| Records |
| Author |
Stranger, M.; Potgieter-Vermaak, S.S.; Van Grieken, R. |
| Title |
Particulate matter and gaseous pollutants in residences in Antwerp, Belgium |
Type |
A1 Journal article |
| Year |
2009 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
407 |
Issue  |
3 |
Pages |
1182-1192 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
This comprehensive study, a first in Flanders, Belgium, aimed at characterizing the residential indoor air quality of subgroups that took part in the European Community Respiratory Health Survey (ECRHS I1991 and ECHRS II1996) questionnaire-based asthma and related illnesses studies. This pilot study aimed at the evaluation of particulate matter and various inorganic gaseous compounds in residences in Antwerp. In addition personal exposure to the gaseous compounds of one individual per residence was assessed. The main objective was to obtain some base-line pollutant levels and compare these with studies performed in other cities, to estimate the indoor air quality in residences in Antwerp. Correlations between the various pollutant levels, indoor:outdoor ratios and the micro-environments of each residence were investigated. This paper presents results on indoor and ambient PM1, PM2.5 and PM10 mass concentrations, its elemental composition in terms of K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Pb, Al, Si, S and Cl and the water-soluble ionic concentrations in terms of SO42−, NO32−, Cl−, NH4+ K+, Ca2+. In addition, indoor, ambient and personal exposure levels of the gases NO2, SO2, and O3 were determined. Elevated indoor:outdoor ratios were found for NO2 in residences containing gas stoves. In smoker's houses increased PM concentrations of 58 and 43% were found for the fine and coarse fractions respectively. Contrary to the fact that all I/O ratios of the registered elements in each individual house were significantly correlated to each other, no correlation could be established between the I/O ratios of the different houses, thus indicating a unique micro-environment for each residence. Linear relationships between the particulate matter elemental composition, SO2 and O3 levels indoors and outdoors could be established. No linear relationships between indoor and outdoor NO2 and particulate mass concentrations were found. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000262660800020 |
Publication Date |
2008-11-15 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:76002 |
Serial |
8361 |
| Permanent link to this record |
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| |
| Author |
Marguí, E.; Van Grieken, R.; Fontàs, C.; Hidalgo, M.; Queralt, I. |
| Title |
Preconcentration methods for the analysis of liquid samples by X-ray fluorescence techniques |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Applied spectroscopy reviews |
Abbreviated Journal |
|
| Volume |
45 |
Issue |
3 |
Pages |
179-205 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
This article gives an overview of the state-of-the-art of multi-element and single-element preconcentration procedures prior to X-ray fluorescence (XRF) analysis of liquid samples. Many of these preconcentration methods were developed long ago and the purpose of this review is to present some new efficient variations of these methods and new techniques extending the possibilities of XRF for liquid solutions analysis. In addition, trends and future perspectives in this domain are also commented on and discussed in the last section of the review. |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000277705800002 |
Publication Date |
2010-01-28 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
|
| ISSN |
0066-5541 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:82557 |
Serial |
8400 |
| Permanent link to this record |
| |
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| |
| Author |
Tsuji, K.; Sato, T.; Wagatsuma, K.; Claes, M.; Van Grieken, R. |
| Title |
Preliminary experiment of total reflection x-ray fluorescence using two glancing x-ray beams excitation |
Type |
A1 Journal article |
| Year |
1999 |
Publication |
The review of scientific instruments |
Abbreviated Journal |
|
| Volume |
70 |
Issue |
3 |
Pages |
1621-1623 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000079012100006 |
Publication Date |
2002-07-26 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0034-6748 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:23184 |
Serial |
8407 |
| Permanent link to this record |
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| |
| Author |
Potgieter-Vermaak, S.; Van Grieken, R.; Potgieter, H. |
| Title |
Die risikoprofiel van Pb en Cr in stedelike padstof |
Type |
A2 Journal article |
| Year |
2012 |
Publication |
Litnet akademies : 'n joernaal vir die geesteswetenskappe |
Abbreviated Journal |
|
| Volume |
9 |
Issue |
3 |
Pages |
1-22 |
| Keywords |
