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Author |
Van Grieken, R.; Markowicz, A.; Veny, P. |
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Title |
Current trends in the literature on X-ray emission spectrometry |
Type |
A1 Journal article |
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Year |
1991 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
20 |
Issue |
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Pages |
271-276 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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A1991HC15900003 |
Publication Date |
2005-05-28 |
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ISSN |
0049-8246 |
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UA library record; WoS full record; WoS citing articles |
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no |
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Call Number |
UA @ admin @ c:irua:665 |
Serial |
7746 |
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Author |
Labrecque, J.J.; Beusen, J.M.; Van Grieken, R.E. |
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Title |
Determination of barium, lanthanum, cerium and neodymium in lateritic materials by various energy-dispersive X-ray fluorescence techniques and neutron activation analysis |
Type |
A1 Journal article |
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Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
1 |
Pages |
13-18 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
A comparison of four methods for the determination of barium, lanthanum, cerium and neodymium in lateritic materials from Brazil is presented. Three of the methods were based on x-ray fluorescence (XRF) spectroscopy: two by radioisotope excitation (Co-57 and Am-241) and one by secondary target XRF (a molybdenum target with a tungsten anode). The other method was based on neutron activation analysis employing both a Ge(Li) coaxial detector and a high-purity germanium detector. The results from these four methods were similar for lanthanum, cerium and neodymium, but for barium at low concentrations (<500 ppm) the neutron activation and the secondary target XRF methods were not suitable. Data on the precision and accuracy of these methods using a series of standard reference rocks are given. The advantages and limitations of each of these methods with respect to the analysis of lateritic materials are discussed. |
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Wos |
A1986AYN6000003 |
Publication Date |
2005-05-28 |
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Series Volume |
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ISSN |
0049-8246 |
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UA library record; WoS full record; WoS citing articles |
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no |
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Call Number |
UA @ admin @ c:irua:116487 |
Serial |
7774 |
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Author |
Araujo, M.F.; van Espen, P.; Van Grieken, R. |
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Title |
Determination of sample thickness via scattered radiation in X-ray fluorescence spectrometry with filtered continuum excitation |
Type |
A1 Journal article |
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Year |
1990 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
19 |
Issue |
1 |
Pages |
29-33 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
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Abstract |
A semi-empirical approach is described for determining the mass per unit area of a sample being analysed. The method can be used to estimate the concentration of minor and trace elements in matrices containing a substantial amount of light elements. The procedure utilizes the coherently and incoherently scattered radiation induced in the sample by the filtered continuum radiation of a rhodium x-ray tube. The relationship between the intensity of the scattered radiation per unit mass and the average atomic number of the sample is established via calibration graphs, which can be applied for different x-ray tube voltages and for different primary beam filters. The overall procedure was validated by the analysis of several geological standards, deposited as thin slurries of unknown thickness either on Mylar foil or on Nuclepore filters. |
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Wos |
A1990CU24700005 |
Publication Date |
2005-05-28 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Call Number |
UA @ admin @ c:irua:116491 |
Serial |
7787 |
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Author |
Injuk, J.; van Malderen, H.; Van Grieken, R.; Swietlicki, E.; Knox, J.M.; Schofield, R. |
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Title |
EDXRS study of aerosol composition variations in air masses crossing the North Sea |
Type |
A1 Journal article |
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Year |
1993 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
22 |
Issue |
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Pages |
220-228 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
A1993LQ04200009 |
Publication Date |
2005-05-28 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Open Access |
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no |
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Call Number |
UA @ admin @ c:irua:6258 |
Serial |
7836 |
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Permanent link to this record |
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Author |
Markowicz, A.; Storms, H.; Van Grieken, R. |
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Title |
Evaluation of an equation for bremsstrahlung background in electron-probe X-ray microanalysis of composite samples |
Type |
A1 Journal article |
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Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
2 |
Pages |
131-133 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
