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Records |
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Author |
Verbueken, A.H.; Bruynseels, F.J.; Van Grieken, R.E. |
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Title |
Laser microprobe mass analysis : a review of applications in the life sciences |
Type |
A3 Journal article |
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Year |
1985 |
Publication |
Biomedical mass spectrometry |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
12 |
Issue |
9 |
Pages |
438-463 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The characteristics and analytical utility of laser microprobe mass analysis (LAMMA) are described and evaluated, and a short history of this recent microanalytical technique is presented. A review of the areas of application of LAMMA and related laser microprobes is presented with special emphasis on applications in the life sciences. |
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Wos |
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Publication Date |
2005-05-31 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0306-042x |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116722 |
Serial |
8153 |
Permanent link to this record |
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Author |
Sholkovitz, E.R.; Van Grieken, R.; Eisma, D. |
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Title |
The major-element composition of suspended matter in the Zaire river and estuary |
Type |
A1 Journal article |
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Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
12 |
Issue |
3/4 |
Pages |
407-413 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
2003-08-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0077-7579; 1873-1406 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116608 |
Serial |
8195 |
Permanent link to this record |
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Author |
Cataldo,.; Evangelista, H.; Simões, J.C.; Godoi, R.H.M.; Simmonds, I.; Hollanda, M.H.; Wainer, I.; Aquino, F.E.; Van Grieken, R. |
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Title |
Mineral dust variability in central West Antarctica associated with ozone depletion |
Type |
A1 Journal article |
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Year |
2012 |
Publication |
Atmospheric chemistry and physics discussions |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
12 |
Issue |
5 |
Pages |
12685-12714 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Here we show that mineral dust retrieved from an ice core in the central West Antarctic sector, spanning the last five decades, provides evidence that northerly air mass incursions into Antarctica, tracked by dust microparticles, have slightly declined. This result contrasts with dust in ice core records reported in West/coastal Antarctica, which show significant increases to the present day. We attribute that difference, in part, to changes in the regional climate regime triggered by the ozone depletion and its consequences for the polar vortex intensity. The vortex maintains the Antarctic central region relatively isolated from mid-latitude air mass incursions with implications to the intensification of the Westerlies and to a persistent positive phase of the Southern Annular Mode. We also show that variability of the diameter of insoluble microparticles in central West Antarctica can be modeled by linear/quadratic functions of both cyclone depth (energy) and wind intensity around Antarctica. |
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Wos |
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Publication Date |
2012-05-21 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1680-7367 |
ISBN |
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Additional Links |
UA library record |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:102568 |
Serial |
8251 |
Permanent link to this record |
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Author |
Schelles, W.; Van Grieken, R. |
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Title |
Quantitative analysis of zirconium oxide by direct glow discharge mass spectrometry using a secondary cathode |
Type |
A1 Journal article |
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Year |
1997 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
12 |
Issue |
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Pages |
49-52 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Place of Publication |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0267-9477 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:18774 |
Serial |
8439 |
Permanent link to this record |
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Author |
Martin, J.-M.; Thomas, A.J.; Van Grieken, R.E. |
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Title |
Trace element composition of Zaire suspended sediments |
Type |
A1 Journal article |
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Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
12 |
Issue |
3/4 |
Pages |
414-420 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
2003-08-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0077-7579; 1873-1406 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116609 |
Serial |
8688 |
Permanent link to this record |
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Author |
Cassiers, K.; Linssen, T.; Aerts, K.; Cool, P.; Lebedev, O.; Van Tendeloo, G.; van Grieken, R.; Vansant, E.F. |
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Title |
Controlled formation of amine-templated mesostructured zirconia with remarkably high thermal stability |
Type |
A1 Journal article |
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Year |
2003 |
Publication |
Journal of materials chemistry |
Abbreviated Journal |
J Mater Chem |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
13 |
Issue |
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Pages |
3033-3039 |
