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Records |
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Author |
Ozen, S.A.; Ozkalayci, F.; Cevik, U.; Van Grieken, R. |
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Title |
Investigation of heavy metal distributions along 15m soil profiles using EDXRF, XRD, SEM-EDX, and ICP-MS techniques |
Type |
A1 Journal article |
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Year |
2018 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
47 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
231-241 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The research of soil contamination by heavy metal is an important field due to its environmental and health implications. The goal was to study the elemental mobility as a function of depth. For this reason, the distribution of heavy metals (V, Cr, Co, Ni, Cu, Zn, As, Sn, and Pb) was investigated along soil profiles up to a depth of 15m at 9 sampling sites in the Nilufer industrial district (Bursa, Turkey). Elemental analyses were done with the Epsilon 5 energy dispersive X-ray fluorescence and inductively coupled plasma mass spectrometry equipment. Particle analysis was performed with a JEOL scanning electron microscope equipped with a Si(Li) X-ray detector. The crystallographic compositions of oxide compounds in soil samples were identified by a Rigaku X-ray diffraction instrument. Different parameters such as the soil's chemical (mineralogical structure, pH, and electrical conductivity) and physical properties (the number of blows, the stiffness index, the liquidity index, the plasticity index, and the water content) were analyzed. To assess the mobility of the heavy metals, diffusion (D) and convection coefficients (?) were calculated with the finite difference method. Convection was determined to dominate the studied region. In addition, the mobility coefficient was determined for each metal. High mobilities were determined for Zn and V, moderate mobilities for Cr, Ni, Cu, and As, and low mobilities were determined for Co and Pb. The results revealed that elements had reached depths of up to 15m, causing irreversible soil contamination that may lead to environmental health issues. |
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Wos |
000430188700005 |
Publication Date |
2018-03-09 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:150722 |
Serial |
8123 |
Permanent link to this record |
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Author |
Van Dyck, P.; Török, S.; Van Grieken, R. |
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Title |
Monte Carlo simulation of backscattered peaks in secondary target energy-dispersive X-ray spectra |
Type |
A1 Journal article |
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Year |
1986 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
15 |
Issue |
4 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
231-238 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
A Monte Carlo simulation has been developed to describe the incoherent and coherent scatter processes for the complex geometry of a secondary target energy-dispersive x-ray fluorescence system. Photons are followed from the x-ray tube anode until the detection of scattered secondary target photons in the active Si layer of the detector. The program quantitatively shows the broadening of the incoherent scatter peak with increasing atomic number, and it models the incoherent peak shape adequately. The incoherent-to-coherent scatter intensity ratios obtained differ by 1030% from the theoretical values, while their dependence on the sample atomic number corresponds to that expected from theory. |
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Wos |
A1986E535600001 |
Publication Date |
2005-05-28 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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no |
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Call Number |
UA @ admin @ c:irua:113612 |
Serial |
8280 |
Permanent link to this record |
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Author |
Deutsch, F.; Vankerkom, J.; Janssen, L.; Janssen, S.; Bencs, L.; Van Grieken, R.; Fierens, F.; Dumont, G.; Mensink, C. |
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Title |
Modelling concentrations of airborne primary and secondary PM10 and PM2.5 with the BelEUROS-model in Belgium |
Type |
A1 Journal article |
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Year |
2008 |
Publication |
Ecological modelling |
Abbreviated Journal |
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Volume |
217 |
Issue |
3/4 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
230-239 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The Eulerian Chemistry-Transport Model BelEUROS was used to calculate the concentrations of airborne PM10 and PM2.5 over Europe. Both primary as well as secondary particulate matter in the respirable size-range was taken into account. Especially PM2.5 aerosols are often formed in the atmosphere from gaseous precursor compounds. Comprehensive computer codes for the calculation of gas phase chemical reactions and thermodynamic equilibria between compounds in the gas-phase and the particulate phase had been implemented into the BelEUROS-model. Calculated concentrations of PM10 and PM2.5 are compared to observations, including both the spatial and daily, temporal distribution of particulate matter in Belgium for certain monitoring locations and periods. The concentrations of the secondary compounds ammonium, nitrate and sulfate have also been compared to observed values. BeIEUROS was found to reproduce the observed concentrations rather well. The model was applied to assess the contribution of emissions derived from the sector agriculture in Flanders, the northern part of Belgium, to PM10- and PM2.5-concentrations. The results demonstrate the importance of ammonia emissions in the formation of secondary particulate matter. Hence, future European emission abatement policy should consider more the role of ammonia in the formation of secondary particles |
