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Author Denecke, M.A.; Janssens, K.; Brendebach, B.; Falkenberg, G.; Römer, J.; Simon, R.; Vekemans, B.
Title Confocal μ-XRF and μ-XAFS studies on fractured granite following a radiotracer migration experiment Type P3 Proceeding
Year 2007 Publication Abbreviated Journal
Volume Issue Pages
Keywords P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:64602 Serial 5551
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Author Denecke, M.A.; Janssens, K.; Brendebach, B.; de Nolf, W.; Falkenberg, G.; Rothe, J.; Simon, R.; Somogyi, A.; Vekemans, B.; Noseck, U.
Title Confocal mu-XRF, mu-XAFS, and mu-XRD studies of sediment from a nuclear waste disposal natural analogue site and fractured granite following a radiotracer migration experiment Type A1 Journal article
Year 2007 Publication AIP conference proceedings Abbreviated Journal
Volume 882 Issue Pages 187-189
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Combined mu-XRF, mu-XAFS, and mu-XRD investigations of a uranium-rich tertiary sediment, from a nuclear repository natural analogue site, and a fractured granite bore core section after a column tracer experiment using a Np(V) containing cocktail have been performed. Most mu-XRF/mu-XAFS measurements are recorded in a confocal geometry to provide added depth information. The U-rich sediment results show uranium to be present as a tetravalent phosphate and that U(IV) is associated with As(V). Arsenic present is either As(V) or As(0). The As(0) form thin coatings on the surface of pyrite nodules. A hypothesis for the mechanism of uranium immobilization is proposed, where arsenopyrite acted as reductant of ground water dissolved U(VI) leading to precipitation of less soluble U(IV) and thereby forming As(V). Results for the granite sample show the immobilized Np to be tetravalent and associated with facture material.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0094-243x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:103614 Serial 5556
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Author Alfeld, M.; Vekemans, B.; Janssens, K.; Falkenberg, G.; Broekaert, J.A.C.; Gao, N.; Gibson, D.
Title Depth profiling of multilayered systems by means of confocal μ-XRF in the laboratory an at HASYLAB BL L: a comparison Type H3 Book chapter
Year 2007 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:64598 Serial 5572
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Author Terzano, R.; al Chami, Z.; Vekemans, B.; Janssens, K.; Miano, T.; Ruggiero, P.
Title Determination of Zn distribution inside edible plants grown on a polluted soil amended with compost by XRF microtomography Type H3 Book chapter
Year 2007 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:64593 Serial 5574
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Author Janssens, K.; Vekemans, B.; Rouchon-Quillet, V.
Title Estimation of relative Fe2+ and Fe3+ contents of original manuscript fragments by means of μ-XANES and Mössbauer spectrometry Type H3 Book chapter
Year 2005 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:50852 Serial 5607
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Author Janssens, K.; Vincze, L.; Vekemans, B.
Title Evaluation and calibration of micro-XRF data Type H3 Book chapter
Year 2000 Publication Abbreviated Journal
Volume Issue Pages 155-207
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:27726 Serial 5609
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Author Vincze, L.; Vekemans, B.; Janssens, K.; Adams, F.; Lippmann, T.
Title Evaluation of a Monte Carlo simulation for EDXRF spectrometers at beamline BW5, HASYLAB Type A3 Journal article
Year 1998 Publication HASYLAB Jahresbericht 1997 Abbreviated Journal
Volume 1 Issue Pages 1043-1044
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:22762 Serial 5610
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Author Vekemans, B.; Janssens, K.; Adams, F.; Andong, L.; He, Y.; Yiming, Y.
Title Evaluation of polycapillary lenses as focussing elements in sub-mm XRF analysis of artistic objects Type H3 Book chapter
Year 1998 Publication Abbreviated Journal
Volume Issue Pages 278-290
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume 41 Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:24652 Serial 5614
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Author Janssens, K.; Vincze, L.; Wei, F.; Proost, K.; Vekemans, B.; Vittiglio, G.; Yan, Y.; Falkenberg, G.
Title Feasibility of (trace-level) micro-XANES at Beamline L Type H3 Book chapter
Year 1999 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:28442 Serial 5622
Permanent link to this record
 

