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Author Van Grieken, R.; de Bruin, M.
Title Nomenclature for radioanalytical chemistry (IUPAC Recommendations 1994) Type A1 Journal article
Year 1994 Publication Pure and applied chemistry Abbreviated Journal
Volume 66 Issue 12 Pages (up) 2513-2526
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Nearly 200 terms commonly used in radioanalytical chemistry are unambiguously defined. The list is partially based on an earlier IUPAC-glossary (Pure Appl. Chem. 54 (1982) 1533-1554), but some modifications have been made, terms related to nuclear physics and technology have not been reconsidered and numerous new entries from the realm of radiometric analysis, radioimmunoassay and related techniques have been included.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1994PZ23000010 Publication Date 2007-10-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0033-4545 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:9506 Serial 8312
Permanent link to this record
 
 
Author Rouchon, V.; Duranton, M.; Burgaud, C.; Pellizzi, E.; Lavédrine, B.; Janssens, K.; de Nolf, W.; Nuyts, G.; Vanmeert, F.; Hellemans, K.
Title Room-temperature study of iron gall ink impregnated paper degradation under various oxygen and humidity conditions : time-dependent monitoring by viscosity and X-ray absorption near-edge spectrometry measurements Type A1 Journal article
Year 2011 Publication Analytical chemistry Abbreviated Journal Anal Chem
Volume 83 Issue 7 Pages (up) 2589-2597
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Many western manuscripts were written using iron gall inks. These inks can damage the paper via two major mechanisms: (a) acid hydrolysis, enhanced by humidity, and (b) oxidative depolymerization provoked by the presence of oxygen and free iron(II) ions. The degradation of unsized Whatman paper impregnated with different combinations of iron sulfate, gallic acid, and gum arabic was studied at room temperature in order to assess the relative importance of each mechanism. The samples were stored in various environments including a dry and/or an oxygen-free atmosphere. The cellulose depolymerization was monitored by viscometry and related to changes in the oxidation state of iron, determined by X-ray absorption near-edge spectrometry. The results indicate that residual amounts of oxygen (less than 0.1%) promote cellulose depolymerization, whereas the level of relative humidity has no impact. The cellulose depolymerization also appears closely correlated to oxidative mechanisms. Regarding the oxidation of iron, it only occurs in the simultaneous presence of oxygen and moisture, suggesting the occurrence of rustlike oxidative mechanisms. Finally, the presence of gallic acid has a strong influence, which is only partially explained by its capacity to reduce iron(III) to iron(II).
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000288887700028 Publication Date 2011-03-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.32 Times cited 28 Open Access
Notes ; This research was supported by the French Ministry of Culture within the National Program of Research (“La conservation des manuscrits: etude du vieillissement naturel de papiers impregnes d'encres ferrogalliques”). It was funded by grants from HASYLAB (experiments I-20090280 EC and II-20060245 EC) and SOLEIL (proposals 20060396 and 20080761) and was supported by the Interuniversity Attraction Poles Programme Belgian Science Policy (1UAP V1/16). The text also presents results of GOA “XANES meets ELNES” (Research Fund University of Antwerp, Belgium) and from FWO (Brussels, Belgium) projects nos. G.0689.06, G.0704.08 and G017909N. We are thankful to Dr. Dominique Thaudiere, Dr. Solenn Reguer, Dr. Andrea Somogyi, Dr. Karen Appel, Dr. Manuela Borchert, and Dr. Gerald Falkenberg for their assistance and help during the experiments performed at SOLEIL beamline “DIFFABS” and at HASYLAB Beam line “L” respectively. ; Approved Most recent IF: 6.32; 2011 IF: 5.856
Call Number UA @ admin @ c:irua:89593 Serial 5822
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Author Bruynseels, F.; Storms, H.; Van Grieken, R.; Van der Auwera, L.
Title Characterization of North-Sea aerosols by individual particle analyses Type A1 Journal article
Year 1988 Publication Atmospheric environment : an international journal Abbreviated Journal
Volume 22 Issue 11 Pages (up) 2593-2602
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract On aerosol and rain water samples, collected in the Southern Bight of the North Sea, single particle analyses were performed using both laser microprobe mass analysis and electron-probe X-ray microanalysis in combination with an automated image analysis system. In the aerosols collected from an air mass that had travelled from the Atlantic Ocean along the coast of North France, pure seasalt constituted the most abundant particle type, while aluminosilicates (mostly spherical fly-ash particles) amounted to about 20% and mixed seasalt/aluminosilicate, carbonaceous particles, CaSO4 and spherical iron oxides contributed each 510 %. In air masses that had a longer residence time over the continent, spherical iron oxides, carbonaceous particles and ammonium sulfates together made up 70 % of the total particle load. Seasalt particles were nearly all enriched in sulfate or nitrate, but they were seen to be washed out efficiently after a rain shower. In rain water, some 40 % of the particles appeared to be spherical or irregularly shaped aluminosilicates, from fly-ash and dust dispersal, but more than 50 % consisted of SiO2. The high relative abundance of these particles in rain water may be the result of Al leaching from fly-ash, or of more efficient scavenging by rain droplets.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1988R523900028 Publication Date 2003-08-06
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1352-2310 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:113610 Serial 7632
Permanent link to this record
 
