| Records |
| Author |
Nelson, J.W.; Williams, I.; Johansson, T.B.; Van Grieken, R.E. |
| Title |
Elemental analysis of aerosols using proton-scattering |
Type |
A1 Journal article |
| Year |
1974 |
Publication |
IEEE transactions on nuclear science |
Abbreviated Journal |
|
| Volume |
Ns21 |
Issue |
1 |
Pages |
618-621 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
Abstract  |
Elemental analysis for all of the light elements up through chlorine by elastic scattering of 16 MeV protons has been shown to be feasible. Basic problems associated with such measurements are discussed including kinematics, angular distribution, and sample backings. Spectra are presented for air particulate matter for both a total filter (Nuclepore) and a size fractionated air impactor (polystyrene backed) sample. The method is absolute, non destructive and can be used in conjunction with proton induced x-ray fluorescence to quantitatively analyze all elements in the same sample in minutes of time. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1974S533700086 |
Publication Date |
2008-07-22 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0018-9499 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:113642 |
Serial |
7881 |
| Permanent link to this record |
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| |
| Author |
Shevchenko, V.P.; Lisitzin, A.P.; Kuptzov, V.M.; Van Malderen, H.; Martin, J.M.; Van Grieken, R.; Huang, W.W. |
| Title |
Composition of aerosols in the marine boundary layer over the seas of the western Russian Arctic |
Type |
A1 Journal article |
| Year |
1999 |
Publication |
Omnia therapeutica. supplemento |
Abbreviated Journal |
|
| Volume |
39 |
Issue |
1 |
Pages |
142-151 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
During the SPASIBA expedition (Scientific Program on Arctic and Siberian Aquatorium) on board RV “Yakov Smirnitzky” to the Laptev Sea 10 samples of aerosols in the marine boundary layer have been collected by nylon meshes in August-September 1991. The composition of the samples was studied by a combined approach of different analytical techniques (single-particle analysis, instrumental neutron activation analysis, and atomic absorption spectrometry). The mass concentration of coarse (>1 mu m) insoluble fraction of aerosols was from 0.08 to 0.46 mu g/m(3). In all samples remains of land vegetation were found as the main component. The organic carbon content of the aerosols ranged from 23 to 49%. The inorganic part of the samples is represented mainly by alumosilicates and quartz, In all samples anthropogenic fly ash particles were detected, Temporal variations of the element concentrations are caused by various air masses transported to the study area. |
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Thesis |
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Place of Publication |
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Editor |
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Wos |
000079729200019 |
Publication Date |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
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| ISSN |
0030-1574 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:103979 |
Serial |
7706 |
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| |
| Author |
Mihucz, V.G.; Varga, Z.; Tatár, E.; Virág, I.; Van Grieken, R.; Koleszár, Z.; Záray, G. |
| Title |
Redistribution of uranium and thorium by soil/plant interaction in a recultivated mining area |
Type |
A1 Journal article |
| Year |
2008 |
Publication |
Microchemical journal |
Abbreviated Journal |
|
| Volume |
90 |
Issue |
1 |
Pages |
44-49 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
During the recultivation of the uranium mining area of Kõvágószõlõs (Hungary), the tailings were covered with clay and loess soil layers having a thickness of 30 cm and 100 cm, respectively. In the loess covering layer, acacia (Robinia pseudoacacia), poplars (Populus × albus, Populus × canescens), oak (Quercus pubescens), silver tree (Eleagnus angustifolia) were planted between 1996 and 2004. In order to establish the extent of the uranium and thorium transport from the sludge to the leaves by uptake and translocation processes through roots with a length higher than 1.3 m results in a remarkable redistribution of these pollutants, a gray poplar tree, growing spontaneously in the last uncovered tailing, being selected as reference tree. The U and Th concentrations in the leaves of the above-mentioned trees, in the covering layers as well as in the original sludge were determined by inductively coupled plasma sector field mass spectrometry (ICP-SF-MS). Generally, the Th concentration of the soils was about 4 times higher than that of uranium, while uranium concentration was about 10130 times higher than that of thorium in the leaf samples and its concentration ranged from 28 to 1045 ng g− 1, the last value belonging to the poplar tree growing on the last uncovered tailing. In order to assume the mobility and bioavailability of uranium if the dry leaves fall down, the uranium species in the leaves of the poplar tree growing in the uncovered reservoir were determined applying ultrasound-assisted extraction with distilled water and ammonium acetate as well as high performance liquid chromatographic (HPLC)-ICP-SF-MS technique. About 20% of total uranium could be extracted in form of uranyl cations and a presumably negatively charged uranium compound. Estimations revealed that the annual increment of U in the soil surface layer due to the dead fallen leaves in case of the investigated gray poplar (Populus × canescens) is about 1.2%. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000258744000008 |
Publication Date |
2008-03-21 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0026-265x; 0026-265x |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:70717 |
Serial |
8464 |
| Permanent link to this record |
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| |
| Author |
Rojas, C.M.; Van Grieken, R.E.; Laane, R.W. |
| Title |
Comparison of 3 dry deposition models applied to field-measurements in the Southern Bight of the North-Sea |
Type |
A1 Journal article |
| Year |
1993 |
Publication |
Atmospheric environment |
Abbreviated Journal |
|
| Volume |
27 |
Issue |
3 |
Pages |
363-370 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Dry deposition velocities have been calculated using three different approaches. Turbulent wind profile theory has been used to predict the drag coefficient, wind speed and friction velocity at 10 m height when the wind speed is measured at a higher altitude. The resulting parameters were introduced in a two-layer deposition model. The second approach was the well-known model of Slinn and Slinn (1980, Atmospheric Environment 14, 1013-1016), whereas the third corresponded to the model published by Williams (1982, Atmospheric Environment 16, 1933 1938). Results point to clear differences. However, in a field experiment carried out at the Southern Bight of the North Sea, all three approaches show relatively comparable results. The role played by the size distribution of atmospheric particulate matter is essential. In our case any of the three models could have given satisfactory outcomes taking into account the wide spread of the experimental results cited in the literature for the same airshed. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1993KQ75200008 |
Publication Date |
2003-08-06 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0004-6981 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
