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Author Aerts, A.; Janssens, K.; Adams, F. openurl 
  Title A chemical investigation of altered jade art objects Type A3 Journal article
  Year 1995 Publication Orientations Abbreviated Journal  
  Volume Issue Pages 79-80  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:10989 Serial 5516  
Permanent link to this record
 

 
Author Rather, J.A.; Debnath, P.; De Wael, K. pdf  doi
openurl 
  Title Fullerene-\beta-cyclodextrin conjugate based electrochemical sensing device for ultrasensitive detection of p-nitrophenol Type A1 Journal article
  Year 2013 Publication Electroanalysis Abbreviated Journal Electroanal  
  Volume 25 Issue 9 Pages 2145-2150  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The article describes the use of a fullerene (C60)-β-cyclodextrin conjugate, synthesized via 1,3-dipolar cycloaddition, for the ultrasensitive electrochemical detection of p-nitrophenol. This conjugate was successfully immobilized on the surface of a glassy carbon electrode and the developed device showed high activity towards p-nitrophenol due to the synergetic effect of C60, the latter becoming highly conductive upon reduction. The determination of p-nitrophenol was performed by using square wave voltammetry over a concentration range from 2.8×10−9 mol L−1 to 4.2×10−7 mol L−1 and the detection limit was calculated to be 1.2×10−9 mol L−1.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000327590600017 Publication Date 2013-08-27  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1040-0397 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.851 Times cited 13 Open Access  
  Notes ; Jahangir Ahmad Rather is highly thankful for mobility grant provided by the Belspo co-funded by Marie Curie Actions. ; Approved Most recent IF: 2.851; 2013 IF: 2.502  
  Call Number (up) UA @ admin @ c:irua:110033 Serial 5629  
Permanent link to this record
 

 
Author Cagno, S.; de Raedt, I.; Jeffries, T.; Janssens, K. doi  openurl
  Title Composition of Facon de Venise glass from early 17th century London in comparison with luxury glass of the same age Type P1 Proceeding
  Year 2012 Publication Proceedings of the Society of Photo-optical Instrumentation Engineers T2 – Conference on Integrated Approaches to the Study of Historical Glass, (IASHG), APR 16-17, 2012, Brussels, BELGIUM Abbreviated Journal  
  Volume Issue Pages 842205-842212  
  Keywords P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract SEM-EDX and LA-ICP-MS analyses were performed on a set of early 17th century London glass fragments. The samples originate from two archaeological sites (Aldgate and Old Broad Street) where glass workshops were active in this period. The great majority of the samples are made of soda glass. Two distinct compositional groups are observed, each typical of one site of provenance. The samples originating from the Old Broad Street excavation feature a silica-soda-lime composition, with a moderate amount of potash. The samples from Aldgate are richer in potassium and feature higher amounts of trace elements such as Rb, Zr and Cu. The distinction between the two groups stems from different flux and silica sources used for glassmaking. A comparison with different European glass compositions of that time reveals no resemblance with genuine Venetian production, yet the composition of the Old Broad Street glass shows a close similarity to that of fragments produced 'a la facon de Venise' in Antwerp at the end of the 16th century. This coincides with historical sources attesting the arrival of glassworkers from the Low Countries in England and suggests that a transfer of technology took place near the turn of the century.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000311900800005 Publication Date 2012-06-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume 8422 Series Issue Edition  
  ISSN 978-0-8194-9104-6; 0277-786x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited 1 Open Access  
  Notes ; ; Approved Most recent IF: NA  
  Call Number (up) UA @ admin @ c:irua:110142 Serial 5543  
Permanent link to this record
 

 
Author Verreydt, G.; Bronders, J.; van Keer, I.; Diels, L.; Vanderauwera, P. isbn  openurl
  Title Passive samplers for monitoring VOCs in groundwater : prospects related to mass flux measurements Type P3 Proceeding
  Year 2011 Publication Abbreviated Journal  
  Volume Issue Pages  
  Keywords P3 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-1-907161-16-2 Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:110412 Serial 8364  
Permanent link to this record
 

