|
Records |
Links |
|
Author |
Buysse, C.; Kovalevsky, A.; Snijkers, F.; Buekenhoudt, A.; Mullens, S.; Luyten, J.; Kretzschmar, J.; Lenaerts, S. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Development, performance and stability of sulfur-free, macrovoid-free BSCF capillaries for high temperature oxygen separation from air |
Type |
A1 Journal article |
|
Year |
2011 |
Publication |
Journal of membrane science |
Abbreviated Journal |
J Membrane Sci |
|
|
Volume |
372 |
Issue |
1/2 |
Pages |
239-248 |
|
|
Keywords |
A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
Capture and storage of CO2 (CCS) from fossil-fuel power plants is vital in order to counteract a pending anthropogenic global warming. High temperature oxygen transport perovskite membranes can fulfill an important role in the separation of oxygen from air needed in the oxy-fuel technologies for CCS. In this study we present the development, performance and stability of gastight, macrovoid-free and sulfur-free Ba0.5Sr0.5Co0.8Fe0.2O3 − δ (BSCF) mixed conductor capillary membranes prepared by phase-inversion spinning and sintering. A sulfur-free phase-inversion polymer was chosen in order to obtain a phase-pure BSCF crystal phase. Special attention was given to the polymer solution and ceramic spinning suspension in order to avoid macrovoids and achieve gastight membranes. The sulfur-free BSCF capillaries showed an average 4-point bending strength of 64 ± 8 MPa and a maximum oxygen flux of not, vert, similar5.3 Nml/(cm2 min) at 950 °C for an argon sweep flow rate of 125 Nml/min. The comparison of the performance of sulfur-free and sulfur-containing BSCF capillaries with similar dimensions revealed a profound impact of the sulfur contamination on both the oxygen flux and the activation energy of the overall oxygen transport mechanism. Both long-term oxygen permeation at different temperatures and post-operation analysis of a sulfur-free BSCF capillary were performed and discussed. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
000289829200026 |
Publication Date |
2011-02-17 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0376-7388 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
6.035 |
Times cited |
32 |
Open Access |
|
|
|
Notes |
; The authors want to express their thanks to the VITO staff for their continuous support, especially B. Molenberghs, W. Doyen, H. Beckers, R. Kemps, M. Mertens, M. Schoeters and H. Chen. C. Buysse thankfully acknowledges a PhD scholarship provided by VITO and the University of Antwerp. This work is performed in the framework of the German Helmholtz Alliance Project “MEM-BRAIN”, aiming at the development of gas separation membranes for zero-emission fossil fuel power plants. ; |
Approved |
Most recent IF: 6.035; 2011 IF: 3.850 |
|
|
Call Number |
UA @ admin @ c:irua:89916 |
Serial |
5942 |
|
Permanent link to this record |
|
|
|
|
Author |
Buysse, C.; Kovalevsky, A.; Snijkers, F.; Buekenhoudt, A.; Mullens, S.; Luyten, J.; Kretzschmar, J.; Lenaerts, S. |
![goto web page (via DOI) doi](http://nano.uantwerpen.be/nanorefs/img/doi.gif)
|
|
Title |
Fabrication and oxygen permeability of gastight, macrovoid-free Ba0.5Sr0.5Co0.8Fe0.2O3-\delta capillaries for high temperature gas separation |
Type |
A1 Journal article |
|
Year |
2010 |
Publication |
Journal of membrane science |
Abbreviated Journal |
J Membrane Sci |
|
|
Volume |
359 |
Issue |
1-2 |
Pages |
86-92 |
|
|
Keywords |
A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
Oxygen-permeable perovskites with mixed ionic-electronic conducting properties can play an important role in the separation of oxygen from air which is needed in the oxy-fuel and pre-combustion technologies for the removal and capture of CO2. In this work, gastight, macrovoid-free Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) capillaries were successfully shaped by a phase-inversion spinning technique, followed by calcination and sintering. It was found that both the rheology of the ceramic suspension and the composition of bore liquid and coagulation bath are key factors for making macrovoid-free green capillaries. Gastight BSCF capillaries were obtained by sintering for 5 h at 1100 °C. The sintered BSCF capillaries contained a significant amount of BaSO4 due to a reaction with the polysulfone binder during calcination. The oxygen permeation flux through the BSCF capillaries was measured and compared to literature data on BSCF disk and hollow fiber membranes measured in similar conditions. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
