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Author Tsuji, K.; Spolnik, Z.; Wagatsuma, K.; Van Grieken, R.E.; Vis, R.D. doi  openurl
  Title Grazing-exit particle-induced X-ray emission analysis with extremely low background Type A1 Journal article
  Year 1999 Publication Analytical chemistry Abbreviated Journal  
  Volume 71 Issue 22 Pages 5033-5036  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000083647100004 Publication Date 2002-07-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:27588 Serial 8010  
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Author Ro, C.-U.; Oh, K.-Y.; Osán, J.; de Hoog, J.; Worobiec, A.; Van Grieken, R. doi  openurl
  Title Heterogeneity assessment in individual CaCO3-CaSO4 particles using ultrathin window electron probe X-ray microanalysis Type A1 Journal article
  Year 2001 Publication Analytical chemistry Abbreviated Journal  
  Volume 73 Issue 19 Pages 4574-4583  
  Keywords A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000171356800012 Publication Date 2002-07-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:36085 Serial 8028  
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Author Marguí, E.; Fontàs, C.; van Meel, K.; Van Grieken, R.; Queralt, I.; Hidalgo, M. doi  openurl
  Title High-energy polarized-beam energy-dispersive X-ray fluorescence analysis combined with activated thin layers for cadmium determination at trace levels in complex environmental liquid samples Type A1 Journal article
  Year 2008 Publication Analytical chemistry Abbreviated Journal  
  Volume 80 Issue 7 Pages 2357-2364  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000254593500015 Publication Date 2008-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:68425 Serial 8032  
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Author Bruynseels, F.J.; Van Grieken, R.E. doi  openurl
  Title Laser microprobe mass spectrometric identification of sulfur species in single micrometer-size particles Type A1 Journal article
  Year 1984 Publication Analytical chemistry Abbreviated Journal  
  Volume 56 Issue 6 Pages 871-873  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1984SP09600012 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:116521 Serial 8163  
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Author Denoyer, E.; Van Grieken, R.; Adams, F.; Ntausch, D.F.S. doi  openurl
  Title Laser microprobe mass spectrometry : 1 : basic principles and performance characteristics Type A1 Journal article
  Year 1982 Publication Analytical chemistry Abbreviated Journal  
  Volume 54 Issue 1 Pages 26a-33a  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2012-05-29  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:116517 Serial 8164  
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Author Marguí, E.; van Meel, K.; Van Grieken, R.; Buendía, A.; Fontás, C.; Hidalgo, M.; Queralt, I. doi  openurl
  Title Method for the determination of Pd-catalyst residues in active pharmaceutical ingredients by means of high-energy polarized-beam energy dispersive X-ray fluorescence Type A1 Journal article
  Year 2009 Publication Analytical chemistry Abbreviated Journal  
  Volume 81 Issue 4 Pages 1404-1410  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract In medicinal chemistry, Pd is perhaps the most-widely utilized precious metal, as catalyst in reactions which represent key transformations toward the synthesis of new active pharmaceutical ingredients (APIs). The disadvantage of this metal-catalyzed chemistry is that expensive and toxic metal residues are invariably left bound to the desired product. Thus, stringent regulatory guidelines exist for the amount of residual Pd that a drug candidate is allowed to contain. In this work, a rapid and simple method for the determination of Pd in API samples by high-energy polarized-beam energy dispersive X-ray fluorescence spectrometry has been developed and validated according to the specification limits of current legislation (10 mg kg−1 Pd) and the International Conference on Harmonisation of Technical Requirements for Registration of Pharmaceuticals for Human Use (ICH guidelines). Sample and calibration standards preparation includes a first step of homogenization and then, in a second step, the pressing of the powdered material into pellets without any chemical treatment. The use of several synthetic calibration standards made of cellulose to simulate the API matrix appears to be an effective means to obtain reliable calibration curves with a good spread of data points over the working range. With the use of the best measuring conditions, the limit of detection (0.11 mg kg−1 Pd) as well as the limit of quantitation (0.37 mg kg−1 Pd) achieved meet rigorous requirements. The repeatability of the XRF measurement appeared to be less than 2%, while the precision of the whole method was around 7%. Trueness was evaluated by analyzing spiked API samples at the level of the specification limit and calculating the recovery factor, which was better than 95%. To study the applicability of the developed methodology for the intended purpose, three batches of the studied API were analyzed for their Pd content, and the attained results were comparable to those obtained by the daily routine method (acid digestion plus atomic spectroscopy) used in most pharmaceutical laboratories.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000263319000015 Publication Date 2009-01-22  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:74340 Serial 8220  