 
Author Vincze, L.; Vekemans, B.; Janssens, K.; Adams, F.; Haller, M.
Title Fluorescent tomography of metals in fly-ash particles at beamline L Type A3 Journal article
Year 1998 Publication HASYLAB Jahresbericht 1997 Abbreviated Journal
Volume 1 Issue Pages 959-960
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:22761 Serial 5624
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Author Vekemans, B.; Vincze, L.; Vittiglio, G.; Janssens, K.; Adams, F.
Title Fluorescent tomography of phantom samples at the beamline L Type A3 Journal article
Year 1999 Publication HASYLAB Jahresbericht Abbreviated Journal
Volume Issue Pages
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:28218 Serial 5625
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Author Vincze, L.; Vekemans, B.; Szalóki, I.; Janssens, K.; Van Grieken, R.; Feng, H.; Jones, K.W.; Adams, F.
Title High-resolution X-ray fluorescence micro-tomography on single sediment particles Type H1 Book chapter
Year 2002 Publication Abbreviated Journal
Volume Issue Pages 240-248
Keywords H1 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000175177400027 Publication Date 2003-11-19
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited 11 Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:39525 Serial 5643
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Author Somogyi, A.; Drakopoulos, M.; Vincze, L.; Vekemans, B.; Camerani, C.; Janssens, K.; Snigirev, A.; Adams, F.
Title ID18F: a new X-ray microprobe end station Type A3 Journal article
Year 2002 Publication ESRF highlights 2001 Abbreviated Journal
Volume Issue Pages 96-97
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:38376 Serial 5646
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Author Terzano, R.; Spagnuolo, M.; Ruggiero, P.; Vekemans, B.; de Nolf, W.; Janssens, K.; Fiore, S.; Falkenberg, G.
Title Identification of the geochemical forms of CR, Zn, Ni, Pb, V, and Cu in an industrial polluted soil by combined μ-XRF/μ-XRD and μ-XANES Type H3 Book chapter
Year 2008 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:64594 Serial 5651
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Author Kempenaers, L.; Vincze, L.; Vekemans, B.; Janssens, K.; Adams, F.; Somogyi, A.; Drakopoulos, M.; Simionovici, A.S.
Title Micro-heterogeneity study of trace elements in reference materials Type MA3 Book as author
Year 2004 Publication Abbreviated Journal
Volume Issue Pages 132 p.
Keywords MA3 Book as author; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:49217 Serial 5714
Permanent link to this record
 

 
Author Vincze, L.; Janssens, K.; Vekemans, B.; Adams, F.
Title Monte Carlo simulation for X-ray fluorescence spectroscopy Type H3 Book chapter
Year 2004 Publication Abbreviated Journal
Volume Issue Pages 435-461
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:45380 Serial 5735
Permanent link to this record
 

