Records |
Author |
Major, L.; Tirry, W.; Van Tendeloo, G. |
Title |
Microstructure and defect characterization at interfaces in TiN/CrN multilayer coatings |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Surface and coatings technology |
Abbreviated Journal |
Surf Coat Tech |
Volume |
202 |
Issue |
24 |
Pages |
6075-6080 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
Microstructures of TiN/CrN multilayer coatings deposited on austenite steel (Cr Ni 18 8) by pulsed laser deposition (PLD) are characterized using transmission electron microscopy while their mechanical properties were assessed in a ball-on-disk test. All coatings have the same total thickness of about 1 ìm. The individual layers show a highly defective columnar structure, which is characterized by conventional electron microscopy (TEM) as well as by high resolution TEM. These techniques, combined with measurements of the local chemical composition through EDS prove that PLD allows to produce fully separated CrN and TiN layers. The friction, and consequently the wear, are lowered by increasing the total number of layers in the coating. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Lausanne |
Editor |
|
Language |
|
Wos |
000260267100042 |
Publication Date |
2008-07-20 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0257-8972; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.589 |
Times cited |
23 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 2.589; 2008 IF: 1.860 |
Call Number |
UA @ lucian @ c:irua:76614 |
Serial |
2049 |
Permanent link to this record |
|
|
|
Author |
Major, L.; Morgiel, J.; Major, B.; Lackner, J.M.; Waldhauser, W.; Ebner, R.; Nistor, L.; Van Tendeloo, G. |
Title |
Crystallographic aspects related to advanced tribological multilayers of Cr/CrN and Ti/TiN types produced by pulsed laser deposition (PLD) |
Type |
A1 Journal article |
Year |
2006 |
Publication |
Surface and coatings technology |
Abbreviated Journal |
Surf Coat Tech |
Volume |
200 |
Issue |
22/23 |
Pages |
6190-6195 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Lausanne |
Editor |
|
Language |
|
Wos |
000237842300007 |
Publication Date |
2005-12-10 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0257-8972; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.589 |
Times cited |
32 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 2.589; 2006 IF: 1.559 |
Call Number |
UA @ lucian @ c:irua:59459 |
Serial |
586 |
Permanent link to this record |
|
|
|
Author |
Mahieu, S.; Ghekiere, P.; de Winter, G.; de Gryse, R.; Depla, D.; Van Tendeloo, G.; Lebedev, O.I. |
Title |
Biaxially aligned titanium nitride thin films deposited by reactive unbalanced magnetron sputtering |
Type |
A1 Journal article |
Year |
2006 |
Publication |
Surface and coatings technology |
Abbreviated Journal |
Surf Coat Tech |
Volume |
200 |
Issue |
8 |
Pages |
2764-2768 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Lausanne |
Editor |
|
Language |
|
Wos |
000235202100023 |
Publication Date |
2004-12-15 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0257-8972; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.589 |
Times cited |
36 |
Open Access |
|
Notes |
IWT-Vlaanderen |
Approved |
Most recent IF: 2.589; 2006 IF: 1.559 |
Call Number |
UA @ lucian @ c:irua:56554 |
Serial |
229 |
Permanent link to this record |
|
|
|
Author |
Solís, C.; Rossell, M.D.; Garcia, G.; Figueras, A.; Van Tendeloo, G.; Santiso, J. |
Title |
Microstructure and high temperature transport properties of high quality epitaxial SrFeO3-\delta films |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Solid state ionics |
Abbreviated Journal |
Solid State Ionics |
Volume |
179 |
Issue |
35/36 |
Pages |
1996-1999 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
We report the high temperature electronic transport properties of SrFeO3 − ä epitaxial thin films obtained by pulsed laser deposition on NdGaO3(110) substrates. The films show total conductivity higher than the bulk material and apparent activation energy of about 0.12 eV in O2, lower than reported values for SrFeO3 − ä films. The conductivity dependence with oxygen partial pressure shows a power dependence with an exponent close to + 1/4, in agreement with expected point defect equilibrium. For a given oxygen partial pressure, the temperature coefficient of resistance (TCR) shows a low positive value of about 1.52.5 10− 3 K− 1, which is still suitable for resistive oxygen sensing applications. The transport properties of the films are discussed in view of their particular microstructure. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000261904800007 |
Publication Date |
2008-07-19 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0167-2738; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.354 |
Times cited |
10 |
Open Access |
|
Notes |
Iap V-1 |
Approved |
Most recent IF: 2.354; 2008 IF: 2.425 |
Call Number |
UA @ lucian @ c:irua:75907 |
Serial |
2053 |
Permanent link to this record |
|
|
|
Author |
Lomakov, M.V.; Istomin, S.Y.; Abakumov, A.M.; Van Tendeloo, G.; Antipov, E.V. |
