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Author Schalm, O.; Proost, K.; De Vis, K.; Cagno, S.; Janssens, K.; Mees, F.; Jacobs, P.; Caen, J.
Title Manganese staining of archaeological glass : the characterization of Mn-rich inclusions in leached layers and a hypothesis of its formation Type A1 Journal article
Year 2011 Publication Archaeometry Abbreviated Journal Archaeometry
Volume 53 Issue 1 Pages 103-122
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract During the study of a large number of archaeological glass fragments, manganese-rich inclusions in leached layers were observed in a limited number of cases. This phenomenon occurs only in black-coloured leached layers. Since the formation mechanism of such manganese-rich inclusions is still unclear, a combination of several analytical techniques was used in order to investigate this phenomenon and, more specifically, to obtain more information on (a) the composition and morphology of the inclusions, (b) the chemical state of Mn and (c) the 3D morphology of the inclusions. A mechanism that might explain the formation of these inclusions is proposed.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000285418100006 Publication Date 2010-07-22
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-813x; 1475-4754 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.47 Times cited 24 Open Access
Notes ; ; Approved Most recent IF: 1.47; 2011 IF: 1.183
Call Number (up) UA @ admin @ c:irua:88754 Serial 5704
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Author Meulebroeck, W.; Cosyns, P.; Baert, K.; Wouters, H.; Cagno, S.; Janssens, K.; Terryn, H.; Nys, K.; Thienpont, H.
Title Optical spectroscopy as a rapid and low-cost tool for the first-line analysis of glass artefacts : a step-by-step plan for Roman green glass Type A1 Journal article
Year 2011 Publication Journal of archaeological science Abbreviated Journal J Archaeol Sci
Volume 38 Issue 9 Pages 2387-2398
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Archaeometric research on glass artefacts is continuously evolving and is converging towards a multidisciplinary research domain where different types of techniques are applied depending on the questions asked and the circumstances involved. The technique described in this work is optical spectroscopy. The benefit of this technique being the possibility of building up a knowledge database for a large amount of material in a relatively short period of time and with a relatively limited budget. This is of particular interest for the investigation of extensive and/or unexplored glass collections where a first-line analysis of artefacts could facilitate the selection of material needing further and more detailed examination. This publication explores the extent to which optical spectroscopy can be used for a first-line analysis of green coloured glass artefacts from the Roman period. It is shown that the colour coordinates calculated from the measured transmission spectrum could reveal information about the fragment under study. In particular it is shown that 1) based on the position of the calculated colour values on the colour diagram (CIE1931) one could easily know whether the artefact was coloured using only iron or if copper oxides were also present. In the case of the artefact owing its colour solely to the presence of iron, the distance between the measured colour values and the colour diagrams white point can roughly indicate the iron concentration of the sample; 2) artefacts that were fabricated under similar furnace conditions can also be identified on the colour diagram; 3) samples with identical compositions and fabrication conditions but with different sample thickness, gave rise to a variation in the colour coordinates, thus allowing optical spectroscopy to help identify fragments which might belong to the same object.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000293551200037 Publication Date 2011-05-12
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0305-4403 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.602 Times cited 18 Open Access
Notes ; The authors would like to express their gratitude to the Vrije Universiteit Brussel for funding this research in the framework of HOA15, a “Horizontal Research Action” which encourages collaboration between research groups from different departments within the same University having expertise in specific research disciplines and also to the OZR-project 1247 BOF. The authors are also very grateful to the following persons for having permitted the study of their material: Rica Annaert and Sofie Vanhoutte of the “Vlaams lnstituut voor Onroerend Erfgoed (VIOE): Grobbendonk, Matagne-la-Petite, Oudenburg; Jean-Louis Antoine of the Musee Archeologique Namur: Nismes; Tom Debruyne of the ”Erfgoedcel“ Tienen: Tienen: Marc Rogge and Kurt Braeckman of the ”Provinciaal Archeologisch Museum (PAM)": Kruishoutem, Velzeke; Walter Sevenants: Rumst and Anne de Pyre-Gysel from the Musee Romain d'Avenches: Avenches. ; Approved Most recent IF: 2.602; 2011 IF: 1.914
Call Number (up) UA @ admin @ c:irua:92389 Serial 5756
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Author Cagno, S.; Nuyts, G.; Bugani, S.; De Vis, K.; Schalm, O.; Caen, J.; Helfen, L.; Cotte, M.; Reischig, P.; Janssens, K.
