| Records |
| Author |
Terzano, R.; Santoro, A.; Spagnuolo, M.; Vekemans, B.; Medici, L.; Janssens, K.; Göttlicher, J.; Denecke, M.A.; Mangold, S.; Ruggiero, P. |
| Title |
Solving mercury (Hg) speciation in soil samples by synchrotron X-ray microspectroscopic techniques |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Environmental pollution |
Abbreviated Journal |
Environ Pollut |
| Volume |
158 |
Issue |
8 |
Pages |
2702-2709 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Direct mercury (Hg) speciation was assessed for soil samples with a Hg concentration ranging from 7 up to 240 mg kg1. Hg chemical forms were identified and quantified by sequential extractions and bulkand micro-analytical techniques exploiting synchrotron generated X-rays. In particular, microspectroscopic techniques such as m-XRF, m-XRD and m-XANES were necessary to solve bulk Hg speciation, in both soil fractions <2 mm and <2 mm. The main Hg-species found in the soil samples were metacinnabar (b-HgS), cinnabar (a-HgS), corderoite (Hg3S2Cl2), and an amorphous phase containing Hg bound to chlorine and sulfur. The amount of metacinnabar and amorphous phases increased in the fraction <2 mm. No interaction among Hg-species and soil components was observed. All the observed Hgspecies originated from the slow weathering of an inert Hg-containing waste material (K106, U.S. EPA) dumped in the area several years ago, which is changing into a relatively more dangerous source of pollution. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000280571500026 |
Publication Date |
2010-06-08 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0269-7491 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
5.099 |
Times cited |
30 |
Open Access |
|
| Notes |
; This research was partially financed by the MIUR (COFIN 2005) project “Innovative chemical, physical, and biological methods to characterize and remediate soils polluted by heavy metals (MICROS)”. Synchrotron experiments at HASYLAB were financially supported by the European Community-Research Infrastructure Action under the FP6 “Structuring the European Research Area” Program I(Integrating Activity on Synchrotron and Free Electron Laser Science; project: contract RII3-CT-2004-506008). This research was also performed as part of the “Interuniversity Attraction Poles” (IAP6) Program financed by the Belgian government. We thank Gerald Falkenberg and Karen Rickers-Appel for their scientific and technical support in obtaining the experimental data at Beam line L (HASYLAB, DESY, Hamburg, Germany). ; |
Approved |
Most recent IF: 5.099; 2010 IF: 3.395 |
Call Number  |
UA @ admin @ c:irua:84050 |
Serial |
5835 |
| Permanent link to this record |
| |
|
| |
| Author |
Harlay, J.; Borges, A.V.; van der Zee, C.; Delille, B.; Godoi, R.H.M.; Schiettecatte, L.-S.; Roevros, N.; Aerts, K.; Lapernat, P.-E.; Rebreanu, L.; Groom, S.; Daro, M.-H.; Van Grieken, R.; Chou, L. |
| Title |
Biogeochemical study of a coccolithophore bloom in the northern Bay of Biscay (NE Atlantic Ocean) in June 2004 |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Progress in oceanography |
Abbreviated Journal |
|
| Volume |
86 |
Issue |
3/4 |
Pages |
317-336 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The present paper synthesizes data obtained during a multidisciplinary cruise carried out in June 2004 at the continental margin of the northern Bay of Biscay. The data-set allows to describe the different stages of a coccolithophore bloom dominated by Emiliania huxleyi. The cruise was carried out after the main spring phytoplankton bloom that started in mid-April and peaked in mid-May. Consequently, low phosphate (PO4 < 0.2 μM) and silicate (DSi < 2.0 μM) concentrations, low partial pressure of carbon dioxide (pCO2) and high calcite saturation degree in surface waters combined with thermal stratification, probably favoured the blooming of coccolithophores. During the period of the year our cruise was carried out, internal tides induce enhanced vertical mixing at the continental shelf break leading to the injection of inorganic nutrients to surface waters that probably trigger the bloom. The bloom developed as the water-column stratified and as the water mass was advected over the continental shelf, following the general residual circulation in the area. The most developed phase of the bloom was sampled in a remote sensed high reflectance (HR) patch over the continental shelf that was characterized by low chlorophyll-a (Chl-a) concentration in surface waters (<1.0 μg L−1), high particulate inorganic carbon (PIC) concentration (not, vert, similar8 μmol L−1) and coccolithophore abundance up to 57 × 106 cells L−1. Transparent exopolymer particles (TEP) concentrations ranged between 15 and 75 μg C L−1 and carbon content of TEP represented up to 26% of the particulate organic carbon (POC; maximum concentration of 15.5 μmol L−1 in the upper 40 m). Integrated primary production (PP) ranged between 210 and 680 mg C m−2 d−1 and integrated calcification (CAL) ranged between 14 and 140 mg C m−2 d−1, within the range of PP and CAL values previously reported during coccolithophore blooms in open and shelf waters of the North Atlantic Ocean. Bacterial protein production (BPP) measurements in surface waters (0.30.7 μg C L−1 h−1) were much higher than those reported during early phases of coccolithophore blooms in natural conditions, but similar to those during peak and declining coocolithophorid blooms reported in mesocosms. Total alkalinity anomalies with respect to conservative mixing (ΔTA) down to −49 μmol kg−1 are consistent with the occurrence of biogenic precipitation of calcite, while pCO2 remained 15107 μatm lower than atmospheric equilibrium (372 μatm). The correlation between ΔTA and pCO2 suggested that pCO2 increased in part due to calcification, but this increase was insufficient to overcome the background under-saturation of CO2. This is related to the biogeochemical history of the water masses due to net carbon fixation by the successive phytoplankton blooms in the area prior to the cruise, hence, the investigated area remained a sink for atmospheric CO2 despite calcification. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000281937800001 |