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Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT); Laboratory of adsorption and catalysis (LADCA); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
Cambridge |
Editor |
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Language |
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Wos |
000186907500040 |
Publication Date |
2003-11-26 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0959-9428;1364-5501; |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
26 |
Open Access |
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Notes |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:43522 |
Serial |
502 |
Permanent link to this record |
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Author |
Van Grieken, R.; Speecke, A.; Hoste, J. |
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Title |
Geometry errors in 14 MeV neutron activation analysis |
Type |
A3 Journal article |
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Year |
1973 |
Publication |
Journal of radioanalytical chemistry |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
13 |
Issue |
1 |
Pages |
225-233 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The effects of inaccurate sample sizes and sample positioning on 14 MeV neutron activation analysis results are estimated for 30, 20 and 10 mm diameter targets. It appears that axial positioning is the most critical parameter and that using a larger tritium target will yield an overall improvement of the reproducibility. |
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Corporate Author |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
2006-10-11 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0134-0719; 2064-2857 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116453 |
Serial |
7999 |
Permanent link to this record |
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Author |
Török, S.; Van Dyck, P.; Van Grieken, R. |
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Title |
Heterogeneity effects in direct X-ray fluorescence analysis of hair |
Type |
A1 Journal article |
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Year |
1984 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
13 |
Issue |
1 |
Pages |
27-32 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The methodology of direct hair analysis by energy-dispersive x-ray fluorescence was studied. The effect on the XRF result of having a non-homogeneous radial distribution of the analyte in a single hair strand and the macroscopic effects in a bundle of hairs were calculated to evaluate possible systematic errors. The detection limits were mapped as a function of the target thickness and surface fraction. It appeared that a 10 mg cm−2 sample thickness, i. e. a target with about four layers of hair strands, is recommended. The standard deviation of this simple direct analytical method is 619% for some important elements. Discrepancies with neutron activation analysis had a mean value of around 15%. About twelve elements can be determined simultaneously on a routine basis. |
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Wos |
A1984SB70200004 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116485 |
Serial |
8029 |
Permanent link to this record |
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Author |
Roekens, E.J.; Van Grieken, R.E. |
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Title |
Kinetics of iron(II) oxidation in seawater of various pH |
Type |
A1 Journal article |
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Year |
1983 |
Publication |
Marine chemistry |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
13 |
Issue |
3 |
Pages |
195-202 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The rate of iron(II) oxidation in North Sea water of pH 5.510 in the range 1025°C has been studied. The oxygenation rate depends linearly on the iron(II) and dissolved oxygen concentrations. The second-order dependence on [OH−], found by several investigators for synthetic solutions, was confirmed in seawater, but only for pOH > 6.9. For pOH < 5.9 the rate appeared to be independent of the pOH. In the intermediate range, pOH 5.96.9, corresponding to the natural pH of seawater, a first-order dependence on the pOH is obeyed. The important discrepancy in the literature between the second-order rate constant for NaCHO3 solutions and for seawater can be attributed predominantly to the incorrect assumption of a second-order pOH dependence in natural seawater. The results can be useful, for example, in predicting the effect of dumping acidic iron waste from the titanium-dioxide industry into the ocean. |
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Corporate Author |
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Place of Publication |
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Wos |
A1983RD52600003 |
Publication Date |
2003-08-08 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0304-4203; 1872-7581 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116695 |
Serial |
8140 |
Permanent link to this record |
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Author |
Cataldo, M.; Evangelista, H.; Simões, J.C.; Godoi, R.H.M.; Simmonds, I.; Hollanda, M.H.; Wainer, I.; Aquino, F.; Van Grieken, R. |
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Title |
Mineral dust variability in central West Antarctica associated with ozone depletion |
Type |
A1 Journal article |
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Year |
2013 |
Publication |
Atmospheric chemistry and physics |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
13 |
Issue |
4 |
Pages |
2165-2175 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
