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Author Mishra, R.S.K.; Pandey, D.; Lemmens, H.; Van Tendeloo, G.
Title Evidence for another low-temperature phase transition in tetragonal Pb(ZrxTi1-x)O3 (x=0.515,0.520) Type A1 Journal article
Year 2001 Publication Physical review : B : condensed matter and materials physics Abbreviated Journal Phys Rev B
Volume 64 Issue 5 Pages 054104
Keywords A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract Results of dielectric and resonance frequency (f(r)) measurements below room temperature are presented for Pb(ZrxTi1-x)O-3, x = 0.515 and 0.520. It is shown that the temperature coefficient of f(r) changes sign from negative to positive around 210 and 265 K for x = 0.520 and 200 and 260 K for x = 0.515. Anomalies in the real part of the dielectric constant (epsilon') are observed around the same temperatures at which the temperature coefficient of f(r) changes sign because of the electrostrictive coupling between the elastic and dielectric responses. Low-temperature powder x-ray-diffraction (XRD) data, however, reveal only one transition from the tetragonal to monoclinic phase similar to that reported by Noheda et al. [Phys. Rev. B, 61, 8687 (2000)]. Electron-diffraction data, on the other hand, reveal yet another structural transition at lower temperatures corresponding to the second anomaly in the epsilon' vs T and f(r) vs T curves. This second transition is shown to be a cell-doubling transition not observed by Noheda et al. in their XRD studies. The observation of superlattice reflections raises doubts about the correctness of the Cm space group proposed by Noheda et al. for the monoclinic phase of Pb(ZrxTi(1-x))O-3 below the second transition temperature.
Address
Corporate Author Thesis
Publisher Place of Publication Lancaster, Pa Editor
Language Wos 000170267000028 Publication Date 2002-07-27
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0163-1829;1095-3795; ISBN Additional Links (up) UA library record; WoS full record; WoS citing articles
Impact Factor 3.836 Times cited Open Access
Notes Approved Most recent IF: 3.836; 2001 IF: NA
Call Number UA @ lucian @ c:irua:103407 Serial 1093
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Author Lemmens, H.; Czank, M.; Van Tendeloo, G.; Amelinckx, S.
Title Defect structure of the low temperature α-cristobalite phase and the cristobalite <-> tridymite transformation in (Si-Ge)O2 Type A1 Journal article
Year 2000 Publication Physics and chemistry of minerals Abbreviated Journal Phys Chem Miner
Volume 27 Issue 6 Pages 386-397
Keywords A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Berlin Editor
Language Wos 000087959700004 Publication Date 2002-10-06
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0342-1791;1432-2021; ISBN Additional Links (up) UA library record; WoS full record; WoS citing articles
Impact Factor 1.521 Times cited 5 Open Access
Notes Approved Most recent IF: 1.521; 2000 IF: 1.513
Call Number UA @ lucian @ c:irua:54725 Serial 622
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Author Lemmens, H.; Amelinckx, S.; Van Tendeloo, G.; Abakumov, A.M.; Rozova, M.G.; Antipov, E.V.
Title Transmission electron microscopy study of polymorphism in barium gallate BaGa2O4 Type A1 Journal article
Year 2003 Publication Phase transitions Abbreviated Journal Phase Transit
Volume 76 Issue 7 Pages 653-670
Keywords A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication New York Editor
Language Wos 000184129400004 Publication Date 2003-11-10
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0141-1594;1029-0338; ISBN Additional Links (up) UA library record; WoS full record; WoS citing articles
Impact Factor 1.06 Times cited 6 Open Access
Notes Approved Most recent IF: 1.06; 2003 IF: 0.558
Call Number UA @ lucian @ c:irua:54857 Serial 3719
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Author Lemmens, H.; Richard, O.; Van Tendeloo, G.; Bismayer, U.
Title Microstructure and phase transitions in Pb(Sc0.5Ta0.5)O3 Type A1 Journal article
Year 1999 Publication Journal of electron microscopy Abbreviated Journal Microscopy-Jpn
Volume 48 Issue 6 Pages 843-847
Keywords A1 Journal article; Electron microscopy for materials research (EMAT)
Abstract The microstructure and phase transitions in the perovskite-based ferroelectric lead scandium tantalate, Pb(Sc0.5Ta0.5)O-3 have been investigated by transmission electron microscopy. The effects of ordering of Sc and Ta cations are apparent in reciprocal space as well as in direct space images. High-resolution observations allow direct structure imaging of the domain structure. The structure of the low temperature ferroelectric phase is studied by selected area electron diffraction (SAED) and electron microdiffraction. The relaxer behaviour of this paraelectric-ferroelectric transition is displayed by diffuse intensities in the SAED patterns at temperatures around the Curie point.
Address
Corporate Author Thesis
Publisher Place of Publication Tokyo Editor
Language Wos 000085129600023 Publication Date 2012-04-19
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0022-0744;1477-9986; ISBN Additional Links (up) UA library record; WoS full record; WoS citing articles
Impact Factor 0.9 Times cited 7 Open Access
Notes Approved Most recent IF: NA
Call Number UA @ lucian @ c:irua:95195 Serial 2057
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