A2 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The risk profile of Cr and Pb in urban road deposited sediment Exponential urbanisation and industrial growth occur on a global scale and result in an ecological burden, of which one important part is pollution. It is well known that the extent of air pollution has escalated over the past two decades in several parts of the world, despite mitigating measures and legislation. Current research points to the fact that air pollution in urban and industrial areas is substantially different from that found in rural areas. Road dust (RD) contributes up to 35% of airborne particulate matter due to resuspension thereof, and poses a health concern due to carcinogenic and toxic components potentially present in the micron-sized fractions. Although literature does report on the concentrations of trace, toxic metals and metalloids present in RD (Hooker and Nathanail 2006), the molecular make-up of particulates generated due to the resuspension of the RD is not well documented. In vitro and animal toxicological studies have confirmed that the chemical composition of inhaled particles plays a major role in its toxic, genotoxic and carcinogenic mechanisms, but the component-specific toxic effects are still not understood. Transition metals binding to air particle matter can result in reactive oxygen species in the human body (particularly in the lungs), and this is a significant risk, especially for vulnerable population groups like elderly people, children and terminally ill patients. The characterisation of the molecular composition of the fine fraction is evidently of importance for public health. During an earlier study, road dust from an inner-city environment in the UK was collected and partially characterised (Barrett e.a. 2010). These same-size fractions were analysed for their elemental concentrations, using X-ray Fluorescence Spectrometry (XRFS) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). In addition, single-particle analysis was performed on the different fractions by means of Computer Controlled Electron Probe X-ray Micro Analysis (CC-EPXMA) and their molecular structure probed by studying elemental associations. These findings were correlated with Micro Raman Spectroscopy (MRS) results. It was found that the fine fraction (<38 μm) had the highest Pb (238 ppm) and Cr (171 ppm) concentrations. The CC-EPXMA data showed >50% association of Cr-rich particles with Pb and the MRS data showed that the Cr was mostly present as lead chromate and therefore in the Cr(VI) oxidation state. Concentrations of both Pb and Cr decreased substantially (279 (<38 mm) 13 ppm (<1mm); 171 (<38 mm) 91 ppm (<1mm) respectively) in the larger fractions. Apart from rather alarmingly high concentrations of oxidative stressors (Cu, Fe, Mn), the carcinogenic and toxic potential of the inhalable fraction is evident. Preliminary bioaccessibility data indicated that both Cr and Pb are readily |
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Thesis |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
1995-5928 |
ISBN |
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Additional Links |
UA library record |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:102566 |
Serial |
8482 |
| Permanent link to this record |
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| |
| Author |
Worobiec, A.; Kaplinski, A.; Van Grieken, R. |
| Title |
Ruthenium staining as an alternative preparation method for automated EPMA of individual biogenic and organic particles |
Type |
A1 Journal article |
| Year |
2005 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
| Volume |
34 |
Issue |
3 |
Pages |
245-252 |
| Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000229093000014 |
Publication Date |
2005-01-31 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:52229 |
Serial |
8488 |
| Permanent link to this record |
| |
|
| |
| Author |
Saxena, D.P.; Joos, P.; Van Grieken, R.; Subramanian, V. |
| Title |
Sedimentation rate of the floodplain sediments of the Yamuna river basin (tributary of the river Ganges, India) by using <tex>210Pb</tex> and <tex>137Cs</tex> techniques |
Type |
A1 Journal article |
| Year |
2002 |
Publication |
Journal of radioanalytical and nuclear chemistry |
Abbreviated Journal |
|
| Volume |
251 |
Issue |
3 |
Pages |
399-408 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000174851200010 |
Publication Date |
2002-12-28 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
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| ISSN |
0236-5731; 1588-2780 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:36664 |
Serial |
8502 |
| Permanent link to this record |
| |
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| |
| Author |
Evangelista, H.; Maldonado, J.; Godoi, R.H.M.; Pereira, E.B.; Koch, D.; Tanizaki-Fonseca, K.; Van Grieken, R.; Sampaio, M.; Setzer, A.; Alencar, A.; Gonçalves, S.C. |
| Title |
Sources and transport of urban and biomass burning aerosol black carbon at the South-West Atlantic coast |
Type |
A1 Journal article |
| Year |
2007 |
Publication |
Journal of atmospheric chemistry |
Abbreviated Journal |
|
| Volume |
56 |
Issue |
3 |
Pages |
225-238 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000245105900002 |
Publication Date |
2007-01-02 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
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| ISSN |
0167-7764 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:63841 |
Serial |
8561 |
| Permanent link to this record |
| |
|
| |
| Author |
Robberecht, H.J.; Van Grieken, R.E. |
| Title |
Sub-part-per-billion determination of total dissolved selenium and selenite in environmental waters by X-ray fluorescence spectrometry |
Type |
A1 Journal article |
| Year |
1980 |
Publication |
Analytical chemistry |
