| Records |
| Author |
Vanderstappen, M.G.; Van Grieken, R.E. |
| Title |
Co-crystallization with 1-(2-pyridylazo)-2-naphthol, and X-ray fluorescence, for trace metal analysis of water |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
|
| Volume |
25 |
Issue |
11/12 |
Pages |
653-658 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Adding 20mg of 1-(2-pyridylazo)-2-naphthol (PAN) to a water sample at 70°, and filtering off the precipitate after cooling, gives efficient preconcentration prior to X-ray fluorescence analysis of water. Up to the capacity of about 100 μeq of PAN used, the trace metal recoveries are around 90% or higher for Cr3+, Mn2+, Ni2+, Cu2+, Zn2+, Hg2+ and Eu3+, and above 70% for many other ions. The recovery yields usually do not vary critically with pH in the neutral pH-range, and are practically independent of the sample salinity, sample volume and trace-metal concentration. Enrichment factors as high as 2 × 105 can be achieved. Counting statistics would then allow detection limits of 0.03 ppM. The blank levels in commercial PAN, however, lead to typical detection limits of about 1 ppm. The coefficient of variation is typically in the 510% range at the 10-ppM level. The accuracy and applicability of the procedure are illustrated by comparative analyses on samples of synthetic solutions, river and drinking water. |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1978GG18200005 |
Publication Date |
2002-07-25 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0039-9140; 1873-3573 |
ISBN |
|
Additional Links  |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116556 |
Serial |
7675 |
| Permanent link to this record |
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| |
| Author |
Vanderborght, B.M.; Van Grieken, R.E. |
| Title |
Water analysis by spark-source mass-spectrometry after preconcentration on activated carbon |
Type |
A1 Journal article |
| Year |
1980 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
|
| Volume |
27 |
Issue |
5 |
Pages |
417-422 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
For trace analyses of environmental waters, spark-source mass-spectrometry has been combined with a preconcentration procedure involving chelation of the dissolved trace elements with oxine and subsequent adsorption of the oxinates and naturally occurring organic and colloidal metal species onto activated carbon. The activated carbon is filtered off and ashed at low temperature. The residue is dissolved, an internal standard and pure graphite are added and, after drying, the electrodes are prepared. The photographically recorded mass spectrum is evaluated by a suitable computer routine. The error of the procedure is around 30%. While this preconcentration and analysis procedure is capable of measuring about 40 elements quantitatively, in practice 1025 trace elements are determined simultaneously above the 0.1-μg/l. detection limit, as is illustrated by analyses of drinking water, surface and ground water samples. Although a sophisticated technique, SSMS can be considered for regular panoramic survey analyses. |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1980JR07800006 |
Publication Date |
2002-07-25 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0039-9140; 1873-3573 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:116557 |
Serial |
8746 |
| Permanent link to this record |
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| |
| Author |
Robberecht, H.J.; Van Grieken, R.E.; Van den Bosch, P.A.; Deelstra, H.; vanden Berghe, D. |
| Title |
Losses of metabolically incorporated selenium in common digestion procedures for biological material |
Type |
A1 Journal article |
| Year |
1982 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
|
| Volume |
29 |
Issue |
11 |
Pages |
1025-1028 |
| Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Two common procedures for wet destruction of biological materials for subsequent determination of selenium have been investigated. Rat organs and biological fluids were endogenously labelled with 75Se to monitor losses during the procedures. Addition of nitric and perchloric acids with gradual heating up to 210° seemed to be the best method: at this temperature the labelled selenium was still recovered quantitatively, and the destruction was fast and efficient. |
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Thesis |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1982PP35500009 |
Publication Date |
2002-07-25 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0039-9140; 1873-3573 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116568 |
Serial |
8186 |
| Permanent link to this record |
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| |
| Author |
Vanderborght, B.M.; Van Grieken, R.E. |
| Title |
Trace metal analysis of water containing humic substances by X-ray fluorescence |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