000279953300010 |
Publication Date |
2009-10-30 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0376-7388 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
6.035 |
Times cited |
38 |
Open Access |
|
|
|
Notes |
; The authors want to express their thanks to the VITO personnel for their continuous support, especially B. Molenberghs, W. Doyen, H. Beckers (Separation and Conversion Technology, VITO), R. Kemps, M. Mertens, I. Thijs, M. Schoeters, W. Bouwen and J. Cooymans (Materials Department, VITO). C. Buysse thankfully acknowledges a PhD scholarship provided by VITO and the University of Antwerp. This work is performed in the framework of the German Helmholtz Alliance Project “MEM-BRAIN”, aiming at the development of gas separation membranes for zero-emission fossil fuel power plants. ; |
Approved |
Most recent IF: 6.035; 2010 IF: 3.673 |
|
|
Call Number |
UA @ admin @ c:irua:82008 |
Serial |
5950 |
|
Permanent link to this record |
|
|
|
|
Author |
Van Noyen, J.; Middelkoop, V.; Buysse, C.; Kovalevsky, A.; Snijkers, F.; Buekenhoudt, A.; Mullens, S.; Luyten, J.; Kretzschmar, J.; Lenaerts, S. |
![goto web page (via DOI) doi](http://nano.uantwerpen.be/nanorefs/img/doi.gif)
|
|
Title |
Fabrication of perovskite capillary membranes for high temperature gas separation |
Type |
A1 Journal article |
|
Year |
2012 |
Publication |
Catalysis today |
Abbreviated Journal |
Catal Today |
|
|
Volume |
193 |
Issue |
1 |
Pages |
172-178 |
|
|
Keywords |
A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
Oxygen-permeable perovskites with mixed ionic-electronic conducting properties can play an important role in carbon capture and storage techniques. Their ability to separate oxygen from air is needed, more specifically, in oxy-fuel and pre-combustion technologies. In this work, the first detailed comparative analysis and new results are reported on four types of Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) capillary membranes: non-coated sulphur-containing; catalyst-coated sulphur-containing; non-coated sulphur-free and catalyst-coated sulphur-free. The fabrication of BSCF capillaries by a spinning technique based on phase inversion is further discussed and their oxygen separation performances are interpreted. The comparison of the performance of these different generations of BSCF capillaries of similar dimensions demonstrates a significant impact of the sulphur contamination on both the oxygen flux through the membrane and the activation energy of the overall oxygen transport mechanism. Careful attention is paid to the effect of activation layers on both sulphur-free and sulphur-containing types of capillaries. Additional long-term testing of the sulphur-free BSCF capillaries is presented, where partial decomposition of the membrane surface was observed due to kinetic demixing. (c) 2012 Elsevier B.V. All rights reserved. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
000308675900025 |
Publication Date |
2012-04-15 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0920-5861 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
4.636 |
Times cited |
9 |
Open Access |
|
|
|
Notes |
; The authors want to express their thanks to the VITO personnel for their continuous support, especially B. Molenberghs, W. Doyen (Separation and Conversion Technology, VITO), R. Kemps, M. Mertens, I. Thijs, M. Schoeters, W. Bouwen and J. Cooymans (Materials Department, VITO). C. Buysse thankfully acknowledges a Ph.D. scholarship provided by VITO and the University of Antwerp. This work is performed in the framework of the German Helmholtz Alliance Project “MEM-BRAIN”, aiming at the development of gas separation membranes for zero-emission fossil fuel power plants. ; |
Approved |
Most recent IF: 4.636; 2012 IF: 2.980 |
|
|
Call Number |
UA @ admin @ c:irua:101797 |
Serial |
5951 |
|
Permanent link to this record |
|
|
|
|
Author |
Buysse, C.; Michielsen, B.; Middelkoop, V.; Snijkers, F.; Buekenhondt, A.; Kretzschmar, J.; Lenaerts, S. |
![goto web page (via DOI) doi](http://nano.uantwerpen.be/nanorefs/img/doi.gif)
|
|
Title |