 
Author Monico, L.; Janssens, K.; Miliani, C.; van der Snickt, G.; Brunetti, B.G.; Guidi, M.C.; Radepont, M.; Cotte, M. doi  openurl
  Title Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods : 4 : artificial aging of model samples of co-precipitates of lead chromate and lead sulfate Type A1 Journal article
  Year 2013 Publication Analytical chemistry Abbreviated Journal Anal Chem  
  Volume 85 Issue 2 Pages 860-867  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Previous investigations about the darkening of chrome yellow pigments revealed that this form of alteration is attributable to a reduction of the original Cr(VI) to Cr(III), and that the presence of sulfur-containing compounds, most often sulfates, plays a key role during this process. We recently demonstrated that different crystal forms of chrome yellow pigments (PbCrO4 and PbCr1xSxO4) are present in paintings by Vincent van Gogh. In the present work, we show how both the chemical composition and the crystalline structure of lead chromate-based pigments influence their stability. For this purpose, oil model samples made with in-house synthesized powders of PbCrO4 and PbCr1xSxO4 were artificially aged and characterized. We observed a profound darkening only for those paint models made with PbCr1xSxO4, rich in SO42 (x ≥ 0.4), and orthorhombic phases (>30 wt %). Cr and S K-edge micro X-ray absorption near edge structure investigations revealed in an unequivocal manner the formation of up to about 60% of Cr(III)-species in the outer layer of the most altered samples; conversely, independent of the paint models chemical composition, no change in the S-oxidation state was observed. Analyses employing UVvisible diffuse reflectance and Fourier transform infrared spectroscopy were performed on unaged and aged model samples in order to obtain additional information on the physicochemical changes induced by the aging treatment.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000313668400032 Publication Date 2012-10-10  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 6.32 Times cited 49 Open Access  
  Notes ; This research was supported by grants from ESRF (experiment EC-799), the Interuniversity Attraction Poles Programme-Belgian Science Policy (IUAP VI/16), and the BELSPO-SDD S2-ART (SD/RI/04) project. The text also presents results from GOA “XANES meets ELNES” (Research Fund University of Antwerp, Belgium) and FWO (Brussels, Belgium) projects G.0704.08 and G.01769.09. The EU FP7 programme CHARISMA (Grant Agreement 228330) and MIUR (PRIN08, Materiali e sistemi innovativi per la conservazione dell'arte contemporanea 2008 FFXXN9) are also acknowledged. ; Approved Most recent IF: 6.32; 2013 IF: 5.825  
  Call Number (up) UA @ admin @ c:irua:110471 Serial 5569  
Permanent link to this record
 

 
Author Rather, J.A.; Pilehvar, S.; De Wael, K. pdf  doi
openurl 
  Title A graphene oxide amplification platform tagged with tyrosinase-zinc oxide quantum dot hybrids for the electrochemical sensing of hydroxylated polychlorobiphenyls Type A1 Journal article
  Year 2014 Publication Sensors and actuators : B : chemical Abbreviated Journal Sensor Actuat B-Chem  
  Volume 190 Issue Pages 612-620  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Graphene oxide can act as an amplification platform for the immobilization of a hybrid structure composed of tyrosinase (Tyr) and zinc oxide quantum dots (ZnO QDs). This article describes how this platform increases the sensitivity for the detection of hydroxylated polychlorobiphenyls (OH-PCBs). The adsorption of Tyr (with low isoelectric point) on the positively charged surface of ZnO QDs is based on electrostatic interactions. The scanning electron microscopic images and UVvis spectroscopic analysis demonstrated the adsorption of Tyr on ZnO QDs. The stepwise assembly process of the fabricated biosensor was characterized by cyclic voltammetry and electrochemical impedance spectroscopy. The synthesized ZnO QDs and graphene oxide were characterized by Raman spectroscopy, infrared spectroscopy, X-ray diffraction and scanning electron microscopic techniques. The determination of OH-PCBs was carried out by using square wave voltammetry over the concentration range of 2.827.65 μM with a detection limit of 0.15 μM with good reproducibility, selectivity and acceptable stability. The high value of surface coverage of ZnO QDs and small value of MichaelisMenten constant (View the MathML source) confirmed an excellent loading of the Tyr and a high affinity of the biosensor toward the detection of OH-PCBs. This biosensor and the described sensing platform offer a great potential for rapid, cost-effective and on-field analysis of OH-PCBs.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000326687700082 Publication Date 2013-09-14  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0925-4005 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 5.401 Times cited 26 Open Access  
  Notes ; The authors are highly thankful for the mobility grant (Non-Europe Postdoc Fellowship) for one of the author (Jahangir Ahmad Rather) supported by the Belgian Federal Science Policy (Belspo) co-funded by the Marie Curie Actions from the European Commission. Sanaz Pilehvar is funded by BOF-DOCPRO UA. We are also thankful to the EMAT (Electron Microscopy for Materials Science) group and Laboratory of adsorption and catalysis group of the University of Antwerp for the XRD, Raman and FTIR characterization of samples (GO and ZnO QDs). ; Approved Most recent IF: 5.401; 2014 IF: 4.097  
  Call Number (up) UA @ admin @ c:irua:110566 Serial 5636  
Permanent link to this record
 

