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Author Rowenczyk, L.; Dazzi, A.; Deniset-Besseau, A.; Beltran, V.; Goudounèche, D.; Wong-Wah-Chung, P.; Boyron, O.; George, M.; Fabre, P.; Roux, C.; Mingotaud, A.F.; ter Halle, A. pdf  doi
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  Title Microstructure characterization of oceanic polyethylene debris Type A1 Journal article
  Year (down) 2020 Publication Environmental Science & Technology Abbreviated Journal Environ Sci Technol  
  Volume 54 Issue 7 Pages 4102-4109  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Plastic pollution has become a worldwide concern. It was demonstrated that plastic breaks down to nanoscale particles in the environment, forming so-called nanoplastics. It is important to understand their ecological impact, but their structure is not elucidated. In this original work, we characterize the microstructure of oceanic polyethylene debris and compare it to the nonweathered objects. Cross sections are analyzed by several emergent mapping techniques. We highlight deep modifications of the debris within a layer a few hundred micrometers thick. The most intense modifications are macromolecule oxidation and a considerable decrease in the molecular weight. The adsorption of organic pollutants and trace metals is also confined to this outer layer. Fragmentation of the oxidized layer of the plastic debris is the most likely source of nanoplastics. Consequently the nanoplastic chemical nature differs greatly from plastics.  
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  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000526418000041 Publication Date 2020-03-09  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0013-936x; 1520-5851 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 11.4 Times cited 3 Open Access  
  Notes ; Foundation and The French National Reaserch Program for Environmental and Occupational Health of Anses (EST/2017/1/219). We thank the 7th Continent Expedition Association, as well as the staff and crew, for the sea sampling campaign. ; Approved Most recent IF: 11.4; 2020 IF: 6.198  
  Call Number UA @ admin @ c:irua:172890 Serial 6560  
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