A new equation for predicting the generated bremsstrahlung background intensity in electron-probe x-ray microanalysis has been verified experimentally. This equation is applicable to all bulk composite specimens and reduces to Kramers' equation for pure elements only. The experimental verification has been carried out for Al2O3, Fe2O3 and ZrO2 with radiation energies from 4.2 to 14.8 keV. The predicted bremsstrahlung intensities are in good agreement with the experimental data. |
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Wos |
A1986C017300009 |
Publication Date |
2005-05-28 |
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Series Editor |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Call Number |
UA @ admin @ c:irua:113873 |
Serial |
7937 |
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Permanent link to this record |
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Author |
Van Grieken, R.E.; Adams, F.C. |
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Title |
Folding of aerosol loaded filters during X-ray fluorescence analysis |
Type |
A1 Journal article |
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Year |
1976 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
5 |
Issue |
2 |
Pages |
61-67 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Folding aerosol loaded filters in two with the loaded side inwards during the X-ray analysis not only reduces possible filter heterogeneity effects and improves sample protection, but also increases the sensitivity and renders filter paper absorption corrections simple and more accurate in many instances. It is shown that folding an aerosol loaded Whatman filter paper during Kα X-rays counting leads to an increased sensitivity for all elements up from calcium, scandium or titanium (depending on the sensitivity definition and on the aerosol load) and for all elements up from phosphorus, sulphur or chlorine in the case of the Nuclepore filter. Although the absorption by the filter, into which the aerosol penetrates to some extent, is always more important in the sandwich than in the usual geometry, the dependence of the absorption correction on the usually unknown average deposition depth is less pronounced. Assuming all the aerosol material to be collected at the very surface of the filter and hence being present in the centre of the sandwich to be analysed, leads to an extremely simple filter paper absorption correction which is less prone to uncertainties than more sophisticated corrections in the usual geometry requiring additional measurements. This is the case for all elements up from potassium on Whatman filters and up from phosphorus on Nuclepore filters. |
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Wos |
A1976BM95300002 |
Publication Date |
2005-05-28 |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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no |
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Call Number |
UA @ admin @ c:irua:116480 |
Serial |
7976 |
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Permanent link to this record |
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Author |
Török, S.; Van Dyck, P.; Van Grieken, R. |
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Title |
Heterogeneity effects in direct X-ray fluorescence analysis of hair |
Type |
A1 Journal article |
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Year |
1984 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
13 |
Issue |
1 |
Pages |
27-32 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The methodology of direct hair analysis by energy-dispersive x-ray fluorescence was studied. The effect on the XRF result of having a non-homogeneous radial distribution of the analyte in a single hair strand and the macroscopic effects in a bundle of hairs were calculated to evaluate possible systematic errors. The detection limits were mapped as a function of the target thickness and surface fraction. It appeared that a 10 mg cm−2 sample thickness, i. e. a target with about four layers of hair strands, is recommended. The standard deviation of this simple direct analytical method is 619% for some important elements. Discrepancies with neutron activation analysis had a mean value of around 15%. About twelve elements can be determined simultaneously on a routine basis. |
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Wos |
A1984SB70200004 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116485 |
Serial |
8029 |
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Permanent link to this record |
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Author |
Török, S.; Braun, T.; Van Dyck, P.; Van Grieken, R. |
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Title |
Heterogeneity effects in direct XRF analysis of traces of heavy metals preconcentrated on polyurethane foam sorbents |
Type |
A1 Journal article |
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Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
1 |
Pages |
7-11 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Trace amounts of heavy metals were preconcentrated on discs of polyurethane (PU) foam loaded with ammonium diethyldithiocarbamate (DDTC), to increase the sensitivity of XRF. Since the diameter of the cavities in the open-cell PU foams reaches 30300 μm, considerable heterogeneity effects might occur, which could reduce the accuracy of the method. The possible systematic error introduced by considering the sample to be homogeneous is calculated using the Berry et al. model. The calculations show that the underestimation of the absorption correction factor when considering the sample as being homogeneous is less than 2% for high-Z elements when the sample thickness is at least 2 mm. The detection limits are also around the minima for this thickness. |
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Wos |
A1986AYN6000002 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116488 |
Serial |
8030 |
