Records |
Author |
Robberecht, H.; Deelstra, H.; Van Grieken, R. |
Title |
Determination of selenium in blood components by X-ray emission spectrometry |
Type |
A1 Journal article |
Year |
1990 |
Publication |
Biological trace element research |
Abbreviated Journal |
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Volume |
25 |
Issue |
3 |
Pages |
149-185 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Sampling, storing, sample pretreatment, and experimental conditions for selenium (Se) determination in human serum, plasma, and whole blood by X-ray emission spectrometric (XRS) methods are described. Concentration levels in these biological fluids, found by this technique, are discussed and compared to values found by other techniques for the same healthy population group in the same area. XRS analysis of blood from patients with various pathological conditions is reviewed, with special attention to the relation of Se with the concentration level of other essential or nonessential trace elements. |
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Wos |
A1990DT88700001 |
Publication Date |
2008-11-18 |
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Series Volume |
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Edition |
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ISSN |
0163-4984 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116798 |
Serial |
7788 |
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Author |
Claes, M.; van Dyck, K.; Deelstra, H.; Van Grieken, R. |
Title |
Determination of silicon in organic matrices with grazing-emission X-ray fluorescence spectrometry |
Type |
A1 Journal article |
Year |
1999 |
Publication |
Spectrochimica acta: part B : atomic spectroscopy |
Abbreviated Journal |
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Volume |
54 |
Issue |
10 |
Pages |
1517-1524 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The potential of a prototype grazing-emission X-ray fluorescence spectrometer for reliable analysis of sample solutions, obtained by pressurized microwave oven digestion of Si-spiked organic and biological materials, was investigated as part of an inter-laboratory study. The fact that this grazing-emission technique is based on the total reflection phenomenon and wavelength-dispersive detection, gives it the benefit to determine light elements in a sensitive way. Results of the determination of silicon in pork liver, cellulose, urine, serum, spinach, beer, mineral water and horsetail (dry plant extract) samples are presented. Some of the results are compared with those obtained with other analytical techniques. The study proved that determination of silicon traces in biological matrices represents an extremely difficult task, however, measurements of silicon are achieved with acceptable precision. The most important problems still arise when sample pre-treatment is needed prior to analysis. (C) 1999 Elsevier Science B.V. All rights reserved. |
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Wos |
000083433600018 |
Publication Date |
2002-08-30 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0584-8547; 1873-3565 |
ISBN |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:25943 |
Serial |
7789 |
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Author |
Robberecht, H.J.; Van Grieken, R.E.; Van den Bosch, P.A.; Deelstra, H.; vanden Berghe, D. |
Title |
Losses of metabolically incorporated selenium in common digestion procedures for biological material |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Talanta : the international journal of pure and applied analytical chemistry |
Abbreviated Journal |
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Volume |
29 |
Issue |
11 |
Pages |
1025-1028 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Two common procedures for wet destruction of biological materials for subsequent determination of selenium have been investigated. Rat organs and biological fluids were endogenously labelled with 75Se to monitor losses during the procedures. Addition of nitric and perchloric acids with gradual heating up to 210° seemed to be the best method: at this temperature the labelled selenium was still recovered quantitatively, and the destruction was fast and efficient. |
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Wos |
A1982PP35500009 |
Publication Date |
2002-07-25 |
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Edition |
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ISSN |
0039-9140; 1873-3573 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116568 |
Serial |
8186 |
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Author |
Robberecht, H.; Deelstra, H.; vanden Berghe, D.; Van Grieken, R. |
Title |
Metal pollution and selenium distributions in soils and grass near a non-ferrous plant |
Type |
A1 Journal article |
Year |
1983 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
29 |
Issue |
3 |
Pages |
229-241 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Multi-element analysis results of direct energy-dispersive X-ray fluorescence of soil samples taken in the vicinity of a non-ferrous plant in Antwerp are reported. High concentrations of Pb, Cu, Zn, As and Se are found in nearby residential areas, especially in top-soil layers. Selenium pollution appears not to be leached significantly to lower soil horizons, but it is available for uptake by rye-grass, in which toxic levels are found. Results are compared to literature data. Hydride generation atomic absorption spectrometry proved to be unsuitable for direct analysis of the heavily contaminated soils. |
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Wos |
A1983RE16300003 |
Publication Date |
2003-09-12 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:116648 |
Serial |
8218 |
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Author |
Robberecht, H.; Deelstra, H.; vanden Berghe, D.; Van Grieken, R. |
Title |
Percentage selenium in consumed belgian feeding |
Type |
A1 Journal article |
Year |
1982 |
Publication |
Revue des fermentations et des industries alimentaires |
Abbreviated Journal |
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Volume |
37 |
Issue |
6 |
Pages |