5 |
Issue |
3 |
Pages |
221-237 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Chelation by oxine followed by adsorption on activated carbon results in the efficient collection of many trace metal ions, independent of the trace metal concentration and of high alkali and alkaline earth ion abundances. Preconcentration factors around 10000 are often achieved. When this preconcentration procedure is combined with energy-dispersive X-ray fluorescence, accurate and precise analysis can be carried out, as was proven in several experiments. The technique can also be applied for the determination of divalent ions in natural waters containing up to 10 ppm of humic substances. Trivalent ions can quantitatively be collected from natural water provided suKicient activated carbon is added. Omitting the oxine chelation prior to the activated carbon adsorption step still results in collection of a sometimes important fraction of the trace metal ions from natural waters. This is related to organically bound or colloidal forms of the trace metals. |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1978FR88000005 |
Publication Date |
2007-07-07 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116570 |
Serial |
8692 |
| Permanent link to this record |
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| |
| Author |
Smits, J.; Van Grieken, R. |
| Title |
Chelating 2,2′-diaminodiethylamine cellulose filters and X-ray fluorescence for preconcentration and trace analysis of natural waters |
Type |
A1 Journal article |
| Year |
1981 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
9 |
Issue |
2 |
Pages |
81-92 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The 2,2′-diaminodiethylamine (DEN) functional group can be expected to have ideal properties for the chelation of transition metals and their collection from aqueous solutions, independent of the alkali and alkaline earth ions concentration. Introducing DEN into cellulose filters allows straightforward preconcentration of trace cations by a simple filtration step, and the DEN-filter constitutes a suitable target for X-ray fluorescence (XRF) analysis. The linearity between the XRF-response on the loaded DEN-filter and the trace cation concentration in the solution appears excellent, up to a total filter capacity of ca. 3 μeq.cm−2. The detection limits are around 0.5 μg. l−1 in most practical cases. Accuracy and precision are around 10%. The applicability of the proposed procedure is illustrated on a comparative basis by XRF-analysis of drinking water and surface water, after preconcentration by DEN-filtration and by alternative procedures. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1981LF48000001 |
Publication Date |
2007-07-07 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116571 |
Serial |
7638 |
| Permanent link to this record |
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| |
| Author |
Chakravorty, R.; Van Grieken, R. |
| Title |
Co-precipitation with iron hydroxide and X-ray fluorescence analysis of trace metals in water |
Type |
A1 Journal article |
| Year |
1982 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
11 |
Issue |
1 |
Pages |
67-80 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Preconcentration of transition trace ions by coprecipitation on iron-hydroxide has been combined with energy-dispersive X-ray fluorescence for environmental water analysis. The optimized preconcentration procedure implies adding 2 mg of iron to a 200 ml water sample, adding dilute NaOH up to pH 9, filtering off on a Nuclepore membrane after a 1 h equilibration time, and analyzing. Quantitative recoveries could then be obtained for Ni, Cu, Zn and Pb, e.g. at the 10 μg/l level in waters of varying salinity while Mn was partially collected. (In fact, for a given problem the iron carrier amount can be adjusted to obtain a satisfactory compromise between high recovery and low detection limit). The precision is 7-8% at the 10 μg/l level, and the detection limits are in the 0.5-1 μg/l range. Various environmental water samples are analysed by way of illustration. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1982NG99200007 |
Publication Date |
2007-07-07 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116573 |
Serial |
7676 |
| Permanent link to this record |
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| |
| Author |
Bruynseels, F.; Storms, H.; Tavares, T.; Van Grieken, R. |
| Title |
Characterization of individual particle types in coastal air by laser microprobe mass analysis |
Type |
A1 Journal article |
| Year |
1985 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
23 |
Issue |
1 |
Pages |
