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Author |
De Bie, C. |
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Title  |
Fluid modeling of the plasma-assisted conversion of greenhouse gases to value-added chemicals in a dielectric barrier discharge |
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Doctoral thesis |
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Year |
2016 |
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Doctoral thesis; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Antwerpen |
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Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:138591 |
Serial |
4466 |
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Author |
Van Grieken, R.; Injuk, J.; Otten, P.; Rojas, C.; van Malderen, H.; Laane, R. |
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Title |
Fluxes and sources of heavy metal inputs into the Southern Bight of the North Sea |
Type |
H3 Book chapter |
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Year |
1992 |
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184-193
T2 - Industrial air pollution: assessment |
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H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:2859 |
Serial |
7975 |
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Author |
De Tommasi, E.; Rogato, A.; Caratelli, D.; Mescia, L.; Gielis, J. |
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Title |
Following the photons route : mathematical models describing the interaction of diatoms with light |
Type |
H1 Book chapter |
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Year |
2022 |
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1-53 |
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H1 Book chapter; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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Abstract |
The interaction of diatoms with sunlight is fundamental in order to deeply understand their role in terrestrial ecology and biogeochemistry, essentially due to their massive contribution to global primary production through photosynthesis and its e↵ect on carbon, oxygen and silicon cycles. Following the journey of light through natural waters, its propagation through the intricate frustule micro- and nano-structure and, finally, its fate inside the photosynthetic machinery of the living cell requires several mathematical and computational models in order to accurately describe all the involved phenomena taking place at di↵erent space scales and physical regimes. In this chapter, we review the main analytical models describing the underwater optical field, the essential numerical algorithms for the study of photonic properties of the diatom frustule seen as a natural metamaterial, as well as the principal models describing photon harvesting in diatom plastids and methods for complex EM propagation problems and wave propagation in dispersive materials with multiple relaxation times. These mathematical methods will be integrated in a unifying geometric perspective. |
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978-1-119-74985-1 |
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Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:186731 |
Serial |
7165 |
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Author |
Kollarahithlu, S.C.; Sathiyamoorthy, S.; Thiruvottriyur Shanmugam, S.; De Wael, K.; Das, J.; Veluswamy, P. |
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Title |
Foodborne outbreaks : sources and mode of transmission of foodborne pathogenic microorganisms |
Type |
H1 Book chapter |
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Year |
2023 |
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Pages |
93-104
T2 - Global food safety : microbial interve |
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Keywords |
H1 Book chapter; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab) |
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Abstract |
The foodborne pathogens and microorganisms have played a prevalent role in the ebb and flow of the economy worldwide. The increasing population has strained the food processing industry to produce food in large quantity, which in turn has affected the quality of food. To curb this issue, there is immense pressure to produce and maintain quality food within a short time frame. Hence, high throughput technology is used to determine and timely assess the safety and hygiene of food. Further, the revolution of the food industry has also seen an upsurge of new pathogens and microorganisms, thereby increasing the risk of exposure towards rarest diseases to a larger population. This chapter sheds light on the different types of foodborne pathogens affecting the food industry and its social impact. It further emphasizes the safety measures to be taken on the prevention of the disease from the farm to the processing industries and in turn to the household. |
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978-1-003-28314-0 |
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Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:200591 |
Serial |
9039 |
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Author |
Huyskens, C. |
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Title |
Fouling in submerged membrane bioreactors |
Type |
Doctoral thesis |
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Year |
2012 |
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Abbreviated Journal |
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Pages |
198 p. |
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Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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978-90-5728-374-1 |
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no |
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Call Number |
UA @ admin @ c:irua:99492 |
Serial |
7980 |
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Author |
Han, M.; De Clippeleir, H.; Al-Omari, A.; Vlaeminck, S.E.; Wett, B.; Murthy, S. |
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Title |
Free ammonia and/or temperature impact study on temperature-acclimated mainstream nitrification sludge |
Type |
P3 Proceeding |
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Year |
2016 |
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Abbreviated Journal |
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Pages |
3 p.
