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| Author | Leus, K.; Liu, Y.-Y.; Meledina, M.; Turner, S.; Van Tendeloo, G.; van der Voort, P. | ||||
| Title | A MoVI grafted metal organic framework : synthesis, characterization and catalytic investigations | Type | A1 Journal article | ||
Year  |
2014 | Publication | Journal of catalysis | Abbreviated Journal | J Catal |
| Volume | 316 | Issue | Pages | 201-209 | |
| Keywords | A1 Journal article; Electron microscopy for materials research (EMAT) | ||||
| Abstract | We present the post-modification of a gallium based Metal Organic Framework, COMOC-4, with a Mo-complex. The resulting Mo@COMOC-4 was characterized by means of N2 sorption, XRPD, DRIFT, TGA, XRF, XPS and TEM analysis. The results demonstrate that even at high Mo-complex loadings on the framework, no aggregation or any Mo or Mo oxide species are formed. Moreover, the Mo@COMOC-4 was evaluated as a catalyst in the epoxidation of cyclohexene, cyclooctene and cyclododecene employing TBHP in decane as oxidant. The post-modified COMOC-4 exhibits a very high selectivity toward the epoxide (up to 100%). Regenerability and stability tests have been carried out demonstrating that the catalyst can be recycled without leaching of Mo or loss of crystallinity. | ||||
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| Corporate Author | Thesis | ||||
| Publisher | Place of Publication | San Diego, Calif. | Editor | ||
| Language | Wos | 000340853800020 | Publication Date | 2014-06-19 | |
| Series Editor | Series Title | Abbreviated Series Title | |||
| Series Volume | Series Issue | Edition | |||
| ISSN | 0021-9517; | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
| Impact Factor | 6.844 | Times cited | 36 | Open Access | |
| Notes | European Research Council under the Seventh Framework Program (FP7); ; ERC Grant No. 246791 – COUNTATOMS; Hercules; FWO | Approved | Most recent IF: 6.844; 2014 IF: 6.921 | ||
| Call Number | UA @ lucian @ c:irua:117416 | Serial | 3546 | ||
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