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Author Storms, H.M.; Janssens, K.H.; Török, S.B.; Van Grieken, R.E. doi  openurl
  Title Evaluation of the ArmstrongBuseck correction for automated electron probe X-ray microanalysis of particles Type A1 Journal article
  Year 1989 Publication X-ray spectrometry Abbreviated Journal  
  Volume 18 Issue (up) 2 Pages 45-52  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The ArmstrongBuseck correction for absorption effects in electron probe x-ray microanalysis of particles considers seven specific particle shapes, and for these geometries exact correction equations are used. This procedure implies that the analyst has to associate the particle to be analysed with a certain particle type; an arbitrary relative thickness is sometimes assumed. A theoretical study was made of this absorption correction as a function of the particle composition, type and thickness for micrometre-sized particles. It appears that a correct choice of the particle type is critical. However, when the analytical results are normalized to 100%, the differences between the models are much less pronounced, and it is justified to assume a spherical model in all cases.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1989U261400001 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116489 Serial 5616  
Permanent link to this record
 

 
Author LaBrecque, J.J.; Beusen, J.M.; Van Grieken, R.E. doi  openurl
  Title Analysis of lateritic material from Cerro impacto by instrumental neutron activation employing a low-energy photon semiconductor and a high-energy Ge(Li) detector Type A1 Journal article
  Year 1986 Publication Applied spectroscopy Abbreviated Journal  
  Volume 40 Issue (up) 2 Pages 140-144  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Nineteen elements were determined in four different grain size fractions of a bulk geological material from Cerro Impacto for a study of the physical (mechanical) concentration process of different elements based upon the hardness of the different minerals. The analysis was performed by excitation of the sample with a high, slow neutron flux followed by gamma-ray spectroscopy with both a conventional Ge(Li) high-energy detector and a low-energy photon detector (LEPD). The accuracy of this method was studied with the use of two standard reference materials, SY-2 and SY-3, which are similar to the real samples. The values determined were also compared with a secondary target x-ray fluorescence method for all the elements that were suitable to both methods. Actually, the x-ray fluorescence method was found to be more complementary than competitive.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986A085900003 Publication Date 2005-07-21  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-7028 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116768 Serial 7448  
Permanent link to this record
 

 
Author Annegarn, H.J.; Storms, H.; Van Grieken, R.E.; Booth-Jones, P.A. pdf  doi
openurl 
  Title Composition and size of individual particles from a gold mine atmosphere Type A3 Journal article
  Year 1987 Publication Mining science & technology Abbreviated Journal  
  Volume 5 Issue (up) 2 Pages 111-119  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Airborne dust particles were collected in a return airway of a South African gold mine using a 7-stage, single-orifice cascade impactor. Between 70 and 130 individual particles were analysed on each stage using automated electron-probe x-ray microanalysis (EPXMA). Particle size and shape parameters are given for different classes of particles sorted by elemental composition. Silicon-rich particles are the most abundant overall, while chlorine-rich particles dominate (up to 80%) in the range 0.21.0 μm. It is shown that EPXMA characterisation of particles can be used to infer relative contributions of various particle sources and dust generating processes to the total dust concentrations in mine atmospheres. An understanding of the nature and source of particles is essential for any source control strategy. We conclude that the EPXMA technique merits inclusion in the repertoire of techniques used for characterising underground dust.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2004-12-15  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0167-9031 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116777 Serial 7701  
Permanent link to this record
 

 
Author Kolaitis, L.N.; Bruynseels, F.J.; Van Grieken, R.E.; Andreae, M.O. doi  openurl
  Title Determination of methanesulfonic acid and non-sea-salt sulfate in single marine aerosol particles Type A1 Journal article
  Year 1989 Publication Environmental science and technology Abbreviated Journal  
  Volume 23 Issue (up) 2 Pages 236-240  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1989T024900023 Publication Date 2005-03-17  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0013-936x; 1520-5851 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116813 Serial 7783  
Permanent link to this record
 