 
Author Herremans, D.; Cagno, S.; Vincke, A.; de Clercq, W.; Janssens, K. doi  openurl
  Title Composition and state of alteration of 18th century glass from the Cistercian nunnery of Clairefontaine (Belgium) Type P1 Proceeding
  Year 2012 Publication Proceedings of the Society of Photo-optical Instrumentation Engineers T2 – Conference on Integrated Approaches to the Study of Historical Glass, (IASHG), APR 16-17, 2012, Brussels, BELGIUM Abbreviated Journal  
  Volume Issue Pages 842206-842211  
  Keywords P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract An extended set of 18th century glass vessels was analyzed by means of SEM-EDX (major and minor element composition) The fragmented archaeological objects were recovered from a latrine belonging to the early 18th century building phase of the nunnery of Clairefontaine, near Arlon (B). On the basis of typology and decoration, the major part of the vessels could be dated around the middle of the 18th century. Variety in color and weathering of the glass suggest differences in glassmaking recipes and in the composition and origin of raw materials. The results of the analysis show how two main compositional groups constitute about 90% of the analyzed glass set, and these are constituted by potash glass (transparent beakers) and high lime low alkali glass (green bottles). Next to these, a few potash-lime and soda glasses are also found. The type of alteration has also a clear relation with the original glass composition.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000311900800006 Publication Date 2012-06-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume 8422 Series Issue Edition  
  ISSN 978-0-8194-9104-6; 0277-786x ISBN Additional Links UA library record; WoS full record  
  Impact Factor Times cited Open Access  
  Notes ; ; Approved Most recent IF: NA  
  Call Number (up) UA @ admin @ c:irua:110799 Serial 5537  
Permanent link to this record
 

 
Author Vazquez, C.; Boeykens, S.; Palacios, O.; Caracciolo, N.; Kontozova-Deutsch, V.; Krupińska, B.; Van Grieken, R. isbn  openurl
  Title Estudio de la contaminacion del aire urbano en cuatro museos de Argentina Type H3 Book chapter
  Year 2013 Publication Abbreviated Journal  
  Volume Issue Pages 271-282 T2 - Patrimonio cultural : la gestion, el  
  Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-987-1323-31-9 Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:110908 Serial 7936  
Permanent link to this record
 

 
Author de Nolf, W. url  openurl
  Title Imaging of crystalline phase distributions by means of scanning and tomographic X-ray powder diffraction Type Doctoral thesis
  Year 2013 Publication Abbreviated Journal  
  Volume Issue Pages 407 p.  
  Keywords Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:110910 Serial 8057  
Permanent link to this record
 

 
Author Janssens, K.; Degryse, P.; Cosyns, P.; Caen, J.; Van 't dack, L. isbn  openurl
  Title Annales of the 17th Congress of the International Association for the History of Glass (Antwerp, Belgium, 2006) Type ME2 Book as editor or co-editor
  Year 2009 Publication Abbreviated Journal  
  Volume Issue Pages 704 p.  
  Keywords ME2 Book as editor or co-editor; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-90-5487-618-2 Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved Most recent IF: NA  
  Call Number (up) UA @ admin @ c:irua:110922 Serial 5473  
Permanent link to this record
 

 
Author Gielis, J.; Tavkhelidze, I.; Ricci, P.E. pdf  doi
openurl 
  Title About “bulky” links generated by generalized Möbius-Listing bodies GML2n Type A2 Journal article
  Year 2013 Publication Journal of mathematical sciences Abbreviated Journal  
  Volume 193 Issue 3 Pages 449-460  
  Keywords A2 Journal article; Sustainable Energy, Air and Water Technology (DuEL)  
  Abstract In this paper, we consider the bulky knots and bulky links, which appear after cutting of a Generalized MöbiusListing GMLn2 body (with the radial cross section a convex plane 2-symmetric figure with two vertices) along a different Generalized MöbiusListing surfaces GMLn2 situated in it. The aim of this report is to investigate the number and geometric structure of the independent objects that appear after such a cutting process of GMLn2 bodies. In most cases we are able to count the indices of the resulting mathematical objects according to the known classification for the standard knots and links.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2013-08-03  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1072-3374; 1573-8795 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:110953 Serial 7404  
Permanent link to this record
 

