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Author Sweevers, E.; Peeters, A.; Van Grieken, R.
Title Weathering of Leinster granite under ambient atmospheric conditions Type A1 Journal article
Year 1995 Publication (up) The science of the total environment Abbreviated Journal
Volume 167 Issue Pages 73-85
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1995RB52200008 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:12345 Serial 8754
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Author Mishra, V.K.; Kumar, P.; Van Poppel, M.; Bleux, N.; Frijns, E.; Reggente, M.; Berghmans, P.; Int Panis, L.; Samson, R.
Title Wintertime spatio-temporal variation of ultrafine particles in a Belgian city Type A1 Journal article
Year 2012 Publication (up) The science of the total environment Abbreviated Journal
Volume 431 Issue Pages 307-313
Keywords A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Simultaneous measurements of ultrafine particles (UFPs) were carried out at four sampling locations situated within a 1 km(2) grid area in a Belgian city, Borgerhout (Antwerp). All sampling sites had different orientation and height of buildings and dissimilar levels of anthropogenic activities (mainly traffic volume). The aims were to investigate: (i) the spatio-temporal variation of UFP within the area, (ii) the effect of wind direction with respect to the volume of traffic on UFP levels, and (iii) the spatial representativeness of the official monitoring station situated in the study area. All sampling sites followed similar diurnal patterns of UFP variation, but effects of local traffic emissions were evident. Wind direction also had a profound influence on UFP concentrations at certain sites. The results indicated a clear influence of local weather conditions and the more dominant effect of traffic volumes. Our analysis indicated that the regional air quality monitoring station represented the other sampling sites in the study area reasonably well; temporal patterns were found to be comparable though the absolute average concentrations showed differences of up to 35%. (C) 2012 Elsevier B.V. All rights reserved.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000306887900037 Publication Date 2012-06-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:101123 Serial 8759
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Author Koch, K.; Wuyts, K.; Denys, S.; Samson, R.
Title The influence of plant species, leaf morphology, height and season on PM capture efficiency in living wall systems Type A1 Journal article
Year 2023 Publication (up) The science of the total environment Abbreviated Journal
Volume 905 Issue Pages 167808-167811
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Green infrastructure (GI) is already known to be a suitable way to enhance air quality in urban environments. Living wall systems (LWS) can be implemented in locations where other forms of GI, such as trees or hedges, are not suitable. However, much debate remains about the variables that influence their particulate matter (PM) accumulation efficiency. This study attempts to clarify which plant species are relatively the most efficient in capturing PM and which traits are decisive when it comes to the implementation of a LWS. We investigated 11 plant species commonly used on living walls, located close to train tracks and roads. PM accumulation on leaves was quantified by magnetic analysis (Saturation Isothermal Remanent Magnetization (SIRM)). Several leaf morphological variables that could potentially influence PM capture were assessed, as well as the Wall Leaf Area Index. A wide range in SIRM values (2.74–417 μA) was found between all species. Differences in SIRM could be attributed to one of the morphological parameters, namely SLA (specific leaf area). This suggest that by just assessing SLA, one can estimate the PM capture efficiency of a plant species, which is extremely interesting for urban greeners. Regarding temporal variation, some species accumulated PM over the growing season, while others actually decreased in PM levels. This decrease can be attributed to rapid leaf expansion and variations in meteorology. Correct assessment of leaf age is important here; we suggest individual labeling of leaves for further studies. Highest SIRM values were found close to ground level. This suggests that, when traffic is the main pollution source, it is most effective when LWS are applied at ground level. We conclude that LWS can act as local sinks for PM, provided that species are selected correctly and systems are applied according to the state of the art.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2023-10-13
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record
Impact Factor 9.8 Times cited Open Access
Notes Approved Most recent IF: 9.8; 2023 IF: 4.9
Call Number UA @ admin @ c:irua:201033 Serial 9049
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Author Van Tendeloo, M.; Baptista, M.C.; Van Winckel, T.; Vlaeminck, S.E.
Title Recurrent multi-stressor floc treatments with sulphide and free ammonia enabled mainstream partial nitritation/anammox Type A1 Journal article
Year 2024 Publication (up) The science of the total environment Abbreviated Journal
Volume 912 Issue Pages 169449-12
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Selective suppression of nitrite-oxidising bacteria (NOB) over aerobic and anoxic ammonium-oxidising bacteria (AerAOB and AnAOB) remains a major challenge for mainstream partial nitritation/anammox implementation, a resource-efficient nitrogen removal pathway. A unique multi-stressor floc treatment was therefore designed and validated for the first time under lab-scale conditions while staying true to full-scale design principles. Two hybrid (suspended + biofilm growth) reactors were operated continuously at 20.2 ± 0.6 °C. Recurrent multi-stressor floc treatments were applied, consisting of a sulphide-spiked deoxygenated starvation followed by a free ammonia shock. A good microbial activity balance with high AnAOB (71 ± 21 mg N L−1 d−1) and low NOB (4 ± 17 % of AerAOB) activity was achieved by combining multiple operational strategies: recurrent multi-stressor floc treatments, hybrid sludge (flocs & biofilm), short floc age control, intermittent aeration, and residual ammonium control. The multi-stressor treatment was shown to be the most important control tool and should be continuously applied to maintain this balance. Excessive NOB growth on the biofilm was avoided despite only treating the flocs to safeguard the AnAOB activity on the biofilm. Additionally, no signs of NOB adaptation were observed over 142 days. Elevated effluent ammonium concentrations (25 ± 6 mg N L−1) limited the TN removal efficiency to 39 ± 9 %, complicating a future full-scale implementation. Operating at higher sludge concentrations or reducing the volumetric loading rate could overcome this issue. The obtained results ease the implementation of mainstream PN/A by providing and additional control tool to steer the microbial activity with the multi-stressor treatment, thus advancing the concept of energy neutrality in sewage treatment plants.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2023-12-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record
Impact Factor 9.8 Times cited Open Access Not_Open_Access
Notes Approved Most recent IF: 9.8; 2024 IF: 4.9
Call Number UA @ admin @ c:irua:202286 Serial 9083
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Author Reynaert, S.; D’Hose, T.; de Boeck, H.J.; Laorden, D.; Dult, L.; Verbruggen, E.; Nijs, I.
Title Can permanent grassland soils with elevated organic carbon buffer negative effects of more persistent precipitation regimes on forage grass performance? Type A1 Journal article
Year 2024 Publication (up) The science of the total environment Abbreviated Journal
Volume 918 Issue Pages 170623-15
Keywords A1 Journal article; Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract Agricultural practices enhancing soil organic carbon (SOC) show potential to buffer negative effects of climate change on forage grass performance. We tested this by subjecting five forage grass varieties differing in fodder quality and drought/flooding resistance to increased persistence in summer precipitation regimes (PR) across sandy and sandy-loam soils from either permanent (high SOC) or temporary grasslands (low SOC) in adjacent parcels. Over the course of two consecutive summers, monoculture mesocosms were subjected to rainy/dry weather alternation either every 3 days or every 30 days, whilst keeping total precipitation equal. Increased PR persistence induced species-specific drought damage and productivity declines. Soils from permanent grasslands with elevated SOC buffered plant quality, but buffering effects of SOC on drought damage, nutrient availability and yield differed between texture classes. In the more persistent PR, Festuca arundinacea FERMINA was the most productive species but had the lowest quality under both ample water supply and mild soil drought, whilst under the most intense soil droughts, Festulolium FESTILO maintained the highest yields. The hybrid Lolium × boucheanum kunth MELCOMBI had intermediate productivity and both Lolium perenne varieties showed the lowest yields under soil drought, but the highest forage quality (especially the tetraploid variety MELFORCE). Performance varied with plant maturity stage and across seasons/years and was driven by altered water and nutrient availability and related nitrogen nutrition among species during drought and upon rewetting. Moreover, whilst permanent grassland soils showed the most consistent positive effects on plant performance, their available water capacity also declined under increased PR persistence. We conclude that permanent grassland soils with historically elevated SOC likely buffer negative effects of increasing summer weather persistence on forage grass performance, but may also be more sensitive to degradation under climate change.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001183615800001 Publication Date 2024-02-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record; WoS full record
Impact Factor 9.8 Times cited Open Access
Notes Approved Most recent IF: 9.8; 2024 IF: 4.9
Call Number UA @ admin @ c:irua:204498 Serial 9191
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Author Li, L.; Lin, Q.; Nijs, I.; De Boeck, H.; Beemster, G.T.S.; Asard, H.; Verbruggen, E.
Title More persistent weather causes a pronounced soil microbial legacy but does not impact subsequent plant communities Type A1 Journal article
Year 2023 Publication (up) The science of the total environment Abbreviated Journal
Volume 903 Issue Pages 166570-166578
Keywords A1 Journal article; Integrated Molecular Plant Physiology Research (IMPRES); Plant and Ecosystems (PLECO) – Ecology in a time of change
Abstract A soil history of exposure to extreme weather may impact future plant growth and microbial community assembly. Currently, little is known about whether and how previous precipitation regime (PR)-induced changes in soil microbial communities influence plant and soil microbial community responses to a subsequent PR. We exposed grassland mesocosms to either an ambient PR (1 day wet-dry alternation) or a persistent PR (30 days consecutive wet-dry alternation) for one year. This conditioned soil was then inoculated as a 10 % fraction into 90 % sterilized “native” soil, after which new plant communities were established and subjected to either the ambient or persistent PR for 60 days. We assessed whether past persistent weather-induced changes in soil microbial community composition affect soil microbial and plant community responses to subsequent weather persistence. The historical regimes caused enduring effects on fungal communities and only temporary effects on bacterial communities, but did not trigger soil microbial legacy effects on plant productivity when exposed to either current PR. This study provides experimental evidence for soil legacy of climate persistence on grassland ecosystems in response to subsequent climate persistence, helping to understand and predict the influences of future climate change on soil biota.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001116596100001 Publication Date 2023-08-24
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 9.8 Times cited Open Access
Notes Approved Most recent IF: 9.8; 2023 IF: 4.9
Call Number UA @ admin @ c:irua:200463 Serial 9213
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Author Gielis, J.; Verhulst, R.; Caratelli, D.; Ricci, P.E.; Tavkhelidze, I.
Title On means, polynomials and special functions Type A1 Journal article
Year 2014 Publication (up) The teaching of mathematics Abbreviated Journal
Volume 17 Issue 1 Pages 1-20
Keywords A1 Journal article; Educational sciences; Sustainable Energy, Air and Water Technology (DuEL)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1451-4966; 2406-1077 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:128660 Serial 8327
Permanent link to this record
 