 
Author Vanderborght, B.M.; Van Grieken, R.E. openurl 
  Title Enrichment of trace metals in water by adsorption on activated carbon Type A1 Journal article
  Year 1977 Publication Analytical chemistry Abbreviated Journal  
  Volume 49 Issue (up) 2 Pages 311-316  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116513 Serial 7923  
Permanent link to this record
 

 
Author Van Grieken, R.E.; Adams, F.C. doi  openurl
  Title Folding of aerosol loaded filters during X-ray fluorescence analysis Type A1 Journal article
  Year 1976 Publication X-ray spectrometry Abbreviated Journal  
  Volume 5 Issue (up) 2 Pages 61-67  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Folding aerosol loaded filters in two with the loaded side inwards during the X-ray analysis not only reduces possible filter heterogeneity effects and improves sample protection, but also increases the sensitivity and renders filter paper absorption corrections simple and more accurate in many instances. It is shown that folding an aerosol loaded Whatman filter paper during Kα X-rays counting leads to an increased sensitivity for all elements up from calcium, scandium or titanium (depending on the sensitivity definition and on the aerosol load) and for all elements up from phosphorus, sulphur or chlorine in the case of the Nuclepore filter. Although the absorption by the filter, into which the aerosol penetrates to some extent, is always more important in the sandwich than in the usual geometry, the dependence of the absorption correction on the usually unknown average deposition depth is less pronounced. Assuming all the aerosol material to be collected at the very surface of the filter and hence being present in the centre of the sandwich to be analysed, leads to an extremely simple filter paper absorption correction which is less prone to uncertainties than more sophisticated corrections in the usual geometry requiring additional measurements. This is the case for all elements up from potassium on Whatman filters and up from phosphorus on Nuclepore filters.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1976BM95300002 Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116480 Serial 7976  
Permanent link to this record
 

 
Author Bernard, P.C.; Van Grieken, R.E.; Brügmann, L. pdf  doi
openurl 
  Title Geochemistry of suspended matter from the baltic sea : 1 : results of individual particle characterization by automated electron microprobe Type A1 Journal article
  Year 1989 Publication Marine chemistry Abbreviated Journal  
  Volume 26 Issue (up) 2 Pages 155-177  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Automated electron probe X-ray microanalysis was used to characterize some 15 000 individual suspension particles from 50 samples of suspended matter collected from different depths at 18 stations throughout the Baltic Sea and the transient area to the North Sea. For each particle, 14 minor and major elements were determined and size information data were obtained. To process this huge amount of results, multivariate analysis techniques were invoked: the particles were classified into specific types and the abundance variations of these groups were studied. It appeared that 80% of all investigated particles contained mostly silicon, and seemed to consist of quartz, and K-rich and Fe-rich aluminosilicates. The abundance of BaSO4 particles averaged 5% throughout the Baltic Sea, but amounted to up to 44% at some stations. The abundance of the Fe-rich particles varied significantly with location and depth, and averaged ∼ 4%. They were often found to be associated with significant amounts of P. Both of these particle types and the Mn-rich particles are thought to be mainly authigenic. Calcium carbonate particles are more abundant towards the North Sea (which seems to act as a source). Principal component analysis of the data revealed that most of the compositional variability can be explained by differences between deep and surface waters and by the influences of inflowing North Sea waters. Additional information about the types and sources of the suspended matter in the Baltic Sea was gained from the comparison and correlation of the single particle results with different fractions of the bulk concentrations of elements such as Al, Ca, Mn, Fe, Zn and Ba.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1989T986200005 Publication Date 2003-08-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0304-4203; 1872-7581 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116699 Serial 7995  
Permanent link to this record
 

