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Author	Fedotov, S.S.; Kuzovchikov, S.M.; Khasanova, N.R.; Drozhzhin, O.A.; Filimonov, D.S.; Karakulina, O.M.; Hadermann, J.; Abakumov, A.M.; Antipov, E.V.
Title	Synthesis, structure and electrochemical properties of LiNaCo0.5Fe0.5PO4F fluoride-phosphate			Type	A1 Journal article
Year	2016	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	242	Issue	242	Pages	70-77
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	LiNaCo 0.5 Fe 0.5 PO 4 F fluoride-phosphate was synthesized via conventional solid-state and novel freeze-drying routes. The crystal structure was refined based on neutron powder diffraction (NPD) data and validated by electron diffraction (ED) and high-resolution transmission electron microscopy (HRTEM). The alkali ions are ordered in LiNaCo 0.5 Fe 0.5 PO 4 F and the transition metals jointly occupy the same crystallographic sites. The oxidation state and oxygen coordination environment of the Fe atoms were verified by 57 Fe Mössbauer spectroscopy. Electrochemical tests of the LiNaCo 0.5 Fe 0.5 PO 4 F cathode material demonstrated a reversible activity of the Fe 3+ /Fe 2+ redox couple at the electrode potential near 3.4 V and minor activity of the Co 3+ /Co 2+ redox couple over 5 V vs Li/Li + . The material exhibits a good capacity retention in the 2.4÷4.6 V vs Li/Li + potential range with the delivered discharge capacity of more than 82% (theo.) regarding Fe 3+ /Fe 2+ .
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000383304900010	Publication Date	2016-02-27
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	1	Open Access
Notes	The authors kindly thank Dr. O. A. Shlyakhtin for the assistance in the freeze-drying synthesis. We are grateful to the Laboratory for Neutron Scattering and Imaging (NLS) at the Paul Scherrer Institut (Villigen, Switzerland) for granting beam time at the HRPT diffractometer and to Dr. D. V. Sheptyakov for the technical support during the experiment. The work was partly supported by Russian Foundation for Basic Research (RFBR grant 13-03-00495a, 14-29-04064 ofim, 16-33-01131 mola), Skoltech Center for Electrochemical Energy Storage and Moscow State University Development Program up to 2020. J. Hadermann, O.M. Karakulina and A.M. Abakumov acknowledge support from FWO under grant G040116N.			Approved	Most recent IF: 2.299
Call Number	c:irua:133776			Serial	4075
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Author	Frangis, N.; Van Tendeloo, G.; Manolikas, C.; Amelinckx, S.
Title	Structural and microstructural aspects of Six(Ta, Nb)Te2			Type	A1 Journal article
Year	1998	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	139	Issue		Pages	105-123
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000075511800013	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	2	Open Access
Notes				Approved	Most recent IF: 2.299; 1998 IF: 1.432
Call Number	UA @ lucian @ c:irua:25664			Serial	3199
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Author	Frolov, D.D.; Kotovshchikov, Y.N.; Morozov, I.V.; Boltalin, A.I.; Fedorova, A.A.; Marikutsa, A.V.; Rumyantseva, M.N.; Gaskov, A.M.; Sadovskaya, E.M.; Abakumov, A.M.
Title	Oxygen exchange on nanocrystalline tin dioxide modified by palladium			Type	A1 Journal article
Year	2012	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	186	Issue		Pages	1-8
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Temperature-programmed oxygen isotopic exchange study was performed on nanocrystalline tin dioxide-based materials synthesized via sol-gel route and modified by palladium. Such materials are widely used as resistive gas sensors. The experiments were carried out in a flow-reactor up to complete isotopic substitution of oxygen. Substantial rates of isotopic exchange for SnO2 were observed from about 700 K. The distribution of isotopic molecules O-16(2). (OO)-O-16-O-18 and O-18(2) corresponds to simple dioxygen heteroexchange mechanism with single lattice oxygen atom. The modification of SnO2 by Pd introduced multiple heteroexchange mechanism with preliminary O-2 dissociation on the clusters surface. Spill-over of atomic oxygen from Pd to the surface of SnO2 and fast exchange with lattice oxygen result in more than 100% increase of apparent heteroexchange rate. The exchange on SnO2/Pd was shown to be a complex process involving partial deactivation of the catalytic centers at temperature higher than 750 K. (C) 2011 Elsevier Inc. All rights reserved.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000299801400001	Publication Date	2011-12-08
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	34	Open Access
Notes				Approved	Most recent IF: 2.299; 2012 IF: 2.040
Call Number	UA @ lucian @ c:irua:96202			Serial	2546
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Author	Gillie, L.J.; Hadermann, J.; Pérez, O.; Martin, C.; Hervieu, M.; Suard, E.
