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Author (up) Álvarez-Martín, A.; Sanchez-Martin, M.J.; Ordax, J.M.; Marin-Benito, J.M.; Sonia Rodriguez-Cruz, M. pdf  url
doi  openurl
  Title Leaching of two fungicides in spent mushroom substrate amended soil : I influence of amendment rate, fungicide ageing and flow condition Type A1 Journal article
  Year 2017 Publication The science of the total environment Abbreviated Journal  
  Volume 584 Issue Pages 828-837  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A study has been conducted on the leaching of two fungicides, tebuconazole and cymoxanil, in a soil amended with spent mushroom substrate (SMS), with an evaluation of how different factors influence this process.The objective was based on the potential use of SMS as a biosorbent for immobilizing pesticides in vulnerable soils, and the need to know how it could affect the subsequent transport of these retained compounds. Breakthrough curves (BTCs) for C-14-fungicides, non-incubated and incubated over 30 days, were obtained in columns packed with an unamended soil (S), and this soil amended with SMS at rates of 5% (S + SMS5) and 50% (S + SMS50) under saturated and saturated-unsaturated flows. The highest leaching of tebuconazole (> 50% of the total C-14 added) was found in S when a saturated water flow was applied to the column, but the percentage of leached fungidde decreased when a saturated-unsaturated flow was applied in both SMS-amended soils. Also a significant decrease in teaching was observed for tebuconazole after incubation in the column, especially in S + SMS50 when both flows were applied. Furthermore, cymoxanil leaching was complete in S and S + SMS when a saturated flow was applied, and maximum peak concentrations were reached at 1 pore volume (PV), although BTCs showed peaks with lower concentrations in S + SMS. The amounts of cymoxanil retained only increased in S + SMS when a saturated-unsaturated flow was applied. A more relevant effect of SMS for reducing the leaching of fungidde was observed when cymoxanil was previously incubated in the column, although mineralization was enhanced in this case. These results are of interest for extending SMS application on the control of the leaching of fungicides with different physicochemical characteristics after different ageing times in the soil and water flow conditions applied. (C) 2017 Elsevier B.V. All rights reserved.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000399358500080 Publication Date 2017-01-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:160643 Serial 8168  
Permanent link to this record
 

 
Author (up) Alvarez-Martin, A.; Trashin, S.; Cuykx, M.; Covaci, A.; De Wael, K.; Janssens, K. pdf  url
doi  openurl
  Title Photodegradation mechanisms and kinetics of Eosin-Y in oxic and anoxic conditions Type A1 Journal article
  Year 2017 Publication Dyes and pigments Abbreviated Journal Dyes Pigments  
  Volume 145 Issue Pages 376-384  
  Keywords A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Toxicological Centre  
  Abstract Lakes based on Eosin-Y are extensively used by 19th century artists. Unfortunately, the identification of these pigments in paintings is a difficult task because Eosin-Y degrades very fast under the influence of light. The characterization of the (photo)degradation products of Eosin-Y can be very useful for the identification of these pigments in historic works of art and related cultural heritage artifacts. Furthermore, knowledge on how different factors influence the discoloration process (e.g. different types of irradiation sources and presence/absence of oxygen) is a valuable tool for preventive conservation. To this aim we performed a study on the photodegradation of Eosin-Y in solution under different illumination and in both oxic and anoxic conditions. The photodegradation of Eosin-Y was monitored by UV-VIS spectrophotometry, LC-QTOFMS and electrochemistry techniques. Results indicated higher degradation rates, by a factor of 20 or higher, under illumination with wavelengths near to the main absorbance band of the red pigment. Two different degradation pathways are observed under the conditions studied. LC-QTOFMS and electrochemistry suggested that in the presence of oxygen the degradation mechanism is an oxidative process where the breakdown of the structure causes the total discoloration. Meanwhile under anoxic conditions, a debromination process takes place while the chromophore, and consequently the color of the molecule in solution, remains essentially intact.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000405972900046 Publication Date 2017-06-16  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0143-7208 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.473 Times cited 18 Open Access  
  Notes ; ; Approved Most recent IF: 3.473  
  Call Number UA @ admin @ c:irua:144385 Serial 5770  
Permanent link to this record
 