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Permanent link to this record |
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Author |
Van Dyck, P.; Markowicz, A.; Van Grieken, R. |
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Title |
Influence of sample thickness, excitation energy and geometry on particle size effects in XRF |
Type |
A1 Journal article |
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Year |
1985 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
14 |
Issue |
4 |
Pages |
183-187 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Expressions are presented for calculating the matrix effect and the pure particle size effect in the XRF analysis of particulate samples with a discrete particle size. The equations are based on the absorption-weighted radiometric diameter concept. Two excitationdetection geometries are considered, with the angles between the sample plane and both the incident and emerging radiation being either 90° (π geometry) or 45° (π/2 geometry). Calculations were made for different sample loadings and exciting radiation energies. The influence of these parameters on the matrix and pure particle size effects is shown. From the results, it is possible to predict the performances of alternative experimental correction procedures for the particle size effect, involving dual measurements at different excitation energies or in different excitationdetection geometries. |
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Wos |
A1985ATB6100007 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116486 |
Serial |
8097 |
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Permanent link to this record |
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Author |
Verbueken, A.H.; Van Grieken, R.E.; Paulus, G.J.; Verpooten, G.A.; de Broe, M.E. |
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Title |
Laser microprobe mass spectrometry of platinum in dog kidney after cisplatin adminstration |
Type |
A3 Journal article |
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Year |
1984 |
Publication |
Biomedical mass spectrometry |
Abbreviated Journal |
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Volume |
11 |
Issue |
4 |
Pages |
159-163 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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Abstract |
By means of laser microprobe mass analysis (LAMMA) platinum was detected in the renal proximal tubular cells of a dog that had been intravenously adminstered the antitumor drug cisplatin (5 mg per kg body weight). No definite subcellular localization of the heavy metal was obtained. Sample prparation and analytical features are examined to increase spatial resolution of analysis while maintaining sufficient detection efficiency. The LAMMA method is destructive, but the amount and type of evaporated material can readily be determined when using LAMMA in combination with transmission electron microscopy. Instrumental optimization and standardization of mass signals is possible by using platinum-loaded, ion chelating resin beads embedded and sectioned with the tissue. |
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Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0306-042x |
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Additional Links |
UA library record |
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Open Access |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116712 |
Serial |
8165 |
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Permanent link to this record |
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Author |
Van Dyck, P.; Török, S.; Van Grieken, R. |
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Title |
Monte Carlo simulation of backscattered peaks in secondary target energy-dispersive X-ray spectra |
Type |
A1 Journal article |
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Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
4 |
Pages |
231-238 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
A Monte Carlo simulation has been developed to describe the incoherent and coherent scatter processes for the complex geometry of a secondary target energy-dispersive x-ray fluorescence system. Photons are followed from the x-ray tube anode until the detection of scattered secondary target photons in the active Si layer of the detector. The program quantitatively shows the broadening of the incoherent scatter peak with increasing atomic number, and it models the incoherent peak shape adequately. The incoherent-to-coherent scatter intensity ratios obtained differ by 1030% from the theoretical values, while their dependence on the sample atomic number corresponds to that expected from theory. |
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Wos |
A1986E535600001 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:113612 |
Serial |
8280 |
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Permanent link to this record |
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Author |
Markowicz, A.; Van Dyck, P.; Van Grieken, R. |
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Title |
Radiometric diameter concept and exact intensities for spherical particles in x-ray fluorescence analysis |
Type |
A1 Journal article |
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Year |
1980 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
9 |
Issue |
2 |
Pages |
52-56 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
In X-ray fluorescence analysis the concept of radiometric diameter, d, is often introduced in considerations of the fluorescent intensity from a particulate sample. It represents the mean geometric path of the X-rays through one particle and is usually simply taken to be equal to the volume-to-area ratio of the particle. The effective radiometric path is, however, itself dependent on geometry and absorption effects. Rigorous calculations of the fluorescent intensity from a particle in the π and π/2 geometries were carried out to evaluate the errors involved. It appears that, for π geometry, the discrepancy between these exact results and the intensity calculated via the use of d does not exceed 5.2%. For the π/2 geometry, the errors are much larger and can amount to 50% in realistic cases of X-ray fluorescence analysis. These conclusions are also applicable to monolayers. The effective radiometric diameter approaches d only when absorption effects become negligible, but is smaller in other cases. |