1-14 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Laser Microprobe Mass Analysis (LAMMA) was used in a preliminary study to characterize aerosol particles from a beach and inland sites and from a heavily industrialized area. As many as six types of both positive and negative mass spectra with different inorganic and organic signals could be distinguished in the different particle size ranges. Information about the elemental composition and the speciation of S and N was obtained. With increasing distance from sea, progressive uptake of nitrate in seasalt particles was found. Complex particles, containing soot and organic ammonium sulfate, were also detected. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1985AZE1800001 |
Publication Date |
2007-07-07 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116575 |
Serial |
7626 |
| Permanent link to this record |
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|
| |
| Author |
Niessner, R.; Klockow, D.; Bruynseels, F.; Van Grieken, R. |
| Title |
Investigation of heterogeneous reactions of PAH's on particle surfaces using laser microprobe mass analysis |
Type |
A1 Journal article |
| Year |
1985 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
22 |
Issue |
3/4 |
Pages |
281-295 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Artificially generated NaCl particles were coated with PAH's by using a condensation technique. These particles were exposed to reactive gases like ozone, bromine and nitrogen dioxide. The original as well as the exposed particles were investigated by fluorimetric analysis and by LAMMA (Laser Microprobe Mass Analysis) in the desorption mode, which allows the evaporation and characterization of surfaces of single particles. The results are interpreted in terms of possible heterogeneous atmospheric reactions. The reactivity of the considered PAH's towards nitrogen dioxide was found to be negligible. The structure of the reaction products formed with ozone was partially elucidated. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1985AZE2300009 |
Publication Date |
2007-07-07 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116576 |
Serial |
8124 |
| Permanent link to this record |
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| |
| Author |
Wouters, L.; Bernard, P.; Van Grieken, R. |
| Title |
Characterization of individual estuarine and marine particles by LAMMA and EPXMA |
Type |
A1 Journal article |
| Year |
1988 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
34 |
Issue |
1 |
Pages |
17-29 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Laser microprobe mass analysis (LAMMA) was applied to particulate matter from the Atlantic Ocean. Inferring information about the surface layer by LAMMA was not probe X-ray microanalysis (EPXMA). Geochemically relevant groups of particles had been identified by EPXMA and cluster analysis. For both locations, the most abundant ones appeared to be those rich in silicon and the alumino-silicates. Afterwards LAMMA was applied to obtain more information about the trace element composition and surface characteristics. The iron-rich phase appeared to contain significant amounts of heavy metals and of phosphate. Lead appeared to be associated in detectable amounts with alumino-silicates in the Scheldt but not with those in the Atlantic Ocean. Inferring information about the surface layer by LAMMA was not always unambiguous. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1988Q274200002 |
Publication Date |
2007-07-07 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116577 |
Serial |
7624 |
| Permanent link to this record |
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| |
| Author |
Goossenaerts, C.; Van Grieken, R.; Jacob, W.; Witters, H.; Vanderborght, O. |
| Title |
A microanalytical study of the gills of aluminium-exposed rainbow trout (Salmo gairdneri) |
Type |
A1 Journal article |
| Year |
1988 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
34 |
Issue |
3 |
Pages |
227-237 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1988T017900005 |
Publication Date |
2007-07-07 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116579 |
Serial |
8240 |
| Permanent link to this record |
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| |
| Author |
Wouters, L.; Artaxo, P.; Van Grieken, R. |
| Title |
Laser microprobe mass analysis of individual Antarctic aerosol particles |
Type |
A1 Journal article |
| Year |
1990 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
38 |
Issue |
3 |
Pages |
427-438 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Individual Antarctic aerosol particles in the 0.54 μm aerodynamic diameter range were analyzed using laser microprobe mass analysis (LAMMA). As they were sampled near the ocean, the great majority consists of seasalt, transformed to various degrees in the atmosphere. Major alterations include the association of an excess sulfate and methane sulfonate with these particles. Sulfate-rich particles containing little or no chloride were found mostly in the smallest size fraction (0.51 μm), where they account for some 5% of all particles: they are most likely highly transformed seasalt. Aluminosilicates, on the other hand, only appear among the coarser particles: they represent 2% of the particulates in the 24 μm range. The remainder of the aerosol consists of organic, Fe-rich, K-rich and Zn-rich particles. The latter groups have very low abundances: always less than 1% of the population of the impactor stage(s) onto which they were collected. |