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Wos |
000259842900004 |
Publication Date |
2008-07-18 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0304-3800 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:70073 |
Serial |
8268 |
Permanent link to this record |
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Author |
Robberecht, H.; Deelstra, H.; vanden Berghe, D.; Van Grieken, R. |
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Title |
Metal pollution and selenium distributions in soils and grass near a non-ferrous plant |
Type |
A1 Journal article |
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Year |
1983 |
Publication |
The science of the total environment |
Abbreviated Journal |
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Volume |
29 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
229-241 |
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Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Multi-element analysis results of direct energy-dispersive X-ray fluorescence of soil samples taken in the vicinity of a non-ferrous plant in Antwerp are reported. High concentrations of Pb, Cu, Zn, As and Se are found in nearby residential areas, especially in top-soil layers. Selenium pollution appears not to be leached significantly to lower soil horizons, but it is available for uptake by rye-grass, in which toxic levels are found. Results are compared to literature data. Hydride generation atomic absorption spectrometry proved to be unsuitable for direct analysis of the heavily contaminated soils. |
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Wos |
A1983RE16300003 |
Publication Date |
2003-09-12 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0048-9697; 1879-1026 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116648 |
Serial |
8218 |
Permanent link to this record |
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Author |
Arana, A.; Loureiro, A.L.; Barbosa, H.M.J.; Van Grieken, R.; Artaxo, P. |
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Title |
Optimized energy dispersive X-ray fluorescence analysis of atmospheric aerosols collected at pristine and perturbed Amazon Basin sites |
Type |
A1 Journal article |
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Year |
2014 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
43 |
Issue |
4 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
228-237 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Elemental composition of aerosols is important to source apportionment studies and to understand atmospheric processes that influence aerosol composition. Energy dispersive X-ray fluorescence spectroscopy was applied for measuring the elemental composition of Amazonian atmospheric aerosols. The instrument used was a spectrometer Epsilon 5, PANalytical B. V., with tridimensional geometry that reduces the background signal with a polarized X-ray detection. The measurement conditions were optimized for low-Z elements, e. g. Mg, Al, Si, that are present at very low concentrations in the Amazon. From Na to K, our detection limits are about 50% to 75% lower than previously published results for similar instrument. Calibration was performed using Micromatter standards, except for P whose standard was produced by nebulization of an aqueous solution of KH2PO4 at our laboratory. The multi-element reference material National Institute of Standards and Technology-2783 (air particulate filter) was used for evaluating the accuracy of the calibration procedure of the 22 elements in our standard analysis routine, and the uncertainty associated with calibration procedures was evaluated. The overall performance of the instrument and validation of our measurements were assessed by comparison with results obtained from parallel analysis using particle-induced X-ray emission and another Epsilon 5 spectrometer. The elemental composition in 660 samples collected at a pristine site in the Amazon Basin and of 1416 samples collected at a site perturbed by land use change was determined. Our measurements show trace elements associated with biogenic aerosols, soil dust, biomass burning, and sea-salt, even for the very low concentrations as observed in Amazonia. Copyright (C) 2014 John Wiley & Sons, Ltd. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000337724600006 |
Publication Date |
2014-06-09 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:118419 |
Serial |
8342 |
Permanent link to this record |
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Author |
Rojas, C.M.; Artaxo, P.; Van Grieken, R. |
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Title |
Aerosols in Santiago de Chile : a study using receptor modeling with X-ray fluorescence and single particle analysis |
Type |
A1 Journal article |
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Year |
1990 |
Publication |
Atmospheric environment: part B : urban atmosphere |
Abbreviated Journal |
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Volume |
24 |
Issue |
2 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
227-241 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
