|   | 
Details
   web
Records
Author (up) Smets, B.; Boschker, H.T.S.; Wetherington, M.T.; Lelong, G.; Hidalgo-Martinez, S.; Polerecky, L.; Nuyts, G.; De Wael, K.; Meysman, F.J.R.
Title Multi-wavelength Raman microscopy of nickel-based electron transport in cable bacteria Type A1 Journal article
Year 2024 Publication Frontiers in microbiology Abbreviated Journal
Volume 15 Issue Pages 1208033-16
Keywords A1 Journal article
Abstract Cable bacteria embed a network of conductive protein fibers in their cell envelope that efficiently guides electron transport over distances spanning up to several centimeters. This form of long-distance electron transport is unique in biology and is mediated by a metalloprotein with a sulfur-coordinated nickel (Ni) cofactor. However, the molecular structure of this cofactor remains presently unknown. Here, we applied multi-wavelength Raman microscopy to identify cell compounds linked to the unique cable bacterium physiology, combined with stable isotope labeling, and orientation-dependent and ultralow-frequency Raman microscopy to gain insight into the structure and organization of this novel Ni-cofactor. Raman spectra of native cable bacterium filaments reveal vibrational modes originating from cytochromes, polyphosphate granules, proteins, as well as the Ni-cofactor. After selective extraction of the conductive fiber network from the cell envelope, the Raman spectrum becomes simpler, and primarily retains vibrational modes associated with the Ni-cofactor. These Ni-cofactor modes exhibit intense Raman scattering as well as a strong orientation-dependent response. The signal intensity is particularly elevated when the polarization of incident laser light is parallel to the direction of the conductive fibers. This orientation dependence allows to selectively identify the modes that are associated with the Ni-cofactor. We identified 13 such modes, some of which display strong Raman signals across the entire range of applied wavelengths (405–1,064 nm). Assignment of vibrational modes, supported by stable isotope labeling, suggest that the structure of the Ni-cofactor shares a resemblance with that of nickel bis(1,2-dithiolene) complexes. Overall, our results indicate that cable bacteria have evolved a unique cofactor structure that does not resemble any of the known Ni-cofactors in biology.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 001189511900001 Publication Date 2024-03-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1664-302x ISBN Additional Links UA library record; WoS full record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:205115 Serial 9214
Permanent link to this record
 

 
Author (up) Smets, W.; Moretti, S.; Denys, S.; Lebeer, S.
Title Airborne bacteria in the atmosphere : presence, purpose, and potential Type A1 Journal article
Year 2016 Publication Atmospheric environment : an international journal Abbreviated Journal
Volume 139 Issue Pages 214-221
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract Numerous recent studies have highlighted that the types of bacteria present in the atmosphere often show predictable patterns across space and time. These patterns can be driven by differences in bacterial sources of the atmosphere and a wide range of environmental factors, including UV intensity, precipitation events, and humidity. The abundance of certain bacterial taxa is of interest, not only for their ability to mediate a range of chemical and physical processes in the atmosphere, such as cloud formation and ice nucleation, but also for their implications -both beneficial and detrimental-for human health. Consequently, the widespread importance of airborne bacteria has stimulated the search for their applicability. Improving air quality, modelling the dispersal of airborne bacteria (e.g. pathogens) and biotechnological purposes are already being explored. Nevertheless, many technological challenges still need to be overcome to fully understand the roles of airborne bacteria in our health and global ecosystems.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000379093900021 Publication Date 2016-05-24
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1352-2310 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:133711 Serial 7432
Permanent link to this record
 

