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Records |
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Author |
Török, S.; Van Dyck, P.; Van Grieken, R. |
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Title |
Heterogeneity effects in direct X-ray fluorescence analysis of hair |
Type |
A1 Journal article |
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Year |
1984 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
13 |
Issue |
1 |
Pages |
27-32 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The methodology of direct hair analysis by energy-dispersive x-ray fluorescence was studied. The effect on the XRF result of having a non-homogeneous radial distribution of the analyte in a single hair strand and the macroscopic effects in a bundle of hairs were calculated to evaluate possible systematic errors. The detection limits were mapped as a function of the target thickness and surface fraction. It appeared that a 10 mg cm−2 sample thickness, i. e. a target with about four layers of hair strands, is recommended. The standard deviation of this simple direct analytical method is 619% for some important elements. Discrepancies with neutron activation analysis had a mean value of around 15%. About twelve elements can be determined simultaneously on a routine basis. |
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Wos |
A1984SB70200004 |
Publication Date |
2005-05-28 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
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UA library record; WoS full record; WoS citing articles |
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no |
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Call Number |
UA @ admin @ c:irua:116485 |
Serial |
8029 |
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Permanent link to this record |
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Author |
Roekens, E.J.; Van Grieken, R.E. |
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Title |
Kinetics of iron(II) oxidation in seawater of various pH |
Type |
A1 Journal article |
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Year |
1983 |
Publication |
Marine chemistry |
Abbreviated Journal |
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Volume |
13 |
Issue |
3 |
Pages |
195-202 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The rate of iron(II) oxidation in North Sea water of pH 5.510 in the range 1025°C has been studied. The oxygenation rate depends linearly on the iron(II) and dissolved oxygen concentrations. The second-order dependence on [OH−], found by several investigators for synthetic solutions, was confirmed in seawater, but only for pOH > 6.9. For pOH < 5.9 the rate appeared to be independent of the pOH. In the intermediate range, pOH 5.96.9, corresponding to the natural pH of seawater, a first-order dependence on the pOH is obeyed. The important discrepancy in the literature between the second-order rate constant for NaCHO3 solutions and for seawater can be attributed predominantly to the incorrect assumption of a second-order pOH dependence in natural seawater. The results can be useful, for example, in predicting the effect of dumping acidic iron waste from the titanium-dioxide industry into the ocean. |
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Wos |
A1983RD52600003 |
Publication Date |
2003-08-08 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0304-4203; 1872-7581 |
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UA library record; WoS full record; WoS citing articles |
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no |
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Call Number |
UA @ admin @ c:irua:116695 |
Serial |
8140 |
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Author |
Cataldo, M.; Evangelista, H.; Simões, J.C.; Godoi, R.H.M.; Simmonds, I.; Hollanda, M.H.; Wainer, I.; Aquino, F.; Van Grieken, R. |
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Title |
Mineral dust variability in central West Antarctica associated with ozone depletion |
Type |
A1 Journal article |
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Year |
2013 |
Publication |
Atmospheric chemistry and physics |
Abbreviated Journal |
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Volume |
13 |
Issue |
4 |
Pages |
2165-2175 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
We present here data of mineral dust variability retrieved from an ice core of the central West Antarctic, spanning the last five decades. Main evidence provided by the geochemical analysis is that northerly air mass incursions to the coring site, tracked by insoluble dust microparticles, have declined over the past 50 yr. This result contrasts with dust records from ice cores reported to the coastal West Antarctic that show increases since mid-20th century. We attribute this difference to regional climatic changes due to the ozone depletion and its implications to westerly winds. We found that the diameters of insoluble microparticles in the central West Antarctica ice core are significantly correlated with cyclone depth (energy) and wind intensity around Antarctica. |
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Wos |
000315406600027 |
Publication Date |
2013-02-25 |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1680-7316; 1680-7324 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Times cited |
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Open Access |
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no |
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Call Number |
UA @ admin @ c:irua:105832 |
Serial |
8250 |
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Permanent link to this record |
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Author |
Verbueken, A.H.; van de Vijver, F.L.; Visser, W.J.; Roels, F.; Van Grieken, R.; de Broe, M.E. |
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Title |
Use of laser microprobe mass analysis (LAMMA) for localizing multiple elements in soft and hard tissues |
Type |
A1 Journal article |
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Year |
1987 |
Publication |
Biological trace element research |
Abbreviated Journal |
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Volume |