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| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:100018 |
Serial |
7690 |
| Permanent link to this record |
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| |
| Author |
Vos, L.; Komy, G.; Reggers, G.; Roekens, E.; Van Grieken, R. |
| Title |
Determination of trace metals in rain water by differential-pulse stripping voltammetry |
Type |
A1 Journal article |
| Year |
1986 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
| Volume |
184 |
Issue |
|
Pages |
271-280 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Differential-pulse stripping voltammetry is applied to measure zinc, cadmium, lead and copper by anodic stripping and selenium(IV) by cathodic stripping in rain water at pH 2; subsequently, at pH 9,1, manganese is measured by anodic stripping on the same portion, and cobalt and nickel are measured in the adsorptive mode after formation of their dimethylglyoximates. The instrumental parameters are optimized. The linear ranges, mutual interferences and detection limits are studied. Excellent accuracy is demonstrated; the standard deviation is around 15% at 2.550 μg l−1 levels. The method is shown to be applicable for rain water. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1986D964700026 |
Publication Date |
2002-07-25 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116444 |
Serial |
7793 |
| Permanent link to this record |
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| |
| Author |
Komy, Z.; Roekens, E.; Van Grieken, R. |
| Title |
Analysis of rain water by differential-pulse stripping voltammetry in nitric acid medium |
Type |
A1 Journal article |
| Year |
1988 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
| Volume |
204 |
Issue |
|
Pages |
179-187 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Differential-pulse anodic stripping voltammetry is applied to determine cadmium, lead and copper in rain water acidified with nitric acid to pH 1.5, and zinc after partial neutralization to pH 4.5. Subsequently, cobalt and nickel are measured in the adsorptive mode after formation of their dimethylglyoximates. The effects of pH on the stripping peaks for Zn, Cd, Pb and Cu and of chloride on the stripping peak of copper are reported. Good agreement is found with d.p.s.v. determinations in hydrochloric acid medium and with a.a.s. measurements in most cases. Excellent accuracy is demonstrated; the average relative standard deviation per measurement appears to be between 12 and 22% for the overall analytical procedure for concentrations of 0.1550 μgl−1 of the various metals in the samples. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1988M945900016 |
Publication Date |
2002-07-25 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
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| ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
|
| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:116449 |
Serial |
7450 |
| Permanent link to this record |
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| |
| Author |
Leysen, L.; Roekens, E.; Van Grieken, R. |
| Title |
Air-pollution-induced chemical decay of a sandy-limestone cathedral in Belgium |
Type |
A1 Journal article |
| Year |
1989 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
78 |
Issue |
|
Pages |
263-277 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Different trace- and microanalytical techniques were used in an extensive study to elucidate the chemical deterioration process of the sandy-limestone St Rombouts Cathedral in Mechelen, Belgium. Samples of stones, mortar joints, slates, atmospheric aerosols and gases, total and wet deposition, and water that had run down the cathedral walls, were all thoroughly characterized. At the east side, usually not exposed to precipitation, a 3001000-μm thick outer crust of microcrystalline gypsum was observed, while at the west side, this surface layer was mostly eroded away due to precipitation. At the north and south sides, the crust contains varying amounts of gypsum and calcite. The gypsum is mostly present in a bar-shaped morphology and carbonaceous fly-ash particles were rarely found in the weathering crust. Local stone characteristics seem to be extremely important in relation to the gypsum content of the crust; black samples always have a much higher sulphate content than the corresponding white samples, irrespective of the predominant direction of orientation. The relative contribution of nitrogen- and chlorine-containing pollutants to the total decay process is much smaller than that of sulphur-containing pollutants. Deposition samples collected at the site of the cathedral mostly had a pH of > 5.6, due to the neutralization of the rainwater by alkaline atmospheric constituents. Runoff water and washdown water were enriched in all ions, especially Ca2+ and SO42−, indicating that, indeed, gypsum is the most important weathering product. The suspension in deposition samples and black-well leaching water was highly enriched in silicon-containing particles, while runoff water and white-wall leaching water contained a predominant calcium-rich suspension. |
| Address |
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| Corporate Author |
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Thesis |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1989R806400021 |
Publication Date |
2003-09-12 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116649 |
Serial |
7431 |
| Permanent link to this record |
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| |
| Author |
Damla, N.; Čevik, U.; Kobya, A.I.; Celik, A.; Celik, N.; Van Grieken, R. |
| Title |
Radiation dose estimation and mass attenuation coefficients of cement samples used in Turkey |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Journal of hazardous materials |
Abbreviated Journal |
|
| Volume |
176 |
Issue |
1/3 |
Pages |
644-649 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Different cement samples commonly used in building construction in Turkey have been analyzed for natural radioactivity using gamma-ray spectrometry. The mean activity concentrations observed in the cement samples were 52, 40 and 324 Bq kg−1 for 226Ra, 232Th and 40K, respectively. The measured activity concentrations for these radionuclides were compared with the reported data of other countries and world average limits. The radiological hazard parameters such as radium equivalent activities (Raeq), gamma index (Iγ) and alpha index (Iα) indices as well as terrestrial absorbed dose and annual effective dose rate were calculated and compared with the international data. The Raeq values of cement are lower than the limit of 370 Bq kg−1, equivalent to a gamma dose of 1.5 mSv y−1. Moreover, the mass attenuation coefficients were determined experimentally and calculated theoretically using XCOM in some cement samples. Also, chemical compositions analyses of the cement samples were investigated. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000274839700087 |
Publication Date |
2009-11-20 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0304-3894 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:80671 |
Serial |
8448 |
| Permanent link to this record |
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| |
| Author |
Robberecht, H.; vanden Berghe, D.; Deelstra, H.; Van Grieken, R. |
| Title |
Selenium in the Belgian soils and its uptake by rye-grass |
Type |
A1 Journal article |
| Year |
1982 |