 
Author (up) Alvarez-Martin, A.; Wilcop, M.; Anderson, R.; Wendt, D.; Barden, R.; Kavich, G.M. pdf  doi
openurl 
  Title Investigation of volatile organic compounds in museum storage areas Type A1 Journal article
  Year 2021 Publication Air Quality Atmosphere And Health Abbreviated Journal Air Qual Atmos Hlth  
  Volume 14 Issue 11 Pages 1797-1809  
  Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp X-ray Imaging and Spectroscopy (AXIS)  
  Abstract This study investigates the complex mixture of volatile organic compounds (VOCs) released by and accumulated within a collection of historic medicinal, pharmaceutical, and cosmetic artifacts housed at the National Museum of American History (Smithsonian Institution). In recent years, staff have become concerned, both for the safety of the objects and for personnel working in the collection, about strong unremediated odors accumulating within several storage cabinets. Museum staff also wondered if non-odorous off-gassing might need remediation. Solid-phase microextraction combined with gas chromatography–mass spectrometry analysis (SPME–GC–MS) was used to identify VOCs present in the storage room housing the collection. Over 160 compounds were detected and identified overall. Among these, 49 appeared to be directly related to ingredients used in the manufacture of many collection items. The results of the study suggest that SPME–GC–MS can be a strong tool for the rapid screening of multicomponent museum collections exhibiting off-gassing problems, before the pursuit of other more tedious analytical approaches. Additionally, the study reveals valuable insight into the characteristic volatile emission of historic medicinal, pharmaceutical, and cosmetic artifacts, increasing understanding of, and decision-making for, similar collections of objects. Eventually, it is hoped that this information can be used to inform mitigation strategies for the capture and reduction of VOCs in collections storage areas.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000659058300001 Publication Date 2021-06-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1873-9318 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.184 Times cited Open Access Not_Open_Access  
  Notes Approved Most recent IF: 3.184  
  Call Number UA @ admin @ c:irua:181923 Serial 8129  
Permanent link to this record
 

 
Author (up) Amato, S.R.; Burnstock, A.; Cross, M.; Janssens, K.; Rosi, F.; Cartechini, L.; Fontana, R.; Dal Fovo, A.; Paolantoni, M.; Grazia, C.; Romani, A.; Michelin, A.; Andraud, C.; Tournie, A.; Dik, J. pdf  doi
openurl 
  Title Interpreting technical evidence from spectral imaging of paintings by Edouard Manet in the Courtauld Gallery Type A1 Journal article
  Year 2019 Publication X-ray spectrometry T2 – MA-XRF Workshop on Developments and Applications of Macro-XRF in, Conservation, Art, and Archeology, SEP 24-25, 2017, Trieste, ITALY Abbreviated Journal X-Ray Spectrom  
  Volume 48 Issue 4 Pages 282-292  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The paintings by edouard Manet in The Courtauld Gallery Dejeuner sur l'herbe (1863-68), Marguerite de Conflans en Toilette de Bal (1870-1880), Banks of the Seine at Argenteuil (1874), and A Bar at the Folies-Bergere (1882) were investigated for the first time using a range of non-invasive in situ analyses. The aims of the study were to investigate the painting techniques and materials used for this group of works and to critically evaluate the technical evidence derived from the integrated use of imaging techniques and portable spectroscopic methods in this context. The paintings were investigated by means of macro X-ray fluorescence (MA-XRF), reflection spectral imaging, portable UV-Vis-NIR spectroscopy, portable Raman spectroscopy, and reflection FTIR. MA-XRF and reflection spectral imaging allowed visualising elements in the compositions that were not visible using traditional methods of technical study. For example, MA-XRF analysis of Dejeuner sur l'herbe revealed elements of the development of the composition that provided new evidence to consider its relationship to other versions of the composition. The study also highlighted questions about the interpretation of elemental distribution maps and spectral images that did not correspond to the reworking visible in X-radiographs. For example, in A Bar at the Folies-Bergere Manet made numerous changes during painting, which were not clearly visualised with any of the techniques used. The research has wider implications for the study of Impressionist paintings, as the results will support technical studies of works by other artists of the period who used similar materials and painting methods.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000472210700005 Publication Date 2018-01-23  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 1.298 Times cited Open Access  
  Notes ; Financial support by the Access to Research Infrastructures activity in the Horizon 2020 Programme of the EU (IPERION CH Grant agreement 654028) is gratefully acknowledged. ; Approved Most recent IF: 1.298  
  Call Number UA @ admin @ c:irua:161296 Serial 5670  
Permanent link to this record
 

 
Author (up) Ameloot, P.C.; Vandeputte, D.F.; Van Grieken, R.E.; Coomans, D. openurl 
  Title Localization of lead in cultured tooth germs by laser microprobe micro-analysis Type A3 Journal article
  Year 1987 Publication Proceedings of the Finnish Dental Society Abbreviated Journal  
  Volume 83 Issue Pages 225-236  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-551x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116799 Serial 8183  
Permanent link to this record
 

 
Author (up) Amiri-Aref, M. openurl 
  Title Utilization of magnetic nanoparticles and carbon nanotubes to fabrication electrochemical sensors for determination of some important biological and pharmaceutical compounds Type Doctoral thesis
  Year 2015 Publication Abbreviated Journal  
  Volume Issue Pages 137 p.  
  Keywords Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:128299 Serial 8727  
Permanent link to this record
 

