date	2019-05-09
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	2	Open Access
Notes	; We thank EPSRC for funding through grant EP/M0189541. CMC thanks the Croucher Foundation and the University of Oxford for the award of a graduate scholarship. ;			Approved	Most recent IF: 2.299
Call Number	UA @ admin @ c:irua:161199			Serial	5396
Permanent link to this record



Author	Volkov, V.V.; Van Tendeloo, G.; van Landuyt, J.; Amelinckx, S.; Busheva, E.E.; Shabunina, G.G.; Aminov, T.G.; Novotortsev, V.M.
Title	HREM image analysis up to structure determination of SbCrSe₃: a new 1D ferromagnet			Type	A1 Journal article
Year	1997	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	132	Issue		Pages	257-266
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1997YE01700005	Publication Date	0000-00-00
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	1	Open Access
Notes				Approved	Most recent IF: 2.299; 1997 IF: 1.486
Call Number	UA @ lucian @ c:irua:21421			Serial	1500
Permanent link to this record



Author	Lebedev, O.I.; Caignaert, V.; Raveau, B.; Pop, N.; Gozzo, F.; Van Tendeloo, G.; Pralong, V.
Title	HRTEM and neutron diffraction study of Li_xMo₅O₁₇ : from the ribbon (x=5) structure to the rock salt (x=12) structure			Type	A1 Journal article
Year	2011	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	184	Issue	4	Pages	790-796
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Structure determination of the fully intercalated phase Li12Mo5O17 and of the deintercalated oxide Li5Mo5O17 has been carried out by electron microscopy and neutron powder diffraction. The reversible topotactic transformation between the ordered rock salt structure of the former and the ribbon structure of the latter (closely related to that of Li4Mo5O17) is explained on the following basis: both structures can be described as strips built up as an assembly of infinite ribbons of MoO6 octahedra that are five octahedra thick, and that differ by slight displacements of the octahedral ribbons. We show that the electrochemical behavior of the LixMo5O17 system is based on two sorts of Li+ sites; those that are located within the strips between the ribbons, and those that are located at the border of the strips. The high rate of Li intercalation in this oxide and its reversibility are discussed in terms of its peculiar structure.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000289597100010	Publication Date	2011-02-12
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	1	Open Access
Notes	Esteem 026019			Approved	Most recent IF: 2.299; 2011 IF: 2.159
Call Number	UA @ lucian @ c:irua:88646			Serial	1515
Permanent link to this record



Author	Kopnin, E.M.; Belik, A.A.; Shpanchenko, R.V.; Antipov, E.V.; Izumi, F.; Takayama-Muromachi, E.; Hadermann, J.
Title	Synthesis, crystal structure, and magnetic properties of new layered hexagonal perovskite Ba₈Ta₄Ru_8/3Co_2/3O₂₄			Type	A1 Journal article
Year	2004	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	177	Issue		Pages	3499-3504
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000224465500035	Publication Date	2004-08-13
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	1	Open Access
Notes	reprint; IUAP V-1			Approved	Most recent IF: 2.299; 2004 IF: 1.815
Call Number	UA @ lucian @ c:irua:49462			Serial	3448
Permanent link to this record