 
Author Araújo, M.F.D.; Bernard, P.C.; Van Grieken, R.E. pdf  doi
openurl 
  Title Heavy metal contamination in sediments from the Belgian coast and Scheldt estuary Type A1 Journal article
  Year 1988 Publication Marine pollution bulletin Abbreviated Journal  
  Volume 19 Issue (up) 2 Pages 269-273  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Sixty-two samples of total sediments and the separated clay/silt size fractions were analysed by energy-dispersive X-ray fluorescence spectrometry to evaluate the pollution level and the trends in samples collected along the Belgian coast over a period of 6 yr and at four stations located in the Scheldt estuary where two of these were sampled periodically for 4 yr. Three correction methods for grain size effects were applied, either to the bulk sediment samples or to the clay/silt size fractions, and the results were compared. Local variations on the concentrations in some of the elements determined were used to establish whether they result from an anthropogenic or natural origin. The level of pollution was assessed as a function of the location, sampling date, and depth.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1988P559400005 Publication Date 2003-08-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0025-326x; 1879-3363 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116801 Serial 8021  
Permanent link to this record
 

 
Author van de Vijver, F.L.; Verbueken, A.H.; Van Grieken, R.E.; de Broe, M.E.; Visser, W.J. pdf  openurl
  Title Laser microprobe mass analysis : a tool for evaluating histochemical staining of trace elements Type L1 Letter to the editor
  Year 1985 Publication Clinical chemistry : international journal of laboratory medicine and molecular diagnostics Abbreviated Journal  
  Volume 31 Issue (up) 2 Pages 351-352  
  Keywords L1 Letter to the editor; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0009-9147; 1530-8561 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116715 Serial 8154  
Permanent link to this record
 

 
Author Eltayeb, M.A.H.; Van Grieken, R.E. doi  openurl
  Title Preconcentration and XRF-determination of heavy metals in hair from Sudanese populations Type A1 Journal article
  Year 1989 Publication Journal of radioanalytical and nuclear chemistry Abbreviated Journal  
  Volume 131 Issue (up) 2 Pages 331-342  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Energy-dispersive X-ray fluorescence analysis was applied for the analysis of hair. The hair samples were digested in a mixture of nitric and perchloric acid and the heavy metals were precipitated with ammonium pyrrolidine dithiocarbamate. The accuracy, precision and recovery of the method for the elements Fe, Ni, Cu, Zn and Pb were evaluated through the analysis of a standard hair sample. The procedure was applied to the analysis of hair from an occupationally exposed group of Sudanese workers and a control group. The hair of the exposed group showed a range of 80550 ppm Fe, 612 ppm Cu, 57190 ppm Zn and 703700 ppm Pb, while that of the control group had a range of 60310 ppm Fe, 722 ppm Cu, 89170 ppm Zn and 317 ppm Pb.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1989AL77700009 Publication Date 2005-08-12  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0236-5731; 1588-2780 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116816 Serial 8399  
Permanent link to this record
 

 
Author Wouters, L.C.; Van Grieken, R.E.; Linton, R.W.; Bauer, C.F. doi  openurl
  Title Discrimination between coprecipitated and adsorbed lead on individual calcite particles using laser microprobe mass analysis Type A1 Journal article
  Year 1988 Publication Analytical chemistry Abbreviated Journal  
  Volume 60 Issue (up) 20 Pages 2218-2220  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1988Q513900012 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116526 Serial 7813  
Permanent link to this record
 

 
Author Tsuji, K.; Spolnik, Z.; Wagatsuma, K.; Van Grieken, R.E.; Vis, R.D. doi  openurl
  Title Grazing-exit particle-induced X-ray emission analysis with extremely low background Type A1 Journal article
  Year 1999 Publication Analytical chemistry Abbreviated Journal  
  Volume 71 Issue (up) 22 Pages 5033-5036  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000083647100004 Publication Date 2002-07-26  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:27588 Serial 8010  
Permanent link to this record
 