Title |
Synthesis and characterization of oxygen-deficient oxides BaCo1-xYxO3-y' x = 0.15, 0.25 and 0.33, with the perovskite structure |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Solid state ionics |
Abbreviated Journal |
Solid State Ionics |
Volume |
179 |
Issue |
33/34 |
Pages |
1885-1889 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
Oxygen-deficient complex cobalt oxides BaCo1 − xYxO3 − y, = 0.15, 0.25 and 0.33, with a cubic perovskite structure have been synthesized in air at 1100 °C using a citrate route. Cation composition of the compounds was confirmed by energy-dispersed X-ray (EDX) microanalysis while oxygen content was determined by iodometric titration. An electron diffraction (ED) study of the x = 0.25 and 0.33 compositions show the presence of a diffuse intensity, indicating possible short-range ordering of the B cations. It was found that the treatment of BaCo0.75Y0.25O2.55 in a humid atmosphere leads to the absorption of water vapour at the first stage. Oxygen permeation studies of the ceramic membranes of BaCo0.75Y0.25O2.55 and BaCo0.67Y0.33O2.55 with variable thickness showed high oxygen fluxes of 0.170.32 µmol/cm2/s at 950 °C. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000261870800009 |
Publication Date |
2008-06-21 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0167-2738; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.354 |
Times cited |
9 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 2.354; 2008 IF: 2.425 |
Call Number |
UA @ lucian @ c:irua:75905 |
Serial |
3415 |
Permanent link to this record |
|
|
|
Author |
Dominiczak, M.; Ruyter, A.; Limelette, P.; Monot-Laffez, I.; Giovannelli, F.; Rossell, M.D.; Van Tendeloo, G. |
Title |
Effects of nanocracks on the magnetic and electrical properties of La0.8Sr0.2MnO3 single crystals |
Type |
A1 Journal article |
Year |
2009 |
Publication |
Solid state communications |
Abbreviated Journal |
Solid State Commun |
Volume |
149 |
Issue |
37/38 |
Pages |
1543-1548 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
An investigation of the physical properties of La0.8Sr0.2MnO3 single crystals grown by the molten zone technique is realized close to the metal-to-insulator transition temperature (TMI). In this paper, we review the effect of the structural defects through magnetotransport and local magnetic microstructures. From electron microscopy observations, some nanocrack defects (i.e. defects at a nanometer scale) were found, essentially in the center part of the single crystals. At room temperature, magnetic force microscopy measurements have shown that the absence of defects allowed a magnetic ordering of the domains at the crystal edge, which is the best-crystallized region. In addition, the magnetization loops have permitted us to verify that the crystal was ferromagnetically weaker in the center. On analyzing the electrical resistivity data, we observed in the linear current regime a sensitive variation of the resistivity due to defects, by comparing the center and the edge of the material at TMI. Additionally, at strong current, non-linearity phenomena have been supposed to be related to local heating. Finally, we discuss the structural disorder effect on the relaxation of the ferromagnetic domains. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
New York, N.Y. |
Editor |
|
Language |
|
Wos |
000269679500012 |
Publication Date |
2009-06-09 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0038-1098; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.554 |
Times cited |
3 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.554; 2009 IF: 1.837 |
Call Number |
UA @ lucian @ c:irua:78289 |
Serial |
868 |
Permanent link to this record |
|
|
|
Author |
Dominiczak, M.; Ruyter, A.; Limelette, P.; Monot-Laffez, I.; Giovannelli, F.; Rossell, M.D.; Van Tendeloo, G. |
Title |
Relaxation phenomena at the metal-to-insulator transition in La0.8Sr0.2MnO3 single crystals |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Solid state communications |
Abbreviated Journal |
Solid State Commun |
Volume |
148 |
Issue |
7/8 |
Pages |
340-344 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
The time dependence of the resistance RAC of a La0.8Sr0.2MnO3 single crystal has been investigated in the vicinity of the metal-to-insulator transition temperature. We used local probe microscopy to show the existence, at room temperature, of coexisting clusters of micrometer size. Our analysis shows that relaxation effects can be described with a simple exponential contribution using a random resistor-network, based on phase separation between insulating and metallic domains. Our results clearly prove the existence of a percolation threshold over which no percolation path exists. Moreover, these results highlight the significant role of the remanent magnetization. |
Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
New York, N.Y. |
Editor |
|
Language |
|
Wos |
000260907800020 |
Publication Date |
2008-09-03 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0038-1098; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.554 |