Abbreviated Journal |
|
| Volume |
52 |
Issue |
3 |
Pages |
449-453 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1980JG67900021 |
Publication Date |
2005-03-08 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0003-2700; 5206-882x |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116514 |
Serial |
8613 |
| Permanent link to this record |
| |
|
| |
| Author |
Vanderborght, B.M.; Van Grieken, R.E. |
| Title |
Trace metal analysis of water containing humic substances by X-ray fluorescence |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
5 |
Issue |
3 |
Pages |
221-237 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Chelation by oxine followed by adsorption on activated carbon results in the efficient collection of many trace metal ions, independent of the trace metal concentration and of high alkali and alkaline earth ion abundances. Preconcentration factors around 10000 are often achieved. When this preconcentration procedure is combined with energy-dispersive X-ray fluorescence, accurate and precise analysis can be carried out, as was proven in several experiments. The technique can also be applied for the determination of divalent ions in natural waters containing up to 10 ppm of humic substances. Trivalent ions can quantitatively be collected from natural water provided suKicient activated carbon is added. Omitting the oxine chelation prior to the activated carbon adsorption step still results in collection of a sometimes important fraction of the trace metal ions from natural waters. This is related to organically bound or colloidal forms of the trace metals. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1978FR88000005 |
Publication Date |
2007-07-07 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116570 |
Serial |
8692 |
| Permanent link to this record |
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|
| |
| Author |
Worobiec, A.; Samek, J.; Krata, A.; van Meel, K.; Krupińska, B.; Stefaniak, E.A.; Karaszkiewicz, P.; Van Grieken, R. |
| Title |
Transport and deposition of airborne pollutants in exhibition areas located in historical buildings: study in Wawel Castle Museum in Cracow, Poland |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Journal of cultural heritage |
Abbreviated Journal |
|
| Volume |
11 |
Issue |
3 |
Pages |
354-359 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
| Abstract |
Historical buildings and castles that have been turned nowadays into museums, as an exhibition area for precious cultural heritage (CH) items, need more attention since they are CH objects by themselves. Moreover, the preservation techniques require often, significant interventions; however such changes are not always possible or are very limited. The aim of the present study was to investigate the influence of outdoor air pollution on the composition of particulate matter and gases inside the museum of Wawel Castle in Cracow, Poland. During this study a combination of micro and trace analysis techniques were applied, including energy dispersive X-ray fluorescence (EDXRF) and electron probe microanalysis (EPMA). An intensive transport of air pollutants coupled with accumulation of the particles inside the museum was noticed (considerably higher in winter than summer). A high content of carbon and organic matter agglomerated with inorganic particles was determined. Those particles are of special concern because of their adhesive properties and reactivity. It was also noted that the conditions inside the museum favour the reaction of the particles with gaseous pollutants. It was especially the case for nitrate particles. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000279867800017 |
Publication Date |
2010-03-25 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1296-2074 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:83277 |
Serial |
8698 |
| Permanent link to this record |
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| |
| Author |
Muia, L.M.; Van Grieken, R. |
| Title |
Use of theoretical accurate binary influence coefficients with Tertian's equation in X-ray fluorescence analysis of silicate rocks in borax glass beads |
Type |
A1 Journal article |
| Year |
1990 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
| Volume |
19 |
Issue |
3 |
Pages |
141-144 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
A study of the suitability of the Tertian algorithm using new accurate binary influence coefficients and a comparison standard for x-ray fluorescence analysis of geological materials prepared as borax glass beads was performed. The algorithm was found to give satisfactory results for the analysis of four major components in geological materials. Even in the worst case, when there is a factor of 20 difference in the concentration in the specimen and a comparison standard, the algorithm gives results which differ from the true results by a factor of about 2. This makes the algorithm attractive as a diagnostic tool in analyses of unknown specimens and in the identification of appropriate standards. The binary coefficients are easily calculated so that the algorithm can be implemented on a minicomputer. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1990DJ47800009 |
Publication Date |
2005-05-28 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116492 |
Serial |
8725 |
| Permanent link to this record |
