Marguí, E, Van Grieken R (2013) X-ray fluorescence spectrometry and related techniques : an introduction. 148 p
Keywords: MA3 Book as author; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
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“Visualizing the 17th century underpainting in Portrait of an Old Man by Rembrandt van Rijn using synchrotron-based scanning macro-XRF”. Alfeld M, Siddons DP, Janssens K, Dik J, Woll A, Kirkham R, van de Wetering E, Applied physics A : materials science &, processing 111, 157 (2013). http://doi.org/10.1007/S00339-012-7490-5
Abstract: In 17th century Old Master Paintings, the underpainting generally refers to the first sketch of a composition. The underpainting is applied to a prepared ground using a monochrome, brown oil paint to roughly indicate light, shade and contours. So far, methods to visualize the underpainting-other than in localized cross-sections-have been very limited. Neither infrared reflectography nor neutron induced autoradiography have proven to be practical, adequate visualization tools. Thus, although of fundamental interest in the understanding of a painting's genesis, the underpainting has virtually escaped all imaging efforts. In this contribution we will show that 17th century underpainting may consist of a highly heterogeneous mixture of pigments, including copper pigments. We suggest that this brown pigment mixture is actually the recycled left-over of a palette scraping. With copper as the heaviest exclusive elemental component, we will hence show in a case study on a Portrait of an Old Man attributed to Rembrandt van Rijn how scanning macro-XRF can be used to efficiently visualize the underpainting below the surface painting and how this information can contribute to the discussion of the painting's authenticity.
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Impact Factor: 1.455
Times cited: 26
DOI: 10.1007/S00339-012-7490-5
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Smits M (2013) Photocatalytic degradation of diesel soot : from application to reaction mechanism. 160 p
Keywords: Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
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“Stability of Ge12C48 and Ge20C40 heterofullerenes : a first principles molecular dynamics study”. Massobrio C, Djimbi DM, Matsubara M, Scipioni R, Boero M, Chemical physics letters 556, 163 (2013). http://doi.org/10.1016/j.cplett.2012.11.033
Abstract: By using first-principles molecular dynamics, we address the issue of structural stability for the C-60 Ge-m(m) family of doped heterofullerenes through a set of calculations targeting C48Ge12 and C40Ge20. Three kinds of theoretical tools are employed: (a) static structural optimization, (b) a bonding analysis based on localized orbitals (Wannier wavefunctions and centers) and (c) first-principles molecular dynamics at finite temperature. This latter tool allows concluding that the segregated form of C40Ge20 is less stable than its Si-based counterpart. However, the non-segregated forms of C40Ge20 and C40Si20 have comparable stabilities at finite temperatures. (C) 2012 Elsevier B. V. All rights reserved.
Keywords: A1 Journal article; Electron microscopy for materials research (EMAT)
Impact Factor: 1.815
Times cited: 3
DOI: 10.1016/j.cplett.2012.11.033
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“Scanning XRF investigation of a Flower Still Life and its underlying composition from the collection of the Kröller-Muller Museum”. Alfeld M, van der Snickt G, Vanmeert F, Janssens K, Dik J, Appel K, van der Loeff L, Chavannes M, Meedendorp T, Hendriks E, Applied physics A : materials science &, processing 111, 165 (2013). http://doi.org/10.1007/S00339-012-7526-X
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Impact Factor: 1.455
Times cited: 35
DOI: 10.1007/S00339-012-7526-X
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“Bulky knots and links generated by cutting generalized Mobius-Listing bodies and applications in the natural sciences”. Gielis J, Caratelli D, Tavkelidze I, Fougerolle Y, Ricci PE, Gerats T page 167 (2013).
Keywords: H2 Book chapter; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
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“Microchemical investigation of bone derived from mice treated with strontium in different chemical forms using scanning electron microscopy and micro-Raman spectroscopy”. Jabłoński MB, Stefaniak EA, Darchuk L, Turzańska K, Gorzelak M, Kuduk R, Dorriné, W, Van Grieken R, Microchemical journal 108, 168 (2013). http://doi.org/10.1016/J.MICROC.2012.10.015
Abstract: We used SEM/EDX and micro-Raman spectroscopy to investigate the chemical changes (both on the level of elementary and molecular composition) of mice bones when strontium is incorporated in their microstructure after being administered in the form of two salts: chloride and ranelate. Strontium accumulated mainly in vicinity of bone edges, both cortical and close to bone marrow. The distribution of other elements comprising bone samples (Ca, P, Mg, K etc.) was also determined by energy-dispersive X-ray analysis (EDX). The area adjacent to a cortical bone edge with accumulated strontium has presented modified Raman spectral profiles. Besides most of the Raman bands typical for both mineral (hydroxyapatite with carbonate substitution type B) and organic phases of a bone, we observed a Raman band at 811 cm− 1. It was detected regularly in the sample with high strontium concentration.