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Author Ro, C.-U.; Osán, J.; Szalóki, I.; de Hoog, J.; Worobiec, A.; Van Grieken, R. doi  openurl
  Title A Monte Carlo program for quantitative electron-induced x-ray analysis of individual particles Type A1 Journal article
  Year 2003 Publication Analytical chemistry Abbreviated Journal  
  Volume 75 Issue 4 Pages 851-859  
  Keywords A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000181073800021 Publication Date 2003-02-14  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:40613 Serial 8279  
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Author de Gendt, S.; Van Grieken, R.E.; Ohorodnik, S.K.; Harrison, W.W. doi  openurl
  Title Parameter evaluation for the analysis of oxide-based samples with radio ferquency glow discharge mass spectrometry Type A1 Journal article
  Year 1995 Publication Analytical chemistry Abbreviated Journal  
  Volume 67 Issue Pages 1026-1033  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1995QM00100002 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:12342 Serial 8356  
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Author Choël, M.; Deboudt, K.; Osán, J.; Flament, P.; Van Grieken, R. doi  openurl
  Title Quantitative determination of low-Z elements in single atmospheric particles on boron substrates by automated scanning electron microscopy: energy-dispersive X-ray spectrometry Type A1 Journal article
  Year 2005 Publication Analytical chemistry Abbreviated Journal  
  Volume 77 Issue 17 Pages 5686-5692  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000231652300046 Publication Date 2005-08-31  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:53593 Serial 8443  
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Author Robberecht, H.J.; Van Grieken, R.E. doi  openurl
  Title Sub-part-per-billion determination of total dissolved selenium and selenite in environmental waters by X-ray fluorescence spectrometry Type A1 Journal article
  Year 1980 Publication Analytical chemistry Abbreviated Journal  
  Volume 52 Issue 3 Pages 449-453  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1980JG67900021 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:116514 Serial 8613  
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Author Vincze, L.; Vekemans, B.; Brenker, F.E.; Falkenberg, G.; Rickers, K.; Somogyi, A.; Kersten, M.; Adams, F. doi  openurl
  Title Three-dimensional trace element analysis by confocal X-ray microfluorescence imaging Type A1 Journal article
  Year 2004 Publication Analytical chemistry Abbreviated Journal  
  Volume 76 Issue 22 Pages 6786-6791  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000225076400034 Publication Date 2004-11-12  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:49817 Serial 8669  
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Author Szalóki, I.; Osán, J.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 2006 Publication Analytical chemistry Abbreviated Journal  
  Volume 78 Issue 12 Pages 4069-4096  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000238252600016 Publication Date 2006-06-10  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:58857 Serial 8771  
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Author Szalóki, I.; Osán, J.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 2004 Publication Analytical chemistry Abbreviated Journal  
  Volume 76 Issue 12 Pages 3445-3470  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000222011100014 Publication Date 2004-06-14  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:46259 Serial 8772  
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Author Szalóki, I.; Török, S.B.; Injuk, J.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 2002 Publication Analytical chemistry Abbreviated Journal  
  Volume 74 Issue 12 Pages 2895-2918  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000176253700020 Publication Date 2002-07-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:39517 Serial 8773  
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Author Szalóki, I.; Török, S.B.; Ro, C.-U.; Injuk, J.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 2000 Publication Analytical chemistry Abbreviated Journal  