 
Author Verbruggen, L.; Verheggen, L.; Vanhoutte, G.; Loly, C.; Lybaert, W.; Borbath, I.; Vergauwe, P.; Hendrickx, K.; Debeuckelaere, C.; de Haar-Holleman, A.; Van Laethem, J.-L.; Peeters, M.
Title A real-world analysis on the efficacy and tolerability of liposomal irinotecan plus 5-fluorouracil and folinic acid in metastatic pancreatic ductal adenocarcinoma in Belgium Type A1 Journal article
Year 2023 Publication (up) Therapeutic advances in medical oncology Abbreviated Journal
Volume 15 Issue Pages 1-13
Keywords A1 Journal article; Center for Oncological Research (CORE)
Abstract Background: Currently, nanoliposomal irinotecan (nal-IRI) + 5-fluorouracil/folinic acid (5-FU/ LV) is the only approved second-line treatment for patients suffering from metastatic pancreatic ductal adenocarcinoma (mPDAC). However, also other chemotherapeutic regimens are used in this setting and due to the lack of clear real-world data on the efficacy of the different regimens, there is no consensus on the optimal treatment sequence for mPDAC patients. Objectives: To provide information on the safe and efficacious use of nal-IRI + 5-FU/LV in clinical practice in Belgium, which is needed for healthcare professionals to estimate the risk-benefit ratio of the intervention. Methods: Medical data of adult patients with mPDAC who were treated with nal-IRI + 5-FU/ LV in one of the participating Belgian hospitals were retrospectively collected. Kaplan-Meier analysis was performed to obtain survival curves to estimate the median overall survival (OS) and progression-free survival (PFS). All other results were presented descriptively. Results: A total of 56 patients [median age at diagnosis: 69 years (range 43 years), 57.1% male] were included. Patients received a median of 5 (range 49 cycles) nal-IRI + 5-FU/LV cycles, extended over 10 weeks (range 130.8 weeks). The median start dose for nal-IRI was 70 mg/ m(2) (range 49.24 mg/m(2)) and chemotherapy dose reduction and delay occurred in, respectively, 42.8% and 37.5% of the patients. The median OS was 6.8 months (95% CI: 5.6-8.4 months) with a 6-month survival rate of 57.4% and a 1-year survival rate of 27.8% in the overall study population. The median OS for patients treated with nal-IRI as second-line therapy or as laterline treatment was, respectively, 6.8 months (95% CI: 5.9-7.0 months) and 5.6 months (95% CI: 4.2-no upper limit). In the overall study population, a median PFS of 3.1 months (95% CI: 2.4-4.6 months) and a disease control rate of 48.3%, comprising 30.4% stable disease, 16.1% partial and 1.8% complete response, was observed. The median PFS for patients treated with nal-IRI as second-line therapy was 3.9 months (95% CI: 2.8-4.8 months) while this was 2.4 months (95% CI: 1.9-9.1 months) for those that received nal-IRI in a later-line treatment. In terms of safety, gastrointestinal problems occurred most (64.3% of the patients) and from all reported treatment emergent adverse events, 39.2% were grade 3 or 4. Conclusion: Nal-IRI + 5-FU/LV is a valuable, effective, and safe sequential treatment option following gemcitabine-based therapy in patients with mPDAC.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001051446400001 Publication Date 2023-08-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1758-8340; 1758-8359 ISBN Additional Links UA library record; WoS full record
Impact Factor 4.9 Times cited Open Access
Notes Approved Most recent IF: 4.9; 2023 IF: 6.294
Call Number UA @ admin @ c:irua:199296 Serial 9183
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Author Ninakanti, R.; Dingenen, F.; Borah, R.; Peeters, H.; Verbruggen, S.W.
Title Plasmonic hybrid nanostructures in photocatalysis : structures, mechanisms, and applications Type A1 Journal article
Year 2022 Publication (up) Topics in Current Chemistry Abbreviated Journal
Volume 380 Issue 5 Pages 40-62
Keywords A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL)
Abstract (Sun)Light is an abundantly available sustainable source of energy that has been used in catalyzing chemical reactions for several decades now. In particular, studies related to the interaction of light with plasmonic nanostructures have been receiving increased attention. These structures display the unique property of localized surface plasmon resonance, which converts light of a specific wavelength range into hot charge carriers, along with strong local electromagnetic fields, and/or heat, which may all enhance the reaction efficiency in their own way. These unique properties of plasmonic nanoparticles can be conveniently tuned by varying the metal type, size, shape, and dielectric environment, thus prompting a research focus on rationally designed plasmonic hybrid nanostructures. In this review, the term “hybrid” implies nanomaterials that consist of multiple plasmonic or non-plasmonic materials, forming complex configurations in the geometry and/or at the atomic level. We discuss the synthetic techniques and evolution of such hybrid plasmonic nanostructures giving rise to a wide variety of material and geometric configurations. Bimetallic alloys, which result in a new set of opto-physical parameters, are compared with core–shell configurations. For the latter, the use of metal, semiconductor, and polymer shells is reviewed. Also, more complex structures such as Janus and antenna reactor composites are discussed. This review further summarizes the studies exploiting plasmonic hybrids to elucidate the plasmonic-photocatalytic mechanism. Finally, we review the implementation of these plasmonic hybrids in different photocatalytic application domains such as H2 generation, CO2 reduction, water purification, air purification, and disinfection.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000839670500009 Publication Date 2022-08-11
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2364-8961 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access OpenAccess
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:189825 Serial 7195
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Author Hellar-Kihampa, H.; Potgieter-Vermaak, S.; van Meel, K.; Gatto Rotondo, G.; Kishimba, M.; Van Grieken, R.
Title Elemental composition of bottom-sediments from Pangani river basin, Tanzania : lithogenic and anthropogenic sources Type A1 Journal article
Year 2012 Publication (up) Toxicological and environmental chemistry Abbreviated Journal
Volume 94 Issue 3 Pages 525-544
Keywords A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract River-bed sediments from the Pangani basin, Tanzania, were characterized for elemental compositions, following contamination risks from rapid expansions of human activities in the area. Samples were collected during two individual seasons and analyzed by high-polarizing beam energy dispersive X-ray fluorescence (EDXRF) for eight major and 14 trace elements. Evaluation of enrichment factors (EFs) was used to investigate the elemental flux and assess the contributions of natural and anthropogenic influences. The abundances of the major elements followed the order Si > Al > Fe > Ca > K > Ti > Mn > P, similar to that of the upper earth's crust, and were generally from the weathering of the bed-rock. The high concentrations of typical anthropogenic trace-elements (Cr < 160 mg kg−1, V < 85 mg kg−1, Ni < 60 mg kg−1, Cu < 87 mg kg−1, La < 90 mg kg−1) coupled with high EFs (>2) in some locations indicated contamination associated with agricultural and industrial activities. Factor analysis extracted five principal components that contributed to 96.0% of the total observed variance. The results indicated that river-bed sediments of the Pangani basin were influenced to a larger extent by lithogenic sources than anthropogenic impacts.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000304276100007 Publication Date 2012-01-16
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0277-2248 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:97080 Serial 7889
Permanent link to this record
 