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Wos |
A1980JN16500003 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116482 |
Serial |
8451 |
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Permanent link to this record |
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Author |
Markowicz, A.; Storms, H.; Van Grieken, R. |
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Title |
A simple absorption correction for electron probe X-ray microanalysis of bulk samples |
Type |
A1 Journal article |
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Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
2 |
Pages |
115-119 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
A simple procedure is proposed for the calculation of the absorption correction factor in electron-probe x-ray microanalysis. It is based on the concept of an effective depth of x-ray production, assuming a rectangular depth distribution function for x-ray generation. This effective x-ray production depth is expressed as a fraction of the x-ray excitation depth given by Whelan's expression. Adequate values for this fraction are presented. Two versions are considered. In the first the effective x-ray production is a function of both the characteristic x-ray energy and the atomic numbers of the matrix elements, whereas in the second one, which is indicated for routine use, the energy dependence is neglected. Calculations pointed to satisfactory results, even for low x-ray energies and high overvoltages. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1986C017300007 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:113872 |
Serial |
8524 |
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Permanent link to this record |
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Author |
Trincavelli, J.; Montoro, S.; van Espen, P.; Van Grieken, R. |
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Title |
M\alpha/L\alpha intensity ratios for Ta, W, Pt, Au, Pb and Bi for electron energies in the 11-40 keV range |
Type |
A1 Journal article |
|
Year |
1993 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
|
Volume |
22 |
Issue |
|
Pages |
372-376 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
|
|
Abstract |
Both energy- and wavelength-dispersive systems were used to obtain Malpha/Lalpha intensity ratios for Ta, W, Pt, Au, Pb and Bi at various overvoltages. A table of these ratios corrected for matrix absorption and detector efficiency is presented, in addition to an interpolatory function of Malpha/Lalpha generated ratios vs. overvoltage, for each element. In addition, three different ZAF correction models were used to predict both detected and generated ratios. Finally, experimental Mbeta/Malpha ratios measured at different overvoltages are presented for the six elements considered. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1993MB01200008 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
|
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|
Notes |
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Approved |
no |
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|
Call Number |
UA @ admin @ c:irua:6221 |
Serial |
8649 |
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Permanent link to this record |
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Author |
Muia, L.M.; Van Grieken, R. |
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Title |
Theoretical evaluation of the effective alpha and De Jongh approaches in X-ray fluorescence analysis of geological materials in borax glass beads |
Type |
A1 Journal article |
|
Year |
1989 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
|
Volume |
18 |
Issue |
6 |
Pages |
259-262 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
An evaluation of the accuracy and suitability of the LachanceTraill algorithm using effective α-coefficients, and the De Jongh α approach for x-ray fluorescence analysis of borax glass beads prepared from geological material was performed. By using theoretical α-coefficients obtained from the same standard and calculated elemental intensities, the two algorithms were compared under identical conditions. When only the monitor standard is used, the LachanceTrail1 approach is found to be inferior to the De Jongh basic α method. If multi-standard calibration is performed for both approaches, the accuracies are almost identical and no significant difference is found in the results. The LachanceTraill algorithm has the advantage of being easier to implement on a minicomputer and, when used without standards, it is found to give results within a few percent of the true values, which is a useful indicator in the choice of appropriate standards for more accurate analytical work. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1989CE70800002 |
Publication Date |
2005-05-28 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
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Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116490 |
Serial |
8660 |
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Permanent link to this record |
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Author |
Sauter, L.; Van der Ben, D.; Van Grieken, R. |
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Title |
Trace analysis of estuarine brown algae by energy-dispersive X-ray fluorescence |
Type |
A1 Journal article |
|
Year |
1979 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
|
Volume |
8 |
Issue |
4 |
Pages |
159-163 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