 
Author Bia, P.; Caratelli, D.; Mescia, L.; Gielis, J. isbn  openurl
  Title Electromagnetic characterization of supershaped lens antennas for high-frequency applications Type H1 Book chapter
  Year 2013 Publication Abbreviated Journal  
  Volume Issue Pages 1679-1682 T2 - Proceedings of the 43rd European Mi  
  Keywords H1 Book chapter; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000330768700424 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-2-87487-031-6 Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:110954 Serial 7865  
Permanent link to this record
 

 
Author Gielis, J.; Caratelli, D.; Tavkelidze, I.; Fougerolle, Y.; Ricci, P.E.; Gerats, T. isbn  openurl
  Title Bulky knots and links generated by cutting generalized Mobius-Listing bodies and applications in the natural sciences Type H2 Book chapter
  Year 2013 Publication Abbreviated Journal  
  Volume Issue Pages 167-183 T2 - Math Art Summit : Koninklijke Vlaamse  
  Keywords H2 Book chapter; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-90-6569-119-4 Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:110955 Serial 7569  
Permanent link to this record
 

 
Author Godoi, R.H.M.; Godoi, A.F.L.; de Quadros, L.C.; Polezer, G.; Silva, T.O.B.; Yamamoto, C.I.; Van Grieken, R.; Potgieter-Vermaak, S. pdf  doi
openurl 
  Title Risk assessment and spatial chemical variability of PM collected at selected bus stations Type A1 Journal article
  Year 2013 Publication Air quality, atmosphere & health Abbreviated Journal  
  Volume Issue Pages 1-11  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The chemical characterization of particulate matter inside and outside of confined bus shelters has been discerned for the first time. Transit patrons are at risk due to the close vicinity of densely trafficked areas resulting in elevated pollution footprints. Incomplete combustion processes, as well as exhaust and wear and tear emissions from public and personal transportation vehicles, are key contributors to degraded urban air quality and are often implicated as causal to various diseases in humans. Urban planning, therefore, includes efficient public transport systems to mitigate the effect. The bus rapid transit system was inaugurated in Curitiba to ensure dedicated traffic lanes, major bus interchanges and semi-confined bus stops called tube stations. To assess the chemical risk that the passengers are exposed to, an investigation of the aerosol inside and outside five of these tube stations was launched. Electron probe X-ray micro-analysis and X-ray fluorescence were used to determine the elemental composition of individual and of bulk particle samples. An aethalometer quantified the black carbon. Elemental concentrations inside the shelters were in general higher than outside, especially for traffic-related elements. The lead concentration exceeded the NAAS standard at times, although the average was below the guideline. The biogenic, organic and soot clusters showed the highest abundance for the city centre sites. The overall carcinogenic risk could be classed as moderate, and the risk was significant at two sites during one of the sampling campaigns. The non-carcinogenic risk is well below the significant value.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000328332500006 Publication Date 2013-11-01  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1873-9318 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111086 Serial 8484  
Permanent link to this record
 

 
Author de Baerdemaeker, T.; Lemmens, B.; Dotremont, C.; Fret, J.; Roef, L.; Goiris, K.; Diels, L. pdf  doi
openurl 
  Title Benchmark study on algae harvesting with backwashable submerged flat panel membranes Type A1 Journal article
  Year 2013 Publication Bioresource technology Abbreviated Journal  
  Volume 129 Issue Pages 582-591  
  Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)  
  Abstract The feasibility of algae harvesting with submerged flat panel membranes was investigated as pre-concentration step prior to centrifugation. Polishing of the supernatant coming from the centrifuge was evaluated as well. The effect of membrane polymer (polyvinyl chloride [PVC], polyethersulfone polyvinyl-pyrollidone [PES-PVP], poly vinylidene fluoride [PVDF]), pore size (microfiltration [MF], ultrafiltration [UF]), algae cell concentrations and species were investigated at lab-scale. In addition, backwashing as fouling control was compared to standard relaxation. PVDF was the superior polymer, and UF showed better fouling resistance. Backwashing outperformed relaxation in fouling control. The backwashable membranes allowed up to 300% higher fluxes compared to commercial flat panel benchmark (PVC) membranes. Estimations on energy consumption for membrane filtration followed by centrifugation revealed relatively low values of 0.169 kW h/kg of dry weight of algae compared to 0.5 kW h/kg for algae harvesting via classical centrifuge alone. (C) 2012 Elsevier Ltd. All rights reserved.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000324566000079 Publication Date 2012-11-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0960-8524 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111203 Serial 7554  
Permanent link to this record
 

