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Author Battle, P.D.; Avdeev, M.; Hadermann, J. doi  openurl
  Title The interplay of microstructure and magnetism in La3Ni2SbO9 Type A1 Journal article
  Year (down) 2014 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 220 Issue Pages 163-166  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract La3Ni2SbO9 adopts a perovskite-related structure in which the six-coordinate cation sites are occupied alternately by Ni2+ and a disordered arrangement of Ni2+/Sb5+. A polycrystalline sample has been studied by neutron diffraction in applied magnetic fields of 0 <= H/kOe <= 50 at 5 K. In 0 kOe, weak magnetic Bragg scattering consistent with the adoption of a G-type ferrimagnetic structure is observed; the ordered component of the magnetic moment was found to be 0.89(7) mu(B) per Ni2+ cation. This increased to 1.60(3) mu(B) in a field of 50 kOe. Transmission electron microscopy revealed variations in the Ni:Sb ratio across crystallites of the sample. It is proposed that these composition variations disrupt the magnetic superexchange interactions within the compound, leading to domain formation and a reduced average moment. The application of a magnetic field aligns the magnetisation vectors across the crystal and the average moment measured by neutron diffraction increases accordingly. The role played by variations in the local chemical composition in determining the magnetic properties invites comparison with the behaviour of relaxor ferroelectrics. (C) 2014 Elsevier Inc. All rights reserved.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000343346100024 Publication Date 2014-09-01  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 13 Open Access  
  Notes Approved Most recent IF: 2.299; 2014 IF: 2.133  
  Call Number UA @ lucian @ c:irua:121134 Serial 3588  
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