Records |
Author |
Van Wesenbeeck, K. |
Title |
Plasma catalysis as an efficient and sustainable air purification technology |
Type |
Doctoral thesis |
Year |
2016 |
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Issue |
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Pages |
171 p. |
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Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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ISBN |
978-90-5728-514-1 |
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UA library record |
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no |
Call Number |
UA @ admin @ c:irua:135267 |
Serial |
8388 |
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Author |
Blommaerts, N. |
Title |
Plasmonic core shell nanoparticles : from synthesis to photocatalytic applications |
Type |
Doctoral thesis |
Year |
2019 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
153 p. |
Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
Abstract |
Het gebruik van plasmon-actieve nanodeeltjes heeft de laatste 10 jaar zeer veel interesse gewekt bij onderzoekers in verschillende toepassingsdomeinen zoals fotokatalyse of oppervlakte versterkte Raman spectroscopie. Er is echter een grote limiterende factor bij het gebruik van edelmetaal nanodeeltjes zoals goud en zilver en dat is de stabiliteit. Deze oxideren en aggregeren snel, zeker in oxidatieve omgeving zoals in lucht. Een interessante aanpak om plasmon-actieve nanodeeltjes te stabiliseren, is om ze te omgeven in een schil, met andere woorden om een kern-schil nanodeeltje te vormen. Er zijn een heel aantal verschillende manieren waarop kern-schil nanodeeltjes gesynthetiseerd kunnen worden. In eerste instantie werden metaal nanodeeltjes omgeven door een (dunne) TiO2 laag. Afhankelijk van de hoeveelheid TiO2 precursor kon de dikte van de laag gecontroleerd worden tot enkele nanometers dik. De stalen werden getest voor de fotokatalytische afbraak van een vaste laag stearinezuur waarbij toevoeging van 2 wt% metaal@TiO2 op P25 leidde tot een significante verbetering in afbraakefficiëntie in vergelijking met zuiver P25. Een andere manier voor het stabiliseren van metaal nanodeeltjes is door ze te omgeven met een polymeerschil. Op deze manier kon de laagdikte gecontroleerd worden met sub-nanometer controle wat een zeer belangrijke factor is voor de hoeveelheid near-field versterking dat buiten de polymeer schil kan gaan. Een XTT test werd uitgevoerd om te bepalen wat de zuurstofactivatie snelheid was van goud en zilver (en goud-zilver bimetallische) nanodeeltjes, al dan niet omgeven door een (niet-)geleidende polymeer laag. Wanneer de stalen gecoat werden met vier niet-geleidende polymeerlagen zakte de zuurstofactivatie nagenoeg tot nul. Aan de andere kant, als goud nanodeeltjes werden omgeven door een geleidende schil was er nog steeds zuurstofactivatie, hoewel lager dan in het geval van goud zonder laag. Het laatste deel van deze thesis focuste meer op mogelijke toepassingen in luchtzuivering. In dit werk werd een glazen buis, gecoat aan de binnenkant met (Ag@polymer gemodificeerd) TiO2, als een spiraal rond een UVA lamp gewikkeld. De geoptimaliseerde spiraalreactor werd dan vergeleken met een conventionele cilindervormige fotoreactor, met dezelfde dimensies en totale katalysatorbelading, over een grote range aan experimentele condities. Uit de resultaten bleek dat de spiraalreactor significant betere afbraakefficiënties vertoonde in vergelijking met de conventionele cilindervormige reactor over een grote range aan debieten. Een adsorptiestap in combinatie met de geoptimaliseerde spiraalreactor zou kunnen leiden tot een zeer krachtige luchtzuiveringstechnologie. |
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no |
Call Number |
UA @ admin @ c:irua:164835 |
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8389 |
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Author |
Bencs, L.; Ravindra, K.; Van Grieken, R. |
Title |
Platinum : environmental pollution and health effects |
Type |
H2 Book chapter |
Year |
2011 |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
580-595
T2 - Encyclopedia of environmental health |
Keywords |
H2 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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978-0-444-52273-3 |
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no |
Call Number |
UA @ admin @ c:irua:93109 |
Serial |
8390 |
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Author |
Trincavelli, J.; Montoro, S.; Van Grieken, R.; van Espen, P. |
Title |
Prediction of Mα/Lα intensity ratios and the use in the spectra evaluation |
Type |
P3 Proceeding |
Year |