 
Author (up) Amiri-Aref, M.; Raoof, J.B.; Kiekens, F.; De Wael, K. pdf  doi
openurl 
  Title Mixed hemi/ad-micelles coated magnetic nanoparticles for the entrapment of hemoglobin at the surface of a screen-printed carbon electrode and its direct electrochemistry and electrocatalysis Type A1 Journal article
  Year 2015 Publication Biosensors and bioelectronics Abbreviated Journal Biosens Bioelectron  
  Volume 74 Issue Pages 518-525  
  Keywords A1 Journal article; Pharmacology. Therapy; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract An efficient procedure for the physical entrapment of proteins within a biocompatible matrix and their immobilization on electrode surfaces is of utmost importance in the fabrication of biosensors. In this work, the magnetic entrapment of hemoglobin (Hb) at the surface of a screen-printed carbon electrode (SPCE), through mixed hemi/ad-micelles (MHAM) array of positively charged surfactant supported iron oxide magnetic nanoparticles (Mag-NPs), is reported. The Hb/MHAM@Mag-NPs biocomposite is captured at SPCE by a super magnet (Hb/MHAM@Mag-NPs/SPCE). To gain insight in the configuration of the mixed hemi/ad-micelles of CTAB at Mag-NPs, zeta-potential measurements were performed. The entrapment of Hb at MHAM@Mag-NPs was confirmed by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Fourier transform infrared spectroscopy (FT-IR). Direct electron transfer of the Hb intercalated into the composite film showed a pair of well-defined quasi-reversible redox peak at formal potential of −0.255 V vs. Ag/AgCl corresponding to heme Fe(III)/Fe(II) redox couple. It shows that the MHAM@Mag-NPs composite could increase the adsorption ability for Hb, thus provides a facile direct electron transfer between the Hb and the substrate. The proposed biosensor showed excellent electrocatalytic activity to the H2O2 reduction in the wide concentration range from 5.0 to 300.0 µM obtained by amperometric measurement. The MichaelisMenten constant (Km) value of Hb at the modified electrode is 55.4 µM, showing its high affinity. Magnetic entrapment offers a promising design for fast, convenient and effective immobilization of protein within a few minutes for determination of the target molecule in low sample volume at disposable cost-effective SPCE.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000360772800071 Publication Date 2015-07-05  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0956-5663 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 7.78 Times cited 14 Open Access  
  Notes ; We are thankful for the BOF financial support from the University of Antwerp and Hercules financial support (SEM). ; Approved Most recent IF: 7.78; 2015 IF: 6.409  
  Call Number UA @ admin @ c:irua:126535 Serial 5731  
Permanent link to this record
 

 
Author (up) Åmit, Å.; Janssens, K.; Schalm, O.; Kos, M. doi  openurl
  Title Spread of façon-de-Venise glassmaking through central and western Europe Type A1 Journal article
  Year 2004 Publication Nuclear instruments and methods in physics research B Abbreviated Journal  
  Volume 213 Issue Pages 717-722  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000187020700143 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved Most recent IF: NA  
  Call Number UA @ admin @ c:irua:45376 Serial 5843  
Permanent link to this record
 

 
Author (up) Anaf, W. openurl 
  Title The influence of particulate matter on cultural heritage : chemical characterisation of the interaction between the atmospheric environment and pigments Type Doctoral thesis
  Year 2014 Publication Abbreviated Journal  
  Volume Issue Pages 319 p.  
  Keywords Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:119329 Serial 8095  
Permanent link to this record
 

 
Author (up) Anaf, W.; Bencs, L.; Van Grieken, R.; Janssens, K.; De Wael, K. pdf  url
doi  openurl
  Title Indoor particulate matter in four Belgian heritage sites : case studies on the deposition of dark-colored and hygroscopic particles Type A1 Journal article
  Year 2015 Publication The science of the total environment Abbreviated Journal Sci Total Environ  
  Volume 506 Issue Pages 361-368  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Atmospheric total suspended particulate (TSP) was passively sampled by means of deployed horizontal and vertical filters in various rooms of four Belgian cultural heritage buildings, installed with various heating/ventilation systems. Soiling/blackening and deposition of inorganic, water-soluble aerosol components were considered. The extent of soiling was determined by means of two independent methods: (1) in terms of the covering rate of the samplers by optical reflection microscopy and (2) the reduction in lightness of the samplers using the CIE L*a*b* color space by spectrophotometry. A fairly good correlation was found between both methods. The inorganic composition of the deposited water-soluble TSP was quantified by means of ion chromatography. Compared to controlled environments, uncontrolled environments showed increased water-soluble aerosol content of the total deposited mass. Higher chloride deposition was observed on horizontal surfaces, compared to vertical surfaces.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000347576800039 Publication Date 2014-11-24  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0048-9697 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.9 Times cited 12 Open Access  
  Notes ; ; Approved Most recent IF: 4.9; 2015 IF: 4.099  
  Call Number UA @ admin @ c:irua:120640 Serial 5662  
Permanent link to this record
 