Between 15 January and 26 February 1987, 51 fine and coarse mode aerosol samples were collected at the Universidad de Santiago de Chile Planetarium using a dichotomous sampler. The samples were analyzed by X-ray fluorescence for up to 17 elements (Mg, Al, Si, P, S, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br and Pb). Aerosol particles were individually studied by Electron Probe Microanalysis (EPMA) and Laser Microprobe Mass Analysis (LAMMA). The data set consisting of aerosol elemental concentrations and meteorological variables was subjected to Principal Factor Analysis (PFA), allowing the identification of six fine mode particle source classes (soil, industrial, sulfate particles, traffic, residual oil, wood-burnings), and five coarse mode particle source classes (soil, industrial, traffic, residual oil, sulfate particles). Both PFA solutions explained about 81 and 90% of the total variance in the data set, respectively. The regression of elemental mass concentrations on the Absolute Principal Factor Scores allowed the estimation of the contribution of the different source classes to the Santiago aerosol. Within the fine fraction, secondary SO42− particles were responsible for about 49% of the fine mode aerosol mass concentration, while 26, 13, 6.4 and 5.6% were attributed to wood-burning/car exhausts, residual oil combustion, soil dust/metallurgical, and soil dust/wood-burning releases, respectively. The coarse fraction source apportionment was mainly dominated by soil dust, accounting for 74% of the coarse mode aerosol mass concentration. A composite of soil dust and industrial release accounted for 13%; a composite of secondary sulfates contributed with 9%; a composite of soil dust and automotive emissions, and secondary sulfates were responsible for 4 and 0.03% of the coarse aerosol mass concentration, respectively. EPMA results are in satisfactory agreement with those from the bulk analysis and allowed the identification of eight particle types in both fine and coarse mode aerosols, pertaining to different source classes, namely soil, seaspray, secondary SO42−, metallurgical emissions and biomass burning release. EPMA also evidenced that one of the most abundant particle types corresponded to marine aerosol, having an average diameter of 0.7 μm for the fine mode and 2.2 μm for the coarse mode aerosol. LAMMA results indicate that, in fact, seaspray has been transported into the city of Santiago de Chile airshed, suffering several transformations and a sulfur enrichment. This analytical technique also provided evidence of the abundance of carbon-rich particles, which were not detected by either the bulk X-ray analysis or EPMA; they are probably due to fossil-fuel combustion releases. |
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Corporate Author |
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Thesis |
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Place of Publication |
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Editor |
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Wos |
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Publication Date |
2003-08-06 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0957-1272; 1878-2132 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116456 |
Serial |
7427 |
Permanent link to this record |
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Author |
Eyckmans, K.; Zhang, J.; de Hoog, J.; Joos, P.; Van Grieken, R. |
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Title |
Leaching of nutrients and trace metals from aerosol samples: a comparison between a re-circulation and an ultrasound system |
Type |
A1 Journal article |
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Year |
2001 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
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Volume |
80 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
227-243 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000172385700006 |
Publication Date |
2007-07-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0306-7319 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:36087 |
Serial |
8167 |
Permanent link to this record |
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Author |
Goossenaerts, C.; Van Grieken, R.; Jacob, W.; Witters, H.; Vanderborght, O. |
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Title |
A microanalytical study of the gills of aluminium-exposed rainbow trout (Salmo gairdneri) |
Type |
A1 Journal article |
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Year |
1988 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
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Volume |
34 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
227-237 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Corporate Author |
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Place of Publication |
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Wos |
A1988T017900005 |
Publication Date |
2007-07-07 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0306-7319 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116579 |
Serial |
8240 |
Permanent link to this record |
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Author |
Samek, L.; Ostachowicz, B.; Worobiec, A.; Spolnik, Z.; Van Grieken, R. |
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Title |
Speciation of selected metals in aerosol samples by TXRF after sequential leaching |
Type |
A1 Journal article |
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Year |
2006 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
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Volume |
35 |
Issue |
4 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
226-231 |
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Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000239321500004 |
Publication Date |
2006-06-29 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0049-8246 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:58901 |
Serial |
8572 |
Permanent link to this record |
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Author |
Bencs, L.; Horemans, B.; Buczyńska, A.J.; Van Grieken, R. |
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Title |
Uneven distribution of inorganic pollutants in marine air originating from ocean-going ships |
Type |