Publication Date |
2010-04-20 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0079-6611 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:84236 |
Serial |
7560 |
| Permanent link to this record |
| |
|
| |
| Author |
Bencs, L.; Ravindra, K.; de Hoog, J.; Spolnik, Z.; Bleux, N.; Berghmans, P.; Deutsch, F.; Roekens, E.; Van Grieken, R. |
| Title |
Appraisal of measurement methods, chemical composition and sources of fine atmospheric particles over six different areas of Northern Belgium |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Environmental pollution |
Abbreviated Journal |
|
| Volume |
158 |
Issue |
11 |
Pages |
3421-3430 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Daily and seasonal variation in the total elemental, organic carbon (OC) and elemental carbon (EC) content and mass of PM2.5 were studied at industrial, urban, suburban and agricultural/rural areas. Continuous (optical Dustscan, standard tapered element oscillating micro-balance (TEOM), TEOM with filter dynamics measurement system), semi-continuous (Partisol filter-sampling) and non-continuous (Dekati-impactor sampling and gravimetry) methods of PM2.5 mass monitoring were critically evaluated. The average elemental fraction accounted for 26% of the PM2.5 mass measured by gravimetry. Metals, like K, Mn, Fe, Cu, Zn and Pb were strongly inter-correlated, also frequently with non-metallic elements (P, S, Cl and/or Br) and EC/OC. A high OC/EC ratio (29) was generally observed. The total carbon content of PM2.5 ranged between 3 and 77% (averages: 1232%), peaking near industrial/heavy trafficked sites. Principal component analysis identified heavy oil burning, ferrous/non-ferrous industry and vehicular emissions as the main sources of metal pollution. This work compares various aerosol monitoring methods to characterize PM2.5 over six locations of different anthropogenic activities over Northern Belgium. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000282563200009 |
Publication Date |
2010-08-23 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0269-7491; 1873-6424 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:84237 |
Serial |
7488 |
| Permanent link to this record |
| |
|
| |
| Author |
Roet, D.; van Espen, P. |
| Title |
Monte Carlo simulation of X-ray spectra from low energy electrons using optical data |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Nuclear instruments and methods in physics research: B: beam interactions with materials and atoms |
Abbreviated Journal |
|
| Volume |
268 |
Issue |
17/18 |
Pages |
2794-2800 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
An approach using optical data to simulate both the bremsstrahlung continuum and characteristic K and L X-ray lines generated by low energy electrons (cfr. electron microscopy) in solids is discussed in this paper. The necessary analytical expressions together with the data to calculate the relevant cross sections for elastic and inelastic interactions at these energies along with variance reduction techniques are given. The results of the Monte Carlo simulation are compared to experimental data measured with a JEOL 6300 electron microscope. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000281498900039 |
Publication Date |
2010-07-15 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0168-583x |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:84261 |
Serial |
8281 |
| Permanent link to this record |
| |
|
| |
| Author |
Hauchecorne, B.; Tytgat, T.; Terrens, D.; Vanpachtenbeke, F.; Lenaerts, S. |
| Title |
Validation of a newly developed FTIR in situ reactor: real time study of photocatalytic degradation of nitric oxide |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Infrared physics and technology |
Abbreviated Journal |
Infrared Phys Techn |
| Volume |
53 |
Issue |
6 |
Pages |
469-473 |
| Keywords |
A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL) |
| Abstract |
For many years, photocatalysis has been proposed as one of the promising techniques to abate environmental pollutants. To improve these reactions it is vital to know the reaction mechanisms of the photocatalytic degradation. This new reactor will make it possible to study the catalytic surface at the moment the reactions occur. By the means of UV LED illumination there is no need of an external UV lamp and thus lowers the cost. The validation of this newly developed reactor is done by investigating the photocatalytic reaction mechanism of nitric oxide (NO) and comparing these findings with those already discussed in literature. From these results, it became clear that the newly developed FTIR in situ reactor allows real time study of photocatalytic degradations. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000285169400009 |
Publication Date |
2010-10-09 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1350-4495 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
1.713 |
Times cited |
12 |
Open Access |
|
| Notes |
; ; |
Approved |
Most recent IF: 1.713; 2010 IF: 0.932 |
| Call Number |
UA @ admin @ c:irua:84561 |
Serial |
6002 |
| Permanent link to this record |
| |
|
| |
| Author |
Darchuk, L.; Worobiec, A.; Khan, V.; Krasnov, V.; Van Grieken, R. |
| Title |
Composition of aerosols from the shelter of the Chernobyl power plant |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
AIP conference proceedings |
Abbreviated Journal |
|
| Volume |
1267 |
Issue |
|
Pages |
512-513 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
| Abstract |
|
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000281210900273 |
Publication Date |
2010-08-05 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0094-243x |
ISBN |
|
Additional Links |
UA library record; WoS full record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:84572 |
Serial |
7705 |
| Permanent link to this record |
| |
|
| |
| Author |
Worobiec, A.; Potgieter-Vermaak, S.; Darchuk, L.; Vishnyakov, V.; Potgieter, H.; Van Grieken, R. |
| Title |
Behavior of semi-volatile particles under a laser and electron beam: influence on the quality of analytical results |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
AIP conference proceedings |
Abbreviated Journal |
|
| Volume |