 
Author Rojas, C.M.; Van Grieken, R.E.; Laane, R.W. pdf  doi
openurl 
  Title Comparison of 3 dry deposition models applied to field-measurements in the Southern Bight of the North-Sea Type A1 Journal article
  Year 1993 Publication Atmospheric environment Abbreviated Journal  
  Volume 27 Issue (up) 3 Pages 363-370  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Dry deposition velocities have been calculated using three different approaches. Turbulent wind profile theory has been used to predict the drag coefficient, wind speed and friction velocity at 10 m height when the wind speed is measured at a higher altitude. The resulting parameters were introduced in a two-layer deposition model. The second approach was the well-known model of Slinn and Slinn (1980, Atmospheric Environment 14, 1013-1016), whereas the third corresponded to the model published by Williams (1982, Atmospheric Environment 16, 1933 1938). Results point to clear differences. However, in a field experiment carried out at the Southern Bight of the North Sea, all three approaches show relatively comparable results. The role played by the size distribution of atmospheric particulate matter is essential. In our case any of the three models could have given satisfactory outcomes taking into account the wide spread of the experimental results cited in the literature for the same airshed.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1993KQ75200008 Publication Date 2003-08-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0004-6981 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:100018 Serial 7690  
Permanent link to this record
 

 
Author Vandeputte, D.F.; Jacob, W.A.; Van Grieken, R.E. pdf  doi
openurl 
  Title Influence of fixation procedures on the microanalysis of lead-induced intranuclear inclusions in rat kidney Type A1 Journal article
  Year 1990 Publication The journal of histochemistry and cytochemistry Abbreviated Journal  
  Volume 38 Issue (up) 3 Pages 331-337  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Using Laser Microprobe Mass Analysis (LAMMA), we studied the chemical composition of lead-induced intranuclear inclusions in rat kidney tissue prepared by three different wet chemical fixation procedures for transmission electron microscopy. Fixation with glutaraldehyde-Na2S gave the same results as fixation with glutaraldehyde only: a high lead concentration could be detected. Therefore, for lead strongly bound to proteins, precipitation procedures are not essential. Post-fixation with osmium tetroxide drastically changed the composition of the inclusions: the lead concentration decreased substantially, while sodium, calcium, and barium were introduced. The osmium tetroxide fixative was found to be the source of the contamination. It also contained aluminum, and we suggest that other proteins (e.g., in neurofibrillary tangles) might be able to take up Al out of solution and that care must be exercised in interpreting the microanalytical results of osmium-fixed material. For the microanalysis of the lead inclusions, fixation with glutaraldehyde only provides a good compromise between preservation of the ultrastructure and maintenance of the element distribution.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2011-04-01  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-1554 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116831 Serial 8091  
Permanent link to this record
 

 
Author Roekens, E.J.; Van Grieken, R.E. pdf  doi
openurl 
  Title Kinetics of iron(II) oxidation in seawater of various pH Type A1 Journal article
  Year 1983 Publication Marine chemistry Abbreviated Journal  
  Volume 13 Issue (up) 3 Pages 195-202  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The rate of iron(II) oxidation in North Sea water of pH 5.510 in the range 1025°C has been studied. The oxygenation rate depends linearly on the iron(II) and dissolved oxygen concentrations. The second-order dependence on [OH−], found by several investigators for synthetic solutions, was confirmed in seawater, but only for pOH > 6.9. For pOH < 5.9 the rate appeared to be independent of the pOH. In the intermediate range, pOH 5.96.9, corresponding to the natural pH of seawater, a first-order dependence on the pOH is obeyed. The important discrepancy in the literature between the second-order rate constant for NaCHO3 solutions and for seawater can be attributed predominantly to the incorrect assumption of a second-order pOH dependence in natural seawater. The results can be useful, for example, in predicting the effect of dumping acidic iron waste from the titanium-dioxide industry into the ocean.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1983RD52600003 Publication Date 2003-08-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0304-4203; 1872-7581 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116695 Serial 8140  
Permanent link to this record
 