 
Author Drăgan, A.-M.; Parrilla, M.; Feier, B.; Oprean, R.; Cristea, C.; De Wael, K.
Title Analytical techniques for the detection of amphetamine-type substances in different matrices : a comprehensive review Type A1 Journal article
Year 2021 Publication (up) Trac-Trends In Analytical Chemistry Abbreviated Journal Trac-Trend Anal Chem
Volume 145 Issue Pages 116447
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab)
Abstract This current review focuses on contributions to amphetamine-type substances (ATS) analysis. This type of synthetic illicit drugs has been increasingly present worldwide reaching 5% of the market on illicit drugs in 2019. The increment of their production in many clandestine laboratories and easy distribution among society are two of the main concerns towards the battle against synthetic drugs. Therefore, the first part of this review details the classification and mechanism of action of ATS in the human body. Second, the pharmacological and toxicological effects of ATS on human health are described to motivate the need of early detection of ATS. Subsequently, the most used laboratory-based and portable methods are presented and critically discussed along the review. Finally, a careful discussion on the advantages and disadvantages of portable techniques employed on the field are addressed as potential tools for on-site ATS detection by law enforcement officers.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000723747000009 Publication Date 2021-09-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0165-9936; 1879-3142 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.442 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 8.442
Call Number UA @ admin @ c:irua:183268 Serial 7460
Permanent link to this record
 