 
Author van der Snickt, G.; Dik, J.; Cotte, M.; Janssens, K.; Jaroszewicz, J.; de Nolf, W.; Groenewegen, J.; van der Loeff, L.
Title Characterization of a degraded cadmium yellow (CdS) pigment in an oil painting by means of synchrotron radiation based X-ray techniques Type A1 Journal article
Year 2009 Publication Analytical chemistry Abbreviated Journal Anal Chem
Volume 81 Issue 7 Pages (up) 2600-2610
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract On several paintings of James Ensor (1860−1949), a gradual fading of originally bright yellow areas, painted with the pigment cadmium yellow (CdS), is observed. Additionally, in some areas exposed to light, the formation of small white-colored globules on top of the original paint surface is observed. In this paper the chemical transformation leading to the color change and to the formation of the globules is elucidated. Microscopic X-ray absorption near-edge spectroscopy (ì-XANES) experiments show that sulfur, originally present in sulfidic form (S2−), is oxidized during the transformation to the sulfate form (S6+). Upon formation (at or immediately below the surface), the highly soluble cadmium sulfate is assumed to be transported to the surface in solution and reprecipitates there, forming the whitish globules. The presence of cadmium sulfate (CdSO4·2H2O) and ammonium cadmium sulfate [(NH4)2Cd(SO4)2] at the surface is confirmed by microscopic X-ray diffraction measurements, where the latter salt is suspected to result from a secondary reaction of cadmium sulfate with ammonia. Measurements performed on cross sections reveal that the oxidation front has penetrated into the yellow paint down to ca. 1−2 ìm. The morphology and elemental distribution of the paint and degradation product were examined by means of scanning electron microscopy equipped with an energy-dispersive spectrometer (SEM-EDS) and synchrotron radiation based micro-X-ray fluorescence spectrometry (SR ì-XRF). In addition, ultraviolet-induced visible fluorescence photography (UIVFP) revealed itself to be a straightforward technique for documenting the occurrence of this specific kind of degradation on a macroscale by painting conservators.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000264759400025 Publication Date 2009-03-11
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.32 Times cited 91 Open Access
Notes Approved Most recent IF: 6.32; 2009 IF: 5.214
Call Number UA @ admin @ c:irua:76415 Serial 5501
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Author Jain, R.; Rather, J.A.; Dwivedi, A.; Vikas
Title Highly sensitive and selective voltammetric sensor fullerene modified glassy carbon electrode for determination of cefitizoxime in solubilized system Type A1 Journal article
Year 2010 Publication Electroanalysis Abbreviated Journal
Volume 22 Issue 21 Pages (up) 2600-2606
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The usefulness of fullerene modified glassy carbon electrode in mediating the reduction of cefitizoxime in solubilized system has been demonstrated. Due to the unique structure and extraordinary properties, fullerene shows higher catalytic efficiency towards cefitizoxime reduction. The kinetic parameters, electron transfer coefficient (α) and rate constant (K0) across the modified electrode are 0.37 and 0.1081/s respectively. The proposed square-wave voltammetric method is linear over the concentration range 1.210.3 µg/mL. The limit of detection (LOD) is found 0.27 ng/mL. High sensitivity and selectivity together with low detection limit of the electrode response make it suitable for the determination of cefitizoxime.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000284052900015 Publication Date 2010-10-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1040-0397 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:98690 Serial 8042
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Author Semenov, M.Y.; Van Grieken, R.
Title Base cation fluxes in mountain landscapes of Lake Baikal southern shore Type A1 Journal article
Year 2007 Publication Communications in soil science and plant analysis Abbreviated Journal
Volume 38 Issue 19-20 Pages (up) 2635-2646
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000251885800005 Publication Date 2007-11-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0010-3624 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:65351 Serial 7551
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Author Adams, F.; Gijbels, R.; Jambers, W.; van Grieken, R.
Title Mass spectrometry, inorganic Type H3 Book chapter
Year 1998 Publication Abbreviated Journal
Volume Issue Pages (up) 2650-2661
Keywords H3 Book chapter; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Wiley Place of Publication Chichester Editor
Language Wos Publication Date 0000-00-00
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ lucian @ c:irua:20970 Serial 1954
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Author Torfs, K.M.; Van Grieken, R.E.; Buzek, F.
Title Use of stable isotope measurements to evaluate the origin of suphur in gypsum layers on limestone buildings Type A1 Journal article
Year 1997 Publication Environmental science and technology Abbreviated Journal
Volume 31 Issue Pages (up) 2650-2655
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0013-936x; 1520-5851 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:18784 Serial 8724
Permanent link to this record
 