13 |
Issue |
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Pages |
397-416 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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Abstract |
The potential of laser microprobe mass analysis (LAMMA) as a sensitive microanalytical technique was explored in applications relevant to nephrology. Aluminum and associated elements, such as iron, were localized in fresh tissue biopsies obtained from uremic patients treatment by chronic hemodialysis. The LAMMA was applied to serum, liver, bone, and parathyroid glands of such patients. In addition, we used LAMMA to evaluate the specificity and sensitivity of routine histochemistry, in particular on human bone sections stained by the aluminon method. The high, multielemental sensitivity and molecular microprobe potential of LAMMA established important advantages over other microchemical methods forin situ analysis at the micron level in histological sections. |
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Wos |
A1987L016000036 |
Publication Date |
2007-12-31 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0163-4984 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Open Access |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116796 |
Serial |
8721 |
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Permanent link to this record |
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Author |
Padilla, R.; Janssens, K.; van Espen, P.; Van Grieken, R. |
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Title |
XRS activities at the Micro & Trace Analysis Centre (MiTAC), University of Antwerp, Belgium |
Type |
A3 Journal article |
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Year |
2006 |
Publication |
IAEA XRF newsletter |
Abbreviated Journal |
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Volume |
12 |
Issue |
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Pages |
13-16 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
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Additional Links |
UA library record |
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Times cited |
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Open Access |
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Notes |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:65080 |
Serial |
5921 |
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Permanent link to this record |
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Author |
Van Dyck, P.; Van Grieken, R. |
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Title |
Automated matrix-correction of line ratios in energy-dispersive x-ray fluorescence spectrum deconvolution |
Type |
A1 Journal article |
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Year |
1983 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
12 |
Issue |
3 |
Pages |
111-114 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Most computer XRF-spectrum deconvolution routines make use of fixed intensity ratios for the lines from one element. The magnitude of the error that fixed ratios imply has been quantitatively evaluated for samples with a varible thickness or matrix. A procedure for routinely adapting the line ratios according to the matrix effect in every sample (by making use of the matrix information present in the scatter peaks) enhances the accuracy of the spectrum evaluation. |
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Wos |
A1983RA69700004 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116484 |
Serial |
7539 |
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Permanent link to this record |
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Author |
Verbueken, A.H.; Bruynseels, F.J.; Van Grieken, R.E. |
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Title |
Laser microprobe mass analysis : a review of applications in the life sciences |
Type |
A3 Journal article |
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Year |
1985 |
Publication |
Biomedical mass spectrometry |
Abbreviated Journal |
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Volume |
12 |
Issue |
9 |
Pages |
438-463 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The characteristics and analytical utility of laser microprobe mass analysis (LAMMA) are described and evaluated, and a short history of this recent microanalytical technique is presented. A review of the areas of application of LAMMA and related laser microprobes is presented with special emphasis on applications in the life sciences. |
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Place of Publication |
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Wos |
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Publication Date |
2005-05-31 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0306-042x |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116722 |
Serial |
8153 |
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Permanent link to this record |
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Author |
Sholkovitz, E.R.; Van Grieken, R.; Eisma, D. |
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Title |
The major-element composition of suspended matter in the Zaire river and estuary |
Type |
A1 Journal article |
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Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
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Volume |
12 |
Issue |
3/4 |
Pages |
407-413 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
2003-08-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0077-7579; 1873-1406 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116608 |
Serial |
8195 |
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Permanent link to this record |
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Author |
Cataldo,.; Evangelista, H.; Simões, J.C.; Godoi, R.H.M.; Simmonds, I.; Hollanda, M.H.; Wainer, I.; Aquino, F.E.; Van Grieken, R. |
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Title |
Mineral dust variability in central West Antarctica associated with ozone depletion |
Type |
A1 Journal article |
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Year |
2012 |
Publication |