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
DOI: 10.1016/J.MICROC.2012.10.015
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“Manufacturing techniques and production defects of 16th-17th century majolica tiles from Antwerp (Belgium)”. Vandevijvere M, Van de Voorde L, Caen J, van Espen P, Vekemans B, Vincze L, Schalm O page 169 (2013).
Keywords: H2 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)
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Verstraelen H (2013) Corrosion in ballast tanks on board of merchant vessels : study of the relation between steel quality and corrosion. 172 p
Keywords: Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
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“Infiltration or indoor sources as determinants of the elemental composition of particulate matter inside a school in Wroclaw, Poland?”.Zwozdziak A, Sowka I, Krupińska B, Zwozdziak J, Nych A, Building and environment 66, 173 (2013). http://doi.org/10.1016/J.BUILDENV.2013.04.023
Abstract: Children's exposure to air pollution requires a focus on air quality in places where they spend most time, e.g. in schools. Therefore, understanding how indoor elemental concentrations relate the outdoor ones is necessary to create healthy indoor school environment. The aims of this study were to examine the elemental composition of particulate matter (PM1, PM2.5, PM10) in the school and also to investigate to what degree indoor elemental concentrations are affected by outdoor air or generated inside the school. The measurements were performed inside and outside the public school building in the centre of the city. It was observed that concentrations of most elements were higher at school than outside. The dominant elements in PM1 both indoors and outdoors were S, Cl, K, and Zn. PM2.5 and PM10 fractions inside the school were clearly enriched in elements of mineral origin, additionally S, Zn, K and Cl were also present in high concentrations both indoors and outdoors. Results suggested that a significant contribution to indoor Zn, Pb and S concentrations in the PM2.5 fraction was from penetration of outdoor air. 88%, 80% and 90% of the observed total variations in indoor concentrations of Zn, Pb, and S were explained by the linear relationship between indoor and outdoor concentrations. The lack of correlation between indoor and outdoor concentrations obtained for Si, Ca, Ti, Sr indicated that these metals were more likely to originate from indoor sources. (C) 2013 Elsevier Ltd. All rights reserved.
Keywords: A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
DOI: 10.1016/J.BUILDENV.2013.04.023
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“Editorial : introducing Dr Markowicz as X-Ray Spectrometry's new associate editor for Europe”. Van Grieken R, X-ray spectrometry 42, 175 (2013). http://doi.org/10.1002/XRS.2447
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
DOI: 10.1002/XRS.2447
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“Spatial monitoring of organohalogen compounds in surface water and sediments of a rural-urban river basin in Tanzania”. Hellar-Kihampa H, De Wael K, Lugwisha E, Govindan M, Covaci A, Van Grieken R, The science of the total environment 447, 186 (2013). http://doi.org/10.1016/J.SCITOTENV.2012.12.083
Abstract: The presence of persistent organic pollutants in Tanzanian environment is not well monitored despite the existing pollution potential from a number of sources. In this study, we investigated for the first time, the concentration profiles of different organohalogen compounds such as organochlorine pesticide residues (OCPs), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) in environmental samples (water and sediments) from the Pangani river basin (PRB). The PRB is one of the largest drainage basins in Tanzania, with its watershed exposed to multiple input sources of trace organic contaminants. Surface water and sediments were sampled from 12 representative stations of diverse characteristics and land-use practices, in three distinct seasons, and extracted by liquidliquid and Soxhlet extraction methods, respectively. Water samples were analyzed by GC-ECD for OCPs only, while sediment samples were analyzed for OCPs, PCBs and PBDEs by GC/MS. Seven compounds, dominated by HCH isomers (5104460 pg/L) and DDT analogs (1601460 pg/L),were detected in the water samples. These concentrations are far below the WHO guidelines for drinking water quality. A total of 42 compounds (8 OCPs, 28 PCB congeners and 6 PBDE congeners) were detected in the sediment samples. Their respective total concentration ranges were 24510,230; 35711,000 and 382175 pg/g dry weight. The spatial distribution patterns and Hierarchical Cluster Analysis reflected the impact of historical agricultural usage in sugarcane plantations (OCPs), and urbanization (PCBs and PBDEs). Risk assessment using sediment quality guidelines indicated no ecotoxicological risks. The results we have found provide preliminary data on levels of the organic contaminants in Pangani river basin as a new insight on the environmental quality of the area.