Brown algae, which are good indicators for estuarine metal pollution, can advantageously be analysed by energy-dispersive X-ray fluorescence. The use of thin film samples and samples of intermediate thickness has several advantages over the conventional thick pellet procedure. A quite homogeneous thin target is prepared by suspending 15 mg of dried and ground seaweed powder in bi-distilled water and evaporating the slurry on a 10 cm2 Mylar foil held in a Teflon ring. The effective sample weight in the beam is calculated by a procedure based on the scatter peaks in the spectrum. Sensitivities are typically in the 215 ppm range. The coefficient of variation per analysis averaged over ten elements amounts to 10%. The natural concentration variation in seaweed specimens at one location is 13%. Samples from locations in the more polluted western Scheldt estuary yield significantly higher values for several elements, relative to the eastern Scheldt sites. Possible trace element variations between the top and base of plants, and between different seaweed specimens and sampling seasons, are discussed. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1979JC63700003 |
Publication Date |
2005-05-28 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116481 |
Serial |
8687 |
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Permanent link to this record |
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|
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Author |
Muia, L.M.; Van Grieken, R. |
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|
Title |
Use of theoretical accurate binary influence coefficients with Tertian's equation in X-ray fluorescence analysis of silicate rocks in borax glass beads |
Type |
A1 Journal article |
|
Year |
1990 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
|
Volume |
19 |
Issue |
3 |
Pages |
141-144 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
A study of the suitability of the Tertian algorithm using new accurate binary influence coefficients and a comparison standard for x-ray fluorescence analysis of geological materials prepared as borax glass beads was performed. The algorithm was found to give satisfactory results for the analysis of four major components in geological materials. Even in the worst case, when there is a factor of 20 difference in the concentration in the specimen and a comparison standard, the algorithm gives results which differ from the true results by a factor of about 2. This makes the algorithm attractive as a diagnostic tool in analyses of unknown specimens and in the identification of appropriate standards. The binary coefficients are easily calculated so that the algorithm can be implemented on a minicomputer. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1990DJ47800009 |
Publication Date |
2005-05-28 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116492 |
Serial |
8725 |
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Permanent link to this record |
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|
|
Author |
Vandeputte, D.F.; Van Grieken, R.E.; Foets, B.J.J.; Misotten, L. |
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|
Title |
Characterization of the spheroliths present in primary atypical bandkeratopathy using laser microprobe mass analysis |
Type |
A1 Journal article |
|
Year |
1989 |
Publication |
Biomedical and environmental mass spectrometry |
Abbreviated Journal |
|
|
|
Volume |
18 |
Issue |
9 |
Pages |
753-756 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
Laser microprobe mass analysis was applied to study the chemical composition of spheroliths in the Bowman's membrane of patients suffering from primary atypical bandkeratopathy. The inclusions appear to consist mainly of calcium phosphate. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
|
Publication Date |
2005-05-29 |
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|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0887-6134 |
ISBN |
|
Additional Links |
UA library record |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116824 |
Serial |
7635 |
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Permanent link to this record |
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|
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Author |
Vandeputte, D.; Van Grieken, R.E.; Jacob, W.A.; Savory, J.; Bertholf, R.L.; Wills, M.R. |
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|
Title |
Ultrastructural localization of aluminium in liver of aluminium maltol-treated rabbits by laser microprobe mass analysis |
Type |
A1 Journal article |
|
Year |
1989 |
Publication |
Biomedical and environmental mass spectrometry |
Abbreviated Journal |
|
|
|
Volume |
18 |
Issue |
8 |
Pages |
598-602 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
By means of laser microprobe mass analysis (LAMMA), we have studied the ultrastructural localization of aluminium in livers of aluminium maltol-treated rabbits. This animal model was developed to study long-term aluminium toxicity using systemic (intravenous) administration of aluminium. We could only detect aluminium in electron-dense inclusion bodies found in large, sometimes multinucleated cells. These results prove that the actual observation of aluminium deposits in liver with LAMMA gives more information than bulk analysis and can be very useful to explore mechanisms of toxicity. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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Language |
|
Wos |
|
Publication Date |
2005-05-29 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0887-6134 |
ISBN |
|
Additional Links |
UA library record |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116817 |
Serial |
8702 |
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Permanent link to this record |
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|
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Author |
Verbueken, A.H.; Bruynseels, F.J.; Van Grieken, R.E. |
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Title |