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| |
| Author |
Johansson, T.B.; Van Grieken, R.E.; Winchester, J.W. |
| Title |
Marine influences on aerosol composition in the coastal zone |
Type |
A1 Journal article |
| Year |
1974 |
Publication |
Journal de recherches atmosphériques |
Abbreviated Journal |
|
| Volume |
8 |
Issue |
3-4 |
Pages |
761-766 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0021-7972 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:113640 |
Serial |
8204 |
| Permanent link to this record |
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| |
| Author |
Van Grieken, R.E.; Johansson, T.B.; Winchester, J.W. |
| Title |
Trace metal fractionation effects between sea water and aerosols from bubble bursting |
Type |
A1 Journal article |
| Year |
1974 |
Publication |
Journal de recherches atmosphériques |
Abbreviated Journal |
|
| Volume |
8 |
Issue |
3-4 |
Pages |
611-621 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
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| ISSN |
0021-7972 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:113641 |
Serial |
8693 |
| Permanent link to this record |
| |
|
| |
| Author |
Kontozova-Deutsch, V.; Deutsch, F.; Godoi, R.H.M.; Spolnik, Z.; Wei, W.; Van Grieken, R. |
| Title |
Application of EPMA and XRF for the investigation of particulate pollutants in the field of cultural heritage |
Type |
A1 Journal article |
| Year |
2008 |
Publication |
Microchimica acta |
Abbreviated Journal |
|
| Volume |
161 |
Issue |
3/4 |
Pages |
465-469 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000256175600029 |
Publication Date |
2008-01-30 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0026-3672; 1436-5073 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:68798 |
Serial |
7474 |
| Permanent link to this record |
| |
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| |
| Author |
Semenov, M.Y.; Spolnik, Z.; Van Grieken, R. |
| Title |
Assessing the size-dependent chemical speciation of soil particles using electron probe X-ray microanalysis |
Type |
A1 Journal article |
| Year |
2007 |
Publication |
Microchimica acta |
Abbreviated Journal |
|
| Volume |
157 |
Issue |
3/4 |
Pages |
121-126 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000244691600001 |
Publication Date |
2006-07-26 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0026-3672; 1436-5073 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:63400 |
Serial |
7498 |
| Permanent link to this record |
| |
|
| |
| Author |
Rojas, C.M.; Injuk, J.; Van Grieken, R.E.; Maenhaut, W. |
| Title |
Atmospheric particulate element concentrations and deposition rates in French Polynesia |
Type |
A3 Journal article |
| Year |
2000 |
Publication |
Journal de recherche océanographique |
Abbreviated Journal |
|
| Volume |
25 |
Issue |
3/4 |
Pages |
74-86 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
|
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0397-5347 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:32610 |
Serial |
7529 |
| Permanent link to this record |
| |
|
| |
| Author |
Harlay, J.; Borges, A.V.; van der Zee, C.; Delille, B.; Godoi, R.H.M.; Schiettecatte, L.-S.; Roevros, N.; Aerts, K.; Lapernat, P.-E.; Rebreanu, L.; Groom, S.; Daro, M.-H.; Van Grieken, R.; Chou, L. |
| Title |
Biogeochemical study of a coccolithophore bloom in the northern Bay of Biscay (NE Atlantic Ocean) in June 2004 |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Progress in oceanography |
Abbreviated Journal |
|
| Volume |
86 |
Issue |
3/4 |
Pages |
317-336 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The present paper synthesizes data obtained during a multidisciplinary cruise carried out in June 2004 at the continental margin of the northern Bay of Biscay. The data-set allows to describe the different stages of a coccolithophore bloom dominated by Emiliania huxleyi. The cruise was carried out after the main spring phytoplankton bloom that started in mid-April and peaked in mid-May. Consequently, low phosphate (PO4 < 0.2 μM) and silicate (DSi < 2.0 μM) concentrations, low partial pressure of carbon dioxide (pCO2) and high calcite saturation degree in surface waters combined with thermal stratification, probably favoured the blooming of coccolithophores. During the period of the year our cruise was carried out, internal tides induce enhanced vertical mixing at the continental shelf break leading to the injection of inorganic nutrients to surface waters that probably trigger the bloom. The bloom developed as the water-column stratified and as the water mass was advected over the continental shelf, following the general residual circulation in the area. The most developed phase of the bloom was sampled in a remote sensed high reflectance (HR) patch over the continental shelf that was characterized by low chlorophyll-a (Chl-a) concentration in surface waters (<1.0 μg L−1), high particulate inorganic carbon (PIC) concentration (not, vert, similar8 μmol L−1) and coccolithophore abundance up to 57 × 106 cells L−1. Transparent exopolymer particles (TEP) concentrations ranged between 15 and 75 μg C L−1 and carbon content of TEP represented up to 26% of the particulate organic carbon (POC; maximum concentration of 15.5 μmol L−1 in the upper 40 m). Integrated primary production (PP) ranged between 210 and 680 mg C