Records |
Author |
Biksham, G.; Subramanian, V.; Ramanathan, A.; Van Grieken, R. |
Title |
Heavy metal distribution in the Godavari river basin |
Type |
A1 Journal article |
Year |
1991 |
Publication |
Environmental geology and water sciences |
Abbreviated Journal |
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Volume |
17 |
Issue |
|
Pages |
117-126 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Series Editor |
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Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0177-5146 |
ISBN |
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UA library record |
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no |
Call Number |
UA @ admin @ c:irua:55571 |
Serial |
8023 |
Permanent link to this record |
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Author |
Subramanian, V.; Van Grieken, R.; Van 't dack, L. |
Title |
Heavy metals distribution in the sediments of Ganges and Brahmaputra rivers |
Type |
A1 Journal article |
Year |
1987 |
Publication |
Environmental geology |
Abbreviated Journal |
|
Volume |
9 |
Issue |
2 |
Pages |
93-103 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Bed sediments were collected from the entire region of the Ganges basin and some parts of the Brahmaputra. In addition, selected stations were sampled for suspended sediments as well. The samples were analysed for a number of heavy metals (Fe, Mn, Ni, Cr, Cu, and Zn) by the thin-film energy dispersive X-ray fluorescence technique. There are pronounced temporal and spatial variations in the heavy metals distributions. Suspended sediments are 510 times richer than the bed sediments. None of the tributaries contribute significant heavy metal load, but around urban areas in Yamuna (tributary of Ganges), very high levels due to the distribution from the drainage network are observed. Compared to the Brahmaputra, the distribution and fractionation of heavy metals in the Ganges sediments are more erratic and highly variable. All the metals considered show high correlation among themselves. Given the high flux of suspended sediments from the Himalayan rivers (nearly 20% of the global flux), the worldwide budget for heavy metal transport may need to be suitably revised. |
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Wos |
A1987F245600004 |
Publication Date |
2006-07-30 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0943-0105 |
ISBN |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:111507 |
Serial |
8024 |
Permanent link to this record |
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Author |
Facetti, J.; Dekov, V.M.; Van Grieken, R. |
Title |
Heavy metals in sediments from the Paraguay river: a preliminary study |
Type |
A1 Journal article |
Year |
1998 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
209 |
Issue |
|
Pages |
79-86 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Wos |
000072368900008 |
Publication Date |
2002-07-26 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:20961 |
Serial |
8025 |
Permanent link to this record |
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Author |
Jha, P.K.; Subramanian, V.; Sitasawad, R.; Van Grieken, R. |
Title |
Heavy metals in sediments of the Yamura River (a tributary of the Ganges), India |
Type |
A1 Journal article |
Year |
1990 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
95 |
Issue |
|
Pages |
7-27 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Yamuna River sediments are more enriched in metals than those of the Ganges and average Indian river sediments. Variation of metals in suspended, bed and core sediment are due to the varying proportions of grain size and mineral content. Iron, Mn and Pb show a preference for the oxide fraction, whereas Cu and Zn are predominant in organic and carbonate fractions of sediments. Of the total elemental content, 80% Mn, 78% Fe, 69% Pb, 67% Cu and 55% Zn are available in chemically mobile phases of the sediments. The high partition coefficient of metals with respect to Mn suggests similar chemical mobility and preferences for solid phases. River sediments in the vicinity of Delhi show an increase in sorption of metals downstream, consequently metals are retained in sediments. The high correlation coefficient and significant regression relation among the metals indicate their similar behaviour during transport. At Allahabad, the contribution of the Yamuna to the Ganges is 3200 t Pb year−1, 12 100 t Zn year−1 and 8500 t Cu year−1 in particulate form. |
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Wos |
A1990DP94300002 |
Publication Date |
2003-09-12 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
ISBN |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116655 |
Serial |
8026 |
Permanent link to this record |
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Author |
Subramanian, V.; Jha, P.K.; Van Grieken, R. |
Title |
Heavy metals in the Ganges estuary |
Type |
A1 Journal article |
Year |
1988 |
Publication |
Marine pollution bulletin |
Abbreviated Journal |
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Volume |
19 |
Issue |
2 |
Pages |
290-293 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Wos |
A1988P559400010 |
Publication Date |
2003-08-07 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0025-326x; 1879-3363 |
ISBN |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116803 |
Serial |
8027 |
Permanent link to this record |
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Author |
Ro, C.-U.; Oh, K.-Y.; Osán, J.; de Hoog, J.; Worobiec, A.; Van Grieken, R. |
Title |
Heterogeneity assessment in individual CaCO3-CaSO4 particles using ultrathin window electron probe X-ray microanalysis |
