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Author Vos, L.; Van Grieken, R.
Title Influence of ion energy-distributions and matrix effects on spark source-mass spectrometric analysis Type A1 Journal article
Year (down) 1983 Publication International journal of mass spectrometry and ion processes Abbreviated Journal
Volume 51 Issue 1 Pages 63-76
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The energy distributions of ions produced in a spark source mass spectrometer were recorded for different trace element ions and for the total ion current. Both electrodes of pure doped graphite, and with 10% potassium salts added, were examined. The results show that the measured energy of an ion is mainly determined by the m/z ratio and that the energy of the total ion current depends on the sample composition. It was also clear that if the accelerating voltage is set to obtain maximum transmission of the total ion current, the fraction of the heavy elements that is discriminated at the β-slit depends on the matrix composition if the pass band of the instrument is narrow. These effects influence considerably the accuracy in the analysis of variable samples.
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Corporate Author Thesis
Publisher Place of Publication Editor
Language Wos A1983QV48400008 Publication Date 2002-07-25
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0168-1176; 1873-2801 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:113624 Serial 8093
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