 
Author Vincze, L.; Janssens, K.; Vekemans, B.; Adams, F.
Title Monte Carlo simulation of X-ray fluorescence and scattering tomography experiments Type H1 Book chapter
Year 1999 Publication Abbreviated Journal
Volume Issue Pages 328-337
Keywords H1 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000083314300033 Publication Date 2003-11-21
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 0-8194-3258-x Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:26197 Serial 5737
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Author Janssens, K.; Vincze, L.; Vekemans, B.; Williams, C.T.; Radtke, M.; Haller, M.; Knöchel, A.
Title The non-destructive determination of REE in fossilized bone using synchrotron radiation induced K-line X-ray microfluorescence analysis Type A1 Journal article
Year 1999 Publication Fresenius' journal of analytical chemistry Abbreviated Journal
Volume 363 Issue 4 Pages 413-420
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The sensitivity and applicability of the synchrotron radiation induced X-ray microfluorescence (mu-SRXRF) spectrometer at the Hamburg synchrotron laboratory Hasylab for the determination of the distribution of trace concentrations of rare-earth elements (REE) in fossilized bone are discussed and critically compared to those of other trace analytical methods such as instrumental neutron activation analysis (INAA) and LAMP-ICPMS (laser ablation microprobe inductively-coupled plasma mass spectrometry). Measurements were carried out on two bone samples from contrasting terrestrial depositional environments at Olduvai Gorge (Tanzania). Results indicate that the microdistribution of the REE in these biological materials is not homogeneous and that the relative abundance of these elements can provide information on the palaeoenvironment during the fossilization process. The heterogeneous distribution of the REE can be determined in a quantitative and completely non-destructive manner provided the concentrations of individual REE are above 10 mu g/g.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000078895300015 Publication Date 2002-08-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0937-0633 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:103505 Serial 5747
Permanent link to this record
 

 
Author de Nolf, W.; Vekemans, B.; Janssens, K.; van der Snickt, G.; Falkenberg, G.
Title Pigment identification by scanning μ-XRF/μ-XRD Type H3 Book chapter
Year 2007 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:64595 Serial 5773
Permanent link to this record
 

 
Author Terzano, R.; Spagnuolo, M.; Ruggiero, P.; Vekemans, B.; Scoonjans, T.; Vincze, L.; Janssens, K.; Tomasi, N.; Cesco, S.; Falkenberg, G.
Title Quantitative Fe determination inside tomato roots by confocal μ-XRF Type H3 Book chapter
Year 2008 Publication Abbreviated Journal
Volume Issue Pages 1513-1514
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:74468 Serial 5794
Permanent link to this record
 

 
Author de Raedt, I.; Vekemans, B.; Janssens, K.; Adams, F.
Title Synchrotron light through ancient glass Type A3 Journal article
Year 2000 Publication Europhysics news Abbreviated Journal
Volume 31 Issue 6 Pages 15
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0531-7479 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:31697 Serial 5863
Permanent link to this record
 

 
Author Vincze, L.; Janssens, K.; Wei, F.; Proost, K.; Vekemans, B.; Vittiglio, G.; Yan, Y.; Falkenberg, G.
Title Trace-level micro-XANES by means of bending magnets radiation focused with a polycapillary lens Type H3 Book chapter
Year 1999 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:28440 Serial 5880
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Author Terzano, R.; al Chami, Z.; Vekemans, B.; Janssens, K.; Miano, T.; Ruggiero, P.
Title μ-XANES speciation of Zn in rhizospheric soil and in edible plants grown on a polluted soil amended with compost Type H3 Book chapter
Year 2007 Publication Abbreviated Journal
Volume Issue Pages
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved (down) Most recent IF: NA
Call Number UA @ admin @ c:irua:64592 Serial 5918
Permanent link to this record
 

 
Author Janssens, K.; de Nolf, W.; van der Snickt, G.; Vincze, L.; Vekemans, B.; Terzano, R.; Brenker, F.E.
Title Recent trends in quantitative aspects of microscopic X-ray fluorescence analysis Type A1 Journal article
Year 2010 Publication Trends in analytical chemistry Abbreviated Journal Trac-Trend Anal Chem
Volume 29 Issue 6 Pages 464-478
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000279235000014 Publication Date 2010-03-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0165-9936 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.442 Times cited 48 Open Access
Notes ; This research was supported by the Interuniversity Attraction Poles Programme-Belgian Science Policy (IUAP VI/16). The text also presents results of FWO (Brussels, Belgium) projects nr. G.0704.08 and G.0179.09 and from the UA-BOF GOA programme. ; Approved (down) Most recent IF: 8.442; 2010 IF: 6.602
Call Number UA @ admin @ c:irua:83903 Serial 5806
Permanent link to this record
 