T2 - WEF/IWA Nutrient Removal and Recovery Co |
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Keywords |
P3 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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no |
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Call Number |
UA @ admin @ c:irua:151134 |
Serial |
7984 |
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Author |
Tan, H. |
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Title |
From EELS to oxidation state mapping : an investigation into oxidation state mapping of transition metals with electron energy-loss spectroscopy |
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Doctoral thesis |
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Year |
2012 |
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Doctoral thesis; Electron microscopy for materials research (EMAT) |
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Antwerpen |
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0000-00-00 |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:96030 |
Serial |
1280 |
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Author |
Shi, H. |
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Title |
From functional properties to micro/nano-structures : a TEM study of NiTiNb shape memory alloys |
Type |
Doctoral thesis |
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Year |
2014 |
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Abbreviated Journal |
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Keywords |
Doctoral thesis; Electron microscopy for materials research (EMAT) |
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Antwerpen |
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0000-00-00 |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:116623 |
Serial |
1281 |
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Author |
Ricci, P.E.; Gielis, J. |
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Title |
From Pythagoras to Fourier and from geometry to nature |
Type |
MA3 Book as author |
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Year |
2022 |
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Abbreviated Journal |
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146 p. |
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Keywords |
MA3 Book as author; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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2022-03-23 |
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978-90-832323-0-0; 978-90-832323-1-7 |
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Open Access |
Not_Open_Access |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:186730 |
Serial |
7166 |
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Author |
Ke, X. |
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Title |
From top-down to bottom-up : from carbon nanotubes to nanodevices |
Type |
Doctoral thesis |
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Year |
2010 |
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Abbreviated Journal |
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Doctoral thesis; Electron microscopy for materials research (EMAT) |
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Antwerpen |
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0000-00-00 |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:87408 |
Serial |
1289 |
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Author |
de Backer, J.; Vanderveken, O.; Vos, W.; Devolder, A.; Verhulst, S.; Verbraecken, J. |
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Title |
Functional imaging to predict treatment success of mandibular advancement devices in sleep-disordered breathing |
Type |
H3 Book chapter |
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Year |
2008 |
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Abbreviated Journal |
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141-155 |
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Keywords |
H3 Book chapter; Condensed Matter Theory (CMT); Laboratory Experimental Medicine and Pediatrics (LEMP); Translational Neurosciences (TNW) |
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Antwerpen |
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0000-00-00 |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:72885 |
Serial |
1298 |
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Author |
Khaletskaya, K. |
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Title |
Functional metal-organic frameworks : from bulk to surface engineered properties |
Type |
Doctoral thesis |
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Year |
2014 |
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Abbreviated Journal |
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Keywords |
Doctoral thesis; Electron microscopy for materials research (EMAT) |
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Antwerpen |
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0000-00-00 |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:123904 |
Serial |
1301 |
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Author |
Charlier, E.; Gijbels, R.; Van Doorselaer, M.; De Keyzer, R. |
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Title |
Functioning of thiocyanate ions during sulphur and sulphur-plus-gold Sensitization |
Type |
P1 Proceeding |
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Year |
2000 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
172-176 |
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Keywords |
P1 Proceeding; Engineering sciences. Technology; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Abstract |
Not much about the effect of thiocyanate addition on the sulphur ripening is known, although it is used for many applications in photographic practice. Via a combination of tracer analysis and diffuse reflectance spectroscopy the effect of thiocyanate addition on the sulphur and sulphur-plus-gold ripening could be unveiled. When thiocyanate is added prior to the sulphur addition, it appears to rearrange the silver halide surface in such way that the sulphur deposition rate is enhanced, but the supply of interstitials is limited. Addition of thiocyanate after the sulphur reaction results in the formation of thiocyanate complexes with silver, from which a silver ion is more easily deposited in a surface cell of the silver sulphide clusters thus enhancing the sensitization rate. For sulphur-plus-gold sensitized emulsions it was observed that part of the gold ions could be removed out of the Ag2-xAuxS clusters by addition of thiocyanate ions and subsequent washing. Hence, it was concluded that two different types of gold ions are present in the silver sulphide clusters; 1. gold ions which are substitutional for silver (bound between sulphur and bromide ions) 2. gold ions which bridge two or three sulphur atoms. Incorporation of gold ions into silver sulphide clusters suppresses their optical absorption in diffuse reflectance spectroscopy. Since the optical absorption at 505 nm can completely be restored by addition of thiocyanate, it is assumed that the entity absorbing at this wavelength is a monomer of silver sulphide. |