We present here data of mineral dust variability retrieved from an ice core of the central West Antarctic, spanning the last five decades. Main evidence provided by the geochemical analysis is that northerly air mass incursions to the coring site, tracked by insoluble dust microparticles, have declined over the past 50 yr. This result contrasts with dust records from ice cores reported to the coastal West Antarctic that show increases since mid-20th century. We attribute this difference to regional climatic changes due to the ozone depletion and its implications to westerly winds. We found that the diameters of insoluble microparticles in the central West Antarctica ice core are significantly correlated with cyclone depth (energy) and wind intensity around Antarctica. |
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Address |
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Corporate Author |
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Thesis |
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Place of Publication |
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Wos |
000315406600027 |
Publication Date |
2013-02-25 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1680-7316; 1680-7324 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:105832 |
Serial |
8250 |
Permanent link to this record |
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Author |
Verbueken, A.H.; van de Vijver, F.L.; Visser, W.J.; Roels, F.; Van Grieken, R.; de Broe, M.E. |
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Title |
Use of laser microprobe mass analysis (LAMMA) for localizing multiple elements in soft and hard tissues |
Type |
A1 Journal article |
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Year |
1987 |
Publication |
Biological trace element research |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
13 |
Issue |
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Pages |
397-416 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
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Abstract |
The potential of laser microprobe mass analysis (LAMMA) as a sensitive microanalytical technique was explored in applications relevant to nephrology. Aluminum and associated elements, such as iron, were localized in fresh tissue biopsies obtained from uremic patients treatment by chronic hemodialysis. The LAMMA was applied to serum, liver, bone, and parathyroid glands of such patients. In addition, we used LAMMA to evaluate the specificity and sensitivity of routine histochemistry, in particular on human bone sections stained by the aluminon method. The high, multielemental sensitivity and molecular microprobe potential of LAMMA established important advantages over other microchemical methods forin situ analysis at the micron level in histological sections. |
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Wos |
A1987L016000036 |
Publication Date |
2007-12-31 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0163-4984 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116796 |
Serial |
8721 |
Permanent link to this record |
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Author |
Kuczumov, A.; Vekemans, B.; Schalm, O.; Dorriné, W.; Chevallier, P.; Dillmann, P.; Ro, C.-U.; Janssens, K.; Van Grieken, R. |
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Title |
Analyses of petrified wood by electron, X-ray and optical microprobes |
Type |
A1 Journal article |
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Year |
1999 |
Publication |
Journal of analytical atomic spectroscopy |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
14 |
Issue |
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Pages |
435-446 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000079138500016 |
Publication Date |
2002-07-26 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
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ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:22889 |
Serial |
5466 |
Permanent link to this record |
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Author |
Bernardi, A.; Becherini, F.; Verità, M.; Godoi, R.H.M.; Kontozova-Deutsch, V.; Van Grieken, R.; et al. |
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Title |
Conservation of stained glass windows with protective glazing : main results from the European VIDRIO research programme |
Type |
A1 Journal article |
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Year |
2013 |
Publication |
Journal of cultural heritage |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
14 |
Issue |
6 |
Pages |
527-536 |
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Keywords |
A1 Journal article; Art; History; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The methodology of protecting the European stained glass windows against environmental risk (e.g. meteorological factors, air pollution, microorganisms) by means of an external glazing is not new. In spite of many scientific studies carried out in the last 20 years, some questions were still up for discussion. The European VIDRIO (20022005) project gave an answer to these questions. The research carried out by the different project partners established a new multidisciplinary approach aimed at evaluating the efficiency of the protective glazing systems and their effects on stained glass windows conservation, and finally at assessing the most appropriate strategy to preserve stained glass windows. Scientific results showed that the so-called isothermal glazing (i.e. ventilation by the air coming from the inside of the building) protected efficiently the ancient stained glass window from environmental attack (i.e. rain, pollutants, condensation, thermal shocks) with very limited secondary effects. The scientific research highlighted that its efficiency was strongly related to the technical design of the protective system. In particular, the ventilation and the size of the interspace had to be carefully considered. The research developed within the VIDRIO project was turned into general recommendations to the owners and practitioners on the best practice for the stained glass windows future conservation. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000326937800009 |
Publication Date |
