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Author Wagaarachchige, J.; Idris, Z.; Kummamuru, N.B.; Sætre, K.A.; Halstensen, M.; Jens, K.-J.
Title A new sulfolane based solvent for CO₂ capture Type P1 Proceeding
Year 2021 Publication (down) SSRN electronic journal Abbreviated Journal
Volume Issue Pages
Keywords P1 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract This study presents novel sulfolane based non-aqueous CO2 capture solvents, as an alternative solution for capturing CO2 from industrial processes. In order to select the most promising amine system, five different amines were tested by monitoring CO2 absorption and desorption processes using the time-base Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy. During absorption experiments, we observed the formation of Monomethyl Carbonate (MMC) in diisopropylamine (DIPA) and 2-amino-2-methyl-1-propanol (AMP) systems, while carbamate was observed as the main product for the other three amine systems tested. In regeneration experiments, the MMC could be desorbed relatively easily from the amine solution at a mild temperature.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2021-04-17
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access OpenAccess
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:180364 Serial 8305
Permanent link to this record
 

 
Author Čevik, U.; Akbulut, S.; Makarovska, Y.; Van Grieken, R.
Title Polarized-beam high-energy EDXRF in geological samples Type A1 Journal article
Year 2013 Publication (down) Spectroscopy letters Abbreviated Journal
Volume 46 Issue 1 Pages 36-46
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Certified reference materials (NIST 1645, BCR 143, IAEA 7, BCR 141, NIESCRM02, and IAEA 375) were used for determining the performance of a secondary target energy-dispersive X-ray fluorescence (EDXRF) spectrometer, Epsilon 5 (PANalytical, Almelo, the Netherlands). For the evaluation of the EDXRF spectra with polarized-beam high-energy excitation, the WinAxil software package has been applied. The results showed that Epsilon 5, EDXRF spectrometry is favorable for the determination of elemental concentrations in geological samples, but the sample preparation has the largest influence on the precision. However, they presented good agreement with certified values for most of the elements.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000314018900005 Publication Date 2013-01-03
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0038-7010 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:106754 Serial 8392
Permanent link to this record
 

 
Author Potgieter-Vermaak, S.; Van Grieken, R.; Potgieter, J.H.
Title Integrated analytical techniques for the characterisation of environmental particles Type A1 Journal article
Year 2010 Publication (down) Spectroscopy Europe Abbreviated Journal
Volume 22 Issue 5 Pages 12-15
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0966-0941; 2634-2561 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:85517 Serial 8109
Permanent link to this record
 

 
Author Gijbels, R.; Bogaerts, A.
Title Modeling of glow discharge ion sources for mass spectrometry: potentials and limitations Type A3 Journal article
Year 1997 Publication (down) Spectroscopy Abbreviated Journal
Volume 9 Issue 2 Pages 8-14
Keywords A3 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 0000-00-00
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ lucian @ c:irua:19600 Serial 2123
Permanent link to this record
 

 
Author Darchuk, L.A.; Zaverbna, L.V.; Bebeshko, V.G.; Worobiec, A.; Stefaniak, E.A.; Van Grieken, R.
Title Infrared investigation of hard human teeth tissues exposed to various doses of ionizing radiation from the 1986 Chernobyl accident Type A1 Journal article
Year 2008 Publication (down) Spectroscopy Abbreviated Journal
Volume 22 Issue 2/3 Pages 105-111
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000256194800004 Publication Date 2012-04-29
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0712-4813 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:68796 Serial 8100
Permanent link to this record
 

 
Author Van Grieken, R.; Roekens, E.; Sweevers, H.; Vleugels, G.
Title Spectroscopy and ion chromatography to study the effects of air pollution on historical buildings Type A1 Journal article
Year 1989 Publication (down) Spectroscopy Abbreviated Journal
Volume 10 Issue Pages 70-81
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0712-4813 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116826 Serial 8575
Permanent link to this record
 

 
Author Aerts, A.; Janssens, K.; Velde, B.; Dijkman, W.
Title Change in silica sources in Roman and post Roman glass Type A1 Journal article
Year 2003 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 58 Issue 4 Pages 659-667
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000182744200009 Publication Date 2003-04-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 2003 IF: 2.361
Call Number UA @ admin @ c:irua:41207 Serial 5499
Permanent link to this record
 