Laser microprobe mass analysis : a review of applications in the life sciences |
Type |
A3 Journal article |
|
Year |
1985 |
Publication |
Biomedical mass spectrometry |
Abbreviated Journal |
|
|
|
Volume |
12 |
Issue |
9 |
Pages |
438-463 |
|
|
Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
The characteristics and analytical utility of laser microprobe mass analysis (LAMMA) are described and evaluated, and a short history of this recent microanalytical technique is presented. A review of the areas of application of LAMMA and related laser microprobes is presented with special emphasis on applications in the life sciences. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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Language |
|
Wos |
|
Publication Date |
2005-05-31 |
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0306-042x |
ISBN |
|
Additional Links |
UA library record |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116722 |
Serial |
8153 |
|
Permanent link to this record |
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|
|
|
Author |
Verbueken, A.H.; Van Grieken, R.E.; Verpooten, G.A.; de Broe, M.E.; Wedeen, R.P. |
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|
Title |
Laser microprobe mass spectrometric identification of cyclosporine-induced intrarenal microliths in rat |
Type |
A1 Journal article |
|
Year |
1992 |
Publication |
Biological mass spectrometry |
Abbreviated Journal |
|
|
|
Volume |
21 |
Issue |
|
Pages |
590-596 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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Language |
|
Wos |
A1992JU83000010 |
Publication Date |
2005-05-31 |
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|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
1052-9306 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
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Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:2842 |
Serial |
8162 |
|
Permanent link to this record |
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Author |
Potgieter-Vermaak, S.S.; Potgieter, J.H.; Kruger, R.A.; Spolnik, Z.; Van Grieken, R. |
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Title |
A characterisation of the surface properties of an ultra fine fly ash (UFFA) used in the polymer industry |
Type |
A1 Journal article |
|
Year |
2005 |
Publication |
Fuel |
Abbreviated Journal |
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|
|
Volume |
84 |
Issue |
18 |
Pages |
2295-2300 |
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|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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|
Abstract |
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|
Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
|
Editor |
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Language |
|
Wos |
000233053100002 |
Publication Date |
2005-06-28 |
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|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0016-2361 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:54564 |
Serial |
7603 |
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Permanent link to this record |
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Author |
LaBrecque, J.J.; Beusen, J.M.; Van Grieken, R.E. |
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Title |
Analysis of lateritic material from Cerro impacto by instrumental neutron activation employing a low-energy photon semiconductor and a high-energy Ge(Li) detector |
Type |
A1 Journal article |
|
Year |
1986 |
Publication |
Applied spectroscopy |
Abbreviated Journal |
|
|
|
Volume |
40 |
Issue |
2 |
Pages |
140-144 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
Nineteen elements were determined in four different grain size fractions of a bulk geological material from Cerro Impacto for a study of the physical (mechanical) concentration process of different elements based upon the hardness of the different minerals. The analysis was performed by excitation of the sample with a high, slow neutron flux followed by gamma-ray spectroscopy with both a conventional Ge(Li) high-energy detector and a low-energy photon detector (LEPD). The accuracy of this method was studied with the use of two standard reference materials, SY-2 and SY-3, which are similar to the real samples. The values determined were also compared with a secondary target x-ray fluorescence method for all the elements that were suitable to both methods. Actually, the x-ray fluorescence method was found to be more complementary than competitive. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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|
Language |
|
Wos |
A1986A085900003 |
Publication Date |
2005-07-21 |
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0003-7028 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116768 |
Serial |
7448 |
|
Permanent link to this record |
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|
|
|
Author |
Eltayeb, M.A.H.; Van Grieken, R.E. |
|
|
Title |
Preconcentration and XRF-determination of heavy metals in hair from Sudanese populations |
Type |
A1 Journal article |
|
Year |
1989 |
Publication |
Journal of radioanalytical and nuclear chemistry |
Abbreviated Journal |
|
|
|
Volume |
131 |
Issue |
2 |
Pages |
331-342 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
Energy-dispersive X-ray fluorescence analysis was applied for the analysis of hair. The hair samples were digested in a mixture of nitric and perchloric acid and the heavy metals were precipitated with ammonium pyrrolidine dithiocarbamate. The accuracy, precision and recovery of the method for the elements Fe, Ni, Cu, Zn and Pb were evaluated through the analysis of a standard hair sample. The procedure was applied to the analysis of hair from an occupationally exposed group of Sudanese workers and a control group. The hair of the exposed group showed a range of 80550 ppm Fe, 612 ppm Cu, 57190 ppm Zn and 703700 ppm Pb, while that of the control group had a range of 60310 ppm Fe, 722 ppm Cu, 89170 ppm Zn and 317 ppm Pb. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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Language |