 
Author Al-Emam, E.; Beltran, V.; De Meyer, S.; Nuyts, G.; Wetemans, V.; De Wael, K.; Caen, J.; Janssens, K.
Title Removal of a past varnish treatment from a 19th-century Belgian wall painting by means of a solvent-loaded double network hydrogel Type A1 Journal article
Year 2021 Publication Polymers Abbreviated Journal Polymers-Basel
Volume 13 Issue 16 Pages (up) 2651-20
Keywords A1 Journal article; Art; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES); Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab); Antwerp X-ray Imaging and Spectroscopy (AXIS)
Abstract Polymeric materials have been used by painting conservator-restorers as consolidants and/or varnishes for wall paintings. The application of these materials is carried out when confronting loose paint layers or as a protective coating. However, these materials deteriorate and cause physiochemical alterations to the treated surface. In the past, the monumental neo-gothic wall painting 'The Last Judgment' in the chapel of Sint-Jan Berchmanscollege in Antwerp, Belgium was treated with a synthetic polymeric material. This varnish deteriorated significantly and turned brown, obscuring the paint layers. Given also that the varnish was applied to some parts of the wall painting and did not cover the entire surface, it was necessary to remove it in order to restore the original appearance of the wall painting. Previous attempts carried out by conservator-restorers made use of traditional cleaning methods, which led to damage of the fragile paint layers. Therefore, gel cleaning was proposed as a less invasive and more controllable method for gently softening and removing the varnish. The work started by identifying the paint stratigraphy and the deteriorated varnish via optical microscopy (OM), scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), and Fourier-transform infrared (FTIR) spectroscopy. A polyvinyl alcohol-borax/agarose (PVA-B/AG) hydrogel loaded with a number of solvents/solvent mixtures was employed in a series of tests to select the most suitable hydrogel composite. By means of the hydrogel composite loaded with 10% propylene carbonate, it was possible to safely remove the brown varnish layer. The results were verified by visual examinations (under visible light 'VIS' and ultraviolet light 'UV') as well as OM and FTIR spectroscopy.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000690248000001 Publication Date 2021-08-10
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2073-4360 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.364 Times cited Open Access OpenAccess
Notes Approved Most recent IF: 3.364
Call Number UA @ admin @ c:irua:181567 Serial 8470
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Author Swaenen, M.; Stefaniak, E.A.; Frost, R.; Worobiec, A.; Van Grieken, R.
Title Investigation of inclusions trapped inside Libyan desert glass by Raman microscopy Type A1 Journal article
Year 2010 Publication Analytical and bioanalytical chemistry Abbreviated Journal
Volume 397 Issue 7 Pages (up) 2659-2665
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)
Abstract Several specimens of Libyan desert glass (LDG), an enigmatic natural glass from Egypt, were subjected to investigation by micro-Raman spectroscopy. The spectra of inclusions inside the LDG samples were successfully measured through the layers of glass and the mineral species were identified on this basis. The presence of cristobalite as typical for high-temperature melt products was confirmed, together with co-existing quartz. TiO2 was determined in two polymorphic species rutile and anatase. Micro-Raman spectroscopy proved also the presence of minerals unusual for high-temperature glasses such as anhydrite and aragonite.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000280122100004 Publication Date 2010-01-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1618-2642; 1618-2650 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:83276 Serial 8125
Permanent link to this record
 