 
Author (up) Smets, W.; Wuyts, K.; Oerlemans, E.; Wuyts, S.; Denys, S.; Samson, R.; Lebeer, S.
Title Impact of urban land use on the bacterial phyllosphere of ivy (Hedera sp.) Type A1 Journal article
Year 2016 Publication Atmospheric environment : an international journal Abbreviated Journal
Volume 147 Issue Pages 376-383
Keywords A1 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract The surface of the aerial parts of the plant, also termed the phyllosphere, is a selective habitat for microbes. The bacterial composition of the phyllosphere depends on host plant species, leaf characteristics, season, climate, and geographic location of the host plant. In this study, we investigated the effect of an urban environment on the bacterial composition of phyllosphere communities. We performed a passive biomonitoring experiment in which leaves were sampled from ivy (Hedera sp.), a common evergreen climber species, in urban and non-urban locations. Exposure to traffic-generated particulate matter was estimated using leaf biomagnetic analyses. The bacterial community composition was determined using 16S rRNA gene sequencing on the Illumina MiSeq. The phyllosphere microbial communities of ivy differed greatly between urban and non-urban locations, as we observed a shift in several of the dominant taxa: Beijerinckia and Methylocystaceae were most abundant in the non-urban phyllosphere, whereas Hymenobacter and Sphingomonadaceae were dominating the urban ivy phyllosphere. The richness, diversity and composition of the communities showed greater variability in the urban than in the non-urban locations, where traffic-generated PM was lower. Interestingly, the relative abundances of eight of the ten most dominant taxa correlated well with leaf magnetism, be it positive or negative. The results of this study indicate that an urban environment can greatly affect the local phyllosphere community composition. Although other urban-related factors cannot be ruled out, the relative abundance of most of the dominant taxa was significantly correlated with exposure to traffic-generated PM.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000388543600033 Publication Date 2016-10-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1352-2310 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:136110 Serial 8066
Permanent link to this record
 

 
Author (up) Šmit, Ž.; Janssens, K.; Schalm, O.; Kos, M.
Title Analysis of façon-de-Venise glass originating from Central and Western Europe Type H3 Book chapter
Year 2005 Publication Abbreviated Journal
Volume Issue Pages 165-176
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:52705 Serial 5467
Permanent link to this record
 

 
Author (up) Smits, J.; Nelissen, J.; Van Grieken, R.
Title Comparison of preconcentration procedures for trace metals in natural waters Type A1 Journal article
Year 1979 Publication Analytica chimica acta Abbreviated Journal
Volume 111 Issue Pages 215-226
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The relative merits of eight procedures for preconcentrations of trace metal ions from natural water samples and synthetic solutions are evaluated. Spikes (100 μg l−1 ) of Mn, Co, Zn, Eu, Cs and Ba and the corresponding radioactive tracers were added to batches of drinking water, estuarine water, sea water, ground water, twice-distilled water and ahumic material solution. After equilibration for 25 months, the following techniques were applied: passage through columns of Dowex Al chelating resin and ofsilylated silica gel, filtration through laminate membrane filters and chelating diethylenetriamine cellulose filters, precipitation with sodium diethyldithiocarbamate and l-(2-pyridylazo)-2-naphthol, extraction with ammonium pyrrolidinedithiocarbamate, and chelation by 8-quinolinol (oxine) followed by adsorption on activated carbon. The quantitative characteristics of these techniques and the influence of the water matrix effects are discussed, as well as the applicability for x-ray fluorescence analysis.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1979HX09300018 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116369 Serial 7695
Permanent link to this record
 

 
Author (up) Smits, J.; Van Grieken, R.
Title Chelating 2,2′-diaminodiethylamine cellulose filters and X-ray fluorescence for preconcentration and trace analysis of natural waters Type A1 Journal article
Year 1981 Publication International journal of environmental analytical chemistry Abbreviated Journal
Volume 9 Issue 2 Pages 81-92
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The 2,2′-diaminodiethylamine (DEN) functional group can be expected to have ideal properties for the chelation of transition metals and their collection from aqueous solutions, independent of the alkali and alkaline earth ions concentration. Introducing DEN into cellulose filters allows straightforward preconcentration of trace cations by a simple filtration step, and the DEN-filter constitutes a suitable target for X-ray fluorescence (XRF) analysis. The linearity between the XRF-response on the loaded DEN-filter and the trace cation concentration in the solution appears excellent, up to a total filter capacity of ca. 3 μeq.cm−2. The detection limits are around 0.5 μg. l−1 in most practical cases. Accuracy and precision are around 10%. The applicability of the proposed procedure is illustrated on a comparative basis by XRF-analysis of drinking water and surface water, after preconcentration by DEN-filtration and by alternative procedures.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1981LF48000001 Publication Date 2007-07-07
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0306-7319 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116571 Serial 7638
Permanent link to this record
 