m−2 d−1 and integrated calcification (CAL) ranged between 14 and 140 mg C m−2 d−1, within the range of PP and CAL values previously reported during coccolithophore blooms in open and shelf waters of the North Atlantic Ocean. Bacterial protein production (BPP) measurements in surface waters (0.30.7 μg C L−1 h−1) were much higher than those reported during early phases of coccolithophore blooms in natural conditions, but similar to those during peak and declining coocolithophorid blooms reported in mesocosms. Total alkalinity anomalies with respect to conservative mixing (ΔTA) down to −49 μmol kg−1 are consistent with the occurrence of biogenic precipitation of calcite, while pCO2 remained 15107 μatm lower than atmospheric equilibrium (372 μatm). The correlation between ΔTA and pCO2 suggested that pCO2 increased in part due to calcification, but this increase was insufficient to overcome the background under-saturation of CO2. This is related to the biogeochemical history of the water masses due to net carbon fixation by the successive phytoplankton blooms in the area prior to the cruise, hence, the investigated area remained a sink for atmospheric CO2 despite calcification. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
000281937800001 |
Publication Date |
2010-04-20 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0079-6611 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:84236 |
Serial |
7560 |
| Permanent link to this record |
| |
|
| |
| Author |
Roekens, E.; Komy, Z.; Leysen, L.; Veny, P.; Van Grieken, R. |
| Title |
Chemistry of precipitation near a limestone building |
Type |
A1 Journal article |
| Year |
1988 |
Publication |
Water, air and soil pollution |
Abbreviated Journal |
|
| Volume |
38 |
Issue |
3/4 |
Pages |
273-282 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
A total of 82 samples of wet and total deposition were sampled near the limestone cathedral at Mechelen, Belgium, which is presently being affected seriously by air pollution, and at a reference site. Most of these samples were analyzed for 10 major and 7 trace ions in solution and for 15 elements in suspension. It appeared that calcite, released from the building, effectively neutralizes the rainwater in the near vicinity and produces high Ca and bicarbonate concentrations. Heavy metal concentrations are hardly affected by the building. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2014-08-25 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0049-6979; 1573-2932 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116806 |
Serial |
7663 |
| Permanent link to this record |
| |
|
| |
| Author |
Godoi, A.F.L.; Sawada, E.Y.; de Marchi, M.R.R.; Van Grieken, R.; Godoi, R.H.M. |
| Title |
Determination of BTEX by GCMS in air of offset printing plants: comparison between conventional and ecological inks |
Type |
A3 Journal article |
| Year |
2009 |
Publication |
Water, air, and soil pollution : focus |
Abbreviated Journal |
|
| Volume |
9 |
Issue |
3/4 |
Pages |
163-169 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The use of inks containing organic solvents by the offset printing process implies in the release of volatile organic compounds to the work environment. Many of these compounds such as benzene, toluene, ethylbenzene, and the xylene isomers (well known by the acronym BTEX) are extremely toxic. In this study, the BTEX concentrations were determined in two different printing plants that use distinct types of inks: the conventional and the so-called ecological, which is manufactured based on vegetal oil. Concentration ranges were 4384, 153,480, 2133, 5459, and 2236 μg m−3 for benzene, toluene, ethylbenzene, m + p-xylene, and o-xylene, respectively, for the conventional printing plant. At the ecological printing plant, concentration ranges were below limit of detection (<LD)-31, <LD-618, <LD-1,690, <LD-10,500, <LD-3,360 μg m−3 for benzene, toluene, ethylbenzene, m + p-xylene, and o-xylene, respectively. BTEX concentrations are lower at the ecological printing environment than in the conventional, where mineral oil-based inks are used. However, the worker who cleans the printing matrices is exposed to high concentrations of ethylbenzene and xylenes, due probably to the cleaning products composition (containing high amounts of BTEX). Although the BTEX concentrations found in both printing work environments were below the limits considered by the Brazilian Law for Activities and Unhealthy Operations (NR-15), the exposure to such vapors characterizes risk to the workers health for some of the evaluated samples, mainly the personal ones. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2009-09-29 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1567-7230 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:80493 |
Serial |
7775 |
| Permanent link to this record |
| |
|
| |
| Author |
Ramesh, R.; Subramanian, V.; Van Grieken, R.; Van 't dack, L. |
| Title |
The elemental chemistry of sediments in the Krishna River basin, India |
Type |
A1 Journal article |
| Year |
1989 |
Publication |
Chemical geology |
Abbreviated Journal |
|
| Volume |
74 |
Issue |
3/4 |
Pages |