Title	SrMn₃O₆: an incommensurate modulated tunnel structure			Type	A1 Journal article
Year	2004	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	177	Issue		Pages	3383-3391
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000224465500020	Publication Date	2004-07-21
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	19	Open Access
Notes	Scootmo: Hrpn-Ct-2002-00293; Super-Gmr: Hprn-Ct-2002-0021			Approved	Most recent IF: 2.299; 2004 IF: 1.815
Call Number	UA @ lucian @ c:irua:49463			Serial	3562
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Author	Gillie, L.J.; Wright, A.J.; Hadermann, J.; Van Tendeloo, G.; Greaves, C.
Title	Synthesis and characterization of the reduced double-layer manganite Sr₃Mn₂O_6+x			Type	A1 Journal article
Year	2003	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	175	Issue		Pages	188-196
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000186126600007	Publication Date	2003-09-03
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	18	Open Access
Notes				Approved	Most recent IF: 2.299; 2003 IF: 1.413
Call Number	UA @ lucian @ c:irua:42713			Serial	3419
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Author	Gillie, L.J.; Wright, A.J.; Hadermann, J.; Van Tendeloo, G.; Greaves, C.
Title	Synthesis and characterization of the reduced single-layer manganite Sr₂MnO_3.5+x			Type	A1 Journal article
Year	2002	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	167	Issue		Pages	145-151
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000177915800018	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	25	Open Access
Notes				Approved	Most recent IF: 2.299; 2002 IF: 1.671
Call Number	UA @ lucian @ c:irua:40347			Serial	3420
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Author	Golovachev, I.B.; Mychinko, M.Y.; Volkova, N.E.; Gavrilova, L.Y.; Raveau, B.; Maignan, A.; Cherepanov, V.A.
Title	Effect of cobalt content on the properties of quintuple perovskites Sm₂Ba₃Fe₅-xCoxO₁₅-δ			Type	A1 Journal article
Year	2021	Publication	Journal Of Solid State Chemistry	Abbreviated Journal	J Solid State Chem
Volume	301	Issue		Pages	122324
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Quintuple perovskites Sm2Ba3Fe5-xCoxO15-delta = 0.5, 1.0 and 1.5) have been prepared by glycerin-nitrate tech- nique in air. The phase purity was confirmed by XRD. Partial substitution of Co for Fe decreases the oxygen content and thus the mean oxidation state of 3d-metals. It also slightly decreases the thermal expansion coefficient of oxides. Positive value of the Seebeck coefficient confirmed p-type conductivity, though the thermopower decreases as the Co content increases. The temperature dependence of electrical conductivity reveals a maximum at 550-750 degrees C.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000684543700028	Publication Date	2021-06-03
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited		Open Access	OpenAccess
Notes				Approved	Most recent IF: 2.299
Call Number	UA @ admin @ c:irua:181656			Serial	6864
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Author	Hadermann, J.; Abakumov, A.M.; Lebedev, O.I.; Van Tendeloo, G.; Rozova, M.G.; Shpanchenko, R.V.; Pavljuk, B.P.; Kopnin, E.M.; Antipov, E.V.
Title	*Structural transformations in the fluorinated T^ phase**			Type	A1 Journal article
Year	1999	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	147	Issue		Pages	647-656
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000083652600028	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	8	Open Access
Notes				Approved	Most recent IF: 2.299; 1999 IF: 1.547
Call Number	UA @ lucian @ c:irua:29279			Serial	3266
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Author	Hadermann, J.; Abakumov, A.M.; Perkisas, T.; d' Hondt, H.; Tan, H.; Verbeeck, J.; Filonenko, V.P.; Antipov, E.V.; Van Tendeloo, G.