Publication |
The science of the total environment |
Abbreviated Journal |
|
| Volume |
25 |
Issue |
1 |
Pages |
61-69 |
| Keywords |
A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Data obtained by atomic absorption spectroscopy showed a selenium concentration of only 0.11 ppm as an average value for the most representative agricultural soils in Belgium. The selenium content in rye-grass grown on different soil types was between 0.05 and 0.11 ppm, and positively correlated with the soil selenium level. Addition of selenium in the form of selenite to the different soil types resulted in an increased selenium uptake by the plant. The ultimate concentration in the plant depended on the structural and chemical composition of the soil. Twelve other elements were determined in the soils by energy-dispersive X-ray fluorescence; none showed a strong correlation with the soil selenium content or with the selenium uptake by ryegrass. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1982PJ93000006 |
Publication Date |
2003-09-12 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0048-9697; 1879-1026 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116646 |
Serial |
8510 |
| Permanent link to this record |
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| |
| Author |
Bencs, L.; Krata, A.; Horemans, B.; Buczyńska, A.J.; Dirtu, A.C.; Godoi, A.F.L.; Godoi, R.H.M.; Potgieter-Vermaak, S.; Van Grieken, R. |
| Title |
Atmospheric nitrogen fluxes at the Belgian coast: 2004-2006 |
Type |
A1 Journal article |
| Year |
2009 |
Publication |
Atmospheric environment : an international journal |
Abbreviated Journal |
|
| Volume |
43 |
Issue |
24 |
Pages |
3786-3798 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Daily and seasonal variations in dry and wet atmospheric nitrogen fluxes have been studied during four campaigns between 2004 and 2006 at a coastal site of the Southern North Sea at De Haan (Belgium) located at coordinates of 51.1723° N and 3.0369° E. Concentrations of inorganic N-compounds were determined in the gaseous phase, size-segregated aerosol (coarse, medium, and fine), and rainwater samples. Dissolved organic nitrogen (DON) was quantified in rainwater. The daily variations in N-fluxes of compounds were evaluated with air-mass backward trajectories, classified into the main air-masses arriving at the sampling site (i.e., continental, North Sea, and Atlantic/UK/Channel). The three, non-episodic campaigns showed broadly consistent fluxes, but during the late summer campaign exceptionally high episodic N-deposition was observed. The average dry and wet fluxes for non-episodic campaigns amounted to 2.6 and 4.0 mg N m−2 d−1, respectively, whereas during the episodic late summer period these fluxes were as high as 5.2 and 6.2 mg N m−2 d−1, respectively. Non-episodic seasons/campaigns experienced average aerosol fluxes of 0.91.4 mg N m−2 d−1. Generally, the contribution of aerosol NH4+ was more significant in the medium and fine particulate fractions than that of aerosol NO3−, whereas the latter contributed more in the coarse fraction, especially in continental air-masses. During the dry mid-summer campaign, the DON contributed considerably (15%) to the total N-budget. Exceptionally high episodic aerosol-N inputs have been observed for the late summer campaign, with especially high deposition rates of 3.6 and 2.9 mg N m−2 d−1 for Atlantic/UK/Channel and North Sea-continental (mixed) air-masses, respectively. During this pollution episode, the flux of NH4+ was dominating in each aerosol fraction/air-mass, except for coarse continental aerosols. High deposition of gaseous-N was also observed in this campaign with an average total N-flux of 22.5-times higher than in other campaigns. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000268609000015 |
Publication Date |
2009-04-17 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1352-2310 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:77255 |
Serial |
7527 |
| Permanent link to this record |
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| |
| Author |
Bencs, L.; Ravindra, K.; de Hoog, J.; Spolnik, Z.; Bleux, N.; Berghmans, P.; Deutsch, F.; Roekens, E.; Van Grieken, R. |
| Title |
Appraisal of measurement methods, chemical composition and sources of fine atmospheric particles over six different areas of Northern Belgium |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Environmental pollution |
Abbreviated Journal |
|
| Volume |
158 |
Issue |
11 |
Pages |
3421-3430 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Daily and seasonal variation in the total elemental, organic carbon (OC) and elemental carbon (EC) content and mass of PM2.5 were studied at industrial, urban, suburban and agricultural/rural areas. Continuous (optical Dustscan, standard tapered element oscillating micro-balance (TEOM), TEOM with filter dynamics measurement system), semi-continuous (Partisol filter-sampling) and non-continuous (Dekati-impactor sampling and gravimetry) methods of PM2.5 mass monitoring were critically evaluated. The average elemental fraction accounted for 26% of the PM2.5 mass measured by gravimetry. Metals, like K, Mn, Fe, Cu, Zn and Pb were strongly inter-correlated, also frequently with non-metallic elements (P, S, Cl and/or Br) and EC/OC. A high OC/EC ratio (29) was generally observed. The total carbon content of PM2.5 ranged between 3 and 77% (averages: 1232%), peaking near industrial/heavy trafficked sites. Principal component analysis identified heavy oil burning, ferrous/non-ferrous industry and vehicular emissions as the main sources of metal pollution. This work compares various aerosol monitoring methods to characterize PM2.5 over six locations of different anthropogenic activities over Northern Belgium. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
000282563200009 |
Publication Date |
2010-08-23 |
| Series Editor |
|
Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
|
| ISSN |
0269-7491; 1873-6424 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:84237 |
Serial |
7488 |
| Permanent link to this record |
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| |
| Author |
Robberecht, H.; Van Grieken, R.; Shani, J.; Barak, S. |
| Title |
Evaluation of multi-element analysis of blood serum by energy-dispersive x-ray spectrometry |
Type |
A1 Journal article |
| Year |
1982 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
| Volume |
136 |
Issue |
|
Pages |
285-292 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Conventional energy-dispersive x-ray fluorescence is applied in the analysis of blood serum to give the concentrations of 710 elements simultaneously with minimal manipulation of the samples. Simple spotting onto a Mylar carrier of 250 μl of serum, doped with two internal standards, was chosen as the sample preparation step. Some 200 serum samples, analyzed in replicate (n = 26), were used to evaluate this procedure. The detection limits are 4 μg ml-1 for K and Ca, 0.50.2 μg ml-1 for Fe, Cu, Pb and Zn, and less than 0.1 μg ml-1 for Se, Rb and Sr. Well above these limits, the standard deviation is around 10%. Comparison with the results of other measurements on the same samples indicates an accuracy of that order. The simplicity and high throughput, and the possibility of automating the x.r.f. measurements, make the proposed procedure suitable for screening large numbers of sera. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1982NL48600032 |
Publication Date |
2002-07-25 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