1992 |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
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no |
Call Number |
UA @ admin @ c:irua:2863 |
Serial |
8405 |
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Author |
Tsuji, K.; Spolnik, Z.; Wagatsuma, K.; Nullens, R.; Van Grieken, R.E. |
Title |
Preliminary experiments on grazing-exit electron probe microanalysis (GE-EPMA) |
Type |
P1 Proceeding |
Year |
1999 |
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Volume |
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Issue |
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Pages |
119-122
T2 - Electron Microscopy and Analysis 1999 |
Keywords |
P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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000088782800027 |
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no |
Call Number |
UA @ admin @ c:irua:27602 |
Serial |
8408 |
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Author |
Goossenaerts, C.; Verbueken, A.; Van Grieken, R. |
Title |
Preliminary LAMMA investigations on healthy and acid rain affected spruce needles |
Type |
P3 Proceeding |
Year |
1986 |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117511 |
Serial |
8409 |
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Author |
Gielis, J.; Potters, G. |
Title |
Proceedings of the 9th World Bamboo Congress, Antwerp 2012 |
Type |
P3 Proceeding |
Year |
2012 |
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P3 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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no |
Call Number |
UA @ admin @ c:irua:97756 |
Serial |
8413 |
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Author |
Jochems, P. |
Title |
Process intensification by immobilization of \beta-galactosidase on a mixed matrix membrance : galacto-oligosaccharides production as a case study |
Type |
Doctoral thesis |
Year |
2013 |
Publication |
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Abbreviated Journal |
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Issue |
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Pages |
199 p. |
Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
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ISBN |
978-90-5728-430-4 |
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no |
Call Number |
UA @ admin @ c:irua:111811 |
Serial |
8415 |
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Author |
Tavkhelidze, I.; Gielis, J. |
Title |
The process of cutting GMLmn bodies with dm-knives |
Type |
A3 Journal article |
Year |
2018 |
Publication |
Sn – 1512-0066 |
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Volume |
32 |
Issue |
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Pages |
67-70 |
Keywords |
A3 Journal article; Sustainable Energy, Air and Water Technology (DuEL) |
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no |
Call Number |
UA @ admin @ c:irua:159971 |
Serial |
8417 |
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Author |
Sui, Y. |
Title |
Producing nutritional protein with Dunaliella microalgae : technological and economic optimization |
Type |
Doctoral thesis |
Year |
2019 |
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Abbreviated Journal |
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Pages |
140 p. |
Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
Abstract |
In this thesis, microalga Dunaliella salina is highlighted as a novel source of protein to sustain the human needs. As demonstrated in this thesis, the biochemical composition of D. salina is not fixed, and can be substantially influenced by internal and external conditions. In order to comply with the human requirement of protein, various important factors affecting the protein quantity and quality of D. salina have been evaluated in this thesis for an optimized production strategy. All tested parameters, namely salinity, pH, light regimes (continuous light and light/dark cycle), light intensity, nutrient levels and growth phases can contribute to significant variations of protein content and essential amino acid (EAA) level in D. salina. Ultimately, D. salina is capable of producing high amount of superior quality protein, complying with the FAO reference for human consumption. Even better, such protein of superior quality can be accompanied by unique β-carotene accumulation in D. salina, a pigment with anti-oxidant pro-vitamin A effect. In the end, according to the techno-economic analysis (TEA), it is economically feasible to produce D. salina biomass for human nutrition. |
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ISBN |
978-90-5728-630-8 |
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UA library record |