| Address |
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| Corporate Author |
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Thesis |
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Place of Publication |
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Editor |
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Wos |
A1990CN56100011 |
Publication Date |
2007-07-07 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116580 |
Serial |
8160 |
| Permanent link to this record |
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| |
| Author |
Sholkovitz, E.R.; Van Grieken, R.; Eisma, D. |
| Title |
The major-element composition of suspended matter in the Zaire river and estuary |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
|
| Volume |
12 |
Issue |
3/4 |
Pages |
407-413 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
|
Publication Date |
2003-08-07 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0077-7579; 1873-1406 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116608 |
Serial |
8195 |
| Permanent link to this record |
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| |
| Author |
Martin, J.-M.; Thomas, A.J.; Van Grieken, R.E. |
| Title |
Trace element composition of Zaire suspended sediments |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
|
| Volume |
12 |
Issue |
3/4 |
Pages |
414-420 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
2003-08-07 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0077-7579; 1873-1406 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116609 |
Serial |
8688 |
| Permanent link to this record |
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| |
| Author |
Verbueken, A.; Van Grieken, R. |
| Title |
Influence on photoplate evaluation parameters in spark source mass spectrometric analysis |
Type |
A1 Journal article |
| Year |
1981 |
Publication |
Bulletin des sociétés chimiques belges |
Abbreviated Journal |
|
| Volume |
90 |
Issue |
|
Pages |
331-341 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
|
| ISSN |
0037-9646 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116626 |
Serial |
8099 |
| Permanent link to this record |
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| |
| Author |
Van Grieken, R.E.; Johansson, T.B.; Winchester, J.W.; Odom, L. |
| Title |
Micro-determination of zirconium-hafnium ratios in zircons by proton induced X-ray emission |
Type |
A3 Journal article |
| Year |
1975 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
275 |
Issue |
5 |
Pages |
343-348 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The zirconium/hafnium ratios of zircons are determined using proton induced X-ray emission. Submilligram samples, imbedded in a starch layer and deposited on a 50 μg/cm2 polystyrene carrier, are irradiated for 1020 min with a 5 nA beam of 3.7 MeV protons, while the Hf-Lβ and Zr-Kα X-rays are counted with a Si(Li) detector. The standard deviation per analysis is in the 36 % range. Only few interferences are possible. To eliminate errors due to absorption effects the zircon layer thickness should be above 40 μm or reproducibly thin samples should be employed. Measuring the Hf-Lβ/Hf-Lα ratio for samples and standards might provide a practical check for the absence of absorption errors. The sensitivity is so favourable that, in practice, the minimal sample size is only limited by the minimal amount that can be handled properly. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
|
Publication Date |
2004-11-11 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116636 |
Serial |
8231 |
| Permanent link to this record |
| |
|
| |
| Author |
Vanderstappen, M.; Van Grieken, R. |
| Title |
Trace metal analysis of sediments and particulate matter in sea water by energy-dispersive X-ray fluorescence |
Type |
A3 Journal article |
| Year |
1976 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
282 |
Issue |
1 |
Pages |
25-30 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The capability of energy-dispersive X-ray fluorescence was investigated for fast and simple chemical analysis of trace elements in sediments and particulate matter in sea water. Nuclepore 0.4 μm pore-size membranes are recommended as optimal filters for a straightforward collection of suspended material. The collection of suspended trace metals by filtration seemed to give a sufficiently homogeneous filter load (s% <2.5). Data are presented on the concentrations of K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Br, Pb, Rb and Sr with a fair precision (s% < 5.6) and accuracy. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