 
Author Kempenaers, L.; Janssens, K.; Vincze, L.; Vekemans, B.; Somogyi, A.; Drakopoulos, M.; Simionovici, A.S.; Adams, F.
Title A Monte Carlo model for studying the microheterogeneity of trace elements in reference materials by means of synchrotron microscopic X-ray fluorescence Type A1 Journal article
Year 2002 Publication Analytical chemistry Abbreviated Journal Anal Chem
Volume 74 Issue 19 Pages 5017-5026
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000178418100031 Publication Date 2002-09-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.32 Times cited 21 Open Access
Notes Approved (down) Most recent IF: 6.32; 2002 IF: 5.094
Call Number UA @ admin @ c:irua:39871 Serial 5734
Permanent link to this record
 

 
Author Vincze, L.; Somogyi, A.; Osán, J.; Vekemans, B.; Török, S.; Janssens, K.; Adams, F.
Title Quantitative trace element analysis of individual fly ash particles by means of X-ray microfluorescence Type A1 Journal article
Year 2002 Publication Analytical chemistry Abbreviated Journal Anal Chem
Volume 74 Issue Pages 1128-1135
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000174187900032 Publication Date 2006-06-10
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.32 Times cited 44 Open Access
Notes Approved (down) Most recent IF: 6.32; 2002 IF: 5.094
Call Number UA @ admin @ c:irua:38377 Serial 5796
Permanent link to this record
 

 
Author Terzano, R.; Spagnuolo, M.; Medici, L.; Vekemans, B.; Vincze, L.; Janssens, K.; Ruggiero, P.
Title Copper stabilization by zeolite synthesis in polluted soils treated with coal fly ash Type A1 Journal article
Year 2005 Publication Environmental science and technology Abbreviated Journal Environ Sci Technol
Volume 39 Issue 16 Pages 6280-6287
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract This study deals with the process of zeolite formation in an agricultural soil artificially polluted by high amounts of Cu (15 mg of Cu/g of soil dry weight) and treated with fused coal fly ash at 30 and 60 degrees C and how this process affects the mobility and availability of the metal. As a consequence of the treatment, the amount of dissolved Cu, and thus its mobility, was strongly reduced, and the percentage of the metal stabilized in the solid phase increased over time, reaching values of 30% at 30 degrees C and 40% at 60 degrees C. The physicochemical phenomena responsible for Cu stabilization in the solid phase have been evaluated by EDTA sequential extractions and synchrotron radiation based X-ray microanalytical techniques. These techniques were used for the visualization of the spatial distribution and the speciation of Cu in and/or on the neo-formed zeolite particles. In particular, micro XRF (X-ray fluorescence) tomography showed direct evidence that Cu can be entrapped as clusters inside the porous zeolitic structures while,mu-XANES (X-ray absorption near edge structure) spectroscopy determinations revealed Cu to be present mainly as Cu(II) hydroxide and Cu(II) oxide. The reported results could be useful as a basic knowledge for planning new technologies for the on site physicochemical stabilization of heavy metals in heavily polluted soils.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000231203100053 Publication Date 2005-08-11
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0013-936x; 1520-5851 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.198 Times cited 39 Open Access
Notes Approved (down) Most recent IF: 6.198; 2005 IF: 4.054
Call Number UA @ admin @ c:irua:103658 Serial 5560
Permanent link to this record
 