Title	New perovskite-based manganite Pb₂Mn₂O₅			Type	A1 Journal article
Year	2010	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	183	Issue	183	Pages	2190-2195
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	A new perovskite based compound Pb2Mn2O5 has been synthesized using a high pressure high temperature technique. The structure model of Pb2Mn2O5 is proposed based on electron diffraction, high angle annular dark field scanning transmission electron microscopy and high resolution transmission electron microscopy. The compound crystallizes in an orthorhombic unit cell with parameters a=5.736(1)Å≈√2a p p p (a p the parameter of the perovskite subcell) and space group Pnma. The Pb2Mn2O5 structure consists of quasi two-dimensional perovskite blocks separated by 1/2[110] p (1̄01) p crystallographic shear planes. The blocks are connected to each other by chains of edge-sharing MnO5 distorted tetragonal pyramids. The chains of MnO5 pyramids and the MnO6 octahedra of the perovskite blocks delimit six-sided tunnels accommodating double chains of Pb atoms. The tunnels and pyramidal chains adopt two mirror-related configurations (left L and right R) and layers consisting of chains and tunnels of the same configuration alternate in the structure according to an -LRLR-sequence. The sequence is sometimes locally violated by the appearance of -LL- or -RR-fragments. A scheme is proposed with a JahnTeller distortion of the MnO6 octahedra with two long and two short bonds lying in the ac plane, along two perpendicular orientations within this plane, forming a d-type pattern.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000282139600041	Publication Date	2010-07-25
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	8	Open Access
Notes	Fwo; Bof; Esteem 026019			Approved	Most recent IF: 2.299; 2010 IF: 2.261
Call Number	UA @ lucian @ c:irua:85472UA @ admin @ c:irua:85472			Serial	2332
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Author	Hadermann, J.; Khasanova, N.R.; Van Tendeloo, G.; Abakumov, A.M.; Rozova, M.G.; Alekseeva, A.M.; Antipov, E.V.
Title	Suppression of modulations in fluorinated Bi-2201 phases			Type	A1 Journal article
Year	2001	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	156	Issue		Pages	445-451
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000167252000027	Publication Date	2002-09-18
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	8	Open Access
Notes				Approved	Most recent IF: 2.299; 2001 IF: 1.614
Call Number	UA @ lucian @ c:irua:36046			Serial	3386
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Author	Hadermann, J.; Van Tendeloo, G.; Abakumov, A.M.; Rozova, M.G.; Antipov, E.V.
Title	HREM study of fluorinated Nd₂CuO₄			Type	A1 Journal article
Year	2001	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	157	Issue		Pages	56-61
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000167634500008	Publication Date	2002-09-18
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	7	Open Access
Notes				Approved	Most recent IF: 2.299; 2001 IF: 1.614
Call Number	UA @ lucian @ c:irua:36047			Serial	1510
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Author	He, Z.B.; Deng, G.; Tian, H.; Xu, Q.; Van Tendeloo, G.
Title	90° Rotation of orbital stripes in bilayer manganite PrCa₂Mn₂O₇ studied by in situ transmission electron microscopy			Type	A1 Journal article
Year	2013	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	200	Issue		Pages	287-293
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	We present an in situ transmission electron microscopy study on the half-doped bilayer manganite PrCa2Mn2O7 to reveal the rotation process of the orbital stripes. Between the reported initial and final ordering phases, we identified an intermediate state with two sets of satellite spots to bridge the 90° rotation of the orbital stripes. Furthermore, we determined that the rotation of the orbital stripes does not always occur. Some restricted conditions for the orbital rotation to occur were found and reasons are discussed.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000317158000043	Publication Date	2013-02-08
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	5	Open Access
Notes	Countatoms			Approved	Most recent IF: 2.299; 2013 IF: 2.200
Call Number	UA @ lucian @ c:irua:106183			Serial	20
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Author	Hendrickx, M.; Tang, Y.; Hunter, E.C.; Battle, P.D.; Cadogan, Jm.; Hadermann, J.
Title	CaLa2FeCoSbO9 and ALa2FeNiSbO9 (A = Ca, Sr, Ba): cation-ordered, inhomogeneous, ferrimagnetic perovskites			Type	A1 Journal article
Year	2020	Publication	Journal Of Solid State Chemistry	Abbreviated Journal	J Solid State Chem
Volume	285	Issue		Pages	121226
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Polycrystalline samples of CaLa2FeCoSbO9 and ALa2FeNiSbO9 (A=Ca, Sr, Ba) have been prepared in solid-state reactions and studied by a combination of transmission electron microscopy, magnetometry, X-ray diffraction, neutron diffraction and Mössbauer spectroscopy. Diffraction and TEM showed that each shows 1:1 B-site ordering in which Co2+/Ni2+ and Sb5+ tend to occupy two distinct crystallographic sites while Fe3+ is distributed over both sites. While X-ray and neutron diffraction agreed that all four compositions are monophasic with space group P21/n, TEM revealed different levels of compositional inhomogeneity at the subcrystal scale, which, in the case of BaLa2FeNiSbO9, leads to the occurrence of both a P21/n and an I2/m phase. Magnetometry and neutron diffraction show that these perovskites are ferrimagnets with a G-type magnetic structure. Their relatively low magnetisation can be attributed to their inhomogeneity. This work demonstrates the importance of studying the microstructure of complex compositions.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000521107900017	Publication Date	2020-01-30
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	3.3	Times cited		Open Access	OpenAccess
Notes	PDB, ECH, and JH acknowledge support from EPSRC under grant EP/M0189954/1. We would also like to thank E. Suard at ILL and I. Da Silva at ISIS for the experimental assistance they provided.			Approved	Most recent IF: 3.3; 2020 IF: 2.299
Call Number	EMAT @ emat @c:irua:167137			Serial	6345
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Author	Hendrickx, M.; Tang, Y.; Hunter, E.C.; Battle, P.D.; Hadermann, J.
