Records |
Author |
Winchester, J.W.; Meinert, D.L.; Nelson, J.W.; Johansson, T.B.; Van Grieken, R.E.; Orsini, C.; Kaufmann, H.C.; Akselsson, R. |
Title |
Trace metals in the St-Louis aerosol |
Type |
H3 Book chapter |
Year |
1975 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
385-394
T2 - Nuclear techniques in environmental r |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117459 |
Serial |
8694 |
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Author |
Van Grieken, R.E.; Johansson, T.B.; Winchester, J.W. |
Title |
Trace metal fractionation effects between sea water and aerosols from bubble bursting |
Type |
A1 Journal article |
Year |
1974 |
Publication |
Journal de recherches atmosphériques |
Abbreviated Journal |
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Volume |
8 |
Issue |
3-4 |
Pages |
611-621 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISSN |
0021-7972 |
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UA library record |
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no |
Call Number |
UA @ admin @ c:irua:113641 |
Serial |
8693 |
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Author |
Van Grieken, R.E.; Johansson, T.B.; Winchester, J.W.; Odom, L. |
Title |
Micro-determination of zirconium-hafnium ratios in zircons by proton induced X-ray emission |
Type |
A3 Journal article |
Year |
1975 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
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Volume |
275 |
Issue |
5 |
Pages |
343-348 |
Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The zirconium/hafnium ratios of zircons are determined using proton induced X-ray emission. Submilligram samples, imbedded in a starch layer and deposited on a 50 μg/cm2 polystyrene carrier, are irradiated for 1020 min with a 5 nA beam of 3.7 MeV protons, while the Hf-Lβ and Zr-Kα X-rays are counted with a Si(Li) detector. The standard deviation per analysis is in the 36 % range. Only few interferences are possible. To eliminate errors due to absorption effects the zircon layer thickness should be above 40 μm or reproducibly thin samples should be employed. Measuring the Hf-Lβ/Hf-Lα ratio for samples and standards might provide a practical check for the absence of absorption errors. The sensitivity is so favourable that, in practice, the minimal sample size is only limited by the minimal amount that can be handled properly. |
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2004-11-11 |
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ISSN |
0016-1152 |
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no |
Call Number |
UA @ admin @ c:irua:116636 |
Serial |
8231 |
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Author |
Johansson, T.B.; Van Grieken, R.E.; Winchester, J.W. |
Title |
Marine influences on aerosol composition in the coastal zone |
Type |
A1 Journal article |
Year |
1974 |
Publication |
Journal de recherches atmosphériques |
Abbreviated Journal |
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Volume |
8 |
Issue |
3-4 |
Pages |
761-766 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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ISSN |
0021-7972 |
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UA library record |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:113640 |
Serial |
8204 |
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Author |
Johansson, T.B.; Van Grieken, R.E.; Winchester, J.W. |
Title |
Interpretation of aerosol trace metal particle size distributions |
Type |
H3 Book chapter |
Year |
1975 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
356-365
T2 - Nuclear techniques in environmental r |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117460 |
Serial |
8117 |
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Author |
Van Grieken, R.E.; Johansson, T.B.; Akselsson, K.R.; Winchester, J.W.; Nelson, J.W.; Chapman, K.R. |
Title |
Geophysical applicability of aerosol size distribution measurements using cascade impactors and proton-induced X-ray-emission |
Type |
A1 Journal article |
Year |
1976 |
Publication |
Atmospheric environment : an international journal |
Abbreviated Journal |
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Volume |
10 |
Issue |
8 |
Pages |
571-576 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Proton Induced X-ray Emission, (PIXE), is capable of high precision analysis for trace element components of aerosol particle size fractions sampled by cascade impactor. A statistical evaluation of data quality has been carried out in order to distinguish between analytical uncertainties in the PIXE procedure, errors caused by cascade impactor performance and by other factors in the sampling procedure, and geophysical causes of differences in composition and particle size distributions of the elements in aerosols. Replicate analyses and simultaneous samplings taken in north Florida and St. Louis have been used for the data evaluation. In addition to the analytical error the sampling procedure contributes an error of ~ 10% to be added quadratically. The resulting precision is sufficient to evaluate the data in geophysical terms. This is illustrated by means of sample sets taken simultaneously in an urban, forest and coastal environment of the same region. |
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A1976BZ75500001 |
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2003-08-06 |
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Edition |
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ISSN |
1352-2310 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:113636 |
Serial |
8000 |
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Author |
Johansson, T.B.; Van Grieken, R.E.; Nelson, J.W.; Winchester, J.W. |
Title |
Elemental trace analysis of small samples by proton-induced X-ray-emission |
Type |
A1 Journal article |
Year |
1975 |
Publication |
Analytical chemistry |
Abbreviated Journal |
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Volume |
47 |
Issue |
6 |
Pages |
855-860 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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A1975AA02900016 |