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no |
Call Number |
UA @ admin @ c:irua:164002 |
Serial |
8420 |
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Author |
Van Grieken, R.; Wollast, R. |
Title |
Progress in Belgian oceanographic research : proceedings of symposium, Brussels, 3-5 March 1985 |
Type |
ME3 Book as editor |
Year |
1985 |
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Pages |
479 p. |
Keywords |
ME3 Book as editor; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:117474 |
Serial |
8422 |
Permanent link to this record |
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Author |
Alloul, A. |
Title |
Purple bacteria as microbial protein source : technology development, community control, economic optimization and biomass valorization |
Type |
Doctoral thesis |
Year |
2019 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
212 p. |
Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
Abstract |
Food production is a cornerstone in contemporary industrial societies. Its production requires land, water and enormous amounts of fertilizers. These precious fertilizers enter the linear food chain and suffer from a cascade of inefficiencies, resulting in detrimental effects to the environment. A radical transforming of the current food production chain is, therefore, essential to guarantee a sustainable future for humanity. This thesis has studied the production of microbial protein (i.e. single-cell protein), which is the use of microorganisms such as yeast, fungi, algae and bacteria as protein ingredient for animal feed. The type of microorganisms targeted in this thesis were purple non-sulfur bacteria (PNSB). These bacteria are an extremely heterogenic group that contain photosynthetic pigments and are able to perform anoxygenic photosynthesis. The core focus of the thesis was technology development for the production of PNSB as a source of microbial protein on wastewater and fresh fertilizers. In the final stage of this research, it was the objective to explore the potential of PNSB as a nutritious feed ingredient for shrimp. Overall, this work has provided the building blocks to transform the conventional food production chain. The findings show that PNSB production and biomass valorization is within reach. Further pilot implementation and cost reduction will facilitate the introduction of PNSB production in future’s wastewater treatment plants and the valorization of the biomass as nutritious animal feed ingredient. |
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ISBN |
978-90-5728-636-0 |
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no |
Call Number |
UA @ admin @ c:irua:164820 |
Serial |
8430 |
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Author |
Markowicz, A.A.; Van Grieken, R.E. |
Title |
Quantification in XRF analysis of intermediate-thickness samples |
Type |
H3 Book chapter |
Year |
2002 |
Publication |
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Abbreviated Journal |
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Issue |
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Pages |
407-431
T2 - Handbook of X-ray spectrometry / Grie |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:36389 |
Serial |
8433 |
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Author |
Markowicz, A.M.; Van Grieken, R.E. |
Title |
Quantification in XRF analysis of intermediate-thickness samples |
Type |
H3 Book chapter |
Year |
1992 |
Publication |
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Abbreviated Journal |
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Issue |
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Pages |
339-358
T2 - Handbook of X-ray spectroscopy / Grie |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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no |
Call Number |
UA @ admin @ c:irua:2855 |
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8434 |
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Author |
Schelles, W.; Van Grieken, R. |
Title |
Quantitative analysis of zirconium oxide by direct glow discharge mass spectrometry using a secondary cathode |
Type |
A1 Journal article |
Year |
1997 |
Publication |
Journal of analytical atomic spectrometry |
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12 |
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49-52 |
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A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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0267-9477 |
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no |
Call Number |
UA @ admin @ c:irua:18774 |
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8439 |