Title	Structural and magnetic properties of the perovskites A₂LaFe₂SbO₉ (A = Ca, Sr, Ba)			Type	A1 Journal article
Year	2021	Publication	Journal Of Solid State Chemistry	Abbreviated Journal	J Solid State Chem
Volume	295	Issue		Pages	121914
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Polycrystalline samples of A(2)LaFe(2)SbO(9) (A = Ca, Sr, Ba) perovskites appeared monophasic to X-ray or neutron powder diffraction but a single-crystal study utilising transmission electron microscopy revealed a greater level of complexity. Although local charge balance is maintained, compositional and structural variations are present among and within the submicron-sized crystals. Despite the inhomogeneity, A = Ca is monophasic with a partially-ordered distribution of Fe3+ and Sb5+ cations across two crystallographically-distinct octahedral sites, i.e. Ca2La(Fe1.25Sb0.25)(2d) (Fe0.75Sb0.75)(2c)O-9. For A = Sr or Ba, the inhomogeneities result in differences in the filling patterns of the octahedra and the ordering of the B cations. Particles of A = Sr contain a phase (Fe:Sb similar to 2:1) without B cation ordering and one (Fe:Sb similar to 1:1) with B cation ordering. Monophasic A = Ba lacks long-range cation order although ordered nanodomains are present within the disordered phase. The temperature dependence of the magnetic properties of each sample is discussed.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000615711800013	Publication Date	2020-12-17
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited		Open Access	OpenAccess
Notes				Approved	Most recent IF: 2.299
Call Number	UA @ admin @ c:irua:176663			Serial	6739
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Author	Hervieu, M.; Pelloquin, D.; Michel, C.; Van Tendeloo, G.; Raveau, B.
Title	Structural characteristics of the 40K superconductor Bi₂Sr₅Cu₃(CO₃)₂O₁₀: a HREM study			Type	A1 Journal article
Year	1994	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	112	Issue		Pages	139-147
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1994PG30500024	Publication Date	0000-00-00
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.133	Times cited	5	Open Access
Notes				Approved
Call Number	UA @ lucian @ c:irua:10034			Serial	3216
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Author	Hervieu, M.; Van Tendeloo, G.; Michel, C.; Martin, C.; Maignan, A.; Raveau, B.
Title	Synthesis and characterization of mercury based “1222” cuprates (Hg_1-xM_x)(Sr,Ba)₂Pr₂Cu₂O_9-\delta (M = Pr, Pb, Bi, Tl)			Type	A1 Journal article
Year	1995	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	115	Issue		Pages	525-531
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Five new layered cuprates, with a 1222-type structure, have been synthesized according to the formula (Hg(1-x)M(x))(Sr,Ba)(2) Pr2Cu2O9-delta with M = Pr, Pb, Pi, and Tl. They crystallize in a tetragonal cell with a approximate to a(p) and c approximate to 29.5 Angstrom; their structure consists in a triple intergrowth of oxygen-deficient perovskite, rock-salt-and fluorite-type layers. They are characterized by a mixed [Hg(1-x)M(x)O(1-delta)] layer in the rock-sail-type slice. The ED and HREM studies show that Tl, Bi, and Pb are statistically distributed in the mixed [Hg(1-x)M(x)O(1-delta)] layer, contrary to Pr which involves an ordering phenomenon along a. Different stacking defects are observed and discussed as well as the cleavage mode of the crystals. (C) 1995 Academic Press, Inc.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1995QN27700033	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.133	Times cited	5	Open Access
Notes				Approved	MATERIALS SCIENCE, MULTIDISCIPLINARY 135/271 Q2 # PHYSICS, APPLIED 70/145 Q2 # PHYSICS, CONDENSED MATTER 40/67 Q3 #
Call Number	UA @ lucian @ c:irua:13311			Serial	3412
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Author	Hunter, E.C.; Battle, P.D.; Sena, R.P.; Hadermann, J.