Times cited |
9 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.554; 2008 IF: 1.557 |
Call Number |
UA @ lucian @ c:irua:75637 |
Serial |
2863 |
Permanent link to this record |
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|
|
Author |
Jalkanen, P.; Tuboltsev, V.; Virtanen, A.; Arutyunov, K.; Räisänen, J.; Lebedev, O.; Van Tendeloo, G. |
Title |
Critical temperature modification of low dimensional superconductors by spin doping |
Type |
A1 Journal article |
Year |
2007 |
Publication |
Solid state communications |
Abbreviated Journal |
Solid State Commun |
Volume |
142 |
Issue |
7 |
Pages |
407-411 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
New York, N.Y. |
Editor |
|
Language |
|
Wos |
000246815800010 |
Publication Date |
2007-03-14 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0038-1098; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.554 |
Times cited |
7 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.554; 2007 IF: 1.535 |
Call Number |
UA @ lucian @ c:irua:64746 |
Serial |
546 |
Permanent link to this record |
|
|
|
Author |
Epurescu, G.; Dinescu, G.; Moldovan, A.; Birjega, R.; Dipietrantonio, F.; Verona, E.; Verardi, P.; Nistor, L.C.; Ghica, C.; Van Tendeloo, G.; Dinescu, A. |
Title |
P-type ZnO thin films grown by RF plasma beam assisted Pulsed Laser Deposition |
Type |
A1 Journal article |
Year |
2007 |
Publication |
Superlattices and microstructures |
Abbreviated Journal |
Superlattice Microst |
Volume |
42 |
Issue |
1-6 |
Pages |
79-84 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
London |
Editor |
|
Language |
|
Wos |
000250271200015 |
Publication Date |
2007-08-01 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0749-6036; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.123 |
Times cited |
19 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 2.123; 2007 IF: 1.344 |
Call Number |
UA @ lucian @ c:irua:66632 |
Serial |
2549 |
Permanent link to this record |
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|
|
Author |
Tikhomirov, V.K.; Rodríguez, V.D.; Méndez-Ramos, J.; del- Castillo, J.; Kirilenko, D.; Van Tendeloo, G.; Moshchalkov, V.V. |
Title |
Optimizing Er/Yb ratio and content in Er-Yb co-doped glass-ceramics for enhancement of the up- and down-conversion luminescence |
Type |
A1 Journal article |
Year |
2012 |
Publication |
Solar energy materials and solar cells |
Abbreviated Journal |
Sol Energ Mat Sol C |
Volume |
100 |
Issue |
|
Pages |
209-215 |
Keywords |
A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) |
Abstract |
Er3+Yb3+ co-doped transparent glass-ceramics with varying Er/Yb content and ratio have been prepared. High quantum yields for up- and down-conversion luminescence by energy transfer from Yb3+ to Er3+ and from Er3+ to Yb3+, respectively, have been detected and optimized with respect to the Er/Yb content and ratio, and proposed in particular for up- and down-conversion of solar spectrum for enhancement of the efficiency of solar cells. The rise and decay kinetics for the population of the excited levels of Er3+ and Yb3+ have been studied and fit. Based on these experimental data, the mechanisms for the energy transfers have been suggested with emphasis on the optimized Er/Yb content and ratio for enhancement of the efficiency of the Er3+↔Yb3+ energy transfers. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000303034700030 |
Publication Date |
2012-02-04 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0927-0248; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
4.784 |
Times cited |
66 |
Open Access |
|
Notes |
Fwo |
Approved |
Most recent IF: 4.784; 2012 IF: 4.630 |
Call Number |
UA @ lucian @ c:irua:97392 |
Serial |
2493 |
Permanent link to this record |
|
|
|
Author |
Hervieu, M.; Damay, F.; Poienar, M.; Elkaim, E.; Rouquette, J.; Abakumov, A.M.; Van Tendeloo, G.; Maignan, A.; Martin, C. |
Title |
Nanostructures in LuFe2O4+\delta |
Type |
A1 Journal article |
Year |
2013 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
23 |
Issue |
|
Pages |
26-34 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
A LuFe2O4+delta sample, previously characterized by X-ray synchrotron and neutron diffraction, has been studied by electron microscopy techniques, in order to get a precise description of its micro- and nanostructures at room temperature. The X-ray synchrotron data vs. temperature show that the monoclinic distortion is associated with the charge ordering; this distortion results in elongated twinning domains, which enhance the complexity of the microstructural state at room temperature. The structural modulation associated with oxygen excess is observed in large domains inside a non modulated matrix, in contrast with the modulations associated with the charge ordering of the Fe2+ and Fe3+ species, which are mostly short-range. The investigation of the nature and density of defects in the sample shows that they are nano-scaled, preserving the regularity of the layer stacking mode, and limited to the formation of one- or two-units large stacking faults, associated with gliding mechanisms. Based on these observations, an original description of the LuFe2O4 ferrite structure, through puckered [LuO4](infinity) sandwiching [Fe-2](infinity) layers, is proposed. (C) 2013 Elsevier Masson SAS. All rights reserved. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000324156200005 |