Atmospheric chemistry and physics discussions |
Abbreviated Journal |
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Volume |
12 |
Issue |
5 |
Pages |
12685-12714 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Here we show that mineral dust retrieved from an ice core in the central West Antarctic sector, spanning the last five decades, provides evidence that northerly air mass incursions into Antarctica, tracked by dust microparticles, have slightly declined. This result contrasts with dust in ice core records reported in West/coastal Antarctica, which show significant increases to the present day. We attribute that difference, in part, to changes in the regional climate regime triggered by the ozone depletion and its consequences for the polar vortex intensity. The vortex maintains the Antarctic central region relatively isolated from mid-latitude air mass incursions with implications to the intensification of the Westerlies and to a persistent positive phase of the Southern Annular Mode. We also show that variability of the diameter of insoluble microparticles in central West Antarctica can be modeled by linear/quadratic functions of both cyclone depth (energy) and wind intensity around Antarctica. |
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Wos |
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Publication Date |
2012-05-21 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1680-7367 |
ISBN |
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Additional Links |
UA library record |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:102568 |
Serial |
8251 |
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Permanent link to this record |
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Author |
Schelles, W.; Van Grieken, R. |
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Title |
Quantitative analysis of zirconium oxide by direct glow discharge mass spectrometry using a secondary cathode |
Type |
A1 Journal article |
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Year |
1997 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
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Volume |
12 |
Issue |
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Pages |
49-52 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0267-9477 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:18774 |
Serial |
8439 |
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Permanent link to this record |
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Author |
Martin, J.-M.; Thomas, A.J.; Van Grieken, R.E. |
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Title |
Trace element composition of Zaire suspended sediments |
Type |
A1 Journal article |
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Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
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Volume |
12 |
Issue |
3/4 |
Pages |
414-420 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
2003-08-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0077-7579; 1873-1406 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116609 |
Serial |
8688 |
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Permanent link to this record |
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Author |
Hellar-Kihampa, H.; De Wael, K.; Lugwisha, E.; Van Grieken, R. |
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Title |
Water quality assessment in Pangani river basin, Tanzania : natural and anthropogenic influences on concentrations of nutrients and inorganic ions |
Type |
A1 Journal article |
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Year |
2013 |
Publication |
International journal of river basin management |
Abbreviated Journal |
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Volume |
11 |
Issue |
1 |
Pages |
55-75 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The ongoing rapid expansions of human activities and population dynamics have potential impact on the environmental quality of the Pangani river basin, one of the largest water resources in Tanzania, including possible loadings of different kinds of micro-contaminants. However, specific extents of the impacts are rather not well investigated. In this work, we assessed the environmental quality of the basin, based on seasonal characterisation of physicochemical water and sediments parameters, dissolved inorganic ions and nutrient loads. The contributions of geochemical processes and land-use practices were evaluated by multivariate correlations and principal component analysis (PCA). Hierarchical cluster analysis was used to classify similar water quality stations and identify the most and least enriched ones. Surface waters were slightly alkaline, characterised by low total dissolved solids (48652 mg/L). Extremely low oxygen concentration (2.0 mg/L) was also a cause of concern at one station. The Na+ and HCO3 − ions provided the dominant cation and anion, respectively. PCA identified weathering of carbonate and Na+ bearing rocks, gypsum dissolution and atmospheric deposition of sea-salt as the major factors controlling the ionic composition, contributing more than 60% of the spatial variance. Concentration profiles of the chemical species showed a generally low level of anthropogenic inputs, except at a few locations where nitrate and nitrite were significantly enriched above the limits of safe exposure, with patterns indicating influences of farming and livestock keeping. A seasonal difference was observed, with lower ion concentrations during the rainy season, likely due to the dilution effect of increased water discharge. The study provides new insights into the environmental quality of the basin, and indicates the need for continuous monitoring and assessment of the chemical species in the area. |
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Place of Publication |
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Wos |
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Publication Date |
2013-01-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1571-5124 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:104621 |
Serial |
5909 |
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Permanent link to this record |