|
Publication Date |
2004-11-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116637 |
Serial |
8691 |
| Permanent link to this record |
| |
|
| |
| Author |
Vandelannoote, R.; Blommaert, W.; Gijbels, R.; van Grieken, R. |
| Title |
Analysis of geothermal waters by spark source mass spectrometry |
Type |
A3 Journal article |
| Year |
1981 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
309 |
Issue |
4 |
Pages |
291-294 |
| Keywords |
A3 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Although the analysis of thermal water by spark-source mass spectrometry (SSMS) is rather timeconsuming, it allows the detection of about 20 elements of geochemical interest down to the ppb-level. A physical preconcentration is proposed in order to collect elements having quite different chemical properties, e.g. alkalis, transition elements, and elements occurring in anionic form. The relative sensitivity factors appear to be rather independent of the salt content of the graphite electrodes. Contrary to neutron activation analysis, SSMS has a quite uniform elemental sensitivity, and allows to determine elements for which neutron activation is not suitable, e.g. Sn and Pb. The precision of SSMS is however by a factor of about 2 worse than that obtained for neutron activation. |
| Address |
|
| Corporate Author |
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Thesis |
|
| Publisher |
|
Place of Publication |
München |
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2004-11-15 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152;1618-2650; |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
8 |
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ lucian @ c:irua:116638 |
Serial |
100 |
| Permanent link to this record |
| |
|
| |
| Author |
Verbueken, A.; Michiels, E.; Van Grieken, R. |
| Title |
Total analysis of plant material and biological tissue by spark source mass spectrometry |
Type |
A3 Journal article |
| Year |
1981 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
309 |
Issue |
4 |
Pages |
300-304 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Analysis of biological material by spark source mass spectrometry is reported. Preliminary studies mainly based upon the analysis of the NBS standard reference material SRM-1571 (Orchard Leaves) are described. Attention is drawn to the importance of a suitable sample preparation method. The advantages of a wet digestion technique in a Teflon bomb are discussed and its use is justified by the satisfactory overall analysis precision of about 20%. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2004-11-15 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116639 |
Serial |
8675 |
| Permanent link to this record |
| |
|
| |
| Author |
Reggers, C.; Van Grieken, R. |
| Title |
2,2′-Diaminodiethylamine cellulose powder for trace metal preconcentrations from water |
Type |
A3 Journal article |
| Year |
1984 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
317 |
Issue |
5 |
Pages |
520-526 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Cellulose powder with 2,2′-diaminodiethylamine (DEN) functional groups exhibits efficient complexation of transition metal cations. Collection yields above 85 % are obtained up to a chelation capacity of 1.5 meq per gram. Since a good collection is obtained for a pH up from 5, no pH adjustments have to be made for natural water samples. The cellulose-DEN powder is insensitive to abundant substances like alkali and alkaline earth ions, and humic matter. Some cations can be eluted efficiently in a small volume of HNO3. Blank concentration levels from the cellulose-DEN powder are reported. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2004-11-17 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116640 |
Serial |
7383 |
| Permanent link to this record |
| |
|
| |
| Author |
Vos, L.; Van Grieken, R. |
| Title |
Matrix effects and analysis of biological material by spark source mass spectrometry |
Type |
A3 Journal article |
| Year |
1985 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
321 |
Issue |
1 |
Pages |
32-36 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Spark-source mass spectrometric analyses of synthetic simulated biological samples were performed to determine the importance of matrix effects. A correlation between the variation of the relative sensitivity coefficients (RSC's) and the spark plasma composition, hence plasma temperature, was found. The determined RSC's were used in the analysis of four biological standard reference materials. An accuracy of 1013% and detection limits between 0.005 and 0.5 ppm were obtained during analysis under normal conditions. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