 
Author (up) Anaf, W.; Cabal, A.; Robbe, M.; Schalm, O. url  doi
openurl 
  Title Real-time wood behaviour : the use of strain gauges for preventive conservation applications Type A1 Journal article
  Year 2020 Publication Sensors Abbreviated Journal  
  Volume 20 Issue 1 Pages 305  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)  
  Abstract Within the heritage field, the application of strain gauges on wood surfaces is a little-explored but inexpensive and effective method to analyse the environmental appropriateness of rooms for the wooden heritage collections they contain. This contribution proposes a wood sensor connected to a data logger to identify short moments with an elevated risk of harm. Two experiments were performed to obtain insights pertaining to the applicability of wood sensors to evaluate preservation conditions. (1) The representativeness of strain gauges on dummies was tested for their use in evaluating the preservation conditions of a range of wooden objects exposed to the same environment. For this, three situations were mimicked: a bare wood surface, a wood surface covered with a preparation layer, and a wood surface covered with a preparation and varnish layer. (2) The usability of strain gauges to monitor the wood behaviour in real-time measurements was tested with a monitoring campaign of almost two years in a church where a new heating system was installed. The results of both experiments are promising, and the authors encourage a broader application of strain gauges in the heritage field.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000510493100305 Publication Date 2020-01-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes ; This research was funded by the Belgian Federal Public Planning Service Science Policy (BELSPO) under project number BR/132/A6/AIRCHECQ. ; Approved Most recent IF: NA  
  Call Number UA @ admin @ c:irua:166595 Serial 6592  
Permanent link to this record
 

 
Author (up) Anaf, W.; Horemans, B.; Madeira, T.I.; Carvalho, M.L.; De Wael, K.; Van Grieken, R. pdf  doi
openurl 
  Title Effects of a constructional intervention on airborne and deposited particulate matter in the Portuguese National Tile Museum, Lisbon Type A1 Journal article
  Year 2013 Publication Environmental Science and Pollution Research Abbreviated Journal Environ Sci Pollut R  
  Volume 20 Issue 3 Pages 1849-1857  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract In the 1970s, a large ambulatory of the National Tile Museum, Lisbon, was closed with glass panes on both ground and first floor. Although this design was meant to protect the museum collection from ambient air pollutants, small openings between the glass panes remain, creating a semi-enclosed corridor. The effects of the glass panes on the indoor air quality were evaluated in a comparative study by monitoring the airborne particle concentration and the extent of particle deposition at the enclosed corridor as well as inside the museum building. Comparison of the indoor/outdoor ratio of airborne particle concentration demonstrated a high natural ventilation rate in the enclosed corridor as well as inside the museum building. PM10 deposition velocities on vertical surfaces were estimated in the order of 3 × 10−4 m s−1 for both indoor locations. Also, the deposition rates of dark-coloured and black particles in specific were very similar at both indoor locations, causing visual degradation. The effectiveness of the glass panes in protecting the museum collection is discussed.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000315442500061 Publication Date 2012-07-24  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0944-1344; 1614-7499 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.741 Times cited 15 Open Access  
  Notes ; ; Approved Most recent IF: 2.741; 2013 IF: 2.757  
  Call Number UA @ admin @ c:irua:100214 Serial 5583  
Permanent link to this record
 

 
Author (up) Anaf, W.; Horemans, B.; Van Grieken, R.; De Wael, K. pdf  doi
openurl 
  Title Chemical boundary conditions for the classification of aerosol particles using computer controlled electron probe microanalysis Type A1 Journal article
  Year 2012 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal Talanta  
  Volume 101 Issue Pages 420-427  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A method for the classification of individual aerosol particles using computer controlled electron probe microanalysis is presented. It is based on chemical boundary conditions (CBC) and enables quick and easy processing of a large set of elemental concentration data (mass%), derived from the X-ray spectra of individual particles. The particles are first classified into five major classes (sea salt related, secondary inorganic, minerals, iron-rich and carbonaceous), after which advanced data mining can be performed by examining the elemental composition of particles within each class into more detail (e.g., by ternary diagrams). The CBC method is validated and evaluated by comparing its results with the output obtained with hierarchical cluster analysis (HCA) for well-known standard particles as well as real aerosol particles collected with a cascade impactor. The CBC method gives reliable results and has a major advantage compared to HCA. CBC is based on boundary conditions that are derived from chemical logical thinking and does not require a translation of a mathematical algorithm output as does HCA. Therefore, the CBC method is more objective and enables comparison between samples without intermediate steps.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000313084400061 Publication Date 2012-09-30  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.162 Times cited 3 Open Access  
  Notes ; ; Approved Most recent IF: 4.162; 2012 IF: 3.498  
  Call Number UA @ admin @ c:irua:101336 Serial 5511  
Permanent link to this record
 