A1 Journal article |
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Year |
2017 |
Publication |
Environmental pollution |
Abbreviated Journal |
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Volume |
222 |
Issue |
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Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
226-233 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The distribution of mass, water-soluble inorganic salts and mineral elements of size-segregated aerosols (PM1, PM2.5-1 and PM10-2.5), precursor gaseous pollutants, black carbon, and nanoparticles (10-300 nm size range) at the Southern Bight of the North Sea has been studied. The concentrations of air pollutants peaked over shipping lanes, open-water anchorage areas and frequently navigated waters, due to the presence of mobile emission sources. A considerable decrease in air pollutant levels was seen when diverting from these marine areas towards remote or coastal banks. These findings showed the rapid dispersion of pollutants in the marine air. The nano-aerosol count, originating from ocean-going ships, peaked at lower average aerodynamic diameters (e.g., approximate to 28 nm) than those, observed from low displacement vessels (45-50 nm, e.g., for fishing boats). The average diameter of nano-PM depended also on weather conditions, e.g., it was higher (approximate to 50 nm) in air of higher humidity. (C) 2016 Elsevier Ltd. All rights reserved. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Wos |
000395360900028 |
Publication Date |
2017-01-06 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0269-7491; 1873-6424 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:142516 |
Serial |
8710 |
Permanent link to this record |
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Author |
Van Grieken, R.; Speecke, A.; Hoste, J. |
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Title |
Geometry errors in 14 MeV neutron activation analysis |
Type |
A3 Journal article |
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Year |
1973 |
Publication |
Journal of radioanalytical chemistry |
Abbreviated Journal |
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Volume |
13 |
Issue |
1 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
225-233 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The effects of inaccurate sample sizes and sample positioning on 14 MeV neutron activation analysis results are estimated for 30, 20 and 10 mm diameter targets. It appears that axial positioning is the most critical parameter and that using a larger tritium target will yield an overall improvement of the reproducibility. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
2006-10-11 |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0134-0719; 2064-2857 |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116453 |
Serial |
7999 |
Permanent link to this record |
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Author |
Ameloot, P.C.; Vandeputte, D.F.; Van Grieken, R.E.; Coomans, D. |
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Title |
Localization of lead in cultured tooth germs by laser microprobe micro-analysis |
Type |
A3 Journal article |
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Year |
1987 |
Publication |
Proceedings of the Finnish Dental Society |
Abbreviated Journal |
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Volume |
83 |
Issue |
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Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
225-236 |
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Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0039-551x |
ISBN |
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Additional Links |
UA library record |
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Impact Factor |
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Times cited |
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Open Access |
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Notes |
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Approved |
no |
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Call Number |
UA @ admin @ c:irua:116799 |
Serial |
8183 |
Permanent link to this record |
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Author |
Evangelista, H.; Maldonado, J.; Godoi, R.H.M.; Pereira, E.B.; Koch, D.; Tanizaki-Fonseca, K.; Van Grieken, R.; Sampaio, M.; Setzer, A.; Alencar, A.; Gonçalves, S.C. |
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Title |
Sources and transport of urban and biomass burning aerosol black carbon at the South-West Atlantic coast |
Type |
A1 Journal article |
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Year |
2007 |
Publication |
Journal of atmospheric chemistry |
Abbreviated Journal |
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Volume |
56 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
225-238 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000245105900002 |
Publication Date |
2007-01-02 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0167-7764 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:63841 |
Serial |
8561 |
Permanent link to this record |
|
|
|
|
Author |
Goossenaerts, C.H.; Verbueken, A.H.; Jacob, W.A.; Van Praag, H.J.; Van Grieken, R.E. |
|
Title |
A microanalytical study of green and necrotic needle tissue |
Type |
H3 Book chapter |
|
Year |
1987 |
Publication |
|
Abbreviated Journal |
|
|
Volume |
|
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
224-234
T2 - Direct effects of dry and wet deposit |
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Keywords |
H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:117533 |
Serial |
8237 |
Permanent link to this record |
|
|
|
|
Author |
Claes, M.; de Bokx, P.; Van Grieken, R. |
|
Title |
Progress in laboratory grazing emission X-ray fluorescence spectrometry |
Type |
