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Author |
Vandelannoote, R.; Blommaert, W.; Gijbels, R.; van Grieken, R. |
![find record details (via OpenURL) openurl](img/xref.gif)
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Title |
Analysis of geothermal waters by spark source mass spectrometry |
Type |
A3 Journal article |
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Year |
1981 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
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Volume |
309 |
Issue |
4 |
Pages |
291-294 |
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Keywords |
A3 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Although the analysis of thermal water by spark-source mass spectrometry (SSMS) is rather timeconsuming, it allows the detection of about 20 elements of geochemical interest down to the ppb-level. A physical preconcentration is proposed in order to collect elements having quite different chemical properties, e.g. alkalis, transition elements, and elements occurring in anionic form. The relative sensitivity factors appear to be rather independent of the salt content of the graphite electrodes. Contrary to neutron activation analysis, SSMS has a quite uniform elemental sensitivity, and allows to determine elements for which neutron activation is not suitable, e.g. Sn and Pb. The precision of SSMS is however by a factor of about 2 worse than that obtained for neutron activation. |
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Place of Publication |
München |
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Wos |
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Publication Date |
2004-11-15 |
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ISSN |
0016-1152;1618-2650; |
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Additional Links |
UA library record |
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Times cited |
8 |
Open Access |
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Approved |
no |
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Call Number |
UA @ lucian @ c:irua:116638 |
Serial |
100 |
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Author |
Tavernier, S.M.F.; Nies, E.; Gijbels, R. |
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Title |
Hard-spere model for hydrodynamic chromatography systems |
Type |
A1 Journal article |
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Year |
1981 |
Publication |
Analytical proceedings |
Abbreviated Journal |
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Volume |
18 |
Issue |
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Pages |
31-34 |
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Keywords |
A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
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Place of Publication |
London |
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Wos |
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Publication Date |
2004-03-18 |
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Series Volume ![sorted by Series Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
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Edition |
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ISSN |
0144-557X; |
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Additional Links |
UA library record |
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Times cited |
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Approved |
no |
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Call Number |
UA @ lucian @ c:irua:110347 |
Serial |
1409 |
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Author |
Costa Dantas, C.; Da Silveira Dantas, H.; Van 't dack, L.; Van Grieken, R. |
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Title |
Analise de solos por meio de fluorescencia de raios-X nao-dispersiva |
Type |
A1 Journal article |
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Year |
1981 |
Publication |
Química nova |
Abbreviated Journal |
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Volume |
4 |
Issue |
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Pages |
110-116 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Series Volume ![sorted by Series Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
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ISSN |
0100-4042; 1678-7064 |
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Additional Links |
UA library record |
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Times cited |
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Open Access |
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no |
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Call Number |
UA @ admin @ c:irua:111435 |
Serial |
7438 |
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Permanent link to this record |
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Author |
Smits, J.; Van Grieken, R. |
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Title |
Chelating 2,2′-diaminodiethylamine cellulose filters and X-ray fluorescence for preconcentration and trace analysis of natural waters |
Type |
A1 Journal article |
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Year |
1981 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
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Volume |
9 |
Issue |
2 |
Pages |
81-92 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The 2,2′-diaminodiethylamine (DEN) functional group can be expected to have ideal properties for the chelation of transition metals and their collection from aqueous solutions, independent of the alkali and alkaline earth ions concentration. Introducing DEN into cellulose filters allows straightforward preconcentration of trace cations by a simple filtration step, and the DEN-filter constitutes a suitable target for X-ray fluorescence (XRF) analysis. The linearity between the XRF-response on the loaded DEN-filter and the trace cation concentration in the solution appears excellent, up to a total filter capacity of ca. 3 μeq.cm−2. The detection limits are around 0.5 μg. l−1 in most practical cases. Accuracy and precision are around 10%. The applicability of the proposed procedure is illustrated on a comparative basis by XRF-analysis of drinking water and surface water, after preconcentration by DEN-filtration and by alternative procedures. |
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Wos |
A1981LF48000001 |
Publication Date |
2007-07-07 |
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Series Volume ![sorted by Series Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
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ISSN |
0306-7319 |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
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Call Number |
UA @ admin @ c:irua:116571 |
Serial |
7638 |
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Permanent link to this record |
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Author |
Smits, J.; Van Grieken, R. |
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Title |
Enrichment of trace anions from water with 2,2'-diaminodiethylamine cellulose filters |
Type |
A1 Journal article |
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Year |
1981 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
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Volume |
123 |
Issue |
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Pages |
9-17 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Cellulose filters with immobilized 2,2'-diaminodiethylamine (DEN) functional groups are studied for trace anion preconcentration from aqueous solution, with subsequent x-ray fluorescence measurements. For most oxoanions with a central metal atom, nearly quantitative collection can be achieved by 10-cm2 DEN filters under the following optimized conditions: pH 36, filtration rate up to 0.5 ml cm-2 min-1, and sample volume up to 100 ml cm-2. The collection yield is independent of the trace oxoanion concentration up to at least 1.5 μmol cm-2. Although the DEN filter exhibits some selectivity towards oxoanions with a central metal atom, ionic strength affects the results; the collection efficiency is strongly depressed with salt (e.g. NaCl) concentrations above 0.01 M. The applicability of the DEN filter in anion collection is therefore limited to dilute solutions. |