Modeling of the performance of BSCF capillary membranes in four-end and three-end integration mode |
Type |
A1 Journal article |
|
Year |
2013 |
Publication |
Ceramics international |
Abbreviated Journal |
Ceram Int |
|
|
Volume |
39 |
Issue |
4 |
Pages |
4113-4123 |
|
|
Keywords |
A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
Owing to their high surface-to-volume ratio, there has been an increasing research interest in mixed ionic electronic conducting (MIEC) capillary membranes for large-scale high temperature oxygen separation applications. They offer an energy-efficient solution for high temperature combustion processes in oxy-fuel and pre-combustion CO2 capture technologies used in fossil fuel power plants. In order to assess the effectiveness of these membranes in power plant applications, the impact of the geometry of Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) capillaries on their performance in the three-end and four-end integration modes has been investigated and thoroughly discussed. The model's parameters were derived from four-end mode lab-scale experiments using gas-tight, macrovoid free and sulfur-free BSCF capillary membranes that were prepared by a phase-inversion spinning technique. The results of this modeling study revealed that in the four-end mode higher average oxygen fluxes and smaller total membrane areas can be obtained than in the three-end mode. This is due to the higher pO(2) gradient across the membrane wall. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
000318129100084 |
Publication Date |
2012-11-09 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0272-8842 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
2.986 |
Times cited |
4 |
Open Access |
|
|
|
Notes |
; The authors wish to thank all the VITO staff involved in the project for their continued support, and in particular B. Molenberghs, W. Doyen, H. Beckers and S. Mullens. C. Buysse would like to acknowledge funding from VITO and the University of Antwerp for a Ph.D. studentship. This work has been performed in the framework of the German Helmholtz Alliance Project “MEM-BRAIN”, aiming at the development of gas separation membranes for zero-emission fossil fuel power plants. ; |
Approved |
Most recent IF: 2.986; 2013 IF: 2.086 |
|
|
Call Number |
UA @ admin @ c:irua:109020 |
Serial |
5971 |
|
Permanent link to this record |
|
|
|
|
Author |
Kovalevsky, A.; Buysse, C.; Snijkers, F.; Buekenhoudt, A.; Luyten, J.; Kretzschmar, J.; Lenaerts, S. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Oxygen exchange-limited transport and surface activation of Ba0.5Sr0.5Co0.8Fe0.2O3-\delta capillary membranes |
Type |
A1 Journal article |
|
Year |
2011 |
Publication |
Journal of membrane science |
Abbreviated Journal |
J Membrane Sci |
|
|
Volume |
368 |
Issue |
1/2 |
Pages |
223-232 |
|
|
Keywords |
A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
Analysis of oxygen permeation fluxes through Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) capillary membranes, fabricated via a phase-inversion spinning technique using polysulfone as binder, showed a significant limiting role of the surface-oxygen exchange kinetics. Within the studied temperature and oxygen partial pressure ranges, the activation of core and shell sides of the BSCF capillary with praseodymium oxide (PrOx) resulted in an increase in permeation rate of about 300%. At 11231223 K the activated BSCF membranes demonstrate almost 3-times lower activation energies for the overall oxygen transport (not, vert, similar35 kJ/mol) than the non-activated capillaries, indicating that the mechanism of oxygen transport through the activated capillaries becomes significantly controlled by bulk diffusion limitations, allowing further improvement of the overall performance by decreasing the wall thickness. XRD, EDS and EPMA studies revealed the formation of (Pr,Ba,Sr)(Co,Fe)O3−δ perovskite-type oxides on the surface of the PrOx-modified membranes, which may be responsible for the drastic increase in oxygen exchange rate. At T > 1123 K both non-activated and activated Ba0.5Sr0.5Co0.8Fe0.2O3−δ membranes demonstrate stable performance with time, while at 1073 K only a small initial decrease in permeation was observed. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
000286701800027 |
Publication Date |