|
Wos |
A1989AL77700009 |
Publication Date |
2005-08-12 |
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0236-5731; 1588-2780 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116816 |
Serial |
8399 |
|
Permanent link to this record |
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|
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Author |
Choël, M.; Deboudt, K.; Osán, J.; Flament, P.; Van Grieken, R. |
|
|
Title |
Quantitative determination of low-Z elements in single atmospheric particles on boron substrates by automated scanning electron microscopy: energy-dispersive X-ray spectrometry |
Type |
A1 Journal article |
|
Year |
2005 |
Publication |
Analytical chemistry |
Abbreviated Journal |
|
|
|
Volume |
77 |
Issue |
17 |
Pages |
5686-5692 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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|
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
|
Editor |
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|
Language |
|
Wos |
000231652300046 |
Publication Date |
2005-08-31 |
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0003-2700; 5206-882x |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:53593 |
Serial |
8443 |
|
Permanent link to this record |
|
|
|
|
Author |
Potgieter-Vermaak, S.S.; Potgieter, J.H.; Monama, P.; Van Grieken, R. |
|
|
Title |
Comparison of limestone, dolomite and fly ash as pre-treatment agents for acid mine drainage |
Type |
A1 Journal article |
|
Year |
2006 |
Publication |
Minerals engineering |
Abbreviated Journal |
|
|
|
Volume |
19 |
Issue |
5 |
Pages |
454-462 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
|
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|
Address |
|
|
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Corporate Author |
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Thesis |
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|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
000235961100009 |
Publication Date |
2005-09-17 |
|
|
Series Editor |
|
Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0892-6875 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:56983 |
Serial |
7694 |
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Permanent link to this record |
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Author |
Belikov, K.N.; Mikhailova, L.I.; Spolnik, Z.M.; Van Grieken, R. |
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Title |
EDXRF determination of impurities in potassium dihydrogenphosphate single crystals and raw materials |
Type |
A1 Journal article |
|
Year |
2006 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
|
Volume |
35 |
Issue |
2 |
Pages |
112-115 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000236405500005 |
Publication Date |
2005-10-14 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
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Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:56727 |
Serial |
7835 |
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Permanent link to this record |
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Author |
Delalieux, F.; Tsuji, K.; Wagatsuma, K.; Van Grieken, R. |
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Title |
Material analysis methods applied to the study of ancient monuments, works of art and artefacts |
Type |
A1 Journal article |
|
Year |
2002 |
Publication |
Materials transactions |
Abbreviated Journal |
|
|
|
Volume |
43 |
Issue |
9 |
Pages |
2197-2200 |
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|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000178449800008 |
Publication Date |
2005-10-17 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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|
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Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:40618 |
Serial |
8208 |
|
Permanent link to this record |
|
|
|
|
Author |
Smekens, A.; Godoi, R.H.M.; Berghmans, P.; Van Grieken, R. |
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|
Title |
Characterisation of soot emitted by domestic heating, aircraft and cars using diesel or biodiesel |
Type |
A1 Journal article |
|
Year |
2005 |
Publication |
Journal of atmospheric chemistry |
Abbreviated Journal |
|
|
|
Volume |
52 |
Issue |
1 |
Pages |
45-62 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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|
Abstract |
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|
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
000232793100003 |
Publication Date |
2005-10-21 |
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|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0167-7764 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:55211 |
Serial |
7601 |
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Permanent link to this record |
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|
|
|
Author |
Potgieter-Vermaak, S.S.; Potgieter, J.H.; Van Grieken, R. |
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|
Title |
The application of Raman spectrometry to investigate and characterize cement: part I: a review |
Type |
A1 Journal article |
|
Year |
2006 |
Publication |
Cement and concrete research |
Abbreviated Journal |
|
|
|
Volume |
36 |
Issue |
4 |
Pages |
656-662 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
|
|
|
Address |
|
|
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Corporate Author |
|
Thesis |
|
|
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Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Wos |
000236781200006 |
Publication Date |
2005-11-03 |
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|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0008-8846 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:57470 |
Serial |
7482 |
|
Permanent link to this record |