 
Author Schalm, O.; Janssens, K.; Caen, J.
Title Characterization of the main causes of deterioration of grisaille paint layers in 19th C. stained-glass windows by J.-B. Capronnier Type A1 Journal article
Year 2003 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 58 Issue 4 Pages 589-607
Keywords A1 Journal article; Art; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Twenty-seven glass fragments containing dark coloured grisaille paint layers of different qualities were collected from ten windows of the cathedral St. Michael & St. Gudule in Brussels (Belgium). The windows were made by J.-B. Capronnier (18141891) and cover the period between 1843 and 1878. The samples were cross-sectioned and examined in an electron microscope. Grisaille paint layers are not homogeneous and therefore, it is not meaningful to characterize them in terms of their average composition. Instead, parameters such as granularity, the number of residual gas bubbles per running millimetre of paint, the type of pigments, and the thickness of the paint layer were used to characterize them. The microscopic morphology allows a classification of the grisaille paint layers in four groups, every group associated with a quality level. Moreover, the main causes of the accelerated degradation of some of these paint layers could be explained. The classification made it possible to distinguish two periods in the work of Capronnier: (1) the early period (18431848) is characterized by the presence of either single granular paint layers or of double-layered systems consisting of a granular paint layer on top of a well-melted paint layer. The granular grisaille paint layers tend to pulverize; (2) the later period (18481878) is characterized by the presence of only well-vitrified paint layers. No sign of deterioration was found on the well-vitrified paint layers.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000182744200002 Publication Date 2003-04-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 2003 IF: 2.361
Call Number UA @ admin @ c:irua:41208 Serial 5505
Permanent link to this record
 

 
Author Schalm, O.; Janssens, K.
Title A flexible and accurate quantification algorithm for EPXMA based on thin-film element yields Type A1 Journal article
Year 2003 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 58 Issue 4 Pages 669-680
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000182744200010 Publication Date 2003-04-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 2003 IF: 2.361
Call Number UA @ admin @ c:irua:41205 Serial 5623
Permanent link to this record
 

 
Author Vincze, L.; Janssens, K.; Adams, F.
Title A general Monte-Carlo simulation of energy-dispersive X-ray fluorescence spectrometers : 1 : unpolarized radiation, homogenious samples Type A1 Journal article
Year 1993 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 48 Issue 4 Pages 553-573
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract A general Monte Carlo program for the simulation of X-ray fluorescence (XRF) spectrometers is presented. The global layout of the program is discussed and the way in which variance reduction techniques have been employed to improve the efficiency of the code is described. For the case of polychromatic excitation in a direct excitation energy-dispersive (ED) XRF instrument, experimentally collected ED-XRF spectra are compared with simulated spectral distributions. Applications of the software in the field of quantitative analysis and thickness estimation of samples of intermediate thickness illustrate the potential of the method.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1993KY21500006 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:6118 Serial 5632
Permanent link to this record
 

 
Author Somogyi, A.; Janssens, K.; Vincze, L.; Vekemans, B.; Rindby, A.; Adams, F.
Title Interpretation and use of inter-element correlation graphs obtained by scanning X-ray fluorescence micro-beam spectrometry from individual particles: part 1: theory Type A1 Journal article
Year 2000 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 55 Issue Pages 75-89
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000085660100006 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 2000 IF: 2.608
Call Number UA @ admin @ c:irua:27562 Serial 5667
Permanent link to this record
 

 
Author Somogyi, A.; Janssens, K.; Vincze, L.; Vekemans, B.; Rindby, A.; Adams, F.
Title Interpretation and use of inter-element correlation graphs obtained by scanning X-ray fluorescence micro-beam spectrometry from individual particles: part 2: application Type A1 Journal article
Year 2000 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 55 Issue Pages 1039-1049
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000088353100033 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 2000 IF: 2.608
Call Number UA @ admin @ c:irua:31700 Serial 5668
Permanent link to this record
 

 
Author Vittiglio, G.; Janssens, K.; Adams, F.; Oost, A.
Title Localised and non-destructive analysis of metallic artefacts from ancient Egypt by means of a compact μ-XRF instrument Type A1 Journal article
Year 1999 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 54 Issue Pages 1697-1710
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000083798600002 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 1999 IF: 2.421
Call Number UA @ admin @ c:irua:26195 Serial 5694
Permanent link to this record
 

 
Author Janssens, K.; Vekemans, B.; Vincze, L.; Adams, F.; Rindby, A.
Title A micro XRF spectrometer based on rotating anode generator and capillary optics Type A1 Journal article
Year 1996 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 51 Issue 13 Pages 1661-1678
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:14256 Serial 5720
Permanent link to this record
 

 
Author Vincze, L.; Janssens, K.; Vekemans, B.; Adams, F.
Title Monte Carlo simulation of X-ray fluorescence spectra: part 4: photon scattering at high X-ray energies Type A1 Journal article
Year 1999 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume Issue Pages 1711-1722
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000083798600003 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 1999 IF: 2.421
Call Number UA @ admin @ c:irua:26354 Serial 5738
Permanent link to this record
 

