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Author | Esquivel, M.R.; Zelaya, E. | ||||
Title | Synthesis and characterisation of lanthanide-based dioxide | Type | A1 Journal article | ||
Year | 2011 | Publication | Advances in applied ceramics | Abbreviated Journal | Adv Appl Ceram |
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110 | Issue | 4 | Pages | 219-224 |
Keywords | A1 Journal article; Electron microscopy for materials research (EMAT) | ||||
Abstract | In the present work, the microstructure and structure of La(0.25)Ce(0.52)Nd(0.17)Pr(0.06)(OH)(3) and La(0.25)Ce(0.52)Nd(0.17)Pr(0.06)O(2) is obtained from transmission electron microscopy and X-ray diffraction measurements. Space group P6(3)/m is assigned to the structure of La(0.25)Ce(0.52)Nd(0.17)Pr(0.06)(OH)(3). Lanthanides are assigned to Wyckoff positions 2c. Cell parameters are a=6.375(5) angstrom and c=3.753(5) angstrom. The thermal decomposition of this compound was studied by differential scanning calorimetry. The process is exothermal with an enthalpy change Delta H degrees value of -254 +/- 10 kJ mol(-1). The decomposition kinetics is complex and two global processes with E(a) values of 98 +/- 4 and 61 +/- 2 kJ mol 21 were observed. The product is a lanthanide dioxide. Space group Fm3m is assigned to the La(0.25)Ce(0.52)Nd(0.17)Pr(0.06)O(2). Lanthanides are distributed in Wyckoff positions 4a. The cell parameter is a=5.479(5) angstrom. Nanopores in the oxide surface are obtained using this method and characterised by STEM measurements. | ||||
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Corporate Author | Thesis | ||||
Publisher | Place of Publication | Leeds | Editor | ||
Language | Wos | 000291206700006 | Publication Date | 2011-05-30 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 1743-6753;1743-6761; | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 1.325 | Times cited | 3 | Open Access | |
Notes | Approved | Most recent IF: 1.325; 2011 IF: 0.871 | |||
Call Number | UA @ lucian @ c:irua:105588 | Serial | 3410 | ||
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Author | Zelaya, E.; Esquivel, M.R.; Schryvers, D. | ||||
Title | Evolution of the phase stability of NiAl under low energy ball milling | Type | A1 Journal article | ||
Year | 2013 | Publication | Advanced powder technology | Abbreviated Journal | Adv Powder Technol |
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24 | Issue | 6 | Pages | 1063-1069 |
Keywords | A1 Journal article; Electron microscopy for materials research (EMAT) | ||||
Abstract | Low energy mechanical alloying of Ni35 at.%Al and Ni40 at.%Al material was performed and the resulting structures were investigated by XRD and TEM. The final intermetallics observed consist of two phases, NiAl(B2) and Ni3Al while 7R and 3R martensite was observed in post-annealed samples. Different integrated milling times were associated to the intermetallic consolidation and initial blend dissociation. | ||||
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Corporate Author | Thesis | ||||
Publisher | Place of Publication | Zeist | Editor | ||
Language | Wos | 000339175000024 | Publication Date | 2013-03-30 | |
Series Editor | Series Title | Abbreviated Series Title | |||
Series Volume | Series Issue | Edition | |||
ISSN | 0921-8831; | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
Impact Factor | 2.659 | Times cited | 10 | Open Access | |
Notes | Fwo | Approved | Most recent IF: 2.659; 2013 IF: 1.642 | ||
Call Number | UA @ lucian @ c:irua:107345 | Serial | 1102 | ||
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