|
| ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116440 |
Serial |
7940 |
| Permanent link to this record |
| |
|
| |
| Author |
Potgieter-Vermaak, S.; Rotondo, G.; Novacovic, V.; Rollins, S.; Van Grieken, R. |
| Title |
Component-specific toxic concerns of the inhalable fraction of urban road dust |
Type |
A1 Journal article |
| Year |
2012 |
Publication |
Environmental geochemistry and health |
Abbreviated Journal |
|
| Volume |
34 |
Issue |
6 |
Pages |
689-696 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Continuous global urbanisation causes an ever-growing ecological footprint of pollution. Road dust (RD), one of these pollutants, poses a health concern due to carcinogenic and toxic components potentially present in the micron-sized fractions. The literature reports on the concentrations of trace, toxic metals and metalloids present in RD (Hooker and Nathanail in Chem Geol 226:340-351, 2006), but the literature on its molecular composition is limited. Recent reports on the bioaccessibility of platinum group metals are also reported (Colombo et al. in Chem Geol 226:340-351, 2008). In vitro and animal toxicological studies confirmed that the chemical composition of inhaled particles plays a major role in its toxic, genotoxic and carcinogenic mechanisms, but the component-specific toxic effects are still not understood. Particle-bound airborne transition metals can also lead to the production of reactive oxygen species in lung tissue; a special concern amongst particularly susceptible cohorts (children and elderly). The characterisation of the molecular composition of the fine fraction is evidently of importance for public health. During a pilot study, partially characterised size-fractioned RD samples (Barrett et al. in Eviron Sci Technol 44:2940-2946, 2010) were analysed for their elemental concentration using X-ray fluorescence spectrometry and inductively coupled plasma mass spectrometry. In addition, separately dispersed particles (200 particles per size fraction) were analysed individually by means of computer-controlled electron probe X-ray micro-analysis (CC-EPXMA) and their molecular structure probed by studying elemental associations. These were correlated with micro-Raman spectroscopy (MRS) results. It was found that the fine fraction (< 38 mu m) had the highest Pb (238 ppm) and Cr (171 ppm) concentrations. The CC-EPXMA data showed > 50 % association of Cr-rich particles with Pb, and the MRS data showed that the Cr was mostly present as lead chromate and therefore in the Cr(VI) oxidation state. Concentrations of both Pb and Cr decreased substantially (279 (< 38 mu m)-13 ppm (< 1 mm); 171 (< 38 mu m)-91 ppm (< 1 mm), respectively) in the larger fractions. Apart from rather alarmingly high concentrations of oxidative stressors (Cu, Fe, Mn), the carcinogenic and toxic potential of the inhalable fraction is evident. Preliminary bioaccessibility data indicated that both Cr and Pb are readily mobilised in artificial lysosomal liquid and up to 19 % of Cr and 47 % of Pb were released. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
|
Editor |
|
| Language |
|
Wos |
000310540300005 |
Publication Date |
2012-09-28 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0269-4042 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:102135 |
Serial |
7699 |
| Permanent link to this record |
| |
|
| |
| Author |
Darchuk, L.; Tsybrii, Z.; Worobiec, A.; Vázquez, C.; Palacios, O.M.; Stefaniak, E.A.; Gatto Rotondo, G.; Sizov, F.; Van Grieken, R. |
| Title |
Argentinean prehistoric pigments' study by combined SEM/EDX and molecular spectroscopy |
Type |
A1 Journal article |
| Year |
2010 |
Publication |
Spectrochimica acta: part A: molecular and biomolecular spectroscopy |
Abbreviated Journal |
|
| Volume |
75 |
Issue |
5 |
Pages |
1398-1402 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
| Abstract |
Composition of the prehistoric pigments (from Carriqueo rock shelter, Rio Negro province, Argentina) has been analysed by means of molecular spectroscopy (Fourier transform infrared (FTIR) and micro-Raman) and scanning electron microscopy (SEM) coupled to an energy-dispersive X-ray spectrometer (EDS). Red and yellow pigments were recognized as red and yellow ochre. The matrix of the pigments is composed of one or more substances. According to the matrix composition yellow and red pigments were also divided into two groupsi.e. those containing kaolinite or sulphates. Green pigment was detected as green earth, made up of celadonite as a chromophore. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
|
| Language |
|
Wos |
000277231700004 |
Publication Date |
2010-02-05 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1386-1425 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:81939 |
Serial |
7493 |
| Permanent link to this record |
| |
|
| |
| Author |
Ramesh, R.; Subramanian, V.; Van Grieken, R.; Van 't dack, L. |
| Title |
The elemental chemistry of sediments in the Krishna River basin, India |
Type |
A1 Journal article |
| Year |
1989 |
Publication |
Chemical geology |
Abbreviated Journal |
|
| Volume |
74 |
Issue |
3/4 |
Pages |
331-341 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Composition of bed, core and suspended sediments collected from Krishna River sediments were studied and the observations are discussed in the light of other Indian rivers, world's average river suspended particles, surficial rock and soils. The contents of V, Cr, Co, Ni, Cu and Zn in the suspended particles are higher in the Krishna River than in the world's average, indicating pollution inputs. Suspended sediments are enriched (5 to 10 times) in all the elements considered relative to bed sediments. Downstream profile and metal/Al ratios of the elements indicate that the mobility of elements within the basin is controlled by basin geology, size and mineralogical characteristics. Good correlations observed for a number of elements point out to their common sink in the clay fraction of the sediments. There is no systematic variation with depth for the major elements and most of the elements are considerably higher compared to estuarine or Bay of Bengal sediments. |
| Address |
|
| Corporate Author |
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Thesis |
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| Publisher |
|
Place of Publication |
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Editor |
|
| Language |
|
Wos |
A1989T007000012 |
Publication Date |
2003-08-06 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0009-2541 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:111482 |
Serial |
7885 |
| Permanent link to this record |
| |
|
| |
| Author |
Roland, M.; Serrano-Ortiz, P.; Kowalski, A.S.; Van Grieken, R.; Janssens, I.A.; et al. |
| Title |
Atmospheric turbulence triggers pronounced diel pattern in karst carbonate geochemistry |
Type |
A1 Journal article |
| Year |
2013 |
Publication |
Biogeosciences |
Abbreviated Journal |
|
| Volume |
10 |
Issue |
7 |
Pages |
5009-5017 |
| Keywords |
A1 Journal article; Plant and Ecosystems (PLECO) – Ecology in a time of change; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