 
Author Daems, E.; Moro, G.; Campos, R.; De Wael, K.
Title Mapping the gaps in chemical analysis for the characterisation of aptamer-target interactions Type A1 Journal article
Year 2021 Publication (up) Trac-Trends In Analytical Chemistry Abbreviated Journal Trac-Trend Anal Chem
Volume 142 Issue Pages 116311
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Aptamers are promising biorecognition elements with a wide applicability from therapeutics to bio-sensing. However, to successfully use these biomolecules, a complete characterisation of their bindingperformance in the presence of the target is crucial. Several multi-analytical approaches have been re-ported including techniques to describe kinetic and thermodynamic aspects of the aptamer-targetinteraction, and techniques which allow an in-depth understanding of the aptamer-target structures.Recent literature shows the need of a critical data interpretation, a combination of characterisationtechniques and suggests the key role of the characterisation protocol design. Indeed, thefinal applicationof the aptamer should be considered before choosing the characterisation method. All the limitations andcapabilities of the analytical tools in use for aptamer characterisation should be taken into account. Here,we present a critical overview of the current methods and multi-analytical approaches to study aptamer-target binding, aiming to provide researchers with guidelines for the design of characterisation protocols.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000682179000010 Publication Date 2021-04-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0165-9936; 1879-3142 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.442 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 8.442
Call Number UA @ admin @ c:irua:179407 Serial 8203
Permanent link to this record
 

 
Author Johansson, T.B.; Nelson, J.W.; Van Grieken, R.E.; Winchester, J.W.
Title Elemental analysis of aerosol-size fractions by proton-induced X-ray-emission Type A1 Journal article
Year 1973 Publication (up) Transactions of the American Nuclear Society Abbreviated Journal
Volume 17 Issue Nov Pages 103-103
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1973R161300114 Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-018x ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:113643 Serial 7880
Permanent link to this record
 

 
Author Shi, P.; Liu, M.; Ratkowsky, D.A.; Gielis, J.; Su, J.; Yu, X.; Wang, P.; Zhang, L.; Lin, Z.; Schrader, J.
Title Leaf area-length allometry and its implications in leaf shape evolution Type A1 Journal article
Year 2019 Publication (up) Trees: structure and function Abbreviated Journal
Volume 33 Issue 4 Pages 1073-1085
Keywords A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL)
Abstract According to Thompson’s principle of similarity, the area of an object should be proportional to its length squared. However, leaf area–length data of some plants have been demonstrated not to follow the principle of similarity. We explore the reasons why the leaf area–length allometry deviates from the principle of similarity and examine whether there is a general model describing the relationship among leaf area, width and length. We sampled more than 11,800 leaves from six classes of woody and herbaceous plants and tested the leaf area–length allometry. We compared six mathematical models based on root-mean-square error as the measure of goodness-of-fit. The best supported model described a proportional relationship between leaf area and the product of leaf width and length (i.e., the Montgomery model). We found that the extent to which the leaf area–length allometry deviates from the principle of similarity depends upon the extent of variation of the ratio of leaf width to length. Estimates of the parameter of the Montgomery model ranged between 1/2, which corresponds to a triangular leaf with leaf length as its height and leaf width as its base, and π/4, which corresponds to an elliptical leaf with leaf length as its major axis and leaf width as its minor axis, for the six classes of plants. The narrow range in practice of the Montgomery parameter implies an evolutionary stability for the leaf area of large-leaved plants despite the fact that leaf shapes of these plants are rather different.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000475992600010 Publication Date 2019-04-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0931-1890; 1432-2285 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:159970 Serial 8170
Permanent link to this record
 

 
Author Lian, M.; Shi, P.; Zhang, L.; Yao, W.; Gielis, J.; Niklas, K.J.
Title A generalized performance equation and its application in measuring the Gini index of leaf size inequality Type A1 Journal article
Year 2023 Publication (up) Trees: structure and function Abbreviated Journal
Volume 37 Issue Pages 1555-1565
Keywords A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL)
Abstract The goal of this study is to provide a rigorous tool to quantify the inequality of the leaf size distribution of an individual plant, thereby serving as a reference trait for quantifying plant adaptations to local environmental conditions. The tool to be presented and tested employs three components: (1) a performance equation (PE), which can produce flexible asymmetrical and symmetrical bell-shaped curves, (2) the Lorenz curve (i.e., the cumulative proportion of leaf size vs. the cumulative proportion of number of leaves), which is the basis for calculating, and (3) the Gini index, which measures the inequality of leaf size distribution. We sampled 12 individual plants of a dwarf bamboo and measured the area and dry mass of each leaf of each plant. We then developed a generalized performance equation (GPE) of which the PE is a special case and fitted the Lorenz curve to leaf size distribution using the GPE and PE. The GPE performed better than the PE in fitting the Lorenz curve. We compared the Gini index of leaf area distribution with that of leaf dry mass distribution and found that there was a significant difference between the two indices that might emerge from the scaling relationship between leaf dry mass and area. Nevertheless, there was a strong correlation between the two Gini indices (r2 = 0.9846). This study provides a promising tool based on the GPE for quantifying the inequality of leaf size distributions across individual plants and can be used to quantify plant adaptations to local environmental conditions.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001069570200001 Publication Date 2023-08-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0931-1890; 1432-2285 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.3 Times cited Open Access Not_Open_Access: Available from 26.02.2024
Notes Approved Most recent IF: 2.3; 2023 IF: 1.842
Call Number UA @ admin @ c:irua:199562 Serial 8874
Permanent link to this record
 

 
Author Janssens, K.; van Espen, P.
Title A general-purpose interface between fortran and the low-level functions of the ibm-pc Type A1 Journal article
Year 1988 Publication (up) Trends in analytical chemistry Abbreviated Journal
Volume 7 Issue 4 Pages 128-130
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1988M999800003 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0165-9936 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:149778 Serial 5450
Permanent link to this record
 