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Author |
Chakravorty, R.; Van Grieken, R. |
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Title |
Co-precipitation with iron hydroxide and X-ray fluorescence analysis of trace metals in water |
Type |
A1 Journal article |
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Year |
1982 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
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Volume |
11 |
Issue |
1 |
Pages |
67-80 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Preconcentration of transition trace ions by coprecipitation on iron-hydroxide has been combined with energy-dispersive X-ray fluorescence for environmental water analysis. The optimized preconcentration procedure implies adding 2 mg of iron to a 200 ml water sample, adding dilute NaOH up to pH 9, filtering off on a Nuclepore membrane after a 1 h equilibration time, and analyzing. Quantitative recoveries could then be obtained for Ni, Cu, Zn and Pb, e.g. at the 10 μg/l level in waters of varying salinity while Mn was partially collected. (In fact, for a given problem the iron carrier amount can be adjusted to obtain a satisfactory compromise between high recovery and low detection limit). The precision is 7-8% at the 10 μg/l level, and the detection limits are in the 0.5-1 μg/l range. Various environmental water samples are analysed by way of illustration. |
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Place of Publication |
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Language |
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Wos |
A1982NG99200007 |
Publication Date |
2007-07-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0306-7319 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116573 |
Serial |
7676 |
|
Permanent link to this record |
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Author |
Verbueken, A.H.; Van Grieken, R.E.; Paulus, G.J.; Verpooten, G.A.; de Broe, M.E. |
|
|
Title |
Laser microprobe mass spectrometry of platinum in dog kidney after cisplatin adminstration |
Type |
A3 Journal article |
|
Year |
1984 |
Publication |
Biomedical mass spectrometry |
Abbreviated Journal |
|
|
|
Volume |
11 |
Issue |
4 |
Pages |
159-163 |
|
|
Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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|
Abstract |
By means of laser microprobe mass analysis (LAMMA) platinum was detected in the renal proximal tubular cells of a dog that had been intravenously adminstered the antitumor drug cisplatin (5 mg per kg body weight). No definite subcellular localization of the heavy metal was obtained. Sample prparation and analytical features are examined to increase spatial resolution of analysis while maintaining sufficient detection efficiency. The LAMMA method is destructive, but the amount and type of evaporated material can readily be determined when using LAMMA in combination with transmission electron microscopy. Instrumental optimization and standardization of mass signals is possible by using platinum-loaded, ion chelating resin beads embedded and sectioned with the tissue. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
|
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0306-042x |
ISBN |
|
Additional Links |
UA library record |
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Impact Factor |
|
Times cited |
|
Open Access |
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Notes |
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Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:116712 |
Serial |
8165 |
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Permanent link to this record |
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|
|
Author |
Horemans, B.; Krata, A.; Buczyńska, A.J.; Dirtu, A.C.; van Meel, K.; Van Grieken, R.; Bencs, L. |
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|
Title |
Major ionic species in size-segregated aerosols and associated gaseous pollutants at a coastal site on the Belgian North Sea |
Type |
A1 Journal article |
|
Year |
2009 |
Publication |
Journal of environmental monitoring |
Abbreviated Journal |
|
|
|
Volume |
11 |
Issue |
3 |
Pages |
670-677 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
The chemical composition of airborne particulate matter (PM) was studied at a coastal region near De Haan, Belgium, during a winterspring and a summer campaign in 2006. The major ionic components of size-segregated PM, i.e. NH4+, Na+, K+, Mg2+, Ca2+, Cl-, NO3-, and SO42-, and related gaseous pollutants (SO2, NO2, NH3, HNO2, and HNO3) were monitored on a daily basis. Air mass backward-trajectories aided in evaluating the origin of the diurnal pollution load. This was characterised with high levels of fine secondary inorganic aerosols (NH4+, NO3-, and non-sea-salt SO42-) for continental air masses, and sea-salts as the dominant species in coarse maritime aerosols. Seasonal variations in the level of major ionic species were explained by weather conditions and the release of dimethyl sulfide from marine regions. This species was responsible for an increased sea-salt Cl- depletion during summer (56%), causing elevated levels of HCl. Neutralisation ratios for the coarse fraction (0.60.8) suggested a depleted NH4+ level, while that for the fine fraction (1.11.3) had definitely an excess of NH4+, formed by the neutralisation of HCl. The results of factor analysis and the extent of SO2 oxidation indicated that the major ionic species originated from both local and remote sources, classifying the Belgian coastal region as a combined sourcereceptor area of air pollution. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000264098400022 |
Publication Date |
2008-12-24 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
1464-0325; 1464-0333 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:74341 |
Serial |
8196 |
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Permanent link to this record |
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|
|
Author |
Schelles, W.; de Gendt, S.; Van Grieken, R.E. |
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|
Title |
Optimization of secondary cathode thickness for direct current glow discharge mass spectrometric analysis of glass |