Type |
A1 Journal article |
Year |
2001 |
Publication |
Analytical chemistry |
Abbreviated Journal |
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Volume |
73 |
Issue |
19 |
Pages |
4574-4583 |
Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Wos |
000171356800012 |
Publication Date |
2002-07-26 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0003-2700; 5206-882x |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:36085 |
Serial |
8028 |
Permanent link to this record |
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Author |
Török, S.; Van Dyck, P.; Van Grieken, R. |
Title |
Heterogeneity effects in direct X-ray fluorescence analysis of hair |
Type |
A1 Journal article |
Year |
1984 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
Volume |
13 |
Issue |
1 |
Pages |
27-32 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The methodology of direct hair analysis by energy-dispersive x-ray fluorescence was studied. The effect on the XRF result of having a non-homogeneous radial distribution of the analyte in a single hair strand and the macroscopic effects in a bundle of hairs were calculated to evaluate possible systematic errors. The detection limits were mapped as a function of the target thickness and surface fraction. It appeared that a 10 mg cm−2 sample thickness, i. e. a target with about four layers of hair strands, is recommended. The standard deviation of this simple direct analytical method is 619% for some important elements. Discrepancies with neutron activation analysis had a mean value of around 15%. About twelve elements can be determined simultaneously on a routine basis. |
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Wos |
A1984SB70200004 |
Publication Date |
2005-05-28 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:116485 |
Serial |
8029 |
Permanent link to this record |
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Author |
Török, S.; Braun, T.; Van Dyck, P.; Van Grieken, R. |
Title |
Heterogeneity effects in direct XRF analysis of traces of heavy metals preconcentrated on polyurethane foam sorbents |
Type |
A1 Journal article |
Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
1 |
Pages |
7-11 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Trace amounts of heavy metals were preconcentrated on discs of polyurethane (PU) foam loaded with ammonium diethyldithiocarbamate (DDTC), to increase the sensitivity of XRF. Since the diameter of the cavities in the open-cell PU foams reaches 30300 μm, considerable heterogeneity effects might occur, which could reduce the accuracy of the method. The possible systematic error introduced by considering the sample to be homogeneous is calculated using the Berry et al. model. The calculations show that the underestimation of the absorption correction factor when considering the sample as being homogeneous is less than 2% for high-Z elements when the sample thickness is at least 2 mm. The detection limits are also around the minima for this thickness. |
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Wos |
A1986AYN6000002 |
Publication Date |
2005-05-28 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:116488 |
Serial |
8030 |
Permanent link to this record |
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Author |
Marguí, E.; Padilla, R.; Hidalgo, M.; Queralt, I.; Van Grieken, R. |
Title |
High-energy polarized-beam EDXRF for trace metal analysis of vegetation samples in environmental studies |
Type |
A1 Journal article |
Year |
2006 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
35 |
Issue |
3 |
Pages |
169-177 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Address |
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Corporate Author |
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Wos |
000237818300005 |
Publication Date |
2006-03-23 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:57751 |
Serial |
8031 |
Permanent link to this record |
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Author |
Marguí, E.; Fontàs, C.; van Meel, K.; Van Grieken, R.; Queralt, I.; Hidalgo, M. |
Title |
High-energy polarized-beam energy-dispersive X-ray fluorescence analysis combined with activated thin layers for cadmium determination at trace levels in complex environmental liquid samples |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Analytical chemistry |
Abbreviated Journal |
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Volume |
80 |
Issue |
7 |
Pages |
2357-2364 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Place of Publication |
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Wos |
000254593500015 |
Publication Date |
2008-03-08 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0003-2700; 5206-882x |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:68425 |
Serial |
8032 |
Permanent link to this record |
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Author |
Jain, R.; Rather, J.A.; Dwivedi, A.; Vikas |
Title |
Highly sensitive and selective voltammetric sensor fullerene modified glassy carbon electrode for determination of cefitizoxime in solubilized system |
Type |
A1 Journal article |
Year |
2010 |
Publication |
Electroanalysis |
Abbreviated Journal |
|
Volume |
22 |
Issue |
21 |
Pages |