1267 |
Issue |
|
Pages |
523-524 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
| Abstract |
|
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000281210900279 |
Publication Date |
2010-08-05 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0094-243x |
ISBN |
|
Additional Links |
UA library record; WoS full record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:84573 |
Serial |
7553 |
| Permanent link to this record |
| |
|
| |
| Author |
Rouchon, V.; Pellizzi, E.; Janssens, K. |
| Title |
FTIR techniques applied to the detection of gelatine in paper artifacts: from macroscopic to microscopic approach |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Applied physics A : materials science & processing |
Abbreviated Journal |
Appl Phys A-Mater |
| Volume |
100 |
Issue |
3 |
Pages |
663-669 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
In order to render paper hydrophobic for ink and thus adequate for writing, gelatine has been largely used. To this day, it is still employed in conservation workshops as an adhesive or a sizing agent, for instance, during the treatment of iron gall ink manuscripts. Various types and concentrations of gelatine are recommended, depending on the desired effect, but little information is available regarding to the physical distribution of gelatine in the paper. This aspect is however determinant for a better control of conservation treatments. In this work, we investigate the possibilities offered by FTIR microscopy for the measurement of the gelatine distribution in paper. Laboratory papers were preliminary treated with different types of gelatine and then embedded in a resin and cut in thin slices. Mapping techniques enable to compare the penetration of different types of gelatine in a semiquantitative way. The performance of conventional laboratory equipment and synchrotron radiation experimental setup are discussed. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
000281317700011 |
Publication Date |
2010-04-01 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0947-8396 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
1.455 |
Times cited |
12 |
Open Access |
|
| Notes |
; This work was performed with the support of the Fondazione Cassa di Risparmio di Torino, who founded the postgraduate internship of Eleonora Pellizzi at the CRCC (Master dei talenti). It received the technical support of the SMIS line of the SOLEIL synchrotron (Saint Aubin, France). We are thankful to all our colleagues who helped us during our experiments: Anne Laurence Dupont for providing gelatine samples, Chakib Djediat (Museum National d'Histoire Naturelle, Paris) for his advice regarding the samples preparation, Christophe Sandt (Synchrotron SOLEIL) for his help and availability during our Beam time allocation, and Paul Dumas (Synchrotron SOLEIL) for his warm reception on the SMIS line. ; |
Approved |
Most recent IF: 1.455; 2010 IF: 1.765 |
| Call Number |
UA @ admin @ c:irua:84579 |
Serial |
5627 |
| Permanent link to this record |
| |
|
| |
| Author |
Schalm, O.; de Raedt, I.; Caen, J.; Janssens, K. |
| Title |
A methodology for the identification of glass panes of different origin in a single stained glass window: application on two 13th century windows |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Journal of cultural heritage |
Abbreviated Journal |
J Cult Herit |
| Volume |
11 |
Issue |
4 |
Pages |
487-492 |
| Keywords |
A1 Journal article; Art; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The chemical composition of 11 glass panes originating from two 13th century non-figurative windows were analyzed by means of Scanning Electron MicroscopyEnergy Dispersive X-ray system (SEM-EDX). The windows were discovered in the back-wall of the triforium during the restoration of the choir of the cathedral St. Michael and St. Gudule in Brussels (Belgium). In order to determine if these windows were fabricated with glass of different origin or not, the compositional difference between the panes were compared with the variation in composition as a result of the following causes: (1) compositional fluctuation between panes cut from the same sheet of glass, (2) compositional fluctuation caused when panes are cut from different sheets that were made with the same batch, (3) compositional fluctuation caused when the glass is made from different batches at the same production center, and (4) compositional fluctuation as a result of glass produced at different fabrication centers. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000282680500016 |
Publication Date |
2010-07-07 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1296-2074 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
1.838 |
Times cited |
7 |
Open Access |
|
| Notes |
; ; |
Approved |
Most recent IF: 1.838; 2010 IF: 1.162 |
| Call Number |
UA @ admin @ c:irua:84942 |
Serial |
5707 |
| Permanent link to this record |
| |
|
| |
| Author |
Potgieter-Vermaak, S.; Van Grieken, R.; Potgieter, J.H. |
| Title |
Integrated analytical techniques for the characterisation of environmental particles |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Spectroscopy Europe |
Abbreviated Journal |
|
| Volume |
22 |
Issue |
5 |
Pages |
12-15 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0966-0941; 2634-2561 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:85517 |
Serial |
8109 |
| Permanent link to this record |
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| |
| Author |
Janssen, E.; Kontozova-Deutsch, V.; Krupińska, B.; Moris, H.; Peckstadt, A.; van Bos, M.; Watteeuw, L.; Van Grieken, R. |
| Title |
Do gaseous pollutants and particulate matter endanger our world heritage? A study in the Museum Plantin-Moretus, Antwerp |
Type |
P3 Proceeding |
| Year |
2010 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
|
Pages |
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| Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
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ISBN |
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Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:85520 |
Serial |
7820 |
| Permanent link to this record |
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| |