Type |
A1 Journal article |
|
Year |
1996 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
|
|
|
Volume |
11 |
Issue |
|
Pages |
937-941 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1996VP01000007 |
Publication Date |
2004-04-20 |
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|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0267-9477 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:14656 |
Serial |
8341 |
|
Permanent link to this record |
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|
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Author |
Worobiec, A.; Samek, J.; Krata, A.; van Meel, K.; Krupińska, B.; Stefaniak, E.A.; Karaszkiewicz, P.; Van Grieken, R. |
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Title |
Transport and deposition of airborne pollutants in exhibition areas located in historical buildings: study in Wawel Castle Museum in Cracow, Poland |
Type |
A1 Journal article |
|
Year |
2010 |
Publication |
Journal of cultural heritage |
Abbreviated Journal |
|
|
|
Volume |
11 |
Issue |
3 |
Pages |
354-359 |
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|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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Abstract |
Historical buildings and castles that have been turned nowadays into museums, as an exhibition area for precious cultural heritage (CH) items, need more attention since they are CH objects by themselves. Moreover, the preservation techniques require often, significant interventions; however such changes are not always possible or are very limited. The aim of the present study was to investigate the influence of outdoor air pollution on the composition of particulate matter and gases inside the museum of Wawel Castle in Cracow, Poland. During this study a combination of micro and trace analysis techniques were applied, including energy dispersive X-ray fluorescence (EDXRF) and electron probe microanalysis (EPMA). An intensive transport of air pollutants coupled with accumulation of the particles inside the museum was noticed (considerably higher in winter than summer). A high content of carbon and organic matter agglomerated with inorganic particles was determined. Those particles are of special concern because of their adhesive properties and reactivity. It was also noted that the conditions inside the museum favour the reaction of the particles with gaseous pollutants. It was especially the case for nitrate particles. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000279867800017 |
Publication Date |
2010-03-25 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
1296-2074 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:83277 |
Serial |
8698 |
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Permanent link to this record |
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|
|
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Author |
Struyf, H.; van Vaeck, L.; Kennis, P.; Gijbels, R.; van Grieken, R. |
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Title |
Chemical characterization of neo-ceramic powders by time-of-flight and Fourier transform laser microprobe mass spectrometry |
Type |
A1 Journal article |
|
Year |
1996 |
Publication |
Rapid communications in mass spectrometry |
Abbreviated Journal |
Rapid Commun Mass Sp |
|
|
Volume |
10 |
Issue |
6 |
Pages |
699-706 |
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|
Keywords |
A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
Laser microprobe mass spectrometry (LMMS) aims at the identification of local organic and inorganic constituents at the surface of solids, The low mass resolution capabilities of the initially used time-of-flight (TOF) mass spectrometers have often proved to be insufficient for identification, Therefore, high mass resolution Fourier transform (ET) LMMS was developed, Neo-ceramic powders with oxide or carbide coatings were analyzed by both FT LMMS and TOF LMMS, The data are useful to compare the analytical information gained from both methods, Analytical results of these samples by electron microprobe x-ray analysis (EPXMA) and secondary ion mass spectrometry (SIMS) are discussed to assess the place of FT LMMS and TOF LMMS in the spectrum of microanalytical techniques. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
London |
Editor |
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Language |
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Wos |
A1996UJ50200016 |
Publication Date |
2002-09-10 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
|
Series Issue |
|
Edition |
|
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ISSN |
0951-4198;1097-0231; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
|
Impact Factor |
2.253 |
Times cited |
11 |
Open Access |
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Notes |
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Approved |
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|
Call Number |
UA @ lucian @ c:irua:12363 |
Serial |
346 |
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Permanent link to this record |
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Author |
Horemans, B.; Worobiec, A.; Buczyńska, A.; van Meel, K.; Van Grieken, R. |
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Title |
Airborne particulate matter and BTEX in office environments |
Type |
A1 Journal article |
|
Year |
2008 |
Publication |
Journal of environmental monitoring |
Abbreviated Journal |
|
|
|
Volume |
10 |
Issue |
7 |
Pages |
867-876 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000257425300010 |
Publication Date |
2008-06-11 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
1464-0325; 1464-0333 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
|
Times cited |
|
Open Access |
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Notes |
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Approved |
no |
|
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Call Number |
UA @ admin @ c:irua:69425 |
Serial |
7434 |
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Permanent link to this record |
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Author |