Title Evaluation of manganese-bodies removal in historical stained glass windows via SR-\mu-XANES/XRF and SR-\mu-CT Type A1 Journal article
Year 2011 Publication Journal of analytical atomic spectrometry Abbreviated Journal J Anal Atom Spectrom
Volume 26 Issue 12 Pages 2442-2451
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The speed and effectiveness of a conservation treatment used for stained glass windows have been investigated. Dark-coloured Mn-rich stains can be found in the alteration layer of ancient glass artefacts and cause the surface to turn brown/black: this phenomenon is known as Mn-browning or Mn-staining. While in glass manganese is present in the +II or +III oxidation states, in the Mn-rich bodies, manganese is in a higher oxidation state (+IV). In restoration practice, mildly reducing solutions are employed to eliminate the dark colour and restore the clear appearance of the glass. In this paper the effectiveness and side effects of the use of hydroxylamine hydrochloride for this purpose are assessed. Archaeological fragments of stained glass windows, dated to the 14th century and originating from Sidney Sussex College, Cambridge (UK), were examined by means of synchrotron radiation (SR) based microscopic X-ray Absorption Near-Edge Spectroscopy (μ-XANES) and microscopic X-Ray Fluorescence (μ-XRF) and with high resolution computed absorption tomography (μ-CT) before, during and after the treatment. The monitoring of the glass fragments during the treatment allows us to better understand the manner in which the process unfolds and its kinetics. The results obtained reveal that the hydroxylamine hydrochloride treatment is effective, but also that it has a number of unwanted side effects. These findings are useful for optimizing the time and other modalities of the Mn-reducing treatment as well as minimizing its unwanted results.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000297030400009 Publication Date 2011-10-11
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0267-9477 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.379 Times cited 17 Open Access
Notes ; This research was supported by the Interuniversity Attraction Poles Programme-Belgian Science Policy (IUAP VI/16). The text also presents results of GOA “XANES meets ELNES” (Research Fund University of Antwerp, Belgium) and from FWO (Brussels, Belgium) projects no. G.0704.08 and G.01769.09. Special thanks to Ms Leonie Seliger, head of the stained-glass conservation studio (The Cathedral Studios-The Chapter of Canterbury Cathedral) for the supply of the archaeological samples. The authors gratefully acknowledge ESRF for granting beamtime (proposal EC-602). ; Approved Most recent IF: 3.379; 2011 IF: 3.220
Call Number (up) UA @ admin @ c:irua:93848 Serial 5613
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Author Bugani, S.; Modugno, F.; Lucejko, J.J.; Giachi, G.; Cagno, S.; Cloetens, P.; Janssens, K.; Morselli, L.
Title Study on the impregnation of archaeological waterlogged wood with consolidation treatments using synchrotron radiation microtomography Type A1 Journal article
Year 2009 Publication Analytical and bioanalytical chemistry Abbreviated Journal Anal Bioanal Chem
Volume 395 Issue 7 Pages 1977-1985
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract In favourable conditions of low temperature and low oxygen concentration, archaeological waterlogged wooden artefacts, such as shipwrecks, can survive with a good state of preservation. Nevertheless, anaerobic bacteria can considerably degrade waterlogged wooden objects with a significant loss in polysaccharidic components. Due to these decay processes, wood porosity and water content increase under ageing. In such conditions, the conservation treatments of archaeological wooden artefacts often involve the replacement of water with substances which fill the cavities and help to prevent collapse and stress during drying. The treatments are very often expensive and technically difficult, and their effectiveness very much depends on the chemical and physical characteristics of the substances used for impregnation. Also important are the degree of cavity-filling, penetration depth and distribution in the structure of the wood. In this study, the distribution in wood cavities of some mixtures based on polyethylene glycols and colophony, used for the conservation of waterlogged archaeological wood, was investigated using synchrotron radiation X-ray computed microtomography (SR-A mu CT). This non-destructive imaging technique was useful for the study of the degraded waterlogged wood and enabled us to visualise the morphology of the wood and the distribution of the materials used in the wood treatments. The study has shown how deposition is strictly related to the dimension of the wooden cavities. The work is currently proceeding with the comparison of synchrotron observations with the data of the solutions viscosity and with those of the properties imparted to the wood by the treatments.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000272017000005 Publication Date 2009-09-16
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1618-2642 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.431 Times cited 30 Open Access
Notes Approved Most recent IF: 3.431; 2009 IF: 3.480
Call Number (up) UA @ admin @ c:irua:94493 Serial 5853
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Author van der Linden, V.; Cosyns, P.; Schalm, O.; Cagno, S.; Nys, K.; Janssens, K.; Nowak, A.; Wagner, B.; Bulska, E.