 
Author (up) Smits, J.; Van Grieken, R.
Title Enrichment of trace anions from water with 2,2'-diaminodiethylamine cellulose filters Type A1 Journal article
Year 1981 Publication Analytica chimica acta Abbreviated Journal
Volume 123 Issue Pages 9-17
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Cellulose filters with immobilized 2,2'-diaminodiethylamine (DEN) functional groups are studied for trace anion preconcentration from aqueous solution, with subsequent x-ray fluorescence measurements. For most oxoanions with a central metal atom, nearly quantitative collection can be achieved by 10-cm2 DEN filters under the following optimized conditions: pH 36, filtration rate up to 0.5 ml cm-2 min-1, and sample volume up to 100 ml cm-2. The collection yield is independent of the trace oxoanion concentration up to at least 1.5 μmol cm-2. Although the DEN filter exhibits some selectivity towards oxoanions with a central metal atom, ionic strength affects the results; the collection efficiency is strongly depressed with salt (e.g. NaCl) concentrations above 0.01 M. The applicability of the DEN filter in anion collection is therefore limited to dilute solutions.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1981LA22400002 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116437 Serial 7922
Permanent link to this record
 

 
Author (up) Smits, J.; Van Grieken, R.
Title Optimization of a simple spotting procedure for x-ray fluorescence analysis of waters Type A1 Journal article
Year 1977 Publication Analytica chimica acta Abbreviated Journal
Volume 88 Issue 1 Pages 97-107
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Several sample preparation methods for waters for energy-dispersive x.r.f. were examined, as well as the influence of sample size on the analytical characteristics. The most satisfactory simple, rapid method proved to be spotting of 1.5 ml of water sample on a Whatman-41 cellulose filter paper provided with a wax ring of 29-mm diameter and evaporating the water with an unheated air stream from underneath. Sensitivities are below 100 p.p.b. for most elements and often below 50 p.p.b. when the optimal secondary fluorescer is used. Accuracy and precision are usually in the 1520 % range. The method is applicable to many dilute aqueous solutions as is illustrated by analysis of industrial water samples and ashed biological material.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1977CQ82600011 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116367 Serial 8337
Permanent link to this record
 

 
Author (up) Smits, J.; Van Grieken, R.
Title Synthesis of a chelating cellulose filter with 2,2-diaminodiethylamine functional groups Type A3 Journal article
Year 1978 Publication Zeitschrift für angewandte Makromolekare Chemie Abbreviated Journal
Volume 72 Issue Pages 105-113
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116644 Serial 8637
Permanent link to this record
 

 
Author (up) Smits, J.A.; Van Grieken, R.E.
Title Characterization of a 2,2'-diaminodiethylamine-cellulose filter toward metal cation extraction Type A1 Journal article
Year 1980 Publication Analytical chemistry Abbreviated Journal
Volume 52 Issue 9 Pages 1479-1489
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1980KB79500027 Publication Date 2005-03-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:116515 Serial 7610
Permanent link to this record
 

 
Author (up) Smits, M.
Title Photocatalytic degradation of diesel soot : from application to reaction mechanism Type Doctoral thesis
Year 2013 Publication Abbreviated Journal
Volume Issue Pages 160 p.
Keywords Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 978-90-5728-415-1 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:108803 Serial 8380
Permanent link to this record
 

 
Author (up) Smits, M.; Tytgat, T.; Hauchecorne, B.; Lenaerts, S.
Title Development and validation of optical detection methods to screen photocatalytic materials for soot oxidation Type P3 Proceeding
Year 2012 Publication Abbreviated Journal
Volume Issue Pages
Keywords P3 Proceeding; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 978-989-97667-4-7 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:98814 Serial 5941
Permanent link to this record
 