188-201 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
A1982QX42300003 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0035-2071 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:167192 |
Serial |
8369 |
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Author |
vanden Berghe, D.; Deelstra, H.; Robberecht, H.; Van Grieken, R. |
Title |
Selenium content of soils and rye grass (Lolium multiflorum) in Belgium |
Type |
H3 Book chapter |
Year |
1981 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
85-105
T2 - Mineral elements '80 : part 1 |
Keywords |
H3 Book chapter; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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UA library record |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:117483 |
Serial |
8506 |
Permanent link to this record |
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Author |
Robberecht, H.; Deelstra, H.; vanden Berghe, D.; Van Grieken, R. |
Title |
Selenium gehalten van levensmiddelen geconsumeerd in België |
Type |
A3 Journal article |
Year |
1983 |
Publication |
Revue des fermentations et des industries alimentaires |
Abbreviated Journal |
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Volume |
37 |
Issue |
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Pages |
188-201 |
Keywords |
A3 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0035-2071 |
ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:116701 |
Serial |
8507 |
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Author |
Robberecht, H.; Van Grieken, R.; van Sprundel, M.; vanden Berghe, D.; Deelstra, H. |
Title |
Selenium in environmental and drinking waters of Belgium |
Type |
A1 Journal article |
Year |
1983 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
26 |
Issue |
2 |
Pages |
163-172 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The tetravalent and hexavalent selenium content of water samples can be determined by conventional energy-dispersive X-ray fluorescence after different preconcentration steps. Selenium values of nearly three-hundred different environmental and drinking water samples in Belgium are reported. The results are quite low, ranging from the detection limits up to 1 μg l−1. The concentration levels are compared to literature data and the speciation is discussed. The contribution of drinking water to the daily intake of selenium in Belgium ranges from less than 0.2 to 5%. |
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Wos |
A1983QD20900006 |
Publication Date |
2003-09-12 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:116647 |
Serial |
8508 |
Permanent link to this record |
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Author |
Robberecht, H.; vanden Berghe, D.; Deelstra, H.; Van Grieken, R. |
Title |
Selenium in the Belgian soils and its uptake by rye-grass |
Type |
A1 Journal article |
Year |
1982 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
25 |
Issue |
1 |
Pages |
61-69 |
Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Data obtained by atomic absorption spectroscopy showed a selenium concentration of only 0.11 ppm as an average value for the most representative agricultural soils in Belgium. The selenium content in rye-grass grown on different soil types was between 0.05 and 0.11 ppm, and positively correlated with the soil selenium level. Addition of selenium in the form of selenite to the different soil types resulted in an increased selenium uptake by the plant. The ultimate concentration in the plant depended on the structural and chemical composition of the soil. Twelve other elements were determined in the soils by energy-dispersive X-ray fluorescence; none showed a strong correlation with the soil selenium content or with the selenium uptake by ryegrass. |
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Wos |
A1982PJ93000006 |
Publication Date |
2003-09-12 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
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Open Access |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:116646 |
Serial |
8510 |
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Author |
van Dyck, K.; Robberecht, H.; van Cauwenbergh, R.; Deelstra, H.; Arnaud, J.; Willemyns, L.; Benijts, F.; Centeno, J.A.; Taylor, H.; Soares, M.E.; Bastos, M.L.; Ferreira, M.A.; d'Haese, P.C.; Lamberts, L.V.; Hoenig, M.; Knapp, G.; Lugowski, S.J.; Moens, L.; Riondato, J.; Van Grieken, R.; Claes, M.; Verheyen, R.; Clement, L.; Uytterhoeven, M. |
Title |
Spectrometric determination of silicon in food and biological samples: an interlaboratory trial |
Type |
A1 Journal article |
Year |
2000 |
Publication |
Journal of analytical atomic spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
6 |
Pages |
735-741 |
Keywords |
A1 Journal article; Behavioural Ecology & Ecophysiology; Pathophysiology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Accuracy and precision of silicon determination in biological matrices (serum, urine, water, beer and spinach) by spectrometric techniques (when necessary after acid destruction) were assessed by means of a collaborative interlaboratory trial. The trial was set up in accordance with ISO 5725-2 (1994). The relative overall repeatability standard deviation was acceptable. It varied between 4% for spinach powder (mean content: 176 mg kg(-1)) and 11% for serum (mean content: 5.33 mg L-1). On the other hand, the relative overall between-laboratory standard deviation was found to vary from a satisfactorily 15% for spinach after destruction (mean content: 3.32 mg L-1) to an unacceptable 107% for spinach powder (mean content: 176 mg kg(-1)). The overall conclusion of the trial was that silicon determination in biological matrices can properly be performed by spectrometric techniques. However, when sample pretreatment (i.e., acid destruction) is needed prior to silicon determination problems still remain. |
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000087419300025 |
Publication Date |
2002-07-26 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0267-9477 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Open Access |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:27841 |
Serial |
8574 |
Permanent link to this record |