 
Author (up) Anaf, W.; Janssens, K.; De Wael, K. pdf  doi
openurl 
  Title Formation of metallic mercury during photodegradation/photodarkening of \alpha-HgS : electrochemical evidence Type A1 Journal article
  Year 2013 Publication Angewandte Chemie: international edition in English Abbreviated Journal Angew Chem Int Edit  
  Volume 52 Issue 48 Pages 12568-12571  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Das rote Pigment α-HgS neigt in Gegenwart von Licht und Chloridionen zur Schwärzung. Als Grund für die Zersetzung und Entfärbung werden die Bildung von (schwarzem) β-HgS oder Quecksilbermetall vermutet, doch diese Substanzen wurden noch nicht auf natürlich oder künstlich zersetzter HgS-Farbe nachgewiesen. Elektrochemische Experimente belegen nun die Bildung von Quecksilbermetall in Gegenwart von Licht und Chloridionen.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000327582900015 Publication Date 2013-10-04  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1433-7851; 0570-0833 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 11.994 Times cited 19 Open Access  
  Notes ; The authors acknowledge L. Klaassen for valuable discussions and providing samples. We acknowledge financial support from the SDD programme (S2-ART project) of the Belgian Federal Goverment. ; Approved Most recent IF: 11.994; 2013 IF: 11.336  
  Call Number UA @ admin @ c:irua:111265 Serial 5626  
Permanent link to this record
 

 
Author (up) Anaf, W.; Leyva Pernia, D.; Schalm, O. url  doi
openurl 
  Title Standardized indoor air quality assessments as a tool to prepare heritage guardians for changing preservation conditions due to climate change Type A1 Journal article
  Year 2018 Publication Geosciences Abbreviated Journal  
  Volume 8 Issue 8 Pages Unsp 276-14  
  Keywords A1 Journal article; Engineering sciences. Technology; Antwerp Systems and software Modelling (AnSyMo); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)  
  Abstract Climate change will affect the preservation conditions of our cultural heritage. Therefore, well-considered mitigation actions should be implemented to safeguard our heritage for future generations. Environmental monitoring is essential to follow up the change in preservation conditions and to evaluate the effectiveness of performed mitigation actions. To support heritage guardians in the processing and evaluation of monitored data, an indoor air quality (IAQ) index for heritage applications is introduced. The index is calculated for each measured point in time and is visualized in a user-friendly and intuitive way. The current paper describes the backbone of the IAQ-calculating algorithm. The algorithm is subsequently applied on a case study in which a mitigation action is implemented in a church.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000443254500006 Publication Date 2018-07-27  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 2076-3263 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:152329 Serial 8578  
Permanent link to this record
 

 
Author (up) Anaf, W.; Schalm, O. pdf  url
doi  openurl
  Title Climatic quality evaluation by peak analysis and segregation of low-, mid-, and high-frequency fluctuations, applied on a historic chapel Type A1 Journal article
  Year 2019 Publication Building and environment Abbreviated Journal  
  Volume 148 Issue Pages 286-293  
  Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)  
  Abstract Heritage-related guidelines and standards recommend stable climatic conditions, since these contribute to the extension of heritage collections life. As a result, numerous museums and other heritage institutions implement (expensive) mitigation measures to achieve stable conditions. Nevertheless, temperature and relative humidity fluctuations are often still observed. This contribution demonstrates that the analysis of temperature and humidity peaks and drops helps to identify hazards which cause fluctuations in different frequency ranges. This hazard identification provides information on the type of mitigation actions that are required in the near future and in which order they need to be implemented. The approach is illustrated with a case study. A 22 month monitoring campaign was performed in a chapel in the center of Antwerp (Belgium) where the climatic conditions are controlled with a heating, ventilation and air conditioning (HVAC) system. Low-, mid- and high-frequency fluctuations were separated and discussed for their hazards.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000457116500024 Publication Date 2018-11-15  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0360-1323 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:157569 Serial 7672  
Permanent link to this record
 

 
Author (up) Anaf, W.; Schalm, O.; Janssens, K.; De Wael, K. pdf  url
doi  openurl
  Title Understanding the (in)stability of semiconductor pigments by a thermodynamic approach Type A1 Journal article
  Year 2015 Publication Dyes and pigments Abbreviated Journal Dyes Pigments  
  Volume 113 Issue Pages 409-415  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)  
  Abstract Several artists pigments are semiconductors. Some of these materials appear stable over time, whereas others already show remarkable signs of degradation after limited time periods. The (in)stability of these pigments can be understood using a thermodynamic approach. For several pigment-related materials, the thermodynamic oxidation and reduction potential (ϕox and ϕred) were determined and evaluated considering the absolute energy positions of the valence and conduction band edges and the water redox potentials. The positions of ϕox and ϕred can be used in a fast screening of the stability of semiconductor pigments towards photoinduced corrosion in an aqueous/humid environment. This theoretical approach corresponds well with experimental data on pigment permanence and degradation phenomena found in literature.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000346543200052 Publication Date 2014-09-16  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0143-7208 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.473 Times cited 14 Open Access  
  Notes ; The authors acknowledge the funding from the Belspo S2-ART project (Belgian Federal Government) SD/RI/04A. ; Approved Most recent IF: 3.473; 2015 IF: 3.966  
  Call Number UA @ admin @ c:irua:118875 Serial 5885  
Permanent link to this record
 