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Toxicological Centre
Impact Factor: 4.9
Times cited: 42
DOI: 10.1016/J.SCITOTENV.2012.12.083
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“Catheter-associated bloodstream infections in pediatric hematology-oncology patients”. Celebi S, Sezgin ME, Çakir D, Baytan B, Demirkaya M, Sevinir B, Bozdemir SE, Gunes AM, Hacimustafaoglu M, Pediatric Hematology And Oncology 30, 187 (2013). http://doi.org/10.3109/08880018.2013.772683
Abstract: Catheter-associated bloodstream infections (CABSIs) are common complications encountered with cancer treatment. The aims of this study were to analyze the factors associated with recurrent infection and catheter removal in pediatric hematology-oncology patients. All cases of CABSIs in patients attending the Department of Pediatric Hematology-Oncology between January 2008 and December 2010 were reviewed. A total of 44 episodes of CABSIs, including multiple episodes involving the same catheter, were identified in 31 children with cancer. The overall CABSIs rate was 7.4 infections per 1000 central venous catheter (CVC) days. The most frequent organism isolated was coagulase-negative Staphylococcus (CONS). The CVC was removed in nine (20.4%) episodes. We found that hypotension, persistent bacteremia, Candida infection, exit-side infection, neutropenia, and prolonged duration of neutropenia were the factors for catheter removal. There were 23 (52.2%) episodes of recurrence or reinfection. Mortality rate was found to be 9.6% in children with CABSIs. In this study, we found that CABSIs rate was 7.4 infections per 1000 catheter-days. CABSIs rates in our hematology-oncology patients are comparable to prior reports. Because CONS is the most common isolated microorganism in CABSIs, vancomycin can be considered part of the initial empirical regimen.
Keywords: A1 Journal article; Condensed Matter Theory (CMT)
Impact Factor: 1.12
DOI: 10.3109/08880018.2013.772683
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“Phonon-assisted Zener tunneling in a p-n diode silicon nanowire”. Carrillo-Nunez H, Magnus W, Vandenberghe WG, Sorée B, Peeters FM, Solid state electronics 79, 196 (2013). http://doi.org/10.1016/j.sse.2012.09.004
Abstract: The Zener tunneling current flowing through a biased, abrupt p-n junction embedded in a cylindrical silicon nanowire is calculated. As the band gap becomes indirect for sufficiently thick wires, Zener tunneling and its related transitions between the valence and conduction bands are mediated by short-wavelength phonons interacting with mobile electrons. Therefore, not only the high electric field governing the electrons in the space-charge region but also the transverse acoustic (TA) and transverse optical (TO) phonons have to be incorporated in the expression for the tunneling current. The latter is also affected by carrier confinement in the radial direction and therefore we have solved the Schrodinger and Poisson equations self-consistently within the effective mass approximation for both conduction and valence band electrons. We predict that the tunneling current exhibits a pronounced dependence on the wire radius, particularly in the high-bias regime. (C) 2012 Elsevier Ltd. All rights reserved.
Keywords: A1 Journal article; Condensed Matter Theory (CMT)
Impact Factor: 1.58
Times cited: 2
DOI: 10.1016/j.sse.2012.09.004
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Jochems P (2013) Process intensification by immobilization of \beta-galactosidase on a mixed matrix membrance : galacto-oligosaccharides production as a case study. 199 p
Keywords: Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
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“High-resolution desktop microcomputed tomography for the evaluation of reducing treatments on historical glass suffering from manganese browning”. Nuyts G, Cagno S, Jaroszewicz J, Wouters H, De Vis K, Caen J, Janssens K page 201 (2013).