Roland, M.; Serrano-Ortiz, P.; Kowalski, A.S.; Van Grieken, R.; Janssens, I.A.; et al. |
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Title |
Atmospheric turbulence triggers pronounced diel pattern in karst carbonate geochemistry |
Type |
A1 Journal article |
|
Year |
2013 |
Publication |
Biogeosciences |
Abbreviated Journal |
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|
|
Volume |
10 |
Issue |
7 |
Pages |
5009-5017 |
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Keywords |
A1 Journal article; Plant and Ecosystems (PLECO) – Ecology in a time of change; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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|
Abstract |
CO2 exchange between terrestrial ecosystems and the atmosphere is key to understanding the feedbacks between climate change and the land surface. In regions with carbonaceous parent material, CO2 exchange patterns occur that cannot be explained by biological processes, such as disproportionate outgassing during the daytime or night-time CO2 uptake during periods when all vegetation is senescent. Neither of these phenomena can be attributed to carbonate weathering reactions, since their CO2 exchange rates are too small. Soil ventilation induced by high atmospheric turbulence is found to explain atypical CO2 exchange between carbonaceous systems and the atmosphere. However, by strongly altering subsurface CO2 concentrations, ventilation can be expected to influence carbonate weathering rates. By imposing ventilation-driven CO2 outgassing in a carbonate weathering model, we show here that carbonate geochemistry is accelerated and does play a surprisingly large role in the observed CO2 exchange pattern of a semi-arid ecosystem. We found that by rapidly depleting soil CO2 during the daytime, ventilation disturbs soil carbonate equilibria and therefore strongly magnifies daytime carbonate precipitation and associated CO2 production. At night, ventilation ceases and the depleted CO2 concentrations increase steadily. Dissolution of carbonate is now enhanced, which consumes CO2 and largely compensates for the enhanced daytime carbonate precipitation. This is why only a relatively small effect on global carbonate weathering rates is to be expected. On the short term, however, ventilation has a drastic effect on synoptic carbonate weathering rates, resulting in a pronounced diel pattern that exacerbates the non-biological behavior of soil-atmosphere CO2 exchanges in dry regions with carbonate soils. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000322242700039 |
Publication Date |
2013-07-24 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
1726-4170; 1726-4189 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:109862 |
Serial |
7533 |
|
Permanent link to this record |
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|
Author |
Jacobs, W.; Dubois, D.; Floren, E.; Aerts, D.; Goris, J.; Buczyńska, A.; Van Grieken, R. |
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Title |
Benzene concentrations on board chemical tankers |
Type |
A1 Journal article |
|
Year |
2011 |
Publication |
WMU journal of maritime affairs |
Abbreviated Journal |
|
|
|
Volume |
10 |
Issue |
1 |
Pages |
117-126 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
Maritime transport of benzene is regulated by the International Maritime Organisation (IMO). Two important guidelines for a ships crew in this matter are IMO circulars 1095 and 1220. The first one describes the minimum safety standards for ships carrying liquids in bulk containing benzene while circular 1220 deals with structural guidelines for new ships carrying liquids in bulk containing benzene, but also technical developments could help in improving safety and health protection on board chemical tankers carrying benzene in bulk. The aim of the present paper is to determine the benzene concentration in the working and living environment on board a modern chemical tanker carrying benzene in bulk, where all safety, technical and operational procedures described by IMO in the above-mentioned circulars are followed. During specific cargo operations, we measured the benzene concentrations on different locations on board by means of Radiello® passive diffusive samplers. Despite all measures taken, we found an important difference in benzene concentration between operations with a benzene cargo compared to operations without benzene on board, as well as inside and outside the accommodation. Moreover, even during discharge operations, where the emission is theoretically zero, we found an important increase in the benzene concentration. In addition, we found less favourable results for the engine room. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
|
Publication Date |
2010-11-22 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
1651-436x; 1654-1642 |
ISBN |
|
Additional Links |
UA library record |
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Impact Factor |
|
Times cited |
|
Open Access |
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Notes |
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Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:89551 |
Serial |
7555 |
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Permanent link to this record |
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|
Author |
de Gendt, S.; Van Grieken, R.; Hang, W.; Harrison, W.W. |
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Title |
Comparison between direct current and radiofrequency glow discharge mass spectrometry for the analysis of oxide-based samples |
Type |
A1 Journal article |
|
Year |
1995 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
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|
Volume |
10 |
Issue |
|
Pages |
689-695 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1995RW12800022 |
Publication Date |
2004-04-20 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0267-9477 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
|
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Notes |
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Approved |
no |
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|
Call Number |
UA @ admin @ c:irua:12352 |
Serial |
7689 |
|
Permanent link to this record |