 
Author (up) Anaf, W.; Trashin, S.; Schalm, O.; van Dorp, D.; Janssens, K.; De Wael, K. pdf  doi
openurl 
  Title Electrochemical photodegradation study of semiconductor pigments : influence of environmental parameters Type A1 Journal article
  Year 2014 Publication Analytical chemistry Abbreviated Journal Anal Chem  
  Volume 86 Issue 19 Pages 9742-9748  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)  
  Abstract Chemical transformations in paintings often induce discolorations, disturbing the appearance of the image. For an appropriate conservation of such valuable and irreplaceable heritage objects, it is important to have a good know-how on the degradation processes of the (historical) materials: which pigments have been discolored, what are the responsible processes, and which (environmental) conditions have the highest impact on the pigment degradation and should be mitigated. Pigment degradation is already widely studied, either by analyzing historical samples or by accelerated weathering experiments on dummies. However, in historic samples several processes may have taken place, increasing the complexity of the current state, while aging experiments are time-consuming due to the often extended aging period. An alternative method is proposed for a fast monitoring of degradation processes of semiconductor pigments, using an electrochemical setup mimicking the real environment and allowing the identification of harmful environmental parameters for each pigment. Examples are given for the pigments cadmium yellow (CdS) and vermilion (α-HgS).  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000343017100058 Publication Date 2014-08-27  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 6.32 Times cited 18 Open Access  
  Notes ; ; Approved Most recent IF: 6.32; 2014 IF: 5.636  
  Call Number UA @ admin @ c:irua:118834 Serial 5593  
Permanent link to this record
 

 
Author (up) Andreae, M.O.; Charlson, R.J.; Bruynseels, F.; Storms, H.; Van Grieken, R.; Maenhaut, W. doi  openurl
  Title Internal mixture of sea salt, silicates, and excess sulfate in marine aerosols Type A1 Journal article
  Year 1986 Publication Science Abbreviated Journal  
  Volume 232 Issue 4758 Pages 1620-1623  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Individual aerosol particles from the remote marine atmosphere were investigated by scanning electron microscopy and electron microprobe analysis. A large fraction of the silicate mineral component of the aerosol was found to be internally mixed with sea-salt aerosol particles. This observation explains the unexpected similarity in the size distributions of silicates and sea salt that has been observed in remote marine aerosols. Reentrainment of dust particles previously deposited onto the sea surface and collision between aerosol particles can be excluded as possible source mechanisms for these internally mixed aerosols. The internal mixing could be produced by processes within clouds, including droplet coalescence. Cloud processes may also be responsible for the observed enrichment of excess (nonsea-salt) sulfate on sea-salt particles.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986C826900027 Publication Date 2006-10-05  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0036-8075; 1095-9203 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113613 Serial 8116  
Permanent link to this record
 

 
Author (up) Andrikopoulos, K.S.; Daniilia, S.; Roussel, B.; Janssens, K. doi  openurl
  Title In vitro validation of a mobile Raman-XRF micro-analytical instrument's capabilities on the diagnosis of Byzantine icons Type A1 Journal article
  Year 2006 Publication Journal of Raman spectroscopy Abbreviated Journal J Raman Spectrosc  
  Volume 37 Issue 10 Pages 1026-1034  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000241209500010 Publication Date 2006-09-20  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0377-0486 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.969 Times cited 53 Open Access  
  Notes Approved Most recent IF: 2.969; 2006 IF: 2.133  
  Call Number UA @ admin @ c:irua:60709 Serial 5742  
Permanent link to this record
 

 
Author (up) Anitha, A.; Brasoveanu, A.; Duarte, M.; Hughes, S.; Daubechies, I.; Dik, J.; Janssens, K.; Alfeld, M. pdf  doi
openurl 
  Title Restoration of X-ray fluorescence images of hidden paintings Type A1 Journal article
  Year 2013 Publication Signal processing Abbreviated Journal Signal Process  
  Volume 93 Issue 3 Pages 592-604  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract This paper describes our methods for repairing and restoring images of hidden paintings (paintings that have been painted over and are now covered by a new surface painting) that have been obtained via noninvasive X-ray fluorescence imaging of their canvases. This recently developed imaging technique measures the concentrations of various chemical elements at each two-dimensional spatial location across the canvas. These concentrations in turn result from pigments present both in the surface painting and in the hidden painting beneath. These X-ray fluorescence images provide the best available data from which to noninvasively study a hidden painting. However, they are typically marred by artifacts of the imaging process, features of the surface painting, and areas of information loss. Repairing and restoring these images thus consists of three stages: (1) repairing acquisition artifacts in the dataset, (2) removal of features in the images that result from the surface painting rather than the hidden painting, and (3) identification and repair of areas of information loss. We describe methods we have developed to address each of these stages: a total-variation minimization approach to artifact correction, a novel method for underdetermined blind source separation with multimodal side information to address surface feature removal, and two application-specific new methods for automatically identifying particularly thick or X-ray absorbent surface features in the painting. Finally, we demonstrate the results of our methods on a hidden painting by the artist Vincent van Gogh. (C) 2012 Elsevier B.V. All rights reserved.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000312521400007 Publication Date 2012-10-13  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0165-1684 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.11 Times cited 13 Open Access  
  Notes ; Marco F. Duarte was supported during this research by NSF Supplemental Funding DMS-0439872 to UCLA-IPAM, PI: R. Caflisch. Matthias Alfeld receives support in the form of a Ph.D. fellowship of the Research Foundation Flanders (FWO). This research was also supported by the Interuniversity Attraction Poles Programme Belgian Science Policy (IUAP VI/16). The text also presents results of GOA “XANES meets ELNES” (Research Fund University of Antwerp, Belgium) and from FWO (Brussels, Belgium) projects no. G.0704.08 and G.01769.09. ; Approved Most recent IF: 3.11; 2013 IF: 2.238  
  Call Number UA @ admin @ c:irua:105921 Serial 5817  
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Author (up) Anitha, A.; Brasoveanu, A.; Duarte, M.F.; Hughes, S.M.; Daubechies, I.; Dik, J.; Janssens, K.; Alfeld, M. openurl 
  Title Virtual underpainting reconstruction from X-ray fluorescence imaging data Type P1 Proceeding
  Year 2011 Publication Abbreviated Journal  
  Volume Issue Pages 1239-1243  
  Keywords P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes ; ; Approved Most recent IF: NA  
  Call Number UA @ admin @ c:irua:124612 Serial 5905  
Permanent link to this record
 