Abstract: Historical glass, especially non-durable mediaeval glass, can undergo corrosion. This sometimes results in the formation of dark-coloured manganese-rich inclusions or stains that reduce the transparency of the glass. A conservation treatment with reducing or chelating agents may be considered with the aim of improving the transparency. In this paper, high-resolution desktop microcomputed tomography (µCT) is used in combination with element-specific twodimensional imaging methods for in situ monitoring of manganese removal by hydroxylamine hydrochloride from an archaeological stained-glass sample suffering from manganese browning and from artificially corroded model glass samples. µCT also proved itself useful for the study of the (re-)penetration of manganese into the gel layer during artificial corrosion of a model glass.
Keywords: H2 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)
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“A biosensor fabricated by incorporation of a redox mediator into a carbon nanotube/nafion composite for tyrosinase immobilization : detection of matairesinol, an endocrine disruptor”. Rather JA, Pilehvar S, De Wael K, The analyst 238, 204 (2013). http://doi.org/10.1039/C2AN35959F
Abstract: An electrochemical matairesinol biosensor was fabricated by immobilizing tyrosinase on a poly(thionine)/nafion/multi-walled carbon nanotube composite film. A polymeric film of the redox dye thionine enables the stable immobilization of tyrosinase while acting as a mediator for the enzymatic process has been incorporated into the carbon nanotube/nafion composite film. The immobilization method is based on crosslinking of the tyrosinase layer with an electropolymerized film of poly(thionine). The good homogenization of the electron conductor CNTs in the integrated films provides the possibility of a three-dimensional electron conductive network. The biosensor was characterized by electrochemical impedance spectroscopy and electrochemical characterization. The composite electrode exhibits catalytic activity, high sensitivity, stability and is applicable over a wide range of concentrations from 180 nM to 4.33 μM with a detection limit (LOD) of 37 nM. The obtained results suggest that the developed sensor can be successfully used for the determination of phenolic endocrine disruptors over a concentration range covering their environmental levels.
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Impact Factor: 3.885
Times cited: 23
DOI: 10.1039/C2AN35959F
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“New insight into UO2F2 particulate structure by micro-Raman spectroscopy”. Stefaniak EA, Darchuk L, Sapundjiev D, Kips R, Aregbe Y, Van Grieken R, Journal of molecular structure 1040, 206 (2013). http://doi.org/10.1016/J.MOLSTRUC.2013.02.012
Abstract: Uranyl fluoride particles produced via hydrolysis of uranium hexafluoride have been deposited on different substrates: polished graphite disks, silver foil, stainless steel and gold-coated silicon wafer, and measured with micro-Raman spectroscopy (MRS). All three metallic substrates enhanced the Raman signal delivered by UO2F2 in comparison to graphite. The fundamental stretching of the UO band appeared at 867 cm−1 in case of the graphite substrate, while in case of the others it was shifted to lower frequencies (down to 839 cm−1). All applied metallic substrates showed the expected effect of Raman signal enhancement; however the gold layer appeared to be most effective. Application of new substrates provides more information on the molecular structure of uranyl fluoride precipitation, which is interesting for nuclear safeguards and nuclear environmental analysis.
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
DOI: 10.1016/J.MOLSTRUC.2013.02.012
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“Low-dimensional confining structures on the surface of helium films suspended on designed cavities”. Dantas DS, Chaves A, Farias GA, Ramos ACA, Peeters FM, Journal of low temperature physics 173, 207 (2013). http://doi.org/10.1007/s10909-013-0895-5
Abstract: We investigate the formation of quantum confined structures on the surface of a liquid helium film suspended on a nanostructured substrate. We show theoretically that, by nanostructuring the substrate, it is possible to change the geometry of the liquid helium surface, opening the possibility of designing and controlling the formation of valleys with different shapes. By applying an external electric field perpendicular to the substrate plane, surface electrons can be trapped into these valleys, as in a quantum dot. We investigate how the external parameters, such as the electric field strength and the height of the liquid helium bath, can be tuned to control the energy spectrum of the trapped surface electrons.