 
Author (up) Smits, M.; Vanpachtenbeke, F.; Hauchecorne, B.; van Langenhove, H.; Demeestere, K.; Lenaerts, S.
Title Exhaust composition of a small diesel engine Type A2 Journal article
Year 2012 Publication Communications in agricultural and applied biological sciences Abbreviated Journal
Volume 77 Issue 1 Pages 85-88
Keywords A2 Journal article; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1379-1176 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:94166 Serial 5949
Permanent link to this record
 

 
Author (up) Smondyrev, M.A.; Peeters, F.M.; Vansant, P.; Devreese, J.T.
Title Exact equations for large bipolarons in the strong-coupling limit Type A1 Journal article
Year 1994 Publication Journal of physics: A: mathematical and general Abbreviated Journal
Volume 27 Issue Pages 7925-7936
Keywords A1 Journal article; Condensed Matter Theory (CMT); Theory of quantum systems and complex systems
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication London Editor
Language Wos A1994PW35300035 Publication Date 0000-00-00
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0305-4470 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited 17 Open Access
Notes Approved no
Call Number UA @ lucian @ c:irua:9276 Serial 1106
Permanent link to this record
 

 
Author (up) Smondyrev, M.A.; Vansant, P.; Peeters, F.M.; Devreese, J.T.
Title Nonlinear Schrödinger equation on a ring Type A3 Journal article
Year 1994 Publication JINR communications Abbreviated Journal
Volume Issue Pages
Keywords A3 Journal article; Condensed Matter Theory (CMT); Theory of quantum systems and complex systems
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 0000-00-00
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved PHYSICS, APPLIED 47/145 Q2 #
Call Number UA @ lucian @ c:irua:9279 Serial 2357
Permanent link to this record
 

 
Author (up) Snoeckx, R.
Title Plasma technology : a novel solution for CO2 conversion? Type Doctoral thesis
Year 2017 Publication Abbreviated Journal
Volume Issue Pages
Keywords Doctoral thesis; Engineering sciences. Technology; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Antwerpen Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ lucian @ c:irua:143110 Serial 4680
Permanent link to this record
 

 
Author (up) Soltani, S.; Azadi, H.; Hosseini, S.J.F.; Witlox, F.; Van Passel, S.
Title Marketing innovation in rural small food industries in Iran Type A1 Journal article
Year 2015 Publication Journal of food products marketing Abbreviated Journal
Volume 21 Issue 5 Pages 533-551
Keywords A1 Journal article; Economics; Engineering Management (ENM); Government and Law
Abstract Marketing innovation is essential for small industries to transform products into profit; therefore, understanding its nature and determinants is of utmost importance. This study aimed at understanding marketing innovation and its determinants in the 60 small food industries in the rural areas of Tehran province, Iran. Using a census sampling method, 111 managers of these firms were interviewed. Results showed that the firms performance in marketing innovation is generally weak, and a higher level of radical innovation in marketing is perceived compared to the incremental innovation. Also, a cause-and-effect relationship exists between both product and organizational innovations and marketing innovation. Furthermore, while incremental marketing innovation was negatively influenced by formal R&D unit, product diversification, and the managers years of experience, radical marketing innovation was affected by the capacity of production, product diversification, and managers age and education. The study concluded that in order to boost marketing innovation, innovation should be made also in products and organization. In addition, in order to facilitate the process of marketing innovation, practical and updated training for managers encouraging incremental innovation in marketing, product diversification, and improving R&D activities in the studied firms should be regarded.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date 2015-09-01
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1045-4446 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:130144 Serial 6225
Permanent link to this record
 