| Author |
Kontozova-Deutsch, V.; Horemans, B.; Cardell, C.; Van Grieken, R. |
| Title |
Atmospheric pollution at the Alhambra monument, Granada, Spain: a preventive conservation study |
Type |
P3 Proceeding |
| Year |
2010 |
Publication |
|
Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
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ISBN |
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Additional Links |
UA library record |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:85522 |
Serial |
7530 |
| Permanent link to this record |
| |
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| |
| Author |
Jacobs, W.; Dubois, D.; Aerts, D.; Declerck, P.; Stranger, M.; Buczyńska, A.; Godoi, A.; Van Grieken, R. |
| Title |
Monitoring of some major volatile organic compounds on board of chemical tankers |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Journal of maritime research |
Abbreviated Journal |
|
| Volume |
7 |
Issue |
2 |
Pages |
3-20 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
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ISBN |
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Additional Links |
UA library record |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:85577 |
Serial |
8275 |
| Permanent link to this record |
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| |
| Author |
Cagno, S.; Mendera, M.; Jeffries, T.; Janssens, K. |
| Title |
Raw materials for medieval to post-medieval Tuscan glassmaking : new insight from LA-ICP-MS analyses |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Journal of archaeological science |
Abbreviated Journal |
J Archaeol Sci |
| Volume |
37 |
Issue |
12 |
Pages |
3030-3036 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
LA-ICP-MS analyses were performed on a set of Tuscan (post) medieval archaeological glass finds dated to the 1316th century in order to quantitatively determine the trace element contents. The results are used for defining and distinguishing several compositional groups. The trace element data are consistent with the distinctions obtained by considering the major element data determined via quantitative SEM-EDX, but allow to obtain new insights into the nature and quality of the silica sources employed and the presumed method of ash purification. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000283903500008 |
Publication Date |
2010-07-06 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
|
| ISSN |
0305-4403 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
2.602 |
Times cited |
38 |
Open Access |
|
| Notes |
; This research was supported by the Interuniversity Attraction Poles Program – Belgian Science Policy (IUAP VI/16). The text also presents results of GOA “Atom” (Research Fund University of Antwerp, Belgium) and of FWO (Brussels, Belgium) projects no. G.0177.03, G.0103.04 and G.0689.06. ; |
Approved |
Most recent IF: 2.602; 2010 IF: 1.710 |
| Call Number |
UA @ admin @ c:irua:85814 |
Serial |
5802 |
| Permanent link to this record |
| |
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| |
| Author |
Basile, F.; Benito, P.; Bugani, S.; de Nolf, W.; Fornasari, G.; Janssens, K.; Morselli, L.; Scavetta, E.; Tonelli, D.; Vaccari, A. |
| Title |
Combined use of synchrotron-radiation-based imaging techniques for the characterization of structured catalysts |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Advanced functional materials |
Abbreviated Journal |
Adv Funct Mater |
| Volume |
20 |
Issue |
23 |
Pages |
4117-4126 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Active-phase-coated metallic supports as structured catalysts are gaining attention in endothermic and exothermic processes because they improve heat transfer. The deposition of a well-adhered and stable catalyst layer on the metallic support constitutes an important feature for the successful application of the final material. In this work, coating of FeCrAlY foams is performed by a one-step electrosynthesis-deposition of hydrotalcite-type compounds, precursors of catalysts active in endothermic steam methane reforming. The catalysts are studied at different length scales by using, for the first time, a combination of several techniques: SEM/EDS and X-ray fluorescence, X-ray powder diffraction and absorption-tomography experiments on the micro- and nanoscales at a synchrotron facility. The results show that the morphology of the coating depends on the synthesis conditions and that the catalyst may be described as Ni metal crystallites dispersed on γ-Al2O3, homogeneously coating the FeCrAlY foam. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000285392900010 |
Publication Date |
2010-09-23 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
|
| ISSN |
1616-301x |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
12.124 |
Times cited |
24 |
Open Access |
|
| Notes |
; The authors give thanks to Dr. Cloetens, for helping during the absorption tomography experiments, performed at ID19 of the ESRF; and P. Blauet and R. Toucolou, for helping during the mu-XRF/XRPD and nano-XRF experiments at ID22 and ID22-NI of the ESRF. The financial support from the Ministero per l'Istruzione, l'Universita e la Ricerca (MIUR, Roma, Italy) is gratefully acknowledged. ; |
Approved |
Most recent IF: 12.124; 2010 IF: 8.508 |
| Call Number |
UA @ admin @ c:irua:85834 |
Serial |
5525 |
| Permanent link to this record |
| |
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| |
| Author |
Schalm, O.; Caen, J.; Janssens, K. |
| Title |
Homogeneity, composition and deterioration of window glass fragments and paint layers from two seventeenth-century stained glass windows created by Jan de Caumont (similar to 1580-1659) |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Studies in conservation |
Abbreviated Journal |
Stud Conserv |
| Volume |
55 |
Issue |
3 |
Pages |
216-226 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000285283600009 |
Publication Date |
2014-01-09 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0039-3630; 2047-0584 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
0.578 |
Times cited |
2 |
Open Access |
|
| Notes |
; ; |
Approved |
Most recent IF: 0.578; 2010 IF: 0.605 |
| Call Number |