Keywords: A1 Journal article; Condensed Matter Theory (CMT)
Impact Factor: 1.3
Times cited: 1
DOI: 10.1007/s10909-013-0895-5
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“Mobile depth profiling and sub-surface imaging techniques for historical paintings : a review”. Alfeld M, Broekaert JAC, Spectrochimica acta: part B : atomic spectroscopy 88, 211 (2013). http://doi.org/10.1016/J.SAB.2013.07.009
Abstract: Hidden, sub-surface paint layers and features contain valuable information for the art-historical investigation of a painting's past and for its conservation for coming generations. The number of techniques available for the study of these features has been considerably extended in the last decades and established techniques have been refined. This review focuses on mobile non-destructive subsurface imaging and depth profiling techniques, which allow for the in-situ investigation of easel paintings, i.e. paintings on a portable support. Among the techniques discussed are: X-ray radiography and infrared reflectography, which are long established methods and are in use for several decades. Their capabilities of element/species specific imaging have been extended by the introduction of energy/wavelength resolved measurements. Scanning macro-X-ray fluorescence analysis made it for the first time possible to acquire elemental distribution images in-situ and optical coherence tomography allows for the non-destructive study the surface paint layers in virtual cross-sections. These techniques and their variants are presented next to other techniques, such as Terahertz imaging, Nuclear Magnetic Resonance depth profiling and established techniques for non destructive testing (thermography, ultrasonic imaging and laser based interference methods) applied in the conservation of historical paintings. Next to selected case studies the capabilities and limitations of the techniques are discussed. (C) 2013 Elsevier B.V. All rights reserved.
Keywords: A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
DOI: 10.1016/J.SAB.2013.07.009
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“Morphological characterization and distribution of autocatalytic-grown Ni4Ti3 precipitates in a Ni-Ti single crystal”. Cao S, Ke CB, Zhang XP, Schryvers D, Journal of alloys and compounds 577, 215 (2013). http://doi.org/10.1016/j.jallcom.2012.02.013
Abstract: The 3D size, morphology and distribution of autocatalytic-grown Ni4Ti3 precipitates in a Ni51Ti49 single crystal were characterized via a FIB/SEM Slice-and-View procedure and phase-field simulation. Important parameters on size and shape of the precipitates were measured. The pair distribution function and the minimum distance between two precipitates from different variants were calculated to describe the 3D distribution of the autocatalytic-grown Ni4Ti3 precipitates in single crystal Ni-Ti, with a comparison to the polycrystalline Ni50.8Ti49.2 alloy. Phase-field simulation was conducted to study the nucleation behavior of precipitates in the single crystal Ni-Ti. (C) 2012 Elsevier B.V. All rights reserved.
Keywords: A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT)
Impact Factor: 3.133
Times cited: 5
DOI: 10.1016/j.jallcom.2012.02.013
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“Surface photovoltage measurements : a quick assessment of the photocatalytic activity?”.Verbruggen SW, Dirckx JJJ, Martens JA, Lenaerts S, Catalysis today 209, 215 (2013). http://doi.org/10.1016/J.CATTOD.2012.11.010
Abstract: Surface photovoltage (SPV) measurements can contribute to a better understanding of electronic properties of photocatalysts under illumination. Direct linking of SPV data to the actual photocatalytic activity remains troublesome. This work aims to discuss SPV measurements from a photocatalytic point of view. By means of several application-based scenarios we illustrate that the trend between SPV and photocatalysis strongly depends on parameters such as the crystal structure, surface modifications, morphology and humidity. This makes the interpretation far from straightforward.
Keywords: A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Impact Factor: 4.636
Times cited: 8
DOI: 10.1016/J.CATTOD.2012.11.010
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“Towards CMOS-compatible single-walled carbon nanotube resonators”. Pathangi H, Cherman V, Khaled A, Sorée B, Groeseneken G, Witvrouw A, Microelectronic engineering 107, 219 (2013). http://doi.org/10.1016/j.mee.2012.06.007
Abstract: We report a totally CMOS-compatible fabrication technique to assemble horizontally suspended single-walled carbon nanotube (SWCNT) resonators. Individual SWCNTs are assembled in parallel at multiple sites by a technique called dielectrophoresis. The mechanical resonance frequencies of the suspended SWCNTs are in the range of 2035 MHz as determined from the piezoresistive response of the resonators during electrostatic actuation. The resistance of the suspended SWCNT either remains unchanged or increases or decreases significantly as a function of the actuation frequency. This can be explained by the effect the nanotube chirality has on the piezoresistive gauge factor.