2010-11-21 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0376-7388 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
6.035 |
Times cited |
21 |
Open Access |
|
|
|
Notes |
; This work was supported by the German Helmholtz Alliance Project “MEM-BRAIN”, aiming at the development of gas separation membranes for zero-emission fossil fuel power plants. Experimental assistance of B. Molenberghs, W. Doyen, H. Chen, R. Kemps, M. Mertens, I. Thijs, and W. Bouwen (VITO) is gratefully acknowledged. ; |
Approved |
Most recent IF: 6.035; 2011 IF: 3.850 |
|
|
Call Number |
UA @ admin @ c:irua:88072 |
Serial |
5975 |
|
Permanent link to this record |
|
|
|
|
Author |
Ramael, M.; van den Bossche, J.; Buysse, C.; van Meerbeeck, J.; Segers, K.; Vermeire, P.; Van Marck, E. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Immunoreactivity for P-170 glycoprotein in malignant mesothelioma and in non-neoplastic mesothelium of the pleura using the murine monoclonal antibody JSB-1 |
Type |
A1 Journal article |
|
Year |
1992 |
Publication |
The journal of pathology |
Abbreviated Journal |
|
|
|
Volume |
167 |
Issue |
|
Pages |
5-8 |
|
|
Keywords |
A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
|
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
A1992HW17700002 |
Publication Date |
2005-06-22 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0022-3417 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:3618 |
Serial |
8059 |
|
Permanent link to this record |
|
|
|
|
Author |
Ramael, M.; Lemmens, G.; Eerdekens, C.; Buysse, C.; Deblier, I.; Jacobs, W.; Van Marck, E. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Immunoreactivity for p53 protein in malignant mesothelioma and non-neoplastic mesothelium |
Type |
A1 Journal article |
|
Year |
1992 |
Publication |
The journal of pathology |
Abbreviated Journal |
|
|
|
Volume |
168 |
Issue |
|
Pages |
371-375 |
|
|
Keywords |
A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
|
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
A1992KE99600005 |
Publication Date |
2005-06-22 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0022-3417 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:3646 |
Serial |
8060 |
|
Permanent link to this record |
|
|
|
|
Author |
Ramael, M.; Buysse, C.; van den Bossche, J.; Segers, K.; Van Marck, E. |
|
|
Title |
Immunoreactivity for the β chain of the platelet derived growth factor receptor (PDGF-R) in malignant mesothelioma and non-neoplastic mesothelium |
Type |
A1 Journal article |
|
Year |
1992 |
Publication |
The journal of pathology |
Abbreviated Journal |
|
|
|
Volume |
167 |
Issue |
|
Pages |
1-4 |
|
|
Keywords |
A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
|
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
|
Publication Date |
|
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0022-3417 |
ISBN |
|
Additional Links |
UA library record |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:3614 |
Serial |
8061 |
|
Permanent link to this record |
|
|
|
|
Author |
Ramael, M.; van den Bossche, J.; Buysse, C.; Van Marck, E. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Nucleolar organizer regions in mesothelial proliferations |
Type |
L1 Letter to the editor |
|
Year |
1992 |
Publication |
The journal of pathology |
Abbreviated Journal |
|
|
|
Volume |
167 |
Issue |
|
Pages |
435 |
|
|
Keywords |
L1 Letter to the editor; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
|
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
A1992JL42900013 |
Publication Date |
2005-06-22 |
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0022-3417 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:3642 |
Serial |
8321 |
|
Permanent link to this record |
|
|
|
|
Author |
Buysse, C. |
|
|
Title |
Perovskite capillaries for gas separation in sustainable energy production |
Type |
Doctoral thesis |
|
Year |
2011 |
Publication |
|
Abbreviated Journal |
|
|
|
Volume |
|
Issue |
|
Pages |
201 p. |
|
|
Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
|
|
Abstract |
|
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
|
Publication Date |
|
|
|
Series Editor |
|
Series Title ![sorted by Series Title field, ascending order (up)](img/sort_asc.gif) |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:90548 |
Serial |
8373 |
|
Permanent link to this record |