 
Author Pilehvar, S.; Rather, J.A.; Dardenne, F.; Robbens, J.; Blust, R.; De Wael, K. pdf  doi
openurl 
  Title Carbon nanotubes based electrochemical aptasensing platform for the detection of hydroxylated polychlorinated biphenyl in human blood serum Type A1 Journal article
  Year 2014 Publication Biosensors and bioelectronics Abbreviated Journal Biosens Bioelectron  
  Volume 54 Issue Pages 78-84  
  Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract A novel strategy to sense target molecules in human blood serum is achieved by immobilizing aptamers (APTs) on multiwalled carbon nanotubes (MWCNT) modified electrodes. In this work, the aminated aptamer selected for hydroxylated polychlorinated biphenyl (OHPCB) was covalently immobilized on the surface of the MWCNTCOOH modified glassy carbon electrode through amide linkage. The aptamers function as recognition probes for OHPCB by the binding induced folding of the aptamer. The developed aptasensing device was characterized by Electrochemical Impedance Spectroscopy (EIS), Atomic Force Microscopy (AFM) and Fourier Transform Infrared Spectroscopy (FTIR). The aptasensor displayed excellent performance for OHPCB detection with a linear range from 0.16 to 7.5 μM. The sensitivity of the developed aptasensing platform is improved (1×10−8 M) compared to the published report (1×10−6 M) for the determination of OH-PCB (Turner et al., 2007). The better performance of the sensor is due to the unique platform, i.e. the presence of APTs onto electrodes and the combination with nanomaterials. The aptamer density on the electrode surface was estimated by chronocoulometry and was found to be 1.4×1013 molecules cm−2. The validity of the method and applicability of the aptasensor was successfully evaluated by the detection of OHPCB in a blood serum sample. The described approach for aptasensing opens up new perspectives in the field of biomonitoring providing a device with acceptable stability, high sensitivity, good accuracy and precision.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000333071500012 Publication Date 2013-11-01  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0956-5663 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 7.78 Times cited 40 Open Access  
  Notes ; We are thankful to UA-DOCPRO and BELSPO for financial support (respectively S. Pilehvar and J. Ahmad Rather). We also thank Prof. A. Covaci (UA) for the kind gift of human blood serum samples. Special thanks to Prof. L Van Vaeck and Y. Vercammen (UA) for AFM imaging and Prof. V. Meynen and M. Kus (LADCA, UA) for performing IR measurements. ; Approved Most recent IF: 7.78; 2014 IF: 6.409  
  Call Number (up) UA @ admin @ c:irua:111262 Serial 5495  
Permanent link to this record
 

 
Author De Wael, K.; Nagels, L.; Van Camp, G. openurl 
  Title Potentiometric sensors and method for measuring intermolecular interactions Type Patent
  Year 2013 Publication Abbreviated Journal  
  Volume Issue Pages  
  Keywords Patent; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved Most recent IF: NA  
  Call Number (up) UA @ admin @ c:irua:111264 Serial 5779  
Permanent link to this record
 

 
Author Anaf, W.; Janssens, K.; De Wael, K. pdf  doi
openurl 
  Title Formation of metallic mercury during photodegradation/photodarkening of \alpha-HgS : electrochemical evidence Type A1 Journal article
  Year 2013 Publication Angewandte Chemie: international edition in English Abbreviated Journal Angew Chem Int Edit  
  Volume 52 Issue 48 Pages 12568-12571  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Das rote Pigment α-HgS neigt in Gegenwart von Licht und Chloridionen zur Schwärzung. Als Grund für die Zersetzung und Entfärbung werden die Bildung von (schwarzem) β-HgS oder Quecksilbermetall vermutet, doch diese Substanzen wurden noch nicht auf natürlich oder künstlich zersetzter HgS-Farbe nachgewiesen. Elektrochemische Experimente belegen nun die Bildung von Quecksilbermetall in Gegenwart von Licht und Chloridionen.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000327582900015 Publication Date 2013-10-04  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1433-7851; 0570-0833 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 11.994 Times cited 19 Open Access  
  Notes ; The authors acknowledge L. Klaassen for valuable discussions and providing samples. We acknowledge financial support from the SDD programme (S2-ART project) of the Belgian Federal Goverment. ; Approved Most recent IF: 11.994; 2013 IF: 11.336  
  Call Number (up) UA @ admin @ c:irua:111265 Serial 5626  
Permanent link to this record
 