 
Author Kempenaers, L.; Vincze, L.; Janssens, K.
Title The use of synchrotron micro-XRF for characterisation of the micro-heterogeneity of low-Z reference materials Type A1 Journal article
Year 2000 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 55 Issue Pages 651-669
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000087765700008 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 2000 IF: 2.608
Call Number UA @ admin @ c:irua:28445 Serial 5900
Permanent link to this record
 

 
Author Margui, E.; Hidalgo, M.; Queralt, I.; van Meel, K.; Fontas, C.
Title Analytical capabilities of laboratory, benchtop and handheld X-ray fluorescence systems for detection of metals in aqueous samples pre-concentrated with solid-phase extraction disks Type A1 Journal article
Year 2012 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 67 Issue Pages 17-23
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract We aimed to achieve improved instrumental sensitivity and detection limits for the analysis of several elements (Cu, Ni, Zn, Pb and Cd) in aqueous samples with energy dispersive X-ray fluorescence spectrometry (EDXRF). The metals were pre-concentrated from aqueous solutions using commercially available organic-based solid-phase extraction (SPE) disks functionalized with iminodiacetate groups. These thin-layer organic materials provide an ideal support for XRF analysis. The elements were collected on the SPE extraction disks using a simple filtration procedure (starting with 1 L of aqueous sample) that allows direct XRF measurements to be performed in the field (in situ). We evaluated the analytical possibilities and drawbacks of using this pre-concentration procedure in combination with the following XRF configurations: a handheld unit, a benchtop EDXRF system and a high-energy polarized-beam EDXRF instrument (HE-P-EDXRF). Using the HE-P-EDXRF system, the detection limits for all metals were more than one order of magnitude lower than those attained using handheld and benchtop EDXRF instrumentation. For the detection of metal concentrations higher than similar to 20 mu g/L, however, handheld or benchtop systems remain a very good option due to their extreme simplicity of operation and low-cost, compact design. We demonstrate the application of these methodologies, using the three equipment systems, to the analysis of trace concentrations of metals in different types of aqueous samples, including tap water and waste water. (C) 2011 Elsevier B.V. All rights reserved.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000302757200003 Publication Date 2011-12-19
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:98338 Serial 7454
Permanent link to this record
 

 
Author Uzonyi, I.; Szöör, G.; Vekemans, B.; Vincze, L.; Rozsa, P.; Szabo, G.; Somogyi, A.; Adams, F.; Kiss, Á.Z.
Title Application of combined micro-proton-induced X-ray emission and micro-synchrotron radiation X-ray fluorescence techniques for the characterization of impact materials around Barringer Meteor Crater Type A1 Journal article
Year 2004 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 59 Issue Pages 1717-1723
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000224848000031 Publication Date 2004-09-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:49638 Serial 7469
Permanent link to this record
 

 
Author Szalóki, I.; Varga, K.; Van Grieken, R.
Title Application of energy dispersive X-ray spectrometry for quantitative evaluation of sorption phenomena at solid-liquid interfaces Type A1 Journal article
Year 2000 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 55 Issue Pages 1031-1038
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000088353100032 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:32124 Serial 7473
Permanent link to this record
 

 
Author Tsuji, K.; Huisman, M.; Spolnik, Z.; Wagatsuma, K.; Mori, Y.; Van Grieken, R.E.; Vis, R.D.
Title Comparison of grazing-exit particle-induced X-ray emission with other related methods Type A1 Journal article
Year 2000 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 55 Issue Pages 1009-1016
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000088353100030 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:31671 Serial 7692
Permanent link to this record
 

 
Author Osán, J.; Török, S.; Alföldy, B.; Alsecz, A.; Falkenberg, G.; Baik, S.Y.; Van Grieken, R.
Title Comparison of sediment pollution in the rivers of the Hungarian Upper Tisza Region using non-destructive analytical techniques Type A1 Journal article
Year 2007 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 62 Issue 2 Pages 123-136
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000246087100006 Publication Date 2007-02-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:63420 Serial 7696
Permanent link to this record
 