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Soc. imaging science technology |
Place of Publication |
Springfield |
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Wos |
000183315900047 |
Publication Date |
0000-00-00 |
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Edition |
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ISSN |
0-89208-229-1 |
ISBN |
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Additional Links |
UA library record; WoS full record; |
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Notes |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:95775 |
Serial |
1307 |
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Author |
van Straaten, M.; Gijbels, R. |
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Title |
Fundamental aspects of an analytical glow discharge |
Type |
H3 Book chapter |
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Year |
1993 |
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Abbreviated Journal |
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Volume |
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Pages |
130-139 |
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Keywords |
H3 Book chapter; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Royal Society of Chemistry |
Place of Publication |
Cambridge |
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Wos |
A1993BY94U00015 |
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0000-00-00 |
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UA library record; WoS full record; |
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Approved |
CHEMISTRY, PHYSICAL 77/144 Q3 # MATHEMATICS, INTERDISCIPLINARY 19/101 Q1 # PHYSICS, ATOMIC, MOLECULAR & CHEMICAL 17/35 Q2 # |
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Call Number |
UA @ lucian @ c:irua:6166 |
Serial |
1309 |
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Author |
Adams, F.; Janssens, K. |
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Title |
Future of m-XRF |
Type |
H3 Book chapter |
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Year |
2000 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
370-390 |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Most recent IF: NA |
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UA @ admin @ c:irua:27580 |
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5631 |
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Author |
Van Grieken, R.; Eyckmans, K. |
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Title |
Geen vuiltje aan de Noordzeelucht: aërosolen kennen geen grenzen |
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P3 Proceeding |
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2001 |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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UA @ admin @ c:irua:36094 |
Serial |
7990 |
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Author |
Zhang, Z.; Lobato, I.; Brown, H.; Jannis, D.; Verbeeck, J.; Van Aert, S.; Nellist, P. |
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Title |
Generalised oscillator strength for core-shell electron excitation by fast electrons based on Dirac solutions |
Type |
Dataset |
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Year |
2023 |
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Dataset; Electron microscopy for materials research (EMAT) |
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Abstract |
Inelastic excitation as exploited in Electron Energy Loss Spectroscopy (EELS) contains a rich source of information that is revealed in the scattering process. To accurately quantify core-loss EELS, it is common practice to fit the observed spectrum with scattering cross-sections calculated using experimental parameters and a Generalized Oscillator Strength (GOS) database [1]. The GOS is computed using Fermi’s Golden Rule and orbitals of bound and excited states. Previously, the GOS was based on Hartree-Fock solutions [2], but more recently Density Functional Theory (DFT) has been used [3]. In this work, we have chosen to use the Dirac equation to incorporate relativistic effects and have performed calculations using Flexible Atomic Code (FAC) [4]. This repository contains a tabulated GOS database based on Dirac solutions for computing double differential cross-sections under experimental conditions. We hope the Dirac-based GOS database can benefit the EELS community for both academic use and industry integration. Database Details: – Covers all elements (Z: 1-108) and all edges – Large energy range: 0.01 – 4000 eV – Large momentum range: 0.05 -50 Å-1 – Fine log sampling: 128 points for energy and 256 points for momentum – Data format: GOSH [3] Calculation Details: – Single atoms only; solid-state effects are not considered – Unoccupied states before continuum states of ionization are not considered; no fine structure – Plane Wave Born Approximation – Frozen Core Approximation is employed; electrostatic potential remains unchanged for orthogonal states when – core-shell electron is excited – Self-consistent Dirac–Fock–Slater iteration is used for Dirac calculations; Local Density Approximation is assumed for electron exchange interactions; continuum states are normalized against asymptotic form at large distances – Both large and small component contributions of Dirac solutions are included in GOS – Final state contributions are included until the contribution of the previous three states falls below 0.1%. A convergence log is provided for reference. Version 1.1 release note: – Update to be consistent with GOSH data format [3], all the edges are now within a single hdf5 file. A notable change in particular, the sampling in momentum is in 1/m, instead of previously in 1/Å. Great thanks to Gulio Guzzinati for his suggestions and sending conversion script. Version 1.2 release note: – Add “File Type / File version” information [1] Verbeeck, J., and S. Van Aert. Ultramicroscopy 101.2-4 (2004): 207-224. [2] Leapman, R. D., P. Rez, and D. F. Mayers. The Journal of Chemical Physics 72.2 (1980): 1232-1243. [3] Segger, L, Guzzinati, G, & Kohl, H. Zenodo (2023). doi:10.5281/zenodo.7645765 [4] Gu, M. F. Canadian Journal of Physics 86(5) (2008): 675-689. |