 
Author Terzano, R.; Santoro, A.; Spagnuolo, M.; Vekemans, B.; Medici, L.; Janssens, K.; Göttlicher, J.; Denecke, M.A.; Mangold, S.; Ruggiero, P.
Title Solving mercury (Hg) speciation in soil samples by synchrotron X-ray microspectroscopic techniques Type A1 Journal article
Year 2010 Publication Environmental pollution Abbreviated Journal Environ Pollut
Volume 158 Issue 8 Pages 2702-2709
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Direct mercury (Hg) speciation was assessed for soil samples with a Hg concentration ranging from 7 up to 240 mg kg1. Hg chemical forms were identified and quantified by sequential extractions and bulkand micro-analytical techniques exploiting synchrotron generated X-rays. In particular, microspectroscopic techniques such as m-XRF, m-XRD and m-XANES were necessary to solve bulk Hg speciation, in both soil fractions <2 mm and <2 mm. The main Hg-species found in the soil samples were metacinnabar (b-HgS), cinnabar (a-HgS), corderoite (Hg3S2Cl2), and an amorphous phase containing Hg bound to chlorine and sulfur. The amount of metacinnabar and amorphous phases increased in the fraction <2 mm. No interaction among Hg-species and soil components was observed. All the observed Hgspecies originated from the slow weathering of an inert Hg-containing waste material (K106, U.S. EPA) dumped in the area several years ago, which is changing into a relatively more dangerous source of pollution.
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000280571500026 Publication Date 2010-06-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0269-7491 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 5.099 Times cited 30 Open Access
Notes ; This research was partially financed by the MIUR (COFIN 2005) project “Innovative chemical, physical, and biological methods to characterize and remediate soils polluted by heavy metals (MICROS)”. Synchrotron experiments at HASYLAB were financially supported by the European Community-Research Infrastructure Action under the FP6 “Structuring the European Research Area” Program I(Integrating Activity on Synchrotron and Free Electron Laser Science; project: contract RII3-CT-2004-506008). This research was also performed as part of the “Interuniversity Attraction Poles” (IAP6) Program financed by the Belgian government. We thank Gerald Falkenberg and Karen Rickers-Appel for their scientific and technical support in obtaining the experimental data at Beam line L (HASYLAB, DESY, Hamburg, Germany). ; Approved (down) Most recent IF: 5.099; 2010 IF: 3.395
Call Number UA @ admin @ c:irua:84050 Serial 5835
Permanent link to this record
 

 
Author Brenker, F.E.; Vollmer, C.; Vincze, L.; Vekemans, B.; Szymanski, A.; Janssens, K.; Szaloki, I.; Nasdala, L.; Joswig, W.; Kaminsky, F.
Title Carbonates from the lower part of transition zone or even the lower mantle Type A1 Journal article
Year 2007 Publication Earth and planetary science letters Abbreviated Journal Earth Planet Sc Lett
Volume 260 Issue 1/2 Pages 1-9
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Effective CO2-storage in the shallow solid Earth mainly occurs by the formation of carbonates. Although the possibility of transport and storage of carbonates to great depth is demonstrated experimentally, ultra-deep mantle carbonates have not been found before. Applying several in situ analytical techniques on inclusions in diamonds from Juina (Brazil) originating from the lower part of the transition zone (> 580 km) or even the lower mantle (> 670 km), reveal the existence of deep Earth carbonates. These finding unquestionably show that at least locally carbonates exist within the deep Earth and may indicate that the Earth's global CO2-cycle has an ultra-deep extension.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000248883300001 Publication Date 2007-03-04
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0012-821x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.409 Times cited 156 Open Access
Notes Approved (down) Most recent IF: 4.409; 2007 IF: 3.873
Call Number UA @ admin @ c:irua:71387 Serial 5496
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Author Flynn, G.J.; Janssens, K.; Vekemans, B.; [et al.]
Title Elemental compositions of comet 81P/Wild 2 samples collected by Stardust Type A1 Journal article
Year 2006 Publication Science Abbreviated Journal Science
Volume 314 Issue 5806 Pages 1731-1735
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos 000242833600046 Publication Date 2006-12-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0036-8075; 1095-9203 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 37.205 Times cited 174 Open Access
Notes Approved (down) Most recent IF: 37.205; 2006 IF: 30.028
Call Number UA @ admin @ c:irua:61923 Serial 5603
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