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2005-03-08 |
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ISSN |
0003-2700; 5206-882x |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:113638 |
Serial |
7895 |
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Author |
Nelson, J.W.; Williams, I.; Johansson, T.B.; Van Grieken, R.E. |
Title |
Elemental analysis of aerosols using proton-scattering |
Type |
A1 Journal article |
Year |
1974 |
Publication |
IEEE transactions on nuclear science |
Abbreviated Journal |
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Volume |
Ns21 |
Issue |
1 |
Pages |
618-621 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Elemental analysis for all of the light elements up through chlorine by elastic scattering of 16 MeV protons has been shown to be feasible. Basic problems associated with such measurements are discussed including kinematics, angular distribution, and sample backings. Spectra are presented for air particulate matter for both a total filter (Nuclepore) and a size fractionated air impactor (polystyrene backed) sample. The method is absolute, non destructive and can be used in conjunction with proton induced x-ray fluorescence to quantitatively analyze all elements in the same sample in minutes of time. |
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Wos |
A1974S533700086 |
Publication Date |
2008-07-22 |
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Edition |
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ISSN |
0018-9499 |
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UA library record; WoS full record; WoS citing articles |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:113642 |
Serial |
7881 |
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Author |
Johansson, T.B.; Nelson, J.W.; Van Grieken, R.E.; Winchester, J.W. |
Title |
Elemental analysis of aerosol-size fractions by proton-induced X-ray-emission |
Type |
A1 Journal article |
Year |
1973 |
Publication |
Transactions of the American Nuclear Society |
Abbreviated Journal |
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Volume |
17 |
Issue |
Nov |
Pages |
103-103 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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A1973R161300114 |
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Edition |
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ISSN |
0003-018x |
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UA library record; WoS full record |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:113643 |
Serial |
7880 |
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Author |
Johansson, T.B.; Van Grieken, R.E.; Winchester, J.W. |
Title |
Elemental abundance variation with particle-size in north florida aerosols |
Type |
A1 Journal article |
Year |
1976 |
Publication |
Journal of geophysical research |
Abbreviated Journal |
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Volume |
81 |
Issue |
6 |
Pages |
1039-1046 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
A nonurban base line has been established for nine trace element constituents of aerosol particles as a function of particle size at ground level sampling stations in north Florida up to 50 km from the Gulf of Mexico. The particle size range 0.25- to >4-μm aerodynamic diameter was investigated by cascade impactor sampling and elemental analysis by proton-induced X ray emission. By using a strategy of sampling at urban, forest, and coastal locations and by choosing approximately 48-hour sample averaging intervals the potential dependence of the base line levels both on local pollution and natural sources and on local particle size specific aerosol removal processes could be evaluated. It is found that elements contained in the largest particles, especially those of >4 μm, display the greatest degree of average concentration difference between sites, a result suggesting short atmospheric residence times and the importance of local dispersion sources and atmospheric cleansing processes in regulating the particle concentrations in air. Elements contained in particles of <2-μm diameter show little average concentration difference between sites unless they are influenced by local pollution sources, a finding suggesting that their concentrations in air are regulated by large-scale sources and transport processes. Sulfur in the smallest particles shows a marked constancy of concentration, but it may be modified in the largest particle size ranges in relation to proximity to the seacoast. No evidence is found for dependence of particulate sulfur concentrations on local pollution sources. K, Ca, Ti, Fe, and Zn appear to be regulated in the main by terrestrial source processes, and Cl by marine source processes, but Br and Pb appear to be accounted for adequately by assuming automotive fuel combustion as their major source. Limited data obtained for V indicate that it may vary considerably with fluctuations in aerosol transport from oil-fired electric power plant sources in the region. Limited additional data also suggest that Mn is derived from sources of natural terrestrial composition. In view of these findings, certain criteria may be set for the design of a meaningful nonurban aerosol monitoring network. |
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A1976BG78300001 |
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2008-02-06 |
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ISSN |
0148-0227; 2156-2202; 0022-1406; 0196-6928; 0196-6936; 0885-3401; 8755-8556; 0196-2256; 0747-7309; 1 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:113637 |
Serial |
7879 |
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Author |
Akselsson, R.; Orsini, C.; Meinert, D.L.; Johansson, T.B.; Van Grieken, R.E.; Kaufmann, H.C.; Chapman, K.R.; Nelson, J.W.; Winchester, J.W. |
Title |
Application of proton induced X-ray emission analysis to the St. Louis regional air pollution study |
Type |
P3 Proceeding |
Year |
1976 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:113633 |
Serial |
7481 |
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