Publication Date |
2013-06-13 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
7 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.811; 2013 IF: 1.679 |
Call Number |
UA @ lucian @ c:irua:111196 |
Serial |
2276 |
Permanent link to this record |
|
|
|
Author |
Lepoittevin, C.; Malo, S.; Van Tendeloo, G.; Hervieu, M. |
Title |
Synthesis and structural mechanisms of the 2201-type ferrites and polytypes: Fe2(Sr2-xAx)FeO6.5-\delta/2 (A = Ba, La, Tl, Pb and Bi) |
Type |
A1 Journal article |
Year |
2009 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
11 |
Issue |
3 |
Pages |
595-607 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
The Fe2(Sr2 − xAx)FeO6.5 − ä/2 systems have been investigated, by doping the iron rich 2201-type parent structure with Ba2+, La3+ and 5d10 post-transition cations. The syntheses have been carried out up to the limit of the 2201-type solid solutions, in order to test the role of the double iron layer Fe2O2.5 − ä/2. The localisation of the charge carriers in these compounds is consistent with their strong antiferro-magnetism. The investigation was then carried out in the transition part of the diagram up to the formation of stable phases. The study of structural mechanisms was carried using high resolution electron microscopy (transmission and scanning transmission), electron diffraction and energy dispersive spectroscopy. Different non-stoichiometry mechanisms are observed, depending on the electronic structure and chemical properties of the doping elements. The specific behavior of the modulated double iron layer is discussed. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000264644800001 |
Publication Date |
2008-12-26 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
3 |
Open Access |
|
Notes |
Esteem 026019 |
Approved |
Most recent IF: 1.811; 2009 IF: 1.675 |
Call Number |
UA @ lucian @ c:irua:76416 |
Serial |
3437 |
Permanent link to this record |
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|
|
Author |
Hadermann, J.; Abakumov, A.M.; Nikolaev, I.V.; Antipov, E.V.; Van Tendeloo, G. |
Title |
Local structure of perovskite-based “Pb2Fe2O5” |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
10 |
Issue |
4 |
Pages |
382-389 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000256200200003 |
Publication Date |
2008-01-20 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
29 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.811; 2008 IF: 1.742 |
Call Number |
UA @ lucian @ c:irua:69289 |
Serial |
1832 |
Permanent link to this record |
|
|
|
Author |
Khobrakova, E.T.; Morozov, V.A.; Khasanov, S.S.; Tsyrenova, G.D.; Khaikina, E.G.; Lebedev, O.I.; Van Tendeloo, G.; Lazoryak, B.I. |
Title |
New molybdenum oxides Ag4M2Zr(MoO4)6 (M=Mg, Mn, Co, Zn) with a channel-like structure |
Type |
A1 Journal article |
Year |
2005 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
7 |
Issue |
11 |
Pages |
1397-1405 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000233620600014 |
Publication Date |
2005-10-15 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
9 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.811; 2005 IF: 1.708 |
Call Number |
UA @ lucian @ c:irua:54703 |
Serial |
2327 |
Permanent link to this record |
|
|
|
Author |
Kremer, S.P.B.; Kirschhock, C.E.A.; Aerts, A.; Aerts, C.A.; Houthoofd, K.J.; Grobet, P.J.; Jacobs, P.A.; Lebedev, O.I.; Van Tendeloo, G.; Martens, J.A. |
Title |
Zeotile-2: a microporous analogue of MCM-48 |
Type |
A1 Journal article |
Year |
2005 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
7 |
Issue |
7 |
Pages |
861-867 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000230259500006 |
Publication Date |
2005-04-20 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
10 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.811; 2005 IF: 1.708 |
Call Number |
UA @ lucian @ c:irua:54702 |
Serial |
3931 |
Permanent link to this record |
|
|
|
Author |
Abakumov, A.M.; Kalyuzhnaya, A.S.; Rozova, M.G.; Antipov, E.V.; Hadermann, J.; Van Tendeloo, G. |
Title |
Compositionally induced phase transition in the Ca2MnGa1-xAlxO5 solid solutions: ordering of tetrahedral chains in brownmillerite structure |
Type |
A1 Journal article |
Year |
2005 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
7 |
Issue |
7 |
Pages |
801-811 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000230259500001 |
Publication Date |
2005-04-30 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
38 |
Open Access |
|
Notes |
IAP V-1; RFBR 04-03-32785-a. |
Approved |
Most recent IF: 1.811; 2005 IF: 1.708 |
Call Number |
UA @ lucian @ c:irua:54700 |
Serial |
448 |
Permanent link to this record |
|
|
|
Author |