UA @ admin @ c:irua:85835 |
Serial |
5645 |
| Permanent link to this record |
| |
|
| |
| Author |
Mishra, V.K.; Dons, E.; Panis, L.I.; Frijns, E.; van Poppel, M.; Berghmans, P.; Bleux, N.; Wuyts, K.; Samson, R. |
| Title |
Understanding ultrafine particles dynamics within a one km urban grid |
Type |
P3 Proceeding |
| Year |
2010 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
P3 Proceeding; Sustainable Energy, Air and Water Technology (DuEL) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
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ISBN |
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Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:88671 |
Serial |
8709 |
| Permanent link to this record |
| |
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| |
| Author |
Bruegelmans, P.; Horemans, B.; Hofkens, J.; Springael, D. |
| Title |
Response to mixed substrate feeds of the structure and activity of a linuron-degrading triple-species biofilm |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Research in microbiology |
Abbreviated Journal |
|
| Volume |
161 |
Issue |
8 |
Pages |
660-666 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
We sought to determine whether the pesticide-degrading performance of a multi-species bacterial biofilm is affected by co-occurrence of multiple nutrient sources Thus, the 3-(3,4-dichlorophenyl)-l-methoxy-l-methyl urea (linuron)-degrading activity of a triple-species linuron-degrading consortium, cultivated in continuous flow biofilm systems, was monitored when exposed to mixed substrate feeds which contained, in addition to linuron, readily assimilated carbon (i e citrate and trypticase soy broth) and/or nitrogen (i e ammonium) sources The addition of alternative carbon sources at different concentrations resulted in diminished linuron degradation efficiency In addition, the efficiency of removal of the linuron metabolite 3,4-dichloroaniline was affected These effects might be attributed to catabolic repression of the linuron metabolic pathway in the presence of alternative carbon substrates Moreover, each nutrient condition resulted in a particular biofilm composition and a particular spatial and structural organization, which might also be related to the performance of the biofilm community Results show that the activity of pesticide-degrading biofilms strongly depends on prevailing nutrient conditions and that the ideal biofilm configuration and activity, as observed under selective conditions, does not exist in real-life environmental conditions where mixtures of substrates are often present (C) 2010 Elsevier Masson SAS All rights reserved. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000283686200004 |
Publication Date |
2010-07-02 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0923-2508; 1769-7123 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:91369 |
Serial |
8477 |
| Permanent link to this record |
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| |
| Author |
Vazquez, C.; Martin Palacios, O.; Darchuk, L.; Marco Parra, L.-M. |
| Title |
Compositional study of prehistoric pigments (Carriqueo rock shelter, Argentina) by synchrotron radiation X-ray diffraction |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Powder diffraction |
Abbreviated Journal |
|
| Volume |
25 |
Issue |
3 |
Pages |
264-269 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
In this work synchrotron radiation X-ray diffraction technique was successfully applied for the analysis of pigments found in excavation at Carriqueo rock shelter, Neuquen, Argentina. The pigment samples of orange, red, and brown shades were collected from different levels of this archaeological site and compared with a suspected source of provenance (La Oficina creek). X-ray diffraction patterns of several yellowish, reddish, and red pigments showed the presence of haematite, goethite, kaolinite, and quartz. The majority of Carriqueo collected samples belonged to the same group of the suspected source, having haematite and quartz as main crystalline phases. The results indicate that the raw material from La Oficina is the source of most of the pigments found at Carriqueo. The present work helps us to understand the strategy of supplying raw materials by human groups in the North Patagonia region. (C) 2010 International Centre for Diffraction Data. [DOI: 10.1154/1.3478884] |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000282386500009 |
Publication Date |
2010-09-15 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0885-7156 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:95582 |
Serial |
7717 |
| Permanent link to this record |
| |
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| |
| Author |
Jain, R.; Yadav, R.K.; Rather, J.A. |
| Title |
Voltammetric assay of anti-vertigo drug betahistine hydrochloride in sodium lauryl sulphate |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Colloids and surfaces: A: physicochemical and engineering aspects |
Abbreviated Journal |
|
| Volume |
366 |
Issue |
|
Pages |
63-67 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Assay and electrochemical behaviour of betahistine hydrochloride in BrittonRobinsons (BR) buffer of pH range 2.512.0 at a glassy carbon electrode have been investigated. Addition of anionic surfactant (sodium lauryl sulphate) to the betahistine hydrochloride solution containing electrolyte enhanced the reduction current signal while neutral surfactant (Tween-20) and cationic surfactant cetyl trimethylammonium bromide (CTAB) showed an opposite effect. Voltammograms of betahistine hydrochloride exhibited a single wave. Based on reduction behaviour of betahistine hydrochloride, a direct square-wave voltammetric method has been developed for the assay of betahistine hydrochloride in pharmaceutical formulation. The proposed method has been validated as per ICH guideline. System and method precision in terms of RSD were 1.88% and 1.60% respectively, whereas the method accuracy was indicated by the recovery of 97.6101.9%. Reduction peak current was linear over the target concentration with correlation coefficient 0.998. The proposed method was successfully applied to the determination of betahistine hydrochloride in pharmaceutical formulation. The results were compared with those obtained by the reference high performance liquid chromatographic method. No significant differences were found between results of proposed and reference methods. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000280501800010 |