Keywords: A1 Journal article; Engineering sciences. Technology; Condensed Matter Theory (CMT)
Impact Factor: 1.806
Times cited: 6
DOI: 10.1016/j.mee.2012.06.007
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“Novel coreshell magnetic nanoparticles for Taxol encapsulation in biodegradable and biocompatible block copolymers : preparation, characterization and release properties”. Filippousi M, Papadimitriou SA, Bikiaris DN, Pavlidou E, Angelakeris M, Zamboulis D, Tian H, Van Tendeloo G, International journal of pharmaceutics 448, 221 (2013). http://doi.org/10.1016/j.ijpharm.2013.03.025
Abstract: Theranostic polymeric nanocarriers loaded with anticancer drug Taxol and superparamagnetic iron oxide nanocrystals have been developed for possible magnetic resonance imaging (MRI) use and cancer therapy. Multifunctional nanocarriers with a coreshell structure have been prepared by coating superparamagnetic Fe3O4 nanoparticles with block copolymer of poly(ethylene glycol)-b-poly(propylene succinate) with variable molecular weights of the hydrophobic block poly(prolylene succinate). The multifunctional polymer nano-vehicles were prepared using a nanoprecipitation method. Scanning transmission electron microscopy revealed the encapsulation of magnetic nanoparticles inside the polymeric matrix. Energy dispersive X-ray spectroscopy and electron energy loss spectroscopy mapping allowed us to determine the presence of the different material ingredients in a quantitative way. The diameter of the nanoparticles is below 250 nm yielding satisfactory encapsulation efficiency. The nanoparticles exhibit a biphasic drug release pattern in vitro over 15 days depending on the molecular weight of the hydrophobic part of the polymer matrix. These new systems where anti-cancer therapeutics like Taxol and iron oxide nanoparticles (IOs) are co-encapsulated into new facile polymeric nanoparticles, could be addressed as potential multifunctional vehicles for simultaneous drug delivery and targeting imaging as well as real time monitoring of therapeutic effects.
Keywords: A1 Journal article; Pharmacology. Therapy; Electron microscopy for materials research (EMAT)
Impact Factor: 3.649
Times cited: 29
DOI: 10.1016/j.ijpharm.2013.03.025
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“Study of a TiO2 photocatalytic coating for use in plasma catalysis”. Van Wesenbeeck K, Hauchecorne B, Lenaerts S, Communications in agricultural and applied biological sciences 78, 227 (2013)
Keywords: A2 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
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“Structure and formation mechanism of rolled-in oxide areas on aluminum lithographic printing sheets”. Tzedaki G, M, Turner S, Godet S, De Graeve I, Kernig B, Hasenclever J, Terryn H, Scripta materialia 68, 233 (2013). http://doi.org/10.1016/j.scriptamat.2012.10.021
Abstract: The subsurface area introduced during rolling on the 1100 aluminum alloy series alters its surface properties, which makes it more susceptible to corrosion. A combination of different transmission electron microscopy techniques is employed to observe the orientation of small grain structures and the distribution elements in the subsurface layer. This approach provided valuable insight into the formation mechanism of the layer and the phenomena taking place during rolling.
Keywords: A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT)
Impact Factor: 3.747
Times cited: 6
DOI: 10.1016/j.scriptamat.2012.10.021
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“Electron-hole symmetry and solutions of Richardson pairing model”. Pogosov WV, Lin N, Misko VR, European physical journal : B : condensed matter and complex systems 86, 235 (2013). http://doi.org/10.1140/epjb/e2013-40234-9
Abstract: Richardson approach provides an exact solution of the pairing Hamiltonian. This Hamiltonian is characterized by the electron-hole pairing symmetry, which is however hidden in Richardson equations. By analyzing this symmetry and using an additional conjecture, fulfilled in solvable limits, we suggest a simple expression of the ground state energy for an equally-spaced energy-level model, which is applicable along the whole crossover from the superconducting state to the pairing fluctuation regime. Solving Richardson equations numerically, we demonstrate a good accuracy of our expression.