 
Author Jambers, W.; Van Grieken, R.
Title Present and future applications of beam techniques in environmental microanalysis Type A1 Journal article
Year 1996 Publication (up) Trends in analytical chemistry Abbreviated Journal
Volume 15 Issue Pages 114-122
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1996UA48000006 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0165-9936; 1879-3142 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:14641 Serial 8412
Permanent link to this record
 

 
Author Madsen, J.; Pennycook, T.J.; Susi, T.
Title ab initio description of bonding for transmission electron microscopy Type A1 Journal article
Year 2021 Publication (up) Ultramicroscopy Abbreviated Journal Ultramicroscopy
Volume 231 Issue Pages
Keywords A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract The simulation of transmission electron microscopy (TEM) images or diffraction patterns is often required to interpret their contrast and extract specimen features. This is especially true for high-resolution phase-contrast imaging of materials, but electron scattering simulations based on atomistic models are widely used in materials science and structural biology. Since electron scattering is dominated by the nuclear cores, the scattering potential is typically described by the widely applied independent atom model. This approximation is fast and fairly accurate, especially for scanning TEM (STEM) annular dark-field contrast, but it completely neglects valence bonding and its effect on the transmitting electrons. However, an emerging trend in electron microscopy is to use new instrumentation and methods to extract the maximum amount of information from each electron. This is evident in the increasing popularity of techniques such as 4D-STEM combined with ptychography in materials science, and cryogenic microcrystal electron diffraction in structural biology, where subtle differences in the scattering potential may be both measurable and contain additional insights. Thus, there is increasing interest in electron scattering simulations based on electrostatic potentials obtained from first principles, mainly via density functional theory, which was previously mainly required for holography. In this Review, we discuss the motivation and basis for these developments, survey the pioneering work that has been published thus far, and give our outlook for the future. We argue that a physically better justified ab initio description of the scattering potential is both useful and viable for an increasing number of systems, and we expect such simulations to steadily gain in popularity and importance.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000744190300006 Publication Date 2021-03-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0304-3991 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.843 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 2.843
Call Number UA @ admin @ c:irua:183955 Serial 6850
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Author Gorji, S.; Kashiwar, A.; Mantha, L.S.; Kruk, R.; Witte, R.; Marek, P.; Hahn, H.; Kübel, C.; Scherer, T.
Title Nanowire facilitated transfer of sensitive TEM samples in a FIB Type A1 Journal article
Year 2020 Publication (up) Ultramicroscopy Abbreviated Journal Ultramicroscopy
Volume 219 Issue Pages 113075
Keywords A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT)
Abstract We introduce a facile approach to transfer thin films and other mechanically sensitive TEM samples inside a FIB with minimal introduction of stress and bending. The method is making use of a pre-synthetized flexible freestanding Ag nanowire attached to the tip of a typical tungsten micromanipulator inside the FIB. The main advantages of this approach are the significantly reduced stress-induced bending during transfer and attachment of the TEM sample, the very short time required to attach and cut the nanowire, the operation at very low dose and ion current, and only using the e-beam for Pt deposition during the transfer of sensitive TEM samples. This results in a reduced sample preparation time and reduced exposure to the ion beam or e-beam for Pt deposition during the sample preparation and thus also reduced contamination and beam damage. The method was applied to a number of thin films and different TEM samples in order to illustrate the advantageous benefits of the concept. In particular, the technique has been successfully tested for the transfer of a thin film onto a MEMS heating chip for in situ TEM experiments.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2020-07-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0304-3991 ISBN Additional Links UA library record
Impact Factor 2.2 Times cited Open Access
Notes Approved Most recent IF: 2.2; 2020 IF: 2.843
Call Number UA @ admin @ c:irua:183618 Serial 6871
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Author Gao, C.; Hofer, C.; Pennycook, T.J.
Title On central focusing for contrast optimization in direct electron ptychography of thick samples Type A1 Journal article
Year 2024 Publication (up) Ultramicroscopy Abbreviated Journal
Volume 256 Issue Pages 113879-7
Keywords A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract Ptychography provides high dose efficiency images that can reveal light elements next to heavy atoms. However, despite ptychography having an otherwise single signed contrast transfer function, contrast reversals can occur when the projected potential becomes strong for both direct and iterative inversion ptychography methods. It has recently been shown that these reversals can often be counteracted in direct ptychography methods by adapting the focus. Here we provide an explanation of why the best contrast is often found with the probe focused to the middle of the sample. The phase contribution due to defocus at each sample slice above and below the central plane in this configuration effectively cancels out, which can prevent contrast reversals when dynamical scattering effects are not overly strong. In addition we show that the convergence angle can be an important consideration for removal of contrast reversals in relatively thin samples.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001112166400001 Publication Date 2023-11-03
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0304-3991 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.2 Times cited Open Access Not_Open_Access
Notes Approved Most recent IF: 2.2; 2024 IF: 2.843
Call Number UA @ admin @ c:irua:202029 Serial 9066
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Author Raes, A.; Ninakanti, R.; Van den Bergh, L.; Borah, R.; Van Doorslaer, S.; Verbruggen, S.W.
Title Black titania by sonochemistry : a critical evaluation of existing methods Type A1 Journal article
Year 2023 Publication (up) Ultrasonics sonochemistry Abbreviated Journal
Volume 100 Issue Pages 106601-106609
Keywords A1 Journal article; Theory and Spectroscopy of Molecules and Materials (TSM²); Laboratory of adsorption and catalysis (LADCA)
Abstract In the field of photocatalysis, the fabrication of black titania is a booming topic, as it offers a system with improved solar light harvesting properties and increased overall efficiency. The darkening of white TiO2 powders can be ascribed to surface hydroxylation, oxygen vacancies, Ti3+ centres, or a combination thereof. A handful of studies suggests these defects can be conveniently introduced by acoustic cavitation, generated during sonochemical treatment of pristine TiO2 powders. In reproducing these studies, P25 TiO2 samples were ultrasonicated for various hours with a power density of 8000 W/L, resulting in powders that indeed became gradually darker with increasing sonication time. However, HAADF–STEM revealed that extensive erosion of the sonotrode tip took place and contaminated the samples, which appeared to be the primary reason for the observed colour change. This was confirmed by UV–Vis DRS and DRIFTS, that showed no significant alteration of the catalyst surface after sonication. EPR measurements showed that only an insignificant fraction of Ti3+ centres were produced, far less than in a TiO2 sample that was chemically reduced with NaBH4. No evidence of the presence oxygen vacancies could be found. The enhanced photocatalytic activities of ultrasonicated materials reported in literature can therefore not be ascribed to the synthesis of actual black (defected) TiO2, but rather to specific changes in morphology as a result of acoustic cavitation. Also, this study underlines the importance of considering probe erosion in sonochemical catalyst synthesis, which is an unavoidable side effect that can have an important impact on the catalyst appearance, properties and performance.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001084391500001 Publication Date 2023-09-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1350-4177 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.4 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 8.4; 2023 IF: 4.218
Call Number UA @ admin @ c:irua:198848 Serial 8838
Permanent link to this record
 