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Not_Open_Access |
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Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:203392 |
Serial |
9042 |
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Author |
Van der Paal, J. |
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Title |
Generation, transport and molecular interactions of reactive species in plasma medicine |
Type |
Doctoral thesis |
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Year |
2019 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
237 p. |
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Keywords |
Doctoral thesis; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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UA library record |
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Notes |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:162591 |
Serial |
6297 |
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| Permanent link to this record |
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Author |
Peeters, F.M.; Kong, M.; Partoens, B. |
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Title |
Geometry induced defects in a confined Wigner lattice |
Type |
P1 Proceeding |
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Year |
2002 |
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Abbreviated Journal |
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Volume |
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Pages |
192-195 |
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Keywords |
P1 Proceeding; Condensed Matter Theory (CMT) |
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s.l. |
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0000-00-00 |
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UA library record; WoS full record; WoS citing articles |
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Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:62449 |
Serial |
1333 |
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Author |
Mabesoone, J.M.; Duarte, P.J.; Van Grieken, R.; Delgao, A.; Freire, E.M.P. |
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Title |
Geoquimica dos microclasticos da Bacio do Parnaiba |
Type |
H3 Book chapter |
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Year |
1985 |
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Pages |
30-31
T2 - Fanerozoico Nordestino : serie D |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
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Call Number |
UA @ admin @ c:irua:117502 |
Serial |
8001 |
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Author |
van Grieken, R.; Gijbels, R.; Blommaert, W.; Vandelannoote, R.; Van 't dack, L. |
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Title |
Geothermal water analysis by X-ray fluorescence and neutron activation |
Type |
H3 Book chapter |
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1978 |
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Abbreviated Journal |
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368-378 |
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Keywords |
H3 Book chapter; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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US Energy Research and Development Administration |
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S.l. |
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0000-00-00 |
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Approved |
PHYSICS, APPLIED 47/145 Q2 # |
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Call Number |
UA @ lucian @ c:irua:117464 |
Serial |
1335 |
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Author |
Bruijnen, Y.; Caen, J.M.A.; Cagno, S.; Janssens, K.; et al. |
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Title |
Getekend Jan R. : Jan Rombouts, een renaissancemeester herontdekt |
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ME2 Book as editor or co-editor |
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2012 |
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207 p. |
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ME2 Book as editor or co-editor; Art; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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978-90-6153-780-9 |
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Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:115160 |
Serial |
5633 |
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Author |
Jiang, J. |
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Title |
Ginzburg-Landau dynamical simulations on the nonreciprocal transport properties of two-dimensional superconductors |
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Doctoral thesis |
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2022 |
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XII, 79 p. |
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Doctoral thesis; Condensed Matter Theory (CMT) |
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The nonreciprocal charge transport property which depends on the polarity of the applied current, such as the diode effect and the rectification effect, is of great importance for both theoretical research and engineering application. The nonreciprocal transport property in superconductors generally requires to break both the spatial inversion symmetry and the time-reversal symmetry, and therefore becomes one of the fundamental issues in superconductivity. Of particular interest, the superconducting diode effect, which exhibits one-way superconductivity, can potentially be applied to dissipationless diode devices, as a consequence has received extensive attention in recent years. In this Ph. D thesis, we simulate vortex dynamics with heat dissipation by numerically solving time-dependent Ginzburg-Landau equations and heat transfer equation. The nonreciprocal transport properties of the following three superconducting systems are studied. We study a superconducting film patterned with a conformal pinning array and find a giant rectification effect which is consistent with the experimental observation. In presence of the funneling effect due to the geometry of the conformal pinning array, Joule heating of the accumulating vortices creates hot spots and drives the