Title Deeply coloured and black glass in the Northern provinces of the Roman Empire : differences and similarities in chemical composition before and after AD 150 Type A1 Journal article
Year 2009 Publication Archaeometry Abbreviated Journal Archaeometry
Volume 51 Issue 5 Pages 822-844
Keywords A1 Journal article; History; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract In this work we attempt to elucidate the chronological and geographical origin of deeply coloured and black glass dating between 100 bc and ad 300 on the basis of their major and trace element compositions. Samples from the western and eastern parts of the Roman Empire were analysed. Analytical data were obtained by means of a scanning electron microscope – energy-dispersive system (SEM-EDS, 63 samples analysed) and laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS, 41 samples analysed). Among the glass fragments analysed, dark brown, dark purple and dark green hues could be distinguished. Only among the dark green fragments could a clear compositional distinction be observed between fragments dated to the periods before and after ad 150. In the early samples (first century bc to first century ad), iron, responsible for the green hue, was introduced by using impure sand containing relatively high amounts of Ti. In contrast, a Ti-poor source of iron was employed, containing Sb, Co and Pb in trace quantities, in order to obtain the dark green colour in the later glass samples. The analytical results obtained by combining SEM-EDS and LA-ICP-MS are therefore consistent with a differentiation of glassmaking recipes, detectable in glass composition, occurring in the period around ad 150.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000269728600009 Publication Date 2008-11-27
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-813x; 1475-4754 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.47 Times cited 39 Open Access
Notes Approved Most recent IF: 1.47; 2009 IF: 1.355
Call Number (up) UA @ admin @ c:irua:94510 Serial 5568
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Author Cagno, S.
Title Compositional analysis of historical glass Type Doctoral thesis
Year 2012 Publication Abbreviated Journal
Volume Issue Pages 346 p.
Keywords Doctoral thesis; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number (up) UA @ admin @ c:irua:98145 Serial 7714
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Author Cagno, S.; Favaretto, L.; Mendera, M.; Izmer, A.; Vanhaecke, F.; Janssens, K.
Title Evidence of early medieval soda ash glass in the archaeological site of San Genesio (Tuscany) Type A1 Journal article
Year 2012 Publication Journal of archaeological science Abbreviated Journal J Archaeol Sci
Volume 39 Issue 5 Pages 1540-1552
Keywords A1 Journal article; Philosophy; History; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The early medieval period marks an important turning point in the history of glassmaking, since it comprises the transition period between the mineral-based silica-soda-lime glass of the Roman tradition and the plant ash-based glass. With the aim of expanding the knowledge on the glass recipes and technologies of this period, 37 glass samples were analyzed, originating from the archaeological excavations of San Genesio (Tuscany) and dated from the fourth to the eleventh century. The major and minor element concentrations were measured with SEM-EDX, while the trace elements were quantified with LA-ICP-MS. The results were compared with published compositions of glass samples of similar age in order to highlight differences and similarities. The results offer a very interesting view on the glass circulation in the religious/residential/manufacturing center of San Genesio in the early medieval period. Most of the glass has a typical late-Roman composition, but some glass fragments are identified as soda ash glass. These are among the earliest medieval ash-fluxed glasses ever found in the Italian peninsula. (C) 2011 Elsevier Ltd. All rights reserved.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000301620900034 Publication Date 2012-01-02
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0305-4403 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.602 Times cited 24 Open Access
Notes ; This research was supported by the Interuniversity Attraction Poles Programme – Belgian Science Policy (IUAP VI/16). The text also presents results of GOA “XANES meets ELNES” (Research Fund University of Antwerp, Belgium) and from FWO (Brussels, Belgium) projects no. G.0704.08 and G.01769.09. ; Approved Most recent IF: 2.602; 2012 IF: 1.889
Call Number (up) UA @ admin @ c:irua:98251 Serial 5618
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