CO2 exchange between terrestrial ecosystems and the atmosphere is key to understanding the feedbacks between climate change and the land surface. In regions with carbonaceous parent material, CO2 exchange patterns occur that cannot be explained by biological processes, such as disproportionate outgassing during the daytime or night-time CO2 uptake during periods when all vegetation is senescent. Neither of these phenomena can be attributed to carbonate weathering reactions, since their CO2 exchange rates are too small. Soil ventilation induced by high atmospheric turbulence is found to explain atypical CO2 exchange between carbonaceous systems and the atmosphere. However, by strongly altering subsurface CO2 concentrations, ventilation can be expected to influence carbonate weathering rates. By imposing ventilation-driven CO2 outgassing in a carbonate weathering model, we show here that carbonate geochemistry is accelerated and does play a surprisingly large role in the observed CO2 exchange pattern of a semi-arid ecosystem. We found that by rapidly depleting soil CO2 during the daytime, ventilation disturbs soil carbonate equilibria and therefore strongly magnifies daytime carbonate precipitation and associated CO2 production. At night, ventilation ceases and the depleted CO2 concentrations increase steadily. Dissolution of carbonate is now enhanced, which consumes CO2 and largely compensates for the enhanced daytime carbonate precipitation. This is why only a relatively small effect on global carbonate weathering rates is to be expected. On the short term, however, ventilation has a drastic effect on synoptic carbonate weathering rates, resulting in a pronounced diel pattern that exacerbates the non-biological behavior of soil-atmosphere CO2 exchanges in dry regions with carbonate soils. |
| Address |
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| Corporate Author |
|
Thesis |
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| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
000322242700039 |
Publication Date |
2013-07-24 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
1726-4170; 1726-4189 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:109862 |
Serial |
7533 |
| Permanent link to this record |
| |
|
| |
| Author |
Vandecasteele, C.; Van Grieken, R.; Hoste, J. |
| Title |
Simultaneous determination of chromium and silicon in steel by 14-mev neutron activation analysis |
Type |
A1 Journal article |
| Year |
1974 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
| Volume |
72 |
Issue |
1 |
Pages |
31-36 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Chromium and silicon are determined simultaneously in steel by 14-MeV neutron activation analysis. The activities of 52V(Eγ=1.43 MeV,TView the MathML source=3.76 min) from 52Cr(n,p)52V and 28Al (Eγ=1.78 MeV; TView the MathML source=2.24 min) from 28Si(n,p)28Al are evaluated by mixed γ-ray spectrometry. The influence of manganese and phosphorus, the main interfering elements, is negligible for most stainless steels. The count rate should be limited, to avoid 52V pulse pile-up effects interfering in the 28Al energy region. Precisions in the 2-10% range are reached, depending on the concentrations, for a 10-min analysis time. Results for a series of steel samples are compared with industrial analyses. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
|
| Language |
|
Wos |
A1974U036600002 |
Publication Date |
2002-07-25 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116366 |
Serial |
8527 |
| Permanent link to this record |
| |
|
| |
| Author |
Vanderborght, B.M.; Van Grieken, R.E. |
| Title |
Trace metal analysis of water containing humic substances by X-ray fluorescence |
Type |
A1 Journal article |
| Year |
1978 |
Publication |
International journal of environmental analytical chemistry |
Abbreviated Journal |
|
| Volume |
5 |
Issue |
3 |
Pages |
221-237 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Chelation by oxine followed by adsorption on activated carbon results in the efficient collection of many trace metal ions, independent of the trace metal concentration and of high alkali and alkaline earth ion abundances. Preconcentration factors around 10000 are often achieved. When this preconcentration procedure is combined with energy-dispersive X-ray fluorescence, accurate and precise analysis can be carried out, as was proven in several experiments. The technique can also be applied for the determination of divalent ions in natural waters containing up to 10 ppm of humic substances. Trivalent ions can quantitatively be collected from natural water provided suKicient activated carbon is added. Omitting the oxine chelation prior to the activated carbon adsorption step still results in collection of a sometimes important fraction of the trace metal ions from natural waters. This is related to organically bound or colloidal forms of the trace metals. |
| Address |
|
| Corporate Author |
|
Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
A1978FR88000005 |
Publication Date |
2007-07-07 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-7319 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116570 |
Serial |
8692 |
| Permanent link to this record |
| |
|
| |
| Author |
Čevik, U.; Akbulut, S.; Makarovska, Y.; Van Grieken, R. |
| Title |
Polarized-beam high-energy EDXRF in geological samples |
Type |
A1 Journal article |
| Year |
2013 |
Publication |
Spectroscopy letters |
Abbreviated Journal |
|
| Volume |
46 |
Issue |
1 |
Pages |
36-46 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Certified reference materials (NIST 1645, BCR 143, IAEA 7, BCR 141, NIESCRM02, and IAEA 375) were used for determining the performance of a secondary target energy-dispersive X-ray fluorescence (EDXRF) spectrometer, Epsilon 5 (PANalytical, Almelo, the Netherlands). For the evaluation of the EDXRF spectra with polarized-beam high-energy excitation, the WinAxil software package has been applied. The results showed that Epsilon 5, EDXRF spectrometry is favorable for the determination of elemental concentrations in geological samples, but the sample preparation has the largest influence on the precision. However, they presented good agreement with certified values for most of the elements. |
| Address |
|
| Corporate Author |
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Thesis |
|
| Publisher |
|
Place of Publication |
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Editor |
|
| Language |
|
Wos |
000314018900005 |
Publication Date |
2013-01-03 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0038-7010 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:106754 |
Serial |
8392 |
| Permanent link to this record |
| |
|
| |
| Author |
Reggers, C.; Van Grieken, R. |
| Title |
2,2′-Diaminodiethylamine cellulose powder for trace metal preconcentrations from water |
Type |
A3 Journal article |
| Year |
1984 |
Publication |
Fresenius' Zeitschrift für analytische Chemie |
Abbreviated Journal |
|
| Volume |
317 |
Issue |
5 |
Pages |
520-526 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Cellulose powder with 2,2′-diaminodiethylamine (DEN) functional groups exhibits efficient complexation of transition metal cations. Collection yields above 85 % are obtained up to a chelation capacity of 1.5 meq per gram. Since a good collection is obtained for a pH up from 5, no pH adjustments have to be made for natural water samples. The cellulose-DEN powder is insensitive to abundant substances like alkali and alkaline earth ions, and humic matter. Some cations can be eluted efficiently in a small volume of HNO3. Blank concentration levels from the cellulose-DEN powder are reported. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
|
Editor |
|
| Language |
|
Wos |
|
Publication Date |
2004-11-17 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0016-1152 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116640 |