A1 Journal article |
|
Year |
1999 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume |
28 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
224-229 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
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Corporate Author |
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Thesis |
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|
Publisher |
|
Place of Publication |
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Editor |
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|
Language |
|
Wos |
000081693400004 |
Publication Date |
2005-12-05 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:24715 |
Serial |
8423 |
Permanent link to this record |
|
|
|
|
Author |
Vanderborght, B.; Van Grieken, R. |
|
Title |
Automated evaluation of photographically recorded spark-source mass spectra |
Type |
A1 Journal article |
|
Year |
1978 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
|
Volume |
103 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
223-235 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
A computer routine was developed for qualitative and quantitative analysis of photographically recorded spark-source mass spectra. Particular attention is given to the case of a graphite matrix. The program starts from the line intensities (expressed as Seidel values) and isotope masses calculated from the densitometer readings by a commercially available routine. From the intensities in the different exposures (typically 15 stages), it computes the parameters for the linear parts of the density curves for each ion. Taking into account mutual interferences of multivalent ions, isotope or C-clusters, oxide, carbide and dicarbide ions, the program automatically identifies and then quantifies the elements present. The precision of the results is around 5%. Reading and complete processing of one photoplate is achieved within 23 h. |
|
Address |
|
|
Corporate Author |
|
Thesis |
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
A1978GD90900003 |
Publication Date |
2002-07-25 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:113631 |
Serial |
7538 |
Permanent link to this record |
|
|
|
|
Author |
Spolnik, Z.; Worobiec, A.; Injuk, J.; Neilen, D.; Schellen, H.; Van Grieken, R. |
|
Title |
Chemical characterization of airborne particles in St. Martinus Cathedral in Weert, The Netherlands |
Type |
A1 Journal article |
|
Year |
2004 |
Publication |
Microchimica acta |
Abbreviated Journal |
|
|
Volume |
145 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
223-227 |
|
Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
|
Thesis |
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
000221453500037 |
Publication Date |
2004-04-21 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:44334 |
Serial |
7645 |
Permanent link to this record |
|
|
|
|
Author |
Belmans, F.; Van Grieken, R.; Brügmann, L. |
|
Title |
Geochemical characterization of recent sediments in the Baltic Sea by bulk and electron microprobe analysis |
Type |
A1 Journal article |
|
Year |
1993 |
Publication |
Marine chemistry |
Abbreviated Journal |
|
|
Volume |
42 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
223-236 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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|
Language |
|
Wos |
A1993LK11300006 |
Publication Date |
2003-08-08 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0304-4203; 1872-7581 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:6255 |
Serial |
7994 |
Permanent link to this record |
|
|
|
|
Author |
Török, S.; Sandor, S.; Xhoffer, C.; Van Grieken, R.; Meszaros, E.; Molnar, A. |
|
Title |
Single particle analysis of Hungarian background aerosol |
Type |
A3 Journal article |
|
Year |
1992 |
Publication |
Idojaras: quarterly journal of the Hungarian Meteorological Service |
Abbreviated Journal |
|
|
Volume |
96 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
223-233 |
|
Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
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|
Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
|
Wos |
|
Publication Date |
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|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:2847 |
Serial |
8532 |
Permanent link to this record |
|
|
|
|
Author |
Gysels, K.; Delalieux, F.; Deutsch, F.; Van Grieken, R.; Camuffo, D.; Bernardi, A.; Sturaro, G.; Busse, H.-J.; Wieser, M. |
|
Title |
Indoor environment and conservation in the Royal Museum of Fine Arts, Antwerp, Belgium |
Type |
A1 Journal article |
|
Year |
2004 |
Publication |
Journal of cultural heritage |
Abbreviated Journal |
|
|
Volume |
5 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
221-230 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
|
Thesis |
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|
Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
000222196400010 |
Publication Date |
2004-05-29 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
1296-2074 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:44970 |
Serial |
8084 |
Permanent link to this record |
|
|
|
|
Author |
Vos, L.; Van Grieken, R. |
|
Title |
Influence of ion-source geometry in spark source-mass spectrometric analysis |
Type |
A1 Journal article |
|
Year |
1984 |
Publication |
International journal of mass spectrometry and ion processes |
Abbreviated Journal |
|
|
Volume |
59 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
221-229 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
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Thesis |
|
|
Publisher |
|
Place of Publication |
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Editor |
|
|
Language |
|
Wos |
A1984TK37900001 |
Publication Date |
2002-07-25 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0168-1176; 1873-2801 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:113618 |