|
| Language |
|
Wos |
|
Publication Date |
2004-11-14 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116641 |
Serial |
8209 |
| Permanent link to this record |
| |
|
| |
| Author |
Van Grieken, R.; Markowicz, A.; Török, S. |
| Title |
Energy-dispersive X-ray spectrometry : present state and trends |
Type |
A3 Journal article |
| Year |
1986 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
324 |
Issue |
8 |
Pages |
825-831 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Recent development, present state and expected future developments in energy-dispersive X-ray spectrometry are discussed. Attention is paid to the improvements in analytical selectivity, sensitivity, detection limit, quantitative character and applicability range, which are the result of new or better excitation sources, detectors, instrument design, automation, computer software and theoretical developments. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
|
| Language |
|
Wos |
|
Publication Date |
2004-11-15 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116642 |
Serial |
7907 |
| Permanent link to this record |
| |
|
| |
| Author |
Vanderborght, B.; Van Grieken, R. |
| Title |
Perspectieven voor energie-dispersieve X-stralen fluorescentie bij de wateranalyse |
Type |
A3 Journal article |
| Year |
1975 |
Publication |
Hydrographica |
Abbreviated Journal |
|
| Volume |
1 |
Issue |
|
Pages |
19-26 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
|
| ISSN |
|
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116643 |
Serial |
8375 |
| Permanent link to this record |
| |
|
| |
| Author |
Smits, J.; Van Grieken, R. |
| Title |
Synthesis of a chelating cellulose filter with 2,2-diaminodiethylamine functional groups |
Type |
A3 Journal article |
| Year |
1978 |
Publication |
Zeitschrift für angewandte Makromolekare Chemie |
Abbreviated Journal |
|
| Volume |
72 |
Issue |
|
Pages |
105-113 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
|
| Corporate Author |
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Thesis |
|
| Publisher |
|
Place of Publication |
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Editor |
|
| Language |
|
Wos |
|
Publication Date |
|
| Series Editor |
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Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
|
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116644 |
Serial |
8637 |
| Permanent link to this record |
| |
|
| |
| Author |
Robberecht, H.; vanden Berghe, D.; Deelstra, H.; Van Grieken, R. |
| Title |
Selenium in the Belgian soils and its uptake by rye-grass |
Type |
A1 Journal article |
| Year |
1982 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
25 |
Issue |
1 |
Pages |
61-69 |
| Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Data obtained by atomic absorption spectroscopy showed a selenium concentration of only 0.11 ppm as an average value for the most representative agricultural soils in Belgium. The selenium content in rye-grass grown on different soil types was between 0.05 and 0.11 ppm, and positively correlated with the soil selenium level. Addition of selenium in the form of selenite to the different soil types resulted in an increased selenium uptake by the plant. The ultimate concentration in the plant depended on the structural and chemical composition of the soil. Twelve other elements were determined in the soils by energy-dispersive X-ray fluorescence; none showed a strong correlation with the soil selenium content or with the selenium uptake by ryegrass. |
| Address |
|
| Corporate Author |
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Thesis |
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| Publisher |
|
Place of Publication |
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Editor |
|
| Language |
|
Wos |
A1982PJ93000006 |
Publication Date |
2003-09-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116646 |
Serial |
8510 |
| Permanent link to this record |
| |
|
| |
| Author |
Robberecht, H.; Van Grieken, R.; van Sprundel, M.; vanden Berghe, D.; Deelstra, H. |
| Title |
Selenium in environmental and drinking waters of Belgium |
Type |
A1 Journal article |
| Year |
1983 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
26 |
Issue |
2 |
Pages |
163-172 |
| Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The tetravalent and hexavalent selenium content of water samples can be determined by conventional energy-dispersive X-ray fluorescence after different preconcentration steps. Selenium values of nearly three-hundred different environmental and drinking water samples in Belgium are reported. The results are quite low, ranging from the detection limits up to 1 μg l−1. The concentration levels are compared to literature data and the speciation is discussed. The contribution of drinking water to the daily intake of selenium in Belgium ranges from less than 0.2 to 5%. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