2600-2606 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The usefulness of fullerene modified glassy carbon electrode in mediating the reduction of cefitizoxime in solubilized system has been demonstrated. Due to the unique structure and extraordinary properties, fullerene shows higher catalytic efficiency towards cefitizoxime reduction. The kinetic parameters, electron transfer coefficient (α) and rate constant (K0) across the modified electrode are 0.37 and 0.1081/s respectively. The proposed square-wave voltammetric method is linear over the concentration range 1.210.3 µg/mL. The limit of detection (LOD) is found 0.27 ng/mL. High sensitivity and selectivity together with low detection limit of the electrode response make it suitable for the determination of cefitizoxime. |
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Wos |
000284052900015 |
Publication Date |
2010-10-04 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1040-0397 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:98690 |
Serial |
8042 |
Permanent link to this record |
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Author |
Vanmeert, F. |
Title |
Highly specific X-ray powder diffraction imaging at the macroscopic and microscopic scale |
Type |
Doctoral thesis |
Year |
2019 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
At or below the surface of painted works of art, valuable information is present that provides insights into an object’s past, such as the artist’s technique and the creative process that was followed or its conservation history, but also on its current state of preservation. Typically, a (very) limited set of small paint samples is taken which provide direct access to the individual paint layers. The chemical build-up of these layers can then be investigated in great detail using various microscopic analytical methods. However, in recent years a new trend towards both elemental and chemical imaging techniques has been set which are capable of visualizing the (often) heterogeneous composition of painted objects on a macroscopic scale. In this dissertation, various forms of specificity attainable with X‑ray powder diffraction (XRPD) imaging are explored: at the chemical, material and spatial level. This high specificity is illustrated throughout several applications stemming from the field of cultural heritage, both at the macroscopic (MA) and microscopic (µ) scale. As a first step, XRPD imaging was transformed to a transportable instrument that can be employed for the in situ investigation of artworks, e.g., inside museums and conservation workshops. With this unique instrument large‑scale maps (cm2 – dm2) reflecting the distribution of crystalline phases on/below the surface of flat painted artefacts can be visualized in a noninvasive manner. In this way compound-specific information was attained which can be related to original pigments or materials that have been added in a later stage and even degradation/secondary products that have formed spontaneously inside the paint layers. Additionally, with MA‑XRPD imaging it was possible to link quantitative information of pigment compositions and preferred orientation effects to the 2D compound‑specific distribution images, allowing for a further distinction between very similar artists’ materials. Furthermore, promising results for the limited depth-selectivity of this technique, obtained by exploiting the small shift in the position of the diffraction signals originating from the layered sequence of the pigments, are shown. Finally, a minute paint sample from Wheat stack under a cloudy sky by Van Gogh was investigated at a synchrotron radiation facility with tomographic µ‑XRPD imaging at the microscopic scale. The high chemical and spatial specificity of this imaging method was exploited to further elucidate the degradation pathway of the red lead pigment. |
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UA library record |
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no |
Call Number |
UA @ admin @ c:irua:159805 |
Serial |
8043 |
Permanent link to this record |
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Author |
Worobiec, A.; Zwozdziak, A.; Sówka, I.; Zwozdziak, J.; Stefaniak, E.A.; Buczyńska, A.; Krata, A.; van Meel, K.; Van Grieken, R.; Górka, M.; Jedrysek, M.-O. |
Title |
Historical changes in air pollution in the tri-border region of Poland, Czech Republic and Germany |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Environment protection engineering |
Abbreviated Journal |
|
Volume |
34 |
Issue |
4 |
Pages |
81-90 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
Abstract |
In this study, we show the trends in the concentration Of SO2 and particulate matter (PM) in two health resorts, located in the tri-border region of Poland, Germany and Czech Republic. We analyze the annual time series and the seasonal variability of PM concentration for the months of July and February over the period of 1996-2007. Additionally, in July 2006, we measured the mean 24-hour concentration of PM and the content of heavy metals (by EDXRF analysis). We prove that nowadays air pollution in this region has diminished to a large extent as compared to the 90s of the last century. In Cieplice, the local influence is still evident; while Czerniawa is exposed to a periodical advection of polluted air from regional sources. |
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Wos |
000262019500010 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0324-8828 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:72491 |
Serial |
8044 |
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Author |
Abreu, Y.; Cruz, C.M.; Pinera, I.; Leyva, A.; Cabal, A.E.; van Espen, P.; Van Remortel, N. |
Title |
Hyperfine electric parameters calculation in Si samples implanted with 57Mn\rightarrow57Fe |
Type |
A1 Journal article |
Year |
2014 |
Publication |
Physica: B : condensed matter |
Abbreviated Journal |
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Volume |
445 |