Publication Date |
2010-05-25 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0927-7757 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:98689 |
Serial |
8741 |
| Permanent link to this record |
| |
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| |
| Author |
Jain, R.; Rather, J.A.; Dwivedi, A.; Vikas |
| Title |
Highly sensitive and selective voltammetric sensor fullerene modified glassy carbon electrode for determination of cefitizoxime in solubilized system |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Electroanalysis |
Abbreviated Journal |
|
| Volume |
22 |
Issue |
21 |
Pages |
2600-2606 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
The usefulness of fullerene modified glassy carbon electrode in mediating the reduction of cefitizoxime in solubilized system has been demonstrated. Due to the unique structure and extraordinary properties, fullerene shows higher catalytic efficiency towards cefitizoxime reduction. The kinetic parameters, electron transfer coefficient (α) and rate constant (K0) across the modified electrode are 0.37 and 0.1081/s respectively. The proposed square-wave voltammetric method is linear over the concentration range 1.210.3 µg/mL. The limit of detection (LOD) is found 0.27 ng/mL. High sensitivity and selectivity together with low detection limit of the electrode response make it suitable for the determination of cefitizoxime. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000284052900015 |
Publication Date |
2010-10-04 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
1040-0397 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
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| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:98690 |
Serial |
8042 |
| Permanent link to this record |
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| |
| Author |
Sankaran, K.; Pourtois, G.; Degraeve, R.; Zahid, M.B.; Rignanese, G.-M.; Van Houdt, J. |
| Title |
First-principles modeling of intrinsic and extrinsic defects in \gamma-Al2O3 |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Applied physics letters |
Abbreviated Journal |
Appl Phys Lett |
| Volume |
97 |
Issue |
21 |
Pages |
212906 |
| Keywords |
A1 Journal article; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
| Abstract |
The electronic properties of a set of intrinsic and extrinsic point defects in gamma-Al2O3 are investigated using quasiparticle calculations within the G(0)W(0) approximation. We find that the electronic signature of atomic vacancies lie deep in the band gap, close to the top of the valence band edge. The introduction of C, Si, and N impurities induces defective levels that are located close to the conduction band edge and near the middle of the band gap of the oxide. The comparison with electrical measurements reveals that the energy levels of some of these defects match with the electronic fingerprint of the defects reported in gamma-Al2O3 based nonvolatile memories. (C) 2010 American Institute of Physics. [doi:10.1063/1.3507385] |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
American Institute of Physics |
Place of Publication |
New York, N.Y. |
Editor |
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| Language |
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Wos |
000284618300039 |
Publication Date |
2010-11-24 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
|
| ISSN |
0003-6951; |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
3.411 |
Times cited |
12 |
Open Access |
|
| Notes |
|
Approved |
Most recent IF: 3.411; 2010 IF: 3.841 |
| Call Number |
UA @ lucian @ c:irua:105617 |
Serial |
1213 |
| Permanent link to this record |
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| |
| Author |
Bending, S.J.; Milošević, M.V.; Moshchalkov, V.V. |
| Title |
Polarity-dependent vortex pinning and spontaneous vortex-antivortex structures in superconductor/ferromagnet hybrids |
Type |
H1 Book chapter |
| Year |
2010 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
299-322 |
| Keywords |
H1 Book chapter; Condensed Matter Theory (CMT) |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
Springer |
Place of Publication |
Berlin |
Editor |
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| Language |
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Wos |
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Publication Date |
0000-00-00 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
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ISBN |
978-3-642-15136-1 |
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
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Approved |
Most recent IF: NA |
| Call Number |
UA @ lucian @ c:irua:106139 |
Serial |
2659 |
| Permanent link to this record |
| |
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| |
| Author |
Nguyen, N.T.T.; Peeters, F.M. |
| Title |
The breakdown of Kohn's theorem in few-electron parabolic quantum dots doped with a single magnetic impurity Mn2+ |
Type |
P1 Proceeding |
| Year |
2010 |
Publication |
Journal of physics : conference series
T2 – Conference on Quantum Dots 2010 (QD2010), APR 26-30, 2010, Nottingham, ENGLAND |
Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
012031-12034 |
| Keywords |
P1 Proceeding; Engineering sciences. Technology; Condensed Matter Theory (CMT) |
| Abstract |
The cyclotron resonance (CR) absorption spectrum is calculated for a II-VI parabolic quantum dot (QD) containing few electrons and a single magnetic dopant (Mn(2+)). We find that Kohn's theorem no longer holds for this system and that the CR spectrum depends on the number of electrons inside the QD. The electron-Mn-ion interaction strength can be tuned for example by the magnetic field and by moving the Mn-ion to different positions inside the QD. We demonstrate that due to the presence of the Mn-ion the relative motion of the electrons couple with their center-of-mass motion through the electron-Mn-ion spin-spin exchange term resulting in an electron-electron interaction dependence of the magneto-optical absorption spectrum. At the ferromagnetic-antiferromagnetic transition we observe significant discontinuities in the CR lines. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