 
Author Roekens, E.J.; Van Grieken, R.E. pdf  doi
openurl 
  Title Kinetics of iron(II) oxidation in seawater of various pH : reply Type A1 Journal article
  Year 1984 Publication Marine chemistry Abbreviated Journal  
  Volume 15 Issue (up) 3 Pages 281-284  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1984TZ60600009 Publication Date 2003-08-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0304-4203; 1872-7581 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116711 Serial 8141  
Permanent link to this record
 

 
Author Robberecht, H.J.; Van Grieken, R.E. doi  openurl
  Title Sub-part-per-billion determination of total dissolved selenium and selenite in environmental waters by X-ray fluorescence spectrometry Type A1 Journal article
  Year 1980 Publication Analytical chemistry Abbreviated Journal  
  Volume 52 Issue (up) 3 Pages 449-453  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1980JG67900021 Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116514 Serial 8613  
Permanent link to this record
 

 
Author Vanderborght, B.M.; Van Grieken, R.E. doi  openurl
  Title Trace metal analysis of water containing humic substances by X-ray fluorescence Type A1 Journal article
  Year 1978 Publication International journal of environmental analytical chemistry Abbreviated Journal  
  Volume 5 Issue (up) 3 Pages 221-237  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract Chelation by oxine followed by adsorption on activated carbon results in the efficient collection of many trace metal ions, independent of the trace metal concentration and of high alkali and alkaline earth ion abundances. Preconcentration factors around 10000 are often achieved. When this preconcentration procedure is combined with energy-dispersive X-ray fluorescence, accurate and precise analysis can be carried out, as was proven in several experiments. The technique can also be applied for the determination of divalent ions in natural waters containing up to 10 ppm of humic substances. Trivalent ions can quantitatively be collected from natural water provided suKicient activated carbon is added. Omitting the oxine chelation prior to the activated carbon adsorption step still results in collection of a sometimes important fraction of the trace metal ions from natural waters. This is related to organically bound or colloidal forms of the trace metals.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1978FR88000005 Publication Date 2007-07-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116570 Serial 8692  
Permanent link to this record
 

 
Author Johansson, T.B.; Van Grieken, R.E.; Winchester, J.W. openurl 
  Title Marine influences on aerosol composition in the coastal zone Type A1 Journal article
  Year 1974 Publication Journal de recherches atmosphériques Abbreviated Journal  
  Volume 8 Issue (up) 3-4 Pages 761-766  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0021-7972 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113640 Serial 8204  
Permanent link to this record
 

 
Author Van Grieken, R.E.; Johansson, T.B.; Winchester, J.W. openurl 
  Title Trace metal fractionation effects between sea water and aerosols from bubble bursting Type A1 Journal article
  Year 1974 Publication Journal de recherches atmosphériques Abbreviated Journal  
  Volume 8 Issue (up) 3-4 Pages 611-621  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0021-7972 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113641 Serial 8693  
Permanent link to this record
 

 
Author Rojas, C.M.; Injuk, J.; Van Grieken, R.E.; Maenhaut, W. openurl 
  Title Atmospheric particulate element concentrations and deposition rates in French Polynesia Type A3 Journal article
  Year 2000 Publication Journal de recherche océanographique Abbreviated Journal  
  Volume 25 Issue (up) 3/4 Pages 74-86  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0397-5347 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:32610 Serial 7529  
Permanent link to this record
 

 
Author Martin, J.-M.; Thomas, A.J.; Van Grieken, R.E. pdf  doi
openurl 
  Title Trace element composition of Zaire suspended sediments Type A1 Journal article
  Year 1978 Publication Netherlands journal of sea research Abbreviated Journal  
  Volume 12 Issue (up) 3/4 Pages 414-420  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2003-08-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0077-7579; 1873-1406 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116609 Serial 8688  
Permanent link to this record
 