 
Author Ceglia, A.; Nuyts, G.; Cagno, S.; Meulebroeck, W.; Baert, K.; Cosyns, P.; Nys, K.; Thienpont, H.; Janssens, K.; Terryn, H.
Title A XANES study of chromophores : the case of black glass Type A1 Journal article
Year 2014 Publication Analytical methods Abbreviated Journal Anal Methods-Uk
Volume 6 Issue 8 Pages (up) 2662-2671
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract We studied the Fe K-edge X-ray absorption near edge (XANES) spectra of several Roman black glass fragments in order to determine the Fe3+/ΣFe ratio of these materials. The selected archaeological glass samples cover the period 1st5th century AD in nine different sites of the North Western provinces of the Roman Empire. The fragments belong to two different compositional groups demonstrating a diachronic evolution: early Roman HMG (High Magnesia Glass) and Roman Imperial LMG (Low Magnesia Glass). The first group contains natural Fe levels (below 2 wt% as Fe2O3), while the LMG has concentrations above 5 wt%. This difference is also reflected by Fe3+/ΣFe values. Low iron glass was produced under strongly reducing conditions in order to obtain the black colour, with average Fe3+/ΣFe values ≈ 0.17. LMG glass is somewhat more oxidised (Fe3+/ΣFe ≈ 0.40.5). While HMG glass required active control of the furnace environment, LMG was made under ambient atmosphere and its higher oxidation degree is mainly determined by the chemistry of the raw glass.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000333524200032 Publication Date 2014-02-05
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1759-9660 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.9 Times cited 14 Open Access
Notes ; The authors are grateful to the staff of beamline L in HASYLAB for their helpful support. The research leading to these results has received funding from the European Union Seventh Framework Programme FP7/2007-2013 under grant agreement no. 265010. Support from the University of Antwerp Research Council through GOA Programme “XANES meets ELNES” is gratefully acknowledged. This work was partly supported by the Research Council of Norway through its Centres of Excellence funding scheme, project number 223268/F50. We would like to thank M. P. Riccardi and E. Basso of the University of Pavia and R. Falcone of the Stazione Sperimentale del Vetro who provided us with the reference glasses. ; Approved Most recent IF: 1.9; 2014 IF: 1.821
Call Number UA @ admin @ c:irua:116596 Serial 5919
Permanent link to this record
 
 
Author Struyf, H.; Van Grieken, R.
Title An overview of wet deposition of micropollutants to the North Sea Type A1 Journal article
Year 1993 Publication Atmospheric environment: part A : general topics Abbreviated Journal
Volume 27 Issue Pages (up) 2669-2687
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1993MJ81600020 Publication Date 2003-08-06
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0960-1686; 1878-2124 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:6262 Serial 8353
Permanent link to this record
 
 
Author Teymourian, H.; Parrilla, M.; Sempionatto, J.R.; Montiel, N.F.; Barfidokht, A.; Van Echelpoel, R.; De Wael, K.; Wang, J.
Title Wearable Electrochemical Sensors for the Monitoring and Screening of Drugs Type A1 Journal article
Year 2020 Publication Acs Sensors Abbreviated Journal Acs Sensors
Volume 5 Issue 9 Pages (up) 2679-2700
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Wearable electrochemical sensors capable of noninvasive monitoring of chemical markers represent a rapidly emerging digital-health technology. Recent advances toward wearable continuous glucose monitoring (CGM) systems have ignited tremendous interest in expanding such sensor technology to other important fields. This article reviews for the first time wearable electrochemical sensors for monitoring therapeutic drugs and drugs of abuse. This rapidly emerging class of drug-sensing wearable devices addresses the growing demand for personalized medicine, toward improved therapeutic outcomes while minimizing the side effects of drugs and the related medical expenses. Continuous, noninvasive monitoring of therapeutic drugs within bodily fluids empowers clinicians and patients to correlate the pharmacokinetic properties with optimal outcomes by realizing patient-specific dose regulation and tracking dynamic changes in pharmacokinetics behavior while assuring the medication adherence of patients. Furthermore, wearable electrochemical drug monitoring devices can also serve as powerful screening tools in the hands of law enforcement agents to combat drug trafficking and support on-site forensic investigations. The review covers various wearable form factors developed for noninvasive monitoring of therapeutic drugs in different body fluids and toward on-site screening of drugs of abuse. The future prospects of such wearable drug monitoring devices are presented with the ultimate goals of introducing accurate real-time drug monitoring protocols and autonomous closed-loop platforms toward precise dose regulation and optimal therapeutic outcomes. Finally, current unmet challenges and existing gaps are discussed for motivating future technological innovations regarding personalized therapy. The current pace of developments and the tremendous market opportunities for such wearable drug monitoring platforms are expected to drive intense future research and

commercialization efforts.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000573560800003 Publication Date 2020-09-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 2379-3694 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.9 Times cited Open Access
Notes Horizon 2020 Framework Programme, 833787 ; Center of Wearable Sensors, University of California San Diego; Approved Most recent IF: 8.9; 2020 IF: NA
Call Number AXES @ axes @c:irua:170894 Serial 6436
Permanent link to this record
 