Malakho, A.P.; Morozov, V.A.; Pokholok, K.V.; Lazoryak, B.I.; Van Tendeloo, G. |
Title |
Layered ordering of vacancies of lead iron phosphate Pb3Fe2(PO4)4 |
Type |
A1 Journal article |
Year |
2005 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
7 |
Issue |
4 |
Pages |
397-404 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000228951300007 |
Publication Date |
2005-03-22 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
7 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.811; 2005 IF: 1.708 |
Call Number |
UA @ lucian @ c:irua:54701 |
Serial |
1806 |
Permanent link to this record |
|
|
|
Author |
Lebedev, O.I.; Van Tendeloo, G.; Collart, O.; Cool, P.; Vansant, E.F. |
Title |
Structure and microstructure of nanoscale mesoporous silica spheres |
Type |
A1 Journal article |
Year |
2004 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
6 |
Issue |
|
Pages |
489-498 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT); Laboratory of adsorption and catalysis (LADCA) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000221604500011 |
Publication Date |
2004-03-20 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
42 |
Open Access |
|
Notes |
Pai/Iuap P5/01 |
Approved |
Most recent IF: 1.811; 2004 IF: 1.598 |
Call Number |
UA @ lucian @ c:irua:46262 |
Serial |
3289 |
Permanent link to this record |
|
|
|
Author |
Lazoryak, B.I.; Morozov, V.A.; Belik, A.A.; Stefanovich, S.Y.; Grebenev, V.V.; Leonidov, I.A.; Mitberg, E.B.; Davydov, S.A.; Lebedev, O.I.; Van Tendeloo, G. |
Title |
Ferroelectric phase transition in the whitlockite-type Ca9Fe(PO4)7; crystal structure of the paraelectric phase at 923 K |
Type |
A1 Journal article |
Year |
2004 |
Publication |
Solid state sciences |
Abbreviated Journal |
Solid State Sci |
Volume |
6 |
Issue |
2 |
Pages |
185-195 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000220312700005 |
Publication Date |
2004-02-06 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
1293-2558; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.811 |
Times cited |
41 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.811; 2004 IF: 1.598 |
Call Number |
UA @ lucian @ c:irua:54699 |
Serial |
1180 |
Permanent link to this record |
|
|
|
Author |
Ionescu, R.; Espinosa, E.H.; Leghrib, R.; Felten, A.; Pireaux, J.-J.; Erni, R.; Van Tendeloo, G.; Bittencourt, C.; Canellas, N.; Llobet, E. |
Title |
Novel hybrid materials for gas sensing applications made of metal-decorated MWCNTs dispersed on nano-particle metal oxides |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Sensors and actuators : B : chemical |
Abbreviated Journal |
Sensor Actuat B-Chem |
Volume |
131 |
Issue |
1 |
Pages |
174-182 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Lausanne |
Editor |
|
Language |
|
Wos |
000255426800026 |
Publication Date |
2007-11-10 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0925-4005; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
5.401 |
Times cited |
47 |
Open Access |
|
Notes |
Pai |
Approved |
Most recent IF: 5.401; 2008 IF: 3.122 |
Call Number |
UA @ lucian @ c:irua:68872 |
Serial |
2377 |
Permanent link to this record |
|
|
|
Author |
Verbeeck, J.; van Dyck, D.; Van Tendeloo, G. |
Title |
Energy-filtered transmission electron microscopy: an overview |
Type |
A1 Journal article |
Year |
2004 |
Publication |
Spectrochimica acta: part B : atomic spectroscopy |
Abbreviated Journal |
Spectrochim Acta B |
Volume |
59 |
Issue |
10/11 |
Pages |
1529-1534 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT); Vision lab |
Abstract |
This paper aims to give an overview of the technique of energy-filtered transmission electron microscopy (EFTEM). It explains the basic principles of the technique and points to the relevant literature for more detailed issues. Experimental examples are given to show the power of EFTEM to study the chemical composition of nanoscale samples in materials science. Advanced EFTEM applications like imaging spectroscopy and EFTEM tomography are briefly discussed. (C) 2004 Elsevier B.V. All rights reserved. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Oxford |
Editor |
|
Language |
|
Wos |
000224848000006 |
Publication Date |
2004-10-13 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0584-8547; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
3.241 |
Times cited |
37 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 3.241; 2004 IF: 3.086 |
Call Number |
UA @ lucian @ c:irua:54869UA @ admin @ c:irua:54869 |
Serial |
1038 |
Permanent link to this record |
|
|
|
Author |
Koblischka, M.R.; Winter, M.; Das, P.; Koblischka-Veneva, A.; Muralidhar, M.; Wolf, T.; Babu, N.H.; Turner, S.; Van Tendeloo, G.; Hartmann, U. |
Title |
Observation of nanostripes and -clusters in (Nd, EuGd)Ba2Cu3Ox superconductors |
Type |
A1 Journal article |
Year |
2009 |
Publication |
Physica: C : superconductivity |
Abbreviated Journal |
Physica C |
Volume |
469 |
Issue |
4 |
Pages |
168-176 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