Title	Ferrimagnetism as a consequence of cation ordering in the perovskite LaSr2Cr2SbO9			Type	A1 Journal article
Year	2017	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	248	Issue		Pages	96-103
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	A polycrystalline sample of LaSr2Cr2SbO9 has been synthesised using a standard ceramic method and characterized by x-ray and neutron diffraction, magnetometry and electron microscopy. The perovskite-related compound crystallises in the triclinic space group I1 with unit cell parameters of a=5.5344(6) angstrom, b=5.5562(5) angstrom, c=7.8292(7) angstrom, a=89.986(12)degrees, beta=90.350(5)degrees and gamma=89.926(9)degrees at room temperature. The two crystallographically-distinct, six-coordinate cation sites are occupied by Cr3+ and Sb5+ in ratios of 0.868(2):0.132(2) and 0.462(2):0.538(2). Ac and de magnetometry revealed that LaSr2Cr2SbO9 is ferrimagnetic below 150 K with a magnetisation of similar to 1.25 mu(B) per formula unit in 50 kOe at 5 K. Neutron diffraction showed that the cations on the two sites order in a G-type arrangement with a mean Cr3+ moment of 2.17(1) mu(B) at 5 K, consistent with a magnetisation of 1.32 mu(B) per formula unit.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000396386300012	Publication Date	2017-01-31
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	14	Open Access	Not_Open_Access
Notes	; Experiments at the ISIS Pulsed Neutron and Muon Source were supported by the STFC. We are grateful to I. da Silva for the assistance provided at ISIS and to the EPSRC for financial support under Grant EP/M018954/1. We also thank Diamond Light Source Ltd (EE13284) for the award of beamtime. ;			Approved	Most recent IF: 2.299
Call Number	UA @ lucian @ c:irua:142413			Serial	4657
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Author	Huve, M.; Martin, C.; Maignan, A.; Michel, C.; Van Tendeloo, G.; Hervieu, M.; Raveau, B.
Title	A new cuprate with mercury bilayers : the “2222” oxide Hg_2-xM_xBa₂Pr₂Cu₂O_10-\delta (M= Cu,Pr)			Type	A1 Journal article
Year	1995	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	114	Issue	1	Pages	230-235
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	A ''2222'' cuprate with mercury bilayers (Hg1.5Cu0.2Pr0.3)Ba2Pr2Cu2O10-delta, has been synthesized for the first time. It crystallizes in the P4/nmm space group with a = 3.9072(1) Angstrom and c = 17.219(1) Angstrom. The powder XRD and HREM studies of this new cuprate show that its structure consists of an intergrowth of double pyramidal (oxygen-deficient perovskite) copper layers, with double fluorite-type layers and distorted triple rock salt layers (mercury bilayers). The structure of this phase can be deduced from that of the ''2212'' mercury cuprate (Hg1.5Cu0.2Pr0.3)Ba2PrCu2O8-delta by the introduction of one additional [PrO2]infinity fluorite layer. The regular stacking of the metallic layer and the uniform cationic distribution in the mercury bilayers are remarkable features of this cuprate. The stabilization of the mercury bilayers by praseodymium and the absence of superconductivity are discussed. (C) 1995 Academic Press, Inc.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1995QA17000033	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.133	Times cited	6	Open Access
Notes				Approved	PHYSICS, APPLIED 28/145 Q1 #
Call Number	UA @ lucian @ c:irua:104448			Serial	2310
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Author	Huvé, M.; Renard, C.; Abraham, F.; Van Tendeloo, G.; Amelinckx, S.
Title	Electron microscopy of a family of hexagonal perovskites: one-dimensional structures related to Sr4Ni3O9			Type	A1 Journal article
Year	1998	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	135	Issue		Pages	1-16
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000072523100001	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	30	Open Access
Notes				Approved	Most recent IF: 2.299; 1998 IF: 1.432
Call Number	UA @ lucian @ c:irua:25656			Serial	958
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Author	Huvé, M.; Van Tendeloo, G.; Amelinckx, S.; Hervieu, M.; Raveau, B.
Title	Structural aspects of modulated superconducting oxides: application to Hg_1-xTl_xSr_4-yBa_yCu₂CO₃O_7-\delta			Type	A1 Journal article
Year	1995	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	120	Issue		Pages	332-342
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1995TN20700018	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.133	Times cited	2	Open Access
Notes				Approved
Call Number	UA @ lucian @ c:irua:13327			Serial	3209
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Author	Istomin, S.Y.; Morozov, A.V.; Abdullayev, M.M.; Batuk, M.; Hadermann, J.; Kazakov, S.M.; Sobolev, A.V.; Presniakov, I.A.; Antipov, E.V.