 
Author Koch, K.; Ysebaert, T.; Denys, S.; Samson, R.
Title Urban heat stress mitigation potential of green walls: A review Type A1 Journal article
Year 2020 Publication (up) Urban Forestry & Urban Greening Abbreviated Journal Urban For Urban Gree
Volume 55 Issue Pages 126843-13
Keywords A1 Journal article; Engineering sciences. Technology; Art; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Cities with resilience to climate change appear to be a vision of the future, but are inevitable to ensure the quality of life for citizens and to avoid an increase in civilian mortality. Urban green infrastructure (UGI), with the focus on vertical green, poses a beneficial mitigation and adaptation strategy for challenges such as climate change through cooling effects on building and street level. This review article explores recent literature regarding this considerable topic and investigates how green walls can be applied to mitigate this problem. Summary tables (see additional information) and figures are presented that can be used by policy makers and researchers to make informed decisions when installing green walls in built-up environments. At last, knowledge gaps are uncovered that need further investigation to exploit the benefits at its best.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000593921600001 Publication Date 2020-09-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1618-8667 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.4 Times cited Open Access
Notes Approved Most recent IF: 6.4; 2020 IF: 2.113
Call Number UA @ admin @ c:irua:172985 Serial 6650
Permanent link to this record
 

 
Author Ysebaert, T.; Koch, K.; Samson, R.; Denys, S.
Title Green walls for mitigating urban particulate matter pollution : a review Type A1 Journal article
Year 2021 Publication (up) Urban Forestry & Urban Greening Abbreviated Journal Urban For Urban Gree
Volume 59 Issue Pages 127014
Keywords A1 Journal article; Engineering sciences. Technology; Art; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Air pollution caused by particulate matter (PM) is a well-known health issue in urban environments. Urban green infrastructure offers opportunities as a nature-based solution to urban PM pollution. Green walls have advantages over other types of urban green infrastructure, since they can be applied to the enormous available wall area in cities and since they do not interfere with the prevailing ventilation resulting in elevated PM levels. However, this has raised questions about the effectiveness of GW in removing PM and this could explain the limited applicability of green walls to tackle PM pollution. Nevertheless, it is suggested that green walls have a significant unexploited potential and this review article aims to address current knowledge gaps and to propose future research requirements for the implementation of green walls to mitigate urban PM pollution. An in-depth analysis is given of the mechanisms behind PM deposition and the influence of vegetation properties on this process, as well as the practices followed to model PM dispersion and deposition. It was suggested that particle deposition on green walls depends on the green wall species, pollution level, and the residence time of PM in a street (canyon). Rainfall plays an important role in the PM pathway, although it is not a necessary requirement to sustain PM deposition on plant leaves. There are still some discrepancies in the literature about the ideal plant characteristics for PM deposition in terms of the macro- and microstructures that require further investigation, especially in comparison with tree and shrub species. In addition, extensively validated models are required to accurately calculate the impact of green walls on air flow and the PM concentration on site.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000632597600001 Publication Date 2021-02-06
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1618-8667 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.113 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 2.113
Call Number UA @ admin @ c:irua:175581 Serial 8011
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Author Van Oijstaeijen, W.; Finizola e Silva, M.; Back, P.; Collins, A.; Verheyen, K.; De Beelde, R.; Cools, J.; Van Passel, S.
Title The Nature Smart Cities business model : a rapid decision-support and scenario analysis tool to reveal the multi-benefits of green infrastructure investments Type Administrative Services
Year 2023 Publication (up) Urban forestry & urban greening Abbreviated Journal
Volume 84 Issue Pages 127923-14
Keywords Administrative Services; A1 Journal article; Art; Engineering Management (ENM)
Abstract Incorporating natural spaces within urban areas has been shown to have multiple benefits. However, despite greening and adaptation strategies at different levels of government, progress remains slow with a lack of easy to use and comprehensive tools identified as key to overcoming this. This paper presents a co-designed tool with academic and local authority partners to demonstrate the ecosystem service benefits of small-scale urban green infrastructure projects. Through the tool, users can readily assess the impact of green infrastructure investments on the delivery of a selection of ecosystem services in the early stages of a project. Furthermore, the tool provides a standardised assessment of cultural ecosystem services' contributions, as well as offering a method to score spatial designs on the impact on habitat for biodiversity. Use of the tool is demonstrated using a pilot study in Kapelle, the Netherlands. The results set out an overview of the impacts of the spatial design on estimated ecosystem service delivery. They also show the tool's potential to add value in early project stages and as a planning and design tool, helping to maximise the benefits that can be achieved through green infrastructure design. Complementing these arguments with ball-park estimations on green infrastructure costs, the Nature Smart Cities Business Model aims to offer public sector officers the means to create a business case for green infrastructure measures, facilitating the translation from strategies to actual plans, thus benefitting green infrastructure implementation in the public realm.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000982199900001 Publication Date 2023-04-11
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1618-8667 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.4 Times cited Open Access
Notes Approved Most recent IF: 6.4; 2023 IF: 2.113
Call Number UA @ admin @ c:irua:196748 Serial 9235
Permanent link to this record
 

