Records |
Author |
Van Dyck, P.; Van Grieken, R. |
Title |
Automated energy-dispersive X-ray fluorescence analysis for diverse environmental samples |
Type |
H3 Book chapter |
Year |
1982 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
315-324
T2 - Analytical techniques in environmenta |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117484 |
Serial |
7536 |
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Author |
Chakravorty, R.; Van Grieken, R. |
Title |
Co-precipitation with iron hydroxide and X-ray fluorescence analysis of trace metals in water |
Type |
A1 Journal article |
Year |
1982 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
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Volume |
11 |
Issue |
1 |
Pages |
67-80 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Preconcentration of transition trace ions by coprecipitation on iron-hydroxide has been combined with energy-dispersive X-ray fluorescence for environmental water analysis. The optimized preconcentration procedure implies adding 2 mg of iron to a 200 ml water sample, adding dilute NaOH up to pH 9, filtering off on a Nuclepore membrane after a 1 h equilibration time, and analyzing. Quantitative recoveries could then be obtained for Ni, Cu, Zn and Pb, e.g. at the 10 μg/l level in waters of varying salinity while Mn was partially collected. (In fact, for a given problem the iron carrier amount can be adjusted to obtain a satisfactory compromise between high recovery and low detection limit). The precision is 7-8% at the 10 μg/l level, and the detection limits are in the 0.5-1 μg/l range. Various environmental water samples are analysed by way of illustration. |
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A1982NG99200007 |
Publication Date |
2007-07-07 |
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Edition |
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ISSN |
0306-7319 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116573 |
Serial |
7676 |
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Author |
Van Grieken, R.; Van 't dack, L.; Costa Dantas, C.; Moura de Amorim, W.; Maenhaut, W. |
Title |
Elemental constituents of atmospheric aerosols in Recife, North-East Brazil |
Type |
A3 Journal article |
Year |
1982 |
Publication |
Environmental pollution: series B : chemical and physical |
Abbreviated Journal |
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Volume |
4 |
Issue |
2 |
Pages |
143-163 |
Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Few data are available on the inorganic atmospheric pollution in the rapidly expanding cities of South America, like Recife, on the Atlantic Coast of North-east Brazil. Therefore, the elemental composition of atmospheric aerosols was investigated for nine sites in the Recife conurbation and a fairly remote site in the area. Total aerosol samples were collected on cellulose filters for analysis by energy dispersive X-ray fluorescence and cascade impactors were used to collect the aerosols as a function of particle size for subsequent analysis by proton-induced X-ray emission. Local soil aliquots were also analysed. About eighteen elements were quantified in all cases. The average total atmospheric concentrations appeared to be well above natural levels but usually lower than, or comparable with, those of North American and European cities. Dispersal of sea spray and of local soil (often contaminated with, for example, Cu, Zn and Pb from industrial sources) contributes predominantly to the total atmospheric load in Recife. However, the particle size fraction results also indicated strong excesses in the small particle mode for S, K, V, Mn, Ni, Cu, Zn, Br and Pb, mainly in the downtown area. Again, the corresponding enrichment factors were only moderate in comparison with other published urban data. |
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Publication Date |
2003-09-11 |
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ISSN |
0143-148x; 1878-0695 |
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no |
Call Number |
UA @ admin @ c:irua:111437 |
Serial |
7894 |
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Author |
Van Grieken, R.; Robberecht, H.; Shani, J.; Van Dyck, P.; Vos, L. |
Title |
Energy-dispersive X-ray fluorescence for direct trace analysis of biomedical and environmental samples |
Type |
H3 Book chapter |
Year |
1982 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
159-178
T2 - X-ray fluorescence (XRF and PIXE) in |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117485 |
Serial |
7904 |
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Author |
Robberecht, H.; Van Grieken, R.; Shani, J.; Barak, S. |
Title |
Evaluation of multi-element analysis of blood serum by energy-dispersive x-ray spectrometry |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
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Volume |
136 |
Issue |
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Pages |
285-292 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Conventional energy-dispersive x-ray fluorescence is applied in the analysis of blood serum to give the concentrations of 710 elements simultaneously with minimal manipulation of the samples. Simple spotting onto a Mylar carrier of 250 μl of serum, doped with two internal standards, was chosen as the sample preparation step. Some 200 serum samples, analyzed in replicate (n = 26), were used to evaluate this procedure. The detection limits are 4 μg ml-1 for K and Ca, 0.50.2 μg ml-1 for Fe, Cu, Pb and Zn, and less than 0.1 μg ml-1 for Se, Rb and Sr. Well above these limits, the standard deviation is around 10%. Comparison with the results of other measurements on the same samples indicates an accuracy of that order. The simplicity and high throughput, and the possibility of automating the x.r.f. measurements, make the proposed procedure suitable for screening large numbers of sera. |
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Wos |
A1982NL48600032 |
Publication Date |
2002-07-25 |
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ISSN |
0003-2670; 1873-4324 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116440 |
Serial |
7940 |
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Author |
Denoyer, E.; Van Grieken, R.; Adams, F.; Ntausch, D.F.S. |
Title |
Laser microprobe mass spectrometry : 1 : basic principles and performance characteristics |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Analytical chemistry |
Abbreviated Journal |
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Volume |
54 |
Issue |
1 |
Pages |
26a-33a |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
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Publication Date |
2012-05-29 |
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Edition |
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ISSN |
0003-2700; 5206-882x |
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UA library record |
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no |
Call Number |
UA @ admin @ c:irua:116517 |
Serial |
8164 |
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Author |