|
Place of Publication |
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Editor |
|
| Language |
|
Wos |
A1983QD20900006 |
Publication Date |
2003-09-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116647 |
Serial |
8508 |
| Permanent link to this record |
| |
|
| |
| Author |
Robberecht, H.; Deelstra, H.; vanden Berghe, D.; Van Grieken, R. |
| Title |
Metal pollution and selenium distributions in soils and grass near a non-ferrous plant |
Type |
A1 Journal article |
| Year |
1983 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
29 |
Issue |
3 |
Pages |
229-241 |
| Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Multi-element analysis results of direct energy-dispersive X-ray fluorescence of soil samples taken in the vicinity of a non-ferrous plant in Antwerp are reported. High concentrations of Pb, Cu, Zn, As and Se are found in nearby residential areas, especially in top-soil layers. Selenium pollution appears not to be leached significantly to lower soil horizons, but it is available for uptake by rye-grass, in which toxic levels are found. Results are compared to literature data. Hydride generation atomic absorption spectrometry proved to be unsuitable for direct analysis of the heavily contaminated soils. |
| Address |
|
| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
|
| Language |
|
Wos |
A1983RE16300003 |
Publication Date |
2003-09-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116648 |
Serial |
8218 |
| Permanent link to this record |
| |
|
| |
| Author |
Leysen, L.; Roekens, E.; Van Grieken, R. |
| Title |
Air-pollution-induced chemical decay of a sandy-limestone cathedral in Belgium |
Type |
A1 Journal article |
| Year |
1989 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
78 |
Issue |
|
Pages |
263-277 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Different trace- and microanalytical techniques were used in an extensive study to elucidate the chemical deterioration process of the sandy-limestone St Rombouts Cathedral in Mechelen, Belgium. Samples of stones, mortar joints, slates, atmospheric aerosols and gases, total and wet deposition, and water that had run down the cathedral walls, were all thoroughly characterized. At the east side, usually not exposed to precipitation, a 3001000-μm thick outer crust of microcrystalline gypsum was observed, while at the west side, this surface layer was mostly eroded away due to precipitation. At the north and south sides, the crust contains varying amounts of gypsum and calcite. The gypsum is mostly present in a bar-shaped morphology and carbonaceous fly-ash particles were rarely found in the weathering crust. Local stone characteristics seem to be extremely important in relation to the gypsum content of the crust; black samples always have a much higher sulphate content than the corresponding white samples, irrespective of the predominant direction of orientation. The relative contribution of nitrogen- and chlorine-containing pollutants to the total decay process is much smaller than that of sulphur-containing pollutants. Deposition samples collected at the site of the cathedral mostly had a pH of > 5.6, due to the neutralization of the rainwater by alkaline atmospheric constituents. Runoff water and washdown water were enriched in all ions, especially Ca2+ and SO42−, indicating that, indeed, gypsum is the most important weathering product. The suspension in deposition samples and black-well leaching water was highly enriched in silicon-containing particles, while runoff water and white-wall leaching water contained a predominant calcium-rich suspension. |
| Address |
|
| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
|
| Language |
|
Wos |
A1989R806400021 |
Publication Date |
2003-09-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116649 |
Serial |
7431 |
| Permanent link to this record |
| |
|
| |
| Author |
Leysen, L.A.; Roekens, E.J.; Van Grieken, R.E.; De Geyter, G. |
| Title |
Characterization of the weathering crust of various historical buildings in Belgium |
Type |
A1 Journal article |
| Year |
1990 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
90 |
Issue |
|
Pages |
117-147 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