 
Author Shevchenko, V.P.; Van Grieken, R.E.; van Malderen, H.; Lisitzin, A.P.; Kuptsov, V.M.; Serova, V.V. openurl 
  Title Composition of individual aerosol particles in the marine boundary layer over seas of the Western Russian Arctic Type A1 Journal article
  Year 1999 Publication Doklady earth sciences Abbreviated Journal  
  Volume 366 Issue (up) 4 Pages 546-551  
  Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000086607800027 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1028-334x ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:27582 Serial 7711  
Permanent link to this record
 

 
Author Verbueken, A.H.; Van Grieken, R.E.; Paulus, G.J.; Verpooten, G.A.; de Broe, M.E. doi  openurl
  Title Laser microprobe mass spectrometry of platinum in dog kidney after cisplatin adminstration Type A3 Journal article
  Year 1984 Publication Biomedical mass spectrometry Abbreviated Journal  
  Volume 11 Issue (up) 4 Pages 159-163  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract By means of laser microprobe mass analysis (LAMMA) platinum was detected in the renal proximal tubular cells of a dog that had been intravenously adminstered the antitumor drug cisplatin (5 mg per kg body weight). No definite subcellular localization of the heavy metal was obtained. Sample prparation and analytical features are examined to increase spatial resolution of analysis while maintaining sufficient detection efficiency. The LAMMA method is destructive, but the amount and type of evaporated material can readily be determined when using LAMMA in combination with transmission electron microscopy. Instrumental optimization and standardization of mass signals is possible by using platinum-loaded, ion chelating resin beads embedded and sectioned with the tissue.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2005-05-28  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0306-042x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116712 Serial 8165  
Permanent link to this record
 

 
Author Bernard, P.C.; Van Grieken, R.E.; Eisma, D. doi  openurl
  Title Classification of estuarine particles using automated electron-microprobe analysis and multivariate techniques Type A1 Journal article
  Year 1986 Publication Environmental science and technology Abbreviated Journal  
  Volume 20 Issue (up) 5 Pages 467-473  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1986C117800013 Publication Date 2005-03-17  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0013-936x; 1520-5851 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:113614 Serial 7668  
Permanent link to this record
 

 
Author Verbueken, A.H.; van de Vijver, F.L.; Visser, W.J.; Van Grieken, R.E.; de Broe, M.E. doi  openurl
  Title Laser microprobe mass analysis (LAMMA) to verify the aluminon staining of bone Type A1 Journal article
  Year 1986 Publication Stain technology Abbreviated Journal  
  Volume 61 Issue (up) 5 Pages 287-295  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract Triammonium aurin tricarboxylate (aluminon) has been used to localize aluminum in 2 μm sections of undecalcified, methyl methacrylate embedded bone obtained from patients with terminal chronic renal failure. Aluminum appeared in four cases as bright red lines at the mineralized-bone boundary. In two cases, however, purplish lines were found and one patient showed red as well as purplish lines. Laser microprobe mass analysis (LAMMA) identified aluminum at the location of the red lines and both aluminum and iron at the purplish lines. Furthermore, both iron and aluminum were found in histiocytic bone marrow cells, which showed brownish aluminon staining. It appears that when aluminum and iron occur together, aluminon staining may yield aberrant results. This study shows that LAMMA can be used for the identification of elements sought by histochemical methods and thus permits the evaluation of their staining effects.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2007-12-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0038-9153 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116764 Serial 8159  
Permanent link to this record
 