 
Author Terzano, R.; Santoro, A.; Spagnuolo, M.; Vekemans, B.; Medici, L.; Janssens, K.; Göttlicher, J.; Denecke, M.A.; Mangold, S.; Ruggiero, P.
Title Solving mercury (Hg) speciation in soil samples by synchrotron X-ray microspectroscopic techniques Type A1 Journal article
Year 2010 Publication Environmental pollution Abbreviated Journal Environ Pollut
Volume 158 Issue 8 Pages (up) 2702-2709
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Direct mercury (Hg) speciation was assessed for soil samples with a Hg concentration ranging from 7 up to 240 mg kg1. Hg chemical forms were identified and quantified by sequential extractions and bulkand micro-analytical techniques exploiting synchrotron generated X-rays. In particular, microspectroscopic techniques such as m-XRF, m-XRD and m-XANES were necessary to solve bulk Hg speciation, in both soil fractions <2 mm and <2 mm. The main Hg-species found in the soil samples were metacinnabar (b-HgS), cinnabar (a-HgS), corderoite (Hg3S2Cl2), and an amorphous phase containing Hg bound to chlorine and sulfur. The amount of metacinnabar and amorphous phases increased in the fraction <2 mm. No interaction among Hg-species and soil components was observed. All the observed Hgspecies originated from the slow weathering of an inert Hg-containing waste material (K106, U.S. EPA) dumped in the area several years ago, which is changing into a relatively more dangerous source of pollution.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000280571500026 Publication Date 2010-06-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0269-7491 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 5.099 Times cited 30 Open Access
Notes ; This research was partially financed by the MIUR (COFIN 2005) project “Innovative chemical, physical, and biological methods to characterize and remediate soils polluted by heavy metals (MICROS)”. Synchrotron experiments at HASYLAB were financially supported by the European Community-Research Infrastructure Action under the FP6 “Structuring the European Research Area” Program I(Integrating Activity on Synchrotron and Free Electron Laser Science; project: contract RII3-CT-2004-506008). This research was also performed as part of the “Interuniversity Attraction Poles” (IAP6) Program financed by the Belgian government. We thank Gerald Falkenberg and Karen Rickers-Appel for their scientific and technical support in obtaining the experimental data at Beam line L (HASYLAB, DESY, Hamburg, Germany). ; Approved Most recent IF: 5.099; 2010 IF: 3.395
Call Number UA @ admin @ c:irua:84050 Serial 5835
Permanent link to this record
 
 
Author Noone, K.J.; Öström, E.; Ferek, R.J.; Garrett, T.; Hobbs, P.V.; Johnson, D.W.; Taylor, J.P.; Russell, L.M.; Flagan, R.C.; Seinfeld, J.H.; O'Dowd, C.D.; Smith, M.H.; Durkee, P.A.; Nielsen, K.; Hudson, J.G.; Pockalny, R.A.; de Bock, L.; Van Grieken, R.E.; Gasparovic, R.F.; Brooks, I.
Title A case study of ships forming and not forming tracks in moderately polluted clouds Type A1 Journal article
Year 2000 Publication Journal of the atmospheric sciences Abbreviated Journal
Volume 57 Issue Pages (up) 2729-2747
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000088911800015 Publication Date 2002-07-27
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0022-4928; 1520-0469 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:31624 Serial 7583
Permanent link to this record
 
 
Author Simionovici, A.S.; Chukalina, M.; Schroer, C.; Drakopoulos, M.; Snigirev, A.; Snigireva, I.; Lengeler, B.; Janssens, K.; Adams, F.
Title High-resolution X-ray fluorescence microtomography of homogeneous samples Type A1 Journal article
Year 2000 Publication IEEE transactions on nuclear science Abbreviated Journal Ieee T Nucl Sci
Volume 47 Issue 6 Pages (up) 2736-2740
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000166992400006 Publication Date 2002-08-24
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0018-9499 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.171 Times cited Open Access
Notes Approved Most recent IF: 1.171; 2000 IF: 1.060
Call Number UA @ admin @ c:irua:32403 Serial 5644
Permanent link to this record
 