Keywords: A1 Journal article; Condensed Matter Theory (CMT)
Impact Factor: 1.461
Times cited: 6
DOI: 10.1140/epjb/e2013-40234-9
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“Study of the early stages of Mn intrusion in corroded glass by means of combined SR FTIR/\muXRF imaging and XANES spectroscopy”. Nuyts G, Cagno S, Hellemans K, Veronesi G, Cotte M, Janssens K, Procedia Chemistry
T2 –, Youth in Conservation of Cultural Heritage Conference (YOCOCU), June 18-20, 2012, University of Antwerp, Antwerp, Belgium , 239 (2013). http://doi.org/10.1016/J.PROCHE.2013.03.030
Abstract: Historical glass, especially medieval glass, can undergo weathering under the influence of time and environmental conditions. The aim of this investigation was to better understand the processes involved in this natural degradation process by studying artificially altered glass samples prepared for the use of evaluation of conservation methods. Non-durable glass sensors produced by the Fraunhofer Institute (type M1.0) were used as a starting material for artificial alteration. These were immersed in acidic (pH = 0, 2, 4) and neutral solutions (1 h – 8 h). In a second stage the glass samples were immersed in a 0.5 M MnCl2 solution (24 h, 48 h and 72 h), allowing intrusion of Mn from the solution into the gel layer. The samples were characterized at different stages with reflectance FTIR spectroscopy, mu XRF mapping and mu XANES. All measurements were carried out at ESRF, beamline ID21. Reflectance FTIR spectroscopy measurements were performed in the 800 4000 cm(-1) range. Cluster analysis of the resulting maps evidenced the rapid growth of the gel layer in strong acidic conditions. The average spectra for each cluster feature show for the original glass a strong Si-O- stretching band between 900 and 1000 cm(-1), whereas the gel layer could be identified by the increasing Si-O-Si bands around 1100 and 1250 cm(-1). mu XRF maps were recorded at different stages of the experiment at energies around the Mn-K edge (6.539 keV) and with a step size of 2 by 2 m. These confirm the leaching of K+ and Ca+2 from the glass and the intrusion of Mn from the solution. Mn was found throughout the entire gel layer, but with a concentration gradient peaking at the surface. XANES point measurements were recorded at various points where Mn was present. No spatial variation was found, but linear combination fitting of the spectra with various Mn reference compounds indicated that Mn2+Mn23+O4 is the main Mn compound in the gel layer, as was hypothesised by Watkinson et al. The standard corroded glass samples studied here can be used for the evaluation of conservation treatments in follow-up experiments. (C) 2013 The Authors. Published by Elsevier B.V. Selection and peer-review under responsibility of the IA-CS (Italian Association of Conservation Scientists) and University of Antwerp
Keywords: P1 Proceeding; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Times cited: 4
DOI: 10.1016/J.PROCHE.2013.03.030
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“The stained-glass panel depicting the anointing at Bethany : art historical research, technical analysis, and treatment”. Caen J, Cagno S, Janssens K page 247 (2013).
Abstract: In 2008, Museum M in Louvain (Flanders, Belgium) acquired a panel depicting The Anointing at Bethany that is believed once to have adorned the citys former Charterhouse. The panel required conservation treatment, which was preceded by a thorough art-historical and technical examination. It emerged that comparable panels are kept at the Metropolitan Museum of Art and the Riverside Church in New York. Chemical analyses show most of the glass in the panel to have a typical 16th century high-limelow-alkali composition. The conservation treatment was based on the evaluation of these findings and focused very strongly on enhancing the aesthetic balance for an improved reading of the panel.
Keywords: H2 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)
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“Fourier-Hankel solution of the Robin problem for the Helmholtz equation in supershaped annular domains”. Caratelli D, Gielis J, Tavkhelidze I, Ricci PE, Boundary value problems , 253 (2013). http://doi.org/10.1186/1687-2770-2013-253
Abstract: The Robin problem for the Helmholtz equation in normal-polar annuli is addressed by using a suitable Fourier-Hankel series technique. Attention is in particular focused on the wide class of domains whose boundaries are defined by the so-called superformula introduced by Gielis. A dedicated numerical procedure based on the computer algebra system Mathematica© is developed in order to validate the proposed methodology. In this way, highly accurate approximations of the solution, featuring properties similar to the classical ones, are obtained.
Keywords: A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
DOI: 10.1186/1687-2770-2013-253
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