Issue |
|
Pages |
1-4 |
Keywords |
A1 Journal article; Particle Physics Group; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Nowadays the electronic structure calculations allow the study of complex systems determining the hyperfine parameters measured at a probe atom, including the presence of crystalline defects. The hyperfine electric parameters have been measured by Mossbauer spectroscopy in silicon materials implanted with Mn-57 ->,Fe-57 ions, observing four main contributions to the spectra. Nevertheless, some ambiguities still remain in the Fe-57 Mossbauer spectra interpretation in this case, regarding the damage configurations and its evolution with annealing. In the present work several implantation environments are evaluated and the Fe-57 hyperfine parameters are calculated. The observed correlation among the studied local environments and the experimental observations is presented, and a tentative microscopic description of the behavior and thermal evolution of the characteristic defects local environments of the probe atoms concerning the location of vacancies and interstitial Si in the neighborhood of Fe-57 ions in substitutional and interstitial sites is proposed. (C) 2014 Elsevier B.V. All rights reserved |
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Wos |
000336478700001 |
Publication Date |
2014-03-22 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0921-4526; 1873-2135 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:117697 |
Serial |
8046 |
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Author |
Abreu Alfonso, Y. |
Title |
Hyperfine parameters and radiation damage in semiconductors and superconducting materials |
Type |
Doctoral thesis |
Year |
2014 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
126 p. |
Keywords |
Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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no |
Call Number |
UA @ admin @ c:irua:116686 |
Serial |
8047 |
Permanent link to this record |
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|
|
Author |
Bondarenko, I.; Treiger, B.; Van Grieken, R.; van Espen, P. |
Title |
IDAS: a new Windows based software for multivariate analysis of atmospheric aerosol composition data bases |
Type |
H3 Book chapter |
Year |
1995 |
Publication |
|
Abbreviated Journal |
|
Volume |
|
Issue |
|
Pages |
308-315
T2 - Space and time in environmental infor |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
Abstract |
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Edition |
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ISSN |
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UA library record |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:12357 |
Serial |
8049 |
Permanent link to this record |
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|
|
Author |
Bondarenko, I.; Treiger, B.; Van Grieken, R.; van Espen, P. |
Title |
IDAS: a Windows based software package for cluster analysis |
Type |
A1 Journal article |
Year |
1996 |
Publication |
Spectrochimica acta: part B : atomic spectroscopy |
Abbreviated Journal |
|
Volume |
51 |
Issue |
|
Pages |
441-456 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Place of Publication |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
|
Edition |
|
ISSN |
0584-8547; 1873-3565 |
ISBN |
|
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UA library record |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:14649 |
Serial |
8050 |
Permanent link to this record |
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|
|
Author |
Salvadó, N.; Butí, S.; Pradell, T.; Beltran, V.; Cinque, G.; Juanhuix, J. |
Title |
Identification and distribution of metal soaps and oxalates in oil and tempera paint layers in fifteenth-century altarpieces using synchrotron radiation Techniques |
Type |
H1 Book chapter |
Year |
2019 |
Publication |
|
Abbreviated Journal |
|
Volume |
|
Issue |
|
Pages |
195-210
T2 - Metal soaps in art : conservation and |
Keywords |
H1 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The formation and distribution of metal soaps produced as a result of the reactivity and aging of the materials in a fifteenth-century egg tempera and oil paintings on wood are presented. The painting technique involves the application of several paint layers over a ground using, sometimes in the same paint layer sequence, drying oil and egg yolk binders. We show, with a selection of examples, how the use of thin sections and a combination of various micro-sensitive analytical techniques is adequate to obtain the high-quality data necessary for the unambiguous identification of metal soaps and metal oxalates as well as their distribution in the paint layers. The techniques include micro infrared spectroscopy (μSR-FTIR) and micro X-ray diffraction (μSR-XRD) with synchrotron radiation, optical microscopy (OM), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS). The data obtained sheds light about the underlying reaction and aging mechanisms happening in each paint layer and among them. This helps to define the state of conservation of the artworks. |
Address |
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Corporate Author |
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Thesis |
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Place of Publication |
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Wos |
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Publication Date |
2019-03-23 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
|
Edition |
|
ISSN |
|
ISBN |
978-3-319-90616-4; 2366-6226; 978-3-319-90617-1 |
Additional Links |
UA library record |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:172891 |