 
Author Noone, K.J.; Johnson, D.W.; Taylor, J.P.; Ferek, R.J.; Garrett, T.; Hobbs, P.V.; Durkee, P.A.; Nielsen, K.; Öström, E.; O'Dowd, C.D.; Smith, M.H.; Russell, L.M.; Flagan, R.C.; Seinfeld, J.H.; de Bock, L.; Van Grieken, R.E.; Hudson, J.G.; Brooks, I.; Gasparovic, R.F.; Pockalny, R.A.
Title A case study of ship track formation in a polluted marine boundary layer Type A1 Journal article
Year 2000 Publication Journal of the atmospheric sciences Abbreviated Journal
Volume 57 Issue Pages (up) 2748-2764
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000088911800016 Publication Date 2002-07-27
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0022-4928; 1520-0469 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:31631 Serial 7582
Permanent link to this record
 
 
Author Roet, D.; van Espen, P.
Title Monte Carlo simulation of X-ray spectra from low energy electrons using optical data Type A1 Journal article
Year 2010 Publication Nuclear instruments and methods in physics research: B: beam interactions with materials and atoms Abbreviated Journal
Volume 268 Issue 17/18 Pages (up) 2794-2800
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract An approach using optical data to simulate both the bremsstrahlung continuum and characteristic K and L X-ray lines generated by low energy electrons (cfr. electron microscopy) in solids is discussed in this paper. The necessary analytical expressions together with the data to calculate the relevant cross sections for elastic and inelastic interactions at these energies along with variance reduction techniques are given. The results of the Monte Carlo simulation are compared to experimental data measured with a JEOL 6300 electron microscope.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000281498900039 Publication Date 2010-07-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0168-583x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:84261 Serial 8281
Permanent link to this record
 
 
Author Markowicz, A.A.; Van Grieken, R.E.
Title Atomic number correction in electron probe X-ray microanalysis of curved samples and particles Type A1 Journal article
Year 1984 Publication Analytical chemistry Abbreviated Journal
Volume 56 Issue 14 Pages (up) 2798-2801
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1984TU34600040 Publication Date 2005-03-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116519 Serial 7535
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Author Marchetti, A.; Saniz, R.; Krishnan, D.; Rabbachin, L.; Nuyts, G.; De Meyer, S.; Verbeeck, J.; Janssens, K.; Pelosi, C.; Lamoen, D.; Partoens, B.; De Wael, K.
Title Unraveling the Role of Lattice Substitutions on the Stabilization of the Intrinsically Unstable Pb2Sb2O7Pyrochlore: Explaining the Lightfastness of Lead Pyroantimonate Artists’ Pigments Type A1 Journal article
Year 2020 Publication Chemistry Of Materials Abbreviated Journal Chem Mater
Volume 32 Issue 7 Pages (up) 2863-2873
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Electron microscopy for materials research (EMAT); Condensed Matter Theory (CMT)
Abstract The pyroantimonate pigments Naples yellow and lead tin antimonate yellow are recognized as some of the most stable synthetic yellow pigments in the history of art. However, this exceptional lightfastness is in contrast with experimental evidence suggesting that this class of mixed oxides is of semiconducting nature. In this study the electronic structure and light-induced behavior of the lead pyroantimonate pigments were determined by means of a combined multifaceted analytical and computational approach (photoelectrochemical measurements, UV-vis diffuse reflectance spectroscopy, STEM-EDS, STEM-HAADF, and density functional theory calculations). The results demonstrate both the semiconducting nature and the lightfastness of these pigments. Poor optical absorption and minority carrier mobility are the main properties responsible for the observed stability. In addition, novel fundamental insights into the role played by Na atoms in the stabilization of the otherwise intrinsically unstable Pb2Sb2O7 pyrochlore were obtained.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000526394000016 Publication Date 2020-04-14
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0897-4756 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.6 Times cited 8 Open Access OpenAccess
Notes Universiteit Antwerpen; Belgian Federal Science Policy Office; Approved Most recent IF: 8.6; 2020 IF: 9.466
Call Number EMAT @ emat @c:irua:168819 Serial 6363
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Author Markowicz, A.A.; Storms, H.M.; Van Grieken, R.E.
Title Bremsstrahlung background in electron-probe X-ray-microanalysis of thin films Type A1 Journal article
Year 1985 Publication Analytical chemistry Abbreviated Journal
Volume 57 Issue 14 Pages (up) 2885-2889
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1985AVD0100033 Publication Date 2005-03-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:113616 Serial 7567
Permanent link to this record
 