 
Author Cardell, C.; Urosevic, M.; Sebastián-Pardo, E.; Horemans, B.; Kontozova-Deutsch, V.; Potgieter-Vermaak, S.; Bencs, L.; Anaf, K.W.; De Wael, K.; Van Grieken, R. isbn  openurl
  Title Risks of atmospheric aerosol for cultural heritage assets in Granada (Spain) Type H1 Book chapter
  Year 2013 Publication Abbreviated Journal  
  Volume Issue Pages 45-49  
  Keywords H1 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN 978-1-138-00009-4 Additional Links UA library record; WoS full record  
  Impact Factor Times cited Open Access  
  Notes ; The authors thank the 'Patronato de la Alhambra y Generalife' and the CEAMA. Financial support was provided by Andalusian Research Groups RNM-179 and Project CGL2012-30729. ; Approved Most recent IF: NA  
  Call Number (up) UA @ admin @ c:irua:111266 Serial 5819  
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Author Satyawali, Y.; Van Roy, S.; Roevens, A.; Meynen, V.; Mullens, S.; Jochems, P.; Doyen, W.; Cauwenberghs, L.; Dejonghe, W. pdf  doi
openurl 
  Title Characterization and analysis of the adsorption immobilization mechanism of \beta-galactosidase on metal oxide powders Type A1 Journal article
  Year 2013 Publication RSC advances Abbreviated Journal  
  Volume 3 Issue 46 Pages 24054-24062  
  Keywords A1 Journal article; Laboratory of adsorption and catalysis (LADCA); Sustainable Energy, Air and Water Technology (DuEL)  
  Abstract Immobilization of the enzymes plays a vital role in enhancing their applicability in a wide range of applications, thus ensuring the use of sustainable enzymatic processes over the conventional chemical processes on an industrial scale. This study provides the background information for the selection and screening of inorganic metal oxide (MO) powders for their use as fillers in mixed matrix membranes for enzyme immobilization as the future aim. A total of 13 MOs, ranging in size from 0.01 μm to <5 μm, were tested for their performance as a support for enzyme (β-galactosidase) immobilization via adsorption. Alumina appeared to be the best performing MO with the amount and activity of the immobilized enzyme being 64 mg g−1 and up to 288 U g−1, respectively. The amount of immobilized enzyme on alumina (α-Al2O3 C and γ-Al2O3) was >3 times higher than ZrO2 (used as a reference MO in this study). Upon heat treatment at 900 °C, up to 15%, 52% and 42% decline was observed in the amount of immobilized enzyme in case of alumina metal oxides (MOs), ZrO2 and TiO2, respectively. The results suggested that both isoelectric point and surface area of the MO influence the immobilization. The most important observation in this study was that the bonding of the enzyme to the MO surface seems to be mediated by the bonding/interaction of the buffer to the enzyme.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000326745100030 Publication Date 2013-10-11  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 2046-2069 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111300 Serial 7607  
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Author Janssens, K.; Alfeld, M.; van der Snickt, G.; de Nolf, W.; Vanmeert, F.; Radepont, M.; Monico, L.; et al. doi  openurl
  Title The use of synchrotron radiation for the characterization of artists' pigments and paintings Type A1 Journal article
  Year 2013 Publication Annual review of analytical chemistry Abbreviated Journal Annu Rev Anal Chem  
  Volume 6 Issue Pages 399-425  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract We review methods and recent studies in which macroscopic to (sub)microscopic X-ray beams were used for nondestructive analysis and characterization of pigments, paint microsamples, and/or entire paintings. We discuss the use of portable laboratory- and synchrotron-based instrumentation and describe several variants of X-ray fluorescence (XRF) analysis used for elemental analysis and imaging and combined with X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS). Macroscopic and microscopic (μ-)XRF variants of this method are suitable for visualizing the elemental distribution of key elements in paint multilayers. Technical innovations such as multielement, large-area XRF detectors have enabled such developments. The use of methods limited to elemental analysis or imaging usually is not sufficient to elucidate the chemical transformations that take place during natural pigment alteration processes. However, synchrotron-based combinations of μ-XRF, μ-XAS, and μ-XRD are suitable for such studies.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000323887500019 Publication Date 2013-06-18  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1936-1327 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 7.435 Times cited 46 Open Access  
  Notes ; ; Approved Most recent IF: 7.435; 2013 IF: 7.814  