Serial |
8051 |
Permanent link to this record |
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|
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Author |
Akbulut, S.; Van Grieken, R.; Kilic, M.A.; Čevik, U.; Rotondo, G.G. |
Title |
Identification of heavy metal origins related to chemical and morphological soil properties using several non-destructive X-ray analytical methods |
Type |
A1 Journal article |
Year |
2013 |
Publication |
Environmental monitoring and assessment |
Abbreviated Journal |
|
Volume |
185 |
Issue |
3 |
Pages |
2377-2394 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Soils are complex mixtures of organic, inorganic materials, and metal compounds from anthropogenic sources. In order to identify the pollution sources, their magnitude and development, several X-ray analytical methods were applied in this study. The concentrations of 16 elements were determined in all the soil samples using energy dispersive X-ray fluorescence spectrometry. Soils of unknown origin were observed by scanning electron microscopy equipped with a Si(Li) X-ray detector using Monte Carlo simulation approach. The mineralogical analyses were carried out using X-ray diffraction spectrometry. Due to the correlations between heavy metals and oxide compounds, the samples were analyzed also by electron probe microanalyzer (EPMA) in order to have information about their oxide contents. On the other hand, soil pH and salinity levels were identified owing to their influence between heavy metal and soil-surface chemistry. Moreover, the geoaccumulation index (I geo) enables the assessment of contamination by comparing current and pre-industrial concentrations. |
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Wos |
000314033300029 |
Publication Date |
2012-06-21 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1420-2026; 1573-2967 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Open Access |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:106755 |
Serial |
8052 |
Permanent link to this record |
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|
Author |
van Malderen, H.; Hoornaert, S.; Van Grieken, R. |
Title |
Identification of individual aerosol particles containing Cr, Pb, and Zn above the North Sea |
Type |
A1 Journal article |
Year |
1996 |
Publication |
Environmental science and technology |
Abbreviated Journal |
|
Volume |
30 |
Issue |
|
Pages |
489-498 |
Keywords |
A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Aerosol samples have been collected over the southern bight of the North Sea from an aircraft. In this way, 96 samples were taken for single-particle analysis during 16 flights. Almost 45 000 individual particles were analyzed with electron probe X-ray microanalysis. More than 5000 of these were found to contain significant concentrations of one or more of the heavy metals Cr, Pb, and Zn. With the help of hierarchical, nonhierarchical, and fuzzy clustering techniques, various heavy metal-containing particle types could be identified. Significant differences in abundances were detected in the North Sea heavy metal aerosol, depending on the origin of the air masses. In samples with continental influence 50 times more Zn- and Pb-containing particles were found than in samples with a marine history. For Cr, on the other hand, we found abundances in the marine sector that were one-third of the values for continental sectors. This might point to a rather undefined marine source, which could be the recycling of previously deposited material by reinjection into the atmosphere by sea spray. The highest values for Cr-, Pb-, and Zn-containing particles were always detected under southeastern wind directions. |
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Wos |
A1996TT49600036 |
Publication Date |
2002-07-26 |
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Edition |
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ISSN |
0013-936x; 1520-5851 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:14639 |
Serial |
8053 |
Permanent link to this record |
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Author |
Verbueken, A.; Verpooten, G.; Nouwen, E.; de Broe, M.; Van Grieken, R. |
Title |
Identification of inorganic and organic microliths in kidney sections by laser microprobe mass analysis (LAMMA) |
Type |
P3 Proceeding |
Year |
1986 |
Publication |
|
Abbreviated Journal |
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Volume |
|
Issue |
|
Pages |
|
Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
Abstract |
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Wos |
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ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:117510 |
Serial |
8054 |
Permanent link to this record |
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|
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Author |
Verbueken, A.H.; Van Grieken, R.E.; de Broe, M.E.; Wedeen, R.P. |
Title |
Identification of inorganic and organic microliths in kidney sections by laser microprobe mass spectrometry |
Type |
A1 Journal article |
Year |
1987 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
Volume |
195 |
Issue |
|
Pages |
97-115 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
Abstract |
Laser microprobe mass spectrometry is used to identify intrarenal microliths; they appear to consist of either oxalate, urate or phosphate. Crystalline and amorphous deposits in rat and human kidney are pin-pointed by the laser beam and their chemical composition determined by mass spectrometry. The method has the potential for wide application in the identification of single organic, inorganic or combination crystals in histological sections. |