 
Author Van Grieken, R.E.; Johansson, T.B.; Winchester, J.W.; Odom, L. doi  openurl
  Title Micro-determination of zirconium-hafnium ratios in zircons by proton induced X-ray emission Type A3 Journal article
  Year 1975 Publication Fresenius' Zeitschrift für analytische Chemie Abbreviated Journal  
  Volume 275 Issue (up) 5 Pages 343-348  
  Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract The zirconium/hafnium ratios of zircons are determined using proton induced X-ray emission. Submilligram samples, imbedded in a starch layer and deposited on a 50 μg/cm2 polystyrene carrier, are irradiated for 1020 min with a 5 nA beam of 3.7 MeV protons, while the Hf-Lβ and Zr-Kα X-rays are counted with a Si(Li) detector. The standard deviation per analysis is in the 36 % range. Only few interferences are possible. To eliminate errors due to absorption effects the zircon layer thickness should be above 40 μm or reproducibly thin samples should be employed. Measuring the Hf-Lβ/Hf-Lα ratio for samples and standards might provide a practical check for the absence of absorption errors. The sensitivity is so favourable that, in practice, the minimal sample size is only limited by the minimal amount that can be handled properly.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2004-11-11  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0016-1152 ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116636 Serial 8231  
Permanent link to this record
 

 
Author Verbueken, A.H.; van de Vijver, F.L.; Van Grieken, R.E.; Paulus, G.J.; Visser, W.J.; d'Haese, P.; de Broe, M.E. pdf  openurl
  Title Ultrastructural localization of aluminum in patients with dialysis-associated osteomalacia Type A1 Journal article
  Year 1984 Publication Clinical chemistry : international journal of laboratory medicine and molecular diagnostics Abbreviated Journal  
  Volume 30 Issue (up) 5 Pages 763-768  
  Keywords A1 Journal article; Pharmacology. Therapy; Pathophysiology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)  
  Abstract Using laser microprobe mass analysis, we studied the ultrastructural localization of aluminum in liver and bone tissue of chronic-hemodialysis patients with proven aluminum-induced osteomalacia. In the liver, aluminum was observed to be almost exclusively associated with iron. Detectable aluminum and large amounts of iron were found in lysosomes of both hepatocytes and Kupffer cells. In bone, aluminum was localized at the osteoid/calcified-bone interface and also was associated with iron in some cases.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1984SR66500043 Publication Date  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0009-9147; 1530-8561 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116713 Serial 8703  
Permanent link to this record
 

 
Author Vanderborght, B.M.; Van Grieken, R.E. pdf  doi
openurl 
  Title Water analysis by spark-source mass-spectrometry after preconcentration on activated carbon Type A1 Journal article
  Year 1980 Publication Talanta : the international journal of pure and applied analytical chemistry Abbreviated Journal  
  Volume 27 Issue (up) 5 Pages 417-422  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract For trace analyses of environmental waters, spark-source mass-spectrometry has been combined with a preconcentration procedure involving chelation of the dissolved trace elements with oxine and subsequent adsorption of the oxinates and naturally occurring organic and colloidal metal species onto activated carbon. The activated carbon is filtered off and ashed at low temperature. The residue is dissolved, an internal standard and pure graphite are added and, after drying, the electrodes are prepared. The photographically recorded mass spectrum is evaluated by a suitable computer routine. The error of the procedure is around 30%. While this preconcentration and analysis procedure is capable of measuring about 40 elements quantitatively, in practice 1025 trace elements are determined simultaneously above the 0.1-μg/l. detection limit, as is illustrated by analyses of drinking water, surface and ground water samples. Although a sophisticated technique, SSMS can be considered for regular panoramic survey analyses.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos A1980JR07800006 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0039-9140; 1873-3573 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116557 Serial 8746  
Permanent link to this record
 

 
Author Markowicz, A.A.; Van Grieken, R.E. doi  openurl
  Title X-ray spectrometry Type A1 Journal article
  Year 1986 Publication Analytical chemistry Abbreviated Journal  
  Volume 58 Issue (up) 5 Pages 279r-294r  
  Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos Publication Date 2005-03-08  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record  
  Impact Factor Times cited Open Access  
  Notes Approved no  
  Call Number UA @ admin @ c:irua:116523 Serial 8781  
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