sample to the normal state. Meanwhile, the density gradient of vortex does not match the gradient of pinning. The two mechanisms together lead to the giant rectification effect. We study the nonreciprocal charge transport property in a pinning-free superconducting nano-ring. We systematically calculate the response of the ratchet signal to various parameters in both D.C. and A.C. currents. By analyzing the vortex potential, we find that the nonreciprocal transport property is caused by the asymmetry potential barriers for vortex entry and exit. We study a superconductor/nanoscale-magnetic-dot hybrid structure. It takes advantage of the external current to control the nucleation of vortex-antivortex pairs, and can produce superconducting diode effect without applied magnetic fields. Our vortex dynamics simulation details the progress of the superconducting-normal phase transition due to motion of vortex pairs and heat dissipation. The nonreciprocal transport properties of the above three systems are all based on the broken symmetry of spatial inversion, which is caused by the anisotropic pinning array, the asymmetric geometry, and the nonuniform distribution of the magnetic field, respectively. The mechanisms we discuss in this thesis do not require special property of the materials and thus can be applied to any kinds of conventional superconductors. The present studies would provide solid theoretical basis for the future design and application of the dissipationless superconducting devices. |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:188525 |
Serial |
7168 |
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Author |
de Raedt, I.; Janssens, K.; Veeckman, J.; Adriaens, A.; Adams, F. |
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Title |
Glass trade in Antwerp during the 15th through 17th century |
Type |
H3 Book chapter |
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Year |
2000 |
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Abbreviated Journal |
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38-44 |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Most recent IF: NA |
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Call Number |
UA @ admin @ c:irua:27860 |
Serial |
5634 |
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Author |
Bogaerts, A. |
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Title |
Glow discharge mass spectrometry, methods |
Type |
H3 Book chapter |
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2000 |
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Abbreviated Journal |
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Pages |
669-676 |
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Keywords |
H3 Book chapter; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Academic Press |
Place of Publication |
San Diego, Calif. |
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0000-00-00 |
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Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:28315 |
Serial |
1349 |
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Author |
Steiner, R.E.; Barshick, C.M.; Bogaerts, A. |
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Title |
Glow discharge optical spectroscopy and mass spectrometry |
Type |
H1 Book chapter |
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Year |
2009 |
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Abbreviated Journal |
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Pages |
1-28 |
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Keywords |
H1 Book chapter; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Abstract |
Optical (atomic absorption spectroscopy, AAS; atomic emission spectroscopy, AES; atomic fluorescence spectroscopy, AFS; and optogalvanic spectroscopy) and mass spectrometric (magnetic sector, quadrupolemass analyzer, QMA; quadrupole ion trap, QIT; Fourier transform ion cyclotron resonance, FTICR; and time-of-flight, TOF) instrumentation are well suited for coupling to the glow discharge (GD). The GD is a relatively simple device. A potential gradient (5001500 V) is applied between an anode and a cathode. In most cases, the sample is also the cathode. A noble gas (e.g. Ar, Ne, and Xe) is introduced into the discharge region before power initiation. When a potential is applied, electrons are accelerated toward the anode. As these electrons accelerate, they collide with gas atoms. A fraction of these collisions are of sufficient energy to remove an electron from a support gas atom, forming an ion. These ions are, in turn, accelerated toward the cathode. These ions impinge on the surface of the cathode, sputtering sample atoms from the surface. Sputtered atoms that do not redeposit on the surface diffuse into the excitation/ionization regions of the plasma where they can undergo excitation and/or ionization via a number of collisional processes. GD sources offer a number of distinct advantages that make them well suited for specific types of analyses. These sources afford direct analysis of solid samples, thus minimizing the sample preparation required for analysis. The nature of the plasma also provides mutually exclusive atomization and excitation processes that help to minimize the matrix effects that plague so many other elemental techniques. Unfortunately, the GD source functions optimally in a dry environment, making analysis of solutions more difficult. These sources also suffer from difficulties associated with analyzing nonconductingsamples. In this article, first, the principles of operation of the GD plasma are reviewed, with an emphasis on how those principles relate to optical spectroscopy and mass spectrometry. Basic applications of the GD techniques are considered next. These include bulk analysis, surface analysis, and the analysis of solution samples. The requirements necessary to obtain optical information are addressed following the analytical applications. This section focuses on the instrumentation needed to make optical measurements using the GD as an atomization/excitation source. Finally, mass spectrometric instrumentation and interfaces are addressed as they pertain to the use of a GD plasma as an ion source. GDsources provide analytically useful gas-phase species from solid samples. These sources can be interfaced with avariety of spectroscopic and spectrometric instruments for both quantitative and qualitative analysis. |
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Wiley |
Place of Publication |
Chichester |
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0000-00-00 |