Robberecht, H.J.; Van Grieken, R.E.; Van den Bosch, P.A.; Deelstra, H.; vanden Berghe, D. |
Title |
Losses of metabolically incorporated selenium in common digestion procedures for biological material |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
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Volume |
29 |
Issue |
11 |
Pages |
1025-1028 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Two common procedures for wet destruction of biological materials for subsequent determination of selenium have been investigated. Rat organs and biological fluids were endogenously labelled with 75Se to monitor losses during the procedures. Addition of nitric and perchloric acids with gradual heating up to 210° seemed to be the best method: at this temperature the labelled selenium was still recovered quantitatively, and the destruction was fast and efficient. |
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Wos |
A1982PP35500009 |
Publication Date |
2002-07-25 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0039-9140; 1873-3573 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116568 |
Serial |
8186 |
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Author |
Robberecht, H.; Deelstra, H.; vanden Berghe, D.; Van Grieken, R. |
Title |
Percentage selenium in consumed belgian feeding |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Revue des fermentations et des industries alimentaires |
Abbreviated Journal |
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Volume |
37 |
Issue |
6 |
Pages |
188-201 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
A1982QX42300003 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0035-2071 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:167192 |
Serial |
8369 |
Permanent link to this record |
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Author |
Van Grieken, R. |
Title |
Preconcentration methods for the analysis of water by X-ray spectrometric techniques |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
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Volume |
143 |
Issue |
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Pages |
3-34 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
All published procedures for multi-element preconcentration of trace elements, prior to x-ray fluorescence analysis of water, are reviewed and critically evaluated. Most preconcentration methods applied to the determination of single elements in water are also listed. |
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A1982PT27300002 |
Publication Date |
2002-10-14 |
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ISSN |
0003-2670; 1873-4324 |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:116441 |
Serial |
8401 |
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Author |
Robberecht, H.; Van Grieken, R. |
Title |
Selenium in environmental waters : determination, speciation and concentration levels |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
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Volume |
29 |
Issue |
10 |
Pages |
823-844 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
This article reviews the different methods used for the determination of selenium species in all types of environmental waters. Basic difficulties are discussed and the efficiency of the methods is explained in view of the sub-μg/1. concentration levels. Special attention is paid to preconcentration steps. Published data on speciation and concentration levels in various water samples are critically reviewed. |
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Wos |
A1982PK22900004 |
Publication Date |
2002-07-25 |
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Edition |
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ISSN |
0039-9140; 1873-3573 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:113627 |
Serial |
8509 |
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Author |
Robberecht, H.; vanden Berghe, D.; Deelstra, H.; Van Grieken, R. |
Title |
Selenium in the Belgian soils and its uptake by rye-grass |
Type |
A1 Journal article |
Year |
1982 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
25 |
Issue |
1 |
Pages |
61-69 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Data obtained by atomic absorption spectroscopy showed a selenium concentration of only 0.11 ppm as an average value for the most representative agricultural soils in Belgium. The selenium content in rye-grass grown on different soil types was between 0.05 and 0.11 ppm, and positively correlated with the soil selenium level. Addition of selenium in the form of selenite to the different soil types resulted in an increased selenium uptake by the plant. The ultimate concentration in the plant depended on the structural and chemical composition of the soil. Twelve other elements were determined in the soils by energy-dispersive X-ray fluorescence; none showed a strong correlation with the soil selenium content or with the selenium uptake by ryegrass. |
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A1982PJ93000006 |
Publication Date |
2003-09-12 |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116646 |
Serial |
8510 |
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Author |
Shani, J.; Barak, S.; Ram, M.; Levi, D.; Pfeifer, Y.; Schlesinger, T.; Avrach, W.W.; Robberecht, H.; Van Grieken, R. |
Title |
Serum bromine levels in psoriasis |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Pharmacology |
Abbreviated Journal |
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Volume |
25 |
Issue |
6 |
Pages |
297-307 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Serum bromine levels in psoriatic Danes increased 2- to 3-fold during a 4-week bathing course in the Dead Sea. This increase correlated well with the improvement in their clinical and psychic condition. Serum bromine levels in psoriatic Danes were somewhat lower than those in healthy subjects residing in Denmark, but the difference was not significant. Israelis working in the open air in the Dead Sea area (air bromine 20-fold higher than in Jerusalem) had higher bromine levels than psoriatic or healthy Israelis residing in Jerusalem or healthy Israelis working in air-conditioned rooms in the Dead Sea area (p < 0.05), but those levels were still within the normal range. As our animal experimentation indicates that the skin is a major target organ for 82Br, applied either by bathing or as an aerosol, we conclude that the higher bromine levels noticed in the psoriatic Danes after their 4-week stay at the Dead Sea may be equally due to their contact with the bromine-containing aerosol and the high bromine level of the Dead Sea waters. |
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A1982PV13800001 |
Publication Date |
2008-06-05 |
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Edition |
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ISSN |
0031-7012 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Open Access |
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no |
Call Number |
UA @ admin @ c:irua:116653 |
Serial |
8515 |
Permanent link to this record |