 
Author Ravindra, K.; Sokhi, R.; Van Grieken, R.
Title Atmospheric polycyclic aromatic hydrocarbons: source attribution, emission factors and regulation Type A1 Journal article
Year 2008 Publication Atmospheric environment : an international journal Abbreviated Journal
Volume 42 Issue 13 Pages (up) 2895-2921
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000256845900001 Publication Date 2008-03-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1352-2310 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:68424 Serial 7531
Permanent link to this record
 
 
Author Szalóki, I.; Török, S.B.; Injuk, J.; Van Grieken, R.E.
Title X-ray spectrometry Type A1 Journal article
Year 2002 Publication Analytical chemistry Abbreviated Journal
Volume 74 Issue 12 Pages (up) 2895-2918
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000176253700020 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:39517 Serial 8773
Permanent link to this record
 
 
Author Schelles, W.; Van Grieken, R.
Title Direct current glow discharge mass spectrometry for elemental characterization of polymers Type A1 Journal article
Year 1997 Publication Analytical chemistry Abbreviated Journal
Volume 69 Issue Pages (up) 2931-2934
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1997XN42400017 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:18773 Serial 7809
Permanent link to this record
 
 
Author Injuk, J.; Van Grieken, R.; de Leeuw, G.
Title Deposition of atmospheric trace elements into the North Sea: coastal, ship, platform measurements and model predictions Type A1 Journal article
Year 1998 Publication Atmospheric environment : an international journal Abbreviated Journal
Volume 32 Issue Pages (up) 3011-3025
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000075270300013 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1352-2310 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:20966 Serial 7761
Permanent link to this record
 
 
Author Ro, C.-U.; Osán, J.; Szalóki, I.; Oh, K.-Y.; Kim, H.; Van Grieken, R.
Title Determination of chemical species in individual aerosol particles using ultrathin window EPMA Type A1 Journal article
Year 2000 Publication Environmental science and technology Abbreviated Journal
Volume 34 Issue Pages (up) 3023-3030
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000088156100023 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0013-936x; 1520-5851 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:31660 Serial 7777
Permanent link to this record
 
 
Author Cagno, S.; Mendera, M.; Jeffries, T.; Janssens, K.
Title Raw materials for medieval to post-medieval Tuscan glassmaking : new insight from LA-ICP-MS analyses Type A1 Journal article
Year 2010 Publication Journal of archaeological science Abbreviated Journal J Archaeol Sci
Volume 37 Issue 12 Pages (up) 3030-3036
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract LA-ICP-MS analyses were performed on a set of Tuscan (post) medieval archaeological glass finds dated to the 1316th century in order to quantitatively determine the trace element contents. The results are used for defining and distinguishing several compositional groups. The trace element data are consistent with the distinctions obtained by considering the major element data determined via quantitative SEM-EDX, but allow to obtain new insights into the nature and quality of the silica sources employed and the presumed method of ash purification.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000283903500008 Publication Date 2010-07-06
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0305-4403 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.602 Times cited 38 Open Access
Notes ; This research was supported by the Interuniversity Attraction Poles Program – Belgian Science Policy (IUAP VI/16). The text also presents results of GOA “Atom” (Research Fund University of Antwerp, Belgium) and of FWO (Brussels, Belgium) projects no. G.0177.03, G.0103.04 and G.0689.06. ; Approved Most recent IF: 2.602; 2010 IF: 1.710
Call Number UA @ admin @ c:irua:85814 Serial 5802
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Author Cassiers, K.; Linssen, T.; Aerts, K.; Cool, P.; Lebedev, O.; Van Tendeloo, G.; van Grieken, R.; Vansant, E.F.
Title Controlled formation of amine-templated mesostructured zirconia with remarkably high thermal stability Type A1 Journal article
Year 2003 Publication Journal of materials chemistry Abbreviated Journal J Mater Chem
Volume 13 Issue Pages (up) 3033-3039
Keywords A1 Journal article; Electron microscopy for materials research (EMAT); Laboratory of adsorption and catalysis (LADCA); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Cambridge Editor
Language Wos 000186907500040 Publication Date 2003-11-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0959-9428;1364-5501; ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited 26 Open Access
Notes Approved Most recent IF: NA
Call Number UA @ lucian @ c:irua:43522 Serial 502
Permanent link to this record
 