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Wos |
A1987K019500009 |
Publication Date |
2002-07-25 |
Series Editor |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
|
ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Open Access |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:116448 |
Serial |
8055 |
Permanent link to this record |
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|
Author |
de Nolf, W. |
Title |
Imaging of crystalline phase distributions by means of scanning and tomographic X-ray powder diffraction |
Type |
Doctoral thesis |
Year |
2013 |
Publication |
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Abbreviated Journal |
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Volume |
|
Issue |
|
Pages |
407 p. |
Keywords |
Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Wos |
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UA library record |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:110910 |
Serial |
8057 |
Permanent link to this record |
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|
|
Author |
Samek, L.; de Maeyer-Worobiec, A.; Spolnik, Z.; Bencs, L.; Kontozova, V.; Bratasz, Ł.; Kozłowski, R.; Van Grieken, R. |
Title |
The impact of electric overhead radiant heating on the indoor environment of historic churches |
Type |
A1 Journal article |
Year |
2007 |
Publication |
Journal of cultural heritage |
Abbreviated Journal |
|
Volume |
8 |
Issue |
4 |
Pages |
361-369 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
Abstract |
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Wos |
000252255500004 |
Publication Date |
2007-12-06 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
|
ISSN |
1296-2074 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
|
Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:65900 |
Serial |
8063 |
Permanent link to this record |
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|
|
Author |
Bottari, F.; Moretto, L.M.; Ugo, P. |
Title |
Impedimetric sensing of the immuno-enzymatic reaction of gliadin with a collagen-modified electrode |
Type |
A1 Journal article |
Year |
2018 |
Publication |
Electrochemistry communications |
Abbreviated Journal |
|
Volume |
97 |
Issue |
|
Pages |
51-55 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
This paper presents a previously unexplored biosensing strategy for detecting gliadin which exploits the crosslinking of gliadin with collagen, catalyzed by transglutaminase at the interfacial electron transfer rate, on a modified electrode. The process is monitored by electrochemical impedance spectroscopy using a glassy carbon electrode coated with a collagen layer. To validate the specificity of the response as well as to eliminate possible interferences from other proteins, such as soy protein or casein, the captured gliadin is further reacted with a specific anti-gliadin antibody. Changes in charge transfer resistance, measured from the Nyquist plots, scale linearly with the gliadin concentration in the range 5-20 mg/L, a range suitable for testing the gliadin concentration in gluten-free food commodities. |
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Place of Publication |
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Wos |
000451326800011 |
Publication Date |
2018-10-10 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
|
ISSN |
1388-2481; 1873-1902 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:156285 |
Serial |
8067 |
Permanent link to this record |
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|
|
Author |
Pinera, I.; Cruz, C.M.; Leyva, A.; Abreu, Y.; Cabal, A.E.; van Espen, P.; Van Remortel, N. |
Title |
Improved calculation of displacements per atom cross section in solids by gamma and electron irradiation |
Type |
A1 Journal article |
Year |
2014 |
Publication |
Interactions With Materials And Atoms |
Abbreviated Journal |
|
Volume |
339 |
Issue |
|
Pages |
1-7 |
Keywords |
A1 Journal article; Engineering sciences. Technology; Particle Physics Group; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Several authors had estimated the displacements per atom cross sections under different approximations and models, including most of the main gamma- and electron-material interaction processes. These previous works used numerical approximation formulas which are applicable for limited energy ranges. We proposed the Monte Carlo assisted Classical Method (MCCM), which relates the established theories about atom displacements to the electron and positron secondary fluence distributions calculated from the Monte Carlo simulation. In this study the MCCM procedure is adapted in order to estimate the displacements per atom cross sections for gamma and electron irradiation. The results obtained through this procedure are compared with previous theoretical calculations. An improvement in about 10-90% for the gamma irradiation induced dpa cross section is observed in our results on regard to the previous evaluations for the studied incident energies. On the other hand, the dpa cross section values produced by irradiation with electrons are improved by our calculations in about 5-50% when compared with the theoretical approximations. When thin samples are irradiated with electrons, more precise results are obtained through the MCCM (in about 20-70%) with respect to the previous studies. (C) 2014 Elsevier B.V. All rights reserved. |
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Thesis |
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Place of Publication |
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Wos |