Bristol |
Editor |
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| Language |
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Wos |
000294907400031 |
Publication Date |
2010-09-21 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
245 |
Series Issue |
|
Edition |
|
| ISSN |
1742-6596; |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
1 |
Open Access |
|
| Notes |
; ; |
Approved |
Most recent IF: NA |
| Call Number |
UA @ lucian @ c:irua:113080 |
Serial |
3572 |
| Permanent link to this record |
| |
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| |
| Author |
Nguyen, N.T.T.; Peeters, F.M. |
| Title |
Phase-diagram for the magnetic states of the Mn-ion subsystem in a magnetic quantum dot |
Type |
P1 Proceeding |
| Year |
2010 |
Publication |
Journal of physics : conference series
T2 – Conference on Quantum Dots 2010 (QD2010), APR 26-30, 2010, Nottingham, ENGLAND |
Abbreviated Journal |
|
| Volume |
|
Issue |
|
Pages |
012032-12034 |
| Keywords |
P1 Proceeding; Engineering sciences. Technology; Condensed Matter Theory (CMT) |
| Abstract |
The interplay between two types of spin-spin exchange interaction (namely of the electron with the Mn-ions and the Mn-ions with each other) that are governed by the positions of the Mn-ions and the magnetic field is studied in the case of a Mn-ion doped CdTe quantum dot. We investigate the formation of different magnetic phases and the existence of frustrated magnetic states due to the dominant contribution of the Mn-Mn energy. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
Bristol |
Editor |
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| Language |
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Wos |
000294907400032 |
Publication Date |
2010-09-21 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
245 |
Series Issue |
|
Edition |
|
| ISSN |
1742-6596; |
ISBN |
|
Additional Links |
UA library record; WoS full record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
; ; |
Approved |
Most recent IF: NA |
| Call Number |
UA @ lucian @ c:irua:113081 |
Serial |
2582 |
| Permanent link to this record |
| |
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| |
| Author |
Khalil-Allafi, J.; Amin-Ahmadi, B.; Zare, M. |
| Title |
Biocompatibility and corrosion behavior of the shape memory NiTi alloy in the physiological environments simulated with body fluids for medical applications |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Materials science and engineering: part C: biomimetic materials |
Abbreviated Journal |
Mat Sci Eng C-Mater |
| Volume |
30 |
Issue |
8 |
Pages |
1112-1117 |
| Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
| Abstract |
Due to unique properties of NiTi shape memory alloys such as high corrosion resistance, biocompatibility, super elasticity and shape memory behavior, NiTi shape memory alloys are suitable materials for medical applications. Although TiO2 passive layer in these alloys can prevent releasing of nickel to the environment, high nickel content and stability of passive layer in these alloys are very debatable subjects. In this study a NiTi shape memory alloy with nominal composition of 50.7 atom% Ni was investigated by corrosion tests. Electrochemical tests were performed in two physiological environments of Ringer solution and NaCl 0.9% solution. Results indicate that the breakdown potential of the NiTi alloy in NaCl 0.9% solution is higher than that in Ringer solution. The results of Scanning Electron Microscope (SEM) reveal that low pitting corrosion occurred in Ringer solution compared with NaCl solution at potentiostatic tests. The pH value of the solutions increases after the electrochemical tests. The existence of hydride products in the X-ray diffraction analysis confirms the decrease of the concentration of hydrogen ion in solutions. Topographical evaluations show that corrosion products are nearly same in all samples. The biocompatibility tests were performed by reaction of mouse fibroblast cells (L929). The growth and development of cells for different times were measured by numbering the cells or statistics investigations. The figures of cells for different times showed natural growth of cells. The different of the cell numbers between the test specimen and control specimen was negligible; therefore it may be concluded that the NiTi shape memory alloy is not toxic in the physiological environments simulated with body fluids. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
Lausanne |
Editor |
|
| Language |
|
Wos |
000282905600006 |
Publication Date |
2010-06-23 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0928-4931; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
4.164 |
Times cited |
34 |
Open Access |
|
| Notes |
|
Approved |
Most recent IF: 4.164; 2010 IF: 2.180 |
| Call Number |
UA @ lucian @ c:irua:122039 |
Serial |
242 |
| Permanent link to this record |
| |
|
| |
| Author |
Amin-Ahmadi, B.; Aashuri, H. |
| Title |
Semisolid structure for M2 high speed steel prepared by cooling slope |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Journal of materials processing technology |
Abbreviated Journal |
J Mater Process Tech |
| Volume |
210 |
Issue |
12 |
Pages |
1632-1635 |
| Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
| Abstract |
Effects of cooling slope angle and the temperature of molten metal on the globular structure of M2 high speed steel after holding at the semisolid state have been investigated. The globular structure was achieved by pouring the molten metal at 1595 °C on the ceramic cooling slope with the length of 200 mm and the angle of 25°. The globular structure of M2 high speed steel in the form of rolledannealed and as cast condition after holding at semisolid state has been achieved. The size of globular grains of cooling slope sample was smaller than that of the rolledannealed and as cast samples. Solid particles of rolledannealed sample after holding at semisolid state had better roundness compared with cooling slope sample. Dissolution of carbides in the austenite phase at grain boundaries leads to formation of globular particles in the semisolid state. MC-type and M6C-type eutectic carbides reprecipitate during cooling cycle along grain boundaries. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