  Volume 72 Issue 12 Pages 211-233  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000087661500018 Publication Date 2002-07-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:27850 Serial 8774  
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Author Török, S.; Labar, J.; Schmeling, M.; Van Grieken, R. openurl 
  Title X-ray spectrometry Type A1 Journal article
  Year 1998 Publication Analytical chemistry Abbreviated Journal  
  Volume 70 Issue Pages 495r-517r  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000074161100020 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:20967 Serial 8776  
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Author Török, S.B.; Labar, J.; Injuk, J.; Van Grieken, R.E. openurl 
  Title X-ray spectrometry Type A1 Journal article
  Year 1996 Publication Analytical chemistry Abbreviated Journal  
  Volume R68 Issue Pages 467-485  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:14650 Serial 8777  
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Author Török, S.B.; Van Grieken, R.E. openurl 
  Title X-ray spectrometry Type A1 Journal article
  Year 1992 Publication Analytical chemistry Abbreviated Journal  
  Volume 64r Issue Pages 180-196  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1992HZ51800011 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:2823 Serial 8778  
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Author Markowicz, A.A.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 1990 Publication Analytical chemistry Abbreviated Journal  
  Volume 62 Issue 12 Pages 101r-113r  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2006-11-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:116527 Serial 8779  
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Author Markowicz, A.A.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 1988 Publication Analytical chemistry Abbreviated Journal  
  Volume 60 Issue 12 Pages 28r-42r  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:116525 Serial 8780  
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Author Markowicz, A.A.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 1986 Publication Analytical chemistry Abbreviated Journal  
  Volume 58 Issue 5 Pages 279r-294r  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:116523 Serial 8781  
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Author Ma, X.; Pavlidis, G.; Dillon, E.; Beltran, V.; Schwartz, J.J.; Thoury, M.; Borondics, F.; Sandt, C.; Kjoller, K.; Berrie, B.H.; Centrone, A. pdf  url
doi  openurl
  Title Micro to nano : multiscale IR analyses reveal zinc soap heterogeneity in a 19th-century painting by Corot Type A1 Journal article
  Year 2022 Publication Analytical chemistry Abbreviated Journal  
  Volume 94 Issue 7 Pages 3103-3110  
  Keywords A1 Journal article; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab)  
  Abstract Formation and aggregation of metal carboxylates (metal soaps) can degrade the appearance and integrity of oil paints, challenging efforts to conserve painted works of art. Endeavors to understand the root cause of metal soap formation have been hampered by the limited spatial resolution of Fourier transform infrared microscopy (mu-FTIR). We overcome this limitation using optical photothermal infrared spectroscopy (O-PTIR) and photothermal-induced resonance (PTIR), two novel methods that provide IR spectra with approximate to 500 and approximate to 10 nm spatial resolutions, respectively. The distribution of chemical phases in thin sections from the top layer of a 19th-century painting is investigated at multiple scales (mu-FTIR approximate to 10(2) mu m(3), O-PTIR approximate to 10(-1) mu m(3), PTIR approximate to 10(-5) mu m(3)). The paint samples analyzed here are found to be mixtures of pigments (cobalt green, lead white), cured oil, and a rich array of intermixed, small (often << 0.1 mu m(3)) zinc soap domains. We identify Zn stearate and Zn oleate crystalline soaps with characteristic narrow IR peaks (approximate to 1530-1558 cm(-1)) and a heterogeneous, disordered, water-permeable, tetrahedral zinc soap phase, with a characteristic broad peak centered at approximate to 1596 cm(-1). We show that the high signal-to-noise ratio and spatial resolution afforded by O-PTIR are ideal for identifying phase-separated (or locally concentrated) species with low average concentration, while PTIR provides an unprecedented nanoscale view of distributions and associations of species in paint. This newly accessible nanocompositional information will advance our knowledge of chemical processes in oil paint and will stimulate new art conservation practices.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000766206700011 Publication Date 2022-02-09  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access OpenAccess  
  Notes Approved (up) no  
  Call Number UA @ admin @ c:irua:187380 Serial 8897  
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