2013-01-03 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1296-2074 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:111817 |
Serial |
7726 |
Permanent link to this record |
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Author |
Tsuji, K.; Nullens, R.; Wagatsuma, K.; Van Grieken, R.E. |
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Title |
Elemental x-ray images obtained by grazing-exit electron probe microanalysis (GE-EPMA) |
Type |
A1 Journal article |
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Year |
1999 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
14 |
Issue |
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Pages |
1711-1713 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000083208000009 |
Publication Date |
2002-07-26 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0267-9477 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:34103 |
Serial |
7896 |
Permanent link to this record |
|
|
|
|
Author |
Van Dyck, P.; Markowicz, A.; Van Grieken, R. |
|
Title |
Influence of sample thickness, excitation energy and geometry on particle size effects in XRF |
Type |
A1 Journal article |
|
Year |
1985 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
14 |
Issue |
4 |
Pages |
183-187 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
Expressions are presented for calculating the matrix effect and the pure particle size effect in the XRF analysis of particulate samples with a discrete particle size. The equations are based on the absorption-weighted radiometric diameter concept. Two excitationdetection geometries are considered, with the angles between the sample plane and both the incident and emerging radiation being either 90° (π geometry) or 45° (π/2 geometry). Calculations were made for different sample loadings and exciting radiation energies. The influence of these parameters on the matrix and pure particle size effects is shown. From the results, it is possible to predict the performances of alternative experimental correction procedures for the particle size effect, involving dual measurements at different excitation energies or in different excitationdetection geometries. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
A1985ATB6100007 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:116486 |
Serial |
8097 |
Permanent link to this record |
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|
|
|
Author |
Kuczumow, A.; Schmeling, M.; Van Grieken, R. |
|
Title |
Critical assessment and proposal for reconstruction of a grazing emission X-ray fluorescence instrument |
Type |
A1 Journal article |
|
Year |
2000 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
|
Pages |
535-542 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
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|
Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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Language |
|
Wos |
000086871600008 |
Publication Date |
2002-07-26 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0267-9477 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:27852 |
Serial |
7741 |
Permanent link to this record |
|
|
|
|
Author |
Labrecque, J.J.; Beusen, J.M.; Van Grieken, R.E. |
|
Title |
Determination of barium, lanthanum, cerium and neodymium in lateritic materials by various energy-dispersive X-ray fluorescence techniques and neutron activation analysis |
Type |
A1 Journal article |
|
Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
1 |
Pages |
13-18 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
A comparison of four methods for the determination of barium, lanthanum, cerium and neodymium in lateritic materials from Brazil is presented. Three of the methods were based on x-ray fluorescence (XRF) spectroscopy: two by radioisotope excitation (Co-57 and Am-241) and one by secondary target XRF (a molybdenum target with a tungsten anode). The other method was based on neutron activation analysis employing both a Ge(Li) coaxial detector and a high-purity germanium detector. The results from these four methods were similar for lanthanum, cerium and neodymium, but for barium at low concentrations (<500 ppm) the neutron activation and the secondary target XRF methods were not suitable. Data on the precision and accuracy of these methods using a series of standard reference rocks are given. The advantages and limitations of each of these methods with respect to the analysis of lateritic materials are discussed. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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|
Language |
|
Wos |
A1986AYN6000003 |
Publication Date |
2005-05-28 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:116487 |
Serial |
7774 |
Permanent link to this record |
|
|
|
|
Author |
Markowicz, A.; Storms, H.; Van Grieken, R. |
|
Title |
Evaluation of an equation for bremsstrahlung background in electron-probe X-ray microanalysis of composite samples |
Type |
A1 Journal article |
|
Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
2 |
Pages |
131-133 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
A new equation for predicting the generated bremsstrahlung background intensity in electron-probe x-ray microanalysis has been verified experimentally. This equation is applicable to all bulk composite specimens and reduces to Kramers' equation for pure elements only. The experimental verification has been carried out for Al2O3, Fe2O3 and ZrO2 with radiation energies from 4.2 to 14.8 keV. The predicted bremsstrahlung intensities are in good agreement with the experimental data. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
|
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Language |
|
Wos |
A1986C017300009 |
Publication Date |
2005-05-28 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:113873 |
Serial |
7937 |
Permanent link to this record |
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|
|
|
Author |
Ramesh, R.; Subramanian, V.; Van Grieken, R. |
|
Title |
Heavy metal distribution in sediments of Krishna River basin, India |
