%&LaTeX
\documentclass{article}

\usepackage[utf8]{inputenc}
\usepackage[T1]{fontenc}
\usepackage{textcomp}

\begin{document}

\begin{thebibliography}{1}

\bibitem{Palacios_etal2013} {\textquotedblleft}\textit{Characterization of black volcanites from the Limay river basin, Patagonia, Argentina, using energy dispersive X-ray fluorescence spectrometry : an aid to infer human group mobility}{\textquotedblright}. Palacios OM, van Meel K, Van Grieken R, Marc{\'o} P L-M, V{\'a}zquez C, Journal of radioanalytical and nuclear chemistry \textbf{298}, 1245 (2013).   http://doi.org/10.1007/S10967-013-2600-1

\end{thebibliography}

\end{document}