Serial |
7383 |
| Permanent link to this record |
| |
|
| |
| Author |
Smits, J.; Van Grieken, R. |
| Title |
Enrichment of trace anions from water with 2,2'-diaminodiethylamine cellulose filters |
Type |
A1 Journal article |
| Year |
1981 |
Publication |
Analytica chimica acta |
Abbreviated Journal |
|
| Volume |
123 |
Issue |
|
Pages |
9-17 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Cellulose filters with immobilized 2,2'-diaminodiethylamine (DEN) functional groups are studied for trace anion preconcentration from aqueous solution, with subsequent x-ray fluorescence measurements. For most oxoanions with a central metal atom, nearly quantitative collection can be achieved by 10-cm2 DEN filters under the following optimized conditions: pH 36, filtration rate up to 0.5 ml cm-2 min-1, and sample volume up to 100 ml cm-2. The collection yield is independent of the trace oxoanion concentration up to at least 1.5 μmol cm-2. Although the DEN filter exhibits some selectivity towards oxoanions with a central metal atom, ionic strength affects the results; the collection efficiency is strongly depressed with salt (e.g. NaCl) concentrations above 0.01 M. The applicability of the DEN filter in anion collection is therefore limited to dilute solutions. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
A1981LA22400002 |
Publication Date |
2002-07-25 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0003-2670; 1873-4324 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116437 |
Serial |
7922 |
| Permanent link to this record |
| |
|
| |
| Author |
Hoornaert, S.; van Malderen, H.; Van Grieken, R. |
| Title |
Gypsum and other calcium-rich particles above the North Sea |
Type |
A1 Journal article |
| Year |
1996 |
Publication |
Environmental science and technology |
Abbreviated Journal |
|
| Volume |
30 |
Issue |
|
Pages |
1515-1520 |
| Keywords |
A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Ca-containing particles, especially CaSO4 particles, have been encountered in several atmospheric aerosol studies. An overview is given of the different sources of airborne Ca-containing particles, The North Sea atmosphere is studied to identify the different Ca-containing particle types and to find the correlation between their occurrence and the source regions of the corresponding air masses. About 50000 individual aerosol samples were collected above the Southern Eight of the North Sea for several wind directions and analyzed for their composition using electron probe X-ray microanalysis. Nonhierarchical cluster analysis is performed on the data to reveal the different particle types, their relative abundances and their sources. CaSO4 in most cases constitutes the largest fraction of the Ca-containing particles. Extremely high numbers of CaSO4 particles are found for northeastern winds, coming from the central part of Germany, suggesting that a great fraction is derived from anthropogenic sources located in this region. Among the other Ca-containing particle types are the aluminosilicates, CaCO3, Fe-Ca-rich particles, and CaSO4 or CaCO3 in combination with NaCl. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
|
Wos |
A1996UG95400042 |
Publication Date |
2002-07-26 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0013-936x; 1520-5851 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:14647 |
Serial |
8015 |
| Permanent link to this record |
| |
|
| |
| Author |
Maenhaut, W.; Raemdonck, H.; Selen, A.; Van Grieken, R.; Winchester, J.W. |
| Title |
Characterization of the atmospheric aerosol over the eastern equatorial Pacific |
Type |
A1 Journal article |
| Year |
1983 |
Publication |
Journal of geophysical research |
Abbreviated Journal |
|
| Volume |
88 |
Issue |
C:9 |
Pages |
5353-5364 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
By using a polyester sailboat as sampling platform, a series of duplicate aerosol samples was collected by cascade impactors on a trip from Panama to Tahiti in 1979. Elemental analysis mainly by particle-induced X ray emission (PIXE) indicated, in the samples collected between Panama and the Galapagos Islands, the presence of a substantial crustal component (∼0.4 μg/m3), fine Cu (∼0.4 ng/m3) and Zn (∼0.6 ng/m3), and excess fine S and K (∼100 and ∼2.4 ng/m3, respectively) in addition to the major sea salt elements. The crustal component and fine Cu and Zn are suggested to result from natural continental sources (i.e., eolian dust transport from the American continents and perhaps geothermal emissions). Samples collected west of the Galapagos Islands in the southern trades showed significantly lower concentrations for the nonseawater components. The average Si and Fe levels were as low as 4.8 and 3.3 ng/m3, corresponding to a maximum of 0.066 μg/m3 for an assumed mineral dust component, whereas heavy metal concentrations were all below the detection limits (typically ranging from 0.05 to 0.15 ng/m3 for V, Cr, Mn, Ni, Cu, Zn, and Se). Excess fine S decreased to a mean of 46 ng/m3, a level similar to those reported for other remote marine and continental locations. This all indicates that the marine atmosphere west of the Galapagos was little influenced by natural continental source processes or by anthropogenic emissions. Under these truly marine conditions, several concentration ratios of the major seawater elements were significantly different from those in bulk seawater. Ca, Sr, and S in >1 μm diameter particles were enriched relative to K and Na, with the enrichment being substantially more pronounced (up to 50% or higher) for l4-μm diameter particles than for particles >4 μm. Comparison of these data with a similar data set from samples collected over the Atlantic indicates that the departures from seawater composition are significantly larger for the Pacific. Differences in sea-to-air fractionation processes, probably involving binding of divalent cations to organic matter in the oceanic surface microlayer, are suggested as being responsible for these observations. |
| Address |
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| Corporate Author |
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Thesis |
|
| Publisher |
|
Place of Publication |
|
Editor |
|
| Language |
|
Wos |
A1983QU67600025 |
Publication Date |
2008-02-06 |
| Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0148-0227; 2156-2202; 0022-1406; 0196-6928; 0196-6936; 0885-3401; 8755-8556; 0196-2256; 0747-7309; 1 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:113625 |
Serial |
7633 |
| Permanent link to this record |
| |
|
| |
| Author |
Vandeputte, D.; Van Grieken, R.E.; Jacob, W.A.; Savory, J.; Bertholf, R.L.; Wills, M.R. |
| Title |
Ultrastructural localization of aluminium in liver of aluminium maltol-treated rabbits by laser microprobe mass analysis |
Type |
A1 Journal article |
| Year |
1989 |
Publication |
Biomedical and environmental mass spectrometry |
Abbreviated Journal |
|
| Volume |
18 |
Issue |
8 |
Pages |
598-602 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
By means of laser microprobe mass analysis (LAMMA), we have studied the ultrastructural localization of aluminium in livers of aluminium maltol-treated rabbits. This animal model was developed to study long-term aluminium toxicity using systemic (intravenous) administration of aluminium. We could only detect aluminium in electron-dense inclusion bodies found in large, sometimes multinucleated cells. These results prove that the actual observation of aluminium deposits in liver with LAMMA gives more information than bulk analysis and can be very useful to explore mechanisms of toxicity. |