000343785500001 |
Publication Date |
2014-09-15 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
|
ISSN |
0168-583x |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:121161 |
Serial |
8069 |
Permanent link to this record |
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|
|
Author |
Schalm, O.; Cabal, A.; van Espen, P.; Laquière, N.; Storme, P. |
Title |
Improved radiographic methods for the investigation of paintings using laboratory and synchrotron X-ray sources |
Type |
A1 Journal article |
Year |
2011 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
|
Volume |
26 |
Issue |
5 |
Pages |
1068-1077 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
It is generally known that radiographic inspection of 1517th century paintings can easily be done with a polychromatic X-ray source using a voltage between 20 kV and 40 kV in combination with classic X-ray films. Unfortunately, the spatial structure of numerous 19th and early 20th century paintings cannot be visualized with conventional radiography due to several reasons such as the use of lead white grounds or low absorbing pigments. Radiographic images are blurred or worse, they do not contain the picture of the painting. During the last decades, many technological innovations have been introduced in the field of radiography but their possibilities in cultural heritage have not been explored in full detail. In our investigation we used phosphor imaging plates, energy dispersive detectors and CCD-cameras in combination with synchrotron radiation and conventional X-ray tubes in order to improve the quality of radiographic images. Several promising techniques that could improve the quality of radiographs of paintings were identified. |
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Wos |
000289731900023 |
Publication Date |
2011-04-11 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
|
Edition |
|
ISSN |
0267-9477 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
|
Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:89928 |
Serial |
8070 |
Permanent link to this record |
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|
|
Author |
Shani, J.; Livshitz, T.; Robberecht, H.; Van Grieken, R.; Rubinstein, N.; Even-Paz, Z. |
Title |
Increased erythrocyte glutathione peroxidase activity in psoriatics consuming high-selenium drinking water at the dead-sea psoriasis treatment center |
Type |
A3 Journal article |
Year |
1985 |
Publication |
Pharmacological research communications |
Abbreviated Journal |
|
Volume |
17 |
Issue |
5 |
Pages |
479-488 |
Keywords |
A3 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Erythrocyte selenium-dependent glutathione peroxidase activity was measured in psoriatic Danes, before and after their four-week balneological therapy at the Ein-Bokek International Psoriasis Treatment Center, on the Dead-Sea shore in Israel. The drinking water in Ein-Bokek was found to be rich in selenium, a trace element with anticarcinogenic properties and of great importance in human nutrition and health. The most reliable biological parameter for increase in selenium bioavailability is the erythrocytes' glutathione-peroxidase activity. As psoriasis is a proliferative skin disease, the activity of this enzyme was assayed in 35 psoriatic Danes and in 25 long-term local hotel workers, as well as in 34 volunteers drinking low-selenium water. The glutathione peroxidase activity in the psoriatic patients increased significantly during their four-week stay in Ein-Bokek. Erythrocyte glutathione peroxidase activity in the hotel workers was 50% higher than that in the healthy volunteers consuming low-selenium water. A possible role of selenium in psoriasis is suggested. |
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Wos |
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Publication Date |
2004-10-04 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0031-6989 |
ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Open Access |
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Notes |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:116758 |
Serial |
8076 |
Permanent link to this record |
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|
|
Author |
Storms, H.; Artaxo, P.; Bruynseels, F.; Van Grieken, R. |
Title |
Individual particle analysis by automated EPMA for the improvement of source apportionment for remote aerosols |
Type |
H3 Book chapter |
Year |
1987 |
Publication |
|
Abbreviated Journal |
|
Volume |
|
Issue |
|
Pages |
343-345
T2 - Microbeam analysis 1987 / Geiss, R.H. |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
|
ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
|
Open Access |
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Notes |
|
Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
no |
Call Number |
UA @ admin @ c:irua:117525 |
Serial |
8077 |
Permanent link to this record |
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|
|
Author |
Wegrzynek, D.; Eisma, D.; Van Grieken, R. |
Title |
Individual particle analysis of sediments from the Gulf of Lions, suspensions from the Rhône river and dust of Saharan origin: preliminary results |
Type |
P3 Proceeding |
Year |
1992 |
Publication |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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UA library record |
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Approved ![sorted by Approved field, ascending order (up)](img/sort_asc.gif) |
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UA @ admin @ c:irua:2861 |
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8078 |
Permanent link to this record |