331-341 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Composition of bed, core and suspended sediments collected from Krishna River sediments were studied and the observations are discussed in the light of other Indian rivers, world's average river suspended particles, surficial rock and soils. The contents of V, Cr, Co, Ni, Cu and Zn in the suspended particles are higher in the Krishna River than in the world's average, indicating pollution inputs. Suspended sediments are enriched (5 to 10 times) in all the elements considered relative to bed sediments. Downstream profile and metal/Al ratios of the elements indicate that the mobility of elements within the basin is controlled by basin geology, size and mineralogical characteristics. Good correlations observed for a number of elements point out to their common sink in the clay fraction of the sediments. There is no systematic variation with depth for the major elements and most of the elements are considerably higher compared to estuarine or Bay of Bengal sediments. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
A1989T007000012 |
Publication Date |
2003-08-06 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0009-2541 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:111482 |
Serial |
7885 |
| Permanent link to this record |
| |
|
| |
| Author |
Godoi, R.H.M.; Avigo, D.; Campos, V.D.; Tavares, T.M.; de Marchi, M.R.R.; Van Grieken, R.; Godoi, A.F.L. |
| Title |
Indoor air quality assessment of elementary schools in Curitiba, Brazil |
Type |
A3 Journal article |
| Year |
2009 |
Publication |
Water, air, and soil pollution : focus |
Abbreviated Journal |
|
| Volume |
9 |
Issue |
3/4 |
Pages |
171-177 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The promotion of good indoor air quality in schools is of particular public concern for two main reasons: (1) school-age children spend at least 30% of their time inside classrooms and (2) indoor air quality in urban areas is substantially influenced by the outdoor pollutants, exposing tenants to potentially toxic substances. Two schools in Curitiba, Brazil, were selected to characterize the gaseous compounds indoor and outdoor of the classrooms. The concentrations of benzene, toluene, ethylbenzene, and the isomers xylenes (BTEX); NO2; SO2; O3; acetic acid (HAc); and formic acid (HFor) were assessed using passive diffusion tubes. BTEX were analyzed by gas chromatographyion trap mass spectrometry and other collected gasses by ion chromatography. The concentration of NO2 varied between 9.5 and 23 µg m−3, whereas SO2 showed an interval from 0.1 to 4.8 µg m−3. Within the schools, BTEX concentrations were predominant. Formic and acetic acids inside the classrooms revealed intermediate concentrations of 1.5 µg m−3 and 1.2 µg m−3, respectively. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2009-09-29 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1567-7230 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:80494 |
Serial |
8081 |
| Permanent link to this record |
| |
|
| |
| Author |
Kontozova-Deutsch, V.; Godoi, R.H.M.; Worobiec, A.; Spolnik, Z.; Krata, A.; Deutsch, F.; Van Grieken, R. |
| Title |
Investigation of gaseous and particulate air pollutants at the Basilica Saint-Urbain in Troyes, related to the preservation of the medieval stained glass windows |
Type |
A1 Journal article |
| Year |
2008 |
Publication |
Microchimica acta |
Abbreviated Journal |
|
| Volume |
162 |
Issue |
3/4 |
Pages |
425-432 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
| Abstract |
|
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
000258194900015 |
Publication Date |
2008-02-22 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0026-3672; 1436-5073 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:70072 |
Serial |
8122 |
| Permanent link to this record |
| |
|
| |
| Author |
Niessner, R.; Klockow, D.; Bruynseels, F.; Van Grieken, R. |
| Title |
Investigation of heterogeneous reactions of PAH's on particle surfaces using laser microprobe mass analysis |
Type |
A1 Journal article |
| Year |
1985 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
22 |
Issue |
3/4 |
Pages |
281-295 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Artificially generated NaCl particles were coated with PAH's by using a condensation technique. These particles were exposed to reactive gases like ozone, bromine and nitrogen dioxide. The original as well as the exposed particles were investigated by fluorimetric analysis and by LAMMA (Laser Microprobe Mass Analysis) in the desorption mode, which allows the evaporation and characterization of surfaces of single particles. The results are interpreted in terms of possible heterogeneous atmospheric reactions. The reactivity of the considered PAH's towards nitrogen dioxide was found to be negligible. The structure of the reaction products formed with ozone was partially elucidated. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
A1985AZE2300009 |
Publication Date |
2007-07-07 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116576 |
Serial |
8124 |
| Permanent link to this record |
| |
|
| |
| Author |
Sholkovitz, E.R.; Van Grieken, R.; Eisma, D. |
| Title |
The major-element composition of suspended matter in the Zaire river and estuary |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
|
| Volume |
12 |
Issue |
3/4 |
Pages |
407-413 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2003-08-07 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0077-7579; 1873-1406 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116608 |