Title	High-temperature properties of (La,Ca)(Fe,Mg,Mo)O_3-\delta perovskites as prospective electrode materials for symmetrical SOFC			Type	A1 Journal article
Year	2018	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	258	Issue	258	Pages	1-10
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	La1-yCayFe0.5+x(Mg,Mo)(0.5-x)O3-delta oxides with the orthorhombic GdFeO3-type perovskite structure have been synthesized at 1573 K. Transmission electron microscopy study for selected samples shows the coexistence of domains of perovskite phases with ordered and disordered B-cations. Mossbauer spectroscopy studies performed at 300 K and 573 K show that while compositions with low Ca-content (La0.55Ca0.45Fe0.5Mg0.2625Mo0.2375O3-delta and La0.5Ca0.5Fe0.6Mg0.175Mo0.225O3-delta) are nearly oxygen stoichiometric, La0.2Ca0.8Fe0.5Mg0.2625Mo0.2375O3-delta is oxygen deficient with delta approximate to 0.15. Oxides are stable in reducing atmosphere (Ar/H-2, 8%) at 1173 K for 12 h. No additional phases have been observed at XRPD patterns of all studied perovskites and Ce1-xGdxO2-x/2 electrolyte mixtures treated at 1173-1373K, while Fe-rich compositions (x >= 0.1) react with Zr1-xYxO2-x/2 electrolyte above 1273 K. Dilatometry studies reveal that all samples show rather low thermal expansion coefficients (TECs) in air of 11.4-12.7 ppm K-1. In reducing atmosphere their TECs were found to increase up to 12.1-15.4 ppm K-1 due to chemical expansion effect. High-temperature electrical conductivity measurements in air and Ar/H-2 atmosphere show that the highest conductivity is observed for Fe- and Ca-rich compositions. Moderate values of electrical conductivity and TEC together with stability towards chemical interaction with typical SOFC electrolytes make novel Fe-containing perovskites promising electrode materials for symmetrical solid oxide fuel cell.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000423650400001	Publication Date	2017-10-11
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	5	Open Access	Not_Open_Access
Notes	; This work was financially supported by Russian Science Foundation (project number 16-13-10327). ;			Approved	Most recent IF: 2.299
Call Number	UA @ lucian @ c:irua:149283			Serial	4936
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Author	Kazin, P.E.; Abakumov, A.M.; Zaytsev, D.D.; Tretyakov, Y.D.; Khasanova, N.R.; Van Tendeloo, G.; Jansen, M.
Title	Synthesis and crystal structure of Sr₂ScBiO₆			Type	A1 Journal article
Year	2001	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	162	Issue	1	Pages	142-147
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000172586400019	Publication Date	2002-09-18
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	3	Open Access
Notes				Approved	Most recent IF: 2.299; 2001 IF: 1.614
Call Number	UA @ lucian @ c:irua:54710			Serial	3426
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Author	Khasanova, N.R.; Van Tendeloo, G.; Lebedev, O.I.; Amelinckx, S.; Grippa, A.Y.; Abakumov, A.M.; Istomin, S.Y.; D'yachenko, O.G.; Antipov, E.V.
Title	A new structure type of the ternary sulfide Eu_1.3Nb_1.9S₅			Type	A1 Journal article
Year	2002	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	164	Issue	2	Pages	345-353
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000174848000020	Publication Date	2002-10-06
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	2	Open Access
Notes				Approved	Most recent IF: 2.299; 2002 IF: 1.671
Call Number	UA @ lucian @ c:irua:54714			Serial	2334
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Author	Kirsanova, M.A.; De Sloovere, D.; Karakulina, O.M.; Hadermann, J.; Van Bael, M.K.; Hardy, A.; Abakumov, A.M.