 
Author (up) Somogyi, A.; Drakopoulos, M.; Vekemans, B.; Vincze, L.; Simionovici, A.S.; Adams, F.
Title Effects of beamline components (undulators, monochromator, focusing devices) on the beam intensity at ID18F (ESRF) Type A1 Journal article
Year 2003 Publication Nuclear instruments and methods: B Abbreviated Journal
Volume 199 Issue Pages 559-564
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000180925400107 Publication Date 2003-02-17
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:40711 Serial 7846
Permanent link to this record
 

 
Author (up) Somogyi, A.; Drakopoulos, M.; Vincze, L.; Vekemans, B.; Camerani, C.; Janssens, K.; Snigirev, A.; Adams, F.
Title ID18F: a new X-ray microprobe end station Type A3 Journal article
Year 2002 Publication ESRF highlights 2001 Abbreviated Journal
Volume Issue Pages 96-97
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:38376 Serial 5646
Permanent link to this record
 

 
Author (up) Sóti, V.
Title Catalytic detoxification of lignocellulose hydrolyzate Type Doctoral thesis
Year 2019 Publication Abbreviated Journal
Volume Issue Pages XXVII, 243 p.
Keywords Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL); Biochemical Wastewater Valorization & Engineering (BioWaVE)
Abstract The present PhD research investigated the possibility of catalytic detoxification of poplar wood based and steam exploded lignocellulosic hydrolyzate with different types of laccase enzymes, with special focus on ethanol and lactic acid products at industrially relevant parameters: high final product concentration, high initial substrate loading and integrated processes. The simultaneous saccharification and fermentation (SSF) process was taken as a base case and five types of laccases were thoroughly investigated on their utilization potential. Phenolic removal from the liquid xylose rich fraction (XRF) was higher with fungal laccases (65-90 %) compared to approximately 30 % removal with bacterial laccase. Moreover, the optimal pH of fungal laccases was close to pH 4.5, the optimum for cellulase, while the bacterial laccase worked at basic pH. Integrating laccase treatment and hydrolysis together showed that fungal laccases have negative impact on final sugar concentration, while bacterial laccase had a strong positive effect. Although bacterial laccase removed less phenol and although its optimal conditions are difficult to integrate with hydrolysis, its enhancing effect on cellulase activity makes it a better candidate for application. The presence of the solid fraction (SF) alters the phenolic concentration evolution significantly, thus screening experiments with the liquid fraction alone do not provide sufficient information for the combined process. Magnetic Cross-Linked Enzyme Aggregates (m-CLEAs) immobilization was assessed for bacterial laccase. m-CLEAs decreased phenolic concentration faster at every pH compared to free bacterial laccase; however, the removal was caused by adsorption rather than by enzyme activity. Although the size of m-CLEAs particles are in the µm range, around 90 % of the initial catalyst mass was recycled from a dense (15 % substrate loading) mixture via magnetic separation. The high recycling rate is promising; m-CLEAs immobilization method can have industrial utilization potential. Minimum sugar revenue (MSR) estimations show that currently hardwood based MSR is 70 % more expensive than corn grain based MSR. About 7-10 fold cellulase activity increase will be needed until MSR will be competitive with corn grain MSR. However, m-CLEAs cellulase can already be competitive if the corn prices are in the higher regime of last year’s prices.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:180125 Serial 7584
Permanent link to this record
 