Type |
A1 Journal article |
|
Year |
1990 |
Publication |
Environmental geology and water sciences |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
|
Pages |
207-216 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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Language |
|
Wos |
|
Publication Date |
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0177-5146 |
ISBN |
|
Additional Links |
UA library record |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:116933 |
Serial |
8022 |
Permanent link to this record |
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|
|
|
Author |
Török, S.; Braun, T.; Van Dyck, P.; Van Grieken, R. |
|
Title |
Heterogeneity effects in direct XRF analysis of traces of heavy metals preconcentrated on polyurethane foam sorbents |
Type |
A1 Journal article |
|
Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
1 |
Pages |
7-11 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
Trace amounts of heavy metals were preconcentrated on discs of polyurethane (PU) foam loaded with ammonium diethyldithiocarbamate (DDTC), to increase the sensitivity of XRF. Since the diameter of the cavities in the open-cell PU foams reaches 30300 μm, considerable heterogeneity effects might occur, which could reduce the accuracy of the method. The possible systematic error introduced by considering the sample to be homogeneous is calculated using the Berry et al. model. The calculations show that the underestimation of the absorption correction factor when considering the sample as being homogeneous is less than 2% for high-Z elements when the sample thickness is at least 2 mm. The detection limits are also around the minima for this thickness. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
|
Editor |
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Language |
|
Wos |
A1986AYN6000002 |
Publication Date |
2005-05-28 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:116488 |
Serial |
8030 |
Permanent link to this record |
|
|
|
|
Author |
Roekens, E.J.; Van Grieken, R.E. |
|
Title |
Kinetics of iron(II) oxidation in seawater of various pH : reply |
Type |
A1 Journal article |
|
Year |
1984 |
Publication |
Marine chemistry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
3 |
Pages |
281-284 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
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Corporate Author |
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Thesis |
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
A1984TZ60600009 |
Publication Date |
2003-08-08 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0304-4203; 1872-7581 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:116711 |
Serial |
8141 |
Permanent link to this record |
|
|
|
|
Author |
Van Dyck, P.; Török, S.; Van Grieken, R. |
|
Title |
Monte Carlo simulation of backscattered peaks in secondary target energy-dispersive X-ray spectra |
Type |
A1 Journal article |
|
Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
4 |
Pages |
231-238 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
A Monte Carlo simulation has been developed to describe the incoherent and coherent scatter processes for the complex geometry of a secondary target energy-dispersive x-ray fluorescence system. Photons are followed from the x-ray tube anode until the detection of scattered secondary target photons in the active Si layer of the detector. The program quantitatively shows the broadening of the incoherent scatter peak with increasing atomic number, and it models the incoherent peak shape adequately. The incoherent-to-coherent scatter intensity ratios obtained differ by 1030% from the theoretical values, while their dependence on the sample atomic number corresponds to that expected from theory. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
|
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Language |
|
Wos |
A1986E535600001 |
Publication Date |
2005-05-28 |
|
Series Editor |
|
Series Title |
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Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:113612 |
Serial |
8280 |
Permanent link to this record |
|
|
|
|
Author |
Jambers, W.; Van Grieken, R. |
|
Title |
Present and future applications of beam techniques in environmental microanalysis |
Type |
A1 Journal article |
|
Year |
1996 |
Publication |
Trends in analytical chemistry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
|
Pages |
114-122 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
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Thesis |
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
A1996UA48000006 |
Publication Date |
2002-07-25 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0165-9936; 1879-3142 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:14641 |
Serial |
8412 |
Permanent link to this record |
|
|
|
|
Author |
Kuczumow, A.; Claes, M.; Schmeling, M.; Van Grieken, R.; de Gendt, S. |
|
Title |
Quantification problems in light element determination by grazing emission X-ray fluorescence |
Type |
A1 Journal article |
|
Year |
2000 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
|
Pages |
415-421 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
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|
Address |
|
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Corporate Author |
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Thesis |
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|
Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
000086323700017 |
Publication Date |
2002-07-26 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0267-9477 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:27592 |
Serial |
8437 |
Permanent link to this record |
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|
|
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Author |
Szalóki, I.; Braun, M.; Van Grieken, R. |
|
Title |
Quantitative characterisation of the leaching of lead and other elements from glazed surfaces of historical ceramics |