Serial |
8195 |
| Permanent link to this record |
| |
|
| |
| Author |
Deutsch, F.; Vankerkom, J.; Janssen, L.; Janssen, S.; Bencs, L.; Van Grieken, R.; Fierens, F.; Dumont, G.; Mensink, C. |
| Title |
Modelling concentrations of airborne primary and secondary PM10 and PM2.5 with the BelEUROS-model in Belgium |
Type |
A1 Journal article |
| Year |
2008 |
Publication |
Ecological modelling |
Abbreviated Journal |
|
| Volume |
217 |
Issue |
3/4 |
Pages |
230-239 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The Eulerian Chemistry-Transport Model BelEUROS was used to calculate the concentrations of airborne PM10 and PM2.5 over Europe. Both primary as well as secondary particulate matter in the respirable size-range was taken into account. Especially PM2.5 aerosols are often formed in the atmosphere from gaseous precursor compounds. Comprehensive computer codes for the calculation of gas phase chemical reactions and thermodynamic equilibria between compounds in the gas-phase and the particulate phase had been implemented into the BelEUROS-model. Calculated concentrations of PM10 and PM2.5 are compared to observations, including both the spatial and daily, temporal distribution of particulate matter in Belgium for certain monitoring locations and periods. The concentrations of the secondary compounds ammonium, nitrate and sulfate have also been compared to observed values. BeIEUROS was found to reproduce the observed concentrations rather well. The model was applied to assess the contribution of emissions derived from the sector agriculture in Flanders, the northern part of Belgium, to PM10- and PM2.5-concentrations. The results demonstrate the importance of ammonia emissions in the formation of secondary particulate matter. Hence, future European emission abatement policy should consider more the role of ammonia in the formation of secondary particles |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
000259842900004 |
Publication Date |
2008-07-18 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0304-3800 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:70073 |
Serial |
8268 |
| Permanent link to this record |
| |
|
| |
| Author |
Dekov, V.; van Alsenoy, V.; Onar, N.; van Put, A.; Van Grieken, R. |
| Title |
Partitioning of heavy metals between estuarine sediments and dissolved phase as a function of salinity, pH and time (Scheldt estuary) |
Type |
A1 Journal article |
| Year |
2001 |
Publication |
Geologica Balcanica |
Abbreviated Journal |
|
| Volume |
30 |
Issue |
3/4 |
Pages |
65-76 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
|
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
|
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0324-0894 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:36086 |
Serial |
8362 |
| Permanent link to this record |
| |
|
| |
| Author |
Worobiec, A.; Samek, L.; Spolnik, Z.; Kontozova, V.; Stefaniak, E.; Van Grieken, R. |
| Title |
Study of the winter and summer changes of the air composition in the church of Szalowa, Poland, related to conservation |
Type |
A1 Journal article |
| Year |
2006 |
Publication |
Microchimica acta |
Abbreviated Journal |
|
| Volume |
156 |
Issue |
3/4 |
Pages |
253-261 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
| Abstract |
The St. Michael Archangel's Church in Szalowa, Poland, was selected for closer investigation with respect to the indoor/outdoor air exchange and its influence on the air quality and work arts preservation. Chemical composition, size and abundance of particulate matter and concentration of gases NO2, SO2, O-3 inside and outside the church were determined. To study seasonal variation of the weather condition (temperature, inversion level, wind direction) and the influence of seasonal sources of the air pollution (like heating of the nearby houses), samples were collected in winter and summer time. It was stated that suspended particulate matter inside the wooden church has in general an outdoor source. Several groups of particles were distinguished such as the organic ones, soil dust, nitrates and sulphates. In case of organic and soil dust particles, the concentration inside was higher than outside. From the results, in comparison to literature data, one can conclude that accumulation of particulate suspended matter in the church is more intense than in other types of buildings. Gaseous pollutants were detected but their concentration was negligible. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
000242830500007 |
Publication Date |
2006-06-05 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0026-3672; 1436-5073 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:61091 |
Serial |
8609 |
| Permanent link to this record |
| |
|
| |
| Author |
Seftel, E.M.; Popovici, E.; Mertens, M.; Stefaniak, E.A.; Van Grieken, R.; Cool, P.; Vansant, E.F. |
| Title |
SnIV-containing layered double hydroxides as precursors for nano-sized ZnO/SnO2 photocatalysts |
Type |
A1 Journal article |
| Year |
2008 |
Publication |
Applied catalysis : B : environmental |
Abbreviated Journal |
|
| Volume |
84 |
Issue |
3/4 |
Pages |
699-705 |
| Keywords |