 
Author (up) Spanoghe, J.
Title Purple bacteria cultivation on light, carbon dioxide and hydrogen gas : exploring and tuning the potential for microbial food production Type Doctoral thesis
Year 2022 Publication Abbreviated Journal
Volume Issue Pages vi, 207 p.
Keywords Doctoral thesis; Engineering sciences. Technology; Sustainable Energy, Air and Water Technology (DuEL)
Abstract The human population is projected to grow to 9.7 billion by 2050, resulting in an estimated increase in protein demand of 50%. From an environmental perspective, the current and future demand of protein cannot be sustainably met as the conventional food production chain is severely altering biogeochemical cycles of nitrogen and phosphorus, biodiversity and land-use, with flows towards the biosphere and oceans that are exceeding the planetary boundaries. Microbial protein (protein derived from microorganisms) has been suggested as an excellent sustainable protein source, a fortiori when produced in a land- and fossil free manner. The photoautohydrogenotrophic cultivation (i.e. with light, CO2 and H2) of purple bacteria links up perfectly with the upcoming green electrification of industry (green H2) and the need for carbon capture and utilization. However, this metabolism represented a gap in literature, and thus this thesis aimed to establish a basic knowledge platform on its kinetic, stoichiometric and nutritional performance. At first, three originally photoheterotrophically enriched purple bacteria were studied of which Rhodobacter capsulatus reached the highest protein productivity of 0.16 g protein/L/d, which aligned well with the commonly-known photoautotrophic microalgae. Moreover, a full dietary essential amino acid match was found for human food, while the fatty acid content was dominated by the health-stimulating vaccenic acid (82-86%). Lastly, the achieved protein yield in photoautohydrogenotrophic purple bacteria was 2.3 times higher compared to hydrogen oxidizing bacteria, indicating a resource-efficient use of H2. Next, a photoautohydrogenotrophic enrichment of wastewater treatment microbiomes was performed in search for specialist species. While the isolates of this enrichment showed improvements in their performance during acclimation, the kinetic and nutritional performance of Rhodobacter capsulatus still excelled. Subsequently, the influence of nutrient limitations (C or N) and nitrogen gas fixation was studied on the nutritional tuning potential. Both the limitations as well as the N2 fixation resulted in the shift of the essential amino acid profiles. Additionally, the limitations significantly decreased the pigment content, while an increase in the storage of poly-P was seen in case of carbon limitations. The next major challenge was the production intensification in a photobioreactor of which the design was linked to minimizing both H2 and light limitations. The chosen bubble-column photobioreactor already resulted in a doubled biomass productivity. Finally, the remaining technological and non-technological challenges ahead for the production of a high-value, cost-efficient, environment-friendly microbial protein that complies with legislative requirements and appeals to future consumers were discussed.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 978-90-5728-741-1 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:188233 Serial 7198
Permanent link to this record
 

 
Author (up) Spiller, M.
Title Measuring adaptive capacity of urban wastewater infrastructure : change impact and change propagation Type A1 Journal article
Year 2017 Publication The science of the total environment Abbreviated Journal
Volume 601-602 Issue Pages 571-579
Keywords A1 Journal article; Sustainable Energy, Air and Water Technology (DuEL)
Abstract The ability of urban wastewater systems to adapt and transform as a response to change is an integral part of sustainable development. This requires technology and infrastructure that can be adapted to new operational challenges. In this study the adaptive capacity of urban wastewater systems is evaluated by assessing the interdependencies between system components. In interdependent and therefore tightly coupled systems, changes to one systems component will require alteration elsewhere in the system, therefore impairing the capacity of these systems to be changed. The aim of this paper is to develop a methodology to evaluate the adaptive capacity of urban wastewater systems by assessing how change drivers and innovation affect existing wastewater technology and infrastructure. The methodology comprises 7 steps and applies a change impact table and a design structure matrix that are completed by experts during workshops. Change impact tables quantify where change drivers, such as energy neutrality and resource recovery, require innovation in a system. The design structure matrix is a tool to quantify emerging changes that are a result of the innovation. The method is applied for the change driver of energy neutrality and shown for two innovations: a decentralised upflow anaerobic sludge blanket reactor followed by an anammox process and a conventional activated sludge treatment with enhanced chemical precipitation and high temperature-high pressure hydrolysis. The results show that the energy neutrality of wastewater systems can be address by either innovation in the decentralised or centralised treatment. The quantification of the emerging changes for both innovations indicates that the decentralised treatment is more disruptive, or in other words, the system needs to undergo more adaptation. It is concluded that the change impact and change propagation method can be used to characterise and quantify the technological or infrastructural transformations. In addition, it provides insight into the stakeholders affected by change.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000406294900057 Publication Date 2017-05-31
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0048-9697; 1879-1026 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:143926 Serial 8212
Permanent link to this record
 