Nanostripes are observed in melt-textured and single-crystalline samples of the ternary light rare earth (LRE)-compound (Nd0.33Eu0.33Gd0.33)Ba2Cu3Ox (NEG) by means of atomic force microscopy, scanning tunnelling microscopy at ambient conditions, combined with transmission electron microscopy and electron backscatter diffraction. This enables the observation of several important features: The nanostripes are formed by chains of nanoclusters, representing the LRE/Ba substitution. The dimensions of the nanostripes are similar for both types of NEG samples. The periodicity of the nanostripes is found to range between 40 and 60 nm; the shape of the nanoclusters is elliptic with a major axis length between 300 and 500 nm and a minor axis length of about 30150 nm. The stripes are filling effectively the space in between the twin boundaries. Concerning the flux pinning, the nanoclusters are the important pinning sites, not the nanostripes themselves. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000264657100008 |
Publication Date |
2009-01-23 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0921-4534; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.404 |
Times cited |
6 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.404; 2009 IF: 0.723 |
Call Number |
UA @ lucian @ c:irua:76403 |
Serial |
2418 |
Permanent link to this record |
|
|
|
Author |
ben Azzouz, F.; Zouaoui, M.; Mellekh, A.; Annabi, M.; Van Tendeloo, G.; ben Salem, M. |
Title |
Flux pinning by Al-based nanoparticles embedded in YBCO: a transmission electron microscopic study |
Type |
A1 Journal article |
Year |
2007 |
Publication |
Physica: C : superconductivity |
Abbreviated Journal |
Physica C |
Volume |
455 |
Issue |
1/2 |
Pages |
19-24 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000246598700003 |
Publication Date |
2007-02-21 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0921-4534; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.404 |
Times cited |
39 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.404; 2007 IF: 1.079 |
Call Number |
UA @ lucian @ c:irua:64754 |
Serial |
1242 |
Permanent link to this record |
|
|
|
Author |
ben Azzouz, F.; Zouaoui, M.; Mani, K.D.; Annabi, M.; Van Tendeloo, G.; ben Salem, M. |
Title |
Structure, microstructure and transport properties of B-doped YBCO system |
Type |
A1 Journal article |
Year |
2006 |
Publication |
Physica: C : superconductivity |
Abbreviated Journal |
Physica C |
Volume |
442 |
Issue |
1 |
Pages |
13-19 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
|
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000238756600003 |
Publication Date |
2006-05-19 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0921-4534; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
1.404 |
Times cited |
14 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.404; 2006 IF: 0.792 |
Call Number |
UA @ lucian @ c:irua:59712 |
Serial |
3304 |
Permanent link to this record |
|
|
|
Author |
Sudheendra, L.; Moshnyaga, V.; Lebedev, O.I.; Gehrke, K.; Belenciuc, A.; Shapoval, O.; Van Tendeloo, G.; Samwer, K. |
Title |
A-site ordering and stripe phases in manganite films |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Physica: B : condensed matter
T2 – International Conference on Strongly Correlated Electron Systems (SCES, 2007), MAY 13-18, 2007, Houston, TX |
Abbreviated Journal |
Physica B |
Volume |
403 |
Issue |
5-9 |
Pages |
1645-1646 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
Insulating and metallic stripes above and below the Curie temperature, T-C, respectively, were observed by a high-resolution scanning tunneling microscopy (STM) and/or spectroscopy (STS) in A-site ordered and macroscopically strain free epitaxial La0.75Ca0.25MnO3 film grown on MgO substrate. The “insulating” stripes were found to be incommensurable to the lattice and aligned along (110) direction. Metallic stripes were commensurable with periodicity 2a(p)similar to 0.8 nm and aligned parallel to the crystallographic a/b-axis. Formation of these stripes involves competing charge, orbital, and lattice orders and is an outcome of an overlapping of electron wave functions mediated by the local lattice-strain distribution, existed even in A-site ordered film due to the difference in cation radii of La and Ca. (C) 2007 Elsevier B.V. All rights reserved. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000254689900330 |
Publication Date |
2007-11-06 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0921-4526; |
ISBN |
|
Additional Links |
UA library record; WoS full record |
Impact Factor |
1.386 |
Times cited |
|
Open Access |
|
Notes |
|
Approved |
Most recent IF: 1.386; 2008 IF: 0.822 |
Call Number |
UA @ lucian @ c:irua:104031 |
Serial |
26 |
Permanent link to this record |
|
|
|
Author |
Kuznetsov, A.S.; Cuong, N.T.; Tikhomirov, V.K.; Jivanescu, M.; Stesmans, A.; Chibotaru, L.F.; Velázquez, J.J.; Rodríguez, V.D.; Kirilenko, D.; Van Tendeloo, G.; Moshchalkov, V.V. |
Title |
Effect of heat-treatment on luminescence and structure of Ag nanoclusters doped oxyfluoride glasses and implication for fiber drawing |
Type |
A1 Journal article |
Year |
2012 |
Publication |