 
Author (up) Annegarn, H.; Van Grieken, R.; van Espen, P.; von Blottnitz, F.; Sellschop, J.; Winchester, J.; Maenhaut, W. openurl 
  Title Background aerosol composition at Gobabeb, South West Africa Type A3 Journal article
  Year 1976 Publication Madoqua Abbreviated Journal  
  Volume Issue 2 Pages 107-118  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1011-5498 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116512 Serial 7544  
Permanent link to this record
 

 
Author (up) Annegarn, H.J.; Madiba, C.C.P.; Sellschop, J.P.F.; Genz, H.; Hoffmann, D.H.H.; Low, W.; Richter, A.; Van Grieken, R.E. url  doi
openurl 
  Title Analysis of X-ray spectra excited by X rays, electrons, and protons in monazite Type A1 Journal article
  Year 1977 Publication Physical review : C : nuclear physics Abbreviated Journal  
  Volume 16 Issue 1 Pages 379-383  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Mineral monazite from Malaysia has been investigated by energy dispersive x-ray analysis employing three different methods: x-ray, relativistic electron and proton induced excitation. An upper limit of 15 ppm has been placed on the possible concentration of the superheavy element with Z=126.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1977DR12200044 Publication Date 2002-07-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0556-2813; 1089-490x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116554 Serial 7453  
Permanent link to this record
 

 
Author (up) Annegarn, H.J.; Storms, H.; Van Grieken, R.E.; Booth-Jones, P.A. pdf  doi
openurl 
  Title Composition and size of individual particles from a gold mine atmosphere Type A3 Journal article
  Year 1987 Publication Mining science & technology Abbreviated Journal  
  Volume 5 Issue 2 Pages 111-119  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Airborne dust particles were collected in a return airway of a South African gold mine using a 7-stage, single-orifice cascade impactor. Between 70 and 130 individual particles were analysed on each stage using automated electron-probe x-ray microanalysis (EPXMA). Particle size and shape parameters are given for different classes of particles sorted by elemental composition. Silicon-rich particles are the most abundant overall, while chlorine-rich particles dominate (up to 80%) in the range 0.21.0 μm. It is shown that EPXMA characterisation of particles can be used to infer relative contributions of various particle sources and dust generating processes to the total dust concentrations in mine atmospheres. An understanding of the nature and source of particles is essential for any source control strategy. We conclude that the EPXMA technique merits inclusion in the repertoire of techniques used for characterising underground dust.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2004-12-15  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0167-9031 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116777 Serial 7701  
Permanent link to this record
 

 
Author (up) Annegarn, H.J.; Van Grieken, R.E.; Dibby, D.M.; Von Blottnitz, F. pdf  doi
openurl 
  Title Background aerosol composition in the Namib Desert, South West-Africa (Namibia) Type A1 Journal article
  Year 1983 Publication Atmospheric environment : an international journal Abbreviated Journal  
  Volume 17 Issue 10 Pages 2045-2053  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A remote site in the Namib Desert was selected for sampling background aerosols in southern Africa, as one of a wide network of stations spanning the Southern Hemisphere in a programme designed to measure the background concentrations of trace elements in the atmosphere. A series of samples was collected over a 6-month period using a single-orifice cascade impactor, which fractionated the particles into six size groups. Analysis was performed using particle-induced X-ray emission (PIXE), yielding results for S, Cl, K, Ca, Ti, Mn, Fe, Br and Sr, and occasionally also for V, Cr, Ni, Cu, Zn and Pb. No direct correlations with wind direction were observed excluding strong local or regional sources of particles. K, Ca, Ti, Mn and Fe can be identified with a dust dispersion source. Cl, large particle S and Br, and part of the K and Sr are derived from sea spray. Relative to the soil components small particle K is not enriched as it normally is in regions with less scarce vegetation. Cr, V, Ni, Cu, Zn and Pb concentrations and enrichments in the aerosol are lower than practically all values measured at any other location hitherto. The concentration of the small particle sulphur, 200 ng m−3, is believed to be related to anaerobic conditions and plankton blooms in the ocean upwelling zones off Namibia.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1983RP58300017 Publication Date 2003-08-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1352-2310 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113623 Serial 7545  
Permanent link to this record
 