Author	Fedotov, S.S.; Kuzovchikov, S.M.; Khasanova, N.R.; Drozhzhin, O.A.; Filimonov, D.S.; Karakulina, O.M.; Hadermann, J.; Abakumov, A.M.; Antipov, E.V.
Title	Synthesis, structure and electrochemical properties of LiNaCo0.5Fe0.5PO4F fluoride-phosphate			Type	A1 Journal article
Year	2016	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	242	Issue	242	Pages	70-77
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	LiNaCo 0.5 Fe 0.5 PO 4 F fluoride-phosphate was synthesized via conventional solid-state and novel freeze-drying routes. The crystal structure was refined based on neutron powder diffraction (NPD) data and validated by electron diffraction (ED) and high-resolution transmission electron microscopy (HRTEM). The alkali ions are ordered in LiNaCo 0.5 Fe 0.5 PO 4 F and the transition metals jointly occupy the same crystallographic sites. The oxidation state and oxygen coordination environment of the Fe atoms were verified by 57 Fe Mössbauer spectroscopy. Electrochemical tests of the LiNaCo 0.5 Fe 0.5 PO 4 F cathode material demonstrated a reversible activity of the Fe 3+ /Fe 2+ redox couple at the electrode potential near 3.4 V and minor activity of the Co 3+ /Co 2+ redox couple over 5 V vs Li/Li + . The material exhibits a good capacity retention in the 2.4÷4.6 V vs Li/Li + potential range with the delivered discharge capacity of more than 82% (theo.) regarding Fe 3+ /Fe 2+ .
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000383304900010	Publication Date	2016-02-27
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	1	Open Access
Notes	The authors kindly thank Dr. O. A. Shlyakhtin for the assistance in the freeze-drying synthesis. We are grateful to the Laboratory for Neutron Scattering and Imaging (NLS) at the Paul Scherrer Institut (Villigen, Switzerland) for granting beam time at the HRPT diffractometer and to Dr. D. V. Sheptyakov for the technical support during the experiment. The work was partly supported by Russian Foundation for Basic Research (RFBR grant 13-03-00495a, 14-29-04064 ofim, 16-33-01131 mola), Skoltech Center for Electrochemical Energy Storage and Moscow State University Development Program up to 2020. J. Hadermann, O.M. Karakulina and A.M. Abakumov acknowledge support from FWO under grant G040116N.			Approved	Most recent IF: 2.299
Call Number	c:irua:133776			Serial	4075
Permanent link to this record



Author	Van Tendeloo, G.; Domengès, B.; Caldes, M.T.; Hervieu, M.; Raveau, B.
Title	Structural aspects of Li-doped tubular bismuth cuprates (Bi₂Sr₃Cu_2-xLi_xO_y): an electron microscopy study			Type	A1 Journal article
Year	1994	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	112	Issue		Pages	161-169
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1994PG30500027	Publication Date	0000-00-00
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record;
Impact Factor	2.133	Times cited		Open Access
Notes				Approved
Call Number	UA @ lucian @ c:irua:10033			Serial	3208
Permanent link to this record



Author	Ben Hafsia, A.; Hendrickx, M.; Batuk, M.; Khitouni, M.; Hadermann, J.; Greneche, J.-M.; Rammeh, N.
Title	Crystal structure study of manganese and titanium substituted BaLaFe2O6-δ			Type	A1 Journal article
Year	2017	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	251	Issue	251	Pages	186-193
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Barium lanthanum ferrite and four Mn/Ti substituted materials were synthesized by the sol-gel method. The crystal structure of the materials was studied by a combination of X-ray powder diffraction, electron diffraction, scanning transmission electron microscopy and 57Fe Mössbauer spectrometry. BaLaFe2O6-δ has a cubic perovskite structure and Ba0.7La1.3FeMnO6-δ is distorted perovskite with the R-3c symmetry, both from electron diffraction and X-ray powder diffraction. However, according to transmission electron microscopy, the crystals of BaLaFeTiO6-δ, BaLaFeTi0.5Mn0.5O6-δ, and BaLaFe0.5Ti0.5MnO6-δ consist of nanodomains with different symmetries (Pm3m next to R-3c due to octahedral tilts), whereas the bulk X-ray powder diffraction patterns for these compounds correspond to the simple cubic structure. 57Fe Mössbauer spectrometry confirms that all materials contain high spin state Fe3+ ions which are strongly influenced by the chemical disorder resulting from various cationic environments.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000402581200024	Publication Date	2017-04-20
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited		Open Access	Not_Open_Access
Notes	This study has been supported by the Tunisian Ministry of Higher Education and Scientific Research and by the University of Antwerp BOF Grant 33024 funding scheme.			Approved	Most recent IF: 2.299
Call Number	EMAT @ emat @ c:irua:143988			Serial	4582
Permanent link to this record