 
Author Kosov, A.D.; Dubrinina, T.V.; Borisova, N.E.; Ivanov, A.V.; Drozdov, K.A.; Trashin, S.A.; De Wael, K.; Kotova, M.S.; Tomilova, L.G.
Title Novel phenyl-substituted pyrazinoporphyrazine complexes of rare-earth elements : optimized synthetic protocols and physicochemical properties Type A1 Journal article
Year 2019 Publication New journal of chemistry Abbreviated Journal New J Chem
Volume 43 Issue 7 Pages (up) 3153-3161
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Novel synthetic protocols based on both template and multi-step methods were developed for phenyl-substituted pyrazinoporphyrazine complexes of rare-earth elements (Y, Eu, Gd, Dy, Er and Lu). p-Hydroquinone was employed as a reaction medium and as a reducing agent in the process of porphyrazine macrocycle formation. Both thermal and microwave irradiation techniques were successfully applied for activation of the template macrocyclization process. An alternative multi-step approach involving the initial stage of free-base ligand formation was realized for the lutetium compound. The target complexes were identified by high-resolution mass spectrometry, infrared spectroscopy and nuclear magnetic resonance (NMR) spectroscopy. Electrochemical behavior in solution and UV-vis absorbance in solutions and films were studied as well. Shifts in the position of the Q band and oxidationreduction potentials in comparison with corresponding phthalocyanine analogues were noticed. Using the IR absorption spectra recorded in the temperature range of 170300 K, the position of the Fermi level of −4.7 ± 0.1 eV and a characteristic energy diagram were obtained for the erbium complex.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000459944500035 Publication Date 2019-01-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1144-0546 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.269 Times cited 1 Open Access
Notes ; We are grateful for main financial support from the Russian Foundation for Basic Research (Grant No. 16-33-60005 and 18-33-00519). Investigation of optical properties was supported by the Russian Science Foundation (Grant 17-13-01197). Electrochemical investigations were supported by ERA.Net RUS Plus Plasmon Electrolight and FWO funding (RFBR No. 18-53-76006 ERA). We also thank the Council under the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (Grants MK-3115.2018.3) and partial support from the framework of the State Assignment of 2019 (Theme 45.5 Creation of compounds with given physicochemical properties). Investigation of electrophysical properties was supported by the RFBR (Grant 16-07-00961). K. A. Drozdov and M. S. Kotova thank Prof. L. I. Ryabova for productive discussion of the electrophysical data. ; Approved Most recent IF: 3.269
Call Number UA @ admin @ c:irua:156555 Serial 5750
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Author Cagno, S.; van der Snickt, G.; Legrand, S.; Caen, J.; Patin, M.; Meulebroeck, W.; Dirkx, Y.; Hillen, M.; Steenackers, G.; Rousaki, A.; Vandenabeele, P.; Janssens, K.
Title Comparison of four mobile, non‐invasive diagnostic techniques for differentiating glass types in historical leaded windows : MA‐XRF , UV–Vis–NIR, Raman spectroscopy and IRT Type A1 Journal article
Year 2020 Publication X-Ray Spectrometry Abbreviated Journal X-Ray Spectrom
Volume Issue Pages (up) xrs.3185-17
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)
Abstract This paper critically compares the performance of four non-invasive techniques that match the accuracy, flexibility, time-efficiency, and transportability required for in situ characterization of leaded glass windows: macroscopic X-ray fluorescence imaging (MA-XRF), UV-Vis-NIR, Raman spectroscopy, and infrared thermography (IRT). In order to compare the techniques on equal grounds, all techniques were tested independently of each other by separate research groups on the same historical leaded window tentatively dated to the 17th century, without prior knowledge. The aim was to assess the ability of these techniques to document the conservation history of the window by classifying and grouping the colorless glass panes, based on differences in composition. IRT, MA-XRF and UV-Vis-NIR spectroscopy positively distinguished at least two glass groups, with MA-XRF providing the most detailed chemical information. In particular, based on the ratio between the network modifier (K) and network stabilizer (Ca) and on the level of colorants and decolorizers (Fe, Mn, As), the number of plausible glass families could be strongly reduced. In addition, UV-Vis-NIR detected cobalt at ppm level and gave more specific information on the chromophore Fe2+/Fe(3+)ratio. Raman spectroscopy was hampered by fluorescence caused by the metal ions of the decolorizer in most of the panes, but nevertheless identified one group as HLLA.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000561869600001 Publication Date 2020-08-24
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.2 Times cited Open Access
Notes ; Belgian Federal Science Policy Office, Grant/Award Number: BR/175/A3/FENESTRA; Fonds Wetenschappelijk Onderzoek, Grant/Award Number: 12X1919N; Baillet-Latour Fund ; Approved Most recent IF: 1.2; 2020 IF: 1.298
Call Number UA @ admin @ c:irua:170972 Serial 6473
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