 
Author Kips, R.; Pidduck, A.J.; Houlton, M.R.; Leenaers, A.; Mace, J.D.; Marie, O.; Pointurier, F.; Stefaniak, E.A.; Taylor, P.D.P.; van den Berghe, S.; van Espen, P.; Van Grieken, R.; Wellum, R.
Title Determination of fluorine in uranium oxyfluoride particles as an indicator of particle age Type A1 Journal article
Year 2009 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 64 Issue 3 Pages 199-207
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)
Abstract As swipe samples from enrichment activities typically contain uranium particles with a detectable amount of fluorine, the question was raised whether the analysis of fluorine in particles could complement the information on the uranium isotope ratios. For this, uranium oxyfluoride particles were prepared from the controlled hydrolysis of uranium hexafluoride (UF6). The relative amount of fluorine was characterized by scanning electron microscopy combined with energy-dispersive X-ray spectrometry (SEM-EDX), as well as ion-microprobe secondary ion mass spectrometry (IM-SIMS). Of particular interest was the assessment of the reduction of the amount of fluorine over time, and after exposure to UV-light and high temperatures. Micro-Raman spectrometry (MRS) was applied to look for differences in molecular structure between these various sample types. Both SEM-EDX and IM-SIMS showed a general reduction of the fluorine-to-uranium ratio after 12 years of storage. The exposure to UV-light and high temperatures was found to have accelerated the loss of fluorine. A distinct peak at 865 cm− 1 Raman shift was detected for the majority of particles analyzed by MRS. For the particles that were heat-treated, the Raman spectra were similar to the spectrum of U3O8. Although often large variations were observed between particles from the same sample, the three particle measurement techniques (IM-SIMS, SEM-EDX and MRS) showed some consistent trends. They therefore appear promising in terms of the ability to place bounds on particle age, as well as shedding light on the complex processes involved in UO2F2 particle ageing.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000265755600002 Publication Date 2008-12-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:77057 Serial 7780
Permanent link to this record
 

 
Author Claes, M.; van Dyck, K.; Deelstra, H.; Van Grieken, R.
Title Determination of silicon in organic matrices with grazing-emission X-ray fluorescence spectrometry Type A1 Journal article
Year 1999 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 54 Issue 10 Pages 1517-1524
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The potential of a prototype grazing-emission X-ray fluorescence spectrometer for reliable analysis of sample solutions, obtained by pressurized microwave oven digestion of Si-spiked organic and biological materials, was investigated as part of an inter-laboratory study. The fact that this grazing-emission technique is based on the total reflection phenomenon and wavelength-dispersive detection, gives it the benefit to determine light elements in a sensitive way. Results of the determination of silicon in pork liver, cellulose, urine, serum, spinach, beer, mineral water and horsetail (dry plant extract) samples are presented. Some of the results are compared with those obtained with other analytical techniques. The study proved that determination of silicon traces in biological matrices represents an extremely difficult task, however, measurements of silicon are achieved with acceptable precision. The most important problems still arise when sample pre-treatment is needed prior to analysis. (C) 1999 Elsevier Science B.V. All rights reserved.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000083433600018 Publication Date 2002-08-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:25943 Serial 7789
Permanent link to this record
 

 
Author Tsuji, K.; Spolnik, Z.; Wagatsuma, K.; Zhang, J.; Van Grieken, R.E.
Title Enhancement of electron-induced X-ray intensity for single particles under grazing-exit conditions Type A1 Journal article
Year 1999 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 54 Issue Pages 1243-1251
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000082048700010 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:27583 Serial 7917
Permanent link to this record
 

 
Author Tsuji, K.; Takenaka, H.; Wagatsuma, K.; de Bokx, P.K.; Van Grieken, R.E.
Title Enhancement of X-ray fluorescence intensity from an ultra-thin sandwiched layer at grazing-emission angles Type A1 Journal article
Year 1999 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 54 Issue Pages 1881-1888
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000084169300013 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:27585 Serial 7918
Permanent link to this record
 

 
Author Bekshaev, A.; de Hoog, J.; Van Grieken, R.
Title Grazing-emission electron probe microanalysis of particles near the substrate edge Type A1 Journal article
Year 2001 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 56 Issue Pages 2385-2395
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000173118900005 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:36384 Serial 8007
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Author Bondarenko, I.; Treiger, B.; Van Grieken, R.; van Espen, P.
Title IDAS: a Windows based software package for cluster analysis Type A1 Journal article
Year 1996 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 51 Issue Pages 441-456
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:14649 Serial 8050
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Author Bekshaev, A.; Van Grieken, R.
Title Interference technique in grazing-emission electron probe microanalysis of submicrometer particles Type A1 Journal article
Year 2001 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 56 Issue Pages 503-515
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000169972200003 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:36083 Serial 8115
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Author Spolnik, Z.; Osán, J.; Klepka, M.; Lawniczak-Jablonska, K.; Van Grieken, R.; Molak, A.; Potgieter, J.H.
Title Investigation of the chemical composition of (Na1-xBix)(MnyNb1-y)O3 ceramics by single particle electron probe X-ray microanalysis with an application of Monte Carlo simulations Type A1 Journal article
Year 2005 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 60 Issue 4 Pages 525-530
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000229955200012 Publication Date 2005-04-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:52668 Serial 8128
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Author Bencs, L.; Ravindra, K.; Van Grieken, R.
Title Methods for the determination of platinum group elements originating from the abrasion of automotive catalytic converters Type A1 Journal article
Year 2003 Publication (down) Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 58 Issue Pages 1723-1755
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000186471700001 Publication Date 2003-10-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:43520 Serial 8225
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