 
Author (up) Annegarn, H.J.; Van Grieken, R.E.; Winchester, J.W.; Sellschop, J.P.F.; von Blottnitz, F. openurl 
  Title Background aerosol concentrations at the Namib-Atlantic interface Type P3 Proceeding
  Year 1979 Publication Abbreviated Journal  
  Volume Issue Pages  
  Keywords P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:117465 Serial 7546  
Permanent link to this record
 

 
Author (up) Arana, A.; Loureiro, A.L.; Barbosa, H.M.J.; Van Grieken, R.; Artaxo, P. pdf  doi
openurl 
  Title Optimized energy dispersive X-ray fluorescence analysis of atmospheric aerosols collected at pristine and perturbed Amazon Basin sites Type A1 Journal article
  Year 2014 Publication X-ray spectrometry Abbreviated Journal  
  Volume 43 Issue 4 Pages 228-237  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Elemental composition of aerosols is important to source apportionment studies and to understand atmospheric processes that influence aerosol composition. Energy dispersive X-ray fluorescence spectroscopy was applied for measuring the elemental composition of Amazonian atmospheric aerosols. The instrument used was a spectrometer Epsilon 5, PANalytical B. V., with tridimensional geometry that reduces the background signal with a polarized X-ray detection. The measurement conditions were optimized for low-Z elements, e. g. Mg, Al, Si, that are present at very low concentrations in the Amazon. From Na to K, our detection limits are about 50% to 75% lower than previously published results for similar instrument. Calibration was performed using Micromatter standards, except for P whose standard was produced by nebulization of an aqueous solution of KH2PO4 at our laboratory. The multi-element reference material National Institute of Standards and Technology-2783 (air particulate filter) was used for evaluating the accuracy of the calibration procedure of the 22 elements in our standard analysis routine, and the uncertainty associated with calibration procedures was evaluated. The overall performance of the instrument and validation of our measurements were assessed by comparison with results obtained from parallel analysis using particle-induced X-ray emission and another Epsilon 5 spectrometer. The elemental composition in 660 samples collected at a pristine site in the Amazon Basin and of 1416 samples collected at a site perturbed by land use change was determined. Our measurements show trace elements associated with biogenic aerosols, soil dust, biomass burning, and sea-salt, even for the very low concentrations as observed in Amazonia. Copyright (C) 2014 John Wiley & Sons, Ltd.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000337724600006 Publication Date 2014-06-09  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:118419 Serial 8342  
Permanent link to this record
 

 
Author (up) Araujo, M.F.; van Espen, P.; Van Grieken, R. doi  openurl
  Title Determination of sample thickness via scattered radiation in X-ray fluorescence spectrometry with filtered continuum excitation Type A1 Journal article
  Year 1990 Publication X-ray spectrometry Abbreviated Journal  
  Volume 19 Issue 1 Pages 29-33  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract A semi-empirical approach is described for determining the mass per unit area of a sample being analysed. The method can be used to estimate the concentration of minor and trace elements in matrices containing a substantial amount of light elements. The procedure utilizes the coherently and incoherently scattered radiation induced in the sample by the filtered continuum radiation of a rhodium x-ray tube. The relationship between the intensity of the scattered radiation per unit mass and the average atomic number of the sample is established via calibration graphs, which can be applied for different x-ray tube voltages and for different primary beam filters. The overall procedure was validated by the analysis of several geological standards, deposited as thin slurries of unknown thickness either on Mylar foil or on Nuclepore filters.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1990CU24700005 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116491 Serial 7787  
Permanent link to this record
 

 
Author (up) Araújo, M.F.D.; Bernard, P.C.; Van Grieken, R.E. pdf  doi
openurl 
  Title Heavy metal contamination in sediments from the Belgian coast and Scheldt estuary Type A1 Journal article
  Year 1988 Publication Marine pollution bulletin Abbreviated Journal  
  Volume 19 Issue 2 Pages 269-273  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Sixty-two samples of total sediments and the separated clay/silt size fractions were analysed by energy-dispersive X-ray fluorescence spectrometry to evaluate the pollution level and the trends in samples collected along the Belgian coast over a period of 6 yr and at four stations located in the Scheldt estuary where two of these were sampled periodically for 4 yr. Three correction methods for grain size effects were applied, either to the bulk sediment samples or to the clay/silt size fractions, and the results were compared. Local variations on the concentrations in some of the elements determined were used to establish whether they result from an anthropogenic or natural origin. The level of pollution was assessed as a function of the location, sampling date, and depth.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1988P559400005 Publication Date 2003-08-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0025-326x; 1879-3363 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116801 Serial 8021  
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