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ISBN |
0471976709 |
Additional Links |
UA library record |
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Open Access |
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Notes |
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Approved |
Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:78169 |
Serial |
1352 |
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| Permanent link to this record |
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Author |
Bogaerts, A. |
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Title |
Glow discharge optical spectroscopy and mass spectrometry |
Type |
H1 Book chapter |
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Year |
2016 |
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Abbreviated Journal |
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Pages |
1-31 |
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Keywords |
H1 Book chapter; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Abstract |
Atomic Spectroscopy Optical (atomic absorption spectroscopy, AAS; atomic emission spectroscopy, AES; atomic fluorescence spectroscopy, AFS; and optogalvanic spectroscopy) and mass spectrometric (magnetic sector, quadrupole mass analyzer, QMA; quadrupole ion trap, QIT; Fourier transform ion cyclotron resonance, FTICR; and time-of-flight, TOF) instrumentation are well suited for coupling to the glow discharge (GD). The GD is a relatively simple device. A potential gradient (500–1500 V) is applied between an anode and a cathode. In most cases, the sample is also the cathode. A noble gas (mostly Ar) is introduced into the discharge region before power initiation. When a potential is applied, electrons are accelerated toward the anode. As these electrons accelerate, they collide with gas atoms. A fraction of these collisions are of sufficient energy to remove an electron from a support gas atom, forming an ion. These ions are, in turn, accelerated toward the cathode. These ions impinge on the surface of the cathode, sputtering sample atoms from the surface. Sputtered atoms that do not redeposit on the surface diffuse into the excitation/ionization regions of the plasma where they can undergo excitation and/or ionization via a number of collisional processes, and the photons or ions created in this way can be detected with optical emission spectroscopy or mass spectrometry. GD sources offer a number of distinct advantages that make them well suited for specific types of analyses. These sources afford direct analysis of solid samples, thus minimizing the sample preparation required for analysis. The nature of the plasma also provides mutually exclusive atomization and excitation processes that help to minimize the matrix effects that plague so many other elemental techniques. In recent years, there is also increasing interest for using GD sources for liquid and gas analyses. In this article, first, the principles of operation of the GD plasma are reviewed, with an emphasis on how those principles relate to optical spectroscopy and mass spectrometry. Basic applications of the GD techniques are considered next. These include bulk analysis, surface analysis, and the analysis of solution and gaseous samples. The requirements necessary to obtain optical information are addressed following the analytical applications. This article focuses on the instrumentation needed to make optical measurements using the GD as an atomization/excitation source. Finally, mass spectrometric instrumentation and interfaces are addressed as they pertain to the use of a GD plasma as an ion source. GD sources provide analytically useful gas-phase species from solid samples. These sources can be interfaced with a variety of spectroscopic and spectrometric instruments for both quantitative and qualitative analyses. |
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John Wiley & Sons |
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Chichester |
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978-0-470-02731-8 |
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Most recent IF: NA |
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UA @ lucian @ c:irua:132064 |
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4187 |
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Jakubowski, N.; Bogaerts, A.; Hoffmann, V. |
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Title |
Glow discharges in emission and mass spectrometry |
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H3 Book chapter |
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2003 |
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H3 Book chapter; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Blackwell |
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Sheffield |
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0000-00-00 |
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Most recent IF: NA |
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UA @ lucian @ c:irua:44024 |
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1353 |
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Cidu, R.; Fanfani, L.; Shand, P.; Edmunds, W.M.; Van 't dack, L.; Gijbels, R. |
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Gold mobility in waters from temperate regions |
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P3 Proceeding |
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1995 |
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P3 Proceeding; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Vladivostok |
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PHYSICS, APPLIED 47/145 Q2 # |
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UA @ lucian @ c:irua:12272 |
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1357 |
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Giorgio, S.; Henry, C.R.; Pauwels, B.; Van Tendeloo, G. |
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Gold particles supported on TiO2 |
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P3 Proceeding |
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2000 |
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369-370 |
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P3 Proceeding; Electron microscopy for materials research (EMAT) |
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s.l. |
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Most recent IF: NA |
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Call Number |
UA @ lucian @ c:irua:29732 |
Serial |
1358 |
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