Author	Kirsanova, M.A.; De Sloovere, D.; Karakulina, O.M.; Hadermann, J.; Van Bael, M.K.; Hardy, A.; Abakumov, A.M.
Title	Toward unlocking the Mn³⁺/Mn²⁺ redox pair in alluaudite-type Na_2+2zMn_2-z(SO₄)_3-x(SeO₄)_x cathodes for sodium-ion batteries			Type	A1 Journal article
Year	2019	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	277	Issue	277	Pages	804-810
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	In polyanion cathodes, the inductive effect alters the potential of a M(n+1)+/Mn+ redox couple (M – transition metal) according to the electronegativity of the X cation in the polyanion groups (XO4m+). To manipulate the operating potential, we synthesized a series of mixed sulfate-selenate alluaudites, with structure formulas Na2+2zMn2-z(SO4)(3-x)(SeO4)(x) and Na2.81Ni1.60(SO4)(1.43)(SeO4)(1.57). Their crystal structure was determined from powder X-ray diffraction data, revealing that the Mn-based alluaudites form solid solutions with the same crystal structure for x = 0.75; 1.125 and 1.5. Na2.81Ni1.60(SO4)(1.43)(SeO4)(1.57) is isostructural to the Mn-based alluaudites. Although the Na2+2zMn2-z(SO4)(3-x)(SeO4)(x) compound with the highest selenium content demonstrates a reversible discharge capacity of 60 mAh g(-1), only a small part of this electrochemical activity can be ascribed to the Mn3+/Mn2+ redox couple. The redox potential of the Mn3+/Mn2+ pair in Na2+2zMn2-z(SO4)(3-)x(SeO4)(x) decreases with increasing values of x, in agreement with the lower electronegativity of Se compared to that of S.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000481726300103	Publication Date	2019-07-24
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record
Impact Factor	2.299	Times cited		Open Access
Notes	; The authors thank the Russian Foundation for Basic Research for financial support (grant 17-03-00370), in addition to Research Foundation-Flanders (project No G040116). ;			Approved	Most recent IF: 2.299
Call Number	UA @ admin @ c:irua:162852			Serial	5401
Permanent link to this record



Author	Hendrickx, M.; Tang, Y.; Hunter, E.C.; Battle, P.D.; Cadogan, Jm.; Hadermann, J.
Title	CaLa2FeCoSbO9 and ALa2FeNiSbO9 (A = Ca, Sr, Ba): cation-ordered, inhomogeneous, ferrimagnetic perovskites			Type	A1 Journal article
Year	2020	Publication	Journal Of Solid State Chemistry	Abbreviated Journal	J Solid State Chem
Volume	285	Issue		Pages	121226
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Polycrystalline samples of CaLa2FeCoSbO9 and ALa2FeNiSbO9 (A=Ca, Sr, Ba) have been prepared in solid-state reactions and studied by a combination of transmission electron microscopy, magnetometry, X-ray diffraction, neutron diffraction and Mössbauer spectroscopy. Diffraction and TEM showed that each shows 1:1 B-site ordering in which Co2+/Ni2+ and Sb5+ tend to occupy two distinct crystallographic sites while Fe3+ is distributed over both sites. While X-ray and neutron diffraction agreed that all four compositions are monophasic with space group P21/n, TEM revealed different levels of compositional inhomogeneity at the subcrystal scale, which, in the case of BaLa2FeNiSbO9, leads to the occurrence of both a P21/n and an I2/m phase. Magnetometry and neutron diffraction show that these perovskites are ferrimagnets with a G-type magnetic structure. Their relatively low magnetisation can be attributed to their inhomogeneity. This work demonstrates the importance of studying the microstructure of complex compositions.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000521107900017	Publication Date	2020-01-30
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	3.3	Times cited		Open Access	OpenAccess
Notes	PDB, ECH, and JH acknowledge support from EPSRC under grant EP/M0189954/1. We would also like to thank E. Suard at ILL and I. Da Silva at ISIS for the experimental assistance they provided.			Approved	Most recent IF: 3.3; 2020 IF: 2.299
Call Number	EMAT @ emat @c:irua:167137			Serial	6345
Permanent link to this record