Serial |
8094 |
Permanent link to this record |
|
|
|
|
Author |
Vanderborght, B.M.; Van Grieken, R.E. |
|
Title |
Trace metal analysis of water containing humic substances by X-ray fluorescence |
Type |
A1 Journal article |
|
Year |
1978 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
|
Volume |
5 |
Issue |
3 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
221-237 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
Chelation by oxine followed by adsorption on activated carbon results in the efficient collection of many trace metal ions, independent of the trace metal concentration and of high alkali and alkaline earth ion abundances. Preconcentration factors around 10000 are often achieved. When this preconcentration procedure is combined with energy-dispersive X-ray fluorescence, accurate and precise analysis can be carried out, as was proven in several experiments. The technique can also be applied for the determination of divalent ions in natural waters containing up to 10 ppm of humic substances. Trivalent ions can quantitatively be collected from natural water provided suKicient activated carbon is added. Omitting the oxine chelation prior to the activated carbon adsorption step still results in collection of a sometimes important fraction of the trace metal ions from natural waters. This is related to organically bound or colloidal forms of the trace metals. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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|
Language |
|
Wos |
A1978FR88000005 |
Publication Date |
2007-07-07 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:116570 |
Serial |
8692 |
Permanent link to this record |
|
|
|
|
Author |
Injuk, J.; van Malderen, H.; Van Grieken, R.; Swietlicki, E.; Knox, J.M.; Schofield, R. |
|
Title |
EDXRS study of aerosol composition variations in air masses crossing the North Sea |
Type |
A1 Journal article |
|
Year |
1993 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
|
Volume |
22 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
220-228 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
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Thesis |
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|
Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
A1993LQ04200009 |
Publication Date |
2005-05-28 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:6258 |
Serial |
7836 |
Permanent link to this record |
|
|
|
|
Author |
Vincze, L.; Vekemans, B.; Szaloki, I.; Brenker, F.E.; Falkenberg, G.; Rickers, K.; Aerts, K.; Van Grieken, R.; Adams, F. |
|
Title |
X-ray fluorescence microtomography and polycapillary based confocal imaging using synchrotron radiation |
Type |
P1 Proceeding |
|
Year |
2004 |
Publication |
|
Abbreviated Journal |
|
|
Volume |
|
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
220-231
T2 - 4th Conference on Developments in X-R |
|
Keywords |
P1 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
Ibis work illustrates the development of X-ray fluorescence tomography and polycapillary based confocal imaging towards a three-dimensional (313), quantitative analytical method with lateral resolution levels down to the 2-20 mum scale. Detailed analytical characterization is given for polycapillary based confocal XRF imaging, which is a new variant of the 3D micro-XRF technique. Applications for 2D/3D micro-XR-F are illustrated for the analysis of biological (zooplankton) and geological samples (microscopic inclusions in natural diamonds and fluid inclusions in quartz). Based on confocal imaging, fully three-dimensional distributions of trace elements could be obtained, representing a significant generalization of the regular 2D scanning technique for micro-XRF spectroscopy. The experimental work described in this paper has been carried out at the ESRF ID18F microfluorescence end-station and at HASYLAB Beam Line L. |
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Address |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
000225665000023 |
Publication Date |
2004-11-02 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0-8194-5473-7 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:94812 |
Serial |
8767 |
Permanent link to this record |
|
|
|
|
Author |
Subramanian, V.; Van Grieken, R.; Van 't dack, L. |
|
Title |
Transport and fractionation of Pb in river sediments from the Indian sub-continent |
Type |
A1 Journal article |
|
Year |
1987 |
Publication |
Journal of the Geological Society of India |
Abbreviated Journal |
|
|
Volume |
30 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
217-226 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
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Thesis |
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|
Publisher |
|
Place of Publication |
|
Editor |
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|
Language |
|
Wos |
|
Publication Date |
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0016-7622 |
ISBN |
|
Additional Links |
UA library record |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:111506 |
Serial |
8699 |
Permanent link to this record |
|
|
|
|
Author |
Van Grieken, R.; Gysels, K.; Hoornaert, S.; Joos, P.; Osán, J.; Szalóki, I.; Worobiec, A. |
|
Title |
Characterisation of individual aerosol particles for atmospheric and cultural heritage studies |
Type |
A1 Journal article |
|
Year |
2000 |
Publication |
Water, air and soil pollution |
Abbreviated Journal |
|
|
Volume |
123 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
215-228 |
|
Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
|
Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
|
Editor |
|
|
Language |
|
Wos |
000089881000020 |
Publication Date |
2002-12-21 |
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