  Call Number (up) UA @ admin @ c:irua:111315 Serial 5902  
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Author Meulebroeck, W.; Baert, K.; Wouters, H.; Cosyns, P.; Ceglia, A.; Cagno, S.; Janssens, K.; Nys, K.; Terryn, H.; Thienpont, H. doi  openurl
  Title The identification of chromophores in ancient glass by the use of UV-VIS-NIR spectroscopy Type A1 Journal article
  Year 2010 Publication Proceedings of the Society of Photo-optical Instrumentation Engineers Abbreviated Journal  
  Volume 7726 Issue Pages 77260d-12  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract In this publication optical spectroscopy is considered to be a supplementary technique to study ancient colored glass. It results from a systematic study of the UV-VIS-NIR transmission spectra of intentionally colored glass fragments from various archaeological and historical sites and dated from the Roman period to the 21th century AD. The main goal consists of defining optical sensing parameters for this type of material. The considered colorants are iron, cobalt, manganese, copper and chromium. It is proved that many cases exist where optical spectroscopy can be seen as a straightforward, non-destructive, low-cost and in-situ applicable technique in identifying authentic material or to obtain information about the origin of the material. Possible sensing parameters are defined as the absence/presence of absorption bands characteristic for a specific coloring metal oxide and the spectral position of these bands. These parameters could reveal information about the applied furnace conditions and/or to the composition of the glass matrix. It is shown that the cobalt absorption band situated around 535 nm for soda rich glasses (Roman and industrial times) is shifted towards 526 nm for potash rich glasses (medieval and post-medieval times).  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000285287900011 Publication Date 2010-04-29  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0277-786x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited 10 Open Access  
  Notes ; ; Approved Most recent IF: NA  
  Call Number (up) UA @ admin @ c:irua:111316 Serial 5650  
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Author Falkenberg, G.; Fleissner, G.E.; Fleissner, G.U.E.; Schuchardt, K.; Kühbacher, M.; Chalmin, E.; Janssens, K. url  doi
openurl 
  Title High resolution micro-XRF maps of iron oxides inside sensory dendrites of putative avian magnetoreceptors Type A1 Journal article
  Year 2009 Publication Journal of physics : conference series Abbreviated Journal  
  Volume 186 Issue 1 Pages 012084-3  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Iron mineral containing sensory dendrites in the inner lining of the upper beak of homing pigeons [1] and various bird species [2] are the first candidate structures for an avian magnetic field receptor. A new concept of magnetoreception [3, 4] is based on detailed ultra-structural optical and electron microscopy analyses in combination with synchrotron radiation microscopic X-ray fluorescence analysis (micro-XRF) and microscopic X-ray absorption near edge structures (micro-XANES). Several behavioral experiments [5, 6] and first mathematical simulations [6] affirm our avian magnetoreceptor model. The iron minerals inside the dendrites are housed in three different subcellular compartments (bullets, platelets, vesicles), which could be clearly resolved and identified by electron microscopy on ultrathin sections [1, 3]. Micro-XRF and micro-XANES data obtained at HASYLAB beamline L added information about the elemental distribution and Fe speciation [3], but are averaged over the complete dendrite due to limited spatial resolution. Here we present recently performed micro-XRF maps with sub-micrometer resolution (ESRF ID21), which reveal for the first time subcellular structural information from almost bulk-like dendrite sample material. Due to the thickness of 30 μm the microarchitecture of the dendrites can be considered as undisturbed and artefacts introduced by sectioning might be widely reduced.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000282023900084 Publication Date 2009-09-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1742-6588; 1742-6596 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited 2 Open Access  
  Notes Approved Most recent IF: NA  
  Call Number (up) UA @ admin @ c:irua:111317 Serial 5642  
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Author Alfeld, M.W. openurl 
  Title Development of scanning macr-XRF for the investigation of historical paintings Type Doctoral thesis
  Year 2013 Publication Abbreviated Journal  
  Volume Issue Pages 264 p.  
  Keywords Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111339 Serial 7803  
Permanent link to this record
 