Author	Parsons, T.G.; Hadermann, J.; Halasyamani, P.S.; Hayward, M.A.
Title	Preparation of the noncentrosymmetric ferrimagnetic phase La_0.9Ba_0.1Mn_0.96O_2.43 by topochemical reduction			Type	A1 Journal article
Year	2020	Publication	Journal Of Solid State Chemistry	Abbreviated Journal	J Solid State Chem
Volume	287	Issue		Pages	121356-121357
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Topochemical reduction of La0.9Ba0.1MnO3 with NaH at 225 degrees C yields the brownmillerite phase La0.9Ba0.1MnO2.5. However, reduction with CaH2 at 435 degrees C results in the formation of La0.9Ba0.1Mn0.96O2.43 via the deintercalation of both oxide anions and manganese cations from the parent perovskite phase. Electron and neutron diffraction data reveal La0.9Ba0.1Mn0.96O2.43 adopts a complex noncentrosymmetric structure, described in space group I23, confirmed by SHG measurements. Low-temperature neutron diffraction data reveal La0.9Ba0.1Mn0.96O2.43 adopts an ordered magnetic structure in which all the nearest neighbor interactions are antiferromagnetic. However, the presence of ordered manganese cation-vacancies results in a net ferrimagnetic structure with net saturated moment of 0.157(2) mu B per manganese center.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000533632700029	Publication Date	2020-04-05
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record
Impact Factor	3.3	Times cited		Open Access	Not_Open_Access
Notes	; We thank the EPSRC for funding this work and E. Suard for assisting with the collection of the neutron powder diffraction data. PSH thanks the Welch Foundation (Grant E-1457) for support. ;			Approved	Most recent IF: 3.3; 2020 IF: 2.299
Call Number	UA @ admin @ c:irua:169450			Serial	6583
Permanent link to this record



Author	Hendrickx, M.; Tang, Y.; Hunter, E.C.; Battle, P.D.; Hadermann, J.
Title	Structural and magnetic properties of the perovskites A₂LaFe₂SbO₉ (A = Ca, Sr, Ba)			Type	A1 Journal article
Year	2021	Publication	Journal Of Solid State Chemistry	Abbreviated Journal	J Solid State Chem
Volume	295	Issue		Pages	121914
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Polycrystalline samples of A(2)LaFe(2)SbO(9) (A = Ca, Sr, Ba) perovskites appeared monophasic to X-ray or neutron powder diffraction but a single-crystal study utilising transmission electron microscopy revealed a greater level of complexity. Although local charge balance is maintained, compositional and structural variations are present among and within the submicron-sized crystals. Despite the inhomogeneity, A = Ca is monophasic with a partially-ordered distribution of Fe3+ and Sb5+ cations across two crystallographically-distinct octahedral sites, i.e. Ca2La(Fe1.25Sb0.25)(2d) (Fe0.75Sb0.75)(2c)O-9. For A = Sr or Ba, the inhomogeneities result in differences in the filling patterns of the octahedra and the ordering of the B cations. Particles of A = Sr contain a phase (Fe:Sb similar to 2:1) without B cation ordering and one (Fe:Sb similar to 1:1) with B cation ordering. Monophasic A = Ba lacks long-range cation order although ordered nanodomains are present within the disordered phase. The temperature dependence of the magnetic properties of each sample is discussed.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000615711800013	Publication Date	2020-12-17
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited		Open Access	OpenAccess
Notes				Approved	Most recent IF: 2.299
Call Number	UA @ admin @ c:irua:176663			Serial	6739
Permanent link to this record



Author	Golovachev, I.B.; Mychinko, M.Y.; Volkova, N.E.; Gavrilova, L.Y.; Raveau, B.; Maignan, A.; Cherepanov, V.A.
Title	Effect of cobalt content on the properties of quintuple perovskites Sm₂Ba₃Fe₅-xCoxO₁₅-δ			Type	A1 Journal article
Year	2021	Publication	Journal Of Solid State Chemistry	Abbreviated Journal	J Solid State Chem
Volume	301	Issue		Pages	122324
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Quintuple perovskites Sm2Ba3Fe5-xCoxO15-delta = 0.5, 1.0 and 1.5) have been prepared by glycerin-nitrate tech- nique in air. The phase purity was confirmed by XRD. Partial substitution of Co for Fe decreases the oxygen content and thus the mean oxidation state of 3d-metals. It also slightly decreases the thermal expansion coefficient of oxides. Positive value of the Seebeck coefficient confirmed p-type conductivity, though the thermopower decreases as the Co content increases. The temperature dependence of electrical conductivity reveals a maximum at 550-750 degrees C.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000684543700028	Publication Date	2021-06-03
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited		Open Access	OpenAccess
Notes				Approved	Most recent IF: 2.299
Call Number	UA @ admin @ c:irua:181656			Serial	6864
Permanent link to this record