0049-6979; 1573-2932 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:31675 |
Serial |
7596 |
Permanent link to this record |
|
|
|
|
Author |
Van Grieken, R.; Gysels, K.; Hoornaert, S.; Joos, P.; Osán, J.; Szalóki, I.; Worobiec, A. |
|
Title |
Characterisation of individual aerosol particles for atmospheric and cultural heritage studies |
Type |
H3 Book chapter |
|
Year |
2000 |
Publication |
|
Abbreviated Journal |
|
|
Volume |
|
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
215-228
T2 - Environmental challenges / Belkin, Sh |
|
Keywords |
H3 Book chapter; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
|
Abstract |
|
|
Address |
|
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Corporate Author |
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Thesis |
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Publisher |
|
Place of Publication |
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Editor |
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Language |
|
Wos |
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Publication Date |
|
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Series Editor |
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Series Title |
|
Abbreviated Series Title |
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|
Series Volume |
|
Series Issue |
|
Edition |
|
|
ISSN |
|
ISBN |
|
Additional Links |
UA library record |
|
Impact Factor |
|
Times cited |
|
Open Access |
|
|
Notes |
|
Approved |
no |
|
Call Number |
UA @ admin @ c:irua:31694 |
Serial |
7597 |
Permanent link to this record |
|
|
|
|
Author |
Smits, J.; Nelissen, J.; Van Grieken, R. |
|
Title |
Comparison of preconcentration procedures for trace metals in natural waters |
Type |
A1 Journal article |
|
Year |
1979 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
|
Volume |
111 |
Issue |
|
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
215-226 |
|
Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Abstract |
The relative merits of eight procedures for preconcentrations of trace metal ions from natural water samples and synthetic solutions are evaluated. Spikes (100 μg l−1 ) of Mn, Co, Zn, Eu, Cs and Ba and the corresponding radioactive tracers were added to batches of drinking water, estuarine water, sea water, ground water, twice-distilled water and ahumic material solution. After equilibration for 25 months, the following techniques were applied: passage through columns of Dowex Al chelating resin and ofsilylated silica gel, filtration through laminate membrane filters and chelating diethylenetriamine cellulose filters, precipitation with sodium diethyldithiocarbamate and l-(2-pyridylazo)-2-naphthol, extraction with ammonium pyrrolidinedithiocarbamate, and chelation by 8-quinolinol (oxine) followed by adsorption on activated carbon. The quantitative characteristics of these techniques and the influence of the water matrix effects are discussed, as well as the applicability for x-ray fluorescence analysis. |
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Wos |
A1979HX09300018 |
Publication Date |
2002-07-25 |
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ISSN |
0003-2670; 1873-4324 |
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UA library record; WoS full record; WoS citing articles |
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Call Number |
UA @ admin @ c:irua:116369 |
Serial |
7695 |
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Author |
Sillanpää, M.; Hillamo, R.; Saarikoski, S.; Frey, A.; Pennanen, A.; Makkonen, U.; Spolnik, Z.; Van Grieken, R.; Braniš, M.; Brunekreef, B.; Chalbot, M.-C.; Kuhlbusch, T.; Sunyer, J.; Kerminen, V.-M.; Kulmala, M.; Salonen, R.O. |
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Title |
Chemical composition and mass closure of particulate matter at six urban sites in Europe |
Type |
A1 Journal article |
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Year |
2006 |
Publication |
Atmospheric environment : an international journal |
Abbreviated Journal |
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Volume |
40 |
Issue |
suppl.2 |
Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
S212-S223 |
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Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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000242023200005 |
Publication Date |
2006-08-29 |
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Edition |
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ISSN |
1352-2310 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Approved |
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Call Number |
UA @ admin @ c:irua:61917 |
Serial |
7650 |
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Author |
Osán, J.; de Hoog, J.; Worobiec, A.; Ro, C.-U.; Oh, K.-Y.; Szalóki, I.; Van Grieken, R. |
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Title |
Application of chemometric methods for classification of atmospheric particles based on thin-window electron probe microanalysis data |
Type |
A1 Journal article |
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Year |
2001 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
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Volume |
446 |
Issue |
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Pages ![sorted by First Page field, descending order (down)](img/sort_desc.gif) |
211-222 |
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Keywords |
A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Wos |
000172309400020 |
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ISSN |
0003-2670; 1873-4324 |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Times cited |
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no |
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Call Number |
UA @ admin @ c:irua:36385 |
Serial |
7468 |
Permanent link to this record |