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|
|
|
Author |
Struyf, H.; Van Vaeck, L.; Van Grieken, R. |
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Title |
Desorption-ionization of inorganic compounds in Fourier transform laser microprobe mass spectrometry with external ion source |
Type |
A1 Journal article |
|
Year |
1996 |
Publication |
Rapid communications in mass spectrometry |
Abbreviated Journal |
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|
Volume |
10 |
Issue |
|
Pages |
551-561 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
A1996UE44900012 |
Publication Date |
2002-09-10 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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Series Volume |
|
Series Issue |
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Edition |
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|
|
ISSN |
0951-4198 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
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Notes |
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Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:12361 |
Serial |
7768 |
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Permanent link to this record |
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Author |
Van Grieken, R.E.; Johansson, T.B.; Akselsson, K.R.; Winchester, J.W.; Nelson, J.W.; Chapman, K.R. |
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Title |
Geophysical applicability of aerosol size distribution measurements using cascade impactors and proton-induced X-ray-emission |
Type |
A1 Journal article |
|
Year |
1976 |
Publication |
Atmospheric environment : an international journal |
Abbreviated Journal |
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|
|
Volume |
10 |
Issue |
8 |
Pages |
571-576 |
|
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
|
Abstract |
Proton Induced X-ray Emission, (PIXE), is capable of high precision analysis for trace element components of aerosol particle size fractions sampled by cascade impactor. A statistical evaluation of data quality has been carried out in order to distinguish between analytical uncertainties in the PIXE procedure, errors caused by cascade impactor performance and by other factors in the sampling procedure, and geophysical causes of differences in composition and particle size distributions of the elements in aerosols. Replicate analyses and simultaneous samplings taken in north Florida and St. Louis have been used for the data evaluation. In addition to the analytical error the sampling procedure contributes an error of ~ 10% to be added quadratically. The resulting precision is sufficient to evaluate the data in geophysical terms. This is illustrated by means of sample sets taken simultaneously in an urban, forest and coastal environment of the same region. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
A1976BZ75500001 |
Publication Date |
2003-08-06 |
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Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
1352-2310 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
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Notes |
|
Approved |
no |
|
|
Call Number |
UA @ admin @ c:irua:113636 |
Serial |
8000 |
|
Permanent link to this record |
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|
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Author |
Bencs, L.; Ravindra, K.; de Hoog, J.; Rasoazanany, E.O.; Deutsch, F.; Bleux, N.; Berghmans, P.; Roekens, E.; Krata, A.; Van Grieken, R. |
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|
Title |
Mass and ionic composition of atmospheric fine particles over Belgium and their relation with gaseous air pollutants |
Type |
A1 Journal article |
|
Year |
2008 |
Publication |
Journal of environmental monitoring |
Abbreviated Journal |
|
|
|
Volume |
10 |
Issue |
10 |
Pages |
1148-1157 |
|
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Mass, major ionic components (MICs) of PM2.5, and related gaseous pollutants (SO2, NOx, NH3, HNO2, and HNO3) were monitored over six locations of different anthropogenic influence (industrial, urban, suburban, and rural) in Belgium. SO42-, NO3-, NH4+, and Na+ were the primary ions of PM2.5 with averages diurnal concentrations ranging from 0.44.5, 0.37.6, 0.94.9, and 0.41.2 µg m-3, respectively. MICs formed 39% of PM2.5 on an average, but it could reach up to 8098%. The SO2, NO, NO2, HNO2, and HNO3 levels showed high seasonal and site-specific fluctuations. The NH3 levels were similar over all the sites (26 µg m-3), indicating its relation to the evenly distributed animal husbandry activities. The sulfur and nitrogen oxidation ratios for PM2.5 point towards a low-to-moderate formation of secondary sulfate and nitrate aerosols over five cities/towns, but their fairly intensive formation over the rural Wingene. Cluster analysis revealed the association of three groups of compounds in PM2.5: (i) NH4NO3, KNO3; (ii) Na2SO4; and (iii) MgCl2, CaCl2, MgF2, CaF2, corresponding to anthropogenic, sea-salt, and mixed (sea-salt + anthropogenic) aerosols, respectively. The neutralization and cation-to-anion ratios indicate that MICs of PM2.5 appeared mostly as (NH4)2SO4 and NH4NO3 salts. Sea-salt input was maximal during winter reaching up to 12% of PM2.5. The overall average Cl-loss for sea-salt particles of PM2.5 at the six sites varied between 69 and 96% with an average of 87%. Principal component analysis revealed vehicular emission, coal/wood burning and animal farming as the dominating sources for the ionic components of PM2.5. |
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000259890100005 |
Publication Date |
2008-10-21 |
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ISSN |
1464-0325; 1464-0333 |
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UA library record; WoS full record; WoS citing articles |
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no |
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Call Number |
UA @ admin @ c:irua:76876 |
Serial |
8206 |
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Author |
Vandeputte, D.F.; Jacob, W.A.; Van Grieken, R.E. |
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Title |