 
Author Geerts, R.; Vandermoere, F.; Halet, D.; Van Winckel, T.; Joos, P.; Van Den Steen, K.; Van Meenen, E.; Blust, R.; Vlaeminck, S.E.
Title Ik drink (geen) afval! Een exploratieve studie naar socio-demografische verschillen in publieke steun voor het hergebruik van afvalwater in Vlaanderen Type A1 Journal article
Year 2020 Publication (up) Vlaams tijdschrift voor overheidsmanagement Abbreviated Journal
Volume Issue 3 Pages 51-69
Keywords A1 Journal article; Sociology; Sustainable Energy, Air and Water Technology (DuEL); Centre for Research on Environmental and Social Change
Abstract In een context van stijgende waterschaarste verkennen wij, naar ons weten voor het eerst in Vlaanderen, publieke steun voor de behandeling en het hergebruik van afvalwater als drinkwater. Vlaanderen is vandaag een van de weinige regio’s waar afvalwater reeds gerecycleerd wordt voor drinkwaterdoeleinden. Dit gebeurt op kleinschalig niveau en de uitbreiding hiervan is vandaag een van de Vlaamse beleidsdoelstellingen. Internationale voorbeelden toonden echter dat een gebrek aan publieke steun een aanzienlijk obstakel kan zijn. Vaak worden gezondheids- en veiligheidsbezorgdheden aangehaald als oorzaak voor het beperkte draagvlak. Minder is geweten over de socio-demografische distributie van dit draagvlak. Daarbovenop blijft er onduidelijkheid over de samenhang tussen socio-demografische kenmerken en gezondheids- en veiligheidsbezorgdheden. Met behulp van een enquête uitgevoerd in Vlaanderen (N=2309), bestudeerden wij ten eerste deze socio-demografische verschillen op basis van bivariate associaties (gender, opleidingsniveau, leeftijd en woonplaats). Ten tweede construeerden we een padmodel om te onderzoeken of deze verschillen verklaard kunnen worden aan de hand van gezondheids- en veiligheidsbezorgdheden. Onze resultaten toonden dat publieke steun voor afvalwaterhergebruik voor drinkwaterdoeleinden in Vlaanderen beperkt is. Het draagvlak was het laagst bij oudere mensen, vrouwen, lager geschoolde groepen en mensen die niet in de Provincie Antwerpen wonen. Voor een groot deel konden socio-demografische verschillen verklaard worden door hogere gezondheids- en veiligheidsbezorgdheden bij vrouwen, lager geschoolden en mensen uit West- en Oost-Vlaanderen. Dit suggereert een gebrek aan vertrouwen in waterexperts en -technologie bij bepaalde socio-demografische groepen, wat zich vertaalt in een verminderde publieke steun voor afvalwaterhergebruik. Op basis van deze bevindingen bespreken we een aantal potentiële actiestrategieën om publieke oppositie te anticiperen en proactief publieke steun te verwerven via doelgerichte (risico)communicatie.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1373-0509 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:171478 Serial 6541
Permanent link to this record
 

 
Author Kovács, A.; Janssens, N.; Mielants, M.; Cornet, I.; Neyts, E.C.; Billen, P.
Title Biocatalyzed vinyl laurate transesterification in natural deep eutectic solvents Type A1 Journal article
Year 2023 Publication (up) Waste and biomass valorization Abbreviated Journal
Volume Issue Pages 1-12
Keywords A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); Biochemical Wastewater Valorization & Engineering (BioWaVE); Intelligence in PRocesses, Advanced Catalysts and Solvents (iPRACS)
Abstract Purpose Natural deep eutectic solvents (NADES) represent a green alternative to conventional organic solvents as reaction medium, offering more benign properties. To efficiently design NADES for biocatalysis, a better understanding of their effect on these reactions is needed. We hypothesize that this effect can be described by separately considering (1) the solvent interactions with the substrates, (2) the solvent viscosities and (3) the enzyme stability in NADES. Methods We investigated the effect of substrate solvation and viscosity on the reaction rate; and the stability of the enzyme in NADES. To this end, we monitored the conversion over time of the transesterification of vinyl laurate with 1- butanol by the lipase enzyme Candida antarctica B in NADES of different compounds and molar ratios. Results The initial reaction rate is higher in most NADES ( varying between 1.14 and 15.07 mu mol min(-1) mg(-1)) than in the reference n-hexane (4.0 mu mol min(-1) mg(-1))), but no clear relationship between viscosity and initial reaction rate was found. The increased reaction rate is most likely related to the solvation of the substrate due to a change in the activation energy of the reaction or a change in the conformation of the substrate. The enzyme retained part of its activity after the first 2 h of reaction (on average 20 % of the substrate reacted in the 2-24 h period). Enzyme incubation in ethylene glycol-based NADES resulted in a reduced reaction rate ( 15.07 vs. 3.34 mu mol min(-1) mg(-1)), but this may also be due to slow dissolution of the substrate. Conclusions The effect of viscosity seems to be marginal next to the effect of solvation and possible enzyme-NADES interaction. The enzyme retains some of its activity during the 24-hour measurements, but the enzyme incubation experiments did not yield accurate, comparable values. [GRAPHICS] .
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001117290800003 Publication Date 2023-12-07
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1877-2641; 1877-265x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.2 Times cited Open Access
Notes Approved Most recent IF: 3.2; 2023 IF: 1.337
Call Number UA @ admin @ c:irua:202709 Serial 9005
Permanent link to this record
 

 
Author Thomassen, G.; Van Passel, S.; Alaerts, L.; Dewulf, J.
Title Retrospective and prospective material flow analysis of the post-consumer plastic packaging waste management system in Flanders Type A1 Journal article
Year 2022 Publication (up) Waste Management Abbreviated Journal Waste Manage
Volume 147 Issue Pages 10-21
Keywords A1 Journal article; Engineering Management (ENM)
Abstract The post-consumer plastic packaging waste management in Flanders was analyzed by performing a retrospective material flow analysis, covering an extensive period from 1985 to 2019. In addition, a prospective material flow analysis of 32 improvement scenarios was performed, based on expected changes in the waste management system. Mass recovery rates were calculated based on different interpretations of the calculation rules. Moreover, various cascading levels were identified to differentiate between the quality level of the secondary applications. The mass recovery rate including only recycling evolved from a value of 0% in 1985 to 31% in 2019 and could be increased to 36-62% depending on the improvement scenario selected. However, the different interpretations of the calculation rules led to a variation of up to 20 and 41% on this mass recovery rates for the retrospective and prospective analysis, respectively. The introduction of monostream recycling for additional post-consumer plastic packaging flows, such as low-density polyethylene, did not lead to increasing mass recovery rates, if no differentiation for the cascading levels was made. The Belgian recycling target of 65% for 2023 will be challenging if the strictest calculation method needs to be followed or if the improvements in the Flemish postconsumer plastic packaging waste system do not follow the best-case collection scenarios under the given assumptions. To harmonize the calculation and monitoring of these targets, clear calculation rules need to be accompanied with a harmonized monitoring system over the entire waste management system.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000802961100002 Publication Date 2022-05-17
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0956-053x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.1 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 8.1
Call Number UA @ admin @ c:irua:188651 Serial 7367
Permanent link to this record
 