 
Author Van Grieken, R.; Van 't dack, L.; Costa Dantas, C.; Da Silveira Dantas, H. pdf  doi
openurl 
  Title Soil analysis by thin-film energy-dispersive X-ray fluorescence Type A1 Journal article
  Year 1979 Publication Analytica chimica acta Abbreviated Journal  
  Volume 108 Issue Pages 93-101  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Energy-dispersive x-ray fluorescence is advantageous for trace analysis of soils present as thin films. A target thickness of about 2 mg cm-2 provides a compromise between optimal sensitivity and minimal absorption effect or optimal accuracy. Sample preparation involves only suspending the finely ground soil in water and drying this suspension on a thin mylar foil glued on a ring that fits into the x.r.f. spectrometer. The effective sample weight present in the exciting beam area is computed from the scatter peaks, a method that cancels out target heterogeneity problems. High accuracy is demonstrated for many elements in reference soil and rock materials; a precision around 5% and a detection limit around 10 ppm can be achieved. As an illustration, results for 16 trace elements and preliminary interpretation are given for a series of pedologically important soil samples from Brasil.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1979HL44100012 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111402 Serial 8549  
Permanent link to this record
 

 
Author van Espen, P.; Van 't dack, L.; Adams, F.; Van Grieken, R. doi  openurl
  Title Effective sample weight from scatter peaks in energy-dispersive x-ray fluorescence Type A1 Journal article
  Year 1979 Publication Analytical chemistry Abbreviated Journal  
  Volume 51 Issue 7 Pages 961-967  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1979GW66100047 Publication Date 2005-03-16  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111404 Serial 7841  
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Author Costa Dantas, C.; Moura de Amorim, W.; Van 't dack, L.; Van Grieken, R. openurl 
  Title Trace elements in the atmospheric aerosols and soils in and around Recife, N.E. Brasil Type A3 Journal article
  Year 1980 Publication Ciencia e cultura Abbreviated Journal  
  Volume 32 Issue Pages 1525-1532  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0009-6725 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111434 Serial 8690  
Permanent link to this record
 

 
Author Costa Dantas, C.; Da Silveira Dantas, H.; Van 't dack, L.; Van Grieken, R. openurl 
  Title Analise de solos por meio de fluorescencia de raios-X nao-dispersiva Type A1 Journal article
  Year 1981 Publication Química nova Abbreviated Journal  
  Volume 4 Issue Pages 110-116  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0100-4042; 1678-7064 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111435 Serial 7438  
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Author Van Grieken, R.; Van 't dack, L.; Costa Dantas, C.; Moura de Amorim, W.; Maenhaut, W. pdf  doi
openurl 
  Title Elemental constituents of atmospheric aerosols in Recife, North-East Brazil Type A3 Journal article
  Year 1982 Publication Environmental pollution: series B : chemical and physical Abbreviated Journal  
  Volume 4 Issue 2 Pages 143-163  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Few data are available on the inorganic atmospheric pollution in the rapidly expanding cities of South America, like Recife, on the Atlantic Coast of North-east Brazil. Therefore, the elemental composition of atmospheric aerosols was investigated for nine sites in the Recife conurbation and a fairly remote site in the area. Total aerosol samples were collected on cellulose filters for analysis by energy dispersive X-ray fluorescence and cascade impactors were used to collect the aerosols as a function of particle size for subsequent analysis by proton-induced X-ray emission. Local soil aliquots were also analysed. About eighteen elements were quantified in all cases. The average total atmospheric concentrations appeared to be well above natural levels but usually lower than, or comparable with, those of North American and European cities. Dispersal of sea spray and of local soil (often contaminated with, for example, Cu, Zn and Pb from industrial sources) contributes predominantly to the total atmospheric load in Recife. However, the particle size fraction results also indicated strong excesses in the small particle mode for S, K, V, Mn, Ni, Cu, Zn, Br and Pb, mainly in the downtown area. Again, the corresponding enrichment factors were only moderate in comparison with other published urban data.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2003-09-11  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0143-148x; 1878-0695 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111437 Serial 7894  
Permanent link to this record
 

 
Author Malenky, B.; Van Grieken, R.; Van 't dack, L.; Luria, M. pdf  doi
openurl 
  Title Atmospheric trace element concentrations in Jerusalem, Israel Type A1 Journal article
  Year 1983 Publication Atmospheric environment Abbreviated Journal  
  Volume 17 Issue 4 Pages 819-822  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Trace elements found in aerosols were monitored in Jerusalem during the 1979 winter season utilizing an X-ray fluoresence technique. Most of the particulate mass was associated with the natural soil elements, such as Ca, Fe, K and Ti. Only a small fraction of the mass was comprised of elements clearly emitted from human sources, e.g. Pb, Br, V, Ni and Zn. An excellent correspondence was found between the enrichment factors observed in this study and those postulated for other parts of the world. However, the concentration of Ca and Sr in the Jerusalem suspended dust is substantially higher when compared with world averages of urban aerosols.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1983QS29300018 Publication Date 2003-08-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1352-2310 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number (up) UA @ admin @ c:irua:111438 Serial 7532  
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