A1 Journal article; Laboratory of adsorption and catalysis (LADCA); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Sn4+-containing LDH was prepared using the co-precipitation method at constant pH, and characterized using X-ray diffraction, UVvis diffuse reflectance spectroscopy and TG/DTG methods. The obtained product was further exposed to different thermal treatments in order to obtain nano-sized coupled ZnO/SnO2 systems with enhanced photocatalytic performances than the ones obtained by mixing the two semiconductor oxides. The formation of a well-defined ZnO/SnO2 system and the crystallite size, fully investigated using XRD, micro-Raman scattering and UVvis DR techniques, were found to be influenced by the nature of the precursors and the calcination temperature. The photocatalytic activity of the ZnO/SnO2 systems, evaluated for the photodegradation of methyl orange (MO) dye, was studied as a function of the initial pH, catalyst loading and the calcination temperature. The metal dispersion supplied by layered structures proved to be an advantage when preparing coupled ZnO/SnO2 systems, the photocatalytic activity being 2.3 times higher comparing with the physical mixtures performances. The maximum photocatalytic activity of the coupled ZnO/SnO2 system having a layered precursor was observed when using neutral pH, at a catalyst loading of 1 g/L calcined at 600 °C for 4 h. |
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Thesis |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000261123600046 |
Publication Date |
2008-06-19 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0926-3373 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:72020 |
Serial |
8651 |
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| Author |
Martin, J.-M.; Thomas, A.J.; Van Grieken, R.E. |
| Title |
Trace element composition of Zaire suspended sediments |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
Netherlands journal of sea research |
Abbreviated Journal |
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| Volume |
12 |
Issue |
3/4 |
Pages |
414-420 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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Thesis |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
2003-08-07 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0077-7579; 1873-1406 |
ISBN |
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Additional Links |
UA library record |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:116609 |
Serial |
8688 |
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| Author |
Godoi, R.H.M.; Braga, D.M.; Makarovska, Y.; Alfoldy, B.; Carvalho Filho, M.A.S.; Van Grieken, R.; Godoi, A.F.L. |
| Title |
Inhable particulate matter from lime industries: chemical composition and deposition in human respiratory tract |
Type |
A1 Journal article |
| Year |
2008 |
Publication |
Atmospheric environment : an international journal |
Abbreviated Journal |
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| Volume |
42 |
Issue |
30 |
Pages |
7027-7033 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Air pollution caused by the lime production industry has become a serious problem with potential effects to human health, especially in developing countries. Colombo is a city included in the Metropolitan Region of Curitiba (capital of Parana State) in South Brazil. In Colombo city, a correlation has been shown between the lime production and the number of persons who need respiratory treatment in a local hospital, indicating that the lime industry can cause deleterious health effects in the exposed workers and population. This research was conducted to deal firstly with the characterization of the size distribution and chemical compositions of particles emitted from lime manufacturing and subsequently to assess the deposition rate of inhaled dolomitic lime aerosol particles in the human respiratory tract. The elemental chemical composition and particle size of individual atmospheric particles was quantitatively elucidated, including low-Z components like C, N and 0, as well as higher-Z elements, using automated electron probe microanalysis. Information concerning the bulk composition is provided by energy-dispersive X-ray detection. The majority of the respirable particulate matter identified was composed of aluminosilicates, Ca-Mg oxides, carbon-rich particles, mixtures of organic particles and Ca-Mg carbonates, soot and biogenic particles. In view of the chemical composition and size distribution of the aerosol particles, local deposition efficiencies in the human respiratory system were calculated, revealing the deposition of CaO center dot MgO at extrathoracic, tracheobronchial and pulmonary levels. The results of this study offer evidence to the threat of the fine and coarse particles emitted from dolomite lime manufacturing, allowing policy-makers to better focus their mitigation strategies in an effective way, as well as to the dolomite producers for the purpose of designing and/or implementing improved emission controls. |
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Thesis |
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Place of Publication |
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Editor |
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Wos |
000260265300001 |
Publication Date |
2008-07-18 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
1352-2310 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:70451 |
Serial |
8101 |
| Permanent link to this record |