 
Author (up) Spolnik, Z.; Belikov, K.; van Meel, K.; Adriaenssens, E.; de Roeck, F.; Van Grieken, R.
Title Optimization of measurement conditions of an energy dispersive X-ray fluorescence spectrometer with high-energy polarized beam excitation for analysis of aerosol filters Type A1 Journal article
Year 2005 Publication Applied spectroscopy Abbreviated Journal
Volume 59 Issue 12 Pages 1465-1469
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000234187500004 Publication Date 2005-12-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-7028 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:55835 Serial 8339
Permanent link to this record
 

 
Author (up) Spolnik, Z.; Bencs, L.; Worobiec, A.; Kontozova, V.; Van Grieken, R.
Title Application of EDXRF and thin window EPMA for the investigation of the influence of hot air heating on the generation and deposition of particulate matter Type A1 Journal article
Year 2005 Publication Microchimica acta Abbreviated Journal
Volume 149 Issue Pages 79-85
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000226408200010 Publication Date 2005-01-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:51258 Serial 7471
Permanent link to this record
 

 
Author (up) Spolnik, Z.; Osán, J.; Klepka, M.; Lawniczak-Jablonska, K.; Van Grieken, R.; Molak, A.; Potgieter, J.H.
Title Investigation of the chemical composition of (Na1-xBix)(MnyNb1-y)O3 ceramics by single particle electron probe X-ray microanalysis with an application of Monte Carlo simulations Type A1 Journal article
Year 2005 Publication Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 60 Issue 4 Pages 525-530
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000229955200012 Publication Date 2005-04-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:52668 Serial 8128
Permanent link to this record
 

 
Author (up) Spolnik, Z.; Tsuji, K.; Van Grieken, R.
Title Grazing-exit electron probe x-ray microanalysis of light elements in particles Type A1 Journal article
Year 2004 Publication X-ray spectrometry Abbreviated Journal
Volume 33 Issue Pages 16-20
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000188743100004 Publication Date 2004-01-21
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:43524 Serial 8009
Permanent link to this record
 

 
Author (up) Spolnik, Z.; Worobiec, A.; Injuk, J.; Neilen, D.; Schellen, H.; Van Grieken, R.
Title Chemical characterization of airborne particles in St. Martinus Cathedral in Weert, The Netherlands Type A1 Journal article
Year 2004 Publication Microchimica acta Abbreviated Journal
Volume 145 Issue Pages 223-227
Keywords A1 Journal article; Laboratory Experimental Medicine and Pediatrics (LEMP); AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000221453500037 Publication Date 2004-04-21
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:44334 Serial 7645
Permanent link to this record
 

 
Author (up) Spolnik, Z.; Worobiec, A.; Samek, L.; Bencs, L.; Belikov, K.; Van Grieken, R.
Title Influence of different types of heating systems on particulate air pollutant deposition: the case of churches situated in a cold climate Type A1 Journal article
Year 2007 Publication Journal of cultural heritage Abbreviated Journal
Volume 8 Issue 1 Pages 7-12
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000245779500002 Publication Date 2007-04-18
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1296-2074 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:63401 Serial 8090
Permanent link to this record
 

 
Author (up) Spolnik, Z.M.; Claes, M.; Van Grieken, R.
Title Determination of trace elements in organic matrices by grazing-emission X-ray fluorescence spectrometry Type A1 Journal article
Year 1999 Publication Analytica chimica acta Abbreviated Journal
Volume 401 Issue Pages 293-298
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000083981600037 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670; 1873-4324 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:27586 Serial 7792
Permanent link to this record
 

 
Author (up) Spolnik, Z.M.; Claes, M.; Van Grieken, R.E.; de Bokx, P.K.; Urbach, H.P.
Title Quantification in grazing-emission X-ray fluorescence spectrometry Type A1 Journal article
Year 1999 Publication Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 54 Issue Pages 1525-1537
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000083433600019 Publication Date 2002-08-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 1873-3565 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:27589 Serial 8432
Permanent link to this record