Title	Toward unlocking the Mn³⁺/Mn²⁺ redox pair in alluaudite-type Na_2+2zMn_2-z(SO₄)_3-x(SeO₄)_x cathodes for sodium-ion batteries			Type	A1 Journal article
Year	2019	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	277	Issue	277	Pages	804-810
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	In polyanion cathodes, the inductive effect alters the potential of a M(n+1)+/Mn+ redox couple (M – transition metal) according to the electronegativity of the X cation in the polyanion groups (XO4m+). To manipulate the operating potential, we synthesized a series of mixed sulfate-selenate alluaudites, with structure formulas Na2+2zMn2-z(SO4)(3-x)(SeO4)(x) and Na2.81Ni1.60(SO4)(1.43)(SeO4)(1.57). Their crystal structure was determined from powder X-ray diffraction data, revealing that the Mn-based alluaudites form solid solutions with the same crystal structure for x = 0.75; 1.125 and 1.5. Na2.81Ni1.60(SO4)(1.43)(SeO4)(1.57) is isostructural to the Mn-based alluaudites. Although the Na2+2zMn2-z(SO4)(3-x)(SeO4)(x) compound with the highest selenium content demonstrates a reversible discharge capacity of 60 mAh g(-1), only a small part of this electrochemical activity can be ascribed to the Mn3+/Mn2+ redox couple. The redox potential of the Mn3+/Mn2+ pair in Na2+2zMn2-z(SO4)(3-)x(SeO4)(x) decreases with increasing values of x, in agreement with the lower electronegativity of Se compared to that of S.
Address
Corporate Author				Thesis
Publisher		Place of Publication		Editor
Language		Wos	000481726300103	Publication Date	2019-07-24
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596	ISBN		Additional Links	UA library record; WoS full record
Impact Factor	2.299	Times cited		Open Access
Notes	; The authors thank the Russian Foundation for Basic Research for financial support (grant 17-03-00370), in addition to Research Foundation-Flanders (project No G040116). ;			Approved	Most recent IF: 2.299
Call Number	UA @ admin @ c:irua:162852			Serial	5401
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Author	Kopnin, E.M.; Belik, A.A.; Shpanchenko, R.V.; Antipov, E.V.; Izumi, F.; Takayama-Muromachi, E.; Hadermann, J.
Title	Synthesis, crystal structure, and magnetic properties of new layered hexagonal perovskite Ba₈Ta₄Ru_8/3Co_2/3O₂₄			Type	A1 Journal article
Year	2004	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	177	Issue		Pages	3499-3504
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000224465500035	Publication Date	2004-08-13
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	1	Open Access
Notes	reprint; IUAP V-1			Approved	Most recent IF: 2.299; 2004 IF: 1.815
Call Number	UA @ lucian @ c:irua:49462			Serial	3448
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Author	Korneychik, O.E.; Batuk, M.; Abakumov, A.M.; Hadermann, J.; Rozova, M.G.; Sheptyakov, D.V.; Pokholok, K.V.; Filimonov, D.S.; Antipov, E.V.
Title	Pb_2.85Ba_2.15Fe₄SnO₁₃ : a new member of the A_nB_nO_3n-2 anion-deficient perovskite-based homologous series			Type	A1 Journal article
Year	2011	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	184	Issue	12	Pages	3150-3157
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Pb2.85Ba2.15Fe4SnO13, a new n=5 member of the anion-deficient perovskite based AnBnO3n−2 (A=Pb, Ba, B=Fe, Sn) homologous series, was synthesized by the solid state method. The crystal structure of Pb2.85Ba2.15Fe4SnO13 was investigated using a combination of neutron powder diffraction, electron diffraction, high angle annular dark field scanning transmission electron microscopy and Mössbauer spectroscopy. It crystallizes in the Ammm space group with unit cell parameters a=5.7990(1) Å, b=4.04293(7) Å and c=26.9561(5) Å. The Pb2.85Ba2.15Fe4SnO13 structure consists of quasi two-dimensional perovskite blocks separated by 1/2[110](1̄01)p crystallographic shear (CS) planes. The corner-sharing FeO6 octahedra at the CS planes are transformed into edge-sharing FeO5 distorted tetragonal pyramids. The octahedral positions in the perovskite blocks between the CS planes are jointly taken up by Fe and Sn, with a preference of Sn towards the position at the center of the perovskite block. The chains of FeO5 pyramids and (Fe,Sn)O6 octahedra of the perovskite blocks delimit six-sided tunnels at the CS planes occupied by double chains of Pb atoms. The compound is antiferromagnetically ordered below TN=368±15 K.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000297662500003	Publication Date	2011-09-30
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	7	Open Access
Notes				Approved	Most recent IF: 2.299; 2011 IF: 2.159
Call Number	UA @ lucian @ c:irua:94013			Serial	3550
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Author	Krekels, T.; Milat, O.; Van Tendeloo, G.; Amelinckx, S.; Babu, T.G.N.; Wright, A.J.; Greaves, C.
Title	Order and disorder in (Nd,Ce)_nO_2nSr₂GaCu₂O₅ and YSr₂CoCu₂O₇			Type	A1 Journal article
Year	1993	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	105	Issue	2	Pages	313-335
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	A1993LT32700002	Publication Date	2002-10-07
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.133	Times cited	50	Open Access
Notes				Approved	no
Call Number	UA @ lucian @ c:irua:102965			Serial	2499
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Author	Lebedev, O.I.; Caignaert, V.; Raveau, B.; Pop, N.; Gozzo, F.; Van Tendeloo, G.; Pralong, V.