Phosphorus, calcium and lead distribution in collagen in lead induced soft tissue calcification : an ultrastructural and X-ray microanalytical study |
Type |
A1 Journal article |
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Year |
1990 |
Publication |
Matrix |
Abbreviated Journal |
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Volume |
10 |
Issue |
1 |
Pages |
33-37 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Repeated intraperitoneal injections of lead acetate in rats caused a calcification of the skin of the abdomen near the site of the injections. In the lead-induced calcifications, electron dense collagen bundles could be observed. On the surface of the collagen fibrils, needle-like crystals were visible. With energy-dispersive X-ray analysis, phosphorus, calcium and lead were detected in the electron dense collagen bundles. X-ray maps of the P-Kα, Ca-Kα, and Pb-Lα plus Pb-Lβ lines showed an equivalent distribution along the collagen fibrils for phosphorus and calcium. The occurrence of the most electron dense areas in the STEM-image was comparable to the lead distribution. A good correlation existed between the structural and the elemental images of the same area. Although the medicinal use of preparations containing lead is no longer recommended, some are still prescribed. From our results we can conclude that they should not be applied to injured or inflamed skin. |
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Publication Date |
2012-04-16 |
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ISSN |
0934-8832 |
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UA library record |
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Call Number |
UA @ admin @ c:irua:116930 |
Serial |
8377 |
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Author |
de Gendt, S.; Schelles, W.; Van Grieken, R.; Müller, V. |
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Title |
Quantitative analysis of iron-rich and other oxide-based samples by means of glow discharge mass spectrometry |
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A1 Journal article |
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Year |
1995 |
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Journal of analytical atomic spectrometry |
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10 |
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681-687 |
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A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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A1995RW12800021 |
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2004-04-20 |
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0267-9477 |
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UA library record; WoS full record; WoS citing articles |
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Call Number |
UA @ admin @ c:irua:12351 |
Serial |
8438 |
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Author |
van Meel, K.; Worobiec, A.; Stranger, M.; Van Grieken, R. |
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Title |
Sample damage during X-ray fluorescence analysis: case study on ammonium salts in atmospheric aerosols |
Type |
A1 Journal article |
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Year |
2008 |
Publication |
Journal of environmental monitoring |
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10 |
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Pages |
989-992 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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000258084000030 |
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2008-07-15 |
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1464-0325; 1464-0333 |
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UA library record; WoS full record; WoS citing articles |
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Call Number |
UA @ admin @ c:irua:69669 |
Serial |
8493 |
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Author |
Van Grieken, R.; Speecke, A.; Hoste, J. |
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Title |
Spatial neutron flux distributions around A 14 MeV neutron generator |
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A3 Journal article |
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Year |
1972 |
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Journal of radioanalytical chemistry |
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10 |
Issue |
1 |
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95-104 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The neutron flux distribution in the vicinity of 30, 20 and 10 mm diameter targets is measured by irradiating concentric ring-type iron monitors at different distances from the target and counting the induced56Mn activity. Considering the many uncertainties, satisfactory agreement was found between theory and experiment. |
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2006-11-07 |
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0134-0719; 2064-2857 |
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UA library record |
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no |
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Call Number |
UA @ admin @ c:irua:116452 |
Serial |
8567 |
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Author |
Van Grieken, R.; Roekens, E.; Sweevers, H.; Vleugels, G. |
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Title |
Spectroscopy and ion chromatography to study the effects of air pollution on historical buildings |
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A1 Journal article |
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1989 |
Publication |
Spectroscopy |
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10 |
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70-81 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISSN |
0712-4813 |
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UA library record |
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no |
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Call Number |
UA @ admin @ c:irua:116826 |
Serial |
8575 |
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