Records |
Author |
Lv, H.; Meng, S.; Cui, Z.; Li, S.; Li, D.; Gao, X.; Guo, H.; Bogaerts, A.; Yi, Y. |
Title |
Plasma-catalytic direct oxidation of methane to methanol over Cu-MOR: Revealing the zeolite-confined Cu2+ active sites |
Type |
A1 Journal Article |
Year |
2024 |
Publication |
Chemical Engineering Journal |
Abbreviated Journal |
Chemical Engineering Journal |
Volume |
496 |
Issue |
|
Pages |
154337 |
Keywords |
A1 Journal Article; Direct oxidation Methanol production Plasma catalysis Copper-mordenite catalysts; Plasma, laser ablation and surface modeling Antwerp (PLASMANT) ; |
Abstract |
Efficient methane conversion to methanol remains a significant challenge in chemical industry. This study investigates the direct oxidation of methane to methanol under mild conditions, employing a synergy of nonthermal plasma and Cu-MOR (Copper-Mordenite) catalysts. Catalytic tests demonstrate that the Cu-MOR IE-3 catalyst (i.e., prepared by three cycles of ion exchange) exhibits superior catalytic performance (with 51 % methanol selectivity and 7.9 % methane conversion). Conversely, the Cu-MOR catalysts prepared via wetness impregnation tend to over-oxidize CH4 to CO and CO2. Through systematic catalyst characterizations (XRD, TPR, UV–Vis, HRTEM, XPS), we elucidate that ion exchange mainly leads to the formation of zeolite-confined Cu2+ species, while wetness impregnation predominantly results in CuO particles. Based on the catalytic performance, catalyst characterizations and in-situ FTIR spectra, we conclude that zeolite-confined Cu2+ species serve as the active sites for plasma-catalytic direct oxidation of methane to methanol. |
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Corporate Author |
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Publisher |
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Place of Publication |
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Editor |
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Language |
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Wos |
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Publication Date |
2024-08-02 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1385-8947 |
ISBN |
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Additional Links |
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Impact Factor |
15.1 |
Times cited |
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Open Access |
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Notes |
PetroChina Innovation Foundation, 2018D-5007-0501 ; Fundamental Research Funds for the Central Universities, DUT21JC40 ; Fundamental Research Funds for the Central Universities; China Scholarship Council; National Natural Science Foundation of China, 22272015 ; |
Approved |
Most recent IF: 15.1; 2024 IF: 6.216 |
Call Number |
PLASMANT @ plasmant @ |
Serial |
9260 |
Permanent link to this record |
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Author |
Fang, W.; Wang, X.; Li, S.; Hao, Y.; Yang, Y.; Zhao, W.; Liu, R.; Li, D.; Li, C.; Gao, X.; Wang, L.; Guo, H.; Yi, Y. |
Title |
Plasma-catalytic one-step steam reforming of CH₄ to CH₃OH and H₂ promoted by oligomerized [Cu-O-Cu] species on zeolites |
Type |
A1 Journal article |
Year |
2024 |
Publication |
Green chemistry : cutting-edge research for a greener sustainable future |
Abbreviated Journal |
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Volume |
26 |
Issue |
9 |
Pages |
5150-5154 |
Keywords |
A1 Journal article; Engineering sciences. Technology; Plasma Lab for Applications in Sustainability and Medicine – Antwerp (PLASMANT) |
Abstract |
Oligomerized [Cu-O-Cu] species are reported to be efficient in promoting plasma catalytic one-step steam reforming of methane to methanol and hydrogen, achieving 6.8% CH4 conversion and 73.1% CH3OH selectivity without CO2. |
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Corporate Author |
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Thesis |
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Publisher |
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Place of Publication |
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Wos |
001195192800001 |
Publication Date |
2024-04-02 |
Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1463-9262; 1463-9270 |
ISBN |
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Additional Links |
UA library record; WoS full record |
Impact Factor |
9.8 |
Times cited |
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Open Access |
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Notes |
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Approved |
Most recent IF: 9.8; 2024 IF: 9.125 |
Call Number |
UA @ admin @ c:irua:205514 |
Serial |
9165 |
Permanent link to this record |