A variety of samples, collected from different historical buildings and monuments throughout Belgium, were thoroughly studied, using several trace- and micro-analysis techniques. Thin sections of stones and mortar joints were characterized by means of electron probe X-ray microanalysis (EPXMA). The morphological appearance of the surface weathering crust and the possible presence of non-innate particles in the crust were elucidated using petrographical and electron microscopy. Quantitative characterization of the total chemical composition of the crust surface layer and underlying layer was performed by energy-dispersive X-ray fluorescence, and by ion chromatography and atomic absorption spectrometry for the leachable components. Special attention was also paid to the chemical composition of rain and air at the particular sampling sites. The element distribution in the transition zone between the weathering crust and the original stone material was found to vary greatly amongst the different samples analyzed. Detailed EPXMA measurements on pieces of the weathering crust showed remarkable differences in morphology and composition between the surface and the underlying layer, and provided information about the presence of fly-ash and soil dust particles in the crust. Except for crusts from the city of Brussels, which were all very high in sulphate, the samples appeared to contain very variable sulphate contents; very local micro-climate and environmental conditions at a particular site are more important in determining the weathering condition of the building stones than the local air pollution situation. Bulk analytical characterization further showed, in all the crust samples studied, a very small contribution of nitrogen- and chlorine-containing weathering products, in contrast to sulphur-containing weathering salts. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
A1990CJ43500010 |
Publication Date |
2003-09-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116650 |
Serial |
7636 |
| Permanent link to this record |
| |
|
| |
| Author |
Van Borman, W.; Wouters, L.; Van Grieken, R.; Adams, F. |
| Title |
Lead particles in an urban atmosphere : an individual particle approach |
Type |
A1 Journal article |
| Year |
1990 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
90 |
Issue |
|
Pages |
55-66 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
In air particulate matter, sampled at a suburban site near the city of Antwerp, Belgium, more than 1500 individual Pb-containing aerosol particles with projected diameters between 0.2 and 15 μm were analyzed by automated electron probe X-ray micro analysis (EPXMA) for 26 elements and morphological features. Laser microprobe mass analysis (LAMMA) was used to detect elements with Z < 11, particularly ammonium compounds. The Pb-containing particles were classified into five main classes: Pb-sulfates, Pb-halides, soil related Pb, Pb associated with medium atomic number elements and Pb associated with high atomic number elements. Each class was divided into several distinct particle types, of which the abundance (in number and mass %), the mean projected particle diameter, and the chemical composition were determined. Auto exhaust products are responsible for Pb-sulfates and Pb-halides, making up respectively 66.7 and 27.8% by mass of the Pb-containing particles. Ammonium sulfate coatings were found to be present on nearly all Pb particles. The observations were correlated with daily concentrations of Pb and Br, obtained by particle induced X-ray emission analysis (PIXE). |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1990CJ43500005 |
Publication Date |
2003-09-12 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:116651 |
Serial |
8169 |
| Permanent link to this record |
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| Author |
Rojas, C.M.; Figueroa, L.; Janssens, K.H.; Van Espen, P.E.; Adams, F.C.; Van Grieken, R.E. |
| Title |
The elemental composition of airborne particulate matter in the Atacama desert, Chile |
Type |
A1 Journal article |
| Year |
1990 |
Publication |
The science of the total environment |
Abbreviated Journal |
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| Volume |
91 |
Issue |
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Pages |
251-267 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Air particulate samples were collected at Chapiquiña near Arica (Chile) with a six-stage cascade impactor for about 17-day periods during a 31 month interval. Sixteen elements were determined by energy dispersive X-ray fluorescence analysis, and the elemental concentrations were subjected to principal factor analysis. The variability with time of the coarse particles was described by two factors both related to soil dispersion, whereas the fine particle variations could be explained by a third factor related to marine influence. Enrichment factors were compared with those obtained in other remote continental areas, in particular those of air particulate matter sampled at Chacaltaya, Bolivia. Results point to a negligible anthropogenic influence. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1990CM36100019 |
Publication Date |
2003-09-12 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0048-9697 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:116652 |
Serial |
5602 |
| Permanent link to this record |