Optical materials |
Abbreviated Journal |
Opt Mater |
Volume |
34 |
Issue |
4 |
Pages |
616-621 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
The effect of heat treatment on the structure and luminescence of Ag nanoclusters doped oxyfluoride glasses was studied and the implication for drawing the corresponding fibers doped with luminescent Ag nanoclusters has been proposed. The heat treatment results, first, in condensation of the Ag nanoclusters into larger Ag nanoparticles and loss of Ag luminescence, and further heat treatment results in precipitation of a luminescent-loss nano- and microcrystalline Ag phases onto the surface of the glass. Thus, the oxyfluoride fiber doped with luminescent Ag nanoclusters was pulled from the viscous glass melt and its attenuation loss was 0.19 dB/cm in the red part of the spectrum; i.e. near to the maximum of Ag nanoclusters luminescence band. The nucleation centers for the Ag nanoclusters in oxyfluoride glasses have been suggested to be the fluorine vacancies and their nanoclusters. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000300124500006 |
Publication Date |
2011-10-18 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0925-3467; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.238 |
Times cited |
25 |
Open Access |
|
Notes |
Methusalem |
Approved |
Most recent IF: 2.238; 2012 IF: 1.918 |
Call Number |
UA @ lucian @ c:irua:93632 |
Serial |
811 |
Permanent link to this record |
|
|
|
Author |
Krsmanovic, R.; Bals, S.; Bertoni, G.; Van Tendeloo, G. |
Title |
Structural characterization of Er-doped Li2O-Al2O3-SiO2 glass ceramics |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Optical materials |
Abbreviated Journal |
Opt Mater |
Volume |
30 |
Issue |
7 |
Pages |
1183-1188 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
Particularly favourable properties of glass ceramics are developed on the basis of two key advantages of these materials: the variation of chemical composition and of microstructure. Therefore, detailed structural and chemical information are necessary to get insight in novel glass ceramic materials. We present here two examples of Er-doped Li2O-Al2O3-SiO2, with different quantities of ZrO2, both obtained with sol-gel synthesis. Different transmission electron microscopy techniques: conventional TEM, HRTEM, and EELS are used and the results are compared with those previously obtained with XRD and Rietveld analysis. We also demonstrate the 3D reconstruction, obtained from HAADF-STEM imaging, to determine the morphology of nanosize precipitates in these composites. (c) 2007 Elsevier B.V. All rights reserved. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
Language |
|
Wos |
000254419100035 |
Publication Date |
2007-07-11 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
0925-3467; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
2.238 |
Times cited |
12 |
Open Access |
|
Notes |
Iap-V1; Esteem |
Approved |
Most recent IF: 2.238; 2008 IF: 1.714 |
Call Number |
UA @ lucian @ c:irua:70004 |
Serial |
3219 |
Permanent link to this record |
|
|
|
Author |
Ying, J.; Yang, X.-Y.; Hu, Z.-Y.; Mu, S.-C.; Janiak, C.; Geng, W.; Pan, M.; Ke, X.; Van Tendeloo, G.; Su, B.-L. |
Title |
One particle@one cell : highly monodispersed PtPd bimetallic nanoparticles for enhanced oxygen reduction reaction |
Type |
A1 Journal article |
Year |
2014 |
Publication |
Nano energy |
Abbreviated Journal |
Nano Energy |
Volume |
8 |
Issue |
|
Pages |
214-222 |
Keywords |
A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) |
Abstract |
Highly monodispersed platinum-based nanoalloys are the best-known catalysts for the oxygen reduction reaction. Although certainly promising, the durability and stability are among the main requirements for commercializing fuel cell electrocatalysts in practical applications. Herein, we synthesize highly stable, durable and catalytic active monodispersed PtPd nano-particles encapsulated in a unique one particle@one cell structure by adjusting the viscosity of solvents using mesocellular foam. PtPd nanoparticles in mesocellular carbon foam exhibit an excellent electrocatalytic activity (over 4 times mass and specific activities than the commercial Pt/C catalyst). Most importantly, this nanocatalyst shows no obvious change of structure and only a 29.5% loss in electrochemically active surface area after 5000 potential sweeps between 0.6 and 1.1 V versus reversible hydrogen electrode cycles. (C) 2014 Elsevier Ltd. All rights reserved. |
Address |
|
Corporate Author |
|
Thesis |
|
Publisher |
|
Place of Publication |
|
Editor |
|
Language |
|
Wos |
000340981700026 |
Publication Date |
2014-06-23 |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
2211-2855; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
12.343 |
Times cited |
40 |
Open Access |
|
Notes |
|
Approved |
Most recent IF: 12.343; 2014 IF: 10.325 |
Call Number |
UA @ lucian @ c:irua:119255 |
Serial |
2465 |
Permanent link to this record |
|
|
|
Author |
Zhang, Z.; Chen, X.; Shi, X.; Hu, Y.; Huang, J.; Liu, S.; Ren, Z.; Huang, H.; Han, G.; Van Tendeloo, G.; Tian, H. |