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Wos |
A1981LA22400002 |
Publication Date |
2002-07-25 |
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Series Volume ![sorted by Series Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
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Series Issue |
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Edition |
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ISSN |
0003-2670; 1873-4324 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116437 |
Serial |
7922 |
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Permanent link to this record |
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Author |
Verbueken, A.; Van Grieken, R. |
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Title |
Influence on photoplate evaluation parameters in spark source mass spectrometric analysis |
Type |
A1 Journal article |
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Year |
1981 |
Publication |
Bulletin des sociétés chimiques belges |
Abbreviated Journal |
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Volume |
90 |
Issue |
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Pages |
331-341 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Series Volume ![sorted by Series Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
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Edition |
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ISSN |
0037-9646 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116626 |
Serial |
8099 |
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Permanent link to this record |
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Author |
Vos, L.; Robberecht, H.; Van Dyck, P.; Van Grieken, R. |
![goto web page (via DOI) doi](http://nano.uantwerpen.be/nanorefs/img/doi.gif)
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Title |
Multi-element analysis of urine by energy-dispersive x-ray fluorescence spectrometry |
Type |
A1 Journal article |
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Year |
1981 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
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Volume |
130 |
Issue |
1 |
Pages |
167-175 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
For multi-element analysis of human urine, 25-ml samples doped with yttrium as internal standard are evaporated gently and then ashed up to 460°C overnight. The residue is pelletized and analysed by energy-dispersive x-ray fluorescence. Acid addition to facilitate the digestion is not mandatory. Recoveries are nearly quantitative for traces of Fe, Ni, Cu, Zn and Sr, to a lesser extent for lead, but not for arsenic or selenium. The standard deviation per measurement is typically around 6%. The detection limits are such that some 10 elements can be determined simultaneously in normal urine, and possibly more in cases of importance to toxicology or industrial hygiene. |
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Wos |
A1981ME98900017 |
Publication Date |
2002-07-25 |
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Series Volume ![sorted by Series Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
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Edition |
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ISSN |
0003-2670; 1873-4324 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116439 |
Serial |
8285 |
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Permanent link to this record |
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Author |
Maenhaut, W.; Selen, A.; van Espen, P.; Van Grieken, R.; Winchester, W.J. |
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Title |
Pixe analysis of aerosol samples collected over the atlantic-ocean from a sailboat |
Type |
A1 Journal article |
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Year |
1981 |
Publication |
Nuclear instruments and methods |
Abbreviated Journal |
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Volume |
181 |
Issue |
1-3 |
Pages |
399-405 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
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Abstract |
Size-fractionated aerosol samples, collected over the Atlantic Ocean, were analyzed for up to 20 elements by PIXE. Using a sailboat as sampling platform, duplicate samples were taken for two-day periods by means of battery operated 6-stage cascade impactors, positioned about 8 m above the sea surface. In the PIXE analysis of the fine particle stages (stages 3 to 5) a 5 times smaller beam size was used than for stages 1 and 2. This led to significant improvement in the detection limits for the former stages. The results from the duplicate impactor samples were normally in good agreement, indicating that the combined uncertainty of sampling and PIXE analysis was of the order of 20%. The precision of the PIXE analysis alone was investigated by rebombarding some samples six months after the first analysis. The trends with time of the fine particle sulfur and the coarse particle iron concentrations are discussed in some detail. |
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Wos |
A1981LH81100073 |
Publication Date |
2002-11-11 |
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ISSN |
0029-554x; 1878-3759 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:113628 |
Serial |
8386 |
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Permanent link to this record |
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Author |
vanden Berghe, D.; Deelstra, H.; Robberecht, H.; Van Grieken, R. |
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Title |
Selenium content of soils and rye grass (Lolium multiflorum) in Belgium |
Type |
H3 Book chapter |
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Year |
1981 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
85-105
T2 - Mineral elements '80 : part 1 |
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Keywords |
H3 Book chapter; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Additional Links |
UA library record |
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Open Access |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:117483 |
Serial |
8506 |
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Permanent link to this record |
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Author |
Verbueken, A.; Michiels, E.; Van Grieken, R. |
![find record details (via OpenURL) openurl](img/xref.gif)
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Title |
Total analysis of plant material and biological tissue by spark source mass spectrometry |
Type |
A3 Journal article |
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Year |
1981 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
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Volume |
309 |
Issue |
4 |
Pages |
300-304 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Analysis of biological material by spark source mass spectrometry is reported. Preliminary studies mainly based upon the analysis of the NBS standard reference material SRM-1571 (Orchard Leaves) are described. Attention is drawn to the importance of a suitable sample preparation method. The advantages of a wet digestion technique in a Teflon bomb are discussed and its use is justified by the satisfactory overall analysis precision of about 20%. |
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Publication Date |
2004-11-15 |
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Series Volume ![sorted by Series Volume (numeric) field, ascending order (up)](img/sort_asc.gif) |
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Edition |
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ISSN |
0016-1152 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116639 |
Serial |
8675 |
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Permanent link to this record |