 
Author Larraín, M.; Billen, P.; Van Passel, S.
Title The effect of plastic packaging recycling policy interventions as a complement to extended producer responsibility schemes : a partial equilibrium model Type A1 Journal article
Year 2022 Publication (up) Waste Management Abbreviated Journal Waste Manage
Volume 153 Issue Pages 355-366
Keywords A1 Journal article; Engineering Management (ENM); Intelligence in PRocesses, Advanced Catalysts and Solvents (iPRACS)
Abstract Extended producer responsibility (EPR) schemes have effectively increased the plastic waste that is separately collected. However, due to the structure of the recycling industry, EPR cannot increase recycling rates up to the target levels.Additional policy instruments to increase recycling rates such as recycled content targets, green dot fees bonus for recycled content, recycling targets and taxes on non-recycled plastic packaging have been discussed on a political level in the last years. However, very little research has quantitatively studied the effectiveness of these policy interventions.Using a partial equilibrium model, this paper examines the effectiveness of the implementation of the aforementioned policy instruments to increase recycling rates and the impact on different stakeholders of the value chain: plastic producers, consumers, producer responsibility organization and recyclers.Results show that direct interventions (recycled content standards and recycling targets) have the benefit of decoupling the recycling industry from external markets such as the oil market. They can be a good starting point to increase recycling, but in the long term they may be restricting by not presenting incentives to achieve recycling levels beyond the targeted amounts and by limiting technological innovation. On the contrary, eco-nomic interventions such as a green dot fee bonus or a packaging tax create economic incentives for recycling. However, these incentives are diminished by the lower perceived quality of packaging with higher recycled content levels.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000868915000004 Publication Date 2022-09-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0956-053x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.1 Times cited Open Access Not_Open_Access
Notes Approved Most recent IF: 8.1
Call Number UA @ admin @ c:irua:191367 Serial 7370
Permanent link to this record
 

 
Author Sakarika, M.; Spiller, M.; Baetens, R.; Donies, G.; Vanderstuyf, J.; Vinck, K.; Vrancken, K.C.; Van Barel, G.; Du Bois, E.; Vlaeminck, S.E.
Title Proof of concept of high-rate decentralized pre-composting of kitchen waste : optimizing design and operation of a novel drum reactor Type A1 Journal article
Year 2019 Publication (up) Waste management Abbreviated Journal
Volume 91 Issue Pages 20-32
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL); Product development
Abstract Each ton of organic household waste that is collected, transported and composted incurs costs (€75/ton gate fee). Reducing the mass and volume of kitchen waste (

KW) at the point of collection can diminish transport requirements and associated costs, while also leading to an overall reduction in gate fees for final processing. To this end, the objective of this research was to deliver a proof of concept for the so-called “urban pre-composter”; a bioreactor for the decentralized, high-rate pre-treatment of KW, that aims at mass and volume reduction at the point of collection. Results show considerable reductions in mass (33%), volume (62%) and organic solids (32%) of real KW, while provision of structure material and separate collection of leachate was found to be unnecessary. The temperature profile, C/N ratio (12) and VS/TS ratio (0.69) indicated that a mature compost can be produced in 68  days (after pre-composting and main composting). An economic Monte Carlo simulation yielded that the urban pre-composter concept is not more expensive than the current approach, provided its cost per unit is €8,000–€14,500 over a 10-year period (OPEX and CAPEX, in 80% of the cases). The urban pre-composter is therefore a promising system for the efficient pre-treatment of organic household waste in an urban context.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000473378700003 Publication Date 2019-04-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0956-053x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:159579 Serial 8426
Permanent link to this record
 

 
Author Ngo, K.N.; Tampon, P.; Van Winckel, T.; Massoudieh, A.; Sturm, B.; Bott, C.; Wett, B.; Murthy, S.; Vlaeminck, S.E.; DeBarbadillo, C.; De Clippeleir, H.
Title Introducing bioflocculation boundaries in process control to enhance effluent quality of high‐rate contact‐stabilization systems Type A1 Journal article
Year 2022 Publication (up) Water environment research Abbreviated Journal Water Environ Res
Volume 94 Issue 8 Pages e10772-17
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract High-rate activated sludge (HRAS) systems suffer from high variability of effluent quality, clarifier performance, and carbon capture. This study proposed a novel control approach using bioflocculation boundaries for wasting control strategy to enhance effluent quality and stability while still meeting carbon capture goals. The bioflocculation boundaries were developed based on the oxygen uptake rate (OUR) ratio between contactor and stabilizer (feast/famine) in a high-rate contact stabilization (CS) system and this OUR ratio was used to manipulate the wasting setpoint. Increased oxidation of carbon or decreased wasting was applied when OUR ratio was <0.52 or >0.95 to overcome bioflocculation limitation and maintain effluent quality. When no bioflocculation limitations (OUR ratio within 0.52–0.95) were detected, carbon capture was maximized. The proposed control concept was shown for a fully automated OUR-based control system as well as for a simplified version based on direct waste flow control. For both cases, significant improvements in effluent suspended solids level and stability (<50-mg TSS/L), solids capture over the clarifier (>90%), and COD capture (median of 32%) were achieved. This study shows how one can overcome the process instability of current HRAS systems and provide a path to achieve more reliable outcomes.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000840360100001 Publication Date 2022-07-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1061-4303; 1554-7531 ISBN Additional Links UA library record; WoS full record
Impact Factor 3.1 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 3.1
Call Number UA @ admin @ c:irua:189409 Serial 7174
Permanent link to this record