Amsterdam |
Editor |
|
| Language |
|
Wos |
000280498200011 |
Publication Date |
2010-06-02 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0924-0136; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
3.147 |
Times cited |
12 |
Open Access |
|
| Notes |
|
Approved |
Most recent IF: 3.147; 2010 IF: 1.570 |
| Call Number |
UA @ lucian @ c:irua:122042 |
Serial |
2983 |
| Permanent link to this record |
| |
|
| |
| Author |
Khalil-Allafi, J.; Amin-Ahmadi, B. |
| Title |
Multiple-step martensitic transformations in the Ni51Ti49 single crystal |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Journal of materials science |
Abbreviated Journal |
J Mater Sci |
| Volume |
45 |
Issue |
23 |
Pages |
6440-6445 |
| Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
| Abstract |
Multiple-step martensitic transformations of an aged Ni51Ti49 single crystal using calorimetric method were investigated. Results show that for short aging times (1045 min) multiple-step martensitic transformations on cooling occur in two steps. Applying intermediate aging times (1.254 h) results in three steps and long aging times (more than 8 h) lead to two-step martensitic transformations again. This behavior has not been recognized in NiTi single crystals in literatures. It can be related to the heterogeneity of composition and stress fields around Ni4Ti3 precipitates. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
London |
Editor |
|
| Language |
|
Wos |
000282429400021 |
Publication Date |
2010-06-30 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0022-2461;1573-4803; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
2.599 |
Times cited |
5 |
Open Access |
|
| Notes |
|
Approved |
Most recent IF: 2.599; 2010 IF: 1.859 |
| Call Number |
UA @ lucian @ c:irua:122046 |
Serial |
2231 |
| Permanent link to this record |
| |
|
| |
| Author |
Amin-Ahmadi, B.; Aashuri, H. |
| Title |
Globular structure of M2 high speed steel by thermomechanical treatment in the semisolid state |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Steel research international |
Abbreviated Journal |
Steel Res Int |
| Volume |
81 |
Issue |
5 |
Pages |
381-386 |
| Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
| Abstract |
The globular structure of M2 high speed steel in the rolled – annealed and as cast conditions was investigated in the semisolid state. Metallographic observations resulted in globular austenite particles that were surrounded by a liquid phase. Dissolution of various carbides in the austenite phase at semisolid temperatures led to grain boundary liquation and formation of near-spherical solid grains in a liquid matrix. Therefore, at the semisolid state, the solid particles were free from carbides. MC- type and M6C- type eutectic carbides re- precipitated at the grain boundaries during cooling of the samples from the semisolid temperature. The variation of shape factor versus holding time and holding temperature was examined. A transition value for shape factor changes in high speed steels was achieved. The growth rate constants of the Ostwald ripening and the coalescence mechanisms were calculated by using the experimentally determined rate constant. It was observed that less liquid droplets were enclosed inside the solid particles compared with non-ferrous alloys. Besides, it has been shown that at high solid fraction, the Ostwald ripening mechanism plays a prominent role in the coarsening phenomenon in comparison with the coalescence mechanism. Grains can rotate and arrange low misorientation with each other at high liquid contents, therefore low energetic grain boundaries form between these grains. These grain boundaries play an important role in the coalescence mechanism. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
Verlag Stahleisen |
Place of Publication |
Düsseldorf |
Editor |
|
| Language |
|
Wos |
000278292200007 |
Publication Date |
2010-05-18 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1611-3683;1869-344X; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
1.235 |
Times cited |
1 |
Open Access |
|
| Notes |
|
Approved |
Most recent IF: 1.235; 2010 IF: 0.455 |
| Call Number |
UA @ lucian @ c:irua:122047 |
Serial |
1347 |
| Permanent link to this record |
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|
| |
| Author |
Dadsetani, M.; Titantah, J.T.; Lamoen, D. |
| Title |
Ab initio calculation of the energy-loss near-edge structure of some carbon allotropes: comparison with n-diamond |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Diamond and related materials |
Abbreviated Journal |
Diam Relat Mater |
| Volume |
19 |
Issue |
1 |
Pages |
73-77 |
| Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
| Abstract |
The energy-loss near-edge structure (ELNES) spectra of several carbon allotropes (non-hydrogenated and hydrogenated face-centered cubic (FCC) carbon, rhombohedral carbon, glitter, hexagonite and lonsdaleite) are calculated within the supercell-core-excited density functional theory approach. In particular an experimental ELNES spectrum of new diamond (n-diamond) [Konyashin et al., Diamond Relat. Mater. 10, (2001) 99102] is compared with the ELNES spectra of FCC carbon, rhombohedral carbon and the so-called glitter structure. Our calculations show that the ELNES spectrum considered in that publication cannot be that of FCC carbon. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
|
Place of Publication |
Amsterdam |
Editor |
|
| Language |
|
Wos |
000274234500013 |
Publication Date |
2009-11-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0925-9635; |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
2.561 |
Times cited |
11 |
Open Access |
|
| Notes |
Goa; Esteem 026019 |
Approved |
Most recent IF: 2.561; 2010 IF: 1.825 |
| Call Number |
UA @ lucian @ c:irua:79444 |
Serial |
29 |
| Permanent link to this record |