Type |
A1 Journal article |
|
Year |
2000 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
|
Pages |
843-850 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
|
|
Language |
|
Wos |
000088267700006 |
Publication Date |
2002-07-26 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0267-9477 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:28426 |
Serial |
8440 |
Permanent link to this record |
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|
|
|
Author |
Injuk, J.; Van Grieken, R. |
|
Title |
Sample preparation for X-ray fluorescence analysis |
Type |
H3 Book chapter |
|
Year |
2000 |
Publication |
|
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
|
Pages |
13338-13347
T2 - Encyclopedia of analytical chemis |
|
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
|
Edition |
|
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:31656 |
Serial |
8495 |
Permanent link to this record |
|
|
|
|
Author |
Markowicz, A.; Storms, H.; Van Grieken, R. |
|
Title |
A simple absorption correction for electron probe X-ray microanalysis of bulk samples |
Type |
A1 Journal article |
|
Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
2 |
Pages |
115-119 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
A simple procedure is proposed for the calculation of the absorption correction factor in electron-probe x-ray microanalysis. It is based on the concept of an effective depth of x-ray production, assuming a rectangular depth distribution function for x-ray generation. This effective x-ray production depth is expressed as a fraction of the x-ray excitation depth given by Whelan's expression. Adequate values for this fraction are presented. Two versions are considered. In the first the effective x-ray production is a function of both the characteristic x-ray energy and the atomic numbers of the matrix elements, whereas in the second one, which is indicated for routine use, the energy dependence is neglected. Calculations pointed to satisfactory results, even for low x-ray energies and high overvoltages. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
A1986C017300007 |
Publication Date |
2005-05-28 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:113872 |
Serial |
8524 |
Permanent link to this record |
|
|
|
|
Author |
van Dyck, K.; Robberecht, H.; van Cauwenbergh, R.; Deelstra, H.; Arnaud, J.; Willemyns, L.; Benijts, F.; Centeno, J.A.; Taylor, H.; Soares, M.E.; Bastos, M.L.; Ferreira, M.A.; d'Haese, P.C.; Lamberts, L.V.; Hoenig, M.; Knapp, G.; Lugowski, S.J.; Moens, L.; Riondato, J.; Van Grieken, R.; Claes, M.; Verheyen, R.; Clement, L.; Uytterhoeven, M. |
|
Title |
Spectrometric determination of silicon in food and biological samples: an interlaboratory trial |
Type |
A1 Journal article |
|
Year |
2000 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
|
|
Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
6 |
Pages |
735-741 |
|
Keywords |
A1 Journal article; Behavioural Ecology & Ecophysiology; Pathophysiology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
Accuracy and precision of silicon determination in biological matrices (serum, urine, water, beer and spinach) by spectrometric techniques (when necessary after acid destruction) were assessed by means of a collaborative interlaboratory trial. The trial was set up in accordance with ISO 5725-2 (1994). The relative overall repeatability standard deviation was acceptable. It varied between 4% for spinach powder (mean content: 176 mg kg(-1)) and 11% for serum (mean content: 5.33 mg L-1). On the other hand, the relative overall between-laboratory standard deviation was found to vary from a satisfactorily 15% for spinach after destruction (mean content: 3.32 mg L-1) to an unacceptable 107% for spinach powder (mean content: 176 mg kg(-1)). The overall conclusion of the trial was that silicon determination in biological matrices can properly be performed by spectrometric techniques. However, when sample pretreatment (i.e., acid destruction) is needed prior to silicon determination problems still remain. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
000087419300025 |
Publication Date |
2002-07-26 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0267-9477 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:27841 |
Serial |
8574 |
Permanent link to this record |
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|
|
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Author |
Van Grieken, R.E. |
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Title |
X-ray spectrometry |
Type |
H3 Book chapter |
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Year |
2000 |
Publication |
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Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
15 |
Issue |
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Pages |
13269-13443
T2 - Encyclopedia of analytical chemis |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:31650 |
Serial |
8775 |
Permanent link to this record |
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Author |
Koleleni, Y.I.A.; Van Grieken, R. |
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Title |
Analysis of biological materials from Tanzania by total reflection X-ray fluorescence (TXRF) analysis |
Type |
A3 Journal article |
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Year |
1990 |
Publication |
Tanzania journal of science |
Abbreviated Journal |
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Volume ![sorted by Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
16 |
Issue |
|
Pages |
143-157 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Place of Publication |
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Series Issue |
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Edition |
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ISSN |
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ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116934 |
Serial |
7442 |
Permanent link to this record |