| Address |
|
| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
2005-05-29 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0887-6134 |
ISBN |
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Additional Links |
UA library record |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
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Approved |
no |
| Call Number |
UA @ admin @ c:irua:116817 |
Serial |
8702 |
| Permanent link to this record |
| |
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| |
| Author |
Verbueken, A.H.; Van Grieken, R.E.; Paulus, G.J.; Verpooten, G.A.; de Broe, M.E. |
| Title |
Laser microprobe mass spectrometry of platinum in dog kidney after cisplatin adminstration |
Type |
A3 Journal article |
| Year |
1984 |
Publication |
Biomedical mass spectrometry |
Abbreviated Journal |
|
| Volume |
11 |
Issue |
4 |
Pages |
159-163 |
| Keywords |
A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Laboratory Experimental Medicine and Pediatrics (LEMP) |
| Abstract |
By means of laser microprobe mass analysis (LAMMA) platinum was detected in the renal proximal tubular cells of a dog that had been intravenously adminstered the antitumor drug cisplatin (5 mg per kg body weight). No definite subcellular localization of the heavy metal was obtained. Sample prparation and analytical features are examined to increase spatial resolution of analysis while maintaining sufficient detection efficiency. The LAMMA method is destructive, but the amount and type of evaporated material can readily be determined when using LAMMA in combination with transmission electron microscopy. Instrumental optimization and standardization of mass signals is possible by using platinum-loaded, ion chelating resin beads embedded and sectioned with the tissue. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
2005-05-28 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0306-042x |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116712 |
Serial |
8165 |
| Permanent link to this record |
| |
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| |
| Author |
Sauter, L.; Van der Ben, D.; Van Grieken, R. |
| Title |
Trace analysis of estuarine brown algae by energy-dispersive X-ray fluorescence |
Type |
A1 Journal article |
| Year |
1979 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
| Volume |
8 |
Issue |
4 |
Pages |
159-163 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Brown algae, which are good indicators for estuarine metal pollution, can advantageously be analysed by energy-dispersive X-ray fluorescence. The use of thin film samples and samples of intermediate thickness has several advantages over the conventional thick pellet procedure. A quite homogeneous thin target is prepared by suspending 15 mg of dried and ground seaweed powder in bi-distilled water and evaporating the slurry on a 10 cm2 Mylar foil held in a Teflon ring. The effective sample weight in the beam is calculated by a procedure based on the scatter peaks in the spectrum. Sensitivities are typically in the 215 ppm range. The coefficient of variation per analysis averaged over ten elements amounts to 10%. The natural concentration variation in seaweed specimens at one location is 13%. Samples from locations in the more polluted western Scheldt estuary yield significantly higher values for several elements, relative to the eastern Scheldt sites. Possible trace element variations between the top and base of plants, and between different seaweed specimens and sampling seasons, are discussed. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1979JC63700003 |
Publication Date |
2005-05-28 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
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| ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
|
Open Access |
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| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116481 |
Serial |
8687 |
| Permanent link to this record |
| |
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| |
| Author |
Trincavelli, J.; Montoro, S.; van Espen, P.; Van Grieken, R. |
| Title |
M\alpha/L\alpha intensity ratios for Ta, W, Pt, Au, Pb and Bi for electron energies in the 11-40 keV range |
Type |
A1 Journal article |
| Year |
1993 |
Publication |
X-ray spectrometry |
Abbreviated Journal |
|
| Volume |
22 |
Issue |
|
Pages |
372-376 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3) |
| Abstract |
Both energy- and wavelength-dispersive systems were used to obtain Malpha/Lalpha intensity ratios for Ta, W, Pt, Au, Pb and Bi at various overvoltages. A table of these ratios corrected for matrix absorption and detector efficiency is presented, in addition to an interpolatory function of Malpha/Lalpha generated ratios vs. overvoltage, for each element. In addition, three different ZAF correction models were used to predict both detected and generated ratios. Finally, experimental Mbeta/Malpha ratios measured at different overvoltages are presented for the six elements considered. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1993MB01200008 |
Publication Date |
2005-05-28 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
|
Edition |
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| ISSN |
0049-8246 |
ISBN |
|
Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:6221 |
Serial |
8649 |
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| |
| Author |
Nowak, D.; Florek, M.; Nowak, J.; Kwiatek, W.; Lekki, J.; Chevallier, P.; Hacura, A.; Wrzalik, R.; Ben-Nissan, B.; Van Grieken, R.; Kuczumow, A. |
| Title |
Morphology and the chemical make-up of the inorganic components of black corals |
Type |
A1 Journal article |
| Year |
2009 |
Publication |
Materials science and engineering: part C: biomimetic materials |
Abbreviated Journal |
|
| Volume |
29 |
Issue |
3 |
Pages |
1029-1038 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Black corals (Cnidaria, Antipatharia) from three different sources were investigated with the aim of detecting inorganic components and their morphology. In general, the skeleton of black corals was composed of the chitin fibrils admixed with peptides and the chitin presence was confirmed by the X-ray diffraction (XRD), Fourier Transformed Infrared Spectrometry (FTIR) and microRaman Microscopy, the latter giving the opportunity of tracing single fibrils and their location. The composition and concentrations of the inorganic components of the black corals were measured, using a scanning electron microprobe and micro-Particle Induced X-ray Emission (µ-PIXE). The application of such instruments enabled the estimation of the constituent distributions in a microscale. The mapping option was the most useful technique of making analyses in these studies, just to reveal the composition of chamber-like cells. Analysis of the morphology and microstructure showed that there were three distinct regions within the coral: a core and the cells encircled with adjacent interface gluing strips. The majority of the elements analyzed were selectively distributed and segregated in a striking way in mentioned distinctive zones of the skeleton and it was detected for the first time. The core area was characterized by the relatively elevated concentrations of Ca. The measurements gave extremely clear images of the distribution of particular elements in the skeletal tissue, with I, Ca, K and Fe much more concentrated in the gluing zones, while C, N, Na and Mg present in the interiors of particular skeletal cells. The distribution of some elements (Mg, Fe) and some compounds (chitin) and functional groups (SS, CI) allows differentiating the biological and mechanical functions of particular fragments of the rods. The kinds of elements and their concentrations measured were essentially in compliance with rare data available in the literature. The Raman technique gave the additional qualitative information about the structure of gluing zone and the chitin fibrils and surrounding matrix inside the cell interior. |