Title	HRTEM and neutron diffraction study of Li_xMo₅O₁₇ : from the ribbon (x=5) structure to the rock salt (x=12) structure			Type	A1 Journal article
Year	2011	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	184	Issue	4	Pages	790-796
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Structure determination of the fully intercalated phase Li12Mo5O17 and of the deintercalated oxide Li5Mo5O17 has been carried out by electron microscopy and neutron powder diffraction. The reversible topotactic transformation between the ordered rock salt structure of the former and the ribbon structure of the latter (closely related to that of Li4Mo5O17) is explained on the following basis: both structures can be described as strips built up as an assembly of infinite ribbons of MoO6 octahedra that are five octahedra thick, and that differ by slight displacements of the octahedral ribbons. We show that the electrochemical behavior of the LixMo5O17 system is based on two sorts of Li+ sites; those that are located within the strips between the ribbons, and those that are located at the border of the strips. The high rate of Li intercalation in this oxide and its reversibility are discussed in terms of its peculiar structure.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000289597100010	Publication Date	2011-02-12
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	1	Open Access
Notes	Esteem 026019			Approved	Most recent IF: 2.299; 2011 IF: 2.159
Call Number	UA @ lucian @ c:irua:88646			Serial	1515
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Author	Lepoittevin, C.; Malo, S.; Barrier, N.; Nguyen, N.; Van Tendeloo, G.; Hervieu, M.
Title	Long-range ordering in the Bi_1-xAe_xFeO_3-x/2 perovskites: Bi_1/3Sr_2/3FeO_2.67 and Bi_1/2Ca_1/2FeO_2.75			Type	A1 Journal article
Year	2008	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	181	Issue	10	Pages	2601-2609
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract	Two-ordered perovskites, Bi1/3Sr2/3FeO2.67 and Bi1/2Ca1/2FeO2.75, have been stabilized and characterized by transmission electron microscopy, Mössbauer spectroscopy and X-ray powder diffraction techniques. They both exhibit orthorhombic superstructures, one with a≈b≈2ap and c≈3ap (S.G.: Pb2n or Pbmn) for the Sr-based compound and one with a≈b≈2ap and c≈8ap (S.G.: B222, Bmm2, B2mm or Bmmm) for the Ca-based one. The high-resolution transmission electron microscopy (HRTEM) images evidence the existence of one deficient [FeOx]∞ layer, suggesting that Bi1/3Sr2/3FeO2.67 and Bi1/2Ca1/2FeO2.75 behave differently compared to their Ln-based homolog. The HAADF-STEM images allow to propose a model of cation ordering on the A sites of the perovskite. The Mössbauer analyses confirm the trivalent state of iron and its complex environment with three types of coordination. Both compounds exhibit a high value of resistivity and the inverse molar susceptibility versus temperature curves evidence a magnetic transition at about 730 K for the Bi1/3Sr2/3FeO2.67 and a smooth reversible transition between 590 and 650 K for Bi1/2Ca1/2FeO2.75.
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000260441000008	Publication Date	2008-06-08
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	27	Open Access
Notes	Esteem 026019			Approved	Most recent IF: 2.299; 2008 IF: 1.910
Call Number	UA @ lucian @ c:irua:75663			Serial	1839
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Author	Liu, Y.; Norén, L.; Withers, R.L.; Hadermann, J.; Van Tendeloo, G.; Garcia-Garcia, J.
Title	The metastable Ni_{7\pm x}S₆ and mixed Ni_{6\pm x}(S_1-ySe_y)₅ phases			Type	A1 Journal article
Year	2003	Publication	Journal of solid state chemistry	Abbreviated Journal	J Solid State Chem
Volume	170	Issue		Pages	351-360
Keywords	A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author				Thesis
Publisher		Place of Publication	London	Editor
Language		Wos	000181875200019	Publication Date	2003-06-02
Series Editor		Series Title		Abbreviated Series Title
Series Volume		Series Issue		Edition
ISSN	0022-4596;	ISBN		Additional Links	UA library record; WoS full record; WoS citing articles
Impact Factor	2.299	Times cited	5	Open Access
Notes				Approved	Most recent IF: 2.299; 2003 IF: 1.413
Call Number	UA @ lucian @ c:irua:42054			Serial	2015
Permanent link to this record