Title |
Morphotropic phase boundary in pure perovskite lead titanate at room temperature |
Type |
A1 Journal article |
Year |
2022 |
Publication |
Materials Today Nano |
Abbreviated Journal |
|
Volume |
20 |
Issue |
|
Pages |
100275-5 |
Keywords |
A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) |
Abstract |
For many decades, great efforts have been devoted to pursue a large piezoelectric response by an intelligent design of morphotropic phase boundaries (MPB) in solid solutions, where tetragonal (T) and rhombohedral (R) structures coexist. For example, classical PbZrxTi1-xO3 and Pb(Mg1/3Nb2/3)O-3-PbTiO3 single crystals demonstrate a giant piezoelectric response near MPB. However, as the end member of these solids, perovskite-structured PbTiO3 always adopts the T phase at room temperature. Here, we report a pathway to create room temperature MPB in a single-phase PbTiO3. The uniaxial stress along the c-axis drives a T-R phase transition bridged by a monoclinic (M) phase, which facilitates a polarization rotation in the monodomain PbTiO3. Meanwhile, we demonstrate that the coexistence of T and R phases at room temperature can be achieved via an extremely mismatched heterointerface system. The uniaxial pressure is proved as an efficient way to break the inherent symmetry and able to substantially tailor the phase transition temperature Tc. These findings provide new insights into MPB, offering the opportunity to explore the giant piezoelectric response in single-phase materials. (c) 2022 Elsevier Ltd. All rights reserved. |
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Corporate Author |
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Thesis |
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Place of Publication |
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Editor |
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Language |
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Wos |
000906548600002 |
Publication Date |
2022-10-18 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
2588-8420 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
10.3 |
Times cited |
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Open Access |
Not_Open_Access |
Notes |
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Approved |
Most recent IF: 10.3 |
Call Number |
UA @ admin @ c:irua:193477 |
Serial |
7324 |
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Author |
Neira, I.S.; Kolen'ko, Y.V.; Lebedev, O.I.; Van Tendeloo, G.; Gupta, H.S.; Matsushita, N.; Yoshimura, M.; Guitian, F. |
Title |
Rational synthesis of a nanocrystalline calcium phosphate cement exhibiting rapid conversion to hydroxyapatite |
Type |
A1 Journal article |
Year |
2009 |
Publication |
Materials science and engineering: part C: biomimetic materials |
Abbreviated Journal |
Mat Sci Eng C-Mater |
Volume |
29 |
Issue |
7 |
Pages |
2124-2132 |
Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
Abstract |
The rational synthesis, comprehensive characterization, and mechanical and micromechanical properties of a calcium phosphate cement are presented. Hydroxyapatite cement biomaterial was synthesized from reactive sub-micrometer-sized dicalcium phosphate dihydrate and tetracalcium phosphate via a dissolution-precipitation reaction using water as the liquid phase. As a result nanostructured, Ca-deficient and carbonated B-type hydroxyapatite is formed. The cement shows good processibility, sets in 22 ± 2 min and entirely transforms to the end product after 6 h of setting reaction, one of the highest conversion rates among previously reported for calcium phosphate cements based on dicalcium and tetracalcium phosphates. The combination of all elucidated physical-chemical traits leads to an essential bioactivity and biocompatibility of the cement, as revealed by in vitro acellular simulated body fluid and cell culture studies. The compressive strength of the produced cement biomaterial was established to be 25 ± 3 MPa. Furthermore, nanoindentation tests were performed directly on the cement to probe its local elasticity and plasticity at sub-micrometer/micrometer level. The measured elastic modulus and hardness were established to be Es = 23 ± 3.5 and H = 0.7 ± 0.2 GPa, respectively. These values are in close agreement with those reported in literature for trabecular and cortical bones, reflecting good elastic and plastic coherence between synthesized cement biomaterial and human bones. |
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Place of Publication |
Lausanne |
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Wos |
000270159200008 |
Publication Date |
2009-04-20 |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0928-4931; |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
4.164 |
Times cited |
18 |
Open Access |
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Notes |
Esteem 026019 |
Approved |
Most recent IF: 4.164; 2009 IF: NA |
Call Number |
UA @ lucian @ c:irua:79312 |
Serial |
2812 |
Permanent link to this record |