| Address |
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Thesis |
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Place of Publication |
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Editor |
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Wos |
000266520400065 |
Publication Date |
2008-09-10 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
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Series Issue |
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Edition |
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| ISSN |
0928-4931 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
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Times cited |
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Open Access |
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| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:76024 |
Serial |
8284 |
| Permanent link to this record |
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| |
| Author |
Bruynseels, F.; Van Grieken, R. |
| Title |
Recombination reactions and geometry effects in laser microprobe mass analysis studied with 12C/13C bilayers |
Type |
A1 Journal article |
| Year |
1986 |
Publication |
International journal of mass spectrometry and ion processes |
Abbreviated Journal |
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| Volume |
74 |
Issue |
2-3 |
Pages |
161-177 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Bilayers of carbon, consisting of a layer of natural carbon and a second layer highly enriched in 13C, were investigated with the LAMMA 500-® instrument. When such a bilayer is perforated by the laser beam, comparable amounts of 12C and 13C are evaporated and partly ionized so that geometry effects and recombination reactions during laser-induced ionization can straightforwardly be studied. |
| Address |
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| Corporate Author |
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Thesis |
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| Publisher |
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Place of Publication |
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Editor |
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| Language |
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Wos |
A1986G343200003 |
Publication Date |
2002-07-25 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
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Edition |
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| ISSN |
0168-1176; 1873-2801 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:113611 |
Serial |
8461 |
| Permanent link to this record |
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| |
| Author |
Rojas, C.M.; Artaxo, P.; Van Grieken, R. |
| Title |
Aerosols in Santiago de Chile : a study using receptor modeling with X-ray fluorescence and single particle analysis |
Type |
A1 Journal article |
| Year |
1990 |
Publication |
Atmospheric environment: part B : urban atmosphere |
Abbreviated Journal |
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| Volume |
24 |
Issue |
2 |
Pages |
227-241 |
| Keywords |
A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
| Abstract |
Between 15 January and 26 February 1987, 51 fine and coarse mode aerosol samples were collected at the Universidad de Santiago de Chile Planetarium using a dichotomous sampler. The samples were analyzed by X-ray fluorescence for up to 17 elements (Mg, Al, Si, P, S, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br and Pb). Aerosol particles were individually studied by Electron Probe Microanalysis (EPMA) and Laser Microprobe Mass Analysis (LAMMA). The data set consisting of aerosol elemental concentrations and meteorological variables was subjected to Principal Factor Analysis (PFA), allowing the identification of six fine mode particle source classes (soil, industrial, sulfate particles, traffic, residual oil, wood-burnings), and five coarse mode particle source classes (soil, industrial, traffic, residual oil, sulfate particles). Both PFA solutions explained about 81 and 90% of the total variance in the data set, respectively. The regression of elemental mass concentrations on the Absolute Principal Factor Scores allowed the estimation of the contribution of the different source classes to the Santiago aerosol. Within the fine fraction, secondary SO42− particles were responsible for about 49% of the fine mode aerosol mass concentration, while 26, 13, 6.4 and 5.6% were attributed to wood-burning/car exhausts, residual oil combustion, soil dust/metallurgical, and soil dust/wood-burning releases, respectively. The coarse fraction source apportionment was mainly dominated by soil dust, accounting for 74% of the coarse mode aerosol mass concentration. A composite of soil dust and industrial release accounted for 13%; a composite of secondary sulfates contributed with 9%; a composite of soil dust and automotive emissions, and secondary sulfates were responsible for 4 and 0.03% of the coarse aerosol mass concentration, respectively. EPMA results are in satisfactory agreement with those from the bulk analysis and allowed the identification of eight particle types in both fine and coarse mode aerosols, pertaining to different source classes, namely soil, seaspray, secondary SO42−, metallurgical emissions and biomass burning release. EPMA also evidenced that one of the most abundant particle types corresponded to marine aerosol, having an average diameter of 0.7 μm for the fine mode and 2.2 μm for the coarse mode aerosol. LAMMA results indicate that, in fact, seaspray has been transported into the city of Santiago de Chile airshed, suffering several transformations and a sulfur enrichment. This analytical technique also provided evidence of the abundance of carbon-rich particles, which were not detected by either the bulk X-ray analysis or EPMA; they are probably due to fossil-fuel combustion releases. |
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| Corporate Author |
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Thesis |
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Place of Publication |
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Editor |
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| Language |
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Wos |
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Publication Date |
2003-08-06 |
| Series Editor |
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Series Title |
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Abbreviated Series Title |
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| Series Volume |
|
Series Issue |
|
Edition |
|
| ISSN |
0957-1272; 1878-2132 |
ISBN |
|
Additional Links |
UA library record |
| Impact Factor |
|
Times cited |
|
Open Access |
|
| Notes |
|
Approved |
no |
| Call Number |
UA @ admin @ c:irua:116456 |
Serial |
7427 |
| Permanent link to this record |