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Author |
Piñera, I.; Abreu, Y.; van Espen, P.; Diaz, A.; Leyva, A.; Cruz, C.M. |
Title |
Radiation damage evaluation on LYSO and LuYAP materials through Dpa calculation assisted by Monte Carlo method |
Type |
P1 Proceeding |
Year |
2011 |
Publication |
IEEE conference record
T2 – IEEE Nuclear Science Symposium/Medical Imaging Conference (NSS/MIC)/18th, International Workshop on Room-Temperature Semiconductor X-Ray and, Gamma-Ray Detectors, OCT 23-29, 2011, Valencia, SPAIN |
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1609-1611 |
Keywords |
P1 Proceeding; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The aim of the present work is to study the radiation damage induced in LYSO and LuYAP crystals by the gamma radiation and the secondary electrons/positrons generated. The displacements per atom (dpa) distributions inside each material were calculated following the Monte Carlo assisted Classical Method (MCCM) introduced by the authors. As gamma sources were used Sc-44, Na-22 and V-48. Also the energy of gammas from the annihilation processes (511 keV) was included in the study. This procedure allowed studying the in-depth dpa distributions inside each crystal for all four sources. It was also possible to obtain the separate contribution from each atom to the total dpa. The LYSO crystals were found to receive more damage, mainly provoked by the displacements of silicon and oxygen atoms. |
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000304755601169 |
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978-1-4673-0120-6 |
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UA library record; WoS full record; WoS citing articles |
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no |
Call Number |
UA @ admin @ c:irua:113072 |
Serial |
8447 |
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Author |
Chakravorty, R.; Van Grieken, R. |
Title |
Radiochemical study of Cd, Co and Eu-coprecititation with iron hydroxide in seawater |
Type |
A3 Journal article |
Year |
1986 |
Publication |
Mikrochimica acta |
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3 |
Issue |
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Pages |
81-87 |
Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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0344-838x |
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UA library record |
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Times cited |
|
Open Access |
|
Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:116774 |
Serial |
8450 |
Permanent link to this record |
|
|
|
Author |
Otten, P.; Bruynseels, F.; Van Grieken, R. |
Title |
Reaction of marine aerosols with HNO3 vapour studied by single particle analysis |
Type |
P3 Proceeding |
Year |
1986 |
Publication |
|
Abbreviated Journal |
|
Volume |
|
Issue |
|
Pages |
|
Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record |
Impact Factor |
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Times cited |
|
Open Access |
|
Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:117508 |
Serial |
8455 |
Permanent link to this record |
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|
|
Author |
Claes, M.; de Bokx, P.; Van Grieken, R. |
Title |
Recent developments of laboratory grazing emission X-ray fluorescence spectrometry |
Type |
P1 Proceeding |
Year |
1999 |
Publication |
|
Abbreviated Journal |
|
Volume |
|
Issue |
|
Pages |
103-107
T2 - Proceedings of the European Conferenc |
Keywords |
P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
|
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Language |
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Wos |
000081658400015 |
Publication Date |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
Series Volume |
|
Series Issue |
|
Edition |
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record; WoS full record |
Impact Factor |
|
Times cited |
|
Open Access |
|
Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:24718 |
Serial |
8459 |
Permanent link to this record |
|
|
|
Author |
Bruynseels, F.; Van Grieken, R. |
Title |
Recombination reactions and geometry effects in laser microprobe mass analysis studied with 12C/13C bilayers |
Type |
P3 Proceeding |
Year |
1986 |
Publication |
|
Abbreviated Journal |
|
Volume |
|
Issue |
|
Pages |
|
Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
|
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
|
ISBN |
|
Additional Links |
UA library record |
Impact Factor |
|
Times cited |
|
Open Access |
|
Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:117512 |
Serial |
8462 |
Permanent link to this record |
|
|
|
Author |
Injuk, J.; Van Grieken, R. |
Title |
Reference matarials for microanalytical nuclear techniques |
Type |
P3 Proceeding |
Year |
1995 |
Publication |
|
Abbreviated Journal |
|
Volume |
|
Issue |
|
Pages |
|
Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
|
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
|
Edition |
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record |
Impact Factor |
|
Times cited |
|
Open Access |
|
Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:55574 |
Serial |
8467 |
Permanent link to this record |
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|
|
Author |
Kabsch-Korbutowicz, M.; Krupinska, B. |
Title |
Removal of natural organic matter from water by using ion-exchange resins |
Type |
A1 Journal article |
Year |
2008 |
Publication |
Przemysl chemiczny
T2 – Scientific and Technical Conference on Water and Wastewater Basis for, Environmental Protection (School of Quality Water 2008), MAY 28-30, 2008, Kolobrzeg, POLAND |
Abbreviated Journal |
|
Volume |
87 |
Issue |
5 |
Pages |
473-475 |
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
Four aq. solns. contg. natural peat components and the water from Odra river were treated with 3 anion-exchange resins (2.5 to 15 cm(3) of resin per 1 dm(3) of the sample) for 5-60 min to remove the org. matter. The process efficiency was detd. by UV absorbance (254 nm) and colour intensity measurements. The treatment resulted in discoloration of the solns. A resin with weak alky, was the most efficient. The degree of removal increased with increasing the resin dose and contact time. The presence of inorg. anions in the soins. contributed to a decrease of process effectivity. |
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Wos |
000257179000020 |
Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
|
Series Volume |
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Series Issue |
|
Edition |
|
ISSN |
0033-2496 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
Impact Factor |
|
Times cited |
|
Open Access |
|
Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:102617 |
Serial |
8471 |
Permanent link to this record |
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|
Author |
Tytgat, T. |
Title |
Research and development of self-supporting TiO2 foams for removal of VOCs from ambient air |
Type |
Doctoral thesis |
Year |
2012 |
Publication |
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Abbreviated Journal |
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Volume |
|
Issue |
|
Pages |
164 p. |
Keywords |
Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
|
ISSN |
|
ISBN |
978-90-5728-395-6 |
Additional Links |
UA library record |
Impact Factor |
|
Times cited |
|
Open Access |
|
Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:104607 |
Serial |
8472 |
Permanent link to this record |
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Author |
Kontozova, V.; Krupińska, B.; Van Grieken, R.; Janssen, E.; Moris, H.; Aerts, D.; Watteeuw, L.; van Bos, M.; Peckstadt, A. |
Title |
Research for preventive conservation and optimal presentation of world heritage in Museum Plantin-Moretus, Antwerp |
Type |
P3 Proceeding |
Year |
2011 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
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ISBN |
978-989-97522-0-7 |
Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:92095 |
Serial |
8473 |
Permanent link to this record |
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Author |
Swerling, G.; Travaglini, B.; Van Grieken, R.; Spolnik, Z.; Bencs, L.; [et al.]; European Project Freindly-Heating |
Title |
Il riscaldamento nelle chiese e la conservazione dei beni culturali = Church heating and the preservation of the cultural heritage |
Type |
ME2 Book as editor or co-editor |
Year |
2006 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
240 p. |
Keywords |
ME2 Book as editor or co-editor; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Address |
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Corporate Author |
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Place of Publication |
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Edition |
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ISSN |
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ISBN |
88-370-5034-8 |
Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:61684 |
Serial |
8480 |
Permanent link to this record |
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Author |
Vandekerckhove, T.G.L.; Courtens, E.N.P.; Prat, D.; Boon, N.; Vlaeminck, S.E. |
Title |
The rise of thermophilic biotechnology for nitrogen removal |
Type |
P3 Proceeding |
Year |
2016 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
17 p.
T2 - WEF/IWA Nutrient Removal and Recovery C |
Keywords |
P3 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL) |
Abstract |
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Address |
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Corporate Author |
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Publisher |
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Place of Publication |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
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ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:151125 |
Serial |
8481 |
Permanent link to this record |
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Author |
Potgieter-Vermaak, S.; Van Grieken, R.; Potgieter, H. |
Title |
Die risikoprofiel van Pb en Cr in stedelike padstof |
Type |
A2 Journal article |
Year |
2012 |
Publication |
Litnet akademies : 'n joernaal vir die geesteswetenskappe |
Abbreviated Journal |
|
Volume |
9 |
Issue |
3 |
Pages |
1-22 |
Keywords |
A2 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
The risk profile of Cr and Pb in urban road deposited sediment Exponential urbanisation and industrial growth occur on a global scale and result in an ecological burden, of which one important part is pollution. It is well known that the extent of air pollution has escalated over the past two decades in several parts of the world, despite mitigating measures and legislation. Current research points to the fact that air pollution in urban and industrial areas is substantially different from that found in rural areas. Road dust (RD) contributes up to 35% of airborne particulate matter due to resuspension thereof, and poses a health concern due to carcinogenic and toxic components potentially present in the micron-sized fractions. Although literature does report on the concentrations of trace, toxic metals and metalloids present in RD (Hooker and Nathanail 2006), the molecular make-up of particulates generated due to the resuspension of the RD is not well documented. In vitro and animal toxicological studies have confirmed that the chemical composition of inhaled particles plays a major role in its toxic, genotoxic and carcinogenic mechanisms, but the component-specific toxic effects are still not understood. Transition metals binding to air particle matter can result in reactive oxygen species in the human body (particularly in the lungs), and this is a significant risk, especially for vulnerable population groups like elderly people, children and terminally ill patients. The characterisation of the molecular composition of the fine fraction is evidently of importance for public health. During an earlier study, road dust from an inner-city environment in the UK was collected and partially characterised (Barrett e.a. 2010). These same-size fractions were analysed for their elemental concentrations, using X-ray Fluorescence Spectrometry (XRFS) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). In addition, single-particle analysis was performed on the different fractions by means of Computer Controlled Electron Probe X-ray Micro Analysis (CC-EPXMA) and their molecular structure probed by studying elemental associations. These findings were correlated with Micro Raman Spectroscopy (MRS) results. It was found that the fine fraction (<38 μm) had the highest Pb (238 ppm) and Cr (171 ppm) concentrations. The CC-EPXMA data showed >50% association of Cr-rich particles with Pb and the MRS data showed that the Cr was mostly present as lead chromate and therefore in the Cr(VI) oxidation state. Concentrations of both Pb and Cr decreased substantially (279 (<38 mm) 13 ppm (<1mm); 171 (<38 mm) 91 ppm (<1mm) respectively) in the larger fractions. Apart from rather alarmingly high concentrations of oxidative stressors (Cu, Fe, Mn), the carcinogenic and toxic potential of the inhalable fraction is evident. Preliminary bioaccessibility data indicated that both Cr and Pb are readily |
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Series Issue |
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Edition |
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ISSN |
1995-5928 |
ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:102566 |
Serial |
8482 |
Permanent link to this record |
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Author |
Moropoulou, A.; Bisbikou, K.; Torfs, K.; Van Grieken, R. |
Title |
Risk analysis for the protection of cultural heritage from industrial pollution |
Type |
H3 Book chapter |
Year |
1999 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
475-484
T2 - Structural studies, repairs and maint |
Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Corporate Author |
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Publisher |
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Place of Publication |
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Publication Date |
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Series Editor |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:27598 |
Serial |
8483 |
Permanent link to this record |
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Author |
Chou, L.; Harlay, J.; Roevros, N.; Lannuzel, D.; Rebreanu, L.; van der Zee, C.; Lapernat, P.-E.; Daro, M.-H.; Aerts, K.; Godoi, R.; Van Grieken, R. |
Title |
Role of oceanic production and dissolution of calcium carbonate in climate change (CCCC): final report |
Type |
Minutes and reports |
Year |
2009 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
Minutes and reports; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
Call Number |
UA @ admin @ c:irua:80696 |
Serial |
8486 |
Permanent link to this record |
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Author |
Delalieux, F.; Van Grieken, R.; Moropoulou, A. |
Title |
Salt weathering research: present state and future directions |
Type |
P3 Proceeding |
Year |
2003 |
Publication |
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Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract |
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Place of Publication |
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Series Issue |
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Edition |
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ISSN |
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ISBN |
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Additional Links |
UA library record |
Impact Factor |
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Times cited |
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Open Access |
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Notes |
|
Approved |
no |
Call Number |
UA @ admin @